Download - Nantucket Compost Fact Sheet and Lab Report
Nantucket Natural Compost-PFAS Fact Sheet (information current as of February 5, 2021) Page 1 of 4
Nantucket Compost Fact Sheet and Lab Report Nantucket Compost is the co-compost from Municipal Solid Waste (MSW) and biosolids (also known as residuals generated by the Wastewater Treatment Facility (WWTF)) that are processed and screened through the compost facility then subsequently mixed with leaf/yard waste. The Town has begun quarterly PFAS sampling of our Nantucket Compost product using an appropriate protocol and a laboratory approved by Massachusetts Department of Environmental Protection (MassDEP), and in compliance with their Approval of Suitability (AOS) permit. The AOS is a co-permit with the Town and its vendor Waste Options Nantucket (WON). Neither MassDEP nor the U.S. EPA have set PFAS standards for biosolids, compost or other land application media. This Fact Sheet provides a summary of PFAS-related information associated the AOS co-compost sampling results. On October 28, 2020, WON began quarterly testing of Nantucket Compost in compliance with requirements of MassDEP’s AOS permit and the results are presented below. The testing Lab Report is attached for reference.
In the absence of PFAS screening levels or loading limits for Massachusetts in 2020, the results were compared to established available screening limits for use as a soil amendment in the State of Maine. The results found the levels of PFAS in Nantucket compost to be below the Maine DEP screening levels.
The bar chart below shows the Nantucket Compost PFAS sampling results alongside the Soil Beneficial Use screening levels per Maine Solid Waste Management Rules: Beneficial Use of Solid Wastes (2018). Please see https://www.maine.gov/dep/spills/topics/pfas/Maine-PFAS-Screening-Levels-11-2020.pdf. These compounds include perfluorooctanoic acid (PFOA), and perfluorooctanesulfonic acid (PFOS).
Nantucket is permitted to beneficially reuse Nantucket Compost as soil enhancements in compliance with the MassDEP AOS permit. Currently, this compost product is used only at the Landfill Facility and is not distributed to the public.
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PFOA PFOS
PFAS Concentrations in Nantucket Compost versus Maine DEP Screening Levels in parts per billion (ng/g)
Nantucket Compost (sampled 10-28-2020) Maine DEP screening level
Nantucket Natural Compost-PFAS Fact Sheet (information current as of February 5, 2021) Page 2 of 4
Nantucket Natural Compost samples were analyzed using U.S. EPA Method 537 Modified. The sample results are summarized in the table below and the raw data are available in the analytical laboratory report posted on the Town’s website: https://nantucket-ma.gov/1574/PFAS
NANTUCKET NATURAL COMPOST TEST RESULTS FOR PFAS COMPOUNDS (Sampled 10/28/2020):
*1 part per billion is equal to 1 second in 31.7 years. We can now measure PFAS in parts per trillion which is equal to 1 eyedrop of water in 20 Olympic size swimming pools (13.2 Million gallons of water).
At this time, MassDEP does not have a standard by which to evaluate PFAS in compost materials. MassDEP indicates that they will use all PFAS data collected from AOS permit holders from around the Commonwealth to develop a standard, and the Town is working with MassDEP to confirm a timeframe.
Nantucket Natural Compost-PFAS Fact Sheet (information current as of February 5, 2021) Page 3 of 4
PFAS is not created in the composting process. PFAS in the compost materials comes from an assortment of products used by households and businesses. PFAS also enter the wastewater treatment system, end up in the residuals that go to the landfill for composting, and are contained in many of the solid waste items sent to the landfill.
Our challenge is to eliminate the sources and reduce the amount of PFAS entering our environment. Major sources of PFAS include firefighting foam, carpeting, fast food containers and wrappers, pizza boxes, popcorn bags, candy wrappers and other food packaging, paints, surfactants, adhesives, floor waxes, non-stick cookware, denture cleaners, other personal care products such as shampoo and cosmetics, and water-resistant coatings (via washing machines). There are things you can do as a consumer to help reduce the amount of PFAS that ends up in the environment by encouraging the responsible use of these products or decreasing their use entirely, contacting elected officials to pass regulations on the use of these products, and promoting elimination of PFAS as ingredients in products to manufacturers.
The diagram below illustrates the basic movement and transport of PFAS containing materials through the Nantucket compost facility.
Due to concerns about the potential health and environmental impacts, there has been a reduction in the manufacture and use of certain PFAS compounds. For example, the U.S. Environmental Protection Agency (EPA) established a PFOA Stewardship Program and New Chemicals Program to assist in elimination of perflourinated PFAS compounds in the marketplace. For more information on these programs, check out this website: https://www.epa.gov/assessing-and-managing-chemicals-under-tsca/risk-management-and-polyfluoroalkyl-substances-pfas.
Additional information on PFAS, including more Frequently Asked Questions, is provided on the Town’s website at: https://nantucket-ma.gov/1574/PFAS. If you have questions about PFAS testing, you may send an email to [email protected] .
Nantucket Natural Compost-PFAS Fact Sheet (information current as of February 5, 2021) Page 4 of 4
FREQUENTLY ASKED QUESTIONS (FAQs)
FAQ #1: What are PFAS and how do they enter Landfill Facility operations?
PFAS stands for per- and polyfluoroalkyl substances which is a class of fluorinated compounds that have been used in numerous commercial and household applications since the 1950s. The original chemicals are long-chain compounds featuring numerous carbon-fluorine-bonds, which is one of the strongest of chemical bonds. That’s why PFAS compounds are nicknamed “forever chemicals.”
PFAS have many beneficial uses in manufacturing of products due to their ability to resist heat, water, and oil. PFAS is commonly found in the environment due to their use in a variety of commercial products such as nonstick cookware; stain-resistant furniture, carpets, and clothing; and water and grease repellents used in cosmetics, paints, microwave popcorn bags and pizza boxes. Household and business use of commercial products containing PFAS can enter the wastewater treatment system and are contained in many items sent to the landfill. WWTF residuals are also sent to the landfill for composting.
FAQ #2: Is it good practice to compare PFAS concentrations in compost or other biosolids sampling results to soil PFAS standards and/or groundwater PFAS standards?
No. PFAS sampling results from compost and other solids (such as leaf/yard waste, WWTF residuals/biosolids) should not be compared to regulatory or other health-based PFAS standards for either soil or groundwater. Risk factors used to develop soil standards and groundwater PFAS standards cannot be applied to compost or other solids because those factors differ. MassDEP is in the process of developing compost and biosolids screening levels for land application.
Regulatory standards are developed based on a variety of factors specific to the media (material) that is sampled. These factors are often based on human and ecological risk assessments and sometimes epidemiological studies. Factors that are considered in developing standards include sample media composition (grain size, organic and moisture content, other ingredients), routes of exposure (inhalation, ingestion, skin), amount of pollutant available for the human, animal or plant to absorb during exposure, and demographics of the exposed individual (age, diet). Each factor is developed specifically for a PFAS compound and sample media type.
