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Lecture 9: Evaporation
Key Questions
1. What is a evaporation?
2. Why does evaporation cool water?
3. What are the main energy inputs into a lake?
4. What is a vapor pressure deficit?
5. How does wind sustain lake evaporation?
6. What cause lake effect snow? evaporation
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Evaporation is the net loss of water from a liquid surface that results from a phase change from a liquid to a vapor.
It is a net process because water vapor is constantly moving back and forth from the water surface.
Evaporation occurs when there are more molecules leaving the water surface then entering.
water surface
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water is polar_
++
Remember, water is a polar molecule. Liquid water is a collection of molecules connected by hydrogen bonds.
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It takes energy for a molecule to break a hydrogen bond and escape the water surface.
water surface
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Phase changes involve heat (energy) exchanges (latent heat )
condensation releases heat
evaporation requires heat
liquidvapor
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The collective motion of water molecules in the water is called kinetic energy. The average kinetic energy of the molecules quantifies the water temperature.
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Molecules with the highest kinetic energy can break the hydrogen bonds and escape the water surface.
Thus, reducing the water temperature because the average kinetic energy is reduced (heat is removed).
water surface
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Evaporation cools off the water!
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Evaporation cools off the water!
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http://www.pinnacleint.com/evap.html
Swamp Cooler (evaporation cools)
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water vapor
cooling towers are designed to evaporate, hence cool water
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What drives evaporation?
1) Energy input to the water to supply heat (i.e., increasethe kinetic energy so molecules can escape).
2) Diffusion of water vapor molecules from the water surface to theatmosphere.
3) Transport of water vapor molecules away from the water surface.
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Heat Inputs
1. Solar radiation is the main source of heat to a lake.
water surface
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Heat Inputs
1. Solar radiation is the main source of heat to a lake.
The amount of solar radiation depends on the time of year and latitude.
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Heat Inputs
1. Solar radiation is the main source of heat to a lake.
The amount of solar radiation depends on the time of year and latitude.
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North Shore Meteorological (MET) Station
Measures rain, temperature, humidity, wind speed, wind direction, and solar radiation
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Jan Jul Dec
Average daily solar radiation collected at the North Shore MET stationSolar R
adiatio
n (W
/m2 )
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2. Longwave radiation (heat) reflected off the clouds
water surface
Heat Inputs
warm
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Heat Inputs
3. Sensible heat - heat conducted to the water from the warm air
water surface
warm air
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LongwaveSensibleSolar
Modeled Heat Inputs into Lake Whatcom
Oct Apr Sep
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What drives evaporation?
1) Energy input to the water to supply heat (i.e., increasethe kinetic energy so molecules can escape).
2) Diffusion of water vapor molecules from the water surface to theatmosphere.
3) Transport of water vapor molecules away from the water surface.
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Actual vapor pressure is a measure of the amount of water vapor molecules present in a given parcel of air.
low vapor pressure high vapor pressure
ea = actual vapor pressure
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cool air has a low saturation vapor pressure
warm air has a higher saturation vapor pressure(more water molecules)
Saturation vapor pressure is the maximum amount of water vapor a parcel of air could hold at a specific temperature (which decreases with temperature).
esat = saturation vapor pressure
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Saturation vapor pressure is the maximum amount of water vapor a parcel of air could hold at a specific temperature (which decreases with temperature).
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water vapor will condense because the saturation vapor pressure decreases
If warm, humid air is cooled off
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Relative humidity is the ratio of the amount of water vapor in a parcel of air (absolute vapor pressure) to how much water vapor the parcel could hold at a given temperature (saturation vapor pressure).
relative humidity =
Dew point temperature is the temperature at which a parcel of air reaches saturation.
actual vapor pressure
saturation vapor pressureX 100
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Diffusion or Vapor Transfer
water surface
water temperature
thin boundary layer of air that is fixed at the water temperature
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Diffusion or Vapor Transfer
water surface
water temperature
the boundary layer is always saturated with water vapor
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Diffusion or Vapor Transfer
water surface
water temperature
the magnitude of the vapor pressure is determined by the water temperature
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Diffusion or Vapor Transfer
water surface
warm water
higher vapor pressure
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Diffusion or Vapor Transfer
water surface
cool water
low vapor pressure
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Variables
ea = actual vapor pressure of the air
esat(Tw) = saturation vapor pressure of the boundary layer
esat(Tair) = saturation vapor pressure of the air
Tw = temperature of the water
Tair = temperature of the air
esat(Tw) - ea is called the vapor pressure deficit
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Diffusion or Vapor Transfer
water surfaceTw
esat(Tw)
ea
Tair
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Diffusion or Vapor Transfer (evaporation)
water surfaceTw
esat(Tw)
ea
Tair
If ea < esat(Tw) then molecules will diffuse from the boundary layer to the air
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Diffusion or Vapor Transfer (no net evaporation)
water surface
cool water
esat(Tw)
ea
Tair
If ea = esat(Tw) then molecules will diffuse back and forth
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Diffusion or Vapor Transfer (condensation)
water surface
cool water
esat(Tw)
ea
Tair
If ea > esat(Tw) then molecules will diffuse from the air to the boundary layer
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What drives evaporation?
1) Energy input to the water to supply heat (i.e., increasethe kinetic energy so molecules can escape).
2) Diffusion of water vapor molecules from the water surface to theatmosphere.
3) Transport of water vapor molecules away from the water surface.
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Diffusion or Vapor Transfer
water surfaceTw
esat(Tw)
ea
Tair
Wind sustains the deficit by sweeping moist air away from the water surface if ea < esat(Tw) then evaporation continues
high deficit low deficit
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I use a numerical model based on the Penman method and data from the MET station to estimate the evaporation off of Lake Whatcom each year.
Lake Whatcom
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inches
Oct Apr Sep
Modeled evaporation from Lake Whatcom in 2009-2010(about 20 inches total)
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On a sunny summer day, the lake evaporates about as much water as the City of Bellingham withdrawals in a given day - about 20 million gallons!
Lake Whatcom
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Lake Powel (Utah/Arizona) is a reservoir on the Colorado River. It evaporates about 10 feet of water per year.
Glen Canyon Dam
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Evaporation pans are used to estimate lake evaporation
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Lake Effect Snow
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Lake Effect Snow
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Lake Effect Snow
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nasaimages.org
Lake Effect Snow
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groundwater recharge
Evaporation is the phase change from liquid to a vapor
Which beaker evaporates more water and why?
cover
ice bathhot water