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    Chemical-mechanical polishing (CMP) Electrochemical machining (ECM) Electrochemical grinding (ECG)

    ELID grinding Electric discharge machining (EDM) Abrasive water jet machining Ultrasonic grinding

    Electron beam machining Laser beam machining Ion beam machining . . . . .

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    Chemical-Mechanical Polishing (CMP)

    A method of controlling the planarity of themultiple metal and dielectric layers

    A process of physically removing material from

    places of high topography to flatten and levelthe wafer surface (IC wafer planarization)

    A wafer surface planarization technology

    applied in the manufacturing of sub-0.35 umsemiconductor devices.

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    Planarization

    Non-planar and planar interconnect layers

    [Borst, Grill and Gutmann 2002, pg. 46 -CMP of low dielectic constant polymersand organosilicate glasses, CL Borst, W