![Page 1: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/1.jpg)
[email protected] Tel: (304) 647-5860Copyright Falcon Analytical 12/14/2015
433 AEI Drive – Lewisburg, WV 24901
Falcon Analytical makers of the . . .
The Case for micro & Fast Gas
Chromatography: A Market Overview
orChromatography?
Not Dead Yet!
John Crandall, President
![Page 2: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/2.jpg)
2
Companies compete…
So do technologies
• Near Infrared
• Mass Spectrometry
• Raman
• Tunable Diode Lasers
• Virtual Analyzers and even…
• The “Optical GC”
•… have all sought to displace
Chromatography.
![Page 3: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/3.jpg)
3
Why drive towards the demise of
chromatography?
•“The entourage” as PV2 coined
•Gases
•Solvents
•Time
•Complexity…
Taking the Chromatograph from the real
analytical chemist is like taking the
hammer from the real carpenter.
![Page 4: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/4.jpg)
4
Customers need & want the answers…..
•“The entourage” PV2 coined
•Gases
•Solvents
•Time
•Complexity…
Not the hassles associated with analytical
chemistry and… chromatography.
![Page 5: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/5.jpg)
5
And the hammer analogy isn’t bad.
Message: use the right tool!
![Page 6: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/6.jpg)
6
Chromatography is intuitively
understandable…
Elements of the Chromatograph
•Carrier
•Sample Valve
•Columns
•Detector
•Data System
Elements of the Processing Plant
•Pumps
•Valves
•Columns
•Sensors
•Control System
“Hmmm, I have those in the plant! It’s like a distillation
column, just smaller! What’s complicated?”
![Page 7: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/7.jpg)
7
And yet… we hear all about
•microGC
•FastGC
•UPLC
•And all kinds of efforts to reduce the
entourage!
A worthy endeavor!
![Page 8: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/8.jpg)
8
Threads of Continuity
•The need to solve users’ requirements
•At the top, make the necessary
measurement
•Reliably
•In the hands of the end user
•And… downsize the entourage!
MODULARITY
![Page 9: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/9.jpg)
9
Some Images of Modularity (not to scale)
![Page 10: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/10.jpg)
10
Modules Make Instruments
Instruments Make Analyzers
Analyzers Make System Solutions… One Solution
CopyrightFalcon Analytical Systems & Technology, LLCDecember 14, 2015
![Page 11: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/11.jpg)
11
IFPAC, Year 2000 – Las Vegas
• Question by Dr. Frank Schweighardt, Air Products,
“Will there even be a gas chromatograph in 2020?”
• Answer by Rajko Puzic, ExxonMobil,
“Will humans be using materials made from
hydrocarbons?”
![Page 12: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/12.jpg)
12
Thus, Gas Chromatography is important!
Year in, year out… 20,000 to 30,000 GCs sold
• Process Gas Chromatographs
• ~ 5000 per year… more or less
• ~55% to Hydrocarbon Processing industries
• ~$200 million for instruments only
• SI accounts for much more possibly up to $0.8 – $1 billion
• Laboratory Gas Chromatographs
• ~25,000 per year… more or less
• ~40% to Hydrocarbon Processing industries
• ~$2 billion
• ~ 60% for routine testing and with accessories… ???
…..It’s a BIG market!
![Page 13: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/13.jpg)
13
And why not? It is useful in a BIG way!
•For many analyses involving hydrocarbons
•Quantitative sampling
•Separation and then
•Detection
… is difficult to beat
•And extremely cost effective!
![Page 14: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/14.jpg)
14
Network
Micro-PROCESS
Photometer
Micro LABMass
Spectometer
Micro LABOptical
Spectrometer
Micro LABPhotometer
Micro-PROCESS
GC
Micro-PROCESS
MassSpectrometer
Micro LABGC
At-LinePackaging
Pro
cess C
on
tro
l N
etw
ork
Lab
In
str
um
en
t N
etw
ork
TransportablePackaging
Network
Micro-PROCESSOpticalSpectrometer
ERP
Copyright Falcon Analytical 2014
Old School
New Thinking…CONVERGENCE!
![Page 15: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/15.jpg)
15
Fast and micro GC Applications (refinery/petrochemical processes & upstream)
• Air components hydrogen, oxygen, nitrogen, CO, CO2
• Low boiling hydrocarbons methane – butane
•Refinery gas BTU
• Ethylene purity & BTEX are examples
• Middle distillates (speciation)
•Naphtha cracker
•Gasoline blender & petrochemicals are examples
• High boilers (fingerprinting)
•Refinery material simulated distillation
•Oligomeric or low molecular weight polymers
![Page 16: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/16.jpg)
16
Crude Oil & Gas, the most important natural
resource next to the human resource.
![Page 17: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/17.jpg)
17
Leads to…
Refining, Gas Processing & Petrochemicals
![Page 18: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/18.jpg)
18
Leads to… Chemicals, Specialty
Chemicals, Plastics & Resins
• You get the idea…
• Efficient production of the materials we use every day
mandates that gas & liquid chromatography live on!
![Page 19: The Case for micro & Fast Gas Chromatography: A …...Chromatography is intuitively understandable… Elements of the Chromatograph •Carrier •Sample Valve •Columns •Detector](https://reader035.vdocument.in/reader035/viewer/2022081612/5f71c5b97eab653d9d439dc4/html5/thumbnails/19.jpg)
19
Chromatography? Not dead yet!
Questions?
The short answer…
YES!
There will be gas chromatography in 2020.