LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
Page 1 of 30
=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
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State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
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Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
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EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
Page 2 of 30
~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW1
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565882 NW-022 552.3 02/13/20 08:53 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 3 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW1
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.48 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
2454 Dibromoacetic acid 552.3 0.300 0.372 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
2451 Dichloroacetic acid 552.3 0.200 7.13 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
2452 Trichloroacetic acid 552.3 0.500 5.40 ug/L 02/20/20 08:47 02/22/20 00:04 4565882
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 4 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW2
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565883 NW-024 552.3 02/13/20 08:34 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 5 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW2
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.59 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
2454 Dibromoacetic acid 552.3 0.300 0.499 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
2451 Dichloroacetic acid 552.3 0.200 6.38 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
2452 Trichloroacetic acid 552.3 0.500 4.14 ug/L 02/20/20 08:47 02/22/20 00:41 4565883
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 6 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW3
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565884 NW-025 552.3 02/13/20 10:29 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 7 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW3
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.36 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
2454 Dibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
2451 Dichloroacetic acid 552.3 0.200 7.53 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
2452 Trichloroacetic acid 552.3 0.500 6.66 ug/L 02/20/20 08:47 02/22/20 01:18 4565884
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 8 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW4
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565885 NW-031 552.3 02/13/20 12:17 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 9 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW4
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.60 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
2454 Dibromoacetic acid 552.3 0.300 0.748 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
2451 Dichloroacetic acid 552.3 0.200 3.84 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
2452 Trichloroacetic acid 552.3 0.500 1.55 ug/L 02/20/20 08:47 02/22/20 03:09 4565885
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 10 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW5
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565886 NW-044 552.3 02/13/20 09:49 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 11 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW5
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.64 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
2454 Dibromoacetic acid 552.3 0.300 0.713 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
2451 Dichloroacetic acid 552.3 0.200 4.50 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
2452 Trichloroacetic acid 552.3 0.500 1.66 ug/L 02/20/20 08:47 02/22/20 03:46 4565886
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 12 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW6
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565887 NW-065 552.3 02/13/20 09:32 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 13 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW6
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.47 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
2454 Dibromoacetic acid 552.3 0.300 0.338 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
2451 Dichloroacetic acid 552.3 0.200 7.32 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
2452 Trichloroacetic acid 552.3 0.500 5.86 ug/L 02/20/20 08:47 02/22/20 04:23 4565887
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 14 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW7
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565888 NW-091 552.3 02/13/20 10:01 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 15 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW7
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.57 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
9339 Chlorodibromoacetic acid 552.3 0.300 0.334 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
2454 Dibromoacetic acid 552.3 0.300 0.707 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
2451 Dichloroacetic acid 552.3 0.200 4.31 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
2452 Trichloroacetic acid 552.3 0.500 1.74 ug/L 02/20/20 08:47 02/22/20 05:00 4565888
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 16 of 30
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478613
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00006
NW8
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565889 NW-127 552.3 02/13/20 11:19 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478613
Authorized Signature Title Date
02/28/2020
Page 1 of 2
Page 17 of 30
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 478613Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290388NW8
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.60 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
2454 Dibromoacetic acid 552.3 0.300 0.443 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
2451 Dichloroacetic acid 552.3 0.200 7.13 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
2452 Trichloroacetic acid 552.3 0.500 5.02 ug/L 02/20/20 08:47 02/22/20 05:36 4565889
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 18 of 30
Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
Page 1 of 1
Page 19 of 30
Page 20 of 30
.•:. eurofins -:~ 110 S. Hill Street 3(.p 978'9 South Bend, IN 46617 Order #
Eaton Analytical T: 1.800.332.4345 '±]X-&L3 F: 1.574.233.8207 Batch#
r.nvw,Eur.2!iasus c'2rnlfatc□ -
UCMR 4 CHAIN OF CUSTODY RECORD Page_ of __
Shaded area for EEA use onlv CLIENT NAME: SAMPLER (Print name) *PWS ID# STATE of s ample origin Check if this is a resample D
Check If requires upload to EPA database D Examplo: IN1234507 w r1 must have info for fields indicated with • for
PO#: If samples are not shipped the same day as collection then the temperature upload
B i ll To: the samples were held at must be recorded here(' C):
*Sampling Even t ---- -- Pres ervative VJ
List 1 Additionals SEH1 SEH2 "' Sampling Event n ___ Ch e c ks w
SEH3 SEH4 z (soe cr•leria below) < ,_
*FACILITY ID: (per EPA *Sampling z COLLECTION *SAMPLE POINT ID : (per EPA Temperature Upon 0
LAB Number Requirement)-5 P o int Type Test N ame UCMR4-pH Residual u
Requirement)-20 characters max L ab Rec e ipt ·c Chlorine ... accep• 0 DATE TIME AM PM characters max Code table?v IP/A\ ..
1 Lt SI n '\ g-~;:} o·z./,3 DR"~3 JJW - 0&d- 552.3 HAAs S.8' NA A- 1
--,, g~s '{)-z,/,3 113'{- /Ju/- O::J 4- I,. .o JJrr fJ- I 2
3 >(\?4 :) Z../1 -:i, !O~ Al Lu-() d'S 4.& /--IA- ,4- r
4 ~<; tJi./1 ~ t:ri 7 Nu.J -() St s.o /I.I 14 /}- I
5 8~11 oi/1 2, oqlfq ;J/1 J - f'JL/l../ t_;.o AlA- 4 I
6 8~1 oi /1 ~ /)q ~;;,. Alu J-n t,_, , l/. '-/- NA- A I
7 ~ ~1-/, 3 Jnf) / JJW-01 I s.n t>.IA 4 (
8 c:,J/ g180) ~2/13 Ill !Cr AIW-J;J7 "· '-/ j}ff A- !
9 ~ l,, ) ()Z./ 7 /lll? ' I II
10
11
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME LAB COM~ENTS,
1Witd It'! I I tt. /fl, (:Jtf !tr AM I PM AMI PM
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
CONDITIONS UPON RECEl~ l~ed: We~ lue Check if received on day of collection: D AM PM AMI PM
RELINQUISHED BY:(Signature) DATE TIME RECEIVED FOR LABORATORY BY: Dr ~i)
TIME Samples received within 48 hours of collection must be received at a temperature of s 1 0'C.
/J~ 14 I/)j£;/~ lft f~,1~ hR'[J_( Samples received past 48 hours of collection are only valid if received at s 6' C, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AM I PM all methods EXCEPT 200.8 and 300.0.
KEY UCMR4 acceptancefiriteria ~ Reqfiving Checks: *Sampling Point Type Code: 11
See Metal Samples P reservation 200.8 pH < 2 I 545 pH s 4 ll 1 pH s 3 SR = source water taken from plant intake; untreated water entering the wa ter treatment plant Log 525.3 pH s 4 544 pH 6 .5-7.5 EP = entry point to the distribution system P = P resent 530 pH a bout 7 (6-8) TOC pH < 2 DS = distribution system sample A = A bs e n t Must be absent of residual chlorine(free): 525.3, 530, 541 . 544. 545. 546, and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO-F091 2 Issue: 7.0 Effective Date: 2019-11-13
Sample analysis will be provided according to lhe standard EEA/Water Services Terms. which are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 21 of 30
Subcontracted Chain of Custody
~ Hillsborough II I I I II 111111111111111 Customer: Northwest Hillsborough CWS Environmental Laboratory
- ,~ -- --- Pro1ec1: ~ - U CMR-HAA
County I rida 9456 E Columbus D r Tampa, FL 33619 Work Order: 20010093
Contact: Stanley, John (Chief Environmental Certification N umber: E44104 Scheduled Sample Scientist)
Public Utilities NW - UCMR4 HAA9
Phone No. (813) 272-5977 x 43635 Set Name: Phone: (813) 272-5977 X 43635
Subcontracted Vendor: Eurofins Eaton Analytical Profile #
''"
Sample Information --6smple ID: Customer. - ----1PWS*n----.,s 11r~e_---,C--,o""ll""eclion Daleffime:
20010093-01-2 Northwest Hillsborough CWS 6290388 NW-022 Start: 2113/2020 8:53:00 AM
Address: 1005 Terra Mar Dr End: 2113/2020 8:53:00 AM
Collector: McClory, Alexandra Title· Environmental Specialist I
20010093-02-2 Northwest Hillsborough CWS 6290388 NW-024 Start: 2/13/2020 8:34 :00 AM
Address: 14906 laurio ln End: 2113/2020 8:34:00 AM
Collector: McClory, Alexandra Tillo: Environmental Specialist I
Sample Type:
Drinking Waler
(Grab)
Drinking Water
(Grab)
20010093-03-2 l~orthwest Hillsborough CWS 6290388 NW-025 Start: 2113/2020 10:29:00 AM Drinking Water
Address: 19109 Sunlake Blvd End: 2113/2020 10:29:00 AM (Grab)
Collector: McClory, Alexandra Title: Environmenlal Specialisl I
20010093-04-2 Northwesl Hillsborough CWS 6290388 NW-031 Start: 2113/2020 12:17:00 PM Drinking Water
Address: 8112 Honeybee ln End: 2113/2020 12:17:00 PM (Grab)
Collector: McClory, Alexandra Tille: Environmental Specialist I
Report Generated: 02/13/2020 01 :45 PM
R1mort Version·3 .6 .63 1 Last RP.vised 10/17/2019 3·13·33 PM
Container Type:
Glass 250 ml Amber
Field Results
Analyte
Preservative:
NH4Cl
Analysis Method:
552,3 - HAA9 Subcontracted
Result
Total Chlorine Residual (10260 - Cl by Chemkey) 3 .54
Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3 .35
Glass 250 ml Amber NH4CL 552.3 - HAA9 Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - Cl by C hemkey)
Result
3.70
Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
Field Results
A na lyte
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3 .03
Analytes:
Units
mg/L
Units
mg/L
U nits
mg/L
Units
mg/L
Page 1 of 3
Page 22 of 30
Subcontracted Chain of Custody
~ II I I I II 111111111111111 Customer: Northwest Hillsborough CWS
Hillsborough Environmenta l Laboratory ProJect: NW-:'UCMR-HAA
County tarida 9456 E Columbus Dr Tampa, FL 33619 Work Order: 20010093
Contact: Stanley, John (Chief Environmental Certification Number: E44104 Scheduled Sample Scientist)
Public Utilities NW - UCMR4 HAA9 Phone No. (813) 272-5977 x 4 3635
Set Name: Phone: (813) 272-5977 X 43635
Subcontracted Vendor: Eurofins E aton Analytical Profile# -Sample Information
SampJeJD: Customer: PWS# Site.
20010093-05-2 Northwest Hillsborough CWS 6290388 NW-044
Address:
Collection Date/Time:
Start: 2/13/2020 9:49:00 AM
End: 2/13/2020 9:49:00 AM
Sample Type:
Drinking Waler
(Grab)
Colleclor:
4413 Rockcresl Cir
Mcclory, Alexandra Title: Environmenlal Specialist I
20010093-06-2 Northwest Hillsborough CWS 6290388 NW-065 Start: 2/13/2020 9:32:00 AM Drinking Water
(Grab) Address: 13608 Pub Pl End: 2/13/2020 9:32:00 AM
Colleclor: McClory, Alexandra Title: Environmental Specialisl I
20010093-07-2 Northwest Hillsborough CWS 6290388 NW-091 Start: 2/13/2020 10:01 :00 AM Drinking Water
Address· 10303 Chadbourne Dr End: 2/13/2020 10:01 :00 AM (Grab)
Colleclor: McClory, Alexandra Title: Environmental Specialist I
20010093·08-2 Northwesl Hillsborough CWS 6290388 NW-127 Start: 2/13/2020 11: 19:00 AM Drinking Waler
Address: 19208 Eastbrook Dr End: 2/13/2020 11:19:00AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialisl I
Container Type:
Glass 250 mL Amber
Field Results
Analyte
Preservalive: Analysis Melhod:
NH4CL 552.3 - HAAS Subcontracted
Result
Total Chlorine Residual (10260 - C l by Chemkey) 3.47
Glass 250 mL Amber
Field Results
Analyte
NH4CL 552.3 - HAAS Subconlracled
Result
Total Chlorine Residual (10260 - C l by Chemkey) 3.54
Glass 250 mL Amber
Field Results
Analyte
NH4CL 552.3 - HAA9 Subcontracted
Result
Total Chlorine Residual (10260 - Cl by Chem key) 3.89
Glass 250 mL Amber
Field Results
Analyte
NH4CL 552.3 - HAAS Subcontracted
Result
Total Chlorine Residual (10260 - Cl by Chemkey) 3.46
Analytes:
Units
m g/L
Units
m g/L
Units
mg/L
U nits
mg/L
---
Report Generated: 02/13/2020 01 :45 PM Page 2 of 3
R,mort VArsion·3 6 63 1 Last RAvised 10/ 17/2019 3 ·13·33 PM
-
Page 23 of 30
RelinQuishcd By: Notes:
~ Relinquished By: DatofTime:
Relinquished By: Date!Time: Accepted By. DatefTlme:
Report Generated: 02/13/2020 01 :45 PM Page 3 of 3
Renort Version:3 .6 .63 1 Last Revised 10/17/2019 3:13:33 PM
Eurofins Eaton AnalyticalRun Log
Run ID: 271736 Method: 552.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4568871 FU m 552.3 022020FU02/21/2020 16:44RW
LRB 4568865 FU m 552.3 022020FU02/21/2020 17:57RW
FS 4565882 NW-022 FU m 552.3 022020FU02/22/2020 00:04DW
FS 4565883 NW-024 FU m 552.3 022020FU02/22/2020 00:41DW
FS 4565884 NW-025 FU m 552.3 022020FU02/22/2020 01:18DW
CCM 4568876 FU m 552.3 022020FU02/22/2020 01:55RW
FS 4565885 NW-031 FU m 552.3 022020FU02/22/2020 03:09DW
FS 4565886 NW-044 FU m 552.3 022020FU02/22/2020 03:46DW
FS 4565887 NW-065 FU m 552.3 022020FU02/22/2020 04:23DW
FS 4565888 NW-091 FU m 552.3 022020FU02/22/2020 05:00DW
FS 4565889 NW-127 FU m 552.3 022020FU02/22/2020 05:36DW
CCH 4568879 FU m 552.3 022020FU02/22/2020 09:17RW
0.00
Page 1 of 5 EEA Run ID 271736 / EEA Report # 478613
Page 24 of 30
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
SS-2-Bromopropionic acid 552.3 N/ACCL 4.9225 ug/L 1.0 4568871--- ------70 - 130985.0 02/20/2020 08:47 02/21/2020 16:44False
Bromochloroacetic acid 552.3 0.300CCL 0.3573 ug/L 1.0 4568871--- ------50 - 1501190.3 02/20/2020 08:47 02/21/2020 16:44False
Bromodichloroacetic acid 552.3 0.500CCL 0.5627 ug/L 1.0 4568871--- ------50 - 1501130.5 02/20/2020 08:47 02/21/2020 16:44False
Chlorodibromoacetic acid 552.3 0.300CCL 0.3642 ug/L 1.0 4568871--- ------50 - 1501210.3 02/20/2020 08:47 02/21/2020 16:44False
Dibromoacetic acid 552.3 0.300CCL 0.2523 ug/L 1.0 4568871--- ------50 - 150840.3 02/20/2020 08:47 02/21/2020 16:44False
Dichloroacetic acid 552.3 0.200CCL 0.1399 ug/L 1.0 4568871--- ------50 - 150700.2 02/20/2020 08:47 02/21/2020 16:44False
Monobromoacetic acid 552.3 0.300CCL 0.2827 ug/L 1.0 4568871--- ------50 - 150940.3 02/20/2020 08:47 02/21/2020 16:44False
Monochloroacetic acid 552.3 2.00CCL 2.1837 ug/L 1.0 4568871--- ------50 - 1501092.0 02/20/2020 08:47 02/21/2020 16:44False
Tribromoacetic acid 552.3 2.00CCL 2.4409 ug/L 1.0 4568871--- ------50 - 1501222.0 02/20/2020 08:47 02/21/2020 16:44False
Trichloroacetic acid 552.3 0.500CCL 0.6877 ug/L 1.0 4568871--- ------50 - 1501380.5 02/20/2020 08:47 02/21/2020 16:44False
IS-1,2,3-Trichloropropane 552.3 N/ACCL 1845 ug/L 1.0 4568871--- ------50 - 150991868 02/20/2020 08:47 02/21/2020 16:44True
SS-2-Bromopropionic acid 552.3 N/ALRB 5.1058 ug/L 1.0 4568865--- ------70 - 1301025.0 02/20/2020 08:47 02/21/2020 17:57True
Bromochloroacetic acid 552.3 0.300LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Bromodichloroacetic acid 552.3 0.500LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Chlorodibromoacetic acid 552.3 0.300LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Dibromoacetic acid 552.3 0.300LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Dichloroacetic acid 552.3 0.200LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Monobromoacetic acid 552.3 0.300LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Monochloroacetic acid 552.3 2.00LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Tribromoacetic acid 552.3 2.00LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
Trichloroacetic acid 552.3 0.500LRB 0.0 ug/L 1.0 4568865--- ------------ < 02/20/2020 08:47 02/21/2020 17:57True
IS-1,2,3-Trichloropropane 552.3 N/ALRB 1828 ug/L 1.0 4568865--- ------50 - 150981868 02/20/2020 08:47 02/21/2020 17:57False
SS-2-Bromopropionic acid 552.3 N/AFS 4.5190 ug/L 1.0 4565882NW-022 ------70 - 130905.0 02/20/2020 08:47 02/22/2020 00:04False
Bromochloroacetic acid 552.3 0.300FS 1.48 ug/L 1.0 4565882NW-022 ------------ 02/20/2020 08:47 02/22/2020 00:04False
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565882NW-022 ------------ < 02/20/2020 08:47 02/22/2020 00:04False
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565882NW-022 ------------ < 02/20/2020 08:47 02/22/2020 00:04False
Dibromoacetic acid 552.3 0.300FS 0.372 ug/L 1.0 4565882NW-022 ------------ 02/20/2020 08:47 02/22/2020 00:04False
Dichloroacetic acid 552.3 0.200FS 7.13 ug/L 1.0 4565882NW-022 ------------ 02/20/2020 08:47 02/22/2020 00:04False
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565882NW-022 ------------ < 02/20/2020 08:47 02/22/2020 00:04False
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565882NW-022 ------------ < 02/20/2020 08:47 02/22/2020 00:04False
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565882NW-022 ------------ < 02/20/2020 08:47 02/22/2020 00:04False
Trichloroacetic acid 552.3 0.500FS 5.40 ug/L 1.0 4565882NW-022 ------------ 02/20/2020 08:47 02/22/2020 00:04False
IS-1,2,3-Trichloropropane 552.3 N/AFS 1803 ug/L 1.0 4565882NW-022 ------50 - 150961868 02/20/2020 08:47 02/22/2020 00:04False
Total HAA5 552.3 2.00FS 12.902 ug/L 1.0 4565882NW-022 ------------ 02/20/2020 08:47 02/22/2020 00:04True
SS-2-Bromopropionic acid 552.3 N/AFS 4.8015 ug/L 1.0 4565883NW-024 ------70 - 130965.0 02/20/2020 08:47 02/22/2020 00:41True
