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ELECTROCERAMICS IV
Volume II
Electronic and Ionic ConductorsSuperconductorsIntegrated Functions and SubstratesMagneticsProcessing and Mechanical Properties
Edited by
R. Waser
and
S. HoffmannD. BonnenbergCh. Hoffmann
Institut fur Werkstoffe der Elektrotechnik (IWE)
RWTH Aachen, University of Technology
GERMANY
Augustinus Buchhandlung
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CONTENTS OF VOLUME 2
ELECTRONIC AND IONIC CONDUCTORS
Ceramic Materials for SOFC and Electrochemical Reactor TechnologyB.C.H. Steele 663
Trends in the Development and Application of Negative Temperature Coefficient OxideCeramics
A. Feltz 677
Electrical Transport in Highly Conducting TitanatesR. Moos, W. Menesklou, A. Gnudi, K.-H. Hardtl 685
Electrical Conductivity and Defect Structure in the System Sr Tii-xFex03_y (x = 0.1 - 0.8)S. Steinsvik, T. Norby, P. Kofstad 691
Theory of Oxygen Transport Through Mixed Conducting PerovskitesM.H.R. Lankhorst, H.J.M. Bouwmeester, H. Verweij 697
Protonic and Native Ionic Conductivity in OxidesT. Norby, Y. Larring 703
Ionic and Electronic Conductors for Solid Oxide Fuel CellsW. Schafer, D. StoRen 711
Ceramic Components for Solid Oxide Fuel Cell (SOFC) with Metallic InterconnectorE. Ivers-Tiffee, W. Wersing, H. Greiner 719
Impedance Spectroscopy Analysis of the Electric Behavior of Ceramic CompositesM. Kleitz. E. Djurado, P.O. Robert, M.C. Steil, F. Thevenot 725
Electrical Conductivity of LaMnO3-Based PerovskitesG. Stochniol, E. Syskakis, E. Wermelskirchen, A. Naoumidis, H. Nickel 733
Impedance Response of Yb-doped SrCeO3 in a Water Vapour Free EnvironmentM. Cappadonia, L.G.J. de Haart, Th. Matzke, U. Stimming 737
Vacuum-Tight Joints of Proton-Conducting SrCeO3 and (X-AI2O3 for Use in an ElectrochemicalHydrogen Gas Sensor
K. Vercammen 741
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Na-Beta-Alumina - a Mixed Ionic-Electronic ConductorH. Nafe 745
Dynamic Characteristics of SrTiO3 Thick Film as an Oxygen SensorS.-S. Cho, H.-G. Kim 749
Electrical Conductivity Change with Crystallization of Some Alkali Alumino Silicate GlassesS. N. Salama and Z. S. El Mandouh 753
Gas and Humidity Sensitive Electrical Properties of La2CuO4-ZnO Hetero-ContactsE. Traversa, A. Bearzotti, M. Mryayama, H. Yanagida 755
Ionic Conductivity Measurements of Natural Fluorite at Low TemperatureM.C. Amamra, H. Klimczyk, M. Rial, G. Petot-Ervas, C. Petot 759
Effects of Structural Disorder on the Optical Properties of Cubic Stabilized ZirconiaM. Bassi, P. Camagni, G. Samoggia, S. Torre 763
Electrical Properties of Sb-Doped SnO2 Powders, Ceramics, and Single CrystalsG. Bebr, J; Werner, P. Dordor, G. Couturier, D. Elefant 767
Lowering of the Cathode Overpotential of SOFC by Electrolyte DopingP. Bohac, A. Orliukas, L.J. Gauckler 771
Electrical Conductivity of P-Alumina Based ElectrolytesM.M. Bucko, G. Rog 775
Electrical Properties of Thick Film Silicon-Doped a-Fe2O3 Humidity SensorC. Cantalini, H.T. Sun, M. Faccio, G. Ferri, M. Pelino 777
Composite (YSZ+LSM) Ceramic Filters with High Oxygen Electrochemical PermeabilityA.D.S. Costa, J.A. Labrincha, F.M.B. Marques 781
Preparation and Properties of the High Temperature NTC Thermistor CeramicsM. Diaconescu, M. Anghel, V. GhHa, M. Nicolae 785
