Download - SAFETY DATA SHEET - School Specialty
Sodium Chloride – Iodized Salt Page 1 of 7 Issue Date: 1-March 2015
SAFETY DATA SHEET
1. Product and Company Identification Product Identifier Iodized Salt Other means of identification Synonyms Superior Iodized Table Salt
Private Label Brand Iodized Table Salt Superior TX-10 Iodized Salt
Recommended Use Food applications
Recommended Restrictions None Known
Manufacturer US Salt LLC 3580 Salt Point Road Watkins Glen, NY 14891 Phone: 607-535-2721 Emergency Telephone Number CHEMTREC (800) 424-9300
2. Hazard(s) Identification
Physical Hazards Not Classified
Health Hazards Not Classified
Environmental Hazards Not Classified
OSHA Defined Hazards Not Classified
Label Elements
Hazard Symbol None Signal Word None Hazard Statement The product does not meet the criteria for classification Precautionary Statement Prevention Observe good industrial hygiene practices Response Wash hands after handling Storage Store away from incompatible materials Disposal Dispose of waste and residues in accordance with local authority requirements
Hazard(s) not otherwise None Known Classified (HNOC)
3. Composition / Information on Ingredients
Salt and/or Salt Mixtures
Chemical Name CAS # % Sodium Chloride 7647-14-5 99.0-99.7 Sodium Silicoaluminate 1344-00-9 < 0.70 Dextrose 50-99-7 0.02-0.03 Sodium Bicarbonate 144-55-8 0.00-0.01 Potassium Iodide 7681-11-0 0.006-0.010 Sodium Ferrocyanide 13601-19-9 0.00-0.0013
GRAS Substance (Generally Recognized as Safe)
4. First Aid Measures
Inhalation Avoid breathing dust. If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist.
Skin Contact Wash skin with soap and water. Get medical attention if irritation develops and persists. Eye Contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Give one or two glasses of water if person is alert and able to swallow. Get medical attention if symptoms occur.
Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed
Indication of immediate Treat symptomatically medical attention and special Treatment needed
20-1673
Sodium Chloride – Iodized Salt Page 2 of 7 Issue Date: 1-March 2015
5. Fire Fighting Measures
Suitable extinguishing media Salt and salt mixtures are non-combustible Unsuitable extinguishing media Not Applicable Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Use appropriate firefighting PPE as a general precaution. and precautions for firefighters Fire-fighting Salt is not combustible and is thus not the material of concern for firefighting equipment or equipment/instructions methods. Specific methods In the event of a fire, equipment and methods that are consistent with the combusting material should be used. General fire hazards No unusual fire or explosion hazards noted.
6. Accidental Release Measures
Personal precautions, Keep unnecessary personnel away. Avoid generation and spreading of dust. Avoid inhalation of dust protective equipment and and contact with skin and eyes. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to emergency procedures dust/fume levels exceeding the exposure limits. Do not touch damaged containers or spilled material
unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Methods and materials for Stop the flow of material, if this is without risk. If sweeping of a contaminated area is necessary, use a dust containment and cleaning up suppressant agent which does not react with the product. Collect dust using a vacuum cleaner equipped
with HEPA filter. Minimize dust generation and accumulation. Avoid release to the environment. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into storm drains or sanitary sewers, groundwater or soil.
7. Handling and Storage
Precautions for safe handling Use work methods which minimize dust production. Provide appropriate exhaust ventilation at places where dust is formed. Avoid inhalation of dust and contact with skin and eyes. Wash thoroughly after handling. Keep away from strong acids. Practice good housekeeping.
Conditions for safe storage, Store in closed original container in a dry place. Store away from incompatible materials (see section 10 of including any incompatibilities the SDS). Becomes hygroscopic at 70-75% relative humidity. Avoid humid or wet conditions as product
will cake and become hard.
