![Page 1: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/1.jpg)
L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle
Spatial patterns of cadmium and lead deposition on National Park Service
lands near Red Dog Mine
![Page 2: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/2.jpg)
#Y
#Y
#Y
#
Kivalina
Kotzebue
Noatak
CapeKrusensternNational
Monument
Kilometers
0 2010
Noatak River
Kobuk River
Chukchi Sea
Port Site
Red Dog Mine
DMTS Haul Road
Alaska
Area of Detail
67°
67°
68°
68°
165°
165°
163°
163°
161°
161°
Study Area
![Page 3: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/3.jpg)
Objectives
1. Determine the spatial patterns and distribution of airborne heavy metal deposition on Monument lands (= this presentation)
2. Identify potential sources of these airborne heavy metals (see manuscript)
![Page 4: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/4.jpg)
Study Design
Collected Moss• Hylocomium splendens• Unwashed• Analyzed for heavy metals &
crustal elements (Al, Fe)
Collected Soil• Subsurface (depth 30”)• Unaffected by surface
activities
![Page 5: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/5.jpg)
#S#S#S
#S
#S#S
#S
#S
#S#S#S
#S#S
#S#S#S
#S#S
#S
#S#S
#S
#S
#S#S
#S#S#S
#S#S#S#S#S#S#S#S#S#S#S#S
#S#S#S#S#S
#S#S#S#S#S#S#S
#S#S#S#S#S#S
#S#S#S#S#S#S#S#S#S
#S#S#S#S#S#S
#S#S
#S#S
#S#S#S#S
#S#S#S#S#S#S#S#S
#S#S
#S#S#S#S#S#S
#S#S#S#S#S
#S#S#S
#S#S#S#S#S
#S#S#S
#S#S#S#S
#S#S#S
#S#S#S#S
#S#S
#S#S#S#S#S
#S#S#S#S
#S#S#S#S#S#S
#S#S#S #S
#S#S#S#S#S#S
#S#S#S#S
#S
#S#S#S
#S#S#S
#S#S#S
#S#S#S#S
#S#S#S#S
#S#S#S
#S
#S#S
#S
#S
#S#S#S#S#S
#S#S#S
#S#S
#S
#S#S#S#S
#S#S
#S
#S#S#S
#S#S
#S#S#S
#S
#S
#S#S#S#S#S
#S#S
#S#S
#S#S
#S#S#S#S#S#S#S
#S#S
#S
#S#S#S
#S
#S
Chukchi Sea
Strata 5
#S#S
#S
#S
#S#S
#S
#S
#S#S
#S
#S
#S
#S
#S
#S
#S#S
#S
#S#S
#S
#S
#S#S
#S#S#S
#S#S#S
#S#S#S#S#S#S#S#S
#S
#S#S #S#S#S
#S
#S#S
#S#S#S#S
#S#S#S
#S
#S#S
#S
#S #S#S
#S#S#S
#S#S
#S#S#S#S#S #S
#S#S
#S#S
#S#S
#S#S
#S#S#S#S#S#S#S#S
#S#S
#S#S
#S#S
#S#S
#S #S#S#S
#S
#S#S
#S
#S#S#S#S#S
#S
#S#S
#S#S
#S#S
#S#S
#S
#S#S#S#S
#S#S
#S#S
#S#S
#S
#S#S#S
#S
#S#S
#S#S#S#S
#S
#S
#S#S
#S#S#S
#S#S#S
#S
#S#S
#S
#S
#S#S
#S
#S#S
#S
#S#S#S
#S
#S#S
#S
#S
#S#S
#S
#S#S
#S
#S
#S#S
#S#S#S
#S#S
#S
#S#S
#S#S#S#S#S
#S
#S
#S#S
$
Strata 1 & 2
Stratum 3
Stratum 4
Stratum 5
Stratum 6
Not to scale
Road Corridor DetailStratum 8
Stratum 7
Kilometers
0 10 20
* Northwest Arctic Native Association
$
Stratum 8: north of Monument
DMTS Haul Road
NANA* land
Cape Krusenstern National Monument
Field Lab
Stratum 7: southern portion of Monument
Legend
#S
Stratum 6: 1000 - 1600 m from road
Stratum 3: 10 - 250 m from road
Stratum 2: 0 - 10 m from road (not shown)
Stratum 5: 100 - 1000 m from NANA* boundary
Stratum 4: 1 - 100 m from NANA* boundary
Stratum 1: 0 - 10 m from road (not shown)
Sample Collection Locations
Study Design
• Centered on haul road
• 45 mi (70 km) north and south of road
• Intensified sampling near road & port
• 155 grid cells
• 226 moss samples
![Page 6: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/6.jpg)
Sources
Moss versus Soil
Moss patterns are not due to subsurface geology
-2
-1
0
1
2
3
4
5
Analyte (mg/kg dw)
-6 -5 -4 -3 -2 -1 0 1 2 3 4 5 6 Distance from DMTS haul road (m)
Figure 8a. Moss (n = 154)
Cd
Pb
Zn
Al
-2
-1
0
1
2
3
4
5
6
Analyte (mg/kg dw)
-6 -4 -2 0 2 4 6
Distance to DMTS haul road (m)
Figure 8b. Soil (n = 46)
N S
N S
Cd
Pb
Zn
Al
45 mi45 mi
45 mi 45 mi
![Page 7: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/7.jpg)
#Y
#Y
#Y
#Y
#Y
#Y
#S
#S
Pb (mg/kg dw)
0 10 20
Kilometers
10
Not to scale
0.05 Quantile Map
NANA Regional Corp. land(not sampled)
#S Port site
Village#Y
DMTS haul road
Cape Krusentsern National Monument boundary
Not to scale
0.95 Quantile Map
PbPrediction
Map
0 - 2 *2 - 55 - 1010 - 2020 - 4040 - 8080 - 140140 - 400 400 - 1000
#Y
#Y
#Y
#S
(NOTE: 20 km = 12 miles)
Lead (Pb)
• Road and port gradient