To learn more about PFAS risk factors used specifically for national and state drinking water PFOA and PFOS standards, refer to the Interstate Technology’s Regulatory Council’s Basis of PFOA and PFOS Values Tables. https://pfas-1.itrcweb.org/fact-sheets/
Currently, there are no established PFAS limits for land application of compost products, biosolids, or other soils amendments in the Commonwealth of Massachusetts. The MassDEP is in the process of developing screening limits for various soil amendment products, and is looking at guidance established in the States of Maine and Vermont for modeling, background levels and ultimately screening limit parameters. Nationally, there is ongoing research to better understand what portion of PFAS present in compost are available for plant uptake and migration to soil, also referred to as the leachability potential.
FAQ #3: Are there some reported concentrations of PFAS in Household Products?
Foundation cosmetics – 2,370 parts per billion (Danish Study, Oct. 2018) Household foodwaste – 6 parts per billion (Brandli et al., 2006) Typical Biosolids Compost Products – 9 to 199 parts per billion (Lazcano,et al., 2020)
ANALYTICAL REPORTEurofins TestAmerica, Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600
Laboratory Job ID: 320-66089-1Client Project/Site: PFAS, MassDEP Biosolids
For:Waste Options Nantucket LLC188 Madaket RdNantucket, Massachusetts 02554
Attn: Nathan Widell
Authorized for release by:11/13/2020 12:37:36 PMNikita Kovalyov, Project Management Assistant [email protected]
Designee for
Cesar Cortes, Project Manager I(916)[email protected]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements foraccredited parameters, exceptions are noted in this report. This report may not be reproducedexcept in full, and with written approval from the laboratory. For questions please contact theProject Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Waste Options Nantucket LLCProject/Site: PFAS, MassDEP Biosolids
Laboratory Job ID: 320-66089-1
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Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
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Definitions/GlossaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Qualifiers
LCMSQualifier Description
F1 MS and/or MSD recovery exceeds control limits.
Qualifier
I Value is EMPC (estimated maximum possible concentration).
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Sacramento
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Case NarrativeClient: Waste Options Nantucket LLC Job ID: 320-66089-1Project/Site: PFAS, MassDEP Biosolids
Job ID: 320-66089-1
Laboratory: Eurofins TestAmerica, Sacramento
Narrative
Receipt The samples were received on 10/29/2020 9:25 AM; the samples arrived in good condition, and where required, properly preserved and
on ice. The temperature of the cooler at receipt was 6.0º C.
Receipt ExceptionThe chain of custody reads LCS-1, 2 LCS-3, 4
LCS-1, 2 (320-66089-1[MS]), LCS-3, 4 (320-66089-1[MSD])
As per the project manager's instruction, what looks like samples 4/5 and 6/7 on the COC will be the ms/msd for sample 1.
The container label for the following samples did not match the information listed on the Chain-of-Custody (COC): LCS-3, 4
(320-66089-1[MSD]). One of the two containers does not have a time listed.
Method 537 (modified)The matrix spike (MS) recoveries for preparation batch 320-428315 and analytical batch 320-430523 were outside control limits for Perfluoroundecanoic acid (PFUnA) and Perfluoropentanesulfonic acid (PFPeS). Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.
The matrix spike duplicate (MSD) recovery for preparation batch 320-428315 and analytical batch 320-430523 was outside control limits for Perfluoropentanesulfonic acid (PFPeS). Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.
The 'I' qualifier means the transition mass ratio for the indicated analyte was outside of the established ratio limits. The qualitative identification of the analyte has some degree of uncertainty. However, analyst judgment was used to positively identify the analyte.
The following samples were yellow in color (after extraction): FC1028 (320-66089-1), LCS-1, 2 (320-66089-1[MS]), LCS-3, 4
(320-66089-1[MSD]) and FC1028 (DUP) (320-66089-2), preparation batch 320-428315.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Detection SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Client Sample ID: FC1028 Lab Sample ID: 320-66089-1
☼Perfluorobutanoic acid (PFBA)
RL
0.26 ng/g
MDL
0.037
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10.48 537 (modified)
☼Perfluoropentanoic acid (PFPeA) 0.26 ng/g0.10 Total/NA10.92 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 0.26 ng/g0.055 Total/NA11.7 537 (modified)
☼Perfluoroheptanoic acid (PFHpA) 0.26 ng/g0.038 Total/NA10.40 537 (modified)
☼Perfluorooctanoic acid (PFOA) 0.26 ng/g0.11 Total/NA11.4 537 (modified)
☼Perfluorononanoic acid (PFNA) 0.26 ng/g0.047 Total/NA10.40 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.26 ng/g0.029 Total/NA10.91 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.26 ng/g0.047 Total/NA10.27 F1 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.26 ng/g0.087 Total/NA10.41 537 (modified)
☼Perfluorotridecanoic acid (PFTriA) 0.26 ng/g0.066 Total/NA10.092 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 0.26 ng/g0.033 Total/NA10.46 537 (modified)
☼Perfluorohexanesulfonic acid (PFHxS) 0.26 ng/g0.040 Total/NA10.12 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.65 ng/g0.26 Total/NA13.5 537 (modified)
☼Perfluorodecanesulfonic acid (PFDS) 0.26 ng/g0.051 Total/NA10.059 J 537 (modified)
Client Sample ID: FC1028 (DUP) Lab Sample ID: 320-66089-2
☼Perfluorobutanoic acid (PFBA)
RL
0.27 ng/g
MDL
0.038
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10.41 537 (modified)
☼Perfluoropentanoic acid (PFPeA) 0.27 ng/g0.10 Total/NA10.86 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 0.27 ng/g0.056 Total/NA11.5 537 (modified)
☼Perfluoroheptanoic acid (PFHpA) 0.27 ng/g0.039 Total/NA10.34 537 (modified)
☼Perfluorooctanoic acid (PFOA) 0.27 ng/g0.12 Total/NA11.1 537 (modified)
☼Perfluorononanoic acid (PFNA) 0.27 ng/g0.048 Total/NA10.34 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.27 ng/g0.030 Total/NA10.78 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.27 ng/g0.048 Total/NA10.26 J I 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.27 ng/g0.090 Total/NA10.34 537 (modified)
☼Perfluorotridecanoic acid (PFTriA) 0.27 ng/g0.069 Total/NA10.082 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 0.27 ng/g0.034 Total/NA10.40 537 (modified)
☼Perfluorohexanesulfonic acid (PFHxS) 0.27 ng/g0.042 Total/NA10.11 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.67 ng/g0.27 Total/NA13.2 537 (modified)
Client Sample ID: FIELD BLANK Lab Sample ID: 320-66089-3
No Detections.
Eurofins TestAmerica, Sacramento
This Detection Summary does not include radiochemical test results.