8. Exposure Controls / Personal Protection
Occupational exposure limits No exposures limits noted for ingredients(s). US. ACGIH Threshold Limit Values Components Type Value Form Potassium Iodide (CAS 7681-11-0) TWA 0.01 ppm Inhalable Form and vapor Sodium Silicoaluminate TWA 1 mg/m
3 Respirable Fraction
(CAS 1344-00-9) US. NIOSH Pocket Guide to Chemical Hazards Components Type Value Sodium Silicoaluminate TWA 2 mg/m
3
Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering TWA PEL: No specific limits have been established for sodium chloride (a soluble substance). As a controls guideline, OSHA (United States) has established the following limits which are generally recognized for
inert or nuisance dust. Particulates Not Otherwise Regulated (PNOR): 5mg/cu.m. Respirable Dust 8-Hour TWA PEL, 15mg/cu.m. Total Dust 8-Hour TWA PEL.
TWA TLV: No specific limits have been established for sodium chloride (a soluble substance). As a
guideline, ACGIH (United States) has established the following limits which are generally recognized for inert or nuisance dust. Particulates (insolubles) Not Otherwise Classified (PNOC): 10mg/cu.m. lnhalable Particulate 8-Hours TWA TLV, 3mg/cu.m. Respirable Particulate TWA TLV.
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Sodium Chloride – Iodized Salt Page 3 of 7 Issue Date: 1-March 2015
Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields. Wear a full-face respirator, if needed. Skin protection Hand protection If there is constant skin contact, rubber gloves are recommended.
Other Wear suitable protective clothing.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134.
Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and Chemical Properties
Appearance White crystalline solid
Physical State Solid Form Crystalline Solid Color White
Odor Halogen odor Odor Threshold Not applicable
pH in aqueous solution 4-9
Melting point/freezing point 1473.8 F (801 C)
Initial boiling point and boiling 2669 F (1465 C) (760 mm Hg) range
Flash Point Not applicable
Evaporation Rate Not applicable
Flammability (solid, gas) Not applicable
Upper/lower flammability or explosive limits
Flammability limit – lower Not applicable (%) Flammability limit – upper Not applicable (%) Explosive limit – lower (%) Not applicable
Explosive limit – upper (%) Not applicable
Vapor pressure 2.4 mm Hg (1376.6 F (747 C))
Vapor density Not applicable
Relative density 2.16 (H2O = 1)
Solubility(ies)
Solubility (water) 26.4%
Partition coefficient Not applicable (n-octanol/water)
Auto-ignition temperature Not applicable
Decomposition temperature Not applicable
Viscosity Not applicable
Other information Bulk density 53 – 83 lb/ft
3
Molecular formula NaCl, 14SiO2·Al2O3·Na2)·3H2O, NaHCO3, KI, Na4Fe(CN)6·10H2O
Molecular weight 58.44, 1059.3, 84.0, 166.02, 484.06
Sodium Chloride – Iodized Salt Page 4 of 7 Issue Date: 1-March 2015
10. Stability and Reactivity Reactivity The product is stable and non-reactive under normal conditions of storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid Contact with incompatible materials, i.e. strong oxidizing agents.
Incompatible materials Strong oxidizing agents, strong acids. Becomes corrosive to metals when wet.
Hazardous decomposition Chlorine gas, hydrogen chloride, oxides of sodium. products
11. Toxicological Information
Information on likely routes of exposure
Ingestion Expected to be low ingestion hazard
Inhalation High concentrations of dust may irritate throat and respiratory system and cause coughing.
Skin contact Dust may irritate skin. May cause irritation through mechanical abrasion.
Eye contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the Dust may cause eye, skin and respiratory tract irritation. Exposed individuals may experience eye physical, chemical and tearing, redness and discomfort. toxicological characteristics
Information on toxicological effects
Acute toxicity In some cases of confirmed hypertension, ingestion may result in elevated blood pressure. Ingestion of large amounts (greater than 0.1 pound) can cause gastrointestinal upset and irritation of the stomach. Rare cases of over exposure can lead to systemic toxicity related to the binding of ionized blood calcium.
