![Page 1: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/1.jpg)
Simulating Material Property Changes of Irradiated Nuclear Graphite
L. Luyken, A. N. Jones, M. Schmidt,
B. J. Marsden, T. J. Marrow
Primarily graphite is used as a moderator
• Slowing down neutrons to thermal
energies
Is also used as a structural component.
• Control rod channels
• Coolant channels
• Reflector bricks
• Fuel Compacts
![Page 2: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/2.jpg)
What Happens to Graphite in a Reactor Core
Components Deform
Material Properties Change
Simple Dose Profile
![Page 3: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/3.jpg)
Why?
![Page 4: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/4.jpg)
Nuclear Graphite is made up of;
Pechinay Bulk Structure (polarised optical image)
Graphite Microstructure
Filler Particles
-Ordered Crystallites
Binder Matrix
- Disordered Crystallites
Porosity
- Calcination cracks- Gas evolution pores
![Page 5: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/5.jpg)
Crystallite Structure.
Crystallite Structure (Image Abbie Jones)
Graphite Microstructure
Mrozowski cracks
Crystal
![Page 6: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/6.jpg)
Damage Mechanism
Standard Model Ruck, Tuck and Buckle
Graphite Structure
![Page 7: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/7.jpg)
Crystallite Structure (Image Abbie Jones)
Damage Mechanism
C
a
a
![Page 8: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/8.jpg)
• Initial Adsorption “unpins” layers
• Intercalate can then penetrate graphite planes.
• Intercalate concentration within microstructure dependant on partial pressure of surrounding atmosphere.
• Bromine can also fill dislocation ribbons and push planes further apart
Widening of Dislocation Ribbons on Intercalation
Simulating Irradiation Damage
![Page 9: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/9.jpg)
-1
0
1
2
3
4
5
0 1 2 3 4
% Br/C%
Str
ain
PGA Perp 1PGA Perp 2PGA para 1PGA Para 2Gilsocarbon 1Gilsocarbon 2EDF
Strain due to Bromination of polycrystalline graphites
-10
-5
0
5
10
15
20
25
30
0 0.01 0.02 0.03 0.04 0.05
% Br/C
% St
rain HOPG in c
HOPG in a
Strain due to Bromination of HOPG
Dimensional Change by Intercalation
(Presented at UNTF 2009)
•Single crystals experience high strain at low bromine concentration
•Polycrystalline graphites experience differing bulk strains depending on orientation of crystals
![Page 10: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/10.jpg)
Tomography at the Swiss Light Source
Experimental Set Up
X-Ray Source Shutter Bromine Rig Camera
Beam Energy: 28KeV (high)
Projections: 1501 (reduces noise)
CCD exposure time: 160ms (fast)
Binning: 2 x 2 (reduces image resolution)
![Page 11: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/11.jpg)
Figure 1 Strain due to bromination of Pile Grade A graphite
Figure 2 Strain due to irradiation of Pile Grade A graphite
Strain due to Bromination
-1
-0.5
0
0.5
1
1.5
2
2.5
3
3.5
0 100 200 300 400 500 600
time (mins)
Str
ain
(%)
PGA_B3
-10.00
-8.00
-6.00
-4.00
-2.00
0.00
2.00
4.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
parallel
perpendicular
![Page 12: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/12.jpg)
Brominating Graphite Microstructure
Filler
Binder
![Page 13: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/13.jpg)
Brominating Graphite Microstructure
![Page 14: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/14.jpg)
Brominating Graphite Microstructure
![Page 15: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/15.jpg)
Brominating Graphite Microstructure
![Page 16: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/16.jpg)
Brominating Graphite Microstructure
![Page 17: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/17.jpg)
Brominating Graphite Microstructure
![Page 18: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/18.jpg)
Brominating Graphite Microstructure
![Page 19: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/19.jpg)
Brominating Graphite Microstructure
![Page 20: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/20.jpg)
Brominating Graphite Microstructure
![Page 21: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/21.jpg)
Brominating Graphite Microstructure
![Page 22: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/22.jpg)
Brominating Graphite Microstructure
![Page 23: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/23.jpg)
Brominating Graphite Microstructure
Binder
However larger regions of the binder matrix
accommodate bromine due to greater open
porosity in this region
Filler
Bromine quickly permeates large
crystalline regions
Filler
Nevertheless the largest deformation vectors are seen in the filler particles
![Page 24: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/24.jpg)
Change in Young’s modulus
)1(
)21)(1(2
vE
Where
E = Young’s modulus
ρ = density
ν = sonic velocity
θ = Poisson's ratio
Experimental Setup
![Page 25: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/25.jpg)
Change in Young’s modulus
PGA Perp
43
43.2
43.4
43.6
43.8
44
44.2
0 200 400 600 800
Time in Bromine (mins)
Tim
e o
f fl
igh
t (u
s)
Time Strain Young’s Modulus
t=0 0% 5.25 GPa**
t=720 0.3 % 5.29 GPa
** literature values vary from 4GPa to 7GPa
![Page 26: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/26.jpg)
Conclusions
• Bromination produces bulk dimensional
• Initially penetrates binder phase due to large amounts of open porosity
• Later quickly fills filler phase
• Largest strains are seen in filler phase
• As with irradiation brominating graphite increases the young’s modulus.
![Page 27: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/27.jpg)
Future Work
• Investigate crystal strains due to bromination.
• Applied for beam time at ILL
• Further develop Young’s modulus experiment to measure bulk strain insitu
• Use laser displacement detector
![Page 28: Simulating Material Property Changes of Irradiated Nuclear Graphite](https://reader031.vdocument.in/reader031/viewer/2022013011/568140e7550346895dacb4cb/html5/thumbnails/28.jpg)
Thank you
James Perrin University of Manchester
David James University of Manchester
Paul Townsend University of Manchester
Sam Macdonald University of Manchester (Swiss Light Source)
Will Bodel University of Manchester
"This work was carried out as part of the TSEC programme KNOO and as such we are grateful to the EPSRC for funding under grant EP/C549465/1“
Questions?