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Client Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Lab Sample ID: 320-66089-1Client Sample ID: FC1028Matrix: SolidDate Collected: 10/28/20 12:00
Percent Solids: 73.6Date Received: 10/29/20 09:25
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 0.48 0.26 0.037 ng/g ☼ 11/04/20 05:23 11/11/20 12:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.26 0.10 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluoropentanoic acid (PFPeA) 0.92
0.26 0.055 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorohexanoic acid (PFHxA) 1.7
0.26 0.038 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluoroheptanoic acid (PFHpA) 0.40
0.26 0.11 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorooctanoic acid (PFOA) 1.4
0.26 0.047 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorononanoic acid (PFNA) 0.40
0.26 0.029 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorodecanoic acid (PFDA) 0.91
0.26 0.047 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluoroundecanoic acid (PFUnA)
0.27 F1
0.26 0.087 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorododecanoic acid (PFDoA)
0.41
0.26 0.066 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorotridecanoic acid (PFTriA) 0.092 J
0.26 0.033 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorobutanesulfonic acid (PFBS)
0.46
0.26 0.026 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND F1
0.26 0.040 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorohexanesulfonic acid (PFHxS)
0.12 J
0.65 0.26 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorooctanesulfonic acid (PFOS)
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0.26 0.026 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorononanesulfonic acid (PFNS) ND
0.26 0.051 ng/g 11/04/20 05:23 11/11/20 12:16 1☼Perfluorodecanesulfonic acid (PFDS)
0.059 J
13C4 PFBA 76 25 - 150 11/04/20 05:23 11/11/20 12:16 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 63 11/04/20 05:23 11/11/20 12:16 125 - 150
13C2 PFHxA 72 11/04/20 05:23 11/11/20 12:16 125 - 150
13C4 PFHpA 81 11/04/20 05:23 11/11/20 12:16 125 - 150
13C4 PFOA 82 11/04/20 05:23 11/11/20 12:16 125 - 150
13C5 PFNA 79 11/04/20 05:23 11/11/20 12:16 125 - 150
13C2 PFDA 68 11/04/20 05:23 11/11/20 12:16 125 - 150
13C2 PFUnA 79 11/04/20 05:23 11/11/20 12:16 125 - 150
13C2 PFDoA 55 11/04/20 05:23 11/11/20 12:16 125 - 150
13C2 PFTeDA 53 11/04/20 05:23 11/11/20 12:16 125 - 150
13C3 PFBS 75 11/04/20 05:23 11/11/20 12:16 125 - 150
18O2 PFHxS 89 11/04/20 05:23 11/11/20 12:16 125 - 150
13C4 PFOS 79 11/04/20 05:23 11/11/20 12:16 125 - 150
General ChemistryRL MDL
Percent Moisture 26.4 0.1 0.1 % 11/03/20 16:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 11/03/20 16:45 1Percent Solids 73.6
Lab Sample ID: 320-66089-2Client Sample ID: FC1028 (DUP)Matrix: SolidDate Collected: 10/28/20 12:00
Percent Solids: 74.0Date Received: 10/29/20 09:25
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 0.41 0.27 0.038 ng/g ☼ 11/04/20 05:23 11/11/20 12:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.27 0.10 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluoropentanoic acid (PFPeA) 0.86
0.27 0.056 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorohexanoic acid (PFHxA) 1.5
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Client Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Lab Sample ID: 320-66089-2Client Sample ID: FC1028 (DUP)Matrix: SolidDate Collected: 10/28/20 12:00
Percent Solids: 74.0Date Received: 10/29/20 09:25
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluoroheptanoic acid (PFHpA) 0.34 0.27 0.039 ng/g ☼ 11/04/20 05:23 11/11/20 12:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.27 0.12 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorooctanoic acid (PFOA) 1.1
0.27 0.048 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorononanoic acid (PFNA) 0.34
0.27 0.030 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorodecanoic acid (PFDA) 0.78
0.27 0.048 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluoroundecanoic acid (PFUnA)
0.26 J I
0.27 0.090 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorododecanoic acid (PFDoA)
0.34
0.27 0.069 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorotridecanoic acid (PFTriA) 0.082 J
0.27 0.034 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorobutanesulfonic acid (PFBS)
0.40
0.27 0.027 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
0.27 0.042 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorohexanesulfonic acid (PFHxS)
0.11 J
0.67 0.27 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorooctanesulfonic acid (PFOS)
3.2
0.27 0.027 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorononanesulfonic acid (PFNS) ND
0.27 0.052 ng/g 11/04/20 05:23 11/11/20 12:44 1☼Perfluorodecanesulfonic acid (PFDS) ND
13C4 PFBA 70 25 - 150 11/04/20 05:23 11/11/20 12:44 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 56 11/04/20 05:23 11/11/20 12:44 125 - 150
13C2 PFHxA 70 11/04/20 05:23 11/11/20 12:44 125 - 150
13C4 PFHpA 79 11/04/20 05:23 11/11/20 12:44 125 - 150
13C4 PFOA 82 11/04/20 05:23 11/11/20 12:44 125 - 150
13C5 PFNA 72 11/04/20 05:23 11/11/20 12:44 125 - 150
13C2 PFDA 75 11/04/20 05:23 11/11/20 12:44 125 - 150
13C2 PFUnA 65 11/04/20 05:23 11/11/20 12:44 125 - 150
13C2 PFDoA 53 11/04/20 05:23 11/11/20 12:44 125 - 150
13C2 PFTeDA 43 11/04/20 05:23 11/11/20 12:44 125 - 150
13C3 PFBS 70 11/04/20 05:23 11/11/20 12:44 125 - 150
18O2 PFHxS 82 11/04/20 05:23 11/11/20 12:44 125 - 150
13C4 PFOS 78 11/04/20 05:23 11/11/20 12:44 125 - 150
General ChemistryRL MDL
