Site Visit Report
The site visit process is a sample on a particular day of an installation's compliance with some of its licence conditions. Where non-compliance against a particular condition has not been reported, this should not be construed to mean that there is full compliance with that condition of the licence.
Instructions and actions arising from the visit shall be addressed, or where applicable noted, by the licensee in order to ensure compliance, to improve the environmental performance of the installation and to provide clarification on certain issues.
The licensee shall take the actions specified to close out the non-compliances and observations raised in this Site Visit Report.
Licensee
Name of Installation Medite Europe Limited
Licensee Medite Europe Limited
Licence Register No. P0027-02
CRO Number 80984
Site Address Redmondstown, Clonmel, Tipperary
Site Visit Reference No. SV08076
Report Detail
Issue Date 14/10/2016
Prepared By David Matthews
Site Visit Detail
Date Of Inspection 26/07/2016 Announced No
Time In 14:00 Time Out 13:00
Visited by on behalf of the EPA Exova Ltd.
Licensee Personnel and Role See report
Photo Taken No Samples Taken Yes Video Taken No
Site Visit Report - SV08076 - Medite Europe Limited Page 1 of 83
Scope
This is a report on monitoring of emissions to atmosphere at this site. Please find the detailed technical report attached.
Media
Air
Site Areas Inspected
See report
Documents Inspected
See report
Site Visit Report - SV08076 - Medite Europe Limited Page 2 of 83
ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279
Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland
Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL
EMISSIONS REPORTEPA AIR EMISSIONS COMPLIANCE MONITORING
Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11
T: +353 86 853 8247E: [email protected]
Your Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)
Clonmel
RedmondstownMedite Europe Ltd
IrelandCo Tipperary
EPA Office of Environmental Enforcement
EP 35 - Face Dryer Stage 1
DELETE & COVER ME
(Prepared on behalf of the EPA by Exova Catalyst - EPA Contract No. OEE-14-DS)-
-
Team Leader
Deputy Regional Manager
TE1 TE2 TE3 TE4MM 08 922
MCERTS Level 2
Patrick O'Brien
Report Approved by
MM 10 1074MCERTS Level 2
Stack Emissions Testing Report Commissioned by
26th - 27th July 2016
Job Reference Number
CDU-0666-CAR16-01
Installation Name & Address
Dates of the Monitoring Campaign
Report Written by
John Glennon
19th September 2016
Report Date
TE1 TE2 TE3 TE4
Version
Stack Reference
Industrial Emissions Licence: P0027-02
Signature of Report Approver
Version 1
CAT-RT (Version BO)Site Visit Report - SV08076 - Medite Europe Limited Page 4 of 83
TITLE PAGE
CONTENTS
Summary of Sampling Deviations
EXECUTIVE SUMMARY
Monitoring Objectives
Monitoring Results
Monitoring Dates & Times
Process Details
Monitoring & Analytical Methods
Sampling Location
Plant Photos / Sample Points
APPENDIX 1 - Monitoring Personnel & List of Equipment
APPENDIX 2 - Raw Data, Sampling Equations & Charts
The testing performed fully meets the technical requirements in Irish
EPA Guidance Note, AG2.
9
3
5
6
8
Opinions and interpretations expressed herein are outside the scope of
Exova Catalyst Ireland's ISO 17025 accreditation.
This test report shall not be reproduced, except in full, without the
written approval of Exova Catalyst Ireland.
7
CONTENTS
4
2
CAT-RT (Version BO)
Page 2 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 5 of 83
Overall Aim of the Monitoring Campaign
Special Requirements
Target Parameters
Exova Catalyst Ireland were commissioned by EPA Office of Environmental Enforcement to carry out stack emissions testing for
Medite Europe Ltd on the EP 35 - Face Dryer Stage 1 at Clonmel.
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in
the Site's Licence.
There were no special requirements.
Total Particulate Matter | Condensable VOCs | Cadmium & Thallium | Heavy Metals | Mercury | Dioxins & Furans |
Formaldehyde | Isocyanates | Oxides of Nitrogen (as NO₂) | Carbon Monoxide |
MONITORING OBJECTIVES
Executive Summary
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
26th - 27th July 2016
(Page 1 of 7)
CAT-RT (Version BO)
Page 3 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 6 of 83
where MU = Measurement Uncertainty associated with the Result
Parameter
Total Particulate Matter ¹
Condensable VOCs ¹ - -
Cadmium & Thallium ¹ - -
Heavy Metals ¹ - -
Mercury ¹ - -
Dioxins & Furans (NATO I-TEQ) - R1 Dioxins & Furans ¹
Formaldehyde ¹ - -
Isocyanates ¹ < <
Oxides of Nitrogen (as NO₂) ¹ - -
Carbon Monoxide ¹ - -
Oxygen Wet Dry
Water Vapour
Stack Gas Temperature
Stack Gas Velocity 2
1 & 2
- -
NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.
¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.
2 Agreed volumetric flow rate with the EPA (this result was not measured by Exova as part of the monitoring campaign).
-
Limit
179800
1281.08
39.80
7.8125.52 g/hr 3150
0.071
20mg/m³
ng/m³
0.0001 0.05
4134.85
-g/hr
1.10
20.0
0.001
1.24
% v/v
0.79
Medite Europe Ltd, Clonmel
`
g/hr 320.565.42
+/-
Units Result
Concentration
0.0007
MU
0.01
0.0018
mg/m³ 0.05 -
g/hr
g/hr
0.1
Limit
+/-
0.04
mg/m³
Executive Summary
0.29 0.12
Mass Emission
201.96
-
MONITORING RESULTS
EP 35 - Face Dryer Stage 1
0.5 g/hr 11.58 -
2399.4
g/hr
-
Dioxins & Furans Upper Limit (worst case where <LOD = LOD)
0.001 0.17
Units
0.0003 0.053
mg/m³
14.70 100 6008.4
-
877.7
Result Limit
37.09
µg/hr
-
mg/m³
MU
0.0002
m³/hr
18.58
174540
m³/hr
mg/m³
mg/m³
20.80
7819
1.06
200.81mg/m³
g/hr
0.070 0.20.01
1.96 130 127.79 317.14
153.89
-12.8m/s
(Page 2 of 7)
0.95 600
% v/v
10.66
162000
% v/v
°C
g/hr
Volumetric Flow Rate (ACTUAL)
0.246
Volumetric Flow Rate (REF)
mg/m³
8424
-
-
CAT-RT (Version BO)
Page 4 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 7 of 83
Parameter
R1 - -
R1 - -
R1 - -
R1 - -
R1 - -
(NATO) R1 - -
R1 - -
R1 < <
R1 - -
R1 - -
R1 -
R1
All results are expressed at the respective reference conditions.
Isocyanates mg/m³ 0.01 g/hr 1.06 27/07/2016 09:55 - 10:25 30
Dioxins & Furans
Heavy Metals
09:20 - 09:50
0.25
Date(s)
Mass Emission
g/hr
27/07/2016
µg/hr
127.79
39.80
mg/m³
ng/m³
% v/v
15:31 - 16:00
Velocity & Volumetric Flow Rate 26/07/2016
0.0370.0002
(Page 3 of 7)
0.29
Mercury
mg/m³
Units
Medite Europe Ltd, Clonmel
MONITORING DATE(S) & TIMES
mins
Concentration
27/07/2016
Sampling
877.74
37.1Condensable VOCs
EP 35 - Face Dryer Stage 1
26th - 27th July 2016
Executive Summary
Sampling
Times
g/hr
27/07/2016
10:35 - 11:35
09:20 - 09:50
6008.4
mg/m³ 0.17
10:35 - 11:35
mg/m³
60
10:35 - 11:35
g/hr
0.0011
g/hr
27/07/2016
27/07/2016
1
0.0018
25.5 4134.9 27/07/2016
30
08:40 - 09:10
Oxides of Nitrogen (as NO₂)
60Cadmium & Thallium
36026/07/2016
Formaldehyde mg/m³ g/hr
60
11:00 - 17:00
mg/m³
Units
Total Particulate Matter 5.42
g/hr 30
30
Duration
26/07/2016
g/hr
19.63
Carbon Monoxide
0.79
26/07/2016
200.811.24 15:31 - 16:00
Oxygen
26/07/2016mg/m³
g/hrmg/m³
15:31 - 16:00
30
30
30
CAT-RT (Version BO)
Page 5 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 8 of 83
Standard Operating Conditions
Value
Medite Europe Ltd, Clonmel
Feedstock (if applicable)
Process Status
Parameter
Visible
100 % of capacity
Woodchip
Fuel
(Page 4 of 7)
Executive Summary
PROCESS DETAILS
EP 35 - Face Dryer Stage 1
26th - 27th July 2016
Abatement System
Abatement System Running Status
Plume Appearance
Cyclone
Capacity (of 100%) and Tonnes / Hour
Continuous or Batch Process
N/A
On
Continuous
Drying Process
CAT-RT (Version BO)
Page 6 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 9 of 83
0.0011 ng/m³
Isocyanates
CAT
CAT-TP-05 YesEN 14790
1
0.0065 mg/m³
Dry Paramagnetic Cell by Horiba PG-350ECATOxygen
CAT-TP-05
NDIR by Horiba PG-350E
ANALYSIS LABORATORIES
Chemiluminescence by Horiba PG-350E
Deviation
0.1 % v/v
EN 15058
0.41 mg/m³CAT-TP-39
CAT
CAT Yes
Yes
EN 14789 CAT-TP-39 Yes
All
Scientific Analysis Laboratories Ltd (SAL)
RPS Laboratories Ltd (RPS)
Yes
(with short name reference as appears in the table above)
Exova Catalyst (CAT)
ISO 17025 Accreditation Number: 0605
0.1 %
Gravimetric
US EPA CTM36
Water Vapour
Yes
Yes
EN 14792
Yes
Dioxins & Furans CAT
IC
Total Particulate Matter EN 13284-1
CAT-TP-19
CAT
Yes
Yes
Yes
SOP 1C
HPLC
0.54 mg/m³
ISO 17025 Accreditation Number: 4279
ISO 17025 Accreditation Number: 1549
Oxides of Nitrogen (as NO₂)
Yes
Carbon Monoxide
Yes
CAT-TP-17
CAT Yes
CAT SAL
Yes
Analytical
TechniqueProcedure
Heavy Metals
YesCAT-AP-05CAT
Yes SAL
Yes
OX-IR
Analytical
M112
Technical
Mercury
ICP-MS
CAT-TP-03
EP 35 - Face Dryer Stage 1
Yes CATEN 14385
US EPA M316
(Page 5 of 7)
Testing ISO
Cadmium & Thallium
Yes
Standard
Yes
Yes CAT
CAT
CAT-TP-01
EN 1948
Lab
Yes
CAT-TP-07
Yes
Yes
GC-HRMS
ISO
Lab
Yes 0.027 mg/m³
CAT
Executive Summary
Testing
0.004 mg/m³
CAT
Yes
SALOX-IR
Analysis
CAT-TP-23In House
Analysis
17025 Analysis
RPS
RPS
CAT-TP-06
EN 14385
Yes
Yes
ICP-MS
Monitoring
CAT
Parameter
Procedure
CAT-TP-06
Yes
0.001 mg/m³
Condensable VOCs
0 mg/m³
LOD
Yes
CAT-TP-06 Yes
MID 14385
Medite Europe Ltd, Clonmel
Gravimetric
MCERTS
17025
Testing
0.21 mg/m³
CV-AFS
RPS
(Average)
M31
M31
Formaldehyde
Yes
26th - 27th July 2016
Ratio highest to lowest velocities between 3 and 5 : 1.
0.027 mg/m³
CAT-TP-39
MONITORING & ANALYTICAL METHODS
1 The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
SUMMARY OF SAMPLING DEVIATIONS
Parameter Run
All
M119
CAT-RT (Version BO)
Page 7 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 10 of 83
Duct Characteristics Location of Sampling Platform
Platform Details
Sampling Location / Platform Improvement Recommendations
EN 15259 Homogeneity Test Requirements
No
-
Parameter
There are no obstructions present which hamper insertion of sampling equipment
-
m²
m
Yes
Yes
SUITABILITY OF SAMPLING LOCATION
Executive Summary
cm
-
Permanent
Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)
-
Sufficient working area to manipulate probe and operate the measuring instruments
Type
2.20
Width
Sample Port Size
There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.
Circular
Value
Vertical
No
Safe Access Available
(Page 6 of 7)
Permanent / Temporary Platform
Inside / Outside
General Platform Information
Platform has vertical base boards (approx. 0.25m high)
Units
Outside
Yes
24
The sampling location does not meet all of the Flow Criteria requirements in the EPA Guidance Note AG1 and EN 15259.
Area
m
3.80
Orientation of Duct
Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements
Yes
Platform has chains / self closing gates at top of ladders
Value
Easy Access Available
Depth
Port Depth
Yes
4" BSP
Value
CAT-RT (Version BO)
Page 8 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 11 of 83
PLANT PHOTOS
(Page 7 of 7)
Photo 2
SAMPLE POINTS
Photo 1
Photo 4Photo 3
Executive Summary
where = isokinetic point sampled at
= isokinetic point not sampled at
= combustion gases sample point
= non-isokinetic sample point Line A
Line B
A1
A3
A2
A6
A5
A4
B3 B2 B1
B6 B5 B4
CAT-RT (Version BO)
Page 9 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 12 of 83
APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDICES
APPENDIX CONTENTS
CAT-RT (Version BO)
Page 10 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 13 of 83
Bioaerosols Temperature Logger -
Electronic Refrigerator -
Servomex 4900
-
-
Stopwatch
Mercury
-
-
CAT 3.59
SELECT FTIR
SELECT Horiba Model (2)
MM 10 1074 TE1 TE2 TE3 TE4
Technician James Magann MCERTS Level 1 MM 15 1330 TE1
CAT 39.9
Position
Digital Temperature Meter
Instrumental Analysers
Oven Box (1)
CAT 3.97
METHODS & TECHNICAL PROCEDURES USED
CAT 7.23
Eco Physics CLD 822Mh
CAT-TP-39
CAT-TP-39
MID 14385
EN 14385
EN 1948
Stack Thermocouple (1)
Gasmet Sampling SystemCAT 5.51
ABB AO2020-URAS26
Condensable VOCs
CAT 3.97-
-
CAT 21S.46
Miscellaneous Items
Oxides of Nitrogen (as NO₂)
Heated Probe (3) -
CAT 6.1
Bernath 3006 FID -
-
- 1m Heated Line (2)Heated Probe (2)
Equipment Type
Control Box DGM (2)
-
John Glennon MCERTS Level 2
Mass Flow Controller (2) CAT 6.21
Technical Endorsements
Team Leader
Equipment Type
MCERTS Number
Equipment I.D.
STACK EMISSIONS MONITORING PERSONNEL
APPENDIX 1
EN 14789
Heavy Metals
Mass View (1) -
20m Heated Line (2)
EN 15058
Parameter
Total Particulate Matter
EN 14385
Tubes Kit Thermocouple -
Carbon Monoxide
EN 14790
US EPA CTM36
-
SELECT Logger 2 -
Dual Channel Heater Controller -
CAT-TP-39
Isocyanates
Water Vapour
15m Heated Line (1)
CAT 17.10
Formaldehyde
CAT 4.491
-
Umbilical (2) Servomex 5200MP
Oxygen
Stack Thermocouple (2)
Equipment I.D.
1m Heated Line (3)
Control Box DGM (1)
CAT 4.605
Extractive Sampling
LIST OF EQUIPMENT
MCERTS Accreditation
Single Channel Heater Controller
CAT-TP-01
Barometer
Digital Manometer (2)
Umbilical (1)
Box Thermocouples (2)
Box Thermocouples (1)
-
Stack Thermocouple (3)
CAT 20.71
-
EN 13284-1
Technical ProcedureStandard
Heated Probe (1)
-
-
CAT 12.105
CAT 3.59
-
Mass View (2)
CAT 12.84
-
CAT 4.705
5m Heated Line (1) -
JCT JCC P1 Cooler
CAT 13.27
Mass Flow Controller (1)
500g / 1Kg Check Weights CAT 17.10
Last Impinger Arm CAT 4.404
Callipers
- 20m Heated Line (1)
S-Pitot (2) CAT 21P.92
SELECT Logger 1
Cadmium & Thallium
Site Balance
M&C PSS
Dioxins & Furans
CAT 20.71
Laboratory Balance CAT 1.18 / 1.18a
Tape Measure CAT 16.95
Equipment I.D.