Bromochloroacetic acid 552.3 0.300FS 1.59 ug/L 1.0 4565883NW-024 ------------ 02/20/2020 08:47 02/22/2020 00:41True
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565883NW-024 ------------ < 02/20/2020 08:47 02/22/2020 00:41True
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565883NW-024 ------------ < 02/20/2020 08:47 02/22/2020 00:41True
Dibromoacetic acid 552.3 0.300FS 0.499 ug/L 1.0 4565883NW-024 ------------ 02/20/2020 08:47 02/22/2020 00:41True
Dichloroacetic acid 552.3 0.200FS 6.38 ug/L 1.0 4565883NW-024 ------------ 02/20/2020 08:47 02/22/2020 00:41
Page 2 of 5 EEA Run ID 271736 / EEA Report # 478613
Page 25 of 30
c=Jl=========:;;::::===ll======l:=======l;:::::====:1==::::::;;::::==::::;;::::====:;;::::====::===:l====ll== c=J===========::::::== c=Jl=========:;;::::== c=Jl=========:;;::::== c=J===========::::::== c=Jl=========:;;::::== c=Jl=========:;;::::== c=Jl=========:;;::::== c=J~=========ll=== c=J~=========ll=== c=J
c=Jl=========:;;::::===ll======l:=======l;:::::====:1==::::::;;::::==::::;;::::====:;;::::====::===:l====ll== c=J===========::::::== c=J~=========ll=== c=J ____________ , ___ .. ________________ ,___,,___. .. ___..___ ________ ~
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
True
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565883NW-024 ------------ < 02/20/2020 08:47 02/22/2020 00:41True
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565883NW-024 ------------ < 02/20/2020 08:47 02/22/2020 00:41True
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565883NW-024 ------------ < 02/20/2020 08:47 02/22/2020 00:41True
Trichloroacetic acid 552.3 0.500FS 4.14 ug/L 1.0 4565883NW-024 ------------ 02/20/2020 08:47 02/22/2020 00:41True
IS-1,2,3-Trichloropropane 552.3 N/AFS 1861 ug/L 1.0 4565883NW-024 ------50 - 1501001868 02/20/2020 08:47 02/22/2020 00:41True
Total HAA5 552.3 2.00FS 11.019 ug/L 1.0 4565883NW-024 ------------ 02/20/2020 08:47 02/22/2020 00:41False
SS-2-Bromopropionic acid 552.3 N/AFS 4.4084 ug/L 1.0 4565884NW-025 ------70 - 130885.0 02/20/2020 08:47 02/22/2020 01:18False
Bromochloroacetic acid 552.3 0.300FS 1.36 ug/L 1.0 4565884NW-025 ------------ 02/20/2020 08:47 02/22/2020 01:18False
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Dibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Dichloroacetic acid 552.3 0.200FS 7.53 ug/L 1.0 4565884NW-025 ------------ 02/20/2020 08:47 02/22/2020 01:18False
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565884NW-025 ------------ < 02/20/2020 08:47 02/22/2020 01:18False
Trichloroacetic acid 552.3 0.500FS 6.66 ug/L 1.0 4565884NW-025 ------------ 02/20/2020 08:47 02/22/2020 01:18False
IS-1,2,3-Trichloropropane 552.3 N/AFS 1840 ug/L 1.0 4565884NW-025 ------50 - 150981868 02/20/2020 08:47 02/22/2020 01:18False
Total HAA5 552.3 2.00FS 14.19 ug/L 1.0 4565884NW-025 ------------ 02/20/2020 08:47 02/22/2020 01:18True
SS-2-Bromopropionic acid 552.3 N/ACCM 5.1258 ug/L 1.0 4568876--- ------70 - 1301035.0 02/20/2020 08:47 02/22/2020 01:55True
Bromochloroacetic acid 552.3 0.300CCM 6.0535 ug/L 1.0 4568876--- ------70 - 1301016.0 02/20/2020 08:47 02/22/2020 01:55True
Bromodichloroacetic acid 552.3 0.500CCM 8.1862 ug/L 1.0 4568876--- ------70 - 1308210.0 02/20/2020 08:47 02/22/2020 01:55True
Chlorodibromoacetic acid 552.3 0.300CCM 4.4904 ug/L 1.0 4568876--- ------70 - 130756.0 02/20/2020 08:47 02/22/2020 01:55True
Dibromoacetic acid 552.3 0.300CCM 6.9265 ug/L 1.0 4568876--- ------70 - 1301156.0 02/20/2020 08:47 02/22/2020 01:55True
Dichloroacetic acid 552.3 0.200CCM 4.8736 ug/L 1.0 4568876--- ------70 - 1301224.0 02/20/2020 08:47 02/22/2020 01:55True
Monobromoacetic acid 552.3 0.300CCM 6.6947 ug/L 1.0 4568876--- ------70 - 1301126.0 02/20/2020 08:47 02/22/2020 01:55True
Monochloroacetic acid 552.3 2.00CCM 20.9704 ug/L 1.0 4568876--- ------70 - 13010520.0 02/20/2020 08:47 02/22/2020 01:55True
Tribromoacetic acid 552.3 2.00CCM 14.6005 ug/L 1.0 4568876--- ------70 - 1307320.0 02/20/2020 08:47 02/22/2020 01:55True
Trichloroacetic acid 552.3 0.500CCM 8.5305 ug/L 1.0 4568876--- ------70 - 1308510.0 02/20/2020 08:47 02/22/2020 01:55True
IS-1,2,3-Trichloropropane 552.3 N/ACCM 1831 ug/L 1.0 4568876--- ------50 - 150981868 02/20/2020 08:47 02/22/2020 01:55False
SS-2-Bromopropionic acid 552.3 N/AFS 4.8425 ug/L 1.0 4565885NW-031 ------70 - 130975.0 02/20/2020 08:47 02/22/2020 03:09False
Bromochloroacetic acid 552.3 0.300FS 1.60 ug/L 1.0 4565885NW-031 ------------ 02/20/2020 08:47 02/22/2020 03:09False
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565885NW-031 ------------ < 02/20/2020 08:47 02/22/2020 03:09False
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565885NW-031 ------------ < 02/20/2020 08:47 02/22/2020 03:09False
Dibromoacetic acid 552.3 0.300FS 0.748 ug/L 1.0 4565885NW-031 ------------ 02/20/2020 08:47 02/22/2020 03:09False
Dichloroacetic acid 552.3 0.200FS 3.84 ug/L 1.0 4565885NW-031 ------------ 02/20/2020 08:47 02/22/2020 03:09False
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565885NW-031 ------------ < 02/20/2020 08:47 02/22/2020 03:09False
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565885NW-031 ------------ < 02/20/2020 08:47 02/22/2020 03:09False
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565885NW-031 ------------ < 02/20/2020 08:47 02/22/2020 03:09False
Trichloroacetic acid 552.3 0.500FS 1.55 ug/L 1.0 4565885NW-031 ------------ 02/20/2020 08:47 02/22/2020 03:09False
IS-1,2,3-Trichloropropane 552.3 N/AFS 1793 ug/L 1.0 4565885NW-031 ------50 - 150961868 02/20/2020 08:47 02/22/2020 03:09False
Total HAA5 552.3 2.00FS 6.138 ug/L 1.0 4565885NW-031 ------------ 02/20/2020 08:47 02/22/2020 03:09
Page 3 of 5 EEA Run ID 271736 / EEA Report # 478613
Page 26 of 30
c=J=========::;ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J=========::;ll==== c=J::=======::;'ll==== c=)l========O=====ll====4!=======41=====4?=====1:1=====4~==:;1======411====:1====41== c=J
c=J=========::;ll==== c=J::=======::;'ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J::=======::;'ll==== c=Jl==========ll=====ll===Ct======::;ll=====l:======::1=====4::==::1======411====:1====41====4::=::1=====::1=====11=====:
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SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
True
SS-2-Bromopropionic acid 552.3 N/AFS 4.5728 ug/L 1.0 4565886NW-044 ------70 - 130915.0 02/20/2020 08:47 02/22/2020 03:46True
Bromochloroacetic acid 552.3 0.300FS 1.64 ug/L 1.0 4565886NW-044 ------------ 02/20/2020 08:47 02/22/2020 03:46True
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565886NW-044 ------------ < 02/20/2020 08:47 02/22/2020 03:46True
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565886NW-044 ------------ < 02/20/2020 08:47 02/22/2020 03:46True
Dibromoacetic acid 552.3 0.300FS 0.713 ug/L 1.0 4565886NW-044 ------------ 02/20/2020 08:47 02/22/2020 03:46True
Dichloroacetic acid 552.3 0.200FS 4.50 ug/L 1.0 4565886NW-044 ------------ 02/20/2020 08:47 02/22/2020 03:46True
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565886NW-044 ------------ < 02/20/2020 08:47 02/22/2020 03:46True
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565886NW-044 ------------ < 02/20/2020 08:47 02/22/2020 03:46True
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565886NW-044 ------------ < 02/20/2020 08:47 02/22/2020 03:46True
Trichloroacetic acid 552.3 0.500FS 1.66 ug/L 1.0 4565886NW-044 ------------ 02/20/2020 08:47 02/22/2020 03:46True
IS-1,2,3-Trichloropropane 552.3 N/AFS 1860 ug/L 1.0 4565886NW-044 ------50 - 1501001868 02/20/2020 08:47 02/22/2020 03:46True
Total HAA5 552.3 2.00FS 6.873 ug/L 1.0 4565886NW-044 ------------ 02/20/2020 08:47 02/22/2020 03:46False
SS-2-Bromopropionic acid 552.3 N/AFS 4.5253 ug/L 1.0 4565887NW-065 ------70 - 130915.0 02/20/2020 08:47 02/22/2020 04:23False
Bromochloroacetic acid 552.3 0.300FS 1.47 ug/L 1.0 4565887NW-065 ------------ 02/20/2020 08:47 02/22/2020 04:23False
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565887NW-065 ------------ < 02/20/2020 08:47 02/22/2020 04:23False
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565887NW-065 ------------ < 02/20/2020 08:47 02/22/2020 04:23False
Dibromoacetic acid 552.3 0.300FS 0.338 ug/L 1.0 4565887NW-065 ------------ 02/20/2020 08:47 02/22/2020 04:23False
Dichloroacetic acid 552.3 0.200FS 7.32 ug/L 1.0 4565887NW-065 ------------ 02/20/2020 08:47 02/22/2020 04:23False
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565887NW-065 ------------ < 02/20/2020 08:47 02/22/2020 04:23False
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565887NW-065 ------------ < 02/20/2020 08:47 02/22/2020 04:23False
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565887NW-065 ------------ < 02/20/2020 08:47 02/22/2020 04:23False
Trichloroacetic acid 552.3 0.500FS 5.86 ug/L 1.0 4565887NW-065 ------------ 02/20/2020 08:47 02/22/2020 04:23False
IS-1,2,3-Trichloropropane 552.3 N/AFS 1824 ug/L 1.0 4565887NW-065 ------50 - 150981868 02/20/2020 08:47 02/22/2020 04:23False
Total HAA5 552.3 2.00FS 13.518 ug/L 1.0 4565887NW-065 ------------ 02/20/2020 08:47 02/22/2020 04:23True
SS-2-Bromopropionic acid 552.3 N/AFS 4.3113 ug/L 1.0 4565888NW-091 ------70 - 130865.0 02/20/2020 08:47 02/22/2020 05:00True
Bromochloroacetic acid 552.3 0.300FS 1.57 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00True
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565888NW-091 ------------ < 02/20/2020 08:47 02/22/2020 05:00True
Chlorodibromoacetic acid 552.3 0.300FS 0.334 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00True
Dibromoacetic acid 552.3 0.300FS 0.707 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00True
Dichloroacetic acid 552.3 0.200FS 4.31 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00True
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565888NW-091 ------------ < 02/20/2020 08:47 02/22/2020 05:00True
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565888NW-091 ------------ < 02/20/2020 08:47 02/22/2020 05:00True
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565888NW-091 ------------ < 02/20/2020 08:47 02/22/2020 05:00True
Trichloroacetic acid 552.3 0.500FS 1.74 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00True
IS-1,2,3-Trichloropropane 552.3 N/AFS 1846 ug/L 1.0 4565888NW-091 ------50 - 150991868 02/20/2020 08:47 02/22/2020 05:00True
Total HAA5 552.3 2.00FS 6.757 ug/L 1.0 4565888NW-091 ------------ 02/20/2020 08:47 02/22/2020 05:00False
SS-2-Bromopropionic acid 552.3 N/AFS 4.7494 ug/L 1.0 4565889NW-127 ------70 - 130955.0 02/20/2020 08:47 02/22/2020 05:36False
Bromochloroacetic acid 552.3 0.300FS 1.60 ug/L 1.0 4565889NW-127 ------------ 02/20/2020 08:47 02/22/2020 05:36False
Bromodichloroacetic acid 552.3 0.500FS 0.500 ug/L 1.0 4565889NW-127 ------------ < 02/20/2020 08:47 02/22/2020 05:36False
Chlorodibromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565889NW-127 ------------ < 02/20/2020 08:47 02/22/2020 05:36False
Dibromoacetic acid 552.3 0.300FS 0.443 ug/L 1.0 4565889NW-127 ------------ 02/20/2020 08:47 02/22/2020 05:36
Page 4 of 5 EEA Run ID 271736 / EEA Report # 478613
Page 27 of 30
c=J===========;l;::::== c=J::==========ill=== c=J::==========ill=== c=J===========;l;::::== c=J::==========ill=== c=)::==========ill====H=====ll======ll=====ll====:l====ll=====ll===U===ll====I::== c=)::==========ill====ll======Cl======ll=====ll====:l====ll=====ll=====l:===11====1::== c=J===========;l;::::== c=J::==========ill=== c=J
c=)::==========ill====ll======Cl======ll=====ll====:l====ll=====ll=====l:===11====1::== c=J===========;l;::::== c=J::==========ill=== c=J::==========ill=== c=J===========;l;::::== c=J::==========ill=== c=)::==========ill====ll======Cl======ll=====ll====:l====ll=====ll=====l:===11====1::== c=)::==========ill====ll======Cl======ll=====ll====:l====ll=====ll=====l:===11====1::== c=J===========;l;::::== c=J::==========ill=== c=J
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
False
Dichloroacetic acid 552.3 0.200FS 7.13 ug/L 1.0 4565889NW-127 ------------ 02/20/2020 08:47 02/22/2020 05:36False
Monobromoacetic acid 552.3 0.300FS 0.300 ug/L 1.0 4565889NW-127 ------------ < 02/20/2020 08:47 02/22/2020 05:36False
Monochloroacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565889NW-127 ------------ < 02/20/2020 08:47 02/22/2020 05:36False
Tribromoacetic acid 552.3 2.00FS 2.00 ug/L 1.0 4565889NW-127 ------------ < 02/20/2020 08:47 02/22/2020 05:36False
Trichloroacetic acid 552.3 0.500FS 5.02 ug/L 1.0 4565889NW-127 ------------ 02/20/2020 08:47 02/22/2020 05:36False
IS-1,2,3-Trichloropropane 552.3 N/AFS 1845 ug/L 1.0 4565889NW-127 ------50 - 150991868 02/20/2020 08:47 02/22/2020 05:36False
Total HAA5 552.3 2.00FS 12.593 ug/L 1.0 4565889NW-127 ------------ 02/20/2020 08:47 02/22/2020 05:36True
SS-2-Bromopropionic acid 552.3 N/ACCH 5.2620 ug/L 1.0 4568879--- ------70 - 1301055.0 02/20/2020 08:47 02/22/2020 09:17True
Bromochloroacetic acid 552.3 0.300CCH 15.1702 ug/L 1.0 4568879--- ------70 - 13010115.0 02/20/2020 08:47 02/22/2020 09:17True
Bromodichloroacetic acid 552.3 0.500CCH 22.0688 ug/L 1.0 4568879--- ------70 - 1308825.0 02/20/2020 08:47 02/22/2020 09:17True
Chlorodibromoacetic acid 552.3 0.300CCH 12.067 ug/L 1.0 4568879--- ------70 - 1308015.0 02/20/2020 08:47 02/22/2020 09:17True
Dibromoacetic acid 552.3 0.300CCH 16.9633 ug/L 1.0 4568879--- ------70 - 13011315.0 02/20/2020 08:47 02/22/2020 09:17True
Dichloroacetic acid 552.3 0.200CCH 10.3025 ug/L 1.0 4568879--- ------70 - 13010310.0 02/20/2020 08:47 02/22/2020 09:17True
Monobromoacetic acid 552.3 0.300CCH 15.0848 ug/L 1.0 4568879--- ------70 - 13010115.0 02/20/2020 08:47 02/22/2020 09:17True
Monochloroacetic acid 552.3 2.00CCH 30.0821 ug/L 1.0 4568879--- ------70 - 13010030.0 02/20/2020 08:47 02/22/2020 09:17True
Tribromoacetic acid 552.3 2.00CCH 21.4036 ug/L 1.0 4568879--- ------70 - 1307130.0 02/20/2020 08:47 02/22/2020 09:17True
Trichloroacetic acid 552.3 0.500CCH 25.3092 ug/L 1.0 4568879--- ------70 - 13010125.0 02/20/2020 08:47 02/22/2020 09:17True
IS-1,2,3-Trichloropropane 552.3 N/ACCH 1847 ug/L 1.0 4568879--- ------50 - 150991868 02/20/2020 08:47 02/22/2020 09:17
Page 5 of 5 EEA Run ID 271736 / EEA Report # 478613
Page 28 of 30
g~1 :::::::::::::::::::::::::::;::~::::::::,i~~:::::::::::::::i,:::::::::::::::i~i====:::::::::::::::::::::~1~
c=Jl============:~======l==~;::::=======:;::::::=::::::;;:::::::======;;:::~;:====:;:::=====:l;:::::====:;==;l==
c=J============::== c=J::==========ill== c=J::==========ill== c=J============::== c=J::==========ill== c=J::==========ill== c=J::==========ill== c=J::==========ill== c=J::==========ill== c=] _____ . _____________ ~---------------·-----.. --.... ~
Sample Type Key
Type (Abbr.) Sample Type Type (Abbr.) Sample Type
CCH Continuing Calibration High
CCL Continuing Calibration Low
CCM Continuing Calibration Mid
FS Field Sample
LRB Laboratory Reagent Blank
1.00
Page 29 of 30
END OF REPORT
Page 30 of 30
LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
Page 1 of 28
=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
STATE CERTIFICATION LIST
State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035
Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005
Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973
Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207
Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837
Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035
EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
Page 2 of 28
~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478601
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00001
0388001
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565778 LPWTP-002 200.8 02/13/20 10:51 Client 02/17/20 08:45
4565779 LPWTP-002 525.3 02/13/20 10:51 Client 02/17/20 08:45
4565780 LPWTP-002 530 02/13/20 10:51 Client 02/17/20 08:45
4565781 LPWTP-002 541 02/13/20 10:51 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478601
Authorized Signature Title Date
03/10/2020
Page 1 of 2
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=:~ eurofins I Eaton Analytical
§
Analytical Services Manager
Client Name: Report #: 478601Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL62903880388001
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
1053 Germanium 200.8 0.300 < 0.300 ug/L 02/21/20 10:20 02/24/20 14:50 4565778
1032 Manganese 200.8 0.400 2.48 ug/L 02/21/20 10:20 02/24/20 14:50 4565778
2115 alpha-Hexachlorocyclohexane 525.3 0.0100 < 0.0100 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2057 Chlorpyrifos 525.3 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2116 Dimethipin 525.3 0.200 < 0.200 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
7570 Ethoprop 525.3 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2117 Oxyfluorfen 525.3 0.0500 < 0.0500 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2118 Profenofos 525.3 0.300 < 0.300 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2119 Tebuconazole 525.3 0.200 < 0.200 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2114 Permethrin, cis & trans 525.3 0.0400 < 0.0400 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2120 Tribufos 525.3 0.0700 < 0.0700 ug/L 02/26/20 08:30 02/27/20 14:39 4565779
2433 Butylated hydroxyanisole 530 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 08:28 4565780
2434 o-Toluidine 530 0.00700 < 0.00700 ug/L 02/26/20 08:30 02/27/20 08:28 4565780
3435 Quinoline 530 0.0200 < 0.0200 ug/L 02/26/20 08:30 02/27/20 08:28 4565780
2084 1-Butanol 541 2.00 < 2.00 ug/L 03/06/20 07:00 03/06/20 23:40 4565781
2431 2-Methoxyethanol 541 0.400 < 0.400 ug/L 03/06/20 07:00 03/06/20 23:40 4565781
2432 2-Propen-1-ol 541 0.500 < 0.500 ug/L 03/06/20 07:00 03/06/20 23:40 4565781
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
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Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
Page 1 of 1
Page 5 of 28
Page 6 of 28
•·:: eurofins -:. 110 S. Hill Street 3&97 21 South Bend, IN 46617 Order#
Eaton Analytical T: 1.800.332.4345 '-fZi&_OI F: 1.574.233.8207 B atch# -
'i:1..'i:1."11. Eut:2fia5US camlEat,m UCMR 4 CHAIN OF CUSTODY RECORD Pagc_ of __
Shaded area for EEA use onlv
CLIENT NAME: SAMPLER (Print name) *PWS ID # S TATE of sample origin Check if this is a resample D Check if requires upload to EPA database D
Examplo: JN1 234567 we m ust have info for fie lds indicated w ith • for
PO#: If samples are not shipped the same day as collection then the temperature upload
Bill To: the samples were held at must be recorded here(°C):
*S ampling Event
--- Preserva,; vc List 1 Additionals SEA 1 SEA2 "' Sampling Event# ___ SEA3 SEA4; SEH1 SEH2 SEH3 Checks w z SEH4
(see cri:eria below) ~ *FACILITY ID: (per EPA *Sampling z
COLLECTION *SAMPLE POINT ID: (per EPA Temperature Upon 0 LAB Number Requirement)-5 Point Type Test Name UCMR4- pH Residual (.)