Percent Moisture 26.0 0.1 0.1 % 11/03/20 16:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 11/03/20 16:45 1Percent Solids 74.0
Lab Sample ID: 320-66089-3Client Sample ID: FIELD BLANKMatrix: WaterDate Collected: 10/28/20 12:00
Date Received: 10/29/20 09:25
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) ND 4.5 2.2 ng/L 11/06/20 05:05 11/07/20 13:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1.8 0.44 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluoropentanoic acid (PFPeA) ND
1.8 0.52 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorohexanoic acid (PFHxA) ND
1.8 0.22 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluoroheptanoic acid (PFHpA) ND
1.8 0.76 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorooctanoic acid (PFOA) ND
1.8 0.24 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorononanoic acid (PFNA) ND
Eurofins TestAmerica, Sacramento
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Client Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Lab Sample ID: 320-66089-3Client Sample ID: FIELD BLANKMatrix: WaterDate Collected: 10/28/20 12:00
Date Received: 10/29/20 09:25
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluorodecanoic acid (PFDA) ND 1.8 0.28 ng/L 11/06/20 05:05 11/07/20 13:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1.8 0.99 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluoroundecanoic acid (PFUnA) ND
1.8 0.49 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorododecanoic acid (PFDoA) ND
1.8 1.2 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorotridecanoic acid (PFTriA) ND
1.8 0.18 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorobutanesulfonic acid (PFBS) ND
1.8 0.51 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorohexanesulfonic acid (PFHxS) ND
1.8 0.29 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorodecanesulfonic acid (PFDS) ND
1.8 0.48 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorooctanesulfonic acid (PFOS) ND
1.8 0.27 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluoropentanesulfonic acid
(PFPeS)
ND
1.8 0.33 ng/L 11/06/20 05:05 11/07/20 13:23 1Perfluorononanesulfonic acid (PFNS) ND
13C4 PFBA 81 25 - 150 11/06/20 05:05 11/07/20 13:23 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 84 11/06/20 05:05 11/07/20 13:23 125 - 150
13C2 PFHxA 82 11/06/20 05:05 11/07/20 13:23 125 - 150
13C4 PFHpA 86 11/06/20 05:05 11/07/20 13:23 125 - 150
13C4 PFOA 93 11/06/20 05:05 11/07/20 13:23 125 - 150
13C5 PFNA 88 11/06/20 05:05 11/07/20 13:23 125 - 150
13C2 PFDA 94 11/06/20 05:05 11/07/20 13:23 125 - 150
13C2 PFUnA 82 11/06/20 05:05 11/07/20 13:23 125 - 150
13C2 PFDoA 78 11/06/20 05:05 11/07/20 13:23 125 - 150
13C2 PFTeDA 64 11/06/20 05:05 11/07/20 13:23 125 - 150
13C3 PFBS 88 11/06/20 05:05 11/07/20 13:23 125 - 150
18O2 PFHxS 92 11/06/20 05:05 11/07/20 13:23 125 - 150
13C4 PFOS 91 11/06/20 05:05 11/07/20 13:23 125 - 150
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
76 63 72 81 82 79 68 79320-66089-1
Percent Isotope Dilution Recovery (Acceptance Limits)
FC1028
72 60 73 8181 78 77 77320-66089-1 MS LCS-1, 2
71 63 74 8581 77 71 74320-66089-1 MSD LCS-3, 4
70 56 70 8279 72 75 65320-66089-2 FC1028 (DUP)
81 86 78 8288 76 77 70LCS 320-428315/2-A Lab Control Sample
89 89 85 9492 86 89 75MB 320-428315/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
55 53 75 89 79320-66089-1
Percent Isotope Dilution Recovery (Acceptance Limits)
FC1028
62 38 73 8093320-66089-1 MS LCS-1, 2
57 51 72 8387320-66089-1 MSD LCS-3, 4
53 43 70 7882320-66089-2 FC1028 (DUP)
85 82 82 8086LCS 320-428315/2-A Lab Control Sample
84 81 93 9089MB 320-428315/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
81 84 82 86 93 88 94 82320-66089-3
Percent Isotope Dilution Recovery (Acceptance Limits)
FIELD BLANK
85 89 87 9491 91 88 90500-190393-A-2-B MS Matrix Spike
78 81 82 8785 82 82 79500-190393-A-2-C MSD Matrix Spike Duplicate
86 89 88 9392 89 88 93LCS 320-428967/2-A Lab Control Sample
89 92 91 9992 91 95 92LCSD 320-428967/3-A Lab Control Sample Dup
85 88 87 9689 91 93 92MB 320-428967/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
78 64 88 92 91320-66089-3
Percent Isotope Dilution Recovery (Acceptance Limits)
FIELD BLANK
84 78 91 9494500-190393-A-2-B MS Matrix Spike
74 61 83 8886500-190393-A-2-C MSD Matrix Spike Duplicate
94 83 90 9395LCS 320-428967/2-A Lab Control Sample
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
95 89 94 95 99LCSD 320-428967/3-A
Percent Isotope Dilution Recovery (Acceptance Limits)
Lab Control Sample Dup
88 83 90 9695MB 320-428967/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 320-428315/1-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
RL MDL
Perfluorobutanoic acid (PFBA) ND 0.20 0.028 ng/g 11/04/20 05:23 11/11/20 11:57 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.0770.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluoropentanoic acid (PFPeA)
ND 0.0420.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorohexanoic acid (PFHxA)
ND 0.0290.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluoroheptanoic acid (PFHpA)
ND 0.0860.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorooctanoic acid (PFOA)
ND 0.0360.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorononanoic acid (PFNA)
ND 0.0220.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorodecanoic acid (PFDA)
ND 0.0360.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluoroundecanoic acid (PFUnA)
ND 0.0670.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorododecanoic acid (PFDoA)
ND 0.0510.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorotridecanoic acid (PFTriA)