-
CAT 14.53
-
S-Pitot (1)
L-Pitot
-
CAT-TP-19
CAT-TP-07
CAT-TP-06
CAT-TP-06
CAT-TP-06
CAT-TP-23
CAT-TP-05
CAT-TP-17
In House
Horiba PG-350E Digital Manometer (1)
Oven Box (2)
1m Heated Line (1)
Name
-
CAT 23.26
EN 14792
US EPA M316
Equipment Type
CAT-RT (Version BO)
Page 11 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 14 of 83
General Stack Details
Stack Gas Composition & Molecular Weights
CO₂ (Estimated)
O₂
Moisture (H₂O)
Where: p = M / 22.41
pi = r x p
Calculation of Stack Gas Densities
Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)
P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)
P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)
P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Volumetric Flowrate, Q
m²
PRELIMINARY STACK SURVEY: CALCULATIONS
Stack Diameter / Depth, D
Gas Volumetric Flowrate (from Traverse)
162000
kg/m³
-
Mass
Component
m³/hr
Result
°C
Units
Pa
Fraction
Density
Dry
0.08565
20.80 32.00
Conc
132.7
Molar Conc
3.80
mStack Width, W
Stack Area, A
-
Volume
kPa
kPa
0.84
Value
2.20
100.9
Average Stack Gas Temperature, Ta
0.010
°C
Average Stack Static Pressure, Pstatic
m³/hr
REF ¹
1.219
Dry Density (Actual), P Actual
m³/hr
Gas Volumetric Flowrate (STP, Dry)
Gas Volumetric Flowrate (Actual)
kg/m³
20.0
Average Barometric Pressure, Pb
m
Actual
kg/m³
0.7914 28.01
101.3
Result
1.9635
Stack Details (from Traverse)
APPENDIX 2
0.05
Units
Average Pitot Tube Calibration Coefficient, Cp
ppm kg/m³
Average Stack Gas Pressure
Conc
10.66
Conc
M
Wet
r% v/v
kg/m³
m³/hr
Total Pressure
Average Wet Density (Actual), P ActualW
10.66
79.14 0.98913
1.287
70.71
Dry Density (STP), P STD
18.02
Determinand
0.0006
20.0
100.9
Temperature
N₂
1.4277 0.29696-
Units
0.00118
Gas Volumetric Flowrate (STP, Wet)
Moisture
kPa
0.1066
18.58
p pi
-
1.2498
44.01
144737
-
-
0.2080
-0.0
% v/v
Units
10.66
kg/m³ 1.236
Duct gas flow conditions
162000
174540
1.195
Wet Density (STP), P STW
-
Gas Volumetric Flowrate REF ¹
%
0.8037
0.06
CAT-RT (Version BO)
Page 12 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 15 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
APPENDIX 2
877.7
mg/m³ 5.42
Run 1
Maximum
mg/m³ 0.77
A3
Positioning of Filter
Mean
320.6
1.08 1.08
320.6
±% v/v
1 / 2
Number of Sampling Points Used 1 / 12
Titanium
Filter Housing Material Borosilicate Glass
Probe Material
Parameter Units
Run 1
Water Vapour
Concentration
Mass Emission
Standard
47mm Glass Fibre
0.77
Parameter
EN 13284-1
Sample Point I.D.'s
10.11
Number of Sampling Lines Used
CAT-TP-01
% v/v
Value
g/hr 877.7
TOTAL PARTICULATE MATTER: RESULTS SUMMARY
Filter Size and Material
Out Stack
Technical Procedure
Parameter Units
Uncertainty ±g/hr
Medite Europe Ltd, Clonmel
Mean
10.11
EP 35 - Face Dryer Stage 1
Parameter
Concentration
5.42
Blank 1
Uncertainty
Uncertainty ±mg/m³ 1.96 1.96
Units
CAT-RT (Version BO)
Page 13 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 16 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
g/gmol 28.84
34.97
0.3592
761.3
m³
g/gmol 27.75
-
0.06
3563.6
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
Bwo = Vwstd / (Vmstd + Vwstd) 0.1011
N/A
N/A
-
Ps = (Pb + (Pstatic / 13.6) 755.5
N₂
- N/A
No
Pitot tube velocity constant, Kp
m³
m³
Average pressure drop across orifice, ∆H
Average stack gas temperature, Ts
46.9
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
Conversion factor (K/mm.Hg), Cf
Total mass collected in impingers (silica trap)
mmHg
g
mmHg
6.01
°C 57.0
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 15.62
mm
m³/min
min 30
m³/min 2634.4
Area of stack, As m²
%
Average of velocity heads, ∆Pavg mmH₂O
Total sampling time, q
3.80
Qa = (60)(As)(Vs)
Run 1
-
0.6666
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
% v/v
0.6534
% v/v
20.80
Velocity of stack gas, Vs
Velocity pressure coefficient, Cp
g
TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS
Test Units
Total mass collected in impingers (liquid trap)
9.7
17.97
4.24
28.34
m³/min
99.7
m/s
-
m³/min
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
0.9310
10.11
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
Stack static pressure, Pstatic
N/A
-
% v/v
m³
% v/v
17.3
Barometric pressure, Pb
53.0
Nozzle diameter, Dn
mmH₂O
0.0660
Volume of gas sample through gas meter, Vm m³
Gas meter correction factor, Yd
43.3g
N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd)
N/A
-
Vmstw = (Vmstd)(100/(100 - Rwv))
% v/v 20.86
% wet oxygen measured in gas stream, ACT%O₂w
0.84
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)
-78.2
0.5873
Average square root of velocity heads, √∆P
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
Vwstd = (0.001246)(Vlc)
Average dry gas meter temperature, Tm °C
Total mass of liquid collected, Vlc
% v/v
APPENDIX 2
% v/v
% v/v
mmH₂O
% oxygen reference condition, REF%O₂ % v/v N/A
% dry oxygen measured in gas stream, ACT%O₂d
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
mm²
m³
Total
2930.6
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)
79.14
√mmH₂O
Nozzle area, An
N/A
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A
10.11
m³
CAT-RT (Version BO)
Page 14 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 17 of 83
Sample Runs
Filter I.D. Number
Probe Rinse I.D. Number
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
Filter I.D. Number
Probe Rinse I.D. Number
Start Probe Rinse Mass
0.00021
5.42
Sampling Device
3.54
0.77
0.00333
-
2.94040
Start Filter Mass
3.18239
-
Total Mass on Filter
mg/m³
0.21
0.14667
Total Mass on Filter
End Filter Mass
-
Parameter
-
End Probe Rinse Mass
47-32937
g
Units
g
g
0.6534
Total Mass in Probe Rinse
09:20 - 09:50
Average Volume Sampled (REF)
PR-47-32938
Start Filter Mass
g
0.15146
0.15479
PR-47-32937
mg/m³
m³
Balance Uncertainty / LOD
Calculated Concentration
TOTAL PARTICULATE MATTER: SAMPLING DETAILS
Balance Uncertainty / LOD
47-32938
mg 0.50
0.21
Calculated Concentration
g
3.18260
0.14625
-
Blank Dates -
mg/m³
Total Mass Collected
Parameter Units
Sampling Dates
ISO
End Probe Rinse Mass
End Filter Mass
Sampling Times
Blank 1
Run 1
APPENDIX 2
-
g
g
27/07/2016
0.6534
g
-
Total Mass in Probe Rinse
Start Probe Rinse Mass
g 0.00042
Volume Sampled (REF) m³
0.00008
mg
g
mg/m³
g
g
2.94032
Total Mass Collected
27/07/2016
CAT-RT (Version BO)
Page 15 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 18 of 83
Sample Runs
MU Acceptable
Test Conditions Units
Allowable Weighing Uncertainty
95 - 115
180
0.27
Weighing Uncertainty Criteria
160
ELV [Daily ELV for IED] mg/m³ 35.00
Weighing Uncertainty Acceptable
Isokinetic Variation
Yes
Run 1
TOTAL PARTICULATE MATTER: QUALITY ASSURANCE
No
%
Yes
± mg/m³
Run 1
Post-Sampling Leak Rate
Leak Test Results
Yes
-
0.41
150
Mean Sampling Rate l/min 20.69
Leak Test Acceptable
l/min 0.30
Allowable Leak Rate
Run 1
Measurement Uncertainty (MU)
-
Silica Gel (Concurrent Water Vapour) Units
Allowable Isokinetic Range %
Allowable MU
(PAGE 1 OF 2)
Units
Units
Filter Temperatures
Units
Yes
Units Run 1
Ambient Temperature Recorded? -
- Yes
Run 1
Are Water Droplets Present
l/min
°C
mg/m³ 1.75
Water Droplets
%
Run 1
20
°C
Yes
APPENDIX 2
Isokinetic Criterion Compliance
Units
Pre-Sampling Leak Rate l/min 0.14
Overall Weighing Uncertainty
Less than 50% Faded
Units
± mg
Run 1
-
°C
%
99.7%
10.7
0.41
%
Isokineticity Acceptable
Maximum Filter Temperature
Pre-Conditioning Temperature
Post-Conditioning Temperature
Run 1
Overall Weighing Uncertainty
MU (Concurrent Water Vapour)
CAT-RT (Version BO)
Page 16 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 19 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
Yes
Post-Sampling Leak Rate l/min 0.18
Leak Test Acceptable
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Ratio highest to lowest velocities between 3 and 5 : 1.
Blank 1
0.40
Units Blank 1
mg/l
-
Run Number
-
Yes
3.5
0.12
(PAGE 2 OF 2)
Validity of Blank vs ELV
Acetone / Water Rinse Value
mg/m³
10
Allowable Leak Rate
Allowable Blank
Units
Nature of Deviation
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
2.7
Pre-Sampling Leak Rate
l/min
l/minExpected Sampling Rate 20.00
Acetone / Water Rinse Blank Units Blank
Blank Acceptable
Leak Test Results
APPENDIX 2
TOTAL PARTICULATE MATTER: QUALITY ASSURANCE
Allowable Blank
mg/l
-
Yes
l/min
Blank Acceptable
CAT-RT (Version BO)
Page 17 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 20 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (STP)
Leak
Mass of Particulate
Uncollected Mass
Sampled Volume (STP)
Leak
Mass of Particulate
Uncollected Mass
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Oxygen Correction Part of MU Budget
Measured Quantities
-
mg
%
Units
- N/A
Overall MU For O₂ Measurement
mg/m³
18.6
3.540
1.53
≤1%
mg/m³
-
0.50
0.4418
Run 1
≤2%
% v/v
Symbol Units
Uncertainty in Measurement Units Sensitivity Coefficient
%
mg/m³
mg/m³
0.2143
9.23
uVm m³
Measured Quantities Symbol
m um
0.5ρm 100.7
mg/m³
Measured Quantities
% 1.45
N/A
N/A
1.96
0.045
kPa
1.45
0.0Hm
Units
% N/A
Parameter Units
N/A
-uL %
%
≤2%
%
mg/m³ 0.142
3.54
mg/m³
Run 1
uHm
%
Uncertainty as a Percentage
N/A
36.2
1.0
0.29
-
Run 1 Requirement of Standard
Run 1
2.00
Measured Quantities
uUCM mg -
Units
0.69
%
Measured Quantities
%
Vm
0.5873
Symbol
uTm
Run 1
36.2
1.53
mg/m³
K 2.0
0.6666
L
% 0.61
Run 1
1.96
1.00
UCM
m³
0.0454
<5% of ELV
Run 1
mg
APPENDIX 2
TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS
Value Standard uncertainty
0.0133
Lr mg
1.01
290.3
L
%
mg/m³
0.50
UCM
Units Run 1
Tm
Vm
% v/v
uρm
≤1%
Uncertainty in Result
mg/m³ 0.51
≤1%
% 1.00
0.14
CAT-RT (Version BO)
Page 18 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 21 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
In HouseStandard
2399.4
Technical Procedure CAT-TP-23
Units
2399.4
CONDENSABLE VOCS: RESULTS SUMMARY
6008.4
1.08
Units
Medite Europe Ltd, Clonmel
47mm Glass FibreFilter Size and Material
Uncertainty
Units
ISO 17025 Accredited Analysis?
±mg/m³
Maximum
12/08/2016
31.19
Mean
31.19
Concentration
Titanium
Parameter
Name of Analytical Laboratory
Number of Sampling Lines Used
Yes
EP 35 - Face Dryer Stage 1
OX-IR
1.08
1 / 2
Filter Housing Material
APPENDIX 2
Positioning of Filter
Borosilicate Glass
Parameter
Absorption Solution HPLC Grade Water
Parameter
Number of Sampling Points Used 1 / 12
Sample Point I.D.'s
10.11
±% v/v
37.09
Run 1
14.70
g/hr
Out Stack
14.70
6008.4
Impinger Material
Run 1
10.11
Blank 1
Probe Material
Parameter
±g/hr
Concentration mg/m³
Mass Emission
A3
Uncertainty
Analytical Laboratory's Procedure
Value
Mean
mg/m³ 37.09
Uncertainty
Borosilicate Glass
SAL
Date of Sample Analysis
Water Vapour % v/v
CAT-RT (Version BO)
Page 19 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 22 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
Total mass collected in impingers (silica trap) g
Total mass of liquid collected, Vlc
0.6534
15.62
Nozzle area, An 28.34
N/A
g
-
% v/v
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
10.11
% v/v
0.1011
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))
Average square root of velocity heads, √∆P
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
3563.6
N₂
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
m³
Vwstd = (0.001246)(Vlc)
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 28.84
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)
20.80
minTotal sampling time, q
27.75
% v/v
%
Volume of gas sample through gas meter, Vm
-
m³ N/A
0.06
79.14
% v/v N/A
N/A
-
Qa = (60)(As)(Vs) m³/min
Velocity of stack gas, Vs
Bwo = Vwstd / (Vmstd + Vwstd)
-
17.97
Area of stack, As
-
N/A
57.0
Velocity pressure coefficient, Cp
3.80
6.01Nozzle diameter, Dn
4.24
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
0.6666
Pitot tube velocity constant, Kp
N/A
No
2930.6
Conversion factor (K/mm.Hg), Cf
mm²
-
°C
Vmstw = (Vmstd)(100/(100 - Rwv))
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
mmHg
Average dry gas meter temperature, Tm
Ps = (Pb + (Pstatic / 13.6)
m³
% v/v N/A
53.0
Total
755.5
20.86
Average pressure drop across orifice, ∆H
17.3
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
% v/v
Stack static pressure, Pstatic
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)
0.0660
mmHg
Barometric pressure, Pb
Run 1
g
-Gas meter correction factor, Yd
mmH₂O
m³
CONDENSABLE VOCS: ISOKINETIC SAMPLING CALCULATIONS
43.3
761.3
-78.2
9.7
Test Units
0.9310
Total mass collected in impingers (liquid trap)
APPENDIX 2
mmH₂O
10.11
% v/v
% oxygen reference condition, REF%O₂
N/A
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
2634.4
m³/min N/A
m³
m³ 0.5873
% v/v
46.9
g/gmol
m³
% wet oxygen measured in gas stream, ACT%O₂w % v/v
% dry oxygen measured in gas stream, ACT%O₂d
m³/min
m³/min
m³/min
Average stack gas temperature, Ts
m²
0.3592
30
0.84
mmH₂O
√mmH₂O
mm
m/s
°C
34.97
99.7
Average of velocity heads, ∆Pavg
CAT-RT (Version BO)
Page 20 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 23 of 83
Sample Runs
-
-
-
-
-
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
-
-
-
-
µg/ml
27/07/2016
µg/ml
Parameter
Laboratory Result for Back Impinger
Parameter
67.00
Volume Sampled (REF)
Sampling Device
mg/m³
0.6534
ISO
246.7
09:20 - 09:50
Volume in Front Impingers
Run 1
-
Volume in Impingers ml
APPENDIX 2
m³
µg/ml
24232.4
Calculated Concentration mg/m³ 31.19
-
Laboratory Result for Impingers
µg
7703.5
Volume in Back Impinger ml
304.2
Units
Average Volume Sampled (REF)
Total Mass Collected
µg
108.5
Mass in Back Impinger
ml
67.00
71.00
µg
Mass in Front Impingers 16528.9
Laboratory Result for Front Impingers
Calculated Concentration
Blank Dates
20381.4
-
CONDENSABLE VOCS: SAMPLING DETAILS
Sampling Times
Sampling Dates
37.09
27/07/2016
Units
Total Mass Collected
m³ 0.6534
µg
-
Blank 1
CAT-RT (Version BO)
Page 21 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 24 of 83
Sample Runs
0 0 0 0
Run 1
Silica Gel (Concurrent Water Vapour)
Yes
-
% Yes
Units
-
Units
%
Run 1
Units
Test Conditions
Absorption Efficiency Acceptable
Allowable Leak Rate
99.7
%
%
l/min 0.14
Are Water Droplets Present
20.69
MU Acceptable
10.7
Isokinetic Criterion Compliance Units
95 - 115
Allowable MU
Run 1
Maximum Filter Temperature
Leak Test Acceptable -
Allowable Isokinetic Range %
150
Yes
MU (Concurrent Water Vapour)
Ambient Temperature Recorded?