Requirement)-20 characters max Lab Receipt •c Chlorine u. acccp- 0 DATE TIME AM PM characters max Code table?~ IP/A\ "" 4S/o C::77? 02/,;;i I /J . ';/ LPLJTP-- 00~ (}. 0 ,. NA 1 1 200.8 Metals
"✓ 11c; r:J./7 / fJ 3 2 525.3
3 7RV 530 .2. '-I ✓ A 3
4 ;:; "'""' 7RI ' , 'v "\ / 541 O.f' ./ A- 3
5
6
7
8
9
10
11
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME LAB COMMENTS
AM I PM AM I PM RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
-AM PM AM I PM
CONDITIONS UPON RECEIP( Iced: Wet~ Blue Check if received on day of collection: D RELINQUISHED BY:(Signature) DATE TIME RECEIVED FOR LABORATORY BY: DATE TIME Samples received within 48 ho~ ._~ · ·· 1on must be received at a temperature of :S 1 0' C.
RD ,/lil/j 2,J!f 1\11\pl> Of?'IS Samples received past 48 hours of collection are only valid if received at :S 6°C, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AM I PM all methods EXCEPT 200.8 and 300.0.
KEY UCMR4 acceptancl criteri(/for ffeceiving Checks: *Sampling Point Type Code: "See Metal Samples Preservation 200.8pH<2 l 545pH s4 541 pHs 3 SR = source water taken from plant intake; untreated water entering the water treatment plant Log 525.3 pH s 4 544 p H 6.5-7.5 EP = entry point to the distribution system P = Present 530 pH about 7 (6-8) TOC pH< 2 DS = distribution system sample A= Absent Must be absent of residual chlorine(free): 525.3, 530, 541 , 544, 545, 546, and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO-F0912 Issue: 8.0 Effective Cate:
Sample analysis will be provided according to the standard EEA/Water Services Terms. which are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 7 of 28
Subcontracted Chain of Custody ,---------------------------------------, ,-------------"'--------------------------~
Hillsborou h County onaa Public Utilities
Environmental Laboratory
9456 E Columbus D r T ampa, FL 33619
Certification Number: E44104
Phone No. (813) 272-5977 x 43635
II I I I II 111111111111111 Work Order: 20010094
Scheduled Sample NW _ UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical 11 ~
Customer: Northwest Hillsborough CWS
-;ect- NW - UeMR>t=SV-
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample ID· Cuslo PWS#- Site: Collection DatefTime:
Sample Information Sample Type:-ContalnerType: Preservative: Analysis Method: Analytes:
20010094-02-10 Northwest Hillsborough CWS 6290388
Address:
NWPWF-002
Start:
End:
Collector:
12950 Fawnridge Blvd
Mcclory, Alexandra TIiie. Environmental Specialist I
20010094-02-11 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Tille: Environmental Specialist I
20010094-02-2 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-3 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Stan:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 02:10 PM
RP.nnrt VP.rsinn:3 .6 63 1 L;cist Revised 10/17/2019 3 ·13:33 PM
2/13/2020 11:47:00 AM
2/13/202011:47:00AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Glass 125 ml Amber
Field Results
Analyte
Sulfite + Bisulfate
Total Chlorine Residual (10260 - Cl by C hemkey)
Result
4 .52
Plastic 250 ml None 200.8 - UCMR Metals Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
4.52
Glass 1 l Amber AA+ EDTA+ Kdihydrogen citrate
525 3 - UCMR List Subcontracted
Field Results
Analyte
Total Chlorine Residual (1 0260 - Cl by Chemkey)
Glass 1 l Amber
Field Results
Analy1e
AA+ EDTA + Kdihydrogen citrate
T otal Chlorine Residual (10260 - C l by Chemkey)
Result
4.52
Result
4.52
Units
mg/L
U nits
mg/L
Units
mg/L
Units
mg/L
Page 1 o f 6
Page 8 of 28
Subcontracted Chain of Custody ~--------------------------------------~ ,------------~------------------------- ---~
Hillsborou h County 10
Environmental Laboratory
Public Utilities C ertification Number: E44104
Phone No. (813) 272-5977 x 4 3635
Sample ID: Customer: PWS# Site: Collectioo_Date/Time·
20010094-02-4 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-5 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnrldge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-6 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-7 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory. Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 02:10 PM
RP.oort Version·3 .6 6'.l 1 I ;ist RP.viserl 10/ 17/2019 J ·1J·JJ PM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/202011:47:00AM
2/13/2020 11:47:00 AM
2/13/202011:47:00AM
2/13/2020 11 :47:00 AM
2/13/2020 11 :47:00 AM
II I I I II 111111111111111 Customer: Northwest Hillsborough CWS
---------------------'P'-rc=o"'·e~c~t:- NW - UCMR4-SV Work Order: 20010094
Scheduled Sample NW _ UCMR4 SV Set Name:
Subcontracted Vendor: E urofins Eaton Analytical
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sam.pie Type·
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
CnotaioeLTyp~
Glass 1 L Amber
Field R esults
Analyte
..&ese!Yatille.;_
AA+EDTA+Kdihydrogen citrate
Analysis-Method:
Total Chlorine Residual (10260 - C l by Chemkey)
Result
4.52
Glass 1 L Amber Trizma +AA+ EDTA + 530 - UCMR Semivolatiles
Field Results
Analyte
dUrea Subcontracted
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 1 L Amber
Field Results
Analyte
Trizma +AA+ EDTA + dUrea
Total Chlo r ine Residual ( 10260 - C l by C hemkey)
Glass 1 L Amber
Field Results
Analyte
Trizma + AA+ EDTA + dUrea
Total Chlo r ine Residual (10260 - C l by Chemkey)
Result
4 .52
Res ul t
4 .52
Result
4 .52
--Analytes::----
Units
mg/L
Units
m g/L
U nits
mg/L
U nits
m g/L
Page 2 of 6
Page 9 of 28
Subcontracted Chain of Custody ~------------- -------------------------~ ,--------------=----------------------------~
H i,.._.__,,~.x..1.--.:~1-'h!....!.-__ ~~E-nv~ir_on_m_en~ta_l ~La_b_o r_at~ory~~--+------l=---•-l _l_l_l_l_l_l_l_l_l_l_l_l_l_l_l_l_l_l_l l_..i:c .l.-'(us1¥>to...._me_r:_,Ncuo.x..:rt~:...~1.u.,.:M...,t :=:=~:-"--:rough CWS
County 9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
Public Utilities Phone No. (813) 272-5977 x 43635
Work Order: 20010094
Scheduled Sample NW _ UCMR4 SV Set Name:
Subcontracted Vendor: Eu rofins Eaton Analytical
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Samp!e ID: Customer: PW Site: Collection Date/Time·
Sample Information Sample. Type.- Container Type: Preservative: Anelysis Method: Analytes:
20010094-02-8 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
2/13/2020 11 :47:00 AM
2113/2020 11:47:00 AM
Drinking Water
(Grab)
Collector: McClory. Alexandra Title· Environmental Specialist I
20010094-02-9 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF• 002
Start:
End:
2113/2020 11:47:00AM
2113/2020 11:47:00 AM
Drinking Water
(Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01 -10 Northwest Hillsborough CWS 6290388
Address. 17316 N Dale Mabry Hwy
LPWTP-002
Start: 2113/2020 10:51:00 AM Drinking Water
End: 2113/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01 -11 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2113/2020 10:51:00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 02:10 PM
Reoort Version·3 6 .63 1 L;,st Revised 10/17/2019 3·13·33 PM
Glass 125 ml Amber Sulfite + B,sulfate 541 - UCMR Alcohols Subcontracted
Field Results
Analyte
Total Chlor ine Residual (10260 - Cl by Chemkey)
Glass 125 ml Amber
Field Results
Analyte
Sulfite + Bisulfate
Total Chlorine Residual (10260 - Cl by Chemkey)
Glass 125 ml Amber
Field Results
Analyte
Sulfite + Bisulfale
Total C hlorine Residual (10260 - Cl by C hemkey)
Result
4.52
Result
4 .52
Result
3.98
Plastic 250 ml None 200.8 - UCMR Metals Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - C l by Chemkey)
Result
3.9 8
Units
mg/L
Units
mg/L
Units
mg/L
Units
mg/L
Page 3 of 6
Page 10 of 28
Subcontracted Chain of Custody ,-------------------- --- ------------, r----------=------------------- ---~
Hillsborough County , rida Pub lic Util ities
Environmental Laboratory
C ertification Numb er: E44 104
Phone No. (813) 272-5977 x 43635
II I I I II 111111111111111 Customer: Northwest Hillsborough CWS
Work·_ o_r_d_e_r_: _2_0_0_1_0_0_9_4 ___ ~~-P~ro~·e~ct: NW. UCMR4-SV
Contact: Stanley, John (Chief Environmental
Scheduled Sample NW • UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical
Scientist)
Phone: (813) 272-5977 x 43635
Profile #
Sample Information Sample ID: Customer: PWS#
2001009/4-01-2 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
Site:
LPWfP· 002
Collection Date/Time: Sample Type:
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra nt1e: Environmental Specialist I
20010094-01-3 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP 002
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: Mcclory, Alexandra nue: Environmental Specialist I
20010094-01 -4 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP-002
Slart: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-0i-5 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Ma ry Hwy
LPWTP-002.
Start: 2/13/2020 10:51:00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 02:10 PM
Rrrnnrt VP.rsinn·3 fi fi3 1 Last RP.vised 10/17/2019 3·13·33 PM
Container Type: Preservative· -Analysis Metbod·
Glass 1 L Amber AA+ EDTA+ Kdihydrogen citrate
525.3 - UCMR List Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 1 L Amber
Field Results
Analyte
AA+ EDTA + Kdihydrogen citrate
Total Chlorine Residual (10260 - Cl by Chemkey)
Glass 1 L Amber
Field Results
Analyte
AA+ EDTA + Kdihydrogen citrate
Tota l Chlorine Residu al (10260 - C l by Chemkey)
Result
3.98
Result
3 .98
Result
3.98
Glass 1 L Amber Trizma + AA+ EDTA + 530 • UCMR Sem,volatiles
Field Results
Analyte
dUrea Subcontracted
To tal Chlorine Resid ua l ( 10260 - Cl by Chemkey)
R esult
3.98
Analytes~: -----
Units
mg/L
Units
mg/L
Units
mg/L
Units
m g/L
Page 4 of 6
Page 11 of 28
Public Utilities
Subcontracted Vendor: Eurofins Eaton Analytical Profile II
Sample Information Sample ID: Customer: PWS#
20010094-01-6 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
Site:
lPWTP-002
Collection Dale/Time: Sam11.le Type:
Start: 2/13/2020 10:51 :00 AM Drinking Water
Ena: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-0 1-7 Northwest Hillsborough CWS 6290388
Address. 1731 6 N Dale Mabry Hwy
lP'NTP• 002
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51:00 AM (Grab)
Collector: McClory, Alexandra Tille: Environmental Specialist I
20010094-01 -8 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2/13/2020 10·51 -00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01-0 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2/13/2020 10:51:00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 02:10 PM
R1mort VP.rsinn".l 6 63 1 Lr1st RevisP.rl 10/17/2019 ::i-B·33 PM
Container Type:
Glass 1 l Amber
Field Results
Analyte
Preservative·
Trizma +AA+ EDTA + dUrea
Total Chlorine Residual (10260 - Cl by Chemkey)
Glass 1 l Amber
Field Results
Analyte
Trizma +AA+ EDTA + dUrea
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3.98
Result
3.98
Glass 125 ml Amber Sulfite + Bisulfale 541 - UCMR Alcohols Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - Cl by Chemkey)
Glass 125 ml Amber
Field Results
Analyte
Sulfite + Bisulfate
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3.98
Result
3.98
Analytes:
Units
mg/L
Units
mg/L
Units
mg/L
Units
mg/L
Page 5 of 6
Page 12 of 28
RclinQu1shed By: Notes:
4',,.. '-1.S Relinquished By: Oatetrime
Relinquished By: Date/Time
Report Generated: 02/13/2020 02:10 PM Page 6 of 6
Rennrt Versinn:3.6.fB .1 L;ist Reviserl 10/17/20Hl 3:13·33 PM
Eurofins Eaton AnalyticalRun Log
Run ID: 271752 Method: 200.8
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4572216 DS 02/24/2020 13:03RW
QCS 4572217 DS 02/24/2020 13:07RW
LDB 4570836 DS 02/24/2020 13:11RW
DFBL 4570839 DS 02/24/2020 13:15RW
CCM 4572218 DS 02/24/2020 13:59RW
FS 4565778 LPWTP-002 DS 02/24/2020 14:50DW
CCH 4572220 DS 02/24/2020 14:54RW
0.00
Page 1 of 2 EEA Run ID 271752 / EEA Report # 478601
Page 13 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
Germanium 200.8 0.300CCL 0.310999 ug/L 1.0 4572216--- ------50 - 1501040.3 02/24/2020 10:20 02/24/2020 13:03False
IS-Indium 200.8 N/ACCL 0.9819 N/A 1.0 4572216--- ------60 - 125981.0 02/24/2020 10:20 02/24/2020 13:03False
Manganese 200.8 0.400CCL 0.308999 ug/L 1.0 4572216--- ------50 - 1501030.3 02/24/2020 10:20 02/24/2020 13:03False
IS-Scandium 200.8 N/ACCL 0.9854 N/A 1.0 4572216--- ------60 - 125991.0 02/24/2020 10:20 02/24/2020 13:03False
IS-Yttrium 200.8 N/ACCL 0.9814 N/A 1.0 4572216--- ------60 - 125981.0 02/24/2020 10:20 02/24/2020 13:03True
Germanium 200.8 0.300QCS 48.255 ug/L 1.0 4572217--- ------90 - 1109750.0 02/24/2020 10:20 02/24/2020 13:07True
IS-Indium 200.8 N/AQCS 0.9798 N/A 1.0 4572217--- ------60 - 125981.0 02/24/2020 10:20 02/24/2020 13:07True
Manganese 200.8 0.400QCS 49.45 ug/L 1.0 4572217--- ------90 - 1109950.0 02/24/2020 10:20 02/24/2020 13:07True
IS-Scandium 200.8 N/AQCS 0.9815 N/A 1.0 4572217--- ------60 - 125981.0 02/24/2020 10:20 02/24/2020 13:07True
IS-Yttrium 200.8 N/AQCS 0.9788 N/A 1.0 4572217--- ------60 - 125981.0 02/24/2020 10:20 02/24/2020 13:07False
Germanium 200.8 0.300LDB 0.008999 ug/L 1.0 4570836--- ------------ < 02/21/2020 10:20 02/24/2020 13:11False
IS-Indium 200.8 N/ALDB 0.9584 N/A 1.0 4570836--- ------60 - 125961.0 02/21/2020 10:20 02/24/2020 13:11False
Manganese 200.8 0.400LDB 0.02 ug/L 1.0 4570836--- ------------ < 02/21/2020 10:20 02/24/2020 13:11False
IS-Scandium 200.8 N/ALDB 0.9735 N/A 1.0 4570836--- ------60 - 125971.0 02/21/2020 10:20 02/24/2020 13:11False
IS-Yttrium 200.8 N/ALDB 0.9636 N/A 1.0 4570836--- ------60 - 125961.0 02/21/2020 10:20 02/24/2020 13:11True
Germanium 200.8 0.300DFBL 0.308999 ug/L 1.0 4570839--- ------50 - 1501030.3 02/21/2020 10:20 02/24/2020 13:15True
IS-Indium 200.8 N/ADFBL 0.9549 N/A 1.0 4570839--- ------60 - 125951.0 02/21/2020 10:20 02/24/2020 13:15True
Manganese 200.8 0.400DFBL 0.318 ug/L 1.0 4570839--- ------50 - 1501060.3 02/21/2020 10:20 02/24/2020 13:15True
IS-Scandium 200.8 N/ADFBL 0.9684 N/A 1.0 4570839--- ------60 - 125971.0 02/21/2020 10:20 02/24/2020 13:15True
IS-Yttrium 200.8 N/ADFBL 0.9569 N/A 1.0 4570839--- ------60 - 125961.0 02/21/2020 10:20 02/24/2020 13:15False
Germanium 200.8 0.300CCM 48.793999 ug/L 1.0 4572218--- ------85 - 1159850.0 02/24/2020 10:20 02/24/2020 13:59False
IS-Indium 200.8 N/ACCM 0.9279 N/A 1.0 4572218--- ------60 - 125931.0 02/24/2020 10:20 02/24/2020 13:59False
Manganese 200.8 0.400CCM 48.444 ug/L 1.0 4572218--- ------85 - 1159750.0 02/24/2020 10:20 02/24/2020 13:59False
IS-Scandium 200.8 N/ACCM 0.9536 N/A 1.0 4572218--- ------60 - 125951.0 02/24/2020 10:20 02/24/2020 13:59False
IS-Yttrium 200.8 N/ACCM 0.9310 N/A 1.0 4572218--- ------60 - 125931.0 02/24/2020 10:20 02/24/2020 13:59True
Germanium 200.8 0.300FS 0.300 ug/L 1.0 4565778LPWTP-002 ------------ < 02/21/2020 10:20 02/24/2020 14:50True
IS-Indium 200.8 N/AFS 0.9097 N/A 1.0 4565778LPWTP-002 ------60 - 125911.0 02/21/2020 10:20 02/24/2020 14:50True
Manganese 200.8 0.400FS 2.48 ug/L 1.0 4565778LPWTP-002 ------------ 02/21/2020 10:20 02/24/2020 14:50True
IS-Scandium 200.8 N/AFS 0.9120 N/A 1.0 4565778LPWTP-002 ------60 - 125911.0 02/21/2020 10:20 02/24/2020 14:50True
IS-Yttrium 200.8 N/AFS 0.8990 N/A 1.0 4565778LPWTP-002 ------60 - 125901.0 02/21/2020 10:20 02/24/2020 14:50False
Germanium 200.8 0.300CCH 183.015999 ug/L 1.0 4572220--- ------85 - 11592200 02/24/2020 10:20 02/24/2020 14:54False
IS-Indium 200.8 N/ACCH 0.9228 N/A 1.0 4572220--- ------60 - 125921.0 02/24/2020 10:20 02/24/2020 14:54False
Manganese 200.8 0.400CCH 182.61 ug/L 1.0 4572220--- ------85 - 11591200 02/24/2020 10:20 02/24/2020 14:54False
