drainage b-component - sbmplus.com · 3 sbmplus.com drainage b-component safety data sheet...

sbmplus.com1

DRAINAGE B-ComponentSAFETY DATA SHEET ACCORDING TO REGULATION (EC) NO. 1907/2006

S1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier: Jointex Drainage B-Component

1.2 Relevant identified uses of the substance or mixture and uses advised againstUse of the substance/mixture: Hardender

1.3. Details of the supplier:

SBM+ bvba, Kapellei 152, 2980 Zoersel, BelgiumTelephone information: +32 (0) 3 380 10 35

1.4. Emergency telephone number+32 (0)475/

S2: Hazards identification

2.1 Classification of the substance or mixture: Hazard classes and hazard categories Hazard statements Classification

procedure

Acute toxicity (oral) (Acute Tox. 4) H302: Harmful if swallowed.

Acute toxicity (dermal) (Acute Tox. 4) H312: Harmful in contact with skin.

Skin corrosion/irritation (Skin Corr. 1A) H314: Causes severe skin burns and eye damage.

Respiratory or skin sensitisation (SkinSens. 1)

H317: May cause an allergic skin reaction.

Serious eye damage/eye irritation (Eye Dam. 1)

H318: Causes serious eye damage.

Acute toxicity (inhalative) (Acute Tox. 4) H332: Harmful if inhaled.

2.2 Label elements: Labelling according to Regulation (EC) No. 1272/2008 [CLP]Hazard pictograms:

GHS05 GHS07 Corrosion Exclamation mark Signal word: DangerHazard components for labelling:

1,3-Cyclohexylenbis (methylamine)N’-(3-Aminopropyl)-N,N-dimethylpropane-1,3-diamineDecanedioic acid, compds. w/ 1,3-benzenedimethanamineoxo alcohol (C9/11)-5 EO

Hazard classes and hazard categories hazard statements for health hazards

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H332 Harmful if inhaled.

Supplemental Hazard information (EU)

Precautionary statements

P102 Keep out of reach of children.

Precautionary statements Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection

Precautionary statements Response

P303 + P361 +P353

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

Precautionary statements Storage

P405 Store locked up.

2.3 Other hazards: No data available

S3: Composition / information on ingredients

3.2 MixturesHazardous ingredients / Hazardous impurities / Stabilisers:

Product identifiers Substance nameClassification according to 67/548/EECClassification according to Regulation (EC) No. 1272/2008 [CLP]

Concentration

CAS No.: 100-51-6EC No.: 202-859-9

benzyl alcoholAcute Tox. 4

Warning H302-H332

Xn; R20/22

< 25Wt %

CAS No.: 2855-13-2EC No.: 220-666-8

3-aminomethyl-3,5,5-trimethylcyclohexylamineSkin Corr. 1B, Acute Tox. 4, Skin Sens. 1, Aquatic Chronic 3

Danger H302-H312-H314-H317-H412

Xn; R21/22 — C; R34 — R43 — R52-R53

< 15Wt %

CAS No.: 2579-20-6EC No.: 219-941-5

1,3-CyclohexanedimethanamineSkin Corr. 1C, Acute Tox. 4, Skin Sens. 1

Danger H302-H312-H314-H317

< 15Wt %

CAS No.: 10563-29-8EC No.: 234-148-4

N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamineSkin Corr. 1A, Acute Tox. 4, Skin Sens. 1

Danger H302-H312-H314-H317

< 15Wt %

CAS No.: 260549-92-6 Decanedioic acid, compds. w/ 1,3-benzenedimethanamineEye Dam. 1

Danger H318

Xi; R41

5 – 10Wt %

CAS No.: 68439-46-3 Oxoalkohol(C9/11)-5 EOEye Dam. 1, Acute Tox. 4

Danger H302-H318

Xn; R22 — Xi; R41

< 2Wt %

Full text of R-, H- and EUH-phrases: see section 16.

S4: First aid measures

4.1 Description of first aid measures General information: Remove contaminated, saturated clothing immediately.Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician.In case of skin contact: Wash immediately with: Water and soap. In case of skin irritati-on, consult a physician.After eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.After ingestion: Rinse mouth immediately and drink plenty of water. Get immediate medical advice/attention.

4.2. Most important symptoms and effects, both acute and delayedNo information available.

4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.

