AMMONIA MERCERIZATIO
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Submitted To:Dr. Ummul Khair Fatema Presented By :
ID Name2011-1-017 Shahanaz Parvin2011-1-018 Rifat Jahan2011-1-098 Nazmun Nahar2011-1-128 Humayra Akhter Himu2011-1-208 Nigar Rashida
WHAT IS MERCERIZATION?Mercerization is a pre-treatment or finishing treatment of cellulosic materials with higher concentrated Alkali (NaOH) for short period at lower temperature. Mercerization gives cotton woven cloth a silky luster, and is the foundation of many improved and beautiful finishes.
Mercerization was discovered by John Mercer and the process is named after him : Mercerizing. Later Horace Lowe found that the glazing effect became even more pronounced when cold caustic soda acted on cotton under tension. He discovered the actual mercerizing process.
OBJECTIVES OF MERCERIZATION
To improve luster of cotton materialsTo increase ability to absorb dye and moistureTo improve reactions with a variety of chemicalsTo improve dimensional stability of materialsTo improve strength/elongation and mechanical propertiesTo improve smoothnessTo improve hand
EFFECT OF MERCERIZATION ON COTTON FIBER
WHAT IS AMMONIA MERCRIZATION?
Ammonia Mercerization is a treatment of cotton fibre with Ammonia (NH3) produces effect similar to that obtained with caustic soda.
Among various amines, the Liquid Ammonia appears to be unique in its swelling action on cellulose and its effect on crystal structure.
Liquid ammonia treatment was first developed by Coats in 1960.
WHY AMMONIA MERCERIZATION?
Liquid Ammonia treatment is a highly effective and well controlled alternative to caustic soda mercerization.
Anhydrous liquid ammonia, being smaller molecule, penetrates cellulose very rapidly and complexes with hydroxyl groups of cellulose after breaking hydrogen bonds in crystalline regions and increases distance between cellulose chain in crystallites.
Ammonia treatment results in a more rounded cotton fiber, which scatters light more, in turn resulting in a luster that is less bright.
WHY AMMONIA MERCERIZATION? ( CONTD.)
This processing makes the inside of the fiber swell equally. There is less
fiber-swelling, therefore the fibers are more pliable, which allows them to bend and recover more easily when tension or stress is applied. The permanent-press effects are achieved without the use of cross-linking resins.The ammonia process was intended as a replacement for conventional mercerizing for both fabrics and in mercerizing sewing threads (Prograde process).The lower pH of ammonia allows safe treatment of more sensitive fibers like linen (flax) or silk.
APPLICATION ON TYPES YARNS & FABRICS
Sewing Thread
Denim Corduroy Chambray
Pillow Material Jute
Linen Cotton PET Blend
Cotton Nylon Blend
PHYSICAL CHANGESImprovement in strength.Change in cross section from bean shape to almost circular.Change in longitudinal view convoluted to cylindrical.
CROSS SECTION OF COTTON FIBER
After Ammonia
Mercerization
After Mercerization
CHEMICAL CHANGESFormation of cellulose-III Improvement in moisture regain properties (more hydroxyl groups)Improvement in dye uptake
ABSORPTION OF AMMONIA IN COTTON FABRIC
1 Cross section before mercerization 2-5 Swelling process in ammonia 6 Rinsing process after swelling 7 After state
PROCESS PARAMETER Concentration of Ammonia
Time of treatment
Tension applied
Temperature
Surface tension of Ammonia
Impurities of Ammonia
CHEMICALS Ammonia
Wetting agent
Temperature : -33ºc
Absorption period : 0.6 sec
Schematic Diagram of Ammonia Mercerizing Machine
Two processes known as PROGRADE for yarn mercerizing and SANFORSET for woven and knitted fabrics are widely used.
Main Parts Of Ammonia Mercerization Machine
Ammonia Impregnation zoneAmmonia Evaporation ZoneWashing Zone
Principle Of Ammonia Mercerization Machine
Process consist of passing the fabric though a bath of liquid ammonia with 100% pickup for approximately 10 seconds.