IS-Scandium 200.8 N/ACCH 0.9226 N/A 1.0 4572220--- ------60 - 125921.0 02/24/2020 10:20 02/24/2020 14:54False
IS-Yttrium 200.8 N/ACCH 0.9196 N/A 1.0 4572220--- ------60 - 125921.0 02/24/2020 10:20 02/24/2020 14:54
Page 2 of 2 EEA Run ID 271752 / EEA Report # 478601
Page 14 of 28
c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:====ll=====ll=======ll=====l:==:::::::1===11======1:====11===11====11====11=====1:=====ll===:::::::1=====: c=J
Eurofins Eaton AnalyticalRun Log
Run ID: 271960 Method: 525.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4573619 DN 5253-DN-020320.mth02/27/2020 09:07RW
LRB 4573622 DN 5253-DN-020320.mth02/27/2020 10:20RW
FBL 4573625 DN 5253-DN-020320.mth02/27/2020 11:34RW
FS 4565779 LPWTP-002 DN 5253-DN-020320.mth02/27/2020 14:39DW
CCM 4573620 DN 5253-DN-020320.mth02/27/2020 18:56RW
0.00
Page 1 of 4 EEA Run ID 271960 / EEA Report # 478601
Page 15 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
IS-Acenaphthene-d10 525.3 N/ACCL 106085 ug/L 1.0 4573619--- ------50 - 15099107371 02/26/2020 08:30 02/27/2020 09:07False
IS-Chrysene-d12 525.3 N/ACCL 186261 ug/L 1.0 4573619--- ------50 - 150102183460 02/26/2020 08:30 02/27/2020 09:07False
IS-Phenanthrene-d10 525.3 N/ACCL 179226 ug/L 1.0 4573619--- ------50 - 15098183211 02/26/2020 08:30 02/27/2020 09:07False
SS-Benzo(a)pyrene-d12 525.3 N/ACCL 1.0330 ug/L 1.0 4573619--- ------70 - 1301031.0 02/26/2020 08:30 02/27/2020 09:07False
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ACCL 1.1210 ug/L 1.0 4573619--- ------70 - 1301121.0 02/26/2020 08:30 02/27/2020 09:07False
SS-Triphenylphosphate 525.3 N/ACCL 1.0650 ug/L 1.0 4573619--- ------70 - 1301061.0 02/26/2020 08:30 02/27/2020 09:07False
Chlorpyrifos 525.3 0.0300CCL 0.03 ug/L 1.0 4573619--- ------50 - 1501000.03 02/26/2020 08:30 02/27/2020 09:07False
Dimethipin 525.3 0.200CCL 0.237 ug/L 1.0 4573619--- ------50 - 1501180.2 02/26/2020 08:30 02/27/2020 09:07False
Ethoprop 525.3 0.0300CCL 0.034 ug/L 1.0 4573619--- ------50 - 1501130.03 02/26/2020 08:30 02/27/2020 09:07False
alpha-Hexachlorocyclohexane 525.3 0.0100CCL 0.009 ug/L 1.0 4573619--- ------50 - 150900.01 02/26/2020 08:30 02/27/2020 09:07False
Oxyfluorfen 525.3 0.0500CCL 0.056 ug/L 1.0 4573619--- ------50 - 1501120.05 02/26/2020 08:30 02/27/2020 09:07False
cis-Permethrin 525.3 0.0109CCL 0.012 ug/L 1.0 4573619--- ------50 - 1501220.00984 02/26/2020 08:30 02/27/2020 09:07False
trans-Permethrin 525.3 0.0290CCL 0.033 ug/L 1.0 4573619--- ------50 - 1501100.03004 02/26/2020 08:30 02/27/2020 09:07False
Profenofos 525.3 0.300CCL 0.35 ug/L 1.0 4573619--- ------50 - 1501170.3 02/26/2020 08:30 02/27/2020 09:07False
Tebuconazole 525.3 0.200CCL 0.201 ug/L 1.0 4573619--- ------50 - 1501000.2 02/26/2020 08:30 02/27/2020 09:07False
Tribufos 525.3 0.0700CCL 0.075 ug/L 1.0 4573619--- ------50 - 1501070.07 02/26/2020 08:30 02/27/2020 09:07True
IS-Acenaphthene-d10 525.3 N/ALRB 96141 ug/L 0.97 4573622--- ------50 - 15090107371 02/26/2020 08:30 02/27/2020 10:20True
IS-Chrysene-d12 525.3 N/ALRB 161086 ug/L 0.97 4573622--- ------50 - 15088183460 02/26/2020 08:30 02/27/2020 10:20True
IS-Phenanthrene-d10 525.3 N/ALRB 159195 ug/L 0.97 4573622--- ------50 - 15087183211 02/26/2020 08:30 02/27/2020 10:20True
SS-Benzo(a)pyrene-d12 525.3 N/ALRB 0.8610 ug/L 0.97 4573622--- ------70 - 130891.0 02/26/2020 08:30 02/27/2020 10:20True
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ALRB 0.9720 ug/L 0.97 4573622--- ------70 - 1301001.0 02/26/2020 08:30 02/27/2020 10:20True
SS-Triphenylphosphate 525.3 N/ALRB 1.0150 ug/L 0.97 4573622--- ------70 - 1301051.0 02/26/2020 08:30 02/27/2020 10:20True
Chlorpyrifos 525.3 0.0300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Dimethipin 525.3 0.200LRB 0.03 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Ethoprop 525.3 0.0300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
alpha-Hexachlorocyclohexane 525.3 0.0100LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Oxyfluorfen 525.3 0.0500LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
cis-Permethrin 525.3 0.0109LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
trans-Permethrin 525.3 0.0290LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Profenofos 525.3 0.300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Tebuconazole 525.3 0.200LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
Tribufos 525.3 0.0700LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
IS-Acenaphthene-d10 525.3 N/AFBL 94681 ug/L 1.0 4573625--- ------50 - 15088107371 02/26/2020 08:30 02/27/2020 11:34False
IS-Chrysene-d12 525.3 N/AFBL 155630 ug/L 1.0 4573625--- ------50 - 15085183460 02/26/2020 08:30 02/27/2020 11:34False
IS-Phenanthrene-d10 525.3 N/AFBL 152564 ug/L 1.0 4573625--- ------50 - 15083183211 02/26/2020 08:30 02/27/2020 11:34False
SS-Benzo(a)pyrene-d12 525.3 N/AFBL 0.8860 ug/L 1.0 4573625--- ------70 - 130891.0 02/26/2020 08:30 02/27/2020 11:34False
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/AFBL 1.0070 ug/L 1.0 4573625--- ------70 - 1301011.0 02/26/2020 08:30 02/27/2020 11:34False
SS-Triphenylphosphate 525.3 N/AFBL 1.0710 ug/L 1.0 4573625--- ------70 - 1301071.0 02/26/2020 08:30 02/27/2020 11:34False
Chlorpyrifos 525.3 0.0300FBL 0.036 ug/L 1.0 4573625--- ------50 - 1501200.03 02/26/2020 08:30 02/27/2020 11:34False
Dimethipin 525.3 0.200FBL 0.232 ug/L 1.0 4573625--- ------50 - 1501160.2 02/26/2020 08:30 02/27/2020 11:34
Page 2 of 4 EEA Run ID 271960 / EEA Report # 478601
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c=J===========;l;::::== c=)l=========H=== c=)l=========U=== c=J;:::::=::::========;:=== c=Jl==========.ll=== c=Jl==========.ll=== c=J;:::::=::::========;:=== c=J===========;l;::::== c=Jl==========.ll=== c=J;:::::=::::========;:=== c=J;:::::=::::========;:=== c=Jl==========.ll=== c=Jl==========.ll====ll=====ll=======ll=====l:====ll====ll======ll====ll===ll====ll====ll=====l:=====ll=====ll======I c=J
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
False
Ethoprop 525.3 0.0300FBL 0.03 ug/L 1.0 4573625--- ------50 - 1501000.03 02/26/2020 08:30 02/27/2020 11:34False
alpha-Hexachlorocyclohexane 525.3 0.0100FBL 0.009 ug/L 1.0 4573625--- ------50 - 150900.01 02/26/2020 08:30 02/27/2020 11:34False
Oxyfluorfen 525.3 0.0500FBL 0.053 ug/L 1.0 4573625--- ------50 - 1501060.05 02/26/2020 08:30 02/27/2020 11:34False
cis-Permethrin 525.3 0.0109FBL 0.01 ug/L 1.0 4573625--- ------50 - 1501020.00984 02/26/2020 08:30 02/27/2020 11:34False
trans-Permethrin 525.3 0.0290FBL 0.029 ug/L 1.0 4573625--- ------50 - 150970.03004 02/26/2020 08:30 02/27/2020 11:34False
Profenofos 525.3 0.300FBL 0.34 ug/L 1.0 4573625--- ------50 - 1501130.3 02/26/2020 08:30 02/27/2020 11:34False
Tebuconazole 525.3 0.200FBL 0.194 ug/L 1.0 4573625--- ------50 - 150970.2 02/26/2020 08:30 02/27/2020 11:34False
Tribufos 525.3 0.0700FBL 0.075 ug/L 1.0 4573625--- ------50 - 1501070.07 02/26/2020 08:30 02/27/2020 11:34True
IS-Acenaphthene-d10 525.3 N/AFS 97790 ug/L 0.99 4565779LPWTP-002 ------50 - 15091107371 02/26/2020 08:30 02/27/2020 14:39True
IS-Chrysene-d12 525.3 N/AFS 175006 ug/L 0.99 4565779LPWTP-002 ------50 - 15095183460 02/26/2020 08:30 02/27/2020 14:39True
IS-Phenanthrene-d10 525.3 N/AFS 167719 ug/L 0.99 4565779LPWTP-002 ------50 - 15092183211 02/26/2020 08:30 02/27/2020 14:39True
SS-Benzo(a)pyrene-d12 525.3 N/AFS 0.9200 ug/L 0.99 4565779LPWTP-002 ------70 - 130931.0 02/26/2020 08:30 02/27/2020 14:39True
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/AFS 0.9760 ug/L 0.99 4565779LPWTP-002 ------70 - 130991.0 02/26/2020 08:30 02/27/2020 14:39True
SS-Triphenylphosphate 525.3 N/AFS 0.9720 ug/L 0.99 4565779LPWTP-002 ------70 - 130981.0 02/26/2020 08:30 02/27/2020 14:39True
Chlorpyrifos 525.3 0.0300FS 0.0300 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Dimethipin 525.3 0.200FS 0.200 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Ethoprop 525.3 0.0300FS 0.0300 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
alpha-Hexachlorocyclohexane 525.3 0.0100FS 0.0100 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Oxyfluorfen 525.3 0.0500FS 0.0500 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
cis-Permethrin 525.3 0.0109FS 0.0109 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
trans-Permethrin 525.3 0.0290FS 0.0290 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Permethrin, cis & trans 525.3 0.0400FS 0.0400 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Profenofos 525.3 0.300FS 0.300 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Tebuconazole 525.3 0.200FS 0.200 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39True
Tribufos 525.3 0.0700FS 0.0700 ug/L 0.99 4565779LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 14:39False
IS-Acenaphthene-d10 525.3 N/ACCM 94812 ug/L 1.0 4573620--- ------50 - 15088107371 02/26/2020 08:30 02/27/2020 18:56False
IS-Chrysene-d12 525.3 N/ACCM 156811 ug/L 1.0 4573620--- ------50 - 15085183460 02/26/2020 08:30 02/27/2020 18:56False
IS-Phenanthrene-d10 525.3 N/ACCM 152706 ug/L 1.0 4573620--- ------50 - 15083183211 02/26/2020 08:30 02/27/2020 18:56False
SS-Benzo(a)pyrene-d12 525.3 N/ACCM 1.0250 ug/L 1.0 4573620--- ------70 - 1301021.0 02/26/2020 08:30 02/27/2020 18:56False
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ACCM 1.0680 ug/L 1.0 4573620--- ------70 - 1301071.0 02/26/2020 08:30 02/27/2020 18:56False
SS-Triphenylphosphate 525.3 N/ACCM 1.1240 ug/L 1.0 4573620--- ------70 - 1301121.0 02/26/2020 08:30 02/27/2020 18:56False
Chlorpyrifos 525.3 0.0300CCM 0.339 ug/L 1.0 4573620--- ------70 - 1301130.3 02/26/2020 08:30 02/27/2020 18:56False
Dimethipin 525.3 0.200CCM 2.3 ug/L 1.0 4573620--- ------70 - 1301152.0 02/26/2020 08:30 02/27/2020 18:56False
Ethoprop 525.3 0.0300CCM 0.325 ug/L 1.0 4573620--- ------70 - 1301080.3 02/26/2020 08:30 02/27/2020 18:56False
alpha-Hexachlorocyclohexane 525.3 0.0100CCM 0.113 ug/L 1.0 4573620--- ------70 - 1301130.1 02/26/2020 08:30 02/27/2020 18:56False
Oxyfluorfen 525.3 0.0500CCM 0.509 ug/L 1.0 4573620--- ------70 - 1301020.5 02/26/2020 08:30 02/27/2020 18:56False
cis-Permethrin 525.3 0.0109CCM 0.109 ug/L 1.0 4573620--- ------70 - 1301110.0984 02/26/2020 08:30 02/27/2020 18:56False
trans-Permethrin 525.3 0.0290CCM 0.309 ug/L 1.0 4573620--- ------70 - 1301030.3004 02/26/2020 08:30 02/27/2020 18:56False
Profenofos 525.3 0.300CCM 3.374 ug/L 1.0 4573620--- ------70 - 1301123.0 02/26/2020 08:30 02/27/2020 18:56False
Tebuconazole 525.3 0.200CCM 2.318 ug/L 1.0 4573620--- ------70 - 1301162.0 02/26/2020 08:30 02/27/2020 18:56False
Tribufos 525.3 0.0700CCM 0.774 ug/L 1.0 4573620--- ------70 - 1301110.7 02/26/2020 08:30 02/27/2020 18:56
Page 3 of 4 EEA Run ID 271960 / EEA Report # 478601
Page 17 of 28
g~1 :::::::::::::::::::::::::::;::~::::::::,i~~:::::::::::::::i,:::::::::::::::i~i====:::::::::::::::::::::~1~
c=Jl==========ll======ll===;lF====l;::::====1;::::=====::l======l::==:;l======:ii======ll=====ll==
c=J==========:===== c=J;::::======::;ll==== c=J;::::======::;ll==== c=J==========:===== c=J;::::======::;'ll==== c=J;::::======::;ll==== c=J;::::======::;ll==== c=J;::::======::;'ll==== c=J;::::======::;ll==== c=J;::::======::;ll==== c=J==========:===== c=J;::::======::;'ll==== c=J;::::======::;ll==== c=J;::::======::;ll==== c=J;::::======::;'ll==== c=Jl==========ll======ll===IF===::;l;::::====1;::::=====::l======l:O==::l======lii======ll=====ll=====l:O=::l=======ll=====II=====: c=J
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
Page 4 of 4 EEA Run ID 271960 / EEA Report # 478601
Page 18 of 28
□1 11 [J=====I =====:::::111= 11 11:JCJDD□□C 11 11 11 :J
Eurofins Eaton AnalyticalRun Log
Run ID: 271873 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4574396 FV M 530 UCMR4 1203201902/26/2020 18:41RW
LRB 4574394 FV M 530 UCMR4 1203201902/26/2020 19:10RW
FBL 4574395 FV M 530 UCMR4 1203201902/26/2020 20:06RW
CCM 4574397 FV M 530 UCMR4 1203201902/26/2020 22:00RW
0.00
Page 1 of 2 EEA Run ID 271873 / EEA Report # 478601
Page 19 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
IS-Acenaphthene-d10 530 N/ACCL 445219 ug/L 1.0 4574396--- ------50 - 15094471807 02/26/2020 08:30 02/26/2020 18:41False
IS-Phenanthrene-d10 530 N/ACCL 846726 ug/L 1.0 4574396--- ------50 - 15097873243 02/26/2020 08:30 02/26/2020 18:41False
SS-Quinoline-d7 530 N/ACCL 0.4941 ug/L 1.0 4574396--- ------70 - 130990.5 02/26/2020 08:30 02/26/2020 18:41False
SS-o-Toluidine-d9 530 N/ACCL 0.6392 ug/L 1.0 4574396--- ------50 - 1301280.5 02/26/2020 08:30 02/26/2020 18:41False
Butylated hydroxyanisole 530 0.0300CCL 0.0286 ug/L 1.0 4574396--- ------50 - 150950.029999 02/26/2020 08:30 02/26/2020 18:41False
Quinoline 530 0.0200CCL 0.0214 ug/L 1.0 4574396--- ------50 - 1501070.019999 02/26/2020 08:30 02/26/2020 18:41False
o-Toluidine 530 0.00700CCL 0.0079 ug/L 1.0 4574396--- ------50 - 1501130.007 02/26/2020 08:30 02/26/2020 18:41True
IS-Acenaphthene-d10 530 N/ALRB 449635 ug/L 0.96 4574394--- ------50 - 15095471807 02/26/2020 08:30 02/26/2020 19:10True
IS-Phenanthrene-d10 530 N/ALRB 853895 ug/L 0.96 4574394--- ------50 - 15098873243 02/26/2020 08:30 02/26/2020 19:10True
SS-Quinoline-d7 530 N/ALRB 0.4228 ug/L 0.96 4574394--- ------70 - 130880.5 02/26/2020 08:30 02/26/2020 19:10True
SS-o-Toluidine-d9 530 N/ALRB 0.5057 ug/L 0.96 4574394--- ------50 - 1301050.5 02/26/2020 08:30 02/26/2020 19:10True
Butylated hydroxyanisole 530 0.0300LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10True
Quinoline 530 0.0200LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10True
o-Toluidine 530 0.00700LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10False
IS-Acenaphthene-d10 530 N/AFBL 458912 ug/L 1.0 4574395--- ------50 - 15097471807 02/26/2020 08:30 02/26/2020 20:06False
IS-Phenanthrene-d10 530 N/AFBL 874738 ug/L 1.0 4574395--- ------50 - 150100873243 02/26/2020 08:30 02/26/2020 20:06False
SS-Quinoline-d7 530 N/AFBL 0.4186 ug/L 1.0 4574395--- ------70 - 130840.5 02/26/2020 08:30 02/26/2020 20:06False
SS-o-Toluidine-d9 530 N/AFBL 0.5182 ug/L 1.0 4574395--- ------50 - 1301040.5 02/26/2020 08:30 02/26/2020 20:06False
Butylated hydroxyanisole 530 0.0300FBL 0.0219 ug/L 1.0 4574395--- ------50 - 150730.029999 02/26/2020 08:30 02/26/2020 20:06False
Quinoline 530 0.0200FBL 0.0176 ug/L 1.0 4574395--- ------50 - 150880.019999 02/26/2020 08:30 02/26/2020 20:06False
o-Toluidine 530 0.00700FBL 0.0072 ug/L 1.0 4574395--- ------50 - 1501030.007 02/26/2020 08:30 02/26/2020 20:06True
IS-Acenaphthene-d10 530 N/ACCM 476562 ug/L 1.0 4574397--- ------50 - 150101471807 02/26/2020 08:30 02/26/2020 22:00True
IS-Phenanthrene-d10 530 N/ACCM 867096 ug/L 1.0 4574397--- ------50 - 15099873243 02/26/2020 08:30 02/26/2020 22:00True
SS-Quinoline-d7 530 N/ACCM 0.5288 ug/L 1.0 4574397--- ------70 - 1301060.5 02/26/2020 08:30 02/26/2020 22:00True
SS-o-Toluidine-d9 530 N/ACCM 0.5881 ug/L 1.0 4574397--- ------50 - 1301180.5 02/26/2020 08:30 02/26/2020 22:00True
Butylated hydroxyanisole 530 0.0300CCM 0.3144 ug/L 1.0 4574397--- ------70 - 1301050.299999 02/26/2020 08:30 02/26/2020 22:00True
Quinoline 530 0.0200CCM 0.2107 ug/L 1.0 4574397--- ------70 - 1301050.199999 02/26/2020 08:30 02/26/2020 22:00True
o-Toluidine 530 0.00700CCM 0.0589 ug/L 1.0 4574397--- ------70 - 130840.07 02/26/2020 08:30 02/26/2020 22:00
Page 2 of 2 EEA Run ID 271873 / EEA Report # 478601
Page 20 of 28
c=J===========;l;::::== c=)l=========U=== c=JI=======::::::;:=== c=Jl========::::::;:=== c=].___ ____ ___,._ _ ___,.______., ___ _.,..___.,..__ _ __.._____.,______.,_____....____.,....____.,____, .. ___.,___ _ _..___ _ ___, .... ____.