Product Species Test Results
Sodium Chloride (CAS 7647-14-5)
Acute
Oral
LD50 Mouse 4000 mg/kg
Rat 3000 mg/kg
Other
LD50 Mouse 2602 mg/kg
Sodium Silicoaluminate (CAS 1344-00-9)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg, 24 hours
Inhalation Rat > 2.08 mg/l, 4 hours
Dextrose (CAS
Acute
Oral
LD50 Rat 25,800 mg/kg
Potassium Iodide
Acute
Oral
LD50 500-5000 mg/kg
Mouse 1000 mg/kg
Rat 4340 mg/kg
Other
LD50 Mouse 430 mg/kg
Rat > 285 mg/kg
Sodium Chloride – Iodized Salt Page 5 of 7 Issue Date: 1-March 2015
Product Species Test Results
Sodium Bicarbonate (CAS 144-55-8)
Acute
Oral
LD50 Rat > 4000 mg/kg
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation
Serious eye damage/eye Dust in the eyes will cause irritation irritation
Respiratory or skin sensitization
Respiratory sensitization Not available
Skin sensitization This product is not expected to cause skin sensitization
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified single exposure
Specific target organ toxicity - Not classified repeated exposure
Aspiration Hazard Due to the physical form of the product, it is not considered an aspiration hazard.
12. Ecological Information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results Sodium Chloride (CAS 7647-14-5) Aquatic
Crustacea EC50 Water flea (Daphnia magna) 340.7 – 469.2 mg/l, 48 hours
Fish LC50 Rainbow trout, Donaldson trout 4747 – 7824 mg/l, 96 hours (Oncorhynchus mykiss) Sodium Aluminosilicate (CAS 1344-00-9) Aquatic
Fish LC50 Guppy (Poecilia reticulate) 1800 – 3200 mg/l, 96 hours
Potassium Iodide (CAS 7681-11-0)
Aquatic
Fish LC50 Rainbow trout, Donaldson trout 896 mg/l, 96 hours (Oncorhynchus mykiss)
Sodium Bicarbonate (CAS 144-55-8)
Aquatic
Crustacea EC50 Daphnia 2350 mg/l, 48 hours
Fish LC50 Bluegill (Lepomis macrochirus) 8600 mg/l, 96 hours
Persistence and degradability No data is available on the degradability of this product
Bioaccumulative potential No data available
Partition coefficient n-octanol/water (log Kow Dextrose (CAS 50-99-7) -3.24 Mobility in soil No data available
Mobility in general No data available
Other Adverse effects None known
Sodium Chloride – Iodized Salt Page 6 of 7 Issue Date: 1-March 2015
13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations Dispose in accordance with all applicable regulations
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some product products residues. This material and its container must be disposed of in a safe manner (see Disposal Instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since Emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport Information
U.S. Department of Transportation (DOT)
Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG – Canada)
Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not Applicable Annex II of MARPOL 73/78 and the IBC Code
15. Regulatory Information
US Federal Regulations All components are on the U.S. EPA TSCA Inventory List This product is not known to be a “hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List Not regulated Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard Categories Immediate Hazard – No Delayed Hazard – No Fire Hazard – No Pressure Hazard – No Reactivity Hazard – No SARA 302 Extremely No Hazardous Substance SARA 311/312 Hazardous No Chemical SARA 313 (TRI reporting) Not regulated
Other federal regulations
Safe Drinking Water Act Not regulated (SDWA)
Sodium Chloride – Iodized Salt Page 7 of 7 Issue Date: 1-March 2015
US state regulations
US Massachusetts RTK – Substance List Not regulated
US New Jersey Worker and Community Right-to Know Act Not listed
US Pennsylvania Worker and Community Right-to-Know Law Sodium Silicoaluminate (CAS 1344-00-9)
US Rhode Island RTK Not regulated
US California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US – California Proposition 65 – Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed. International Inventories Country(s) or region Inventory name On inventory (Yes/No)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Yes
Europe European List of Notified Chemical Substances (ENCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or are exempt from listing on the inventory administered by the governing country(s)
16. Other Information, including date of preparation or last revision
Issue Date 01-March-2015
Revision Date -
Version # 01
Legend HMIS Ratings Health 1 Flammability 0 Severe 4 Physical Hazard 0 Serious 3 Personal protection A Moderate 2 Slight 1 NFPA Ratings Health 1 Minimal 0 Flammability 0 Reactivity 0 Disclaimer The information contained herein was obtained from current and reliable sources. However, the data is
provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond the manufacturer’s control, it is the users responsibility both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or expense arising from the product’s improper use. No warranty, expressed or implied, regarding the product described herein shall be created by or inferred from any statement or omission in this SDS. Various government agencies may have specific regulations concerning the transportation, handling storage, use or disposal of this product which may not be reflected in this SDS. The user should review these regulations to ensure full compliance.