S5: Firefighting measures

5.1 Extinguishing mediaSuitable extinguishing media: Carbon dioxide (CO2) - Extinguishing powder - Water spray Unsuitable extinguishing media: Full water jet5.2. Special hazards arising from the substance or mixtureDuring heating or in case of fire, toxic gases is possible.Hazardous combustion products: CNitrogen oxides (NOx) Carbon monoxide. Carbon dioxide (CO2)5.3. Advice for firefightersIn case of fire: Wear self-contained breathing apparatus.5.4. Additional informationDo not inhale explosion and combustion gases. Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

S6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures:

2017

1017

-ENG

sbmplus.com 2

Eye/face protection: Eye glasses with side protectionSkin protection:Hand protectionSuitable material: NR (natural rubber, natural latex) FKM (fluoro rubber) PVC (Polyvinyl chloride) Thickness of the glove material: >= 0,5 mm. Check leak tightness/impermeability prior to use. Breakthrough times and swelling properties of thematerial must be taken into consideration. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.Body protection: Protective clothingRespiratory protection: Respiratory protection necessary at: exceeding exposure limit values insufficient ventilation Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190).8.2.3. Recommended Filter type: A -P2 Environmental exposure controls: See section 7. No additional measures necessary.

8.3. Additional informationNo data available

S9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance• Physical state: liquid • Colour: light yellow• Odour: AminesSafety relevant basis data:

at °C method remark

pH not determined

Melting point/freezing point not determined

Freezing point not determined not determined

Initial boiling point and boiling range > 100 °C

Decomposition temperature (°C): not determined

Flash point > 100 °C

Evaporation rate not determined

Ignition temperature in °C not determined

Upper/lower flammability or explosive limits

not determined

Vapour pressure 23 hPa 20 °C

Vapour density not determined

Density 1.009 g/cm³ 20 °C

Bulk density not determined

Water solubility (g/L) partially miscible

Partition coefficient: n-octanol/ water not determined

Dynamic viscosity not determined

Kinematic viscosity not determined 40 °C

9.2. Other informationNo data available

S10: Stability and reactivity10.1 Reactivity: No hazardous reaction when handled and stored according to provisions.10.2 Chemical stability: The mixture is chemically stable under recommended conditions of storage, use and temperature.

10.3 Possibility of hazardous reactions: No hazardous reaction when handled and stored according to provisions.

10.4 Conditions to avoid: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

10.5. Incompatible materialsAlkali (lye) - Acid - Oxidising agent, strong

10.6. Hazardous decomposition productsDuring heating or in case of fire, toxic gases is possible.

S11: Toxicological information

6.1.1. For non-emergency personnelPersonal precautions: Use personal protection equipment. Avoid contact with skin, eyes and clothes.6.1.2. For emergency respondersPersonal protection equipment: Use appropriate respiratory protection.

6.2. Environmental precautionsDo not allow to enter into soil/subsoil. Do not empty into drains.

6.3. Methods and material for containment and cleaning upFor containment: Suitable material for taking up: Sand Kieselguhr Universal binder Chemical binding agents, containing acidsFor cleaning up: Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

6.4. Reference to other sectionsSafe handling: see section 7Personal protection equipment: see section 8Disposal: see section 13

6.5. Additional informationClear spills immediately.

S7: Handling and storage7.1 Precautions for safe handling: Protective measuresAdvices on safe handling: Keep container tightly closed. Minimum standard for preven-tive measures while handling with working materials are specified in the TRGS 500.Fire prevent measures: Keep away from sources of ignition. - No smoking.Environmental precautions: Shafts and sewers must be protected from entry of the product.Advices on general occupational hygieneMinimum standard for preventive measures while handling with working materials are specified in the TRGS 500. Wash hands before breaks and after work. Apply skin care products after work. When using do not eat, drink, smoke, sniff. Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing immediately.

7.2 Conditions for safe storage, including any incompatibilities: Requirements for storage rooms and vessels: Shafts and sewers must be protected from entry of the product. Keep/Store only in original container.Hints on storage assembly: Do not store together with: Food and feedingstuffsStorage class: 8 AFurther information on storage conditions: Keep locked up and out of reach of children.

7.3 Specific end use(s): No data available

S8: Exposure controls/personal protection8.1 Control parameters: 8.1.1. Occupational exposure limit values: No data available8.1.2. biological limit values: No data available8.1.3. DNEL-/PNEC-values:

Substance name DNEL value DNEL type Exposure route

benzyl alcoholCAS No.: 100-51-6

90 mg/m³ DNEL worker DNEL long-term inhalative (systemic)


9.5 mg/kgbw/day

DNEL worker DNEL long-term dermal (systemic)

3-aminomethyl-3,5,5-trimethylcyclohexylamineCAS No.: 2855-13-2

20.1 mg/m³ DNEL worker DNEL acute inhalative (systemic)

