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Laboratory Measurements of Primordial Chemistry.
Daniel Wolf SavinColumbia Astrophysics Laboratory
Xavier UrbainUniversité catholique de Louvain
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousand
~ 15 million
Outline
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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H(0.9)
He (0.1)Li (10-10)
GravityAs volume decreases temperature increases
γ
γ
γ
γ
Cloud cools byH radiation
T 8000 K
Structure formation in the early universe
What happens below 8,000 K?
H2 (.01%)
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Molecular H2 can radiatively cool the gas down to T ~ 200 K.
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H2 Formation during Epoch of Protogalaxy and First Star Formation
Associative detachment (AD)
H- + H → H2 + e-
How well do we understand this simple reaction?
And what are the cosmological implications?
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There is nearly an order of magnitude spread!What are the cosmological implications of this?
Published AD data for H- + H → H2 + e-
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Implications for Protogalaxy Formation
• Initially ionized gas (Pop III.2).
• 3D simulation.
• Curves is for limits of H- + H → H2 + e-
rate coefficient.
•
• MJ uncertain by factor of 20. (Kreckel et al. 2010, Science, 329, 69)
Fragmentation mass scale related to Tgas minimum (Larson MNRAS 2005).
Number density n (cm-3)
Tem
pera
ture
(K)
3/2 1/2JM T n
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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We use a merged beams technique.
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We use a merged beams technique.
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We use a merged beams technique.
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We use a merged beams technique.
Varying the floating cell potential Uf allow us to control the relative energy between the beams.
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We use a merged beams technique.
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We use a merged beams technique.
After the AD process EH2 ≈ EH- + EH ≈ 20 keV.
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We use a merged beams technique.
How to separate the 100 s-1 H2 from the 1011 s-1 of H?
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We use a merged beams technique.
We do this by ionizing ~ 5% of the H2 and H.
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We use a merged beams technique.
We do this by ionizing ~ 5% of the H2 and H.
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We use a merged beams technique.
The signal-to-noise ratio at this point is ~ 10-9.
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We use a merged beams technique.
We use an electrostatic energy analyzer to separate the 20 keV H2
+ from the 10 keV H+.
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The day after we first got signal.
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Celebrating our success!
K. A. Miller, DWS, H. Kreckel, X. Urbain, H. Bruhns
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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The experimental AD rate coefficient
Converting RH2+ to RH2
Beam densities
Overlap factor (emission measure)
-
-
2H H
ad rst He H H
1(1 )e v vSv
N f I I
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Our measured AD rate coefficient
Circles – data pointsError bars – statisticsDotted – systematics Solid – Čížek et al.Dashed – Langevin
Excellent agreement with Čížek et al. in both energy dependence and magnitude.
Kreckel et al. 2010, Science 329, 69Miller et al. 2011, PRA, 84, 052709
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Rate coefficient implications
Good agreement with Čížek et al. suggests past experimental and theoretical work is incomplete.
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Implications for Protogalaxy Formation
• Initially ionized gas (Pop III.2).
• 3D simulation.
• Red & black due to previous AD uncert.
• Other points show new ±25% uncert.
• MJ uncertainty goes from 20 to 2! (Kreckel et al. 2010, Science, 329, 69)
Fragmentation mass scale related to Tgas minimum (Larson MNRAS 2005).
Number density n (cm-3)
Tem
pera
ture
(K)
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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There is nearly an order of magnitude spread!
H- destruction reduces H2 formation
H- + H+ → H + H
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Implications for Protogalaxy Formation
• Initially ionized gas.
• 3D simulation.
• Each curve is for different values of H- + H+
→ H + H.
• Can a cloud form a protogalaxy before it is gravitationally disrupted? (Glover et al. 2006, ApJ, 641, 157)
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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Experimental setup at UCLouvain
A
B-
+
A+
-B
AB+
Source ECR
Source duoplasmatron
H+
H-
Mutual neutralizationH+ + H-
→ H + HECR (H+)
Duoplasmatron (H-)Associative ionization
H+ + H- → e- + H2
+
10-10 mbar
Bias cell
MagnetCEM for AI products
Detectors for MN products
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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What was the mass of the first stars?
AD and MN important for Pop III.2 formation.
Both important when cloud is < 0.01% H2.
Both play key role in setting upper limit for MJ.
But mass of the first stars still a big unknown.
Depends on physical conditions of initial cloud.
It also depends on the chemistry that converts the cloud to fully molecular H2.
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How does the cloud go fully molecular?Three Body Association (3BA)
H + H + H → H2 + H
(Turk et al. 2011, 726, 55)
Abel et al. (2002)Palla et al. (1983)
Flower & Harris (2007)
Uncertain by factor of ~ 100 at relevant T.Important in both Pop III.1 and III.2 formation.
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Implications of 3BA uncertainty.
Has potentially important implications for ability of gas to fragment and form multiple stars.
(Turk et al. 2011, ApJ, 726, 55)
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I. H- + H → H2 + e-
a. Importance b. Experiment c. ResultsII. H- + H+ → H + H a. Importance b. Experiment c. ResultsIII. H + H + H → H2 + H a. Importance b. Experiment?
First Stars(Pop III)
~ 377 thousandOutline
~ 15 million
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Experimental challenges of measuringH + H + H → H2 + H
• How to create a volume of neutral H largely uncontaminated?
• How to separate neutral daughter H2 from neutral parent H?
• Somehow create H2+ in a volume V ≈ 1 mm3.
• Rate coefficient α ≈ 10-33 – 10-30 cm6 s-1.
• R = αnH3V and for R = 1 s-1 gives nH ≈ 1012 cm-3.
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How to generate nH ≈ 1012 cm-3 ?• Compressed spin
polarized H– T ~ 600 mK is too low.
• H Bose-Einstein condensates– nK temperatures.
• Photodetachment of H-
– nH ≈ 103 cm-3.
• Discharges– Chemistry too complex.
• Tokamak neutral beam injectors– nH < 1010 cm-3 (70% pure).
• Cracked atom source– nH < 1010 cm-3 (99% pure).
• Pulsed gas jet discharges– nH
< 1010 cm-3 (~ 30% pure).
• Is it beyond current lab capabilities?
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Conclusions
• We have performed the first energy dependent measurements for the H- + H → H2 + e- reaction.
• We have resolved the dilemma of the low energy behavior of H- + H+ → H + H.
• Both these results will improve cosmological models for protogalaxy and first star formation.
• Experimental studies of H + H + H → H2 + H seem just beyond current technical capabilities.
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Collaborators
C. C. HavenerOak Ridge National Lab
M. RappaportWeizmann Institute of Science, Rehovot, Israel
Simon C. O. GloverUniversität Heidelberg,Germany
Martin ČížekCharles University Prague, Czech Republic
Hjalmar Bruhns, Holger Kreckel, M. Lestinsky, Ken A. Miller, W. Mittumsiri, B. Seredyuk, M. Schnell, B. Schmitt
Julien Lecointre, Ferid Mezdari