PN: 96-3063 REV 003
PN: 96-3063 REV 003
PN: 96-3050 REV 003
PN: 96-3050 REV 003
PN: 96-3131 REV 003
PN: 96-3131 REV 003
Section 5 Fire Fighting Measures
Section 6 Accidental Release Measures
Section 4 First Aid Measures
Section 2 Hazards Identification
Section 3 Composition / Information on Ingredients
Product
CHEMTREC 24 Hour Emergency Phone Number (800) 424-9300
For laboratory use only. Not for drug, food or household use.
Section 1 Chemical Product and Company Identification
Synonyms
Chemical Name CAS # % EINECS
Page E1 of E2
SAFETY DATA SHEET
Ca Prop 65: This product does not contain any chemicals known to the State of California to cause cancer or reproductive toxicity.
Personal Precautions: Evacuate personnel to safe area. Use proper personal protective equipment as indicated in Section 8. Provide adequate ventilation. Environmental Precautions: Avoid runoff into storm sewers and ditches which lead to waterways. Containment and Cleanup: Sweep or vacuum up and place in a suitable container for proper disposal. Wash spill area with soap and water.
Suitable Extinguishing Media: Use any media suitable for extinguishing supporting fire. Protective Actions for Fire-fighters: In fire conditions, wear a NIOSH/MSHA-approved self-contained breathing apparatus and full protective gear. Use water spray to keep fire-exposed containers cool. Specific Hazards: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This material is commonly used to extinguish fires.
INGESTION: Call physician or Poison Control Center immediately. Induce vomiting only if advised by appropriate medical personnel. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
EYE CONTACT: Check for and remove contact lenses. Flush thoroughly with water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get immediate medical attention.
SKIN ABSORPTION: Remove contaminated clothing. Flush thoroughly with mild soap and water. If irritation occurs, get medical attention.
This substance or mixture has not been classified as hazardous according to the Globally Harmonized System (GHS) of Classification and Labeling of Chemicals.
Signal word: Not classified Pictograms: Not classifiedTarget organs: None known
GHS Classification: Not classified
GHS Label information: Hazard statement(s): Not classified
Sodium bicarbonate 144-55-8 100% 205-633-8
Precautionary statement(s):Do not breathe dust. Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands thoroughly after handling. Get medical attention if you feel unwell.
SODIUM BICARBONATE, ANHYDROUS
Baking Soda / Sodium Hydrogen Carbonate / Carbonic Acid Sodium (1:1)
SDS No.: SS0270 GENERAL STORAGE CODE GREEN
AldonCorporation
221 Rochester StreetAvon, NY 14414(585) 226-6177
Section 7 Handling & Storage
Section 9 Physical & Chemical Properties
Section 10 Stability & Reactivity
Section 11 Toxicological Information
Section 16 Other Information
Section 12 Ecological Information
Section 13 Disposal Considerations
Section 14 Transport Information (US DOT / CANADA TDG)
Section 15 Regulatory InformationA chemical is considered to be listed if the CAS number for the anhydrous form is on the Inventory list.