Isokineticity Acceptable
Post-Sampling Leak Rate l/min
%
Less than 50% Faded
Run 1
N/A
°C
Yes
Pre-Sampling Leak Rate
Isokinetic Variation
N/A
Water Droplets
20
Measurement Uncertainty (MU)
Absorption Efficiency
Units
Yes
-
CONDENSABLE VOCS: QUALITY ASSURANCE
(PAGE 1 OF 2)
Leak Test Results Units
Run 1
Allowable Absorption Efficiency
% 68.2
-
Run 1
Run 1
%
Filter Temperatures
Units
No
0.41
APPENDIX 2
0.30
Mean Sampling Rate
Run 1Absorption Efficiency
l/min
Units
l/min
CAT-RT (Version BO)
Page 22 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 25 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
20.00Expected Sampling Rate l/min
APPENDIX 2
Pre-Sampling Leak Rate
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Allowable Leak Rate
Blank 1
10.0
Blank Acceptable - No
Ratio highest to lowest velocities between 3 and 5 : 1.
l/min 0.12
mg/m³
Validity of Blank vs ELV
0.40l/min
Nature of Deviation
Post-Sampling Leak Rate l/min
Units Blank 1
0.18
Allowable Blank
Units
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
Leak Test Acceptable - Yes
CONDENSABLE VOCS: QUALITY ASSURANCE(PAGE 2 OF 2)
Leak Test Results
CAT-RT (Version BO)
Page 23 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 26 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
N/A
Units Run 1
Overall MU For O₂ Measurement
Oxygen Correction Part of MU Budget
Measured Quantities
%
mg/m³
m³
mg/m³
%
0.5873
290.3
m³0.6666
0.5
0.69
1.00
-
% v/v N/A
% N/A
-
%
Sensitivity Coefficient
Vm
≤2%
0.3105
10.00
10.00
Measured Quantities
39.6
63.15
Run 1
≤1%
%
-
Measured Quantities
7.54
Units
Measured Quantities
mg/m³
% 0.50
1.00
mg/m³
Run 1
N/A
2.00
L
0.9724
Run 1
Tm
Symbol
CONDENSABLE VOCS: MEASUREMENT UNCERTAINTY CALCULATIONS
uVm
uTm K 2.0
mg/m³ 3.709
mg/m³
uHm
uρm
Run 1
0.0
%
% N/A
%
mg/m³ 3.709
14.70
Uncertainty in Result
% v/v
%
L
% 39.6
1.45
14.70mg/m³
mg/m³ N/A
Symbol
3.85
Uncertainty as a Percentage
20.3
Units
Symbol Units
Parameter Units Run 1
Run 1
No Requirement
Lr
Units
APPENDIX 2
1.0
Vm
Measured Quantities
-
Hm
mg/m³
1.00
Uncertainty in Measurement Units
0.311
%
uLr
0.0133
uL
ρm 100.7
Value Standard uncertainty
Run 1
1.45
≤1%
≤2%
Requirement of Standard
≤1%
%
kPa
Lr
CAT-RT (Version BO)
Page 24 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 27 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
1.15
0.1
Run 1
Impinger Material Borosilicate Glass
Concentration
0.1
Name of Analytical Laboratory RPS
mg/m³
Borosilicate Glass
Nitric Peroxide
Sample Point I.D.'s
Uncertainty
1.15
Maximum
0.0011
Absorption Solution
47mm Quartz Fibre
Uncertainty
EN 14385
ISO 17025 Accredited Analysis? Yes
Value
Date of Sample Analysis 09/08/2016
10.88
Units
M31
Number of Sampling Points Used
Out Stack
±% v/v
Filter Size and Material
±mg/m³
Filter Housing Material
Units
Number of Sampling Lines Used 1 / 1
Probe Material Titanium
0.0008
Parameter
Mean
Technical Procedure
Mean
% v/vWater Vapour
Parameter
0.0003
APPENDIX 2
Run 1
±g/hr
CADMIUM & THALLIUM: RESULTS SUMMARY
1 / 1
0.0011
Uncertainty
Mass Emission
0.0003
mg/m³
A3
Positioning of Filter
Analytical Laboratory's Procedure
Standard
CAT-TP-06
Units
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
10.88
Parameter
g/hr
0.0008
Parameter
0.2
Concentration
0.2
Blank 1
CAT-RT (Version BO)
Page 25 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 28 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Velocity of stack gas, Vs
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
Barometric pressure, Pb
Total mass collected in impingers (liquid trap)
Ps = (Pb + (Pstatic / 13.6)
47.0
mmH₂O 17.28
5.0
mmH₂O -78.2
m³/min
Nozzle diameter, Dn
Total sampling time, q
2877.9
Area of stack, As m² 3.80
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
Total mass of liquid collected, Vlc
Volume of gas sample through gas meter, Vm
Gas meter correction factor, Yd
Test
% wet oxygen measured in gas stream, ACT%O₂w % v/v
15.34
4.16
Conversion factor (K/mm.Hg), Cf
755.5
Total mass collected in impingers (silica trap)
g/gmol
N/A
% v/v
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
1.1309
No
m³/min
°C 21.4
m³
20.80
m³ 0.1381
min 60
mmHg
m/s
% v/v 10.88
m³
-
10.88
98.6
761.3
% oxygen reference condition, REF%O₂
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
Average stack gas temperature, Ts °C
g 105.8
mmHg
mm
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A
g/gmol
N/A
0.1088
Total
Stack static pressure, Pstatic
N₂
% v/v
79.14
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
Vmstw = (Vmstd)(100/(100 - Rwv))
28.84
m³/min
% v/v
0.84-
% v/v
m³
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
Run 1Units
APPENDIX 2
CADMIUM & THALLIUM: ISOKINETIC SAMPLING CALCULATIONS
Bwo = Vwstd / (Vmstd + Vwstd)
-
m³
g
Average pressure drop across orifice, ∆H mmH₂O
0.9310
g
110.8
N/A
20.86
1.3020
Average dry gas meter temperature, Tm
-
N/A
Nozzle area, An
34.97
% dry oxygen measured in gas stream, ACT%O₂d
m³
-
1.2690
N/A
28.34
% v/v
m³ N/A
N/A
% v/v
Average of velocity heads, ∆Pavg
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)
6.01
3499.6
-
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
Vwstd = (0.001246)(Vlc)
Velocity pressure coefficient, Cp
%
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
2564.8
mm²
N/A
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
Pitot tube velocity constant, Kp -
27.66
% v/v
0.06
0.3592
Qa = (60)(As)(Vs)
Average square root of velocity heads, √∆P √mmH₂O
57.0
CAT-RT (Version BO)
Page 26 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 29 of 83
Sample Runs
Cadmium
-
-
Mass in Back Impinger <
-
-
-
-
Thallium
-
<
Mass in Back Impinger <
-
-
-
-
Cadmium & Thallium Combined
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
Cadmium
<
<
Mass in Back Impinger <
<
<
<
Thallium
<
<
Mass in Back Impinger <
<
<
<
Cadmium & Thallium Combined
<
<
<
0.05
g/hr
µg
mg/m³
-
Calculated Concentration
µg
Total Mass Collected
10:35 - 11:35
0.0007
µg 0.50
Total Mass Collected
Mass in Front Impingers
0.0004
0.46
Calculated Concentration
Sampling Dates
Sampling Device
Total Mass Collected µg
Sampling Times
µg
Reported Concentration
0.0004
0.0004
0.55
µg
0.40
0.04
0.06
0.0008
m³
Run 1
µg
Units
0.89
Mass on Filter / in Rinse µg 0.80
0.01
1.2690
0.01
µg
Total Mass Collected
-
0.0011
mg/m³
mg/m³
0.0008
0.01
mg/m³
g/hr
Blank 1
0.11
Mass on Filter / in Rinse
µg 0.45
µg
0.04
CADMIUM & THALLIUM: SAMPLING DETAILS
mg/m³
Total Mass Collected µg
Calculated Concentration
mg/m³
ISO
Reported Concentration
Reported Concentration
Mass on Filter / in Rinse
Total Mass Collected µg
-
27/07/2016
Volume Sampled (REF)
27/07/2016
Reported Concentration
Mass in Front Impingers
APPENDIX 2
Mass Emission
m³
µg
mg/m³
Calculated Concentration
µg
mg/m³ 0.0004
µg
Average Volume Sampled (REF)
Mass in Front Impingers
Blank Dates -
Parameter
0.0011
Mass in Front Impingers
µg
Reported Concentration
Parameter
Units
0.01
0.08
0.0007
Mass Emission
mg/m³
Calculated Concentration
Reported Concentration mg/m³
0.0004
1.2690
0.99
Mass on Filter / in Rinse µg 0.40
mg/m³
Calculated Concentration mg/m³ 0.0004
1.35
CAT-RT (Version BO)
Page 27 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 30 of 83
Sample Runs
Units Run 1
%
Units
Units
Less than 50% Faded
Run 1
% Yes
Silica Gel (Concurrent Water Vapour)
Allowable Isokinetic Range
Exit Temperature Acceptable
l/min
- Yes
Maximum Temperature Recorded 18
% 95 - 115
µg/m³
Isokineticity Acceptable
Isokinetic Criterion Compliance
Maximum Filter Temperature °C
Run 1
- Yes
Yes
Measurement Uncertainty (MU) % 10.6
Isokinetic Variation
Units
180
98.6
Water Droplets Units
5
Run 1
°C
°C 30
Units Run 1
Ambient Temperature Recorded? Yes-
Allowable Detection Limit
-
Allowable Leak Rate
%
APPENDIX 2
0.40
l/min
MU (Concurrent Water Vapour)
Pre-Sampling Leak Rate l/min
20.20
%
20
Leak Test Results Run 1
0.4
Yes
(PAGE 1 OF 2)
µg/m³
Absorption Efficiency
Where the emissions are < 30% of the ELV, MID 14385 does not require the 90% absorption efficiency requirement to be applied
Allowable Absorption Efficiency
0.21
Filter Temperatures
Units Run 1
Units
Post-Sampling Leak Rate
Run 1
l/min
100.0
Run 1
N/A
0.16
Thallium % 100.0
-
Thallium
MU Acceptable
Absorption Efficiency Acceptable
%
-
µg/m³
Run 1
Units
Mean Sampling Rate
Allowable MU
Units
Detection Limit
Cadmium
Are Water Droplets Present
Detection Limit Acceptable
Impingers Exit Temperature
Cadmium
Maximum Allowable Temperature
Leak Test Acceptable
No
-
Test Conditions
N/A
0.4
%
Yes
CADMIUM & THALLIUM: QUALITY ASSURANCE
CAT-RT (Version BO)
Page 28 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 31 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
Allowable Blank
0.40
APPENDIX 2
Blank 1
Pre-Sampling Leak Rate l/min
Leak Test Acceptable
0.0050
Validity of Blank vs ELV Units
mg/m³
l/min 20.00Expected Sampling Rate
Allowable Leak Rate
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
Leak Test Results
Post-Sampling Leak Rate
0.20
Ratio highest to lowest velocities between 3 and 5 : 1.