ND 0.0250.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorobutanesulfonic acid (PFBS)
ND 0.0310.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorohexanesulfonic acid (PFHxS)
ND 0.200.50 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorooctanesulfonic acid (PFOS)
ND 0.0390.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorodecanesulfonic acid (PFDS)
ND 0.0200.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.0200.20 ng/g 11/04/20 05:23 11/11/20 11:57 1Perfluorononanesulfonic acid (PFNS)
13C4 PFBA 89 25 - 150 11/11/20 11:57 1
MB MB
Isotope Dilution
11/04/20 05:23
Dil FacPrepared AnalyzedQualifier Limits%Recovery
89 11/04/20 05:23 11/11/20 11:57 113C5 PFPeA 25 - 150
85 11/04/20 05:23 11/11/20 11:57 113C2 PFHxA 25 - 150
92 11/04/20 05:23 11/11/20 11:57 113C4 PFHpA 25 - 150
94 11/04/20 05:23 11/11/20 11:57 113C4 PFOA 25 - 150
86 11/04/20 05:23 11/11/20 11:57 113C5 PFNA 25 - 150
89 11/04/20 05:23 11/11/20 11:57 113C2 PFDA 25 - 150
75 11/04/20 05:23 11/11/20 11:57 113C2 PFUnA 25 - 150
84 11/04/20 05:23 11/11/20 11:57 113C2 PFDoA 25 - 150
81 11/04/20 05:23 11/11/20 11:57 113C2 PFTeDA 25 - 150
93 11/04/20 05:23 11/11/20 11:57 113C3 PFBS 25 - 150
89 11/04/20 05:23 11/11/20 11:57 118O2 PFHxS 25 - 150
90 11/04/20 05:23 11/11/20 11:57 113C4 PFOS 25 - 150
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-428315/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorobutanoic acid (PFBA) 2.00 2.30 ng/g 115 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 2.00 1.94 ng/g 97 69 - 129
Perfluorohexanoic acid (PFHxA) 2.00 2.25 ng/g 113 71 - 131
Perfluoroheptanoic acid (PFHpA) 2.00 2.04 ng/g 102 71 - 131
Perfluorooctanoic acid (PFOA) 2.00 1.97 ng/g 99 72 - 132
Perfluorononanoic acid (PFNA) 2.00 1.96 ng/g 98 73 - 133
Perfluorodecanoic acid (PFDA) 2.00 2.00 ng/g 100 72 - 132
Perfluoroundecanoic acid
(PFUnA)
2.00 2.20 ng/g 110 66 - 126
Perfluorododecanoic acid
(PFDoA)
2.00 2.18 ng/g 109 71 - 131
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-428315/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorotridecanoic acid
(PFTriA)
2.00 2.30 ng/g 115 71 - 131
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorobutanesulfonic acid
(PFBS)
1.77 2.04 ng/g 115 69 - 129
Perfluorohexanesulfonic acid
(PFHxS)
1.82 1.85 ng/g 102 62 - 122
Perfluorooctanesulfonic acid
(PFOS)
1.86 2.09 ng/g 113 68 - 141
Perfluorodecanesulfonic acid
(PFDS)
1.93 2.23 ng/g 116 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
1.88 2.15 ng/g 115 66 - 126
Perfluorononanesulfonic acid
(PFNS)
1.92 2.13 ng/g 111 72 - 132
13C4 PFBA 25 - 150
Isotope Dilution
81
LCS LCS
Qualifier Limits%Recovery
8613C5 PFPeA 25 - 150
7813C2 PFHxA 25 - 150
8813C4 PFHpA 25 - 150
8213C4 PFOA 25 - 150
7613C5 PFNA 25 - 150
7713C2 PFDA 25 - 150
7013C2 PFUnA 25 - 150
8513C2 PFDoA 25 - 150
8213C2 PFTeDA 25 - 150
8213C3 PFBS 25 - 150
8618O2 PFHxS 25 - 150
8013C4 PFOS 25 - 150
Client Sample ID: LCS-1, 2Lab Sample ID: 320-66089-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorobutanoic acid (PFBA) 0.48 2.59 2.97 ng/g 96 76 - 136☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 0.92 2.59 3.52 ng/g 100 69 - 129☼
Perfluorohexanoic acid (PFHxA) 1.7 2.59 4.85 ng/g 123 71 - 131☼
Perfluoroheptanoic acid (PFHpA) 0.40 2.59 3.25 ng/g 110 71 - 131☼
Perfluorooctanoic acid (PFOA) 1.4 2.59 4.02 ng/g 103 72 - 132☼
Perfluorononanoic acid (PFNA) 0.40 2.59 3.17 ng/g 107 73 - 133☼
Perfluorodecanoic acid (PFDA) 0.91 2.59 3.59 ng/g 103 72 - 132☼
Perfluoroundecanoic acid
(PFUnA)
0.27 F1 2.59 3.79 F1 ng/g 136 66 - 126☼
Perfluorododecanoic acid
(PFDoA)
0.41 2.59 3.50 ng/g 119 71 - 131☼
Perfluorotridecanoic acid
(PFTriA)
0.092 J 2.59 2.28 ng/g 84 71 - 131☼
Perfluorobutanesulfonic acid
(PFBS)
0.46 2.29 3.11 ng/g 116 69 - 129☼
Perfluoropentanesulfonic acid
(PFPeS)
ND F1 2.43 3.54 F1 ng/g 146 66 - 126☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: LCS-1, 2Lab Sample ID: 320-66089-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorohexanesulfonic acid
(PFHxS)
0.12 J 2.36 2.25 ng/g 90 62 - 122☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluorooctanesulfonic acid
(PFOS)
3.5 2.41 6.49 ng/g 126 68 - 141☼
Perfluorononanesulfonic acid
(PFNS)
ND 2.49 3.12 ng/g 125 72 - 132☼
Perfluorodecanesulfonic acid
(PFDS)
0.059 J 2.50 2.82 ng/g 110 71 - 131☼
13C4 PFBA 25 - 150
Isotope Dilution
72
MS MS
Qualifier Limits%Recovery
6013C5 PFPeA 25 - 150
7313C2 PFHxA 25 - 150
8113C4 PFHpA 25 - 150
8113C4 PFOA 25 - 150
7813C5 PFNA 25 - 150
7713C2 PFDA 25 - 150
7713C2 PFUnA 25 - 150
6213C2 PFDoA 25 - 150
3813C2 PFTeDA 25 - 150
7313C3 PFBS 25 - 150
9318O2 PFHxS 25 - 150
8013C4 PFOS 25 - 150
Client Sample ID: LCS-3, 4Lab Sample ID: 320-66089-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorobutanoic acid (PFBA) 0.48 2.53 2.82 ng/g 93 76 - 136 5 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 0.92 2.53 3.42 ng/g 99 69 - 129 3 30☼
Perfluorohexanoic acid (PFHxA) 1.7 2.53 4.41 ng/g 108 71 - 131 9 30☼
Perfluoroheptanoic acid (PFHpA) 0.40 2.53 3.20 ng/g 110 71 - 131 2 30☼
Perfluorooctanoic acid (PFOA) 1.4 2.53 3.62 ng/g 89 72 - 132 10 30☼
Perfluorononanoic acid (PFNA) 0.40 2.53 3.10 ng/g 107 73 - 133 2 30☼
Perfluorodecanoic acid (PFDA) 0.91 2.53 3.72 ng/g 111 72 - 132 4 30☼
Perfluoroundecanoic acid
(PFUnA)
0.27 F1 2.53 3.29 ng/g 119 66 - 126 14 30☼
Perfluorododecanoic acid
(PFDoA)
0.41 2.53 3.19 ng/g 110 71 - 131 9 30☼
Perfluorotridecanoic acid
(PFTriA)
0.092 J 2.53 2.65 ng/g 101 71 - 131 15 30☼
Perfluorobutanesulfonic acid
(PFBS)
0.46 2.24 3.16 ng/g 120 69 - 129 1 30☼
Perfluoropentanesulfonic acid
(PFPeS)
ND F1 2.38 3.36 F1 ng/g 141 66 - 126 5 30☼