Influence of the Microstructure on the Ionic Conductivity of Yttrium Doped ZirconiaM. Rial, C. Lacour, M.C. Amamra, G. Petot-Ervas, C. Petot 789
Electrical Conductivity of the Brownmillerite-Structured Oxides, Ba2ln2-XMXO5C.A.J. Rsher, R.J. Brook 793
Humidity Sensitive and Varistor Tin Dioxide Based CeramicsA.B. Glot. A.M. Nadzhafzade, A.I. h/on 797
Solid Solutions of Ternary Oxide Ceramics as Active Materials for Humidity SensorsD.L. Hates, T. Hashemi, A.W. Brinkman 801
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Activation Volume of Proton Transport in NH4NDWO6R. Hinrichs, G. Tomandl, J.A.H. da Jornada 803
Oxide Ionic Conductivity of Lanthanum-Strontium Manganites CeramicsV. V. Kharton, A. V. Nicolaev, E. N. Naumovich, J. S. Gayduk, A. A. Vecher 807
Electrochemical and Structural Properties of SnO2 and Sb:SnO2 Transparent Electrodes withMixed Electronically Conductive and Ion-Storage Characteristics
U. Lavrencic Stangar, B. Orel, F. Svegl 809
Electrochemical Method of Determination of the Oxygen Diffusion Coefficient in ZirconiaM. Mokchah, M. Rial, C. Petot, G. Petot-Ervas 813
Thermopower of Highly Donor Doped Sri_xLaxTIO3-CeramicsR. Moos, A. Gnudi, K.-H. Hardtl 815
Oxide Ionic Conductors in the System Bi2O3 - PbO - Y2O3E. N. Naumovich, S. A. Skilkov, V. V. Kharton, A. A. Vecher 819
Oxide Ionic and Electronic Conductivity of SrCoi_xMxO3-
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Xll
Mechanical Relaxation Measurements in the Protonic Conductors SrCeO3 and SrZrO3L. Zimmermann, H.G. Bohn, W. Schilling, E. Syskakis 857
EPR Study of the Cerium Valence State in Nd2_xCexCuO4C.B. Azzoni, A. Pateari, F. Scardina, L. Bolis, G. Spinolo 861
Cathodic Polarization of Lao.9Mn03-$ Screen-Printed Electrodes on Thin YSZ ElectrolyteLayers
F.M. Figueiredo, JA. Labrincha, J.R. Frade, F.M. Marques 865
Thermoelectric Properties of CdIn2O4 with Spinel StructureY. Ochi 869
Low Temperature Sol-Gel Syntheses of the Cubic Zirconium Oxide for Ceramic SolidElectrolyte Production
M.V. Tsodikov, O.G. Ellert, O.V. Bukhtenko, D. I. Kochubey 873
Electrical Properties of Bioactive Ceramics in a Broad Frequency and Temperature RangeH. Rail, P. Lunkenheimer, J. Alkemper, H. Fuess, R. Bohmer, A. LokJI 875
Kinetics of Charge Carriers in Nd2CuO4 and Nd2Cui_xLix04_5 (0
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Xll l
EBSP and SIMS Studies of Oxygen Tracer Diffusion in the High Temperature SuperconductorLa2-xSrxCu04-6
J.CIaus, G.Borchardt, S.Weber, S.Scherrer 917
The Oxygen Content of the High-Temperature Superconducting CompoundBi2+xSr3_yCay Cu2Og.ni with Respect to Varying Ca and Bi Contents
P. Majewski, H.L. Su, F. Aldinger 923
Possible Application of HTSC Ceramics in Power EngineeringP. Komarek 929
Enhancement in Critical Current Density of Ultra-Fine MgO Added Bi-2212/Ag CompositeTape under Magnetic Field
H.-D. Kim, J.-W. Ko, S.-Y. Lee, K.-H. Ha, J.-H. Ahn, H.-S. Chung, K. Togano 939
Processing of YBaCuO by a Sol-Gel Precursor: Sintering and Weak Links BehaviourF.J. Gotor, P. Odier, N. Pellerin, A.R. Fert 945
Melt Processing of YBa2Cu3O7G.J. Schmitz 951
Phase Diagrams as the Guide for Microstructure Control of Y-Ba-Cu-0 CeramicsG. Krabbes, P. Schatzle, U. Wiesner, W. Bieger, G. Stover 957