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
-
0.18
l/min
Nature of Deviation Run Number
CADMIUM & THALLIUM: QUALITY ASSURANCE(PAGE 2 OF 2)
Yes
Yes
l/min
Units Blank 1
Blank Acceptable -
CAT-RT (Version BO)
Page 29 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 32 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
%
- N/A
Units Run 1
% -
m³
1.04 uL
Measured Quantities Requirement of Standard
%
≤1%0.68
2.00
≤2%
%
1.04
≤1%
% 1.00
Run 1
uLr % -
Tm 294.4
uρm
uVm
Run 1 Run 1
ρm
mg/m³ 0.0002
mg/m³ 0.0003
0.0003
L mg/m³ 0.0000
% v/v N/A
- N/A
Overall MU For O₂ Measurement % N/A
% 15.6
mg/m³
Uncertainty as a Percentage
%
Measured Quantities
Uncertainty in Result
Vm 1.3020
0.5
Hm 0.0
CADMIUM & THALLIUM: MEASUREMENT UNCERTAINTY CALCULATIONS
Symbol
Symbol Units
uTm
Uncertainty in Measurement Units
≤2%
≤1%
0.50
Measured Quantities Symbol
kPa
0.0260
Measured Quantities
m³ 0.00
Run 1
1.1309
Oxygen Correction Part of MU Budget
Units Run 1
%
7.50 No Requirement
Vm
K
L
100.7
Measured Quantities Units Run 1
1.00
Sensitivity Coefficient
Units
mg/m³
0.0001
% 30.5
mg/m³ 0.0001
mg/m³ 0.0000
mg/m³ N/A
mg/m³ 0.0000
% N/A
Parameter Units
% 30.5
Lr mg/m³ 0.0001 1.00
Run 1
Standard uncertainty
APPENDIX 2
uHm % v/v 1.0
2.0
Lr
Value
7.50
CAT-RT (Version BO)
Page 30 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 33 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
11.6Uncertainty
Units
Nitric Peroxide
Run 1
APPENDIX 2
Date of Sample Analysis
10.88
Uncertainty ±% v/v 1.15 1.15
Borosilicate Glass
Mass Emission g/hr
Blank 1
Mean
Concentration mg/m³
Maximum
Concentration mg/m³
% v/v
Number of Sampling Points Used 1 / 1
0.005
47mm Quartz Fibre
Parameter Units
09/08/2016
39.8
0.246
A3
Parameter
±g/hr
EN 14385
Mean
CAT-TP-06
0.246
Name of Analytical Laboratory RPS
Analytical Laboratory's Procedure M31
ISO 17025 Accredited Analysis? Yes
Titanium
Filter Housing Material Borosilicate Glass
Impinger Material
0.071
HEAVY METALS: RESULTS SUMMARY
Water Vapour
Out Stack
Filter Size and Material
10.88
Parameter
11.6
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
Probe Material
Sample Point I.D.'s
Technical Procedure
Absorption Solution
Positioning of Filter
Value
Parameter Units Run 1
0.005
0.071Uncertainty ±mg/m³
39.8
Number of Sampling Lines Used 1 / 1
Standard
CAT-RT (Version BO)
Page 31 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 34 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Velocity of stack gas, Vs
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
Average of velocity heads, ∆Pavg mmH₂O
Velocity pressure coefficient, Cp
17.28
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min
%
N/A
min 60
N/A
4.16
Average stack gas temperature, Ts °C
3.80
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
HEAVY METALS: ISOKINETIC SAMPLING CALCULATIONS
Test Units Run 1
Barometric pressure, Pb 761.3
Gas meter correction factor, Yd
N₂
-
g 110.8
g 5.0
% v/v
m³ 1.2690
m³/min
Vmstw = (Vmstd)(100/(100 - Rwv))
10.88% v/v
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) -
2564.8
Nozzle area, An mm² 28.34
Bwo = Vwstd / (Vmstd + Vwstd) m³
2877.9
98.6
Vwstd = (0.001246)(Vlc) m³
Total sampling time, q
N/A
-
47.0
% v/v
% wet oxygen measured in gas stream, ACT%O₂w
Conversion factor (K/mm.Hg), Cf
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s
m³/min N/AQstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)
-
Average dry gas meter temperature, Tm °C 21.4
Total mass collected in impingers (silica trap)
No
10.88
Total mass collected in impingers (liquid trap) g
Volume of gas sample through gas meter, Vm
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
N/A
15.34
Nozzle diameter, Dn mm 6.01
m²
0.06
57.0
Pitot tube velocity constant, Kp
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
-
0.1381
Total mass of liquid collected, Vlc
m³
0.1088
g/gmol 28.84
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol 27.66
N/A
- 0.84
N/A
Average square root of velocity heads, √∆P √mmH₂O
Qa = (60)(As)(Vs) m³/min 3499.6
Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
- 0.3592
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
20.86
20.80
mmHg 755.5
Total % v/v
mmHg
0.9310
% oxygen reference condition, REF%O₂
1.3020
105.8
mmH₂O
m³
% dry oxygen measured in gas stream, ACT%O₂d % v/v
% v/v
APPENDIX 2
% v/v 79.14
% v/v
m³/min
Stack static pressure, Pstatic mmH₂O -78.2
N/A
Area of stack, As
Ps = (Pb + (Pstatic / 13.6)
% v/v N/A
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 1.1309
Average pressure drop across orifice, ∆H
34.97
CAT-RT (Version BO)
Page 32 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 35 of 83
Sample Runs
Arsenic
-
-
Mass in Back Impinger <
-
-
-
-
Cobalt
<
<
Mass in Back Impinger <
<
<
<
<
Chromium
-
-
Mass in Back Impinger -
-
-
-
-
Copper
-
-
Mass in Back Impinger -
-
-
-
-
Manganese
-
-
Mass in Back Impinger <
-
-
-
-
Reported Concentration
Volume Sampled (REF)
µg
Total Mass Collected µg 0.56
mg/m³
0.0004
Mass on Filter / in Rinse µg
µg
Units Run 1
Mass on Filter / in Rinse µg
mg/m³ 0.0143
0.07
0.0185
0.0185
Mass in Front Impingers µg 6.86
0.50
Reported Concentration mg/m³ 0.0033
Mass on Filter / in Rinse µg
Mass in Front Impingers µg 0.05
µg
108.00
11.00
4.17Total Mass Collected
Mass Emission
m³ 1.2690
HEAVY METALS: SAMPLING DETAILS
Parameter
0.0033Calculated Concentration mg/m³
0.01
Calculated Concentration mg/m³
Sampling Times
27/07/2016
µg 0.15
Sampling Device - ISO
0.53
Sampling Dates
APPENDIX 2
(PAGE 1 OF 5)
-
4.00
- 10:35 - 11:35
Mass on Filter / in Rinse µg
Mass in Front Impingers
µg
g/hr
Mass Emission
Mass on Filter / in Rinse
µg 0.25
µg
108.26
mg/m³
mg/m³ 0.0004
Mass Emission g/hr 2.99
3.00
0.25
Calculated Concentration
20.32
Mass Emission
µg
Mass in Front Impingers
mg/m³
g/hr
Calculated Concentration
Total Mass Collected µg 23.42
Reported Concentration
µg
mg/m³ 0.0143
Mass in Front Impingers
µg
µg 18.11Total Mass Collected
0.10
0.02
2.31
µgTotal Mass Collected
0.01
Reported Concentration
Calculated Concentration
Mass Emission
Reported Concentration mg/m³
g/hr
g/hr
0.0853
0.0853
13.82
CAT-RT (Version BO)
Page 33 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 36 of 83
Sample Runs (continued)
Nickel
-
-
Mass in Back Impinger <
-
-
-
-
Lead
-
-
Mass in Back Impinger -
-
-
-
-
Antimony
-
<
Mass in Back Impinger <
-
-
-
-
Vanadium
<
<
Mass in Back Impinger <
<
<
<
<
Total Mass Collected
µg 0.25
µgTotal Mass Collected
0.0063
mg/m³
µg
mg/m³
1.06
Run 1
0.1164
18.86
µg
Mass on Filter / in Rinse
g/hr 1.02
0.03
µg 0.01
µg
mg/m³
Mass on Filter / in Rinse
Calculated Concentration
µg
147.76
Mass in Front Impingers
Mass Emission
0.01
mg/m³
0.05
0.40
Mass on Filter / in Rinse µg
0.0003
Calculated Concentration
g/hr
µg
0.14
Mass in Front Impingers
Mass Emission
Reported Concentration
Total Mass Collected
Mass Emission g/hr
0.0008
µg
Mass Emission g/hr
mg/m³
1.00
Calculated Concentration
0.0008
0.05
µg
Mass in Front Impingers
mg/m³
Total Mass Collected
Units
µg 7.00
0.51
µg 147.00
µg 0.43
Calculated Concentration 0.0063
Reported Concentration
8.03
Parameter
APPENDIX 2
HEAVY METALS: SAMPLING DETAILS(PAGE 2 OF 5)
Mass in Front Impingers µg
Mass on Filter / in Rinse
Reported Concentration
1.02
0.01
0.1164
Reported Concentration
0.0003
mg/m³
µg
mg/m³
CAT-RT (Version BO)
Page 34 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 37 of 83
Sample Runs (continued)
Heavy Metals Combined
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
Arsenic
<
<
Mass in Back Impinger <
<
<
<
Cobalt
<
<
Mass in Back Impinger <
<
<
<
m³
Total Mass Collected
µg
Calculated Concentration 0.0004
Mass in Front Impingers µg
µg
Mass on Filter / in Rinse µg
µg
Average Volume Sampled (REF)
0.50
Mass on Filter / in Rinse
0.06
311.80
mg/m³
Blank Dates
1.2690
mg/m³
- 27/07/2016
µg
APPENDIX 2
(PAGE 3 OF 5)
Parameter
Total Mass Collected
HEAVY METALS: SAMPLING DETAILS
0.57
Run 1
mg/m³
UnitsParameter
Reported Concentration
mg/m³
0.50
0.01
0.0004
0.0004
0.02
Calculated Concentration 0.2457
µg
0.04
0.55Total Mass Collected
Reported Concentration
0.2457
µg
µg
Mass in Front Impingers
0.0004mg/m³
Units Blank 1
Reported Concentration
Calculated Concentration mg/m³
CAT-RT (Version BO)
Page 35 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 38 of 83
Blank Runs (continued)
Chromium
<
-
Mass in Back Impinger -
-
-
-
Copper
<
-
Mass in Back Impinger -
-
-
-
Manganese
-
<
Mass in Back Impinger <
-
-
-
Nickel
<
<
Mass in Back Impinger <
<
<
<
Lead
<
-
Mass in Back Impinger -
-
-
-
Antimony
<
<
Mass in Back Impinger <
<
<
<
Vanadium
<
<
Mass in Back Impinger <
<
<
<
0.0005
0.59
Mass in Front Impingers
Mass in Front Impingers µg
mg/m³
0.0003
0.0014
mg/m³
Mass in Front Impingers
Mass on Filter / in Rinse
0.0005
mg/m³
Reported Concentration
mg/m³
µg
0.42
µg
Mass on Filter / in Rinse
µg
Calculated Concentration
0.02
0.0005
HEAVY METALS: SAMPLING DETAILS
mg/m³
Reported Concentration
mg/m³
µg
mg/m³
Mass on Filter / in Rinse
mg/m³
Calculated Concentration
0.07
µg
µg
µg
Calculated Concentration
0.0008
0.04
Reported Concentration
0.40
Total Mass Collected
mg/m³
mg/m³
0.65
0.0005
Reported Concentration mg/m³ 0.0004
µgMass on Filter / in Rinse
0.0004
0.50
Total Mass Collected
Total Mass Collected
Reported Concentration
0.0008
0.04
0.0005
µg
0.60
mg/m³
mg/m³
µg
µg
0.65
µg 0.50
0.0005
µg
µg
0.55
µg 0.18
0.21
0.60
0.01
µg
µg
mg/m³
0.02
Total Mass Collected
Calculated Concentration 0.0003
Mass in Front Impingers
µg
0.01
0.01
0.60
Mass on Filter / in Rinse
Total Mass Collected
µg
APPENDIX 2
µg 1.73
0.99
µg
0.60
Calculated Concentration
0.0014
Mass in Front Impingers
Calculated Concentration
Reported Concentration
µg
1.10
0.01
Total Mass Collected
Units Blank 1
Mass on Filter / in Rinse
Mass in Front Impingers µg 0.04
µg
µg
Calculated Concentration
Mass in Front Impingers µg
µg
0.03
Mass on Filter / in Rinse
(PAGE 4 OF 5)
Parameter
Total Mass Collected
Reported Concentration
CAT-RT (Version BO)
Page 36 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 39 of 83
Blank Runs (continued)
Heavy Metals Combined
-
-
-
Units Blank 1
Calculated Concentration
0.0053
(PAGE 5 OF 5)
Parameter
APPENDIX 2
µg
HEAVY METALS: SAMPLING DETAILS
mg/m³ 0.0053
6.70
Reported Concentration mg/m³
Total Mass Collected
CAT-RT (Version BO)
Page 37 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 40 of 83
Sample Runs
0.4
% N/A <1% Total
% N/A <1% Total
100.0
-
0.4
% 10.6
Arsenic
µg/m³
Chromium
Absorption Efficiency Units Run 1
Vanadium
Detection Limit
Absorption Efficiency Acceptable
µg/m³
20
Pre-Sampling Leak Rate
% N/A <1% Total
Cobalt
0.4
Run 1
90
Units
µg/m³
Units
Run 1
Allowable Detection Limit
MU (Concurrent Water Vapour)
MU Acceptable % Yes
Units
%
Mean Sampling Rate
98.6
%
Nickel
Lead
Chromium %
Arsenic
l/min 0.40
l/min
- Yes
Nickel %
(PAGE 1 OF 2)
Copper %
100.0
Manganese
0.5
HEAVY METALS: QUALITY ASSURANCE
99.6
% 100.0
l/min 20.20
0.21
0.16
0.3
Antimony µg/m³ 0.5
Leak Test Results Units
Post-Sampling Leak Rate l/min
Cobalt
Leak Test Acceptable
Allowable Absorption Efficiency
Antimony
Allowable Leak Rate
µg/m³
µg/m³
0.5
99.8
%
0.6
Lead
0.5
Copper
Yes
APPENDIX 2
µg/m³
Water Droplets
µg/m³
Manganese
Vanadium µg/m³
µg/m³
Run 1
Detection Limit Acceptable -
Measurement Uncertainty (MU)
Run 1
5
Are Water Droplets Present - No
Yes
Allowable MU %
CAT-RT (Version BO)
Page 38 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 41 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
APPENDIX 2
18
% 98.6
Less than 50% Faded %
°C
Allowable Isokinetic Range
Yes
Pre-Sampling Leak Rate
Leak Test Acceptable
Ambient Temperature Recorded?
Allowable Blank mg/m³
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
0.0500
Nature of Deviation Run Number
Run 1Test Conditions Units
Allowable Leak Rate
Silica Gel (Concurrent Water Vapour) Units Run 1
30
Isokinetic Criterion Compliance
Isokinetic Variation
%
HEAVY METALS: QUALITY ASSURANCE
20.00
- Yes
°C 180
Impingers Exit Temperature Units Run 1
Filter Temperatures Units
Units Run 1
95 - 115
(PAGE 2 OF 2)
Blank 1
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Ratio highest to lowest velocities between 3 and 5 : 1.
Units
Yes
Isokineticity Acceptable - Yes
Expected Sampling Rate
0.18
Maximum Filter Temperature
Leak Test Results
Post-Sampling Leak Rate
l/min
Run 1
Maximum Allowable Temperature
-
Blank Acceptable -
0.20
l/min
Maximum Temperature Recorded °C
0.40
Yes
Exit Temperature Acceptable
l/min
l/min
- Yes
Units Blank 1
Validity of Blank vs ELV
CAT-RT (Version BO)
Page 39 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 42 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
28.7
1.00Lr mg/m³ 0.0172
% 1.00
L
0.0362
2.00
Measured Quantities
mg/m³
Units
0.0065
mg/m³ 0.0184
% 28.7
% 14.7
1.04
- N/A
mg/m³
% N/A
% v/v N/A
mg/m³ 0.0705
L 1.04
0.50
Symbol Units Run 1
mg/m³
≤2%
%
Symbol
Requirement of Standard
%
Measured Quantities Units
APPENDIX 2
Run 1
Run 1
mg/m³
%
Tm 294.4
1.0
m³
Lr 7.00
uTm K
0.0260
0.0015 1.00
0.0015
mg/m³
mg/m³
Parameter Units Run 1
HEAVY METALS: MEASUREMENT UNCERTAINTY CALCULATIONS
Value Standard uncertainty
Measured Quantities Symbol
0.68
- N/A
m³
N/A
Uncertainty in Result
Oxygen Correction Part of MU Budget
1.1309
mg/m³
uL %
≤1%
%
Uncertainty as a Percentage
≤1%
Run 1
0.0705
-
≤2%
% 7.00
Run 1
Uncertainty in Measurement Units Sensitivity Coefficient
≤1%
No Requirement
N/A
%
uLr
Run 1Units
Vm 1.3020
Overall MU For O₂ Measurement
Measured Quantities
0.5
Run 1
0.0
ρm 100.7 uρm kPa
2.0
uHm % v/v
0.22
uVm
% -
%
Vm
0.0172
Measured Quantities Units
Hm
CAT-RT (Version BO)
Page 40 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 43 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
Uncertainty
Water Vapour % v/v 10.88
Uncertainty ±% v/v
±g/hr 0.0
Mean
Units
Filter Housing Material Borosilicate Glass
0.0001
10.88
Impinger Material
Medite Europe Ltd, Clonmel
Parameter Units
Probe Material Titanium
1.15
Name of Analytical Laboratory RPS
Analytical Laboratory's Procedure M112
0.0
APPENDIX 2
MERCURY: RESULTS SUMMARY
0.0002
Uncertainty ±mg/m³ 0.0001
Parameter
Blank 1
Parameter Units Run 1
0.0001
Parameter
ISO 17025 Accredited Analysis?