These disposal guidelines are intended for the disposal of catalog-size quantities only. Federal regulations may apply to empty container. State and/or local regulations may be different. Dispose of in accordance with all local, state and federal regulations or contract with a licensed chemical disposal agency.
Component TSCA CERLCA (RQ) RCRA code DSL NDSL
Section 8 Exposure Controls / Personal Protection
Exposure Limits: Chemical Name ACGIH (TLV) OSHA (PEL) NIOSH (REL)
The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make indepen-dent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. NTP: National Toxicology Program, IARC: International Agency for Research on Cancer, OSHA: Occupational Safety and Health Administration, STOT: Specific Target Organ Toxicity, SE: Single Exposure, RE: Repeated Exposure, ERG: Emergency Response Guidebook.
Page E2 of E2
Form 06/2015 Revision Date: December 15, 2016 Supercedes: May 13, 2016
Engineering controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower and fire extinguishing material. Personnel should wear safety glasses, goggles, or faceshield, lab coat or apron, appropriate protective gloves. Use adequate ventilation to keep airborne concentrations low.Respiratory protection: None should be needed in normal laboratory handling at room temperatures. If dusty conditions prevail, work in fume hood or wear a NIOSH/MSHA-approved respirator.
Precautions for Safe Handling: Read label on container before using. Do not wear contact lenses when working with chemicals. Keep out of reach of children. Avoid contact with eyes, skin and clothing. Do not inhale dusts. Use with adequate ventilation. Avoid ingestion. Wash thoroughly after handling. Remove and wash clothing before reuse.Conditions for Safe Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Store away from acids.
Appearance: Solid, white crystalline powder.Odor: No odor. Odor threshold: Data not available.pH: 8.2 (1% solution)Melting / Freezing point: Data not availableBoiling point: Decomposes Flash point: Non combustible
Evaporation rate ( = 1): Data not available Flammability (solid/gas): Data not available. Explosion limits: Lower / Upper: Data not availableVapor pressure (mm Hg): NegligibleVapor density (Air = 1): Data not availableRelative density (Specific gravity): 2.16 @ 20°CSolubility(ies): 8.6 g/100 ml water at 20°C
Chemical stability: Stable Hazardous polymerization: Will not occur.Conditions to avoid: High temperature causes decomposition to sodium carbonate, water and carbon dioxide.Incompatible materials: Reacts with acids to yield acid salts, water and carbon dioxide.Hazardous decomposition products: Gaseous carbon dioxide.