Ammonia is removed with dry heat applied by passing over blanketed, steam heated dry cans which removes about 90% of the ammonia which is recovered by a recovery plant and made available for recycling.
The rest of the ammonia, which chemically bonded to the cellulose, was removed by light steaming.
Diagram of the “Sanfor-set" process
Ammonia Impregnation zoneThe untreated fabric in dry condition, is passed over smoothing rolls and then around some heated dry cans. The dry cans assure an adequate level of dryness(water content less than 10%) in the fabric. Then the fabric is cooled by a fan before entering through a gas lock to the processing chamber . In the treatment chamber, the fabric passes over a guide roller and is directed downward and around an immersion roll disposed in the lower portion of a liquid pan, which retains liquid ammonia . The liquid ammonia bath is at a temperature of - 33° C.After passing the liquid ammonia bath, fabric is directed upward to a guide roller. The fabric web advances at a rate such that its immersion in the liquid ammonia bath may be for only a fraction of a second.
Ammonia Impregnation zone (Contd.)The atmosphere within the chamber is saturated with ammonia vapor, such that the liquid ammonia does not evaporate from the impregnated fabric emerging from the bath. The guide roll serves to smooth and apply a slight widthwise tension to the fabric before it enters the pad rollers. After having passed through the pad rollers , the fabric passes over a tension control roller ,to impart a desired amount of warpwise tension.
Ammonia Evaporation ZoneThe fabric passes around some guide rollers and is brought into a pressure contact with the surface of a heated dryer drum. The dryer includes a blanket which serves to both press the fabric tightly against the surface of the heated drum and to geometrically confine the fabric by frictional forces. The dryer drum typically may be heated by high temperature steam. Thus, when the fabric, saturated with liquid ammonia at -33° C, comes into contact with the heated drum surface, the ammonia is almost instantly washed off, to a level at which no further substantial reaction occurs. Thus, the reaction period is effectively terminated almost instantly upon contact of the fabric with the heated drum. In this heat treatment some 90-95% of the ammonia is removed.
Recovery of ammonia
Recovery of ammonia occurs by the reaction between ammonia water and gas that is discharged. Ammonia water is to mix with air, it goes outside and is then separated through the distillation column. Ammonia is distilled then send to the storage unit finally.
In the recovery device of ammonia, there are gas vents to wash the top of the tower, to control the ammonia content, and to lower than the amount for environment protection.
Property
ConventionalMercerization
HotMercerization
Ammoniamercerization
Swelling speed Low Fast Very fastEvenness Uneven Good GoodLuster Good Good Very goodDye up take Good Not quite good GoodDimensional stability
Good Good Good
Alkaline chemical
Sodium hydroxide
Sodium hydroxide
Ammonia
Comparison among different mercerization process
EFFECT OF AMMONIA MERCERIZATION
1. More rounded yarn structure and orientation.2. Excellent form stability ( having good Wash & Wear properties)3. Low shrinkage in post washing.4. Increase in wrinkle resistance.5. Increase in fiber elasticity.6. Enhanced tear resistance as well as tensile strength.7. This process add gentle, elegant luster to the fiber.8. Fibers keep their soft feel as no damage is done by this
processing.9. Highly uniform dyeing properties.10.Dye uptake % increased.
ADVANTAGES OF AMMONIA MERCERISATION
1. Evenness and uniformity of swelling comparatively better.2. Less pollution.3. Jute and linen can be mercerized.4. Safe treatment of more sensitive fibers like flax or silk.5. Higher productivity.6. Higher quality fabric. 7. Longer life after long periods of wear and repeated
washing.
DISADVANTAGES OF AMMONIA MERCERIZATION
1. Very costly equipments.2. Non-availability of machine.3. Lower color yield.4. Large capital investment for NH3 recovery.5. NH3 recovery problem.6. Leakages cause great harm to personnel working.
Thank You