Absorption Solution Nitric Peroxide & Potassium Dichromate
1 / 1
Mass Emission
1.15
Technical Procedure CAT-TP-06
Number of Sampling Lines Used 1 / 1
0.0
Mean
Standard
Concentration mg/m³ 0.0001
A3
EP 35 - Face Dryer Stage 1
MID 14385
Value
Borosilicate Glass
0.0
Out Stack
Run 1
Number of Sampling Points Used
Maximum
g/hr
Concentration mg/m³ 0.0002
Positioning of Filter
Filter Size and Material 47mm Quartz Fibre
Date of Sample Analysis 09/08/2016
Sample Point I.D.'s
Yes
CAT-RT (Version BO)
Page 41 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 44 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Velocity of stack gas, Vs
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
% wet oxygen measured in gas stream, ACT%O₂w % v/v
Ps = (Pb + (Pstatic / 13.6)
110.8
755.5
°C
Area of stack, As 3.80
4.16
10.88
1.3020
Barometric pressure, Pb
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
57.0
% v/v
%
Velocity pressure coefficient, Cp
m³/min
mmHg
0.3592
N₂
% v/v
Average pressure drop across orifice, ∆H
Volume of gas sample through gas meter, Vm m³
mmHg 761.3
% v/v
Total mass of liquid collected, Vlc g
Vwstd = (0.001246)(Vlc) m³ 0.1381
APPENDIX 2
m²
% v/v N/A
20.86
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³
Bwo = Vwstd / (Vmstd + Vwstd)
79.14
1.2690
g/gmol
Run 1
mm 6.01
N/A
Nozzle diameter, Dn
28.34Nozzle area, An mm²
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min
Average of velocity heads, ∆Pavg
m³/min
Total sampling time, q min 60
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)
Average stack gas temperature, Ts
m³/min N/A
-
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
% oxygen reference condition, REF%O₂
0.1088
mmH₂O
% v/v
mmH₂O
10.88
N/A
0.84
Units
34.97
m³
-
N/A
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
Average dry gas meter temperature, Tm °C 21.4
Vmstw = (Vmstd)(100/(100 - Rwv)) m³
% dry oxygen measured in gas stream, ACT%O₂d
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
% v/v
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
- No
- N/A
N/A
m³
Conversion factor (K/mm.Hg), Cf
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
m³
2877.9
m³/min 3499.6
17.28
20.80
√mmH₂O
Qa = (60)(As)(Vs)
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s
98.6
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
2564.8
Average square root of velocity heads, √∆P
Gas meter correction factor, Yd - 0.9310
N/A
15.34
27.66
% v/v
N/A
0.06
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -
47.0
Total mass collected in impingers (liquid trap) g 105.8
Total mass collected in impingers (silica trap) g 5.0
Pitot tube velocity constant, Kp -
g/gmol 28.84
1.1309
% v/v
Total
Stack static pressure, Pstatic mmH₂O -78.2
MERCURY: ISOKINETIC SAMPLING CALCULATIONS
Test
CAT-RT (Version BO)
Page 42 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 45 of 83
Sample Runs
<
-
Mass in Final Impinger -
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
<
<
Mass in Final Impinger <
<
<
<
0.0002
0.03
ISO
µg 0.04
mg/m³
MERCURY: SAMPLING DETAILS
Parameter Units
mg/m³ 0.0001
1.2690
-
Units Blank 1
Mass in Front Impinger/s
Total Mass Collected
Sampling Device
Volume Sampled (REF)
m³
µg
µg
m³
Reported Concentration
Mass in Front Impinger/s
µg
Calculated Concentration
10:35 - 11:35
Blank Dates -
Reported Concentration
0.02
Total Mass Collected
Mass on Filter / in Rinse
0.13
27/07/2016
Average Volume Sampled (REF)
27/07/2016
Calculated Concentration
Sampling Dates
µg 0.03
mg/m³ 0.0002
Run 1
0.29
1.2690
Parameter
APPENDIX 2
µg
Sampling Times -
µg
-
0.22
Mass on Filter / in Rinse
µg 0.18
mg/m³ 0.0001
CAT-RT (Version BO)
Page 43 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 46 of 83
Sample Runs
Maximum Filter Temperature
Ambient Temperature Recorded?
µg/m³ 2.0
Yes
Run 1
Allowable Absorption Efficiency
Units
Units Run 1
MU (Concurrent Water Vapour)
Units
Yes
% 98.6
Run 1
Absorption Efficiency
180
Maximum Allowable Temperature
Maximum Temperature Recorded
°C 30
Allowable Isokinetic Range
Allowable MU
- Yes
Where the emissions are < 30% of the ELV, MID 14385 does not require the 95% absorption efficiency requirement to be applied
Run 1
Filter Temperatures
MERCURY: QUALITY ASSURANCE
Leak Test Acceptable
-
Silica Gel (Concurrent Water Vapour)
Isokinetic Variation
Less than 50% Faded
%
Impingers Exit Temperature
10.6
Units Run 1
Absorption Efficiency Acceptable
Concentration Acceptable
Are Water Droplets Present
°C 18
Units Run 1
% 95 - 115
Measurement Uncertainty (MU)
-
0.03
UnitsWater Droplets
Units Run 1
Run 1
- Yes
Run 1
Run 1
-
Units
Concentration in Final Impinger
Pre-Sampling Leak Rate l/min 0.16
No
0.40
86.1
Leak Test Results
Units
%
Allowable Concentration
Isokineticity Acceptable
µg/m³Concentration in Final Impinger
Exit Temperature Acceptable - Yes
MU Acceptable % Yes
20.20
Absorption Efficiency
%
°C
APPENDIX 2
Mean Sampling Rate l/min
l/min
%
-
Units
(PAGE 1 OF 2)
Post-Sampling Leak Rate
Allowable Leak Rate
% 20
Yes
l/min 0.21
N/A
Test Conditions
N/A
Isokinetic Criterion Compliance
CAT-RT (Version BO)
Page 44 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 47 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
20.00
Allowable Leak Rate l/min
Validity of Blank vs ELV
-
l/min
0.0050
Leak Test Acceptable
0.40
Yes
Blank Acceptable
APPENDIX 2
MERCURY: QUALITY ASSURANCE(PAGE 2 OF 2)
l/min
Blank 1
Allowable Blank mg/m³
0.20
Nature of Deviation
Post-Sampling Leak Rate l/min
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
Ratio highest to lowest velocities between 3 and 5 : 1.
Leak Test Results Units
Units
0.18
Yes-
Blank 1
Pre-Sampling Leak Rate
Expected Sampling Rate
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
CAT-RT (Version BO)
Page 45 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 48 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Run 1
uρm kPa 0.5
25.2
%
Uncertainty in Result
25.2
Run 1
1.00L
mg/m³
Measured Quantities Units
% N/A
N/A-
Oxygen Correction Part of MU Budget
uL %
Hm
Measured Quantities Symbol Symbol
Standard uncertainty
1.3020
Tm
%
%
0.00002mg/m³
No Requirement
Measured Quantities Units Run 1
%
mg/m³ 0.00001
Vm
Units Run 1
mg/m³ 0.0001
Overall MU For O₂ Measurement % N/A
mg/m³
N/A
0.0260uVm m³
0.00
0.00001
0.000001
294.4 uTm K
0.000001
12.9
Measured Quantities
% v/v
0.00001
mg/m³
mg/m³
Run 1
- N/A
1.00
1.04
uHm
0.0001
%
1.1309
≤2%
≤1%
% 0.50
1.00
Run 1
Lr
≤1%
%
mg/m³
%
mg/m³
m³
Measured Quantities Units
Units
uLr
0.0
Lr 6.00
0.00003
1.04
6.00
≤2%
Uncertainty in Measurement Units Sensitivity Coefficient
Symbol
2.00
ρm
Uncertainty as a Percentage
APPENDIX 2
mg/m³
% v/v N/A
-
1.0
0.68
Parameter
100.7
Units Run 1
Run 1
L
2.0
Value
%
≤1%
Requirement of Standard
MERCURY: MEASUREMENT UNCERTAINTY CALCULATIONS
% -
Vm
CAT-RT (Version BO)
Page 46 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 49 of 83
Sample Runs (UPPER NATO I-TEQ)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Humans / Mammals)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Fish)
- -
- -
- -
- -
- -
Sample Runs (UPPER WHO TEQ Birds)
- -
- -
- -
- -
- -
Uncertainty
Uncertainty
ng/m³
Parameter
0.0016
µg/hr 0.3
APPENDIX 2
ng/m³ 0.0018 0.0018
Parameter Units
Mass Emission
0.0020
0.0007
DIOXINS & FURANS: RESULTS SUMMARY
Medite Europe Ltd, Clonmel
0.0016
(PAGE 1 OF 4)
Uncertainty ±ng/m³ 0.0007
EP 35 - Face Dryer Stage 1
Parameter Units
Concentration ng/m³
0.0008
Mass Emission
±ng/m³
Parameter Units
0.1
Concentration ng/m³ 0.0017
0.3
Uncertainty ±µg/hr 0.1
0.0017
Uncertainty
Run 1 Mean
NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.
µg/hr 0.3
Run 1
Mean
0.0020
0.3
Uncertainty ±µg/hr 0.1 0.1
Run 1
Uncertainty ±µg/hr
Concentration
Units Run 1
0.7
0.1
0.0007
Mass Emission µg/hr 0.3 0.3
TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)
Uncertainty ±µg/hr 0.1
Concentration
Mass Emission µg/hr 0.7
0.0041 0.0041
±ng/m³
Mean
±ng/m³ 0.0007
Mean
0.30.3
0.0008
CAT-RT (Version BO)
Page 47 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 50 of 83
Sample Runs (LOWER NATO I-TEQ)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Humans / Mammals)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Fish)
- -
- -
- -
- -
- -
Sample Runs (LOWER WHO TEQ Birds)
- -
- -
- -
- -
- -
Run 1
Uncertainty
Uncertainty
Parameter
Mean
Parameter
Concentration ng/m³
±µg/hr 0.1
µg/hr 0.7
Run 1
0.1 0.1
0.0018
Run 1
0.1
±ng/m³
0.0017
Uncertainty
0.0008
0.0020
Uncertainty
Mean
0.0007
APPENDIX 2
Mass Emission µg/hr 0.3
Uncertainty ±µg/hr
NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.
0.3
NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.
Concentration ng/m³
0.1
µg/hr
±µg/hr 0.1
0.3
Units
Concentration ng/m³ 0.00410.0041
Concentration ng/m³ 0.0018
Uncertainty ±ng/m³
Mass Emission
DIOXINS & FURANS: RESULTS SUMMARY
0.0016
Uncertainty
Mean
Mass Emission
Parameter Units
±ng/m³ 0.0007
(PAGE 2 OF 4)
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
TEQ2 - LOWER LIMITS (best case where <LOD = 0)
0.0008
0.0020
±ng/m³
0.7
Uncertainty ±µg/hr 0.3
0.0016
Units
Mass Emission
Run 1
0.0007
NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.
Parameter Units
0.3
0.0017
Mean
0.3
0.3
0.0007
NOTE: Where the maximum Blank concentration is higher than the Sample concentration, the Blank concentration has been reported.
µg/hr 0.3
CAT-RT (Version BO)
Page 48 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 51 of 83
Blank Runs (UPPER NATO I-TEQ)
- -
- -
Blank Runs (UPPER WHO TEQ Humans / Mammals)
- -
- -
Blank Runs (UPPER WHO TEQ Fish)
- -
- -
Blank Runs (UPPER WHO TEQ Birds)
- -
- -
Blank Runs (LOWER NATO I-TEQ)
- -
- -
Blank Runs (LOWER WHO TEQ Humans / Mammals)
- -
- -
Blank Runs (LOWER WHO TEQ Fish)
- -
- -
Blank Runs (LOWER WHO TEQ Birds)
- -
- -
0.0041
DIOXINS & FURANS: RESULTS SUMMARY(PAGE 3 OF 4)
Units
0.0017
ng/m³
0.0018
Maximum
Medite Europe Ltd, Clonmel
ng/m³
0.0041
Parameter
TEQ2 - LOWER LIMITS (best case where <LOD = 0)
Parameter Blank 1
Concentration ng/m³ 0.0018
Concentration
ng/m³ 0.0041
Units
Units Blank 1
Blank 1 Maximum
Blank 1
Parameter
0.0017
ng/m³
Maximum
Concentration
0.0020
0.0018
Parameter Units
0.0041
Maximum
0.0017
Concentration
0.0020 0.0020
0.0020
Units Maximum
Concentration
Blank 1
Concentration
Concentration
Maximum
Parameter
Units Blank 1
ng/m³
ng/m³
0.0018
Concentration ng/m³ 0.0017
APPENDIX 2
Parameter Units Blank 1
Parameter Maximum
EP 35 - Face Dryer Stage 1
Maximum
TEQ1 - UPPER LIMITS (worst case where <LOD = LOD)
Parameter Units Blank 1
CAT-RT (Version BO)
Page 49 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 52 of 83
- -
- -
- -
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
Number of Sampling Lines Used 1 / 2
Date of Sample Analysis
1.06
EN 1948
1.06
Filter Housing Material Borosilicate Glass
Water Vapour % v/v
(PAGE 4 OF 4)
Medite Europe Ltd, Clonmel
APPENDIX 2
Technical Procedure CAT-TP-07
Name of Analytical Laboratory SAL
B3
90mm Quartz Fibre
Parameter Value
Borosilicate Glass
Uncertainty ±% v/v
Analytical Laboratory's Procedure
EP 35 - Face Dryer Stage 1
16/08/2016
DIOXINS & FURANS: RESULTS SUMMARY
Mean
9.51
XAD-2
Yes
Number of Sampling Points Used
SOP 1C
9.51
Parameter Units Run 1
Probe Material Titanium
Glassware Material
Out Stack
Filter Size and Material
ISO 17025 Accredited Analysis?