Perfluorohexanesulfonic acid
(PFHxS)
0.12 J 2.31 2.40 ng/g 98 62 - 122 6 30☼
Perfluorooctanesulfonic acid
(PFOS)
3.5 2.35 5.85 ng/g 102 68 - 141 10 30☼
Perfluorononanesulfonic acid
(PFNS)
ND 2.43 2.82 ng/g 116 72 - 132 10 30☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: LCS-3, 4Lab Sample ID: 320-66089-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 430523 Prep Batch: 428315
Perfluorodecanesulfonic acid
(PFDS)
0.059 J 2.44 2.22 ng/g 88 71 - 131 24 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
13C4 PFBA 25 - 150
Isotope Dilution
71
MSD MSD
Qualifier Limits%Recovery
6313C5 PFPeA 25 - 150
7413C2 PFHxA 25 - 150
8113C4 PFHpA 25 - 150
8513C4 PFOA 25 - 150
7713C5 PFNA 25 - 150
7113C2 PFDA 25 - 150
7413C2 PFUnA 25 - 150
5713C2 PFDoA 25 - 150
5113C2 PFTeDA 25 - 150
7213C3 PFBS 25 - 150
8718O2 PFHxS 25 - 150
8313C4 PFOS 25 - 150
Client Sample ID: Method BlankLab Sample ID: MB 320-428967/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
RL MDL
Perfluorobutanoic acid (PFBA) ND 5.0 2.4 ng/L 11/06/20 05:05 11/07/20 10:20 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.492.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluoropentanoic acid (PFPeA)
ND 0.582.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorohexanoic acid (PFHxA)
ND 0.252.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluoroheptanoic acid (PFHpA)
ND 0.852.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorooctanoic acid (PFOA)
ND 0.272.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorononanoic acid (PFNA)
ND 0.312.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorodecanoic acid (PFDA)
ND 1.12.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluoroundecanoic acid (PFUnA)
ND 0.552.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorododecanoic acid (PFDoA)
ND 1.32.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorotridecanoic acid (PFTriA)
ND 0.202.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorobutanesulfonic acid (PFBS)
ND 0.572.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorohexanesulfonic acid (PFHxS)
ND 0.542.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorooctanesulfonic acid (PFOS)
ND 0.322.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorodecanesulfonic acid (PFDS)
ND 0.302.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.372.0 ng/L 11/06/20 05:05 11/07/20 10:20 1Perfluorononanesulfonic acid (PFNS)
13C4 PFBA 85 25 - 150 11/07/20 10:20 1
MB MB
Isotope Dilution
11/06/20 05:05
Dil FacPrepared AnalyzedQualifier Limits%Recovery
88 11/06/20 05:05 11/07/20 10:20 113C5 PFPeA 25 - 150
87 11/06/20 05:05 11/07/20 10:20 113C2 PFHxA 25 - 150
89 11/06/20 05:05 11/07/20 10:20 113C4 PFHpA 25 - 150
96 11/06/20 05:05 11/07/20 10:20 113C4 PFOA 25 - 150
91 11/06/20 05:05 11/07/20 10:20 113C5 PFNA 25 - 150
93 11/06/20 05:05 11/07/20 10:20 113C2 PFDA 25 - 150
Eurofins TestAmerica, Sacramento
Page 14 of 25 11/13/2020
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 320-428967/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
13C2 PFUnA 92 25 - 150 11/07/20 10:20 1
MB MB
Isotope Dilution
11/06/20 05:05
Dil FacPrepared AnalyzedQualifier Limits%Recovery
88 11/06/20 05:05 11/07/20 10:20 113C2 PFDoA 25 - 150
83 11/06/20 05:05 11/07/20 10:20 113C2 PFTeDA 25 - 150
90 11/06/20 05:05 11/07/20 10:20 113C3 PFBS 25 - 150
95 11/06/20 05:05 11/07/20 10:20 118O2 PFHxS 25 - 150
96 11/06/20 05:05 11/07/20 10:20 113C4 PFOS 25 - 150
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-428967/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
Perfluorobutanoic acid (PFBA) 40.0 43.8 ng/L 109 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 40.0 38.7 ng/L 97 71 - 131
Perfluorohexanoic acid (PFHxA) 40.0 42.7 ng/L 107 73 - 133
Perfluoroheptanoic acid (PFHpA) 40.0 41.9 ng/L 105 72 - 132
Perfluorooctanoic acid (PFOA) 40.0 38.9 ng/L 97 70 - 130
Perfluorononanoic acid (PFNA) 40.0 44.5 ng/L 111 75 - 135
Perfluorodecanoic acid (PFDA) 40.0 45.4 ng/L 113 76 - 136
Perfluoroundecanoic acid
(PFUnA)
40.0 42.9 ng/L 107 68 - 128
Perfluorododecanoic acid
(PFDoA)
40.0 43.3 ng/L 108 71 - 131
Perfluorotridecanoic acid
(PFTriA)
40.0 45.7 ng/L 114 71 - 131
Perfluorobutanesulfonic acid
(PFBS)
35.4 38.0 ng/L 108 67 - 127
Perfluorohexanesulfonic acid
(PFHxS)
36.4 35.1 ng/L 96 59 - 119
Perfluorooctanesulfonic acid
(PFOS)
37.1 39.6 ng/L 107 70 - 130
Perfluorodecanesulfonic acid
(PFDS)
38.6 43.3 ng/L 112 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
37.5 43.5 ng/L 116 66 - 126
Perfluorononanesulfonic acid
(PFNS)
38.4 42.0 ng/L 109 75 - 135
13C4 PFBA 25 - 150
Isotope Dilution
86
LCS LCS
Qualifier Limits%Recovery
8913C5 PFPeA 25 - 150
8813C2 PFHxA 25 - 150
9213C4 PFHpA 25 - 150
9313C4 PFOA 25 - 150
8913C5 PFNA 25 - 150
8813C2 PFDA 25 - 150
9313C2 PFUnA 25 - 150
9413C2 PFDoA 25 - 150
8313C2 PFTeDA 25 - 150
9013C3 PFBS 25 - 150
9518O2 PFHxS 25 - 150
Eurofins TestAmerica, Sacramento
Page 15 of 25 11/13/2020
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-428967/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
13C4 PFOS 25 - 150
Isotope Dilution
93
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 320-428967/3-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
Perfluorobutanoic acid (PFBA) 40.0 42.7 ng/L 107 76 - 136 2 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 40.0 36.8 ng/L 92 71 - 131 5 30
Perfluorohexanoic acid (PFHxA) 40.0 41.6 ng/L 104 73 - 133 3 30
Perfluoroheptanoic acid (PFHpA) 40.0 41.0 ng/L 103 72 - 132 2 30
Perfluorooctanoic acid (PFOA) 40.0 37.0 ng/L 93 70 - 130 5 30
Perfluorononanoic acid (PFNA) 40.0 43.0 ng/L 107 75 - 135 4 30