Substance name PNEC value PNEC type


1 mg/l PNEC aquatic, freshwater


0.1 mg/l PNEC aquatic, marine water


0.06 mg/l PNEC aquatic, freshwater


0.006 mg/l PNEC aquatic, marine water

8.2 Exposure controls8.2.1. Appropriate engineering controls: No data available8.2.2. Personal protection equipment:


3 sbmplus.com


11.1. Information on toxicological effects

CAS No. Substance name Toxicological information

100-51-6 benzyl alcohol LD50 oral: 1,230 mg/l (Rat)LD50 dermal: 2,000 mg/l (Rabbit)ATE inhalativ Dämpfe: 11 mg/l

2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine

LD50 oral: 1,030 mg/kg (Mouse)LD50 dermal: 1,840 mg/kg (Rabbit)

2579-20-6 1,3-Cyclohexanedimethanamine LD50 oral: 700 mg/kg (Rat)LD50 dermal: 1,700 mg/kg (Rabbit)

2605-49-92-6

Decanedioic acid, compds. w/ 1,3-benzenedimethanamine

LD50 oral: 2 mg/kg (Rat)LD50 dermal: 2 mg/kg (Rabbit)

10563-29-8 N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine

LD50 oral: 2,000 mg/kg (Rat)LD50 dermal: 1,310 mg/kg (Rat)

68439-46-3 Oxoalkohol(C9/11)-5 EO LD50 oral: 2,000 mg/kg (Rat)

• Acute oral toxicity: There are no data available on the preparation/mixture itself.• Acute dermal toxicity: There are no data available on the preparation/mixture itself.• Acute inhalation toxicity: There are no data available on the preparation/mixture

itself.• Skin corrosion/irritation: Corrosive• Eye damage/irritation: strongly corrosive.• Respiratory or skin sensitisation: May cause sensitization by inhalation and skin

contact.• Germ cell mutagenicity: No indications of human germ cell mutagenicity exist.• Carcinogenicity: No indication of human carcinogenicity.• Reproductive toxicity: No indications of human reproductive toxicity exist.• Additional information: If ingested, severe burns of the mouth and throat and to the

danger of perforation of the esophagus and stomach.

S12: Ecological information 12.1. Toxicity

CAS No. Substance name Toxicological information

100-51-6 benzyl alcohol LC50: 645 mg/l 4 d (Leuciscus idus (golden orfe))EC50: 400 mg/l 4 d (Daphnia magna)ErC50: 640 mg/l 4 d

2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine

LC50: 110 mg/l 4 d (Leuciscus idus (golden orfe))EC50: 23 mg/l 2 d (Daphnia magna)ErC50: 50 mg/l 3 d

2579-20-6 1,3-Cyclohexanedimethanamine EC50: 90 mg/lLC50: 130 mg/l

10563-29-8 N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine

EC50: 181 mg/l 1 dLC50: 220 mg/l 4 dEC50: 9.2 mg/l 2 d

Aquatic toxicity: There are no data available on the preparation/mixture itself.Sediment toxicity: There are no data available on the preparation/mixture itself.Terrestrial toxicity: There are no data available on the preparation/mixture itself.12.2. Persistence and degradabilityAbiotic degradation: No information available.12.3. Bioaccumulative potentialAccumulation / Evaluation: No information available.12.4. Mobility in soilNo information available.12.5. Results of PBT and vPvB assessmentThe substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.12.6. Other adverse effects: No information available.

S13: Disposal considerations13.1. Waste treatment methodsDispose of waste according to applicable legislation.13.1.1. Product/Packaging disposalWaste codes/waste designations according to EWC/AVV.Waste code product:remark: The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.Waste treatment optionsAppropriate disposal / Product: Dispose of waste according to applicable legislation.Appropriate disposal / Package: Handle contaminated packages in the same way as the

substance itself.13.2. Additional informationDelivery to an approved waste disposal company.

S14: Transport information

Land transport (ADR/RID)

Inland waterway craft(ADN)

Sea transport (IMDG) Air transport (ICAOTI/ IATA-DGR)

14.1. UN-No.

2735 2735 2735 2735

14.2. UN proper shipping name

AMINES, LIQUID, CORROSIVE,N.O.S. (ISOPHO-RONEDIAMINE,Benzyl alcohol )




14.3. Transport hazard class(es)

8 8 8 8

14.4. Packing group

III III III III

14.5. Environmental hazards

no no no no

14.6. Special precautions for user

Special provisions:Limited quantity(LQ): 5 LHazard identificationnumber (Kemler No.): 80Classification code: C7tunnel restriction code: Eremark:

Special provisions:Limited quantity(LQ): 5 LClassification code:C7remark:

Special provisions:Limited quantity(LQ): 5 LEmS-No.: F-A, S-Bremark:

Special provisions:Limited quantity(LQ):remark:

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

not applicable not applicable not applicable not applicable

S15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixture 15.1.1. EU legislation: No data available15.1.2. National regulations[DE] National regulationsRestrictions of occupation: 22 JArbSchG. 5 MuSchRiV.Water hazard class (WGK)WGK: 2 - deutlich wassergefährdendDescription: hazardous to water (WGK 2)Berufsgenossenschaftliche Vorschriften (BGV):

Berufsgenossenschaftliche Regeln (BGR) 190, 192, 195BG code: M 042 “skin protection”; M 004 “Irritating substances / corrosive substances”UVV: “Processing of coating materials” (BGV D 25)Practice Guide for the handling of epoxy resins (issued by the professional association in the construction industry) - www.bgbau.de or www.gisbau.deEpoxy systems safely handle (published by Plastics Europe) - www.plasticseurope.orgBGR 227 “Epoxy Resins” (issued by the Association of BGs) - www.dguv.de

15.2. Chemical Safety Assessment: No data available15.3. Additional information: No data available

S16: Other information16.1. Indication of changesSECTION 1: Identification of the substance/mixture and of the company/undertaking16.2. Abbreviations and acronymsSee overview table at www.euphrac.eu

• AGW: workplace exposure limit• Technical Rule: Technical Guidelines for Hazardous Substances• TLV - Threshold Limit Value TWA - Time Weighted Average• STEL - short term exposure limit for permissible workplace concentration -

Permissible Workplace concentration

4sbmplus.com


• STOT RE - Specific target organ toxicity (repeated exposure)• Acute Tox. - Acute toxicity• PBT - substances which are persistent, bioaccumulative and toxic• vPvB - substances which are very persistent and very bioaccumulative• ADR: Accord européen sur le transport of marchandises dangereuses par Route

(European agreemen• Concerning the International Carriage of Dangerous Goods by Road)• RID: Government regulation internationally concernant le transport of

marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)

• IMDG: International Maritime Code for Dangerous Goods• IATA: International Air Transport Association• IATA-DGR: Dangerous Goods Regulations by the “International Air Transport

Association” (IATA) • ICAO: International Civil Aviation Organization• ICAO-TI: Technical Instructions by the “International Civil Aviation Organization”

(ICAO)• GHS: Globally Harmonized System of Classification and Labeling of Chemicals• EEC: Hazardous Substances (Ordinance on Hazardous Substances, Germany)

16.3. Key literature references and sources for dataEuropean Chemicals Agency (ECHA), ECHA CHEM Registered substancesOECD The Global Portal to Information on Chemical Substances (ChemPortal)Institute for Occupational Safety and Health of the German Social Accident Insurance (IFA): GESTISsubstance database and International limit values for chemical substancesFederal Environment Agency, Section IV 2.4: Documentation and Information Centre substances hazardous to water Rigoletto (catalog substances hazardous to water)

16.4. Classification for mixtures and used evaluation method according toregulation (EC) 1272/2008 [CLP]Classification according to Regulation (EC) No. 1272/2008 [CLP]:

Hazard classes and hazard categories

Hazard statements Classification procedure

Acute toxicity (oral) (Acute Tox. 4) H302: Harmful if swallowed.

Acute toxicity (dermal) (Acute Tox. 4) H312: Harmful in contact with skin.

Skin corrosion/irritation (Skin Corr. 1A)

H314: Causes severe skin burns and eye damage.

Respiratory or skin sensitisation (Skin Sens. 1)

H317: May cause an allergic skin reaction.

Serious eye damage/eye irritation (Eye Dam. 1)

H318: Causes serious eye damage.

Acute toxicity (inhalative) (Acute Tox. 4)

H332: Harmful if inhaled.

16.5. Relevant R-, H- and EUH-phrases (Number and full text)

Hazard statements (R-phrases)

R20/22 Harmful by inhalation and if swallowed.

R21/22 Harmful in contact with skin and if swallowed.

R22 Harmful if swallowed.

R34 Causes burns.

R41 Risk of serious damage to eyes.

R43 May cause sensitisation by skin contact.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Hazard statements

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H314 Causes severe skin burns and eye damage.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H332 Harmful if inhaled.

H412 Harmful to aquatic life with long lasting effects.16.6. Training advice: No data available

16.7. Additional information

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new madeup material.

Creator of the safety data sheet:Uta Sabath GefahrgutberatungPostfach 15 01 0533731 Bielefeld

drainage b-component - sbmplus.com · 3 sbmplus.com drainage b-component safety data sheet...

Documents