Absorption Material
Standard
Positioning of Filter
Sample Point I.D.'s
1 / 12
CAT-RT (Version BO)
Page 50 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 53 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
Average square root of velocity heads, √∆P
18.32
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min
Velocity of stack gas, Vs
Conversion factor (K/mm.Hg), Cf
N/A
48.0
N/A
Stack static pressure, Pstatic
APPENDIX 2
DIOXINS & FURANS: ISOKINETIC SAMPLING CALCULATIONS
Ps = (Pb + (Pstatic / 13.6)
-78.2
Total mass collected in impingers (silica trap)
g
0.3592
Total mass of liquid collected, Vlc
min
N/A
0.84
Vmstw = (Vmstd)(100/(100 - Rwv))
% v/v 9.51
m³/min
15.76
28.34
591.7
7.7542
Total sampling time, q
Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³
% v/v 0.06
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol
√mmH₂O
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min
g
Average pressure drop across orifice, ∆H
N₂ % v/v
N/A
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
28.84
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
Test
35.9g
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
m³
Barometric pressure, Pb mmHg 761.3
Average dry gas meter temperature, Tm
Volume of gas sample through gas meter, Vm
mmHg
Bwo = Vwstd / (Vmstd + Vwstd)
Qa = (60)(As)(Vs)
Velocity pressure coefficient, Cp -
2674.4
% oxygen reference condition, REF%O₂ % v/v N/A
% dry oxygen measured in gas stream, ACT%O₂d % v/v
°C
% v/v
Total % v/v 20.86
No
% wet oxygen measured in gas stream, ACT%O₂w
Vwstd = (0.001246)(Vlc) m³ 0.7373
m³ 0.0951
Units Run 1
7.0169
Gas meter correction factor, Yd - 0.9310
555.8
27.81
mmH₂O
Total mass collected in impingers (liquid trap)
m³ 8.1511
% v/v
-
mmH₂O
N/A
755.5
-
24.1
N/A
mmH₂OAverage of velocity heads, ∆Pavg
- 34.97
4.28
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) m/s
20.80
-
Nozzle area, An
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
m³ N/A
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) % 97.8
Area of stack, As m²
Pitot tube velocity constant, Kp
79.14
3593.9
3.80
-
N/A
% v/v
Average stack gas temperature, Ts °C 57.0
360
mm²
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³
9.51
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min
Nozzle diameter, Dn mm 6.01
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273) m³/min 2955.4
CAT-RT (Version BO)
Page 51 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 54 of 83
Where: ISO stands for Manual Isokinetic Sampling Train
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HPeCDD
OCDD
Total Dioxins
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HPeCDF
1234789-HPeCDF
OCDF
Total Furans
Totals
Total Concentration
Limit of Detection
Where: ND stands for Non Detected
DL stands for Analytical Detection Limit
TEQ1 refers to Non Detected Congeners at the Detection Limit
TEQ2 refers to Non Detected Congeners at Zero
% Rec stands for the Recovery Percentage of the Sample
-
- 0.0014
-
-
0.0003
0.0017
0.0003
0.0001
0.0080
0.0080
0.0109
0.0014
0.0003
-
0.0042
0.0003
113
127
- -
0.000001
0.0003
0.0028
0.000001
0.0002
-0.0030
ng
ng
-
- 0.0012
0.0075
-
0.0003
-
0.0001
0.000002
0.0022
0.0050
0.0050
-
0.0001
0.0001
0.0096
0.0001
0.000001
0.0028
0.0075
0.0003
ng
780.0030
0.0022
0.0022
0.0030
0.0002
0.0000
0.0001
99
0.0030
0.0020
0.00300.0030
0.0020
0.0003
0.0003
0.0003
0.0030
0.0003
0.0003
0.0003
TEQ2 TEQ1
0.0003
0.0050
0.00002
0.00001
11:00 - 17:00Sampling Times
Sampling Dates
Sampling Device
0.000008
0.0004
0.0003
0.000002
0.0051
0.0019
0.0020
0.0030
0.0540
0.0030 0.0030
0.0030
0.000008
0.0020
0.0039 0.0047
0.0002
0.0002
0.0001
0.0003
0.0001
0.0015
0.0001
96
0.0047 0.0149
0.0080 0.000001
0.0022
0.0003
1230.0080
0.0015
0.0022
0.0050
0.000001
0.0003
0.0003
ng
0.0002
-
0.0011
0.0030
Units
-
0.0012
0.00420.0216
0.0020
0.0003
0.0055
0.0003
0.0050
0.0055
0.0003
0.0003
0.0002
ng/m³
0.0051 0.0039
0.0012
0.0093
0.0012
0.0093 0.0202
0.0026
0.0096
0.0012
RUN 1
0.000001
ng
ng
0.0030
0.0001
0.000002
0.0020
0.0003
0.0003
0.0001
0.0001
0.0020
0.00002
0.0001
0.0008
0.0003
0.0001
-
-
0.0061ng
0.000005
TEQ1
Parameter
0.00002
0.0003
0.0030
0.0011
0.0002
0.0003
0.00002
0.00001
TEQ2TEQ2
0.0008
26/07/2016
Volume Sampled (REF) m³
Value
ng
0.0001
0.0030
0.0055
7.7542
NATO
I-TEQ
WHO Humans /
Mammals
WHO
Fish
WHO
Birds
DL TEQ1 TEQ2Parameter Units Result
APPENDIX 2
ISO
TEQ1
-ng
0.0022
ng
0.0004
0.0055
0.0002
ng
0.00020.0002
0.0003
ng
0.0005
0.0008
0.0001
0.0000
0.0001
0.000005
0.0003
0.0028
0.0003
0.0003
-
100
121
106
109
0.0149
0.0003
DIOXINS & FURANS: SAMPLING DETAILS
0.0020
0.0075
0.0050ng
78
75
0.0030
0.0021
0.0002
0.0001
0.0002
0.0054 0.0054
0.000001
0.0002
0.00001
0.0028
0.0109
0.0014
ng
ng
0.0003
0.0002
0.00001ng
ng
0.0061
0.0080
0.0003
0.0002
0.000002
-
0.0020
% Rec
0.0001
0.0003
0.0057 0.0057
0.0008
0.0001
0.000001
0.0020
0.0002
0.0017
0.0001
116
0.0011
ng
ng
- -
ng 0.0756 0.0202
0.0026
ng/m³ -
0.00010.0080
0.0005
CAT-RT (Version BO)
Page 52 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 55 of 83
Where: ISO stands for Manual Isokinetic Sampling Train
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HPeCDD
OCDD
Total Dioxins
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HPeCDF
1234789-HPeCDF
OCDF
Total Furans
Totals
Total Concentration
Where: ND stands for Non Detected
DL stands for Analytical Detection Limit
TEQ1 refers to Non Detected Congeners at the Detection Limit
TEQ2 refers to Non Detected Congeners at Zero
% Rec stands for the Recovery Percentage of the Sample
BLANK 1
0.00002
0.0006
0.0006 0.0006
0.0058
0.0005 0.0005 0.0005
TEQ2 TEQ1TEQ2
Sampling Device -
0.0135 0.0135
-
-
0.0050
0.00200.0020
ng 0.0050 0.00050.0005
0.0035
-
0.0001
0.0018 0.0018
Parameter Units Result
0.000008
0.0080
ng
0.00002
0.00001
0.0020
0.0001 0.0001 0.0001
0.000001
0.0001
0.0060
0.0005
TEQ1
Parameter
0.0062 0.0065
0.0002
0.0073
0.0141 0.0141
0.0008 0.0008 0.0008
ISO
WHO
Fish
% RecDL
0.00330.0020
0.0006
0.0020
0.00002
0.0035
0.00001
ng
Units
0.0001
0.000002 0.0000020.0080 0.0080
0.0044 0.0044
WHO
Birds
- 0.0041
ng
0.0002
0.0002
ng
0.0020
0.0002
0.000002 0.0000020.00001
TEQ2 TEQ1
0.0050
99
0.0008
0.000001 0.000001
0.0012
0.0026
ng 0.0727 - 0.0097 0.0097 0.0073
0.0001
0.0020
0.0006 96
106
0.0080 0.0001
ng 0.0075
0.0050 0.0001
0.0006ng 0.0058 0.0021
-
0.0006 0.00060.00120.0012
-
0.000001 0.000001 0.000001
0.0002
0.0006
103
0.0120
0.0017
0.0156 0.0322- 0.0322
ng/m³
0.1002
-
0.0006
m³
Value
0.0018 0.0018 0.0041
0.0012
ng
99
0.0004
0.0110
TEQ1 TEQ2
0.0055
0.00200.0020
ng
0.00002
0.0020
0.0020
0.00001
0.0002
121
0.0020 0.0020 0.0020ng 0.0020
0.0002
0.0055
0.0020
0.0008
0.0020 0.0020
0.0035
0.0002
ng
0.0002
0.0275
0.0002
7.7542
Sampling Dates - 26/07/2016
Average Volume Sampled (REF)
APPENDIX 2
DIOXINS & FURANS: SAMPLING DETAILS
ng 0.0035
0.0058
0.0055
0.0050
0.0004 0.0002
0.0006 0.0006 0.0006
ng 0.00020.0002
0.0020 0.0020
76
0.0020
0.0006 0.0006
0.0120 0.0120
0.0050
0.0077
0.0001 0.0001
0.0005
0.0062
0.000020.0002 0.00002
0.0055
WHO Humans /
Mammals
ng
NATO
I-TEQ
0.0033
0.0001
-
0.0050
0.0002
106
0.0010
0.0035
0.000008
(Continued)
1060.0002
0.0020
0.0035 0.0035
0.0065
0.0035
0.0001
0.0010
0.0001
0.0001
-0.0004 0.0008
0.0006 0.0006
0.0156
0.0004
1220.0001
102
0.000001
-
-
0.0001
0.0008
0.0001 0.0001 0.0001 0.00001
ng
ng 0.0008 0.0008 0.0008
0.0001
ng
0.0001ng
0.0110 0.0110
0.0005
0.0091 0.0091 0.0263 0.0263
0.00001
0.0017
1010.0077
0.0006
128
ng
0.000001
CAT-RT (Version BO)
Page 53 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 56 of 83
Sample Runs
Leak Test Acceptable
%
Are Water Droplets Present
-
No
l/min
Isokinetic Criterion Compliance
Ambient Temperature Recorded?
Exit Temperature Acceptable
Maximum Allowable Temperature
Less than 50% Faded
-
Condenser Exit Temperature Units Run 1
19
%
Units
Pre-Sampling Leak Rate
APPENDIX 2
DIOXINS & FURANS: QUALITY ASSURANCE
MU Acceptable %
0.24
Units
Run 1
%
Allowable Isokinetic Range 95 - 115
Isokinetic Variation
Run 1
Maximum Filter Temperature
(PAGE 1 OF 2)
Yes
11.2
20
l/min 0.40Post-Sampling Leak Rate
°C 120
Silica Gel (Concurrent Water Vapour) Units
Run 1
MU (Concurrent Water Vapour) Units Run 1
Yes
Units Run 1
97.8
% Yes
Allowable MU
l/min
21.08
Run 1
%
Units
Water Droplets
Measurement Uncertainty (MU)
Units
Mean Sampling Rate
-
-
°C 20
Run 1
Maximum Temperature Recorded °C
Leak Test Results
Allowable Leak Rate l/min 1.05
Yes
Isokineticity Acceptable - Yes
Filter Temperatures
Test Conditions
Yes
CAT-RT (Version BO)
Page 54 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 57 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
-
APPENDIX 2
(PAGE 2 OF 2)
Units Blank 1
Expected Sampling Rate l/min 20.00
0.0100
Allowable Leak Rate
Blank 1
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Ratio highest to lowest velocities between 3 and 5 : 1.
l/min
Blank Acceptable
Validity of NATO I-TEQ Blank vs ELV
Allowable Blank ng/m³
DIOXINS & FURANS: QUALITY ASSURANCE
Leak Test Results Units
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
l/min 1.00
Nature of Deviation
0.23Sampling Leak Rate
Yes
Leak Test Acceptable Yes
-
CAT-RT (Version BO)
Page 55 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 58 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Symbol UnitsRun 1
Tm
%
Run 1
0.0 % v/v 1.0
0.0000L
ng/m³ 0.0002
L
%
kPa 0.5
uVm 0.163
0.67
Requirement of Standard
%
uL
ng/m³
Hm
2.0297.1
39.8%
ng/m³
%
Units
Measured Quantities
ng/m³
1.90
Measured Quantities Units Run 1
1.00
8.1511
≤1%
-
APPENDIX 2
DIOXINS & FURANS (NATO I-TEQ): MEASUREMENT UNCERTAINTY CALCULATIONS
Value
UnitsParameter
≤1%
Vm
%
%
uHm
Run 1
1.00
uTm
N/A
K
%
20.4
≤1%
1.00
Symbol
%
- N/A
0.0007
ng/m³
-
Measured Quantities
ρm
N/A
- N/A
% v/v N/A
ng/m³
ng/m³ 0.0002
N/A
%
Lr
%
Units Run 1
0.0004
Uncertainty in Result
Measured Quantities
Uncertainty in Measurement Units
39.8
m³ 7.0169
Units Run 1
Sensitivity Coefficient
Measured Quantities
10.00 No Requirement
0.0007
ng/m³
ng/m³ 0.0000
Vm
Uncertainty as a Percentage
0.00
1.90
Lr 10.00
ng/m³ 0.0000
Run 1
Symbol
100.7
m³
uρm
%
Standard uncertainty
≤2%
≤5%
Oxygen Correction Part of MU Budget
uLr
Run 1
0.50
%
0.0002
2.00
Overall MU For O₂ Measurement
CAT-RT (Version BO)
Page 56 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 59 of 83
Sample Runs
- -
- -
- -
- -
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
11.10
APPENDIX 2
FORMALDEHYDE: RESULTS SUMMARY
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
Parameter Units Run 1
Filter Housing Material Borosilicate Glass
Mean
Parameter
CAT-TP-19
Maximum
Concentration
Blank 1
mg/m³ 0.02
Standard
Out Stack
Filter Size and Material 47mm Quartz Fibre
Number of Sampling Lines Used
Units Run 1
Uncertainty ±% v/v 1.21 1.21
Uncertainty
1281.1
Parameter
±mg/m³
Probe Material Titanium
0.02
Parameter Value
Water Vapour
B3
11.10
Units
Sample Point I.D.'s
US EPA M316
Technical Procedure
Mean
CAT-AP-05
1 / 1
Number of Sampling Points Used 1 / 1
7.81
Mass Emission g/hr 4134.9
±g/hr
Impinger Material Polyethylene
Absorption Solution HPLC Grade Water
Positioning of Filter
1281.1
Date of Sample Analysis 04/08/2016
% v/v
mg/m³ 25.52
7.81
25.52
4134.9
Uncertainty
Concentration
ISO 17025 Accredited Analysis? Yes
Name of Analytical Laboratory CAT
Analytical Laboratory's Procedure
CAT-RT (Version BO)
Page 57 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 60 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
% v/v
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd)
Nozzle area, An
m³/min
mmHg 755.5
Barometric pressure, Pb mmHg
% wet oxygen measured in gas stream, ACT%O₂w
Gas meter correction factor, Yd -
761.3
Ps = (Pb + (Pstatic / 13.6)
g
m³ 0.6643
27.64
Average stack gas temperature, Ts
Area of stack, As m²
m³/min
Vmstd@X%oxygen = (Vmstd) / (O₂REFd)
Total mass of liquid collected, Vlc
Total mass collected in impingers (liquid trap)
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
3560.6
59.2
m³ N/A
Stack static pressure, Pstatic
Units Run 1
20.86
- 34.97
N/A
FORMALDEHYDE: ISOKINETIC SAMPLING CALCULATIONS
Test
°C 26.3
% 101.4
APPENDIX 2
g/gmol 28.84
Average of velocity heads, ∆Pavg
m³/min N/A
Volume of gas sample through gas meter, Vm
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)
N₂ % v/v 79.14
N/A
28.34
N/A
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)
g
15.61
Nozzle diameter, Dn mm
3.80
4.23
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min
Conversion factor (K/mm.Hg), Cf
Vmstw@X%oxygen = (Vmstw) / (O₂REFw)
Total % v/v
% v/v 20.80
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)
Total mass collected in impingers (silica trap) g
0.9310
m³ 0.0738
-
% v/v
5.5
53.7
mmH₂O
% dry oxygen measured in gas stream, ACT%O₂d
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)
% v/v
-
N/A
m³ 0.1110
- N/A
No
% v/v
% oxygen reference condition, REF%O₂ % v/v
m³ N/A
N/A
Vmstw = (Vmstd)(100/(100 - Rwv))
°C
Average square root of velocity heads, √∆P √mmH₂O
mm²
-
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))
Velocity pressure coefficient, Cp
mmH₂O 17.87
Qa = (60)(As)(Vs)
6.01
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)
2603.0
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min
m³ 0.5906
11.10
m/s
m³ 0.6912
% v/v 11.10
Total sampling time, q
Velocity of stack gas, Vs
Pitot tube velocity constant, Kp
Bwo = Vwstd / (Vmstd + Vwstd)
min 30
2928.1
-78.2
0.06
48.1
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)
0.84
Average dry gas meter temperature, Tm
57.0
Average pressure drop across orifice, ∆H mmH₂O
g/gmol
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))
Vwstd = (0.001246)(Vlc)
- 0.3592
CAT-RT (Version BO)
Page 58 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 61 of 83
Sample Runs
-
-
-
-
-
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
<
-
<
<
63.24
Parameter Units
APPENDIX 2
mg/m³ 25.52
FORMALDEHYDE: SAMPLING DETAILS
Mass in Back Impinger
-
Laboratory Result for Impingers
Calculated Concentration
Volume in Impingers
Calculated Concentration
µg 16956.5
16221.1
Sampling Dates
Parameter Units Blank 1
735.5
Sampling Device -
ml 304.1
µg/ml 0.05
Volume in Front Impingers
m³ 0.6643
6.76
µg
ml
µg/ml
ISO
µg
108.8
Run 1
Blank Dates
0.02
26/07/2016
Volume in Back Impinger
Volume Sampled (REF)
Total Mass Collected
-
- 08:40 - 09:10
256.5
Mass in Front Impingers
ml
15.2Total Mass Collected µg
Sampling Times
Laboratory Result for Back Impinger
Laboratory Result for Front Impingers µg/ml
27/07/2016
Average Volume Sampled (REF) m³ 0.6643
mg/m³
CAT-RT (Version BO)
Page 59 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 62 of 83
Sample Runs
0 0 0 0
Run 1
%
0.43
Run 1
0.31
%
Units Run 1
Water Droplets
%
Units
Isokinetic Criterion Compliance
10.9
Units
Absorption Efficiency Acceptable -
Measurement Uncertainty (MU) %
Less than 50% Faded
21.45l/min
Run 1
APPENDIX 2
120
0.24
Units
Allowable Absorption Efficiency
Post-Sampling Leak Rate
N/A
l/min
Mean Sampling Rate
Units
Maximum Filter Temperature °C
101.4
Isokineticity Acceptable -
Run 1
Yes
MU (Concurrent Water Vapour)
Units
Units
Allowable Isokinetic Range
Pre-Sampling Leak Rate l/min
N/A
-
Units Run 1
Yes
20
-
NoAre Water Droplets Present
Run 1
Filter Temperatures
%
Leak Test Results
- Yes
Test Conditions
Allowable MU
Isokinetic Variation
Yes
Yes
Ambient Temperature Recorded?