Eurofins Eaton AnalyticalRun Log
Run ID: 271924 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4573518 FV M 530 UCMR4 1203201902/27/2020 00:23RW
LRB 4573516 FV M 530 UCMR4 1203201902/27/2020 01:20RW
FBL 4573517 FV M 530 UCMR4 1203201902/27/2020 02:16RW
FS 4565780 LPWTP-002 FV M 530 UCMR4 1203201902/27/2020 08:28DW
CCM 4573519 FV M 530 UCMR4 1203201902/27/2020 08:57RW
0.00
Page 1 of 2 EEA Run ID 271924 / EEA Report # 478601
Page 21 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Acenaphthene-d10 530 N/ACCL 449021 ug/L 1.0 4573518--- ------50 - 15095471807 02/26/2020 08:30 02/27/2020 00:23True
IS-Phenanthrene-d10 530 N/ACCL 868175 ug/L 1.0 4573518--- ------50 - 15099873243 02/26/2020 08:30 02/27/2020 00:23True
SS-Quinoline-d7 530 N/ACCL 0.5019 ug/L 1.0 4573518--- ------70 - 1301000.5 02/26/2020 08:30 02/27/2020 00:23True
SS-o-Toluidine-d9 530 N/ACCL 0.6249 ug/L 1.0 4573518--- ------50 - 1301250.5 02/26/2020 08:30 02/27/2020 00:23True
Butylated hydroxyanisole 530 0.0300CCL 0.0279 ug/L 1.0 4573518--- ------50 - 150930.029999 02/26/2020 08:30 02/27/2020 00:23True
Quinoline 530 0.0200CCL 0.0208 ug/L 1.0 4573518--- ------50 - 1501040.019999 02/26/2020 08:30 02/27/2020 00:23True
o-Toluidine 530 0.00700CCL 0.0075 ug/L 1.0 4573518--- ------50 - 1501070.007 02/26/2020 08:30 02/27/2020 00:23False
IS-Acenaphthene-d10 530 N/ALRB 464556 ug/L 0.96 4573516--- ------50 - 15098471807 02/26/2020 08:30 02/27/2020 01:20False
IS-Phenanthrene-d10 530 N/ALRB 885937 ug/L 0.96 4573516--- ------50 - 150101873243 02/26/2020 08:30 02/27/2020 01:20False
SS-Quinoline-d7 530 N/ALRB 0.4249 ug/L 0.96 4573516--- ------70 - 130890.5 02/26/2020 08:30 02/27/2020 01:20False
SS-o-Toluidine-d9 530 N/ALRB 0.4845 ug/L 0.96 4573516--- ------50 - 1301010.5 02/26/2020 08:30 02/27/2020 01:20False
Butylated hydroxyanisole 530 0.0300LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20False
Quinoline 530 0.0200LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20False
o-Toluidine 530 0.00700LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20True
IS-Acenaphthene-d10 530 N/AFBL 477977 ug/L 1.0 4573517--- ------50 - 150101471807 02/26/2020 08:30 02/27/2020 02:16True
IS-Phenanthrene-d10 530 N/AFBL 914561 ug/L 1.0 4573517--- ------50 - 150105873243 02/26/2020 08:30 02/27/2020 02:16True
SS-Quinoline-d7 530 N/AFBL 0.4146 ug/L 1.0 4573517--- ------70 - 130830.5 02/26/2020 08:30 02/27/2020 02:16True
SS-o-Toluidine-d9 530 N/AFBL 0.4865 ug/L 1.0 4573517--- ------50 - 130970.5 02/26/2020 08:30 02/27/2020 02:16True
Butylated hydroxyanisole 530 0.0300FBL 0.0209 ug/L 1.0 4573517--- ------50 - 150700.029999 02/26/2020 08:30 02/27/2020 02:16True
Quinoline 530 0.0200FBL 0.017 ug/L 1.0 4573517--- ------50 - 150850.019999 02/26/2020 08:30 02/27/2020 02:16True
o-Toluidine 530 0.00700FBL 0.0067 ug/L 1.0 4573517--- ------50 - 150960.007 02/26/2020 08:30 02/27/2020 02:16False
IS-Acenaphthene-d10 530 N/AFS 450775 ug/L 0.98 4565780LPWTP-002 ------50 - 15096471807 02/26/2020 08:30 02/27/2020 08:28False
IS-Phenanthrene-d10 530 N/AFS 771659 ug/L 0.98 4565780LPWTP-002 ------50 - 15088873243 02/26/2020 08:30 02/27/2020 08:28False
SS-Quinoline-d7 530 N/AFS 0.4501 ug/L 0.98 4565780LPWTP-002 ------70 - 130920.5 02/26/2020 08:30 02/27/2020 08:28False
SS-o-Toluidine-d9 530 N/AFS 0.4483 ug/L 0.98 4565780LPWTP-002 ------50 - 130910.5 02/26/2020 08:30 02/27/2020 08:28False
Butylated hydroxyanisole 530 0.0300FS 0.0300 ug/L 0.98 4565780LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 08:28False
Quinoline 530 0.0200FS 0.0200 ug/L 0.98 4565780LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 08:28False
o-Toluidine 530 0.00700FS 0.00700 ug/L 0.98 4565780LPWTP-002 ------------ < 02/26/2020 08:30 02/27/2020 08:28True
IS-Acenaphthene-d10 530 N/ACCM 459525 ug/L 1.0 4573519--- ------50 - 15097471807 02/26/2020 08:30 02/27/2020 08:57True
IS-Phenanthrene-d10 530 N/ACCM 809605 ug/L 1.0 4573519--- ------50 - 15093873243 02/26/2020 08:30 02/27/2020 08:57True
SS-Quinoline-d7 530 N/ACCM 0.5361 ug/L 1.0 4573519--- ------70 - 1301070.5 02/26/2020 08:30 02/27/2020 08:57True
SS-o-Toluidine-d9 530 N/ACCM 0.5695 ug/L 1.0 4573519--- ------50 - 1301140.5 02/26/2020 08:30 02/27/2020 08:57True
Butylated hydroxyanisole 530 0.0300CCM 0.3314 ug/L 1.0 4573519--- ------70 - 1301100.299999 02/26/2020 08:30 02/27/2020 08:57True
Quinoline 530 0.0200CCM 0.2136 ug/L 1.0 4573519--- ------70 - 1301070.199999 02/26/2020 08:30 02/27/2020 08:57True
o-Toluidine 530 0.00700CCM 0.0571 ug/L 1.0 4573519--- ------70 - 130820.07 02/26/2020 08:30 02/27/2020 08:57
Page 2 of 2 EEA Run ID 271924 / EEA Report # 478601
Page 22 of 28
c=J:=======:::;:==== c=J:=======:::;:==== c=J:=======:::;l==== c=)l==========ll======ll===Cl=====:::;1=====1:======1:1======4:,==::1======11F===::l=====::l=====4:0=::l=======ll=====II=====: c=J
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Eurofins Eaton AnalyticalRun Log
Run ID: 272157 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4571409 FN M 541 UCMR4 0302202003/03/2020 23:01OS
LRB 4571405 FN M 541 UCMR4 0302202003/04/2020 00:13RW
FBL 4571408 FN M 541 UCMR4 0302202003/04/2020 01:26RW
CCM 4571411 FN M 541 UCMR4 0302202003/04/2020 10:01OS
CCH 4571413 FN M 541 UCMR4 0302202003/04/2020 18:02OS
0.00
Page 1 of 2 EEA Run ID 272157 / EEA Report # 478601
Page 23 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Chlorobenzene-d5 541 N/ACCL 137738 ug/L 1.0 4571409--- ------50 - 15091150782 02/23/2020 07:00 03/03/2020 23:01True
SS-1-Butanol-d10 541 N/ACCL 10.2300 ug/L 1.0 4571409--- ------70 - 13010210.0 02/23/2020 07:00 03/03/2020 23:01True
1-Butanol 541 2.00CCL 1.955 ug/L 1.0 4571409--- ------50 - 150982.0 02/23/2020 07:00 03/03/2020 23:01True
2-Methoxyethanol 541 0.400CCL 0.48 ug/L 1.0 4571409--- ------50 - 1501200.4 02/23/2020 07:00 03/03/2020 23:01True
2-Propen-1-ol 541 0.500CCL 0.504 ug/L 1.0 4571409--- ------50 - 1501010.5 02/23/2020 07:00 03/03/2020 23:01False
IS-Chlorobenzene-d5 541 N/ALRB 134942 ug/L 1.0 4571405--- ------50 - 15089150782 02/23/2020 07:00 03/04/2020 00:13False
SS-1-Butanol-d10 541 N/ALRB 9.7100 ug/L 1.0 4571405--- ------70 - 1309710.0 02/23/2020 07:00 03/04/2020 00:13False
1-Butanol 541 2.00LRB 0.0 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13False
2-Methoxyethanol 541 0.400LRB 0.002 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13False
2-Propen-1-ol 541 0.500LRB 0.039 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13True
IS-Chlorobenzene-d5 541 N/AFBL 148042 ug/L 1.0 4571408--- ------50 - 15098150782 02/23/2020 07:00 03/04/2020 01:26True
SS-1-Butanol-d10 541 N/AFBL 9.7900 ug/L 1.0 4571408--- ------70 - 1309810.0 02/23/2020 07:00 03/04/2020 01:26True
1-Butanol 541 2.00FBL 2.204 ug/L 1.0 4571408--- ------50 - 1501102.0 02/23/2020 07:00 03/04/2020 01:26True
2-Methoxyethanol 541 0.400FBL 0.355 ug/L 1.0 4571408--- ------50 - 150890.4 02/23/2020 07:00 03/04/2020 01:26True
2-Propen-1-ol 541 0.500FBL 0.523 ug/L 1.0 4571408--- ------50 - 1501050.5 02/23/2020 07:00 03/04/2020 01:26False
IS-Chlorobenzene-d5 541 N/ACCM 166811 ug/L 1.0 4571411--- ------50 - 150111150782 02/23/2020 07:00 03/04/2020 10:01False
SS-1-Butanol-d10 541 N/ACCM 10.4200 ug/L 1.0 4571411--- ------70 - 13010410.0 02/23/2020 07:00 03/04/2020 10:01False
1-Butanol 541 2.00CCM 21.232 ug/L 1.0 4571411--- ------70 - 13010620.0 02/23/2020 07:00 03/04/2020 10:01False
2-Methoxyethanol 541 0.400CCM 4.065 ug/L 1.0 4571411--- ------70 - 1301024.0 02/23/2020 07:00 03/04/2020 10:01False
2-Propen-1-ol 541 0.500CCM 5.121 ug/L 1.0 4571411--- ------70 - 1301025.0 02/23/2020 07:00 03/04/2020 10:01True
IS-Chlorobenzene-d5 541 N/ACCH 170049 ug/L 1.0 4571413--- ------50 - 150113150782 02/23/2020 07:00 03/04/2020 18:02True
SS-1-Butanol-d10 541 N/ACCH 10.0800 ug/L 1.0 4571413--- ------70 - 13010110.0 02/23/2020 07:00 03/04/2020 18:02True
1-Butanol 541 2.00CCH 98.509 ug/L 1.0 4571413--- ------70 - 13099100 02/23/2020 07:00 03/04/2020 18:02True
2-Methoxyethanol 541 0.400CCH 19.116 ug/L 1.0 4571413--- ------70 - 1309620.0 02/23/2020 07:00 03/04/2020 18:02True
2-Propen-1-ol 541 0.500CCH 24.309 ug/L 1.0 4571413--- ------70 - 1309725.0 02/23/2020 07:00 03/04/2020 18:02
Page 2 of 2 EEA Run ID 272157 / EEA Report # 478601
Page 24 of 28
c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:=== c=):=======:::::;l====ll=====ll=====H====ll==::::::;1====11=====1:===0===ll====tl====ll====l~==:::::;1:===::::::;1===::::::; c=J
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Eurofins Eaton AnalyticalRun Log
Run ID: 272272 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4580546 FN M 541 UCMR4 0302202003/06/2020 15:54RW
LRB 4580542 FN M 541 UCMR4 0302202003/06/2020 17:11RW
FBL 4580544 FN M 541 UCMR4 0302202003/06/2020 18:31RW
FS 4565781 LPWTP-002 FN M 541 UCMR4 0302202003/06/2020 23:40DW
CCM 4580548 FN M 541 UCMR4 0302202003/07/2020 03:33RW
0.00
Page 1 of 2 EEA Run ID 272272 / EEA Report # 478601
Page 25 of 28
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Chlorobenzene-d5 541 N/ACCL 154614 ug/L 1.0 4580546--- ------50 - 150103150782 03/06/2020 07:00 03/06/2020 15:54True
SS-1-Butanol-d10 541 N/ACCL 10.6600 ug/L 1.0 4580546--- ------70 - 13010710.0 03/06/2020 07:00 03/06/2020 15:54True
1-Butanol 541 2.00CCL 2.003 ug/L 1.0 4580546--- ------50 - 1501002.0 03/06/2020 07:00 03/06/2020 15:54True
2-Methoxyethanol 541 0.400CCL 0.469 ug/L 1.0 4580546--- ------50 - 1501170.4 03/06/2020 07:00 03/06/2020 15:54True
2-Propen-1-ol 541 0.500CCL 0.525 ug/L 1.0 4580546--- ------50 - 1501050.5 03/06/2020 07:00 03/06/2020 15:54False
IS-Chlorobenzene-d5 541 N/ALRB 161905 ug/L 1.0 4580542--- ------50 - 150107150782 03/06/2020 07:00 03/06/2020 17:11False
SS-1-Butanol-d10 541 N/ALRB 7.7900 ug/L 1.0 4580542--- ------70 - 1307810.0 03/06/2020 07:00 03/06/2020 17:11False
1-Butanol 541 2.00LRB 0.0 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11False
2-Methoxyethanol 541 0.400LRB 0.019 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11False
2-Propen-1-ol 541 0.500LRB 0.012 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11True
IS-Chlorobenzene-d5 541 N/AFBL 162741 ug/L 1.0 4580544--- ------50 - 150108150782 03/06/2020 07:00 03/06/2020 18:31True
SS-1-Butanol-d10 541 N/AFBL 9.7900 ug/L 1.0 4580544--- ------70 - 1309810.0 03/06/2020 07:00 03/06/2020 18:31True
1-Butanol 541 2.00FBL 1.791 ug/L 1.0 4580544--- ------50 - 150902.0 03/06/2020 07:00 03/06/2020 18:31True
2-Methoxyethanol 541 0.400FBL 0.367 ug/L 1.0 4580544--- ------50 - 150920.4 03/06/2020 07:00 03/06/2020 18:31True
2-Propen-1-ol 541 0.500FBL 0.437 ug/L 1.0 4580544--- ------50 - 150870.5 03/06/2020 07:00 03/06/2020 18:31False
IS-Chlorobenzene-d5 541 N/AFS 160422 ug/L 1.0 4565781LPWTP-002 ------50 - 150106150782 03/06/2020 07:00 03/06/2020 23:40False
SS-1-Butanol-d10 541 N/AFS 10.1800 ug/L 1.0 4565781LPWTP-002 ------70 - 13010210.0 03/06/2020 07:00 03/06/2020 23:40False
1-Butanol 541 2.00FS 2.00 ug/L 1.0 4565781LPWTP-002 ------------ < 03/06/2020 07:00 03/06/2020 23:40False
2-Methoxyethanol 541 0.400FS 0.400 ug/L 1.0 4565781LPWTP-002 ------------ < 03/06/2020 07:00 03/06/2020 23:40False
2-Propen-1-ol 541 0.500FS 0.500 ug/L 1.0 4565781LPWTP-002 ------------ < 03/06/2020 07:00 03/06/2020 23:40True
IS-Chlorobenzene-d5 541 N/ACCM 152112 ug/L 1.0 4580548--- ------50 - 150101150782 03/06/2020 07:00 03/07/2020 03:33True
SS-1-Butanol-d10 541 N/ACCM 10.1400 ug/L 1.0 4580548--- ------70 - 13010110.0 03/06/2020 07:00 03/07/2020 03:33True
1-Butanol 541 2.00CCM 20.846 ug/L 1.0 4580548--- ------70 - 13010420.0 03/06/2020 07:00 03/07/2020 03:33True
2-Methoxyethanol 541 0.400CCM 3.845 ug/L 1.0 4580548--- ------70 - 130964.0 03/06/2020 07:00 03/07/2020 03:33True
2-Propen-1-ol 541 0.500CCM 5.033 ug/L 1.0 4580548--- ------70 - 1301015.0 03/06/2020 07:00 03/07/2020 03:33
Page 2 of 2 EEA Run ID 272272 / EEA Report # 478601
Page 26 of 28
c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:=== c=):=======:::::;l====ll=====ll=====H====ll==::::::;1====11=====1:===0===ll====tl====ll====l~==:::::;1:===::::::;1===::::::; c=J
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Sample Type Key
Type (Abbr.) Sample Type Type (Abbr.) Sample Type
CCH Continuing Calibration High
CCL Continuing Calibration Low
CCM Continuing Calibration Mid
DFBL DFB Low
FS Field Sample
FBL Fortified Blank Low
LDB Laboratory Digestion Blank
LRB Laboratory Reagent Blank
QCS Quality Control Sample
1.00
Page 27 of 28
END OF REPORT
Page 28 of 28
LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
Page 1 of 29
=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
STATE CERTIFICATION LIST
State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035
Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005
Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973
Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207
Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837
Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035
EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
Page 2 of 29
~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
478603
FL6290388
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00002
0388002
SE4
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4565794 NWPWF-002 200.8 02/13/20 11:47 Client 02/17/20 08:45
4565795 NWPWF-002 525.3 02/13/20 11:47 Client 02/17/20 08:45
4565796 NWPWF-002 530 02/13/20 11:47 Client 02/17/20 08:45
4565797 NWPWF-002 541 02/13/20 11:47 Client 02/17/20 08:45
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
478603
Authorized Signature Title Date
03/10/2020
Page 1 of 2
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=:~ eurofins I Eaton Analytical
§
Analytical Services Manager
Client Name: Report #: 478603Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL62903880388002
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
1053 Germanium 200.8 0.300 < 0.300 ug/L 02/21/20 10:30 02/24/20 15:50 4565794
1032 Manganese 200.8 0.400 2.14 ug/L 02/21/20 10:30 02/24/20 15:50 4565794
2115 alpha-Hexachlorocyclohexane 525.3 0.0100 < 0.0100 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2057 Chlorpyrifos 525.3 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2116 Dimethipin 525.3 0.200 < 0.200 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
7570 Ethoprop 525.3 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2117 Oxyfluorfen 525.3 0.0500 < 0.0500 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2118 Profenofos 525.3 0.300 < 0.300 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2119 Tebuconazole 525.3 0.200 < 0.200 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2114 Permethrin, cis & trans 525.3 0.0400 < 0.0400 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2120 Tribufos 525.3 0.0700 < 0.0700 ug/L 02/26/20 08:30 02/27/20 15:15 4565795
2433 Butylated hydroxyanisole 530 0.0300 < 0.0300 ug/L 02/26/20 08:30 02/27/20 10:51 4565796
2434 o-Toluidine 530 0.00700 < 0.00700 ug/L 02/26/20 08:30 02/27/20 10:51 4565796
3435 Quinoline 530 0.0200 < 0.0200 ug/L 02/26/20 08:30 02/27/20 10:51 4565796
2084 1-Butanol 541 2.00 < 2.00 ug/L 03/06/20 07:00 03/07/20 00:18 4565797
2431 2-Methoxyethanol 541 0.400 < 0.400 ug/L 03/06/20 07:00 03/07/20 00:18 4565797
2432 2-Propen-1-ol 541 0.500 < 0.500 ug/L 03/06/20 07:00 03/07/20 00:18 4565797
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
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Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
Page 1 of 1
Page 5 of 29
Page 6 of 29
•·:: eu rofi ns -:. 11 O S. Hill Street ..3&92%3 South Bend, IN 46617 Order#
Eaton Analytical T : 1.800.332.4345
~7?~03 F: 1.574.233.8207 Batch #
- 11!1'111! ~rQflns!.!S ,!lmZEal!ln UCMR 4 CHAIN OF CUSTODY RECORD Page_ of __
Shaded area for EEA use onlv
CLIENT NAME: SAMPLER (Print nam e) - *PWS ID# STATE of sample origin Check if this is a resample D Check if requires upload to EPA database D
Example: IN1234567 we must have info for fields indicated w it h .. for
PO#: If samples are not shipped the same day as collection then the temperature upload
Bill To: the samples were held at must be recorded here(0 C}:
*Sampling Event Preservative - - Li:11 1 Additional:, SEA 1 SEA2
U)
"' Sampling Event # ___ SEA3 SEA4; SEHi SEH2 SEH3 Checks w z SEH4 ($00 c1rterla below) < ....