Toxicity to fish: Gambusia affinis (fish, freshwater) LC50: 7550 mg/l/24 hours Toxicity to daphnia and other aquatic invertebrates: Daphnia magna (Crustacea) EC50: 2350 mg/l/48 hoursToxicity to algae: Nitcheria linearis (Algae) LC50: 650 mg/l/5 dayPersistence and degradability: No data available Bioaccumulative potential: No data availableMobility in soil: No data available PBT and vPvB assessment: No data availableOther adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Sodium bicarbonate Listed Not listed Not listed Listed Not listed
Partition coefficient: Data not availableAuto-ignition temperature: Data not availableDecomposition temperature: Data not availableViscosity: Data not available.Molecular formula: NaHCO3Molecular weight: 84.01
Sodium bicarbonate None established None established None established
Acute toxicity: Oral-rat LD50: 4220-4400 mg/kg Skin corrosion/irritation: Skin-rabbit - not irritatingSerious eye damage/irritation: Eye-rabbit - not irritating Respiratory or skin sensitization: Non sensitizingGerm cell mutagenicity: Data not available Carcinogenity: Data not availableNTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.Reproductive toxicity: Data not available STOT-single exposure: Data not available STOT-repeated exposure: Data not available Aspiration hazard: Data not available Potential health effects: Inhalation: Excessive dust may irritate respiratory tract. Ingestion: Ingestion may cause gastrointestinal disturbance if ingested. Skin: No hazard known. Eyes: Contact with eyes may cause very slight irritation. Signs and symptoms of exposure: See Potential health effects above. Additional information: RTECS #: VZ0950000
UN/NA number: Not applicable Shipping name: Not RegulatedHazard class: Not applicable Packing group: Not applicable Reportable Quantity: No Marine pollutant: No Exceptions: Not applicable 2016 ERG Guide # Not applicable
Produit
Section 1 L’identification de produit chimique et de compagnie
Section 4 Mesures De Premiers Soins
Section 5 Mesures De Lutte Contre l’Incendie
Synonymes
Section 6 Mesures De Déchargement Accidentel
Nommé Chimique # CAS % EINECSSection 3 Composition / Information Sur Des Ingrédients
Section 2 Identification De Risques
CHEMTREC 24 Numéros De Téléphone De Secours D’Heure (800) 424-9300
Pour l’usage de laboratoire seulement. Pas pour l’usage de drogue, de nourriture
ou de ménage.
Page F1 of F2
FICHE DE DONNÉES DE SÉCURITÉ
Précautions personnelles: Évacuer le personnel vers la zone sûre. Utiliser un équipement de protection personnelle comme indiqué dans la Section 8. Assurer une ventilation adéquate. Précautions environnementales: Éviter tout ruissellement vers les égouts pluviaux et les fossés qui aboutissent aux voies navigables. Confinement et de nettoyage: Balayez ou nettoyez à l’aspirateur vers le haut et placez dans un récipient approprié pour la disposition appropriée. Laver la zone de déversement avec du savon et de l’eau.
Moyens d’extinction: Utilisez des supports adaptés pour éteindre le feu à l’appui.
Actions de protection pour les sapeurs-pompiers: En cas d’incendie, porter un appareil respiratoire NIOSH / MSHA approuvé autonome et un équipement complet de protection. Utiliser un jet d’eau pour maintenir incendie refroidir les conteneurs exposés. Dangers spécifiques: En cas d’incendie, des gaz irritants et très toxiques peuvent être générés par la décomposition thermique ou la combustion. Ce matériau est couramment utilisé pour éteindre les incendies.
CA Prop 65: Ce produit ne contient pas de produits chimiques connus à l’État de Californie pour causer le cancer ou de toxicité reproductive.
INGESTION: Appeler un médecin ou un centre antipoison immédiatement. Provoquer le vomissement seulement si elle est informée par le personnel compétent médicaux. Ne jamais rien donner par la bouche à une personne inconsciente.
INHALATION: Sortir au grand air. Si elle ne respire pas, pratiquer la respiration artificielle. Si la respiration est difficile, donner de l’oxygène. Obtenir des soins médicaux.
CONTACT AVEC LES YEUX: Vérifier et enlever les lentilles de contact. Rincer abondamment à l’eau pendant au moins 15 minutes, en soulevant les paupières inférieures et supérieures de temps en temps. Obtenez une attention médicale immédiate.
ABSORPTION PAR LA PEAU: Enlever les vêtements contaminés. Rincer soigneusement avec du savon doux et d’eau. En cas d’irritation, consulter un médecin.
Déclarations de précaution(s):Ne pas respirer les poussières. Éviter tout contact avec les yeux, la peau ou les vêtements. Porter des gants de protection / des vêtements de protection / un équipement de protection des yeux / du visage. Se laver les mains soigneusement après manipulation. Consulter un médecin en cas de malaise.
Cette substance ou un mélange n’a pas été classé comme dangereux à ce selon le Système général harmonisé (SGH) de classification et d’étiquetage des produits chimiques.