95.7
(PAGE 1 OF 2)
FORMALDEHYDE: QUALITY ASSURANCE
Absorption Efficiency
Leak Test Acceptable
Silica Gel (Concurrent Water Vapour)
%
%
Absorption Efficiency
%
MU Acceptable
95 - 115
Run 1
Allowable Leak Rate l/min
CAT-RT (Version BO)
Page 60 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 63 of 83
Blank Runs
Method Deviations
1
wx
wx
- - - - -
- - - - -
- - - - -
- - - - -
Blank 1
Expected Sampling Rate
APPENDIX 2
FORMALDEHYDE: QUALITY ASSURANCE
Blank Acceptable
Post-Sampling Leak Rate l/min
l/min 0.40
Run Number
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
Leak Test Results
Blank 1
Allowable Leak Rate
- Yes
20.00l/min
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Ratio highest to lowest velocities between 3 and 5 : 1.
2.0
Nature of Deviation
0.10
(PAGE 2 OF 2)
Pre-Sampling Leak Rate
Leak Test Acceptable - Yes
Units
Allowable Blank mg/m³
Validity of Blank vs ELV Units
l/min 0.10
CAT-RT (Version BO)
Page 61 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 64 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
% v/v
uρm
Tm
N/A
mg/m³
mg/m³
Vm
% 15.7
1.00
7.50
0.67 ≤1%
1.45
Requirement of Standard
Units Run 1
%
Sensitivity Coefficient
m³
2.00
0.5
L
% v/v
4.01
Measured Quantities
mg/m³
0.50
Units
Uncertainty in Measurement Units
Symbol
Run 1
Measured Quantities
Measured Quantities
mg/m³
2.04
1.00
7.81
Units
Parameter Units
%
mg/m³ N/A
0.684
Oxygen Correction Part of MU Budget
Run 1
mg/m³
N/A
1.914
30.6
mg/m³
%
1.00
Units Run 1
UnitsMeasured Quantities
Lr
≤1%
% -
N/A
0.5906
mg/m³
43.22
0.6912
0.0
%
mg/m³ 7.81
FORMALDEHYDE: MEASUREMENT UNCERTAINTY CALCULATIONS
kPa
Standard uncertainty
1.0uHmHm
%
0.0138uVm
Run 1
m³
0.2130
Overall MU For O₂ Measurement
≤2%
% 30.6
1.9143
Run 1
APPENDIX 2
uLr
% -
Uncertainty as a Percentage
Measured Quantities
≤2%
Value
uL
≤1%%
%
7.50
Run 1
K
Vm
ρm
2.0299.3
100.7
uTm
L 1.45
SymbolSymbol
%
mg/m³
Run 1
0.213
Lr
Uncertainty in Result
No Requirement
-
%
N/A
- N/A
CAT-RT (Version BO)
Page 62 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 65 of 83
Sample Runs
- -
< <
- -
< <
- -
- -
- -
- -
Blank Runs
- -
< <
General Sampling Information
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
Concentration
Concentration
Parameter Units Blank 1
0.001
1.1
0.007
g/hr 1.1
Uncertainty ±mg/m³
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
APPENDIX 2
ISOCYANATES: RESULTS SUMMARY
0.007
Parameter Value
mg/m³
Uncertainty ±g/hr 0.2 0.2
Parameter Units Run 1
Units Run 1
0.007
Maximum
Filter Housing / Nozzle Material Borosilicate Glass
mg/m³ 0.007
Out Stack
Filter Size and Material 1 2-PP Impregnated 47mm Glass Fibre
Number of Sampling Lines Used
B3
Yes
Probe Material Titanium
Mean
0.001
Date of Sample Analysis 12/08/2016
MeanParameter
Mass Emission
Name of Analytical Laboratory SAL
Analytical Laboratory's Procedure M119
ISO 17025 Accredited Analysis?
Positioning of Filter
Number of Sampling Points Used
Water Vapour % v/v 12.23
Uncertainty ±% v/v 1.00
Standard US EPA CTM36
1 / 1
1 / 1
Technical Procedure
Sample Point I.D.'s
CAT-TP-17
1.00
12.23
CAT-RT (Version BO)
Page 63 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 66 of 83
Absolute pressure of stack gas, Ps
Volume of water vapour collected, Vwstd
Volume of gas metered dry, Vmstd
Moisture content, Bwo & Rwv
Bwo as a percentage
Reported Water Vapour, checked with Tables in EN 14790, Rwv
Volume of gas metered wet, Vmstw
Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂
Molecular weight of dry gas stream, Md
CO₂ (Estimated)
O₂
Molecular weight of stack gas (wet), Ms
Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)
Percent isokinetic, %I
mm 4.97
m³/min
Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))
mm² 19.43
Total sampling time, q min 30
m/s 15.66
Average stack gas temperature, Ts °C 57.0
%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100)) %
Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 2578.1
QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw) m³/min N/A
QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A
Qa = (60)(As)(Vs) m³/min
2937.3
3571.8
-
Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)
Nozzle diameter, Dn
Average square root of velocity heads, √∆P √mmH₂O 4.23
Nozzle area, An
101.8
Total mass collected in impingers (silica trap)
m³
0.3592Conversion factor (K/mm.Hg), Cf
Area of stack, As m² 3.80
Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A
Vmstd@X%oxygen = (Vmstd) / (O₂REFd) m³ N/A
% v/v 0.06
% v/v 20.80
Total % v/v 20.86
% oxygen reference condition, REF%O₂ % v/v N/A
27.52
Velocity of stack gas, Vs
Pitot tube velocity constant, Kp - 34.97
Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂) g/gmol 28.84
Velocity pressure coefficient, Cp - 0.84
Ms = Md(1 - (Rwv/100)) + 18(Rwv/100) g/gmol
O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w) -
Total mass collected in impingers (liquid trap) g
APPENDIX 2
ISOCYANATES: ISOKINETIC SAMPLING CALCULATIONS
Test Units Run 1
Barometric pressure, Pb mmHg 761.3
Vmstw = (Vmstd)(100/(100 - Rwv)) m³ 0.4584
g 16.5
IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction) - No
Ps = (Pb + (Pstatic / 13.6) mmHg 755.5
O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d) - N/A
mmH₂O
N₂ % v/v 79.14
12.23% v/v
Vwstd = (0.001246)(Vlc)
Gas meter correction factor, Yd -
% v/v 12.23
Average pressure drop across orifice, ∆H
0.0561
Volume of gas sample through gas meter, Vm
28.5
Average of velocity heads, ∆Pavg mmH₂O 17.90
N/A
0.9310
N/A
% dry oxygen measured in gas stream, ACT%O₂d % v/v N/A
m³ 0.4650
Average dry gas meter temperature, Tm °C 21.8
Bwo = Vwstd / (Vmstd + Vwstd) m³ 0.1223
Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³ 0.4024
Total mass of liquid collected, Vlc g 45.0
Stack static pressure, Pstatic mmH₂O -78.2
% wet oxygen measured in gas stream, ACT%O₂w % v/v
22.3
CAT-RT (Version BO)
Page 64 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 67 of 83
Sample Runs
<
<
-
-
-
Where: ISO stands for Manual Isokinetic Sampling Train
Blank Runs
<
<
<
<
<
- ISO
ISOCYANATES: SAMPLING DETAILS
Calculated Concentration
0.007
Sampling Times - 09:55 - 10:25
Sampling Dates - 27/07/2016
Sampling Device
APPENDIX 2
µg
Methyl Diisocyanate (MDI) µg
Hexamethylene Diisocyanate (HDI) µg 1.00
0.4584
Total Mass Collected µg 3.00
Calculated Concentration mg/m³
m³
1.00
Volume Sampled (REF)
Methyl Diisocyanate (MDI)
Hexamethylene Diisocyanate (HDI)
Toluene Diisocyanates (TDI)
µg
µg 1.00
0.007
Parameter
Toluene Diisocyanates (TDI) µg 1.00
1.00
26/07/2016Blank Dates -
1.00
Total Mass Collected µg 3.00
mg/m³
Average Volume Sampled (REF) m³ 0.4584
Parameter Units Run 1
Units Blank 1
CAT-RT (Version BO)
Page 65 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 68 of 83
Sample Runs
Blank Runs
Method Deviations
1
wx
- - - - -
- - - - -
Yes
Allowable Leak Rate
Isokinetic Criterion Compliance Units Run 1
Leak Test Results
Ambient Temperature Recorded? - Yes
Isokinetic Variation % 101.8
Yes
Run 1
The sample points where the angle of swirl was > 15° were omitted from the sampling exercise.
Run Number
Expected Sampling Rate l/min
Units
20.00
Allowable Blank mg/m³ 0.0
Filter Temperatures
Blank 1
- Yes
Sampling Leak Rate l/min 0.20
Nature of Deviation
Blank 1
Blank Acceptable -
(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)
l/min
Allowable Isokinetic Range
0.40
°C
Are Water Droplets Present
105
Units Run 1
Isokineticity Acceptable - Yes
Maximum Filter Temperature
Leak Test Acceptable
% 95 - 115
Test Conditions Units
Validity of Blank vs ELV Units
MU (Concurrent Water Vapour)
Allowable Leak Rate
0.14
APPENDIX 2
ISOCYANATES: QUALITY ASSURANCE
Leak Test Results Units Run 1
l/min
Leak Test Acceptable - Yes
MU Acceptable % Yes
Silica Gel (Concurrent Water Vapour) Units Run 1
Pre-Sampling Leak Rate l/min
Measurement Uncertainty (MU) % 8.2
Units Run 1
0.15
Mean Sampling Rate l/min 14.43
0.29
%Less than 50% Faded
Water Droplets Units
Post-Sampling Leak Rate l/min
Run 1
- No
% 20Allowable MU
CAT-RT (Version BO)
Page 66 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 69 of 83
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (Actual)
Sampled Gas Temperature
Sampled Gas Pressure
Sampled Gas Humidity
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
Sampled Volume (STP)
Leak
Laboratory Result
O₂ Correction Factor
Stack Gas O₂ Content
MU for O₂ Correction
Combined uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
Expanded uncertainty (95% confidence), without Oxygen Correction
Expanded uncertainty (95% confidence), with Oxygen Correction
Expanded uncertainty (95% confidence), estimated with Method Deviations
Reported Uncertainty
ρm 100.7
1.00
%
1.00mg/m³
Requirement of Standard
% 2.00
Lr
Units
mg/m³ 0.00
mg/m³ 0.00
Symbol
% 0.68
0.00
12.9
%
Vm
uHm % v/v
0.4024
mg/m³ 0.0004
Lr
% 1.04
6.00
%
Measured Quantities
Vm
0.000
mg/m³ 0.0000
Parameter Units
Uncertainty as a Percentage
Measured Quantities
≤2%
Measured Quantities
mg/m³ N/A
≤1%
uL
Uncertainty in Measurement Units
Oxygen Correction Part of MU Budget
- N/A
mg/m³ 0.000
m³
No Requirement
K
19.4
mg/m³ 0.00
%
mg/m³
19.4%
%
% N/A
Run 1
-
0.02
0.50
Measured Quantities Units Run 1
Units
uLr %
Sensitivity Coefficient
0.000L
Uncertainty in Result
mg/m³
Units
≤1%
6.00
Run 1
≤1%
-
N/A
N/A
% v/v
% -
0.5
≤2%
Hm
1.00
Run 1
1.0
L 1.04
Run 1
uρm
Run 1
kPa
2.0Tm 294.8
Symbol Units Run 1Run 1
uTm
uVm m³ 0.0093
0.0
APPENDIX 2
0.4650
ISOCYANATES: MEASUREMENT UNCERTAINTY CALCULATIONS
Symbol
Value Standard uncertainty
Measured Quantities
Overall MU For O₂ Measurement % N/A
CAT-RT (Version BO)
Page 67 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 70 of 83
Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
APPENDIX 2
Parameter
1 / 1
127.8
OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY
Medite Europe Ltd, Clonmel
413.34
Yes
EP 35 - Face Dryer Stage 1
Parameter Units Mean
04/12/2019
0.79
Uncertainty ±mg/m³
0.79
Probe Material Titanium
317.1
Mass Emission
1.96
Sample Point I.D.'s
Heated Head Filter Used
Filtration Type / Size
CAT-TP-39
317.1±g/hr
Standard
Technical Procedure
Number of Sampling Lines Used 1 / 1
Number of Sampling Points Used
Span Gas Uncertainty (%)
Run 1
EN 14792
0.1µm Glass Fibre
Uncertainty
2
C1
Span Gas Reference Number CYL 4.0161
Span Gas Expiry Date
Concentration mg/m³
Span Gas Start Pressure (bar) 100
Gas Cylinder Concentration (ppm)
Span Gas Type Nitrogen Monoxide
180°C
Nitrogen (5 Grade)Zero Gas Type
1.96
g/hr 127.8
Value
Heated Line Temperature
Date & Result of Last Converter Check 20/08/2015 - 95.5%
CAT-RT (Version BO)
Page 68 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 71 of 83
Graphical Trend of Data
COVER ME WITH CHART/S
APPENDIX 2
OXIDES OF NITROGEN (as NO₂): DATA TREND
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
15
:31
15
:32
15
:33
15
:34
15
:35
15
:36
15
:37
15
:38
15
:39
15
:40
15
:41
15
:42
15
:43
15
:44
15
:45
15
:46
15
:47
15
:48
15
:49
15
:50
15
:51
15
:52
15
:53
15
:54
15
:55
15
:56
15
:57
15
:58
15
:59
16
:00
Co
nce
ntr
atio
n (
mg/
m³)
Oxides of Nitrogen (as NO₂) At Reference Conditions
- Run 1
CAT-RT (Version BO)
Page 69 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 72 of 83
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Zero Drift 0 0 0
Zero Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
Span Gas Value ppm
Span Down Sampling Line (Pre) ppm 63.50
Run 1
ppm
ppm
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
18 - 19
CA
L 2
Span Down Sampling Line (Post)
Units
Span Down Sampling Line (Post) ppm 63.10
ppm -0.40
ppmSpan Down Sampling Line (Post)
ppm
Span Down Sampling Line (Pre) ppm
Yes
-
APPENDIX 2
ppm
Run Ambient Temperature Range
Zero Down Sampling Line (Pre)
Sampling Dates
Temperature Acceptable
ppm -0.10
Average Temperature °C 2.0
Sampling Times -
-
4.0
± ppm 3.17
< °C
Run Number
Conditioning Unit Temperature Units
OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE
Parameter
63.3
CA
L 1
Run 1
Zero Down Sampling Line (Post) ppm -0.10
CA
L 1
CA
L 2
ppm
Units
250
3.17
Span Drift Acceptable - Yes
INPUT
Nature of Deviation
15:31 - 16:00
Allowable Temperature
0.00
Instrument Range
Zero Drift
Zero Down Sampling Line (Pre) ppm
°C
ppm
-
Run 1
Zero Down Sampling Line (Post) ppm
Zero Down Sampling Line (Post)
Yes
ppm
ppm
Units
CA
L 3
Span Drift
Allowable Span Drift
Test Conditions Units Run 1
CA
L 3
Allowable Zero Drift
ppm
± ppm
Zero Drift Acceptable
ppm
Zero Down Sampling Line (Pre)
Span Down Sampling Line (Pre)
Run 1
CAT-RT (Version BO)
Page 70 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 73 of 83
k =
mg/m³
mg/m³
RUN 1 Units
Measurement uncertainty Result 0.88
mg/m³
Uncertainty corrected to std conds. (O₂) 2.19
0.63
% of value
mg/m³ (REF)
mg/m³
0.00
% of full scale
5 %
205.0 mg/m³
Cal gas conc. 63.3 ppm
Conversion 2.05 ppm to mg/m³
MCERTS Range [B] 205.0 mg/m³
Ration NO / NO₂
mg/m³ (STP, dry)Measured concentration
TGN M2 Allowable MU
Limit value
seconds
-
Repeatability at zero 0.00 % full scale
% of value
Zero drift -0.16 % full scale
Atmospheric pressure dependence 0.10 % of value/kPa
Ambient temperature dependence 0.04 % full scale/10K
% full scale
Deviation from linearity 0.29
Span drift -0.63 % full scale
Volume or pressure flow dependence 0.10
2.19
Result of Compliance with Uncertainty Requirement in M2
Uncertainty of calibration gas
Units
% of Value
Range Used [A] 513.1
0.01 mg/m³
Combined interference (from MCERTS Certificate) 0.75
Repeatability at span level 0.10
Performance characteristic RUN 1 Units
Units
Response time 31
mg/m³
mg/m³
Combined uncertainty 1.12
N/A % at ELV
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A
% full scale/10V
95.5 %
mg/m³
% range
RUN 1
-
Requirement for SRM is that Uncertainty should be <10% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 10% + the
uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
mg/m³
Standard deviation of repeatability at span level
Dependence on voltage
0.34 mg/m³
Drift -0.12