Phase Equilibria in the System Bi203/Pb0-Sr0-Ca0-Cu0 with Special Regard to the(Bi,Pb)2Sr2Ca2Cu30io+d Phase
S. Kaesche, P. Majewski, F. Aldinger 961
Thin Films of YBa2Cu307_x for Microwave ApplicationsJ. Musorf, E. Waffenschmidt, X. He, F. Arndt, K. Heime 965
Preparation and Characterization of YBa2(Cui_xZnx)3O7-$ Thin FilmsM. Ye, M. Mehbod, R. Deltour, Y.F. Guo, C. De Boeck, P.H. Duvigneaud, G. Moorgat,F. Cambier 969
Phase Diagrams of the Systems La(Nd)2Cui_xLix04_5 and La(Nd)2CuLix04+ 8 >n a SubsolidusRegion
O.N. Razumovskaya, L.M. Rudkovskaya, L.A. Shilkina, V.I. Makarov 973
Electrochemical Deposition of Superconducting Bi-Sr-Ca-Cu-O and Tl-Bi-Sr-Ca-Cu-OFilms on Silver Substrate
S. Chatterjee, S. Banerjee, B.K. Chaudhuri 975
Controlled Precipitation of Pinning Centres During Melt Growth of Freeze Dried PrecursorsD. Dterickx, O. van der Biest, W. Boon, K. Rosseel, Y. Bruynseraede 979
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XIV
Influence of the Oxygen Partial Pressure During Cooling Procedure, and Mechnical Stresses onthe Superconducting Properties of Ag-Bi2Sr2CaCu2Ox Screen-Printed "Bipes
BA. Glowacki 983
Sol-Gel Chemistry of Y - B a - C u - 0 SystemM. Bele, S. Pejovnik 987
Synthesis of Single-Phase Bi2Sr3CaCu2Og+5 Superconductor by Spray-Drying Nitrate-EDTASolution and Characterization
Y.-F. Guo, P.-H. Duvigneaud 989
Low Temperature and Low P02 Preparation of Melt Quenched High-TemperatureSuperconducting Bi2212 Bulk Ceramics
P. Majewski, S. Kaesche 993
Preparation, Characterization and Optimization of YiBa2Cu3O7_3c and Bi2Sr2CaiCu2Og+8 ThinFilms
J. Auge, U. Rudiger, B. Beschoten, H.G. Roskos, G. Guntherodt, H. Kurz 997
Bi-Sr-Ca-Cu Superconducting Ceramics Prepared from Amorphous MaterialN. Nanba, M. Kokubun, K. Nagata 1001
Preparation and Densification of HTc (2223) Phase SuperconductorA. Tampteri, G. Celotti, G.N. Babini 1005
Ferroelectric and Superconducting Properties of YBa2Cu3O7_8—BaT103 CompositesSA. Gridnev, S.A. Fadeev, S.P. Rogova 1009
Determination of Temperature Dependence of Oxygen in YBa2Cu3Ox by Structure RefinementsBased on Powder X-Ray Diffraction Analysis
K. Ikeda, T. Horiuchi, H. Shima 1011
Low-J'ield Dependence of the Intergranular Jc Measured Using AC SusceptibilityA. Buekenhoudt, J. Cornells 1015
Polarized Dght Microstructure Analysis of DYBa2Cu3O7_x Melt Textured in Magnetic FieldP. Diko, M. Ausloos, R. Cloots 1019
7_x Superconductive Tapes and Wires: Suspension Spinning and Tape Casting Using aPhase Inversion Technique
H. Weyten, W. Adriansens, V. Bukenbergs, A. Buekenhoudt, R. Leysen, J. Comelis 1021
Densification of Y2BaCuOs Substrates for Solid-Liquid Processing of YBa2Cu3O7_xSuperconductive Layers
L. Ryelandt, J. Lapin, F. Delannay 1025
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Grain Growth in YBa2Cu3O7_x (123)-Y2BaCu05 (211) Sintered Powder CompositesI. Sargankova, P. Diko 1029
Relaxation of Mechanically Milled YBa2Cu3O7_x Studied by Differential Scanning CalorimetryI. Sargankova, P. Diko, S. Matas, J. Mihalik, M. Reissner, W. Steiner 1031
I N T E G R A T E D F U N C T I O N S A N D SUBSTRATES
Miniaturization and Integration of Passive Components by Multilayer Ceramic TechnologyA. Okamoto 1035
Ceramic Multilayer Modules: A New Concept for Integration of Passive ComponentsP.H.M. Keizer, W.R. De Wild 1045
