Download - IR spectrum of A (Nujol, cm
![Page 1: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/1.jpg)
NH2·HOTfA
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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83,3
cm-1
%T
IR spectrum of A (Nujol, cm-1)
![Page 2: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/2.jpg)
1H NMR spectrum of A (DMSO-d6, 25 ºC)
![Page 3: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/3.jpg)
13 C APT NMR spectrum of A (DMSO-d6, 25 ºC)
![Page 4: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/4.jpg)
NH2·HOTfB
CO2MeH
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 450,00,0
5
10
15
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64,5
cm-1
%T
IR spectrum of B (Nujol, cm-1)
![Page 5: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/5.jpg)
1H NMR spectrum of B (DMSO-d6, 25 ºC)
![Page 6: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/6.jpg)
13 C APT NMR spectrum of C (DMSO-d6, 25 ºC)
![Page 7: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/7.jpg)
NHMe·HOTf
C
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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84,9
cm-1
%T
IR spectrum of C (Nujol, cm-1)
![Page 8: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/8.jpg)
1H NMR spectrum of C (DMSO-d6, 25 ºC)
![Page 9: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/9.jpg)
13 C APT NMR spectrum of C (DMSO-d6, 25 ºC)
![Page 10: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/10.jpg)
NH2Pd
AcO 2
1a-OAc
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400,00,0
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81,2
cm-1
%T
IR spectrum of 1a-OAc (Nujol, cm-1)
![Page 11: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/11.jpg)
1H NMR spectrum of 1a-OAc (DMSO-d6, 25 ºC)
![Page 12: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/12.jpg)
13 C APT NMR spectrum of 1a-OAc (DMSO-d6, 25 ºC)
![Page 13: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/13.jpg)
NH2Pd
Cl 2
1a-Cl
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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85
9092,5
cm-1
%T
IR spectrum of 1a-Cl (Nujol, cm-1)
![Page 14: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/14.jpg)
1H NMR spectrum of 1a-Cl (DMSO-d6, 25 ºC)
![Page 15: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/15.jpg)
13 C APT NMR spectrum of 1a-Cl (DMSO-d6, 25 ºC)
![Page 16: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/16.jpg)
NH2Pd
Br 2
1a-Br
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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95,9
cm-1
%T
IR spectrum of 1a-Br (Nujol, cm-1)
![Page 17: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/17.jpg)
1H NMR spectrum of 1a-Br (DMSO-d6, 25 ºC)
![Page 18: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/18.jpg)
NH2Pd
I 21a-I
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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85
89,6
1/cm
%T
IR spectrum of 1a-I (Nujol, cm-1)
![Page 19: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/19.jpg)
1H NMR spectrum of 1a-I (DMSO-d6, 25 ºC)
![Page 20: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/20.jpg)
13 C APT NMR spectrum of 1a-I (DMSO-d6, 25 ºC)
![Page 21: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/21.jpg)
NH2Pd
Cl 21b-Cl
CO2MeH
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 450,00,0
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70,7
cm-1
%T
IR spectrum of 1b-Cl (Nujol, cm-1)
![Page 22: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/22.jpg)
1H NMR spectrum of 1b-Cl (DMSO-d6, 25 ºC)
![Page 23: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/23.jpg)
13 C APT NMR spectrum of 1b-Cl (DMSO-d6, 25 ºC)
![Page 24: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/24.jpg)
NH2Pd
I 21b-I
CO2MeH
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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69,3
1/cm
%T
IR spectrum of 1b-I (Nujol, cm-1)
![Page 25: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/25.jpg)
1H NMR spectrum of 1b-I (DMSO-d6, 25 ºC)
![Page 26: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/26.jpg)
13 C APT NMR spectrum of 1b-I (DMSO-d6, 25 ºC)
![Page 27: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/27.jpg)
NHMePd
Cl 2
1c-Cl
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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8586,8
cm-1
%T
IR spectrum of 1c-Cl (Nujol, cm-1)
![Page 28: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/28.jpg)
1H NMR spectrum of 1c-Cl (DMSO-d6, 25 ºC)
![Page 29: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/29.jpg)
13 C APT NMR spectrum of 1c-Cl (DMSO-d6, 25 ºC)
![Page 30: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/30.jpg)
NHMePd
Br 2
1c-Br
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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9596,9
cm-1
%T
IR spectrum of 1c-Br (Nujol, cm-1)
![Page 31: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/31.jpg)
1H NMR spectrum of 1c-Br (CDCl3 + TMS, 25 ºC)
![Page 32: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/32.jpg)
NHMePd
I 21c-I
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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84,3
1/cm
%T
IR spectrum of 1c-I (Nujol, cm-1)
![Page 33: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/33.jpg)
1H NMR spectrum of 1c-I (DMSO-d6, 25 ºC)
![Page 34: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/34.jpg)
13C NMR spectrum of 1c-I (DMSO-d6, 25 ºC)
![Page 35: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/35.jpg)
PdN
I 2
CMe2
2
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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65
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85
90
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98,7
cm-1
%T
IR spectrum of 2 (Nujol, cm-1)
![Page 36: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/36.jpg)
1H NMR spectrum of 2 (DMSO-d6, 25 ºC)
![Page 37: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/37.jpg)
13 C APT NMR spectrum of 2 (DMSO-d6, 25 ºC)
![Page 38: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/38.jpg)
PdNH2
PhosS Cl
3a-Cl
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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88,0
cm-1
%T
IR spectrum of 3a-Cl (Nujol, cm-1)
![Page 39: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/39.jpg)
1H NMR spectrum of 3a-Cl (CD2Cl2, 25 ºC)
![Page 40: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/40.jpg)
3a-Br
PdNH2
PhosS Br
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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105107,0
cm-1
%T
IR spectrum of 3a-Br (Nujol, cm-1)
![Page 41: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/41.jpg)
1H NMR spectrum of 3a-Br (CD2Cl2, 25 ºC)
![Page 42: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/42.jpg)
NH2Pd
PhosS I3b-I
CO2MeH
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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76,1
1/cm
%T
IR spectrum of 3b-I (Nujol, cm-1)
![Page 43: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/43.jpg)
1H NMR spectrum of 3b-I (CDCl3 + TMS, 25 ºC)
![Page 44: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/44.jpg)
PdN
Ph3P I
CMe2
4
4000,0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 200,00,0
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100
105
110
115117,5
cm-1
%T
IR spectrum of 4 (Nujol, cm-1)
![Page 45: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/45.jpg)
1H NMR spectrum of 4 (CDCl3 + TMS, 25 ºC)
![Page 46: IR spectrum of A (Nujol, cm](https://reader031.vdocument.in/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea92/html5/thumbnails/46.jpg)
13 C APT NMR spectrum of 4 (CDCl3+ TMS, 25 ºC)