Signal word: Non classé Pictograms: Non classéTarget organs: Aucun connu.
GHS Classification: Non classé
GHS Label information: Hazard statement(s): Non classé
Bicarbonate de sodium 144-55-8 100% 205-633-8
BICARBONATE DE SODIUM, ANHYDRE
Bicarbonate de soude / Carbonate d’hydrogène de sodium / Soude acide carbonique (1:1)
GÉNÉRAL CODE D’ENTREPOSAGE VERT SDS No.: SS0270
AldonCorporation
221 Rochester StreetAvon, NY 14414(585) 226-6177
Section 7 Manipulation Et Stockage
Section 16 L’autre Information
Section 9 Propriétés Physiques Et Chimiques
Section 8 Commandes D’Exposition / Protection PersonnelleLimites d’exposition: Nommé Chimique ACGIH (TLV) OSHA (PEL) NIOSH (REL)
Section 10 Stabilité Et Réactivité
Section 11 L’Information Toxicologique
Section 12 L’Information Écologique
Section 13 Considérations De DispositionCes lignes directrices sont destinées à l’élimination de la disposition d’un catalogue de taille seules les quantités. Les règlements fédéraux peuvent s’appliquer aux contenants vides. Des réglementations nationales et / ou local peut être différent. Éliminer conformément à toutes les réglementations locales, provinciales et fédérales ou d’un contrat avec une agence élimination des produits chimiques sous licence.Section 14 L’Information De Transport (US DOT / CANADA TMD)
Section 15 L’Information De NormalisationUn produit chimique est considéré comme inscrit si le numéro CAS pour la forme anhydre est sur la liste d’inventaire.
Composant TSCA CERLCA (RQ) RCRA code DSL NDSL
Les informations contenues dans ce document sont fournis sans garantie d’aucune sorte. Les employeurs devraient considérer cette information seulement comme complément à d’autres informations recueillies par eux et doivent prendre des décisions indépendantes de la pertinence et l’exhaustivité de l’information de toutes les sources afin d’assurer une utilisation correcte de ces matériaux et de la sé-curité et la santé des employés. NTP: National Toxicology Program, IARC: International Agency for Research on Cancer, OSHA: Occupational Safety and Health Administration, STOT: Specific Target Organ Toxicity, SE: Single Exposure, RE: Repeated Exposure, ERG: Emergency Response Guidebook.
Page F2 of F2
Forme 06/2015 Date de révision: 15 décembre, 2016 Remplace: 13 mai, 2016
Contrôles d’ingénierie: Les installations d’entreposage ou d’utilisation de ce matériel doit être équipé d’une douche oculaire et une douche de sécurité et le matériel d’extinction d’incendie. Le personnel doit porter des lunettes de sécurité, des lunettes, ou un écran facial, une blouse de laboratoire ou tablier, des gants protecteurs appropriés. Utiliser une ventilation adéquate pour maintenir les concentrations atmosphériques faible.Protection respiratoire: Aucun ne devrait être nécessaire dans le laboratoire normal manipulant aux températures ambiantes. Si les conditions poussiéreuses prévaloir, tra-vailler dans la hotte ou de porter un masque respiratoire approuvé NIOSH / MSHA.
Précautions pour la manutention en toute sécurité: Lire l’étiquette sur le contenant avant d’utiliser. Ne pas porter de lentilles cornéennes lorsque vous travaillez avec des produits chimiques. Tenir hors de portée des enfants. Éviter tout contact avec les yeux, la peau et les vêtements. Ne pas inhaler les poussières. Utiliser avec une ventilation adéquate. Éviter l’ingestion. Bien se laver après la manipulation. Retirer et laver les vêtements avant de les réutiliser.
Conditions de stockage: Stocker dans un endroit frais, sec et bien aéré, loin des substances incompatibles. Stocker à l’écart des acides.