Losses in the line (leak)
% at ELV
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -
RUN 1
Volume or pressure flow dependence 0.00
Lower of [A] or [B]
mg/m³
Atmospheric pressure dependence 0.06 mg/m³
mg/m³
Lack of fit
Ambient temperature dependence
mg/m³Converter efficiency
Losses in the line (leak) 0.00 mg/m³
Units
Expanded uncertainty (with O₂) - at 95% Confidence N/A
0.01
mg/m³
Dependence on voltage -0.03
mg/m³
% of value
% of value
0.00
% of Value
Standard deviation of repeatability at zero use rep at span
Expanded uncertainty (no O₂) - at 95% Confidence 248.12
Expanded uncertainty (no O₂) - at 95% Confidence 1.69 % at ELV
Overall Allowable uncertainty (no O₂) - at 95% Confidence 10.0 % at ELV
Performance characteristics RUN 1
ppmRange Used
%
0.88
250.0
mg/m³
mg/m³ (REF)
10.0
130.0
OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS
Combined interference
Expanded uncertainty 1.96
Uncertainty of calibration gas blending 0.01
Uncertainty of calibration gas blending 1.40
Uncertainty of calibration gas 2.00
Expanded uncertainty (with O₂) - at 95% Confidence
N/A
-0.23
Performance characteristics RUN 1
Converter efficiency
Number of readings in measurement 30
0.02
Cal gas conc. 130.0
APPENDIX 2
Units
CAT-RT (Version BO)
Page 71 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 74 of 83
Sample Runs
- -
- -
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
Parameter
Uncertainty
Zero Gas Type
153.9
Yes
Heated Line Temperature 180°C
C1
Heated Head Filter Used
200.8
±mg/m³ 0.95
1.24
200.8
Span Gas Type Carbon Monoxide
Run 1
Number of Sampling Lines Used 1 / 1
Number of Sampling Points Used
Span Gas Expiry Date
1 / 1
Nitrogen (5 Grade)
g/hr
APPENDIX 2
EP 35 - Face Dryer Stage 1
Parameter Units
Medite Europe Ltd, Clonmel
Uncertainty
Concentration
Value
mg/m³ 1.24
Probe Material Titanium
Filtration Type / Size
153.9
Gas Cylinder Concentration (ppm) 409.64
Span Gas Uncertainty (%) 2
Technical Procedure CAT-TP-39
Standard EN 15058
Span Gas Reference Number CYL 2.0097
0.1µm Glass Fibre
0.95
Sample Point I.D.'s
Mean
CARBON MONOXIDE: RESULTS SUMMARY
±g/hr
20/06/2019
Span Gas Start Pressure (bar) 110
Mass Emission
CAT-RT (Version BO)
Page 72 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 75 of 83
Graphical Trend of Data
APPENDIX 2
CARBON MONOXIDE: DATA TREND
COVER ME WITH CHART/S
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
1.8
15
:31
15
:32
15
:33
15
:34
15
:35
15
:36
15
:37
15
:38
15
:39
15
:40
15
:41
15
:42
15
:43
15
:44
15
:45
15
:46
15
:47
15
:48
15
:49
15
:50
15
:51
15
:52
15
:53
15
:54
15
:55
15
:56
15
:57
15
:58
15
:59
16
:00
Co
nce
ntr
atio
n (
mg/
m³)
Carbon Monoxide At Reference Conditions
- Run 1
CAT-RT (Version BO)
Page 73 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 76 of 83
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Zero Drift 0 0 0
Zero Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
ppm
°C 2.0
Span Gas Value
CA
L 1
Units Run 1
Zero Down Sampling Line (Pre)
ppm
ppm
0.50
Span Down Sampling Line (Pre)
Span Drift
Allowable Span Drift ± ppm
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
Run Ambient Temperature Range
Span Down Sampling Line (Post) ppm
Zero Drift Acceptable -
ppm
ppm -3.20
Span Down Sampling Line (Post)
Zero Down Sampling Line (Pre) ppm
Yes
Sampling Times
ppm 406.00
Allowable Zero Drift ± ppm
-
ppm
ppm
0.50
-
Yes
Zero Down Sampling Line (Post)
Units
409.6
ppm
ppm
Run 1
Average Temperature
Allowable Temperature < °C
Zero Down Sampling Line (Pre)
ppm
ppm
Span Down Sampling Line (Pre)
Units
ppm
Run 1
Test Conditions
20.48
Units Run 1
Run Number
Span Down Sampling Line (Pre)
Span Down Sampling Line (Post)
CA
L 2
Temperature Acceptable
Zero Drift
CA
L 3
ppm
Units
APPENDIX 2
CA
L 1
CA
L 2
4.0
CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE
Parameter
Zero Down Sampling Line (Post)
ppm
ppm 0.00
Sampling Dates - INPUT
Instrument Range ppm 500
15:31 - 16:00
Run 1
°C 18 - 19
20.48
Zero Down Sampling Line (Post)
Conditioning Unit Temperature
CA
L 3
409.20
YesSpan Drift Acceptable -
ppm
Nature of Deviation
CAT-RT (Version BO)
Page 74 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 77 of 83
k =
Requirement for SRM is that Uncertainty should be <6% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 6% + the uncertainty
associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
Measured concentration
TGN M2 Allowable MU
Limit value
Performance characteristics RUN 1 Units
600.0 mg/m³ (REF)
6.0 %
1.39 mg/m³ (STP, dry)
RUN 1 Units
Expanded uncertainty (no O₂) - at 95% Confidence 76.48
Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV
1.06 mg/m³ (REF)
1.06 mg/m³
Uncertainty corrected to std conds. (O₂)
Lack of fit 0.27 mg/m³
Drift 0.35 mg/m³
Volume or pressure flow dependence 0.00 mg/m³
Atmospheric pressure dependence 0.05
Result of Compliance with Uncertainty Requirement in M2 N/A -
Losses in the line (leak) 0.00 mg/m³
Uncertainty of calibration gas blending 0.01 mg/m³
% of Value
Expanded uncertainty (no O₂) - at 95% Confidence 0.18 % at ELV
Overall Allowable uncertainty (no O₂) - at 95% Confidence 6.0 % at ELV
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -
RUN 1 Units
Expanded uncertainty (with O₂) - at 95% Confidence N/A % of Value
Uncertainty of calibration gas 0.02 mg/m³
RUN 1 Units
Measurement uncertainty Result 1.39 mg/m³
Combined uncertainty 0.54 mg/m³
Expanded uncertainty 1.96
mg/m³
Ambient temperature dependence -0.03 mg/m³
Combined interference (from MCERTS Certificate) -0.21 mg/m³
Dependence on voltage -0.04 mg/m³
% range
Dependence on voltage -0.35 % full scale/10V
Losses in the line (leak) 0.10 % of value
Uncertainty of calibration gas blending 1.40 % of value
Uncertainty of calibration gas 2.00 % of value
Performance characteristic RUN 1 Units
Standard deviation of repeatability at zero use rep at span mg/m³
Standard deviation of repeatability at span level 0.04 mg/m³
Units
Response time 28
% full scale
Repeatability at span level 0.20 % full scale
Deviation from linearity 0.63 % of value
Number of readings in measurement 30
APPENDIX 2
CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS
% of full scale
Atmospheric pressure dependence 0.22 % of value/kPa
Ambient temperature dependence -0.20 % full scale/10K
ppm
Range Used [A] 624.6 mg/m³
Cal gas conc. 409.6 ppm
Conversion 1.25 ppm to mg/m³
RUN 1
-
Repeatability at zero
Performance characteristics
Zero drift 0.12 % full scale
Span drift -0.78 % full scale
Volume or pressure flow dependence 0.10
mg/m³
Cal gas conc. 511.7 mg/m³
Combined interference -0.48
MCERTS Range [B] 75.0
seconds
Range Used 500.0
mg/m³
Lower of [A] or [B] 75.0
0.10
CAT-RT (Version BO)
Page 75 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 78 of 83
Sample Runs
- -
- -
- -
General Sampling Information
NOTE: Dilution performed to achieve correct span value
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Span Gas Type Synthetic Air (5 Grade)
Span Gas Reference Number
Units Run 1
Value
Standard
Nitrogen (5 Grade)
Number of Sampling Points Used 1 / 1
Sample Point I.D.'s C1
EN 14789
Technical Procedure CAT-TP-39
Probe Material Titanium
Filtration Type / Size
Span Gas Expiry Date 07/12/2020
Span Gas Start Pressure (bar) 80
Gas Cylinder Concentration (% v/v) 21.67
Number of Sampling Lines Used 1 / 1
Parameter Mean
Parameter
180°C
Span Gas Uncertainty (%) 2
Zero Gas Type
0.1µm Glass Fibre
Heated Head Filter Used Yes
Heated Line Temperature
Uncertainty ±% v/v 0.49 0.49
CYL 11.0228
APPENDIX 2
Medite Europe Ltd, Clonmel
EP 35 - Face Dryer Stage 1
Concentration % v/v 19.63 19.63
OXYGEN: RESULTS SUMMARY
CAT-RT (Version BO)
Page 76 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 79 of 83
Graphical Trend of Data
OXYGEN: DATA TREND
APPENDIX 2
COVER ME WITH CHART/S
0.0
5.0
10.0
15.0
20.0
25.0
15
:31
15
:32
15
:33
15
:34
15
:35
15
:36
15
:37
15
:38
15
:39
15
:40
15
:41
15
:42
15
:43
15
:44
15
:45
15
:46
15
:47
15
:48
15
:49
15
:50
15
:51
15
:52
15
:53
15
:54
15
:55
15
:56
15
:57
15
:58
15
:59
16
:00
Co
nce
ntr
atio
n (
% v
/v)
Oxygen Oxygen
- Run 1
CAT-RT (Version BO)
Page 77 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 80 of 83
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Zero Drift 0 0 0
Zero Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Span Drift 0 0 0
Method Deviations
1
x
- - -
- - -
- - -
Zero Down Sampling Line (Post)
% v/v
% v/v
CA
L 3
4.0
-0.09
Zero Down Sampling Line (Pre) % v/v
CA
L 1
Zero Down Sampling Line (Pre) % v/v
-
Conditioning Unit Temperature Units Run 1
15:31 - 16:00
Parameter
Span Gas Value
Run 1
Span Down Sampling Line (Post) % v/v
Allowable Temperature < °C
0.03
Zero Down Sampling Line (Post) % v/v -0.06
Units Run 1
Sampling Times
Average Temperature
CA
L 2
Zero Down Sampling Line (Pre) % v/v
Zero Drift Acceptable
Instrument Range % v/v 25
Span Down Sampling Line (Post) % v/v
CA
L 3
-
Nature of Deviation
Temperature Acceptable - Yes
Span Drift Units
Run Number
(x = deviation applies to the associated run)
There are no deviations associated with the sampling employed.
% v/v
Allowable Span Drift ± % v/v 1.08
°C 2.0
Yes
Units Run 1
Span Drift Acceptable - Yes
Test Conditions Units Run 1
Run Ambient Temperature Range °C 18 - 19
CA
L 2
Span Down Sampling Line (Pre) % v/v
Span Down Sampling Line (Post) % v/v
% v/v
% v/v
21.83
% v/v
Zero Down Sampling Line (Post)
% v/v
% v/v
21.94
Span Down Sampling Line (Pre) % v/v
APPENDIX 2
OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE
% v/v 21.67
% v/v -0.11
Allowable Zero Drift ± % v/v 1.08
Zero Drift
CA
L 1
Span Down Sampling Line (Pre)
Sampling Dates - INPUT
CAT-RT (Version BO)
Page 78 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 81 of 83
k =
% range
Dependence on voltage 0.02 % full scale/10V
Losses in the line (leak) 0.00 % of value
Uncertainty of calibration gas
2.50 % of Value
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -
Expanded uncertainty 1.96 0.55 %vol
RUN 1 Units
Standard deviation of repeatability at zero use rep at span %vol
Standard deviation of repeatability at span level 0.00 %vol
Lack of fit 0.00 %vol
Drift -0.11 %vol
Volume or pressure flow dependence 0.00 %vol
Atmospheric pressure dependence %vol
Ambient temperature dependence -0.03 %vol
N/A %vol
6.0 %
0.01
Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.
Combined interference (from MCERTS Certificate) 0.00 %vol
Dependence on voltage 0.00 %vol
Losses in the line (leak) 0.00 %vol
Uncertainty of calibration gas 0.25 %vol
RUN 1 Units
Measurement uncertainty Result 21.97 %vol
Combined uncertainty 0.28 %vol
-0.21 % full scale/10K
Atmospheric pressure dependence 0.19 % of value/kPa
Ambient temperature dependence
Volume or pressure flow dependence 0.10
2.00
Expanded uncertainty (no O₂) - at 95% Confidence
% of full scale
Number of readings in measurement 30 -
Repeatability at zero 0.02 % full scale
Repeatability at span level 0.02 % full scale
Deviation from linearity
% full scale
Span drift -0.50 % full scale
21.97 %vol
Range Used 25.0 %vol
Cal gas conc. 21.7 %vol
Performance characteristics RUN 1 Units
Response time 41 seconds
Combined interference 0.00
Performance characteristics RUN 1 Units
Measured concentration
TGN M2 Allowable MU
Limit value
% of value
Performance characteristic RUN 1 Units
0.03 % of value
Zero drift -0.41
APPENDIX 2
OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS
CAT-RT (Version BO)
Page 79 of 79
Medite Europe Ltd
Clonmel
EP 35 - Face Dryer Stage 1
Job Number: CDU-0666-CAR16-01, Version 1
Sample Date/s: 26th - 27th July 2016
Industrial Emissions Licence: P0027-02
Site Visit Report - SV08076 - Medite Europe Limited Page 82 of 83
Summary
See report
FOLLOW-UP ACTIONS
You are required to complete the instructions and actions, as outlined in this report, within the specified timeframe. Where required, you shall respond to actions specified in Compliance Investigations within the required timeframe. The licensee shall maintain documentary evidence, for review by the EPA, that the prescribed corrective actions were completed within the required timeframe.
You are not required to respond directly to items contained in this EPA site visit report; where an issue requires a direct response, the EPA will generate a Compliance Investigation through the EDEN system. You will receive notification when a Compliance Investigation instruction or action is generated.
Please note that this Site Visit Report will be made available for public viewing via the EPA’s Licence Enforcement Access Portal within one day of the issue date and will be published on the Licence Details Page of the EPA’s website, www.epa.ie, that relates to your licence 60 calendar days after the issue date.
You may if you choose submit, within 45 calendar days of the issue date of this Site Visit Report, a Licensee Public Response that will be published alongside the Site Visit Report. This Response, should you wish to avail of it, provides you with an opportunity to inform the public about how you are implementing the actions set out in the report, activities underway, timescales and target completion dates. Please be aware that the content of your Licensee Public Response must be factual and should not breach the EPAs stated online publication standards.
If you wish to submit a Licensee Public Response to an EPA Site Visit Report, you should do this by clicking on the ‘Make a Response’ link on the Site Visits page in EDEN. A .pdf document containing your response can be attached and submitted from here.
Please note that you are required to comply with the conditions of your licence at all times, and where noncompliance occurs you must restore compliance within the shortest possible time. These actions will be verified during subsequent EPA visits.
Please quote the above Inspection Reference Number in any future correspondence in relation to this Report.
Site Visit Report - SV08076 - Medite Europe Limited Page 83 of 83