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Transition metal molecular glasses by design: Mexylaminotriazine-functionalizedsalicylaldehyde imine ligands
Supporting Information
Mahboubeh Jokar,† Michael Cherry,† Jennifer L. Scott*,† and Olivier Lebel*,†
† Department of Chemistry and Chemical Engineering, Royal Military College ofCanada, Kingston, ON, K7K 7B4, Canada
*Corresponding author: [email protected]; [email protected]
Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019
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Figure S1. DSC traces for precursor 1 and ligands 6-10, recorded at a heating rate of 5°C/min.
Figure S2. DSC traces for complexes 8Mn, 8Fe, 8Ni, 8Cu, 8Zn, 9Zn and 10Zn, recorded at aheating rate of 5 °C/min.
S2
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Position [°2θ] (Copper (Cu))θ] (Copper (Cu))] (Copper (Cu))
10 2θ] (Copper (Cu))0 30 40 50 60 70 80
Counts
0
500
1000
OL -VI-186-[RTS] Gonio 5-90 5min inorganic_1
Figure S3. Powder X-ray diffraction pattern for complex 8Co.
Figure S4. Thermal Gravimetric Analysis of complex 8Mn.
S3
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Figure S5. Thermal Gravimetric Analysis of complex 8Fe.
Figure S6. Thermal Gravimetric Analysis of complex 8Co.
S4
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Figure S7. Thermal Gravimetric Analysis of complex 8Ni.
Figure S8. Thermal Gravimetric Analysis of complex 8Cu.
S5
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Figure S9. Thermal Gravimetric Analysis of complex 8Zn.
Figure S10. Thermal Gravimetric Analysis of complex 9Zn.
S6
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Figure S11. Thermal Gravimetric Analysis of complex 10Zn.
NMR Spectra of New Compounds
S7
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