Perfluorodecanoic acid (PFDA) 40.0 42.7 ng/L 107 76 - 136 6 30
Perfluoroundecanoic acid
(PFUnA)
40.0 41.1 ng/L 103 68 - 128 4 30
Perfluorododecanoic acid
(PFDoA)
40.0 40.5 ng/L 101 71 - 131 7 30
Perfluorotridecanoic acid
(PFTriA)
40.0 44.4 ng/L 111 71 - 131 3 30
Perfluorobutanesulfonic acid
(PFBS)
35.4 37.0 ng/L 105 67 - 127 3 30
Perfluorohexanesulfonic acid
(PFHxS)
36.4 33.9 ng/L 93 59 - 119 4 30
Perfluorooctanesulfonic acid
(PFOS)
37.1 38.1 ng/L 103 70 - 130 4 30
Perfluorodecanesulfonic acid
(PFDS)
38.6 40.1 ng/L 104 71 - 131 8 30
Perfluoropentanesulfonic acid
(PFPeS)
37.5 41.8 ng/L 111 66 - 126 4 30
Perfluorononanesulfonic acid
(PFNS)
38.4 40.2 ng/L 105 75 - 135 4 30
13C4 PFBA 25 - 150
Isotope Dilution
89
LCSD LCSD
Qualifier Limits%Recovery
9213C5 PFPeA 25 - 150
9113C2 PFHxA 25 - 150
9213C4 PFHpA 25 - 150
9913C4 PFOA 25 - 150
9113C5 PFNA 25 - 150
9513C2 PFDA 25 - 150
9213C2 PFUnA 25 - 150
9513C2 PFDoA 25 - 150
8913C2 PFTeDA 25 - 150
9413C3 PFBS 25 - 150
9518O2 PFHxS 25 - 150
9913C4 PFOS 25 - 150
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 500-190393-A-2-B MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
Perfluorobutanoic acid (PFBA) 16 36.5 54.1 ng/L 105 76 - 136
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 13 36.5 46.0 ng/L 90 71 - 131
Perfluorohexanoic acid (PFHxA) 3.3 36.5 41.3 ng/L 104 73 - 133
Perfluoroheptanoic acid (PFHpA) 0.80 J 36.5 37.3 ng/L 100 72 - 132
Perfluorooctanoic acid (PFOA) 1.1 J 36.5 34.7 ng/L 92 70 - 130
Perfluorononanoic acid (PFNA) ND 36.5 37.1 ng/L 102 75 - 135
Perfluorodecanoic acid (PFDA) ND 36.5 39.0 ng/L 107 76 - 136
Perfluoroundecanoic acid
(PFUnA)
ND 36.5 35.9 ng/L 98 68 - 128
Perfluorododecanoic acid
(PFDoA)
ND 36.5 38.0 ng/L 104 71 - 131
Perfluorotridecanoic acid
(PFTriA)
ND 36.5 36.0 ng/L 99 71 - 131
Perfluorobutanesulfonic acid
(PFBS)
ND 32.2 33.6 ng/L 104 67 - 127
Perfluorohexanesulfonic acid
(PFHxS)
ND 33.2 31.2 ng/L 94 59 - 119
Perfluorooctanesulfonic acid
(PFOS)
0.57 J 33.8 35.6 ng/L 104 70 - 130
Perfluorodecanesulfonic acid
(PFDS)
ND 35.2 35.6 ng/L 101 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
ND 34.2 38.3 ng/L 112 66 - 126
Perfluorononanesulfonic acid
(PFNS)
ND 35.0 35.8 ng/L 102 75 - 135
13C4 PFBA 25 - 150
Isotope Dilution
85
MS MS
Qualifier Limits%Recovery
8913C5 PFPeA 25 - 150
8713C2 PFHxA 25 - 150
9113C4 PFHpA 25 - 150
9413C4 PFOA 25 - 150
9113C5 PFNA 25 - 150
8813C2 PFDA 25 - 150
9013C2 PFUnA 25 - 150
8413C2 PFDoA 25 - 150
7813C2 PFTeDA 25 - 150
9113C3 PFBS 25 - 150
9418O2 PFHxS 25 - 150
9413C4 PFOS 25 - 150
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 500-190393-A-2-C MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
Perfluorobutanoic acid (PFBA) 16 37.0 56.1 ng/L 109 76 - 136 4 30
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 13 37.0 49.8 ng/L 98 71 - 131 8 30
Perfluorohexanoic acid (PFHxA) 3.3 37.0 41.3 ng/L 103 73 - 133 0 30
Perfluoroheptanoic acid (PFHpA) 0.80 J 37.0 39.6 ng/L 105 72 - 132 6 30
Perfluorooctanoic acid (PFOA) 1.1 J 37.0 36.3 ng/L 95 70 - 130 5 30
Eurofins TestAmerica, Sacramento
Page 17 of 25 11/13/2020
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QC Sample ResultsJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 500-190393-A-2-C MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 429491 Prep Batch: 428967
Perfluorononanoic acid (PFNA) ND 37.0 39.7 ng/L 107 75 - 135 7 30
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluorodecanoic acid (PFDA) ND 37.0 40.3 ng/L 109 76 - 136 3 30
Perfluoroundecanoic acid
(PFUnA)
ND 37.0 39.2 ng/L 106 68 - 128 9 30
Perfluorododecanoic acid
(PFDoA)
ND 37.0 44.5 ng/L 120 71 - 131 16 30
Perfluorotridecanoic acid
(PFTriA)
ND 37.0 40.5 ng/L 109 71 - 131 12 30
Perfluorobutanesulfonic acid
(PFBS)
ND 32.7 34.5 ng/L 106 67 - 127 3 30
Perfluorohexanesulfonic acid
(PFHxS)
ND 33.7 34.8 ng/L 103 59 - 119 11 30
Perfluorooctanesulfonic acid
(PFOS)
0.57 J 34.3 37.0 ng/L 106 70 - 130 4 30
Perfluorodecanesulfonic acid
(PFDS)
ND 35.7 36.5 ng/L 102 71 - 131 3 30
Perfluoropentanesulfonic acid
(PFPeS)
ND 34.7 41.6 ng/L 120 66 - 126 8 30
Perfluorononanesulfonic acid
(PFNS)
ND 35.5 37.0 ng/L 104 75 - 135 3 30
13C4 PFBA 25 - 150
Isotope Dilution
78
MSD MSD
Qualifier Limits%Recovery
8113C5 PFPeA 25 - 150
8213C2 PFHxA 25 - 150
8513C4 PFHpA 25 - 150
8713C4 PFOA 25 - 150
8213C5 PFNA 25 - 150
8213C2 PFDA 25 - 150
7913C2 PFUnA 25 - 150
7413C2 PFDoA 25 - 150
6113C2 PFTeDA 25 - 150
8313C3 PFBS 25 - 150
8618O2 PFHxS 25 - 150
8813C4 PFOS 25 - 150
Method: D 2216 - Percent Moisture
Client Sample ID: FC1028Lab Sample ID: 320-66089-1 DUMatrix: Solid Prep Type: Total/NAAnalysis Batch: 428216
Percent Moisture 26.4 27.7 % 5 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Percent Solids 73.6 72.3 % 2 20
Eurofins TestAmerica, Sacramento
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QC Association SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
LCMS
Prep Batch: 428315
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid SHAKE320-66089-1 FC1028 Total/NA
Solid SHAKE320-66089-2 FC1028 (DUP) Total/NA
Solid SHAKEMB 320-428315/1-A Method Blank Total/NA
Solid SHAKELCS 320-428315/2-A Lab Control Sample Total/NA
Solid SHAKE320-66089-1 MS LCS-1, 2 Total/NA
Solid SHAKE320-66089-1 MSD LCS-3, 4 Total/NA
Prep Batch: 428967
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3535320-66089-3 FIELD BLANK Total/NA
Water 3535MB 320-428967/1-A Method Blank Total/NA
Water 3535LCS 320-428967/2-A Lab Control Sample Total/NA
Water 3535LCSD 320-428967/3-A Lab Control Sample Dup Total/NA
Water 3535500-190393-A-2-B MS Matrix Spike Total/NA
Water 3535500-190393-A-2-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 429491