*FAC ILITY ID: (p e r EPA *S a m p l ing z COLLECTION *SAMPLE P OINT ID: (p e r EPA Tem perature Upon 0
LAB Number Requirement)-5 P oin t Type Test Name UCMR4- pH Residual u Requirement)-20 characters max Lab Rece ipt ·c Chlorine u.. acccp- 0
DATE TIME AM PM characters max Code table?~ IP/Al .. lf S°Lo'\·1q4 oi,/,_1 11:47 Nt..uPWF-0fJ2 o.~ " NA 1 1 200.8 Metals
2 ._7 -,q5
525.3 1-J ✓ A- 3
3 7q1d 530 J.0 ✓ A- 3
◄L--- 1q1 \I/ -.1..-- I) f) ✓ .j4 3 4 ' / 541
5
6
7
8
9
10
11
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME LAB COMMENTS
AM PM AMI PM RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
AM PM AMI PM CONDITIONS UPON RECEIPi{r lced: Wcl"\Blue Check if received on day of collection: D RELINQUISHED BY:(Signature) DATE TIME RECEIVED FOR LABORATORY BY: DATE TIME Samples received within 48 hours,n-,:011ection must be received at a temperature of,; 1 o•c.
/J,j nJ ,l}Jt:l/ 1:/J. l~~J) {)xu( Samples received past 48 hours of collection are only valid if received at,; 6' C, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AMI PM a ll methods EXCEPT 200.8 and 300.0.
KEY UCMR4 acceptanc</criteria(!f:~ Ri(/:eiving Checks: *Sampling Point Type Code: "See Metal Samples Preservation 200.8 pH< 2 1545 pH s 4 541 pH 5 3 SR = source water taken from plant intake; untreated water entering the water treatment plant Log 525.3 pH s 4 544 pH 6.5-7.5 EP = entry point to the distribution system
P = Present 530 pH about 7 (6-8) TOC pH< 2 OS = d istribution system sample A= Absent Must be absent of residual chlorine(free): 525.3, 530, 541, 544, 545, 546, and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO-F0912 Issue; 8.0 Effective Date;
Samplo analysis will be provided according to the standard EEA/Water Services Tenms, which are available upon request. Any other tenms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 7 of 29
Subcontracted Chain of Custody ,--------------------------------------, ,------------=----------------------------,
Hillsboro u g_h __ -----rr71=:c-c-,En...,.v;r,;iro=n"--m"'en-rtar.-l -r,La=b=or.,...at--=ory
County I
da 9456 E Columbus Dr lampa, FL ""3'.3o1S-
Certification Number: E44104 Public Utilities
Phone No. (813) 272-5977 x 43635
II I I I II 111111111111111 Work Order: 20010094
Scheduled Sample NW - UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical I I,--.
Customer: Northwest Hillsborough CWS
Project: NW - UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sample ID: Customer: PWS# Site: Collection Date{Ti!Jle·
20010094-02-10 Northwest Hillsborough CWS 6290388
Address:
NWPWF-002
Start:
End:
Collector:
12950 Fawnridge Blvd
McClory, Alexandra Title: Environmental Specialist I
20010094-02-11 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnndge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
2113/2020 11:47:00 AM
2/13/2020 11 :47:00 AM
2113/2020 11:47:00 AM
2113/2020 11"47:00 AM
Sample Ty11e·
Drinking Water
(Grab)
Drinking Water
(Grab)
20010094-02-2 Northwest Hillsborough CWS 6290388 NWPWF_ 002
Start: 2113/2020 11 :47.00 AM Drinking Water
Address: 12950 Fawnridge Blvd
McClory, Alexandra
End: 2113/2020 11 :47:00 AM (Grab)
Collector: Title: Environmental Specialist I
20010094-02-3 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Gene rated: 02/1312020 01 :42 PM
RP.oort Version·3 fi 63 1 1 rist RevisP.rl 10/17/201!13·13:33 PM
2113/2020 11 :47:00 AM
2113/2020 11 :47:00 AM
Drinking Water
(Grab)
Cantaioeuype:
Glass 125 ml Amber
Field Resu lts
Analyte
Prese[Yative· An.ilysis Methorl·
Sulfite + Bisulfate
T otal Chlorine Residual (10260 - Cl by Chemkey)
Result
4.52
Plastic 250 ml None 200.8 - UCMR Metals Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
4 .52
Glass 1 l Amber AA+ EDTA + Kdihydrogen citrate
525.3 - UCMR Lisi Subcontracted
Field Results
Analyte
T otal Chlorine Residual (10260 - Cl by Chemkey)
Glass 1 l Amber
Field Results
Analyte
AA• EDTA + Kdihydrogen citrate
T otal Chlorine Residual (10260 - C l by Chemkey)
Result
4.52
Result
4.52
Analy1es:
Units
mg/L
Units
mg/L
Units
mg/L
Units
mg/L
Page 1 of 6
Page 8 of 29
Subcontracted Chain of Custody ~----------- ---------------------------~ ,------------=-----------------------------, Environmental Laboratory II I I I II 111111111111111
-----
Customer: Northwest Hillsborough CWS
eroject:. --lll.W.....UCMR4-SV · rough TT"T1-- i1-,1-=,....,...~cr-:- ---""-----9456-E-eolumboS"flrramp:r,Ft"336'tS- -
Y Certification Nu mber: E44104
Work Order: 20010094 Contact: Stanley, John (Chief Environmental
Scientist) Public Utilities
Phone No . (813) 272-5977 x 43635
Sample ID: Customer: PWS# Site: Collection Date/Time:
20010094-02-4 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: Mcclory, Alexandra Title: Environmental Specialist I
20010094-02-5 Northwest Hillsborough CWS 6290388
Address 12950 Fawnridge Blvd
NWPWF-002
Slart:
End:
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-6 Northwest Hillsborough CWS 6290388
Address. 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
Collector: McClory, Alexandra Tille: Environmental Specialist I
20010094-02-7 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF• 002
Start:
End:
Collector· McClory, Alexandra Title: Environmental Specialist I
Report Generated : 02/ 13/2020 01 :4 2 PM
Reoort Version·3 6 63 1 L;ist Rev iserl 10/ 17/2019 3 :13·33 PM
2/13/2020 11 :47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00 AM
2/13/2020 11:47:00AM
2/13/2020 t1 :47:00AM
Scheduled Sample NW • UCMR4 SV Set Name: Phone: (813) 272-5977 x 43635
Subcontracted Vendor: Eurofins Eaton A nalytical Profile#
Sample Information Sample Tu~ Container Type: -Pre&er:valiv6'--- Analysis Mi.,e"'th"'o<+d-. ----~
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Waler
(Grab)
Drinking Waler
(Grab)
Glass 1 L Amber
Field Results
A nalyte
AA+EDTA+Kdihydrogen citrate
Total Chlorine Residual (10260 - C l by Chemkey)
Result
4 .52
Glass 1 L Amber Trizma +AA+ EDTA + 530 - UCMR Sem,volatiles
Field Results
Analyte
dUrea Subcontracted
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 1 L Amber
Field Results
Analyte
Trizma +AA + EDTA + dUrea
T o tal C hlorine Residual (1 0260 - C l by Chemkey)
Glass 1 L Amber
Field Results
A nalyte
Trizma +AA + EDTA + dUrea
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
4 .52
Result
4 .52
Result
4.52
U nits
m g/L
U nits
m g /L
U nits
m g/L
U nits
m g/L
Page 2 of 6
Page 9 of 29
Subcontracted Chain of Custody ,----- - - -------- - - - ---------------- - ----, ,------------=- - - ---- - - - ------ ------- - --
Hillsborough C. t - ~ - ----..,_94....,56 .E.Columbus..Oi:..Iai:i:ipa,-R-33
\.Oun y l:maa Certification Number : E44 104
Env ironmental Laboratory
Public Util ities Phone No. (8 13 ) 272-5977 x 43635
111111111111 1 111111 111 -wofk Ura er: 20010094
Scheduled Sample NW - UCMR4 SV Set Name:
Subcontracted Vendor: Eurofin s Ea ton Analytical
Customer: Northwest Hillsborough CWS
Project: NW • UCMR4=.SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile #
Sample Information Sample ID: Customer: PWS# Site: Collection Dateffime: Sample Type:
20010094-02-8 Northwest Hills orough CWS 6290388 NWPWF Start: 2/13/2020 11:47:00 AM Drinking Water
Address: 12950 Fawnridge Blvd 002 End: 2/13/2020 11:47:00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-02-9 Northwest Hillsborough CWS 6290388
Address: 12950 Fawnridge Blvd
NWPWF-002
Start:
End:
2/13/2020 11 :47:00 AM
2/13/2020 11:47:00 AM
Drinking Water
(Grab)
Collector: McClory. Alexandra Title: Environmental Specialist I
20010094-01-1 0 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01 -11 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2/13/2020 10:51:00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/13/2020 01 :42 PM
RP.nnrt VP.rsinn·3 6 63 1 L;ist Reviseri 10/17/2019 3:13·33 PM
Container Type: Preservative· AnalysisJJethod:
Glass 125 ml Amber Sulfite + Bisulfate 541 • UCMR Alcohols Subcontracted
Field Results
A nalyte
Total C hlorine Residual (10260 - C l by C hemkey)
Glass 125 ml Amber
Field Re sults
A nalyte
Sulfite + Bisulfate
Total Chlo r ine Residual (1 0260 - C l by Chemkey)
Glass 125 ml Amber
Field Results
Ana lyte
Sulfite + Bisulfate
Total Chlorine Residua l (10260 - C l by Chemkey)
R esult
4 .52
Resu lt
4.52
Result
3.9 8
Plastic 250 ml None 200.8 - UCMR Metals Subcontracted
Fie ld Results
A nalyte
Total Ch lo rine Residual ( 10260 - Cl by C hemkey)
Result
3.98
Analytes.
Units
mg/L
Units
mg/L
Units
m g/L
Units
m g/L
Page 3 of 6
Page 10 of 29
Subcontracted Chain of Custody ~--------------------------------------~ ,-----------...::C------------------------- ----
Hillsborough County V :
Public Utilities
Environmental Laboratory
Certification Number: E44104
Phone No. (813) 272-5977 x 43635
1111111111111 111111 111 -1-- ""'vw,vorl<Order: 20010094
Scheduled Sample NW - UCMR4 SV Set Name:
Subcontracted Vendor: Eu:_ofins Eaton Analytical
Customer: Northwest Hillsborough CWS
Project: NW - UCMl!!.Rn!t4-:;;SuYL-------- - 1.-c-
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sample ID: Customer: PWS# Site: Collection DaterTime: Sample Type:
20010094-01-2 Northwest Hillsborough CWS 6290388 LPWTP- Start: 2/13/2020 10:51 :00 AM Drinking Water
Address: 17316 N Dale Mabry Hwy 002 End: 2/13/2020 10:51:00 AM (Grab)
Collector: McClory, Alexandra Tille: Environmental Specialist I
20010094-01-3 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP-002
Start: 2/13/2020 10:51 :00 AM Dnnking Water
End: 2/13/2020 10:51:00 AM (Grab)
Collector: McClory, Alexandra nue: Environmental Specialist I
20010094-01-4 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP-002
Start: 2/13/2020 10:51 :00 AM Drinking Water
End: 2/13/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Tille: Environmental Specialist I
20010094-01-5 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP-002
Start: 2/13/2020 10:51:00 AM Drinking Waler
End: 2/13/2020 10:51:00 AM (Grab)
Collector: McClory. Alexandra TIiie: Environmental Specialist I
Report Generated: 02/13/2020 01 :42 PM
RP.nor! VP.rsion·3 .6 n3 1 L;ist RP.visP.ci 10/17/2019 3·13:33 PM
Container Type: Preservative: Analysis.Method·
Glass 1 L Amber AA+ EDTA + Kdihydrogen citrate
525.3 - UCMR List Subcontracted
Field Results
Analyte
Total Chlorine Residual (10260 - C l b y Chemkey)
Glass 1 L Amber
Field Results
Analyte
AA+EDTA+Kdihydrogen citrate
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 1 L Amber
Field R esults
Analyte
AA + EDTA + Kdihydrogen citrate
T otal Chlorine Residual (10260 - Cl by Chemkey)
Result
3.98
Result
3.98
Result
3.98
Glass 1 L Amber Trizma + AA+ EDTA + 530 - UCMR Semivolatiles
Field Results
Analyte
dUrea Subcontracted
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3.98
Analytes:
Units
mg/L
Units
mg/L
Units
mg/L
Units
mg/L
Page 4 of 6
Page 11 of 29
Subcontracted Chain of Custody
~ II I I I II 111111111111111 Customer: Northwest Hillsborough CWS
Hillsborough Environmental Laboratory Project: NW - UCMR4-SV
9456-E-Columbus-lJi:--+am~a,Fk--336-1: ~ rder: 20010094 County 1orida Contact: Stanley, John (Chief Environmental Certification Number: E44104 Scheduled Sample Scientist)
Public Utilities NW - UCMR4 SV
Phone No. (813) 272-5977 x 43635 Set Name: Phone: (813) 272-5977 X 43635
Subcontracted Vendor: Eurofins Ealon Analytical Profile II 1 11"
Sample Information Sample ID: Customer: PWS#
20010094-01-6 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
Site:
l PWTP-002
Collection Dale/Time: Sample Type:
Start: 211312020 10:51:00 AM Drinking Water
End: 2113/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01-7 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
LPWTP-002
Start: 2113/2020 10:51 :00 AM Dnnking Waler
End: 211312020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01 -8 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2113/2020 10:51 :00 AM Drinking Waler
End: 2113/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
20010094-01-9 Northwest Hillsborough CWS 6290388
Address: 17316 N Dale Mabry Hwy
lPWTP-002
Start: 2113/2020 10:51 :00 AM Drinking Water
End: 2113/2020 10:51 :00 AM (Grab)
Collector: McClory, Alexandra Title: Environmental Specialist I
Report Generated: 02/ 13/2020 01 :42 PM
Rirnort Vr.rsinn ·3 fl 63 1 Lr1st Rr.viserl 10/17/2019 3 :13·33 PM
Container Type:
Glass 1 l Amber
Field Results
Analyte
Preservative:
Trizma +AA+ EDTA + dUrea
Analysi.s Method·
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 1 l Amber
Field Results
Analyte
Trizma + AA+ EDTA + dUrea
Total Chlorine Residual (10260 - C l by Chemkey)
Result
3.98
Result
3 .98
Glass 125 ml Amber Sulfite + Bisulfate 541 - UCMR Alcohols Subcontracted
Field Results
A nalyte
Total Chlorine Residual (10260 - C l by Chemkey)
Glass 125 ml Amber
Field Results
Analyte
Sulfite + Bisulfate
Total Chlorine Residual (10260 - Cl by Chemkey)
Result
3.98
Result
3.98
Analytes:
Units
mg/L
Units
mg/L
Units
m g/L
Units
m g/L
Page 5 of 6
Page 12 of 29
Dalc/Tlme: NOies:
2- 13 z..o 1345 Accepted By: Dote/Time:
RolinquishDCI By: Date/Time:
Report Generated: 02/13/2020 01 :42 PM Page 6 of 6
Renort Version:3.6.63.1 Last Revised 10/17/2019 3:13:33 PM
Eurofins Eaton AnalyticalRun Log
Run ID: 271765 Method: 200.8
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4572396 DS 02/24/2020 15:31RW
QCS 4572398 DS 02/24/2020 15:39RW
LDB 4570848 DS 02/24/2020 15:42RW
DFBL 4570876 DS 02/24/2020 15:46RW
FS 4565794 NWPWF-002 DS 02/24/2020 15:50DW
CCM 4572399 DS 02/24/2020 16:30RW
0.00
Page 1 of 2 EEA Run ID 271765 / EEA Report # 478603
Page 13 of 29
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
Germanium 200.8 0.300CCL 0.298999 ug/L 1.0 4572396--- ------50 - 1501000.3 02/24/2020 11:15 02/24/2020 15:31False
IS-Indium 200.8 N/ACCL 0.9911 N/A 1.0 4572396--- ------60 - 125991.0 02/24/2020 11:15 02/24/2020 15:31False
Manganese 200.8 0.400CCL 0.321 ug/L 1.0 4572396--- ------50 - 1501070.3 02/24/2020 11:15 02/24/2020 15:31False
IS-Scandium 200.8 N/ACCL 0.9814 N/A 1.0 4572396--- ------60 - 125981.0 02/24/2020 11:15 02/24/2020 15:31False
IS-Yttrium 200.8 N/ACCL 0.9914 N/A 1.0 4572396--- ------60 - 125991.0 02/24/2020 11:15 02/24/2020 15:31True
Germanium 200.8 0.300QCS 47.689999 ug/L 1.0 4572398--- ------90 - 1109550.0 02/24/2020 11:15 02/24/2020 15:39True
IS-Indium 200.8 N/AQCS 0.9721 N/A 1.0 4572398--- ------60 - 125971.0 02/24/2020 11:15 02/24/2020 15:39True