Integrated Passive Functions: Toward a new Generation of ChipsH. Salze 1055
Composite "Moonie" Actuator and its ReliabiltiyA. Dogan, K. Uchino, R.E. Newnham 1061
Multilayer Electronic CeramicsD. Schmid, B. Hoffmann 1069
Improvement of Multilayer Chip LC Filters Utilizing a New Ceramic Material for HighFrequency, Low-Loss Functional Devices
U. Ender, B.E. Helms et al 1075
SAW Properties of La, Sm Modified Lead TStanate CeramicsC.E. Millar, L. Pedersen, L. Pardo, J. Ricote, C. Atemany, B. Jimenez.G. Feuillard,Y. Janin 1083
Modern Substrate Concepts for the Microelectronic IndustryA. Roosen 1089
Integrated SubstrateR.R. Tummala 1097
AI2O3-AI2O3 Laminnar CeramicsJ. Ravez, V. Andriamampianina, J.L. Miane, P. Letullier, J.M. Heintz 1105
Sintering and Properties of Aluminium Nitride SubstratesD. Ltoert 1107
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Sintering of Ruthenium Oxide-Based Resistive CoatingsA. Ntemann, G. Roche, P. Marchet, J.P. Mercurio 1111
Diffusion of Titanium into Alumina Ceramics using Active SoldersW.K. Wtosinski, W. Otesinska, A. Bien 1115
Problems of Surface Conductivity in Electrical Resistance Measurements and Their Implicationfor the R E D Effect
F. Scneuermann, W. Kestemich 1119
Fabrication and Characterization of Erbium-Doped LiNbO3 for Integrated OpticsM. Fleuster, L. Beckers, St. Bauer, W. Zander, Ch. Buchal, H. Holzbrecher, U. Breuer 1123
MAGNETICS
Recent Developments in Power FerritesJ. Pankert 1129
Effect of Additions on Electromagnetic Properties of High Frequency MnZn FerritesR. Lebourgeois, J.P. Ganne, S. Pignard, P. Garrin, B. Lloret 1137
Dry Pressing of Tliin -Walled Ferrite PotcoresM.J.M. de Graaf, R.J.A. van der Drift, H.J. Glass 1143
Low Temperature Sintering in Ni-Zn-Cu FerriteT. Nakamura, T. Tsutaoka 1149
Microcrystalline and Nanocrystalline Hexaferrites Prepared by the Glass Crystallization MethodP. GSrnert 1155
Magnetostrictive and Demagnetizing Phenomena in FerritesP. Perriat, M. Guyot 1157
3 D ^ E M Modelling of Ferrite Cores Power Losses and Corresponding Temperature DistributionM. Esguerra, R. Lucke 1159
Ferrimagnetic Thin Films Prepared by Pulsed Laser DepositionM. Guyot, R. Krishnan, A. Lifsi, M. Porte, M. Raibaut, P. Renaudin, P. Rougier, M. Tessier,V. Cagan 1165
The Preparation of Fe-Ferrite and its Magnetic PropertiesM. Alavi, J. Amighian, E. Musavi 1167
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Preparation of Isotropic Ba-Hexaferrite Using Hematite By-Product of Local Steel FactoryJ. Amighian, M. Mozaffari 1171
The Preparation and Thermal Properties of Cobalt Ferroxplana Single CrystalS.J. Kim, T.O. Kim 1175
Sol-Gel Derived Fine Hexaferrite ParticlesC. Surig, K.A. Hempel, D. Bonnenberg, J. Roumen, H.^J. Klaar 1179
Glass Crystallization of Nanocrystalline BaFei2-2XCoxTixOi9 ParticlesR. Muller, W. Schuppel, P. G6rnert 1183
About New Magnetic CoIn2Se4T. Koneshova, O.G. Ellert 1187
Microstructure and Electromagnetic Properties of Polycrystalline YIG Containing DopantsJ.-D. Lee, T.-O. Kim 1189
Magnetic Susceptibility and Dielectric Studies on Iron-Titanium Oxygen System at LowTemperatures
R.P. Viswanath, A.T. Seshadri 1193
Sol-Gel Processing of YIG Fibers and FilmsF. Essl, A. Thierauf, R. Jahn, D. Sporn, M. Baier, A. Forchel 1197
PROCESSING AND MECHANICAL PROPERTIES