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 (modified) 428967320-66089-3 FIELD BLANK Total/NA
Water 537 (modified) 428967MB 320-428967/1-A Method Blank Total/NA
Water 537 (modified) 428967LCS 320-428967/2-A Lab Control Sample Total/NA
Water 537 (modified) 428967LCSD 320-428967/3-A Lab Control Sample Dup Total/NA
Water 537 (modified) 428967500-190393-A-2-B MS Matrix Spike Total/NA
Water 537 (modified) 428967500-190393-A-2-C MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 430523
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 537 (modified) 428315320-66089-1 FC1028 Total/NA
Solid 537 (modified) 428315320-66089-2 FC1028 (DUP) Total/NA
Solid 537 (modified) 428315MB 320-428315/1-A Method Blank Total/NA
Solid 537 (modified) 428315LCS 320-428315/2-A Lab Control Sample Total/NA
Solid 537 (modified) 428315320-66089-1 MS LCS-1, 2 Total/NA
Solid 537 (modified) 428315320-66089-1 MSD LCS-3, 4 Total/NA
General Chemistry
Analysis Batch: 428216
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid D 2216320-66089-1 FC1028 Total/NA
Solid D 2216320-66089-2 FC1028 (DUP) Total/NA
Solid D 2216320-66089-1 DU FC1028 Total/NA
Eurofins TestAmerica, Sacramento
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Lab ChronicleClient: Waste Options Nantucket LLC Job ID: 320-66089-1Project/Site: PFAS, MassDEP Biosolids
Client Sample ID: FC1028 Lab Sample ID: 320-66089-1Matrix: SolidDate Collected: 10/28/20 12:00
Date Received: 10/29/20 09:25
Analysis D 2216 KDB11/03/20 16:451 TAL SAC428216
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: FC1028 Lab Sample ID: 320-66089-1Matrix: SolidDate Collected: 10/28/20 12:00
Percent Solids: 73.6Date Received: 10/29/20 09:25
Prep SHAKE NSS11/04/20 05:23 TAL SAC428315
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.21 g 10.0 mL
Analysis 537 (modified) 1 430523 11/11/20 12:16 JY1 TAL SACTotal/NA
Client Sample ID: FC1028 (DUP) Lab Sample ID: 320-66089-2Matrix: SolidDate Collected: 10/28/20 12:00
Date Received: 10/29/20 09:25
Analysis D 2216 KDB11/03/20 16:451 TAL SAC428216
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: FC1028 (DUP) Lab Sample ID: 320-66089-2Matrix: SolidDate Collected: 10/28/20 12:00
Percent Solids: 74.0Date Received: 10/29/20 09:25
Prep SHAKE NSS11/04/20 05:23 TAL SAC428315
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.03 g 10.0 mL
Analysis 537 (modified) 1 430523 11/11/20 12:44 JY1 TAL SACTotal/NA
Client Sample ID: FIELD BLANK Lab Sample ID: 320-66089-3Matrix: WaterDate Collected: 10/28/20 12:00
Date Received: 10/29/20 09:25
Prep 3535 EG11/06/20 05:05 TAL SAC428967
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 278.5 mL 10.0 mL
Analysis 537 (modified) 1 429491 11/07/20 13:23 K1S TAL SACTotal/NA
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Accreditation/Certification SummaryClient: Waste Options Nantucket LLC Job ID: 320-66089-1Project/Site: PFAS, MassDEP Biosolids
Laboratory: Eurofins TestAmerica, SacramentoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
Alaska (UST) 17-020State 01-20-21
ANAB Dept. of Defense ELAP L2468 01-20-21
ANAB Dept. of Energy L2468.01 01-20-21
ANAB ISO/IEC 17025 L2468 01-20-21
Arizona State AZ0708 08-11-21
Arkansas DEQ State 88-0691 06-17-21
California State 2897 01-31-22
Colorado State CA0004 08-31-21
Connecticut State PH-0691 06-30-21
Florida NELAP E87570 06-30-21
Georgia State 4040 01-30-21
Hawaii State <cert No.> 01-29-21
Illinois NELAP 200060 03-17-21
Kansas NELAP E-10375 10-31-20 *
Louisiana NELAP 01944 06-30-21
Maine State CA00004 04-14-22
Michigan State 9947 08-03-23
Nevada State CA000442021-1 07-31-21
New Hampshire NELAP 2997 04-18-21
New Jersey NELAP CA005 06-30-21
New York NELAP 11666 04-01-21
Oregon NELAP 4040 01-29-21
Pennsylvania NELAP 68-01272 03-31-21
Texas NELAP T104704399-19-13 06-01-21
US Fish & Wildlife US Federal Programs 58448 07-31-21
USDA US Federal Programs P330-18-00239 07-31-21
Utah NELAP CA000442019-01 02-28-21
Vermont State VT-4040 04-16-21
Virginia NELAP 460278 03-14-21
Washington State C581 05-05-21
West Virginia (DW) State 9930C 12-31-20
Wisconsin State 998204680 08-31-21
Wyoming State Program 8TMS-L 01-28-19 *
Eurofins TestAmerica, Sacramento
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 21 of 25 11/13/2020
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Method SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL SAC
ASTMD 2216 Percent Moisture TAL SAC
SW8463535 Solid-Phase Extraction (SPE) TAL SAC
SW846SHAKE Shake Extraction with Ultrasonic Bath Extraction TAL SAC
Protocol References:
ASTM = ASTM International
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Sample SummaryJob ID: 320-66089-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP Biosolids
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
320-66089-1 FC1028 Solid 10/28/20 12:00 10/29/20 09:25
320-66089-2 FC1028 (DUP) Solid 10/28/20 12:00 10/29/20 09:25
320-66089-3 FIELD BLANK Water 10/28/20 12:00 10/29/20 09:25
Eurofins TestAmerica, Sacramento
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Login Sample Receipt Checklist
Client: Waste Options Nantucket LLC Job Number: 320-66089-1
Login Number: 66089
Question Answer Comment
Creator: Thompson, Sarah W
List Source: Eurofins TestAmerica, Sacramento
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact. 1397336, 1397337
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information. Client confirmed login accurate.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins TestAmerica, SacramentoPage 25 of 25 11/13/2020
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