• Lowest in southern portion of Monument
• Northern areas higher than southern areas
• Entire northern portion of Monument affected
• Mine-related deposition 15 miles north of road
Depositional Patterns
![Page 8: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/8.jpg)
Depositional Patterns
Lead (Pb)
• Metals decrease with distance from haul road
• Metals decrease with distance from port site
#S
#S Port site
Pb (mg/kg dw)
NANA Regional Corp. land(not sampled)
DMTS haul road
Cape Krusentsern National Monument boundary
3 0 3 6
Kilometers
1 - 22 - 55 - 1010 - 2020 - 4040 - 8080 - 140140 - 400400 - 1000
NOTE: 6 km = 3.5 miles
![Page 9: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/9.jpg)
Context
Regional moss sampling locations
Lead
Median
Lead Range
Cadmium Median
Cadmium Range
REGIONAL DATA:
Ford et al. 1995 0.6 0.4 – 2.3
0.15 0.02 – 0.48*
CURRENT STUDY:
< 30 ft from haul road (Stratum 1)
448 271 – 912
11.6 6.9 – 24.3
> 30 ft from haul road (Strata 2 – 8)
15 1 – 350
0.5 0.09 – 7.98
Study Area Data ComparisonElemental data in ppm (= mg/kg dw)
![Page 10: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/10.jpg)
Topography
as related to depositional patterns
#Y
#Y
![Page 11: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/11.jpg)
as related to
depositional patterns
Wind
• Bulge = Fallout zone
![Page 12: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/12.jpg)
Deposition in Outlying Areas
South of Haul Road
• Least affected portion of study area
• Equal to regional background levels* by Igichuck Hills
#Y
#Y
#Y
#Y
#Y
#Y
#S
#S
Pb (mg/kg dw)
0 10 20
Kilometers
10
Not to scale
0.05 Quantile Map
NANA Regional Corp. land(not sampled)
#S Port site
Village#Y
DMTS haul road
Cape Krusentsern National Monument boundary
Not to scale
0.95 Quantile Map
PbPrediction
Map
0 - 2 *2 - 55 - 1010 - 2020 - 4040 - 8080 - 140140 - 400 400 - 1000
#Y
#Y
#Y
#S
(NOTE: 20 km = 12 miles)
* Ford et al. (1995) arctic Alaska maximum = 2.3 mg/kg dw Pb
![Page 13: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/13.jpg)
Deposition in Outlying Areas
North of Haul Road
• Fallout zone/bulge
• Mine-related versus natural sources (or both)
• Background level comparison (2 ppm Pb)
Actual Pb concentrationsin stratum 8
Surface ornear-surfacelead sulfidedeposits
#Y
#Y
#Y
#Y
7
PbContour Map
Pb concentrationin 1 mg/kg dw intervals
Cape Krusenstern National Monument boundary
DMTS haul road
Northwest Arctic Native Assoc. (NANA) land
#Y Village
9 0 9 18
Kilometers
7
24
7
677
7
18
23
4210
3
17
17
Pb tissue concentrations (mg/kg dw) at Stratum 8 sample points
Not to scale
![Page 14: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/14.jpg)
Summary
1. Very high heavy metal levels along haul road
2. Decrease with distance from road and port
3. Mine-related deposition occurs throughout the northern half of the Monument
4. Moss patterns not attributable to subsurface geology at sample points
![Page 15: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/15.jpg)
Summary
5. SOUTH of road • Constrained by topography
• Lowest levels at Igichuck Hills
– Deposition unlikely to occur in Kotzebue and south
6. NORTH of road
• Deposition extends 15 miles or more
• Levels not high in far north (e.g., 7-15 ppm Pb)
• Beyond 15 miles, source = mine-related or natural, or both
![Page 16: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/16.jpg)
Summary
Future NPS Studies (NRPP)2005: Risk Assessment review2005-6: Small mammals along haul
road
Full Report Available• On-line: www/nps.gov/AKSO
• In Press: Science of the Total Env’t
• Hard Copies from NPS in Kotzebue
![Page 17: L. Hasselbach, J. M. Ver Hoef, J. Ford, P. Neitlich, E. Crecelius, S. Berryman, B. Wolk and T. Bohle Spatial patterns of cadmium and lead deposition on](https://reader035.vdocument.in/reader035/viewer/2022062320/56649d045503460f949d8372/html5/thumbnails/17.jpg)
END