Fracture of Dielectric Ceramics: A Brief ReviewG. de With 1 2 0 3
Crack Growth in Ferrroelectric Ceramics under Mechanical and Electrical LoadingG.A. Schneider, A. Rostek, B. Zickgraf, F. Aldinger 1211
Mechanical Reliability of Ferrite Cores: Thermo-Mechanical Stress in Operating Conditionsand in Strength Tests
LJ.M.G. Dortmans, M.J.M. de Graaf, G. de With 1217
Electric and Magnetic Field Contribution to the Microwave Sintering of CeramicsA. Cherradi, G. Desgardin, J. Provost, B. Raveau 1219
Spin-On Processing of Perovskite Thin Films for Innovative Microelectronic DevicesM.KIee 1 2 2 5
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Single Crystal Thin Films via Solution Precursor ProcessingF.F. Lange 1233
Chemical Homogeneity and Morphology of Alkoxy-Derived PZT PowdersM. Kosec, B. Malic 1245
Processing and Properties of Wet-Chemically Derived Modified PZT Thin FilmsS. Seifert, S. Meridein, W. Grond, A. Schonecker 1251
Surface Segregation, Microstructure and Sinterability of a -Alumina Powders Doped withMagnesium
M. Tebtoub, D. Monceau, M.C. Amamra, C. Petot, G. Petot-Ervas 1255
Low Sintering PZT by Liquid Phase FormationH.-O. Gesemann, A. Schdnecker 1259
Electrical Conductivity of LaCrO3 Sintered at Low Temperature (
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Novel Preparation Method and Properties of PTS and PZTS Glass-CeramicK. Yao, L. Zhang, X. Yao 1303
Preparation and Properties of ZnS Doped GlassH. Liu, S. Wang, S. Lu, L. Zhang, X. Yao 1307
PUT Powders from Water Soluble PrecursorsW. Liu, L Zhang, X. Yao 1311
Sol-Gel Synthesis and Characterization of a Conducting Ceramic/Metal CompositeS. Dandoy, I. Baukens, M. Ghodsi 1315
Processing and Physical Properties of Sol-Gel Derived Nanostructured Ni-ZrO2 CermetsJ. GroBmann, K. Rose, D. Sporn 1319
Zirconia-Tungsten ElectrocompositeS. Vives, C. Guizard, L. Cot, C. Oberlin 1323
Properties of Ceramics-Copper Joint "Directly Bonded" by Means of Copper-Carbon FibreComposite
W.K. Wlosinski, Z. Librant, W. Olesinska 1327
Electrotechnical Ceramics, Based on Porcelain Stones of KirgistanS.J. Jekisheva, T.I. Koneshova 1331
Electrotechnical Porcelain Based on Calcinated Caoline with Addition of MineralisatorG.N. Maslennikova 1333
Gel Cordierite for Electronic PackagingA. Goldstein, V. Belov, I. Belov 1335
Powder Preparation of Inorganic Materials by Spray DryingH.A.M. van Hal, W.A. Groen 1339
Electrophysical Properties of CasGasOu Single CrystalsS.L Londar 1343
Preparation of Materials with Controllable Grain Boundary Size from Water-Soluble Com-pounds
L.A. Reznitchenko, O.N. Razumovskaya, LA. Shilkina, V.A. Aleshin, V.I. Makarov,Yu.F. Korovin, V.G. Chiprinko, A.G. Okhapkin 1345
Conformational Mechanism of Pyroelectric Response in Macromolecules SystemsN.N. Matveev, A.F. Klinskikh 1349
A Possible Application of Volcanic Stones for Electric and Electronic CeramicsE. Albert 1351
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Preparation of La Doped Sr(Ti(i_y)Zry)O3 (y = 0... 1) Dielectric Ceramic Thin FilmsS. Hoffmann, M. Klee, R. Waser 1353
Hot-Forging of Ba6-3XSmg+2XTiigO54 Ceramics for Microwave ApplicationsCh. Hoffmann, R. Waser 1357
Pulsed Laser Deposition and Patterning of Electroceramic Thin FilmsM. Mertin, D. Offenberg, C.W. An, DA. Wesner, E.W. Kreutz 1361