Apparence: Solide, poudre cristalline blanche.Odeur: Aucune odeur.Seuil de l’odeur: Données non disponibles.pH: 8.2 (Solution de 1%)Point de fusion / congélation: Données non disponiblesPoint d’ébullition: Se décompose Point d’éclair: Non combustible
Taux d’évaporation ( = 1): Données non disponibles Inflammabilité (solide / gaz): Données non disponibles.Limites d’explosivité: Bas / Max: Données non disponiblesPression de vapeur (mm Hg): NégligeableDensité de vapeur (Air = 1): Données non disponiblesDensité relative (gravité spécifique): 2.16 @ 20°CSolubilité(s): 8.6 g/100 ml water at 20°C
Stabilité chimique: Stable Polymérisation dangereuse: N’aura pas lieu.Conditions à éviter: La température élevées cause la décomposition au carbonate de sodium, à l’eau et à l’anhydride carbonique.Matières incompatibles: Réagit avec des acides aux sels de rendement, à l’eau et à l’anhydride carbonique acides.Produits dangereux de décomposition: Anhydride carbonique gazeux.
Toxicité pour les poissons: Gambusia affinis (fish, freshwater) LC50: 7550 mg/l/24 hoursToxicité pour les daphnies et autres invertébrés aquatiques: Daphnia magna (Crustacea) EC50: 2350 mg/l/48 hoursToxicité pour les algues: Nitcheria linearis (Algae) LC50: 650 mg/l/5 dayPersistance et dégradabilité: Pas de données disponible Potentiel de bioaccumulation: Pas de données disponibleMobilité dans le sol: Pas de données disponibles Évaluation PBT et vPvB: Pas de données disponiblesAutres effets indésirables: Un danger pour l’environnement ne peut pas être exclu dans l’éventualité d’une manipulation ou d’élimination.
Bicarbonate de sodium Listed Not listed Not listed Listed Not listed
Coefficient de partage: Données non disponiblesAuto-inflammation: Données non disponibles Température de décomposition: Données non disponiblesViscosité: Données non disponiblesFormule moléculaire: NaHCO3Poids moléculaire: 84.01
Toxicité aiguë: Oral-rat LD50: 4220-4400 mg/kg La corrosion de la peau et l’irritation: Skin-rabbit - non irritantDes lésions oculaires graves / irritation: Eye-rabbit - non irritantRespiratoire ou sensibilisation de la peau: Non sensibilisantMutagénicité des cellules germinales: Données non disponibles Cancérogène: Données non disponiblesNTP: Aucun composant de ce produit présent à des niveaux supérieurs ou égaux à 0,1% n’a été identifié comme cancérigène reconnu ou présumé par NTP.IARC: Aucun composant de ce produit présent à des niveaux supérieurs ou égaux à 0,1% n’a été identifié comme cancérigène probable, possible ou confirmé par IARC.OSHA: Aucun composant de ce produit présent à des niveaux supérieurs ou égaux à 0,1% n’a été identifié comme cancérigène ni comme cancérigène possible par OSHA.Reproductive toxicity: Données non disponibles STOT-exposition unique: Données non disponibles STOT-une exposition répétée: Données non disponibles Risque d’aspiration: Données non disponibles Effets d’une surexposition: Inhalation: Excessive aux poussières peut irriter les voies respiratoires. Ingestion: L’ingestion peut provoquer des troubles gastrointestinale. Peau: Aucun danger connu. Yeux: Contact avec les yeux peut provoquer une irritation très légère. Les signes et les symptômes de l’exposition: Voir les effets sanitaires potentiels ci-dessus. Informations complémentaires: RTECS #: VZ0950000
Numéro UN / NA: Non applicable Nom d’expédition: Non régléClasse de danger: Non applicable Groupe d’emballage: Non applicable Quantité à déclarer: Non Polluant marin: Non Exceptions: Non applicable 2016 ERG Guide #: Non applicable
Bicarbonate de sodium Aucun établi Aucun établi Aucun établi