Manganese 200.8 0.400QCS 48.572 ug/L 1.0 4572398--- ------90 - 1109750.0 02/24/2020 11:15 02/24/2020 15:39True
IS-Scandium 200.8 N/AQCS 0.9618 N/A 1.0 4572398--- ------60 - 125961.0 02/24/2020 11:15 02/24/2020 15:39True
IS-Yttrium 200.8 N/AQCS 0.9734 N/A 1.0 4572398--- ------60 - 125971.0 02/24/2020 11:15 02/24/2020 15:39False
Germanium 200.8 0.300LDB -0.012001 ug/L 1.0 4570848--- ------------ < 02/21/2020 10:30 02/24/2020 15:42False
IS-Indium 200.8 N/ALDB 0.9813 N/A 1.0 4570848--- ------60 - 125981.0 02/21/2020 10:30 02/24/2020 15:42False
Manganese 200.8 0.400LDB -0.046 ug/L 1.0 4570848--- ------------ < 02/21/2020 10:30 02/24/2020 15:42False
IS-Scandium 200.8 N/ALDB 0.9662 N/A 1.0 4570848--- ------60 - 125971.0 02/21/2020 10:30 02/24/2020 15:42False
IS-Yttrium 200.8 N/ALDB 0.9801 N/A 1.0 4570848--- ------60 - 125981.0 02/21/2020 10:30 02/24/2020 15:42True
Germanium 200.8 0.300DFBL 0.332 ug/L 1.0 4570876--- ------50 - 1501110.3 02/21/2020 10:30 02/24/2020 15:46True
IS-Indium 200.8 N/ADFBL 0.9826 N/A 1.0 4570876--- ------60 - 125981.0 02/21/2020 10:30 02/24/2020 15:46True
Manganese 200.8 0.400DFBL 0.256 ug/L 1.0 4570876--- ------50 - 150850.3 02/21/2020 10:30 02/24/2020 15:46True
IS-Scandium 200.8 N/ADFBL 0.9745 N/A 1.0 4570876--- ------60 - 125971.0 02/21/2020 10:30 02/24/2020 15:46True
IS-Yttrium 200.8 N/ADFBL 0.9840 N/A 1.0 4570876--- ------60 - 125981.0 02/21/2020 10:30 02/24/2020 15:46False
Germanium 200.8 0.300FS 0.300 ug/L 1.0 4565794NWPWF-002 ------------ < 02/21/2020 10:30 02/24/2020 15:50False
IS-Indium 200.8 N/AFS 0.9568 N/A 1.0 4565794NWPWF-002 ------60 - 125961.0 02/21/2020 10:30 02/24/2020 15:50False
Manganese 200.8 0.400FS 2.14 ug/L 1.0 4565794NWPWF-002 ------------ 02/21/2020 10:30 02/24/2020 15:50False
IS-Scandium 200.8 N/AFS 0.9509 N/A 1.0 4565794NWPWF-002 ------60 - 125951.0 02/21/2020 10:30 02/24/2020 15:50False
IS-Yttrium 200.8 N/AFS 0.9506 N/A 1.0 4565794NWPWF-002 ------60 - 125951.0 02/21/2020 10:30 02/24/2020 15:50True
Germanium 200.8 0.300CCM 48.161 ug/L 1.0 4572399--- ------85 - 1159650.0 02/24/2020 11:15 02/24/2020 16:30True
IS-Indium 200.8 N/ACCM 0.9919 N/A 1.0 4572399--- ------60 - 125991.0 02/24/2020 11:15 02/24/2020 16:30True
Manganese 200.8 0.400CCM 47.436999 ug/L 1.0 4572399--- ------85 - 1159550.0 02/24/2020 11:15 02/24/2020 16:30True
IS-Scandium 200.8 N/ACCM 0.9968 N/A 1.0 4572399--- ------60 - 1251001.0 02/24/2020 11:15 02/24/2020 16:30True
IS-Yttrium 200.8 N/ACCM 1.0018 N/A 1.0 4572399--- ------60 - 1251001.0 02/24/2020 11:15 02/24/2020 16:30
Page 2 of 2 EEA Run ID 271765 / EEA Report # 478603
Page 14 of 29
c=J:=======:::;:==== c=J:=======:::;:==== c=J:=======:::;l==== c=J
Eurofins Eaton AnalyticalRun Log
Run ID: 271960 Method: 525.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4573619 DN 5253-DN-020320.mth02/27/2020 09:07RW
LRB 4573622 DN 5253-DN-020320.mth02/27/2020 10:20RW
FBL 4573625 DN 5253-DN-020320.mth02/27/2020 11:34RW
FS 4565795 NWPWF-002 DN 5253-DN-020320.mth02/27/2020 15:15DW
CCM 4573620 DN 5253-DN-020320.mth02/27/2020 18:56RW
0.00
Page 1 of 4 EEA Run ID 271960 / EEA Report # 478603
Page 15 of 29
:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Acenaphthene-d10 525.3 N/ACCL 106085 ug/L 1.0 4573619--- ------50 - 15099107371 02/26/2020 08:30 02/27/2020 09:07True
IS-Chrysene-d12 525.3 N/ACCL 186261 ug/L 1.0 4573619--- ------50 - 150102183460 02/26/2020 08:30 02/27/2020 09:07True
IS-Phenanthrene-d10 525.3 N/ACCL 179226 ug/L 1.0 4573619--- ------50 - 15098183211 02/26/2020 08:30 02/27/2020 09:07True
SS-Benzo(a)pyrene-d12 525.3 N/ACCL 1.0330 ug/L 1.0 4573619--- ------70 - 1301031.0 02/26/2020 08:30 02/27/2020 09:07True
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ACCL 1.1210 ug/L 1.0 4573619--- ------70 - 1301121.0 02/26/2020 08:30 02/27/2020 09:07True
SS-Triphenylphosphate 525.3 N/ACCL 1.0650 ug/L 1.0 4573619--- ------70 - 1301061.0 02/26/2020 08:30 02/27/2020 09:07True
Chlorpyrifos 525.3 0.0300CCL 0.03 ug/L 1.0 4573619--- ------50 - 1501000.03 02/26/2020 08:30 02/27/2020 09:07True
Dimethipin 525.3 0.200CCL 0.237 ug/L 1.0 4573619--- ------50 - 1501180.2 02/26/2020 08:30 02/27/2020 09:07True
Ethoprop 525.3 0.0300CCL 0.034 ug/L 1.0 4573619--- ------50 - 1501130.03 02/26/2020 08:30 02/27/2020 09:07True
alpha-Hexachlorocyclohexane 525.3 0.0100CCL 0.009 ug/L 1.0 4573619--- ------50 - 150900.01 02/26/2020 08:30 02/27/2020 09:07True
Oxyfluorfen 525.3 0.0500CCL 0.056 ug/L 1.0 4573619--- ------50 - 1501120.05 02/26/2020 08:30 02/27/2020 09:07True
cis-Permethrin 525.3 0.0109CCL 0.012 ug/L 1.0 4573619--- ------50 - 1501220.00984 02/26/2020 08:30 02/27/2020 09:07True
trans-Permethrin 525.3 0.0290CCL 0.033 ug/L 1.0 4573619--- ------50 - 1501100.03004 02/26/2020 08:30 02/27/2020 09:07True
Profenofos 525.3 0.300CCL 0.35 ug/L 1.0 4573619--- ------50 - 1501170.3 02/26/2020 08:30 02/27/2020 09:07True
Tebuconazole 525.3 0.200CCL 0.201 ug/L 1.0 4573619--- ------50 - 1501000.2 02/26/2020 08:30 02/27/2020 09:07True
Tribufos 525.3 0.0700CCL 0.075 ug/L 1.0 4573619--- ------50 - 1501070.07 02/26/2020 08:30 02/27/2020 09:07False
IS-Acenaphthene-d10 525.3 N/ALRB 96141 ug/L 0.97 4573622--- ------50 - 15090107371 02/26/2020 08:30 02/27/2020 10:20False
IS-Chrysene-d12 525.3 N/ALRB 161086 ug/L 0.97 4573622--- ------50 - 15088183460 02/26/2020 08:30 02/27/2020 10:20False
IS-Phenanthrene-d10 525.3 N/ALRB 159195 ug/L 0.97 4573622--- ------50 - 15087183211 02/26/2020 08:30 02/27/2020 10:20False
SS-Benzo(a)pyrene-d12 525.3 N/ALRB 0.8610 ug/L 0.97 4573622--- ------70 - 130891.0 02/26/2020 08:30 02/27/2020 10:20False
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ALRB 0.9720 ug/L 0.97 4573622--- ------70 - 1301001.0 02/26/2020 08:30 02/27/2020 10:20False
SS-Triphenylphosphate 525.3 N/ALRB 1.0150 ug/L 0.97 4573622--- ------70 - 1301051.0 02/26/2020 08:30 02/27/2020 10:20False
Chlorpyrifos 525.3 0.0300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Dimethipin 525.3 0.200LRB 0.03 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Ethoprop 525.3 0.0300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
alpha-Hexachlorocyclohexane 525.3 0.0100LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Oxyfluorfen 525.3 0.0500LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
cis-Permethrin 525.3 0.0109LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
trans-Permethrin 525.3 0.0290LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Profenofos 525.3 0.300LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Tebuconazole 525.3 0.200LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20False
Tribufos 525.3 0.0700LRB 0.0 ug/L 0.97 4573622--- ------------ < 02/26/2020 08:30 02/27/2020 10:20True
IS-Acenaphthene-d10 525.3 N/AFBL 94681 ug/L 1.0 4573625--- ------50 - 15088107371 02/26/2020 08:30 02/27/2020 11:34True
IS-Chrysene-d12 525.3 N/AFBL 155630 ug/L 1.0 4573625--- ------50 - 15085183460 02/26/2020 08:30 02/27/2020 11:34True
IS-Phenanthrene-d10 525.3 N/AFBL 152564 ug/L 1.0 4573625--- ------50 - 15083183211 02/26/2020 08:30 02/27/2020 11:34True
SS-Benzo(a)pyrene-d12 525.3 N/AFBL 0.8860 ug/L 1.0 4573625--- ------70 - 130891.0 02/26/2020 08:30 02/27/2020 11:34True
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/AFBL 1.0070 ug/L 1.0 4573625--- ------70 - 1301011.0 02/26/2020 08:30 02/27/2020 11:34True
SS-Triphenylphosphate 525.3 N/AFBL 1.0710 ug/L 1.0 4573625--- ------70 - 1301071.0 02/26/2020 08:30 02/27/2020 11:34True
Chlorpyrifos 525.3 0.0300FBL 0.036 ug/L 1.0 4573625--- ------50 - 1501200.03 02/26/2020 08:30 02/27/2020 11:34True
Dimethipin 525.3 0.200FBL 0.232 ug/L 1.0 4573625--- ------50 - 1501160.2 02/26/2020 08:30 02/27/2020 11:34
Page 2 of 4 EEA Run ID 271960 / EEA Report # 478603
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c=J:=======:::;:==== c=J:=======:::;:==== c=J:=======:::;l==== c=)l==========ll======ll===Cl=====:::;1=====1:======1:1======4:,==::1======11F===::l=====::l=====4:0=::l=======ll=====II=====:
c=Jl==========ll======ll===Cl=====:::;1=====1:======1:1======4::==::1======11F===::l=====::I==
c=J=========::;ll==== c=J:=======:::;l==== c=J:=======:::;:==== c=J=========::;ll==== c=J:=======:::;l==== c=Jl==========ll======ll===Cl=====:::;1=====1:======1:1======4::==::1======11F===::l=====::I==
c=Jl==========ll======ll===Cl=====:::;1=====1:======1:1======4::==::1======11F===::l=====::I==
c=J=========::;ll==== c=J:=======:::;l==== c=J
c=J=========::;ll==== c=J:=======:::;l==== c=Jl==========ll======ll===Cl=====:::;1=====1:======1:1======4::==::1======11F===::l=====::I==
c=Jl==========ll======ll===Cl=====:::;1=====1:======1:1======4::==::1======11F===::l=====::I==
c=J=========::;ll==== c=J:=======:::;l==== c=J ____________ , ___ .. ________________ ,___,,___. .. ___..___ ________ ~
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
True
Ethoprop 525.3 0.0300FBL 0.03 ug/L 1.0 4573625--- ------50 - 1501000.03 02/26/2020 08:30 02/27/2020 11:34True
alpha-Hexachlorocyclohexane 525.3 0.0100FBL 0.009 ug/L 1.0 4573625--- ------50 - 150900.01 02/26/2020 08:30 02/27/2020 11:34True
Oxyfluorfen 525.3 0.0500FBL 0.053 ug/L 1.0 4573625--- ------50 - 1501060.05 02/26/2020 08:30 02/27/2020 11:34True
cis-Permethrin 525.3 0.0109FBL 0.01 ug/L 1.0 4573625--- ------50 - 1501020.00984 02/26/2020 08:30 02/27/2020 11:34True
trans-Permethrin 525.3 0.0290FBL 0.029 ug/L 1.0 4573625--- ------50 - 150970.03004 02/26/2020 08:30 02/27/2020 11:34True
Profenofos 525.3 0.300FBL 0.34 ug/L 1.0 4573625--- ------50 - 1501130.3 02/26/2020 08:30 02/27/2020 11:34True
Tebuconazole 525.3 0.200FBL 0.194 ug/L 1.0 4573625--- ------50 - 150970.2 02/26/2020 08:30 02/27/2020 11:34True
Tribufos 525.3 0.0700FBL 0.075 ug/L 1.0 4573625--- ------50 - 1501070.07 02/26/2020 08:30 02/27/2020 11:34False
IS-Acenaphthene-d10 525.3 N/AFS 97459 ug/L 0.99 4565795NWPWF-002 ------50 - 15091107371 02/26/2020 08:30 02/27/2020 15:15False
IS-Chrysene-d12 525.3 N/AFS 169266 ug/L 0.99 4565795NWPWF-002 ------50 - 15092183460 02/26/2020 08:30 02/27/2020 15:15False
IS-Phenanthrene-d10 525.3 N/AFS 164722 ug/L 0.99 4565795NWPWF-002 ------50 - 15090183211 02/26/2020 08:30 02/27/2020 15:15False
SS-Benzo(a)pyrene-d12 525.3 N/AFS 0.9240 ug/L 0.99 4565795NWPWF-002 ------70 - 130931.0 02/26/2020 08:30 02/27/2020 15:15False
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/AFS 0.9880 ug/L 0.99 4565795NWPWF-002 ------70 - 1301001.0 02/26/2020 08:30 02/27/2020 15:15False
SS-Triphenylphosphate 525.3 N/AFS 1.0370 ug/L 0.99 4565795NWPWF-002 ------70 - 1301051.0 02/26/2020 08:30 02/27/2020 15:15False
Chlorpyrifos 525.3 0.0300FS 0.0300 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Dimethipin 525.3 0.200FS 0.200 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Ethoprop 525.3 0.0300FS 0.0300 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
alpha-Hexachlorocyclohexane 525.3 0.0100FS 0.0100 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Oxyfluorfen 525.3 0.0500FS 0.0500 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
cis-Permethrin 525.3 0.0109FS 0.0109 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
trans-Permethrin 525.3 0.0290FS 0.0290 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Permethrin, cis & trans 525.3 0.0400FS 0.0400 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Profenofos 525.3 0.300FS 0.300 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Tebuconazole 525.3 0.200FS 0.200 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15False
Tribufos 525.3 0.0700FS 0.0700 ug/L 0.99 4565795NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 15:15True
IS-Acenaphthene-d10 525.3 N/ACCM 94812 ug/L 1.0 4573620--- ------50 - 15088107371 02/26/2020 08:30 02/27/2020 18:56True
IS-Chrysene-d12 525.3 N/ACCM 156811 ug/L 1.0 4573620--- ------50 - 15085183460 02/26/2020 08:30 02/27/2020 18:56True
IS-Phenanthrene-d10 525.3 N/ACCM 152706 ug/L 1.0 4573620--- ------50 - 15083183211 02/26/2020 08:30 02/27/2020 18:56True
SS-Benzo(a)pyrene-d12 525.3 N/ACCM 1.0250 ug/L 1.0 4573620--- ------70 - 1301021.0 02/26/2020 08:30 02/27/2020 18:56True
SS-1,3-Dimethyl-2-nitrobenzene 525.3 N/ACCM 1.0680 ug/L 1.0 4573620--- ------70 - 1301071.0 02/26/2020 08:30 02/27/2020 18:56True
SS-Triphenylphosphate 525.3 N/ACCM 1.1240 ug/L 1.0 4573620--- ------70 - 1301121.0 02/26/2020 08:30 02/27/2020 18:56True
Chlorpyrifos 525.3 0.0300CCM 0.339 ug/L 1.0 4573620--- ------70 - 1301130.3 02/26/2020 08:30 02/27/2020 18:56True
Dimethipin 525.3 0.200CCM 2.3 ug/L 1.0 4573620--- ------70 - 1301152.0 02/26/2020 08:30 02/27/2020 18:56True
Ethoprop 525.3 0.0300CCM 0.325 ug/L 1.0 4573620--- ------70 - 1301080.3 02/26/2020 08:30 02/27/2020 18:56True
alpha-Hexachlorocyclohexane 525.3 0.0100CCM 0.113 ug/L 1.0 4573620--- ------70 - 1301130.1 02/26/2020 08:30 02/27/2020 18:56True
Oxyfluorfen 525.3 0.0500CCM 0.509 ug/L 1.0 4573620--- ------70 - 1301020.5 02/26/2020 08:30 02/27/2020 18:56True
cis-Permethrin 525.3 0.0109CCM 0.109 ug/L 1.0 4573620--- ------70 - 1301110.0984 02/26/2020 08:30 02/27/2020 18:56True
trans-Permethrin 525.3 0.0290CCM 0.309 ug/L 1.0 4573620--- ------70 - 1301030.3004 02/26/2020 08:30 02/27/2020 18:56True
Profenofos 525.3 0.300CCM 3.374 ug/L 1.0 4573620--- ------70 - 1301123.0 02/26/2020 08:30 02/27/2020 18:56True
Tebuconazole 525.3 0.200CCM 2.318 ug/L 1.0 4573620--- ------70 - 1301162.0 02/26/2020 08:30 02/27/2020 18:56True
Tribufos 525.3 0.0700CCM 0.774 ug/L 1.0 4573620--- ------70 - 1301110.7 02/26/2020 08:30 02/27/2020 18:56
Page 3 of 4 EEA Run ID 271960 / EEA Report # 478603
Page 17 of 29
c=J=========::;ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J=========::;ll==== c=J::=======::;'ll==== c=Jl==========ll======ll===Cl=====::;ll=====l:======1:1======4:,==::1======111===::1====::1== c=J
c=Jl==========ll======ll==='ill======::1=====1:======1:1======4:,==::1======111===::1====::1==
c=J=========::;ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J=========::;ll==== c=J::=======::;'ll==== c=Jl==========ll======ll===Cl=====::;ll=====l:======1:1======4:,==::1======111===::1====::1==
c=Jl==========ll======ll==='ill=====::;ll=====l:======1:1======4:,==::1======111===::1====::1==
c=J=========::;ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J=========::;ll==== c=J::=======::;'ll==== c=J::=======::;ll==== c=J::=======::;ll==== c=J::=======::;'ll==== c=J __________ .__, ___ .. .__.,..__ _ ___.._____..______.._____....____.,---...,___. .. ___..____ .... .,__ _ ____, .... ____.
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
Page 4 of 4 EEA Run ID 271960 / EEA Report # 478603
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□1 11 [J=====I =====:::::111= 11 11:JCJDD□□C 11 11 11 :J
Eurofins Eaton AnalyticalRun Log
Run ID: 271873 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4574396 FV M 530 UCMR4 1203201902/26/2020 18:41RW
LRB 4574394 FV M 530 UCMR4 1203201902/26/2020 19:10RW
FBL 4574395 FV M 530 UCMR4 1203201902/26/2020 20:06RW
CCM 4574397 FV M 530 UCMR4 1203201902/26/2020 22:00RW
0.00
Page 1 of 2 EEA Run ID 271873 / EEA Report # 478603
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:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Acenaphthene-d10 530 N/ACCL 445219 ug/L 1.0 4574396--- ------50 - 15094471807 02/26/2020 08:30 02/26/2020 18:41True
IS-Phenanthrene-d10 530 N/ACCL 846726 ug/L 1.0 4574396--- ------50 - 15097873243 02/26/2020 08:30 02/26/2020 18:41True
SS-Quinoline-d7 530 N/ACCL 0.4941 ug/L 1.0 4574396--- ------70 - 130990.5 02/26/2020 08:30 02/26/2020 18:41True
SS-o-Toluidine-d9 530 N/ACCL 0.6392 ug/L 1.0 4574396--- ------50 - 1301280.5 02/26/2020 08:30 02/26/2020 18:41True
Butylated hydroxyanisole 530 0.0300CCL 0.0286 ug/L 1.0 4574396--- ------50 - 150950.029999 02/26/2020 08:30 02/26/2020 18:41True
Quinoline 530 0.0200CCL 0.0214 ug/L 1.0 4574396--- ------50 - 1501070.019999 02/26/2020 08:30 02/26/2020 18:41True
o-Toluidine 530 0.00700CCL 0.0079 ug/L 1.0 4574396--- ------50 - 1501130.007 02/26/2020 08:30 02/26/2020 18:41False
IS-Acenaphthene-d10 530 N/ALRB 449635 ug/L 0.96 4574394--- ------50 - 15095471807 02/26/2020 08:30 02/26/2020 19:10False
IS-Phenanthrene-d10 530 N/ALRB 853895 ug/L 0.96 4574394--- ------50 - 15098873243 02/26/2020 08:30 02/26/2020 19:10False
SS-Quinoline-d7 530 N/ALRB 0.4228 ug/L 0.96 4574394--- ------70 - 130880.5 02/26/2020 08:30 02/26/2020 19:10False
SS-o-Toluidine-d9 530 N/ALRB 0.5057 ug/L 0.96 4574394--- ------50 - 1301050.5 02/26/2020 08:30 02/26/2020 19:10False
Butylated hydroxyanisole 530 0.0300LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10False
Quinoline 530 0.0200LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10False
o-Toluidine 530 0.00700LRB 0.0 ug/L 0.96 4574394--- ------------ < 02/26/2020 08:30 02/26/2020 19:10True
IS-Acenaphthene-d10 530 N/AFBL 458912 ug/L 1.0 4574395--- ------50 - 15097471807 02/26/2020 08:30 02/26/2020 20:06True
IS-Phenanthrene-d10 530 N/AFBL 874738 ug/L 1.0 4574395--- ------50 - 150100873243 02/26/2020 08:30 02/26/2020 20:06True
SS-Quinoline-d7 530 N/AFBL 0.4186 ug/L 1.0 4574395--- ------70 - 130840.5 02/26/2020 08:30 02/26/2020 20:06True
SS-o-Toluidine-d9 530 N/AFBL 0.5182 ug/L 1.0 4574395--- ------50 - 1301040.5 02/26/2020 08:30 02/26/2020 20:06True
Butylated hydroxyanisole 530 0.0300FBL 0.0219 ug/L 1.0 4574395--- ------50 - 150730.029999 02/26/2020 08:30 02/26/2020 20:06True
Quinoline 530 0.0200FBL 0.0176 ug/L 1.0 4574395--- ------50 - 150880.019999 02/26/2020 08:30 02/26/2020 20:06True
o-Toluidine 530 0.00700FBL 0.0072 ug/L 1.0 4574395--- ------50 - 1501030.007 02/26/2020 08:30 02/26/2020 20:06False
IS-Acenaphthene-d10 530 N/ACCM 476562 ug/L 1.0 4574397--- ------50 - 150101471807 02/26/2020 08:30 02/26/2020 22:00False
IS-Phenanthrene-d10 530 N/ACCM 867096 ug/L 1.0 4574397--- ------50 - 15099873243 02/26/2020 08:30 02/26/2020 22:00False
SS-Quinoline-d7 530 N/ACCM 0.5288 ug/L 1.0 4574397--- ------70 - 1301060.5 02/26/2020 08:30 02/26/2020 22:00False
SS-o-Toluidine-d9 530 N/ACCM 0.5881 ug/L 1.0 4574397--- ------50 - 1301180.5 02/26/2020 08:30 02/26/2020 22:00False
Butylated hydroxyanisole 530 0.0300CCM 0.3144 ug/L 1.0 4574397--- ------70 - 1301050.299999 02/26/2020 08:30 02/26/2020 22:00False
Quinoline 530 0.0200CCM 0.2107 ug/L 1.0 4574397--- ------70 - 1301050.199999 02/26/2020 08:30 02/26/2020 22:00False
o-Toluidine 530 0.00700CCM 0.0589 ug/L 1.0 4574397--- ------70 - 130840.07 02/26/2020 08:30 02/26/2020 22:00
Page 2 of 2 EEA Run ID 271873 / EEA Report # 478603
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c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:=== c=J:=======:::::;:====ll=====ll=======ll=====l:==:::::::1===11======1:====11===11====11====11=====1:=====ll===:::::::1=====: c=J
c=Jl=========O====ll======ll=======ll====U=====ll====U=======ll===U===ll=====ll==== c=J::==========;::::::== c=J:=======:::::;:=== c=J:=======:::::;:=== c=J::==========;::::::== c=J:=======:::::;:=== c=J
Eurofins Eaton AnalyticalRun Log
Run ID: 271924 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4573518 FV M 530 UCMR4 1203201902/27/2020 00:23RW
LRB 4573516 FV M 530 UCMR4 1203201902/27/2020 01:20RW
FBL 4573517 FV M 530 UCMR4 1203201902/27/2020 02:16RW
CCM 4573519 FV M 530 UCMR4 1203201902/27/2020 08:57RW
FS 4565796 NWPWF-002 FV M 530 UCMR4 1203201902/27/2020 10:51DW
CCH 4573520 FV M 530 UCMR4 1203201902/27/2020 17:01RW
0.00
Page 1 of 3 EEA Run ID 271924 / EEA Report # 478603
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:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
False
IS-Acenaphthene-d10 530 N/ACCL 449021 ug/L 1.0 4573518--- ------50 - 15095471807 02/26/2020 08:30 02/27/2020 00:23False
IS-Phenanthrene-d10 530 N/ACCL 868175 ug/L 1.0 4573518--- ------50 - 15099873243 02/26/2020 08:30 02/27/2020 00:23False
SS-Quinoline-d7 530 N/ACCL 0.5019 ug/L 1.0 4573518--- ------70 - 1301000.5 02/26/2020 08:30 02/27/2020 00:23False
SS-o-Toluidine-d9 530 N/ACCL 0.6249 ug/L 1.0 4573518--- ------50 - 1301250.5 02/26/2020 08:30 02/27/2020 00:23False
Butylated hydroxyanisole 530 0.0300CCL 0.0279 ug/L 1.0 4573518--- ------50 - 150930.029999 02/26/2020 08:30 02/27/2020 00:23False
Quinoline 530 0.0200CCL 0.0208 ug/L 1.0 4573518--- ------50 - 1501040.019999 02/26/2020 08:30 02/27/2020 00:23False
o-Toluidine 530 0.00700CCL 0.0075 ug/L 1.0 4573518--- ------50 - 1501070.007 02/26/2020 08:30 02/27/2020 00:23True
IS-Acenaphthene-d10 530 N/ALRB 464556 ug/L 0.96 4573516--- ------50 - 15098471807 02/26/2020 08:30 02/27/2020 01:20True
IS-Phenanthrene-d10 530 N/ALRB 885937 ug/L 0.96 4573516--- ------50 - 150101873243 02/26/2020 08:30 02/27/2020 01:20True
SS-Quinoline-d7 530 N/ALRB 0.4249 ug/L 0.96 4573516--- ------70 - 130890.5 02/26/2020 08:30 02/27/2020 01:20True
SS-o-Toluidine-d9 530 N/ALRB 0.4845 ug/L 0.96 4573516--- ------50 - 1301010.5 02/26/2020 08:30 02/27/2020 01:20True
Butylated hydroxyanisole 530 0.0300LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20True
Quinoline 530 0.0200LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20True
o-Toluidine 530 0.00700LRB 0.0 ug/L 0.96 4573516--- ------------ < 02/26/2020 08:30 02/27/2020 01:20False
IS-Acenaphthene-d10 530 N/AFBL 477977 ug/L 1.0 4573517--- ------50 - 150101471807 02/26/2020 08:30 02/27/2020 02:16False
IS-Phenanthrene-d10 530 N/AFBL 914561 ug/L 1.0 4573517--- ------50 - 150105873243 02/26/2020 08:30 02/27/2020 02:16False
SS-Quinoline-d7 530 N/AFBL 0.4146 ug/L 1.0 4573517--- ------70 - 130830.5 02/26/2020 08:30 02/27/2020 02:16False
SS-o-Toluidine-d9 530 N/AFBL 0.4865 ug/L 1.0 4573517--- ------50 - 130970.5 02/26/2020 08:30 02/27/2020 02:16False
Butylated hydroxyanisole 530 0.0300FBL 0.0209 ug/L 1.0 4573517--- ------50 - 150700.029999 02/26/2020 08:30 02/27/2020 02:16False
Quinoline 530 0.0200FBL 0.017 ug/L 1.0 4573517--- ------50 - 150850.019999 02/26/2020 08:30 02/27/2020 02:16False
o-Toluidine 530 0.00700FBL 0.0067 ug/L 1.0 4573517--- ------50 - 150960.007 02/26/2020 08:30 02/27/2020 02:16True
IS-Acenaphthene-d10 530 N/ACCM 459525 ug/L 1.0 4573519--- ------50 - 15097471807 02/26/2020 08:30 02/27/2020 08:57True
IS-Phenanthrene-d10 530 N/ACCM 809605 ug/L 1.0 4573519--- ------50 - 15093873243 02/26/2020 08:30 02/27/2020 08:57True
SS-Quinoline-d7 530 N/ACCM 0.5361 ug/L 1.0 4573519--- ------70 - 1301070.5 02/26/2020 08:30 02/27/2020 08:57True
SS-o-Toluidine-d9 530 N/ACCM 0.5695 ug/L 1.0 4573519--- ------50 - 1301140.5 02/26/2020 08:30 02/27/2020 08:57True
Butylated hydroxyanisole 530 0.0300CCM 0.3314 ug/L 1.0 4573519--- ------70 - 1301100.299999 02/26/2020 08:30 02/27/2020 08:57True
Quinoline 530 0.0200CCM 0.2136 ug/L 1.0 4573519--- ------70 - 1301070.199999 02/26/2020 08:30 02/27/2020 08:57True
o-Toluidine 530 0.00700CCM 0.0571 ug/L 1.0 4573519--- ------70 - 130820.07 02/26/2020 08:30 02/27/2020 08:57False
IS-Acenaphthene-d10 530 N/AFS 437809 ug/L 0.98 4565796NWPWF-002 ------50 - 15093471807 02/26/2020 08:30 02/27/2020 10:51False
IS-Phenanthrene-d10 530 N/AFS 748650 ug/L 0.98 4565796NWPWF-002 ------50 - 15086873243 02/26/2020 08:30 02/27/2020 10:51False
SS-Quinoline-d7 530 N/AFS 0.5135 ug/L 0.98 4565796NWPWF-002 ------70 - 1301050.5 02/26/2020 08:30 02/27/2020 10:51False
SS-o-Toluidine-d9 530 N/AFS 0.4847 ug/L 0.98 4565796NWPWF-002 ------50 - 130990.5 02/26/2020 08:30 02/27/2020 10:51False
Butylated hydroxyanisole 530 0.0300FS 0.0300 ug/L 0.98 4565796NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 10:51False
Quinoline 530 0.0200FS 0.0200 ug/L 0.98 4565796NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 10:51False
o-Toluidine 530 0.00700FS 0.00700 ug/L 0.98 4565796NWPWF-002 ------------ < 02/26/2020 08:30 02/27/2020 10:51True
IS-Acenaphthene-d10 530 N/ACCH 448251 ug/L 1.0 4573520--- ------50 - 15095471807 02/26/2020 08:30 02/27/2020 17:01True
IS-Phenanthrene-d10 530 N/ACCH 804819 ug/L 1.0 4573520--- ------50 - 15092873243 02/26/2020 08:30 02/27/2020 17:01True
SS-Quinoline-d7 530 N/ACCH 0.5463 ug/L 1.0 4573520--- ------70 - 1301090.5 02/26/2020 08:30 02/27/2020 17:01True
SS-o-Toluidine-d9 530 N/ACCH 0.5795 ug/L 1.0 4573520--- ------50 - 1301160.5 02/26/2020 08:30 02/27/2020 17:01True
Butylated hydroxyanisole 530 0.0300CCH 1.6269 ug/L 1.0 4573520--- ------70 - 1301081.499999 02/26/2020 08:30 02/27/2020 17:01
Page 2 of 3 EEA Run ID 271924 / EEA Report # 478603
Page 22 of 29
c=J===========;l;::::== c=)l=========U=== c=JI=======::::::;:=== c=Jl========::::::;:===
Rl=======~l===
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c=Jl========::::::;:====ll======l:====::::::::;:===::::::::;i====ll====I:======::====::===::====::=== c=J===========;l;::::== c=JI=======::::::;:=== c=J ____________ , ___ .. ________________ ,___,,___. .. ___..,___ ________ ~
SampleType
EEAID #
AnalyzedExtractedRPDUnitsTargetAmountClient IDMRLMethodAnalyte DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
QC Summary Report (cont.)
True
Quinoline 530 0.0200CCH 1.0794 ug/L 1.0 4573520--- ------70 - 1301080.999999 02/26/2020 08:30 02/27/2020 17:01True
o-Toluidine 530 0.00700CCH 0.3124 ug/L 1.0 4573520--- ------70 - 130890.35 02/26/2020 08:30 02/27/2020 17:01
Page 3 of 3 EEA Run ID 271924 / EEA Report # 478603
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c=J I I I I D ~I
Eurofins Eaton AnalyticalRun Log
Run ID: 272157 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4571409 FN M 541 UCMR4 0302202003/03/2020 23:01OS
LRB 4571405 FN M 541 UCMR4 0302202003/04/2020 00:13RW
FBL 4571408 FN M 541 UCMR4 0302202003/04/2020 01:26RW
CCM 4571411 FN M 541 UCMR4 0302202003/04/2020 10:01OS
CCH 4571413 FN M 541 UCMR4 0302202003/04/2020 18:02OS
0.00
Page 1 of 2 EEA Run ID 272157 / EEA Report # 478603
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:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Chlorobenzene-d5 541 N/ACCL 137738 ug/L 1.0 4571409--- ------50 - 15091150782 02/23/2020 07:00 03/03/2020 23:01True
SS-1-Butanol-d10 541 N/ACCL 10.2300 ug/L 1.0 4571409--- ------70 - 13010210.0 02/23/2020 07:00 03/03/2020 23:01True
1-Butanol 541 2.00CCL 1.955 ug/L 1.0 4571409--- ------50 - 150982.0 02/23/2020 07:00 03/03/2020 23:01True
2-Methoxyethanol 541 0.400CCL 0.48 ug/L 1.0 4571409--- ------50 - 1501200.4 02/23/2020 07:00 03/03/2020 23:01True
2-Propen-1-ol 541 0.500CCL 0.504 ug/L 1.0 4571409--- ------50 - 1501010.5 02/23/2020 07:00 03/03/2020 23:01False
IS-Chlorobenzene-d5 541 N/ALRB 134942 ug/L 1.0 4571405--- ------50 - 15089150782 02/23/2020 07:00 03/04/2020 00:13False
SS-1-Butanol-d10 541 N/ALRB 9.7100 ug/L 1.0 4571405--- ------70 - 1309710.0 02/23/2020 07:00 03/04/2020 00:13False
1-Butanol 541 2.00LRB 0.0 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13False
2-Methoxyethanol 541 0.400LRB 0.002 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13False
2-Propen-1-ol 541 0.500LRB 0.039 ug/L 1.0 4571405--- ------------ < 02/23/2020 07:00 03/04/2020 00:13True
IS-Chlorobenzene-d5 541 N/AFBL 148042 ug/L 1.0 4571408--- ------50 - 15098150782 02/23/2020 07:00 03/04/2020 01:26True
SS-1-Butanol-d10 541 N/AFBL 9.7900 ug/L 1.0 4571408--- ------70 - 1309810.0 02/23/2020 07:00 03/04/2020 01:26True
1-Butanol 541 2.00FBL 2.204 ug/L 1.0 4571408--- ------50 - 1501102.0 02/23/2020 07:00 03/04/2020 01:26True
2-Methoxyethanol 541 0.400FBL 0.355 ug/L 1.0 4571408--- ------50 - 150890.4 02/23/2020 07:00 03/04/2020 01:26True
2-Propen-1-ol 541 0.500FBL 0.523 ug/L 1.0 4571408--- ------50 - 1501050.5 02/23/2020 07:00 03/04/2020 01:26False
IS-Chlorobenzene-d5 541 N/ACCM 166811 ug/L 1.0 4571411--- ------50 - 150111150782 02/23/2020 07:00 03/04/2020 10:01False
SS-1-Butanol-d10 541 N/ACCM 10.4200 ug/L 1.0 4571411--- ------70 - 13010410.0 02/23/2020 07:00 03/04/2020 10:01False
1-Butanol 541 2.00CCM 21.232 ug/L 1.0 4571411--- ------70 - 13010620.0 02/23/2020 07:00 03/04/2020 10:01False
2-Methoxyethanol 541 0.400CCM 4.065 ug/L 1.0 4571411--- ------70 - 1301024.0 02/23/2020 07:00 03/04/2020 10:01False
2-Propen-1-ol 541 0.500CCM 5.121 ug/L 1.0 4571411--- ------70 - 1301025.0 02/23/2020 07:00 03/04/2020 10:01True
IS-Chlorobenzene-d5 541 N/ACCH 170049 ug/L 1.0 4571413--- ------50 - 150113150782 02/23/2020 07:00 03/04/2020 18:02True
SS-1-Butanol-d10 541 N/ACCH 10.0800 ug/L 1.0 4571413--- ------70 - 13010110.0 02/23/2020 07:00 03/04/2020 18:02True
1-Butanol 541 2.00CCH 98.509 ug/L 1.0 4571413--- ------70 - 13099100 02/23/2020 07:00 03/04/2020 18:02True
2-Methoxyethanol 541 0.400CCH 19.116 ug/L 1.0 4571413--- ------70 - 1309620.0 02/23/2020 07:00 03/04/2020 18:02True
2-Propen-1-ol 541 0.500CCH 24.309 ug/L 1.0 4571413--- ------70 - 1309725.0 02/23/2020 07:00 03/04/2020 18:02
Page 2 of 2 EEA Run ID 272157 / EEA Report # 478603
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Eurofins Eaton AnalyticalRun Log
Run ID: 272272 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4580546 FN M 541 UCMR4 0302202003/06/2020 15:54RW
LRB 4580542 FN M 541 UCMR4 0302202003/06/2020 17:11RW
FBL 4580544 FN M 541 UCMR4 0302202003/06/2020 18:31RW
FS 4565797 NWPWF-002 FN M 541 UCMR4 0302202003/07/2020 00:18DW
CCM 4580548 FN M 541 UCMR4 0302202003/07/2020 03:33RW
0.00
Page 1 of 2 EEA Run ID 272272 / EEA Report # 478603
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:::: e LI rofi n s I Eaton Analytical
QC Summary Report
EEAID #
RPDUnitsTargetAmountClient IDMethodAnalyteSampleType
DilFactor
RPDLimit
RecoveryLimits
% Recovery
ResultFlag
MRL Extracted Analyzed
True
IS-Chlorobenzene-d5 541 N/ACCL 154614 ug/L 1.0 4580546--- ------50 - 150103150782 03/06/2020 07:00 03/06/2020 15:54True
SS-1-Butanol-d10 541 N/ACCL 10.6600 ug/L 1.0 4580546--- ------70 - 13010710.0 03/06/2020 07:00 03/06/2020 15:54True
1-Butanol 541 2.00CCL 2.003 ug/L 1.0 4580546--- ------50 - 1501002.0 03/06/2020 07:00 03/06/2020 15:54True
2-Methoxyethanol 541 0.400CCL 0.469 ug/L 1.0 4580546--- ------50 - 1501170.4 03/06/2020 07:00 03/06/2020 15:54True
2-Propen-1-ol 541 0.500CCL 0.525 ug/L 1.0 4580546--- ------50 - 1501050.5 03/06/2020 07:00 03/06/2020 15:54False
IS-Chlorobenzene-d5 541 N/ALRB 161905 ug/L 1.0 4580542--- ------50 - 150107150782 03/06/2020 07:00 03/06/2020 17:11False
SS-1-Butanol-d10 541 N/ALRB 7.7900 ug/L 1.0 4580542--- ------70 - 1307810.0 03/06/2020 07:00 03/06/2020 17:11False
1-Butanol 541 2.00LRB 0.0 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11False
2-Methoxyethanol 541 0.400LRB 0.019 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11False
2-Propen-1-ol 541 0.500LRB 0.012 ug/L 1.0 4580542--- ------------ < 03/06/2020 07:00 03/06/2020 17:11True
IS-Chlorobenzene-d5 541 N/AFBL 162741 ug/L 1.0 4580544--- ------50 - 150108150782 03/06/2020 07:00 03/06/2020 18:31True
SS-1-Butanol-d10 541 N/AFBL 9.7900 ug/L 1.0 4580544--- ------70 - 1309810.0 03/06/2020 07:00 03/06/2020 18:31True
1-Butanol 541 2.00FBL 1.791 ug/L 1.0 4580544--- ------50 - 150902.0 03/06/2020 07:00 03/06/2020 18:31True
2-Methoxyethanol 541 0.400FBL 0.367 ug/L 1.0 4580544--- ------50 - 150920.4 03/06/2020 07:00 03/06/2020 18:31True
2-Propen-1-ol 541 0.500FBL 0.437 ug/L 1.0 4580544--- ------50 - 150870.5 03/06/2020 07:00 03/06/2020 18:31False
IS-Chlorobenzene-d5 541 N/AFS 167300 ug/L 1.0 4565797NWPWF-002 ------50 - 150111150782 03/06/2020 07:00 03/07/2020 00:18False
SS-1-Butanol-d10 541 N/AFS 10.2900 ug/L 1.0 4565797NWPWF-002 ------70 - 13010310.0 03/06/2020 07:00 03/07/2020 00:18False
1-Butanol 541 2.00FS 2.00 ug/L 1.0 4565797NWPWF-002 ------------ < 03/06/2020 07:00 03/07/2020 00:18False
2-Methoxyethanol 541 0.400FS 0.400 ug/L 1.0 4565797NWPWF-002 ------------ < 03/06/2020 07:00 03/07/2020 00:18False
2-Propen-1-ol 541 0.500FS 0.500 ug/L 1.0 4565797NWPWF-002 ------------ < 03/06/2020 07:00 03/07/2020 00:18True
IS-Chlorobenzene-d5 541 N/ACCM 152112 ug/L 1.0 4580548--- ------50 - 150101150782 03/06/2020 07:00 03/07/2020 03:33True
SS-1-Butanol-d10 541 N/ACCM 10.1400 ug/L 1.0 4580548--- ------70 - 13010110.0 03/06/2020 07:00 03/07/2020 03:33True
1-Butanol 541 2.00CCM 20.846 ug/L 1.0 4580548--- ------70 - 13010420.0 03/06/2020 07:00 03/07/2020 03:33True
2-Methoxyethanol 541 0.400CCM 3.845 ug/L 1.0 4580548--- ------70 - 130964.0 03/06/2020 07:00 03/07/2020 03:33True
2-Propen-1-ol 541 0.500CCM 5.033 ug/L 1.0 4580548--- ------70 - 1301015.0 03/06/2020 07:00 03/07/2020 03:33
Page 2 of 2 EEA Run ID 272272 / EEA Report # 478603
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Sample Type Key
Type (Abbr.) Sample Type Type (Abbr.) Sample Type
CCH Continuing Calibration High
CCL Continuing Calibration Low
CCM Continuing Calibration Mid
DFBL DFB Low
FS Field Sample
FBL Fortified Blank Low
LDB Laboratory Digestion Blank
LRB Laboratory Reagent Blank
QCS Quality Control Sample
1.00
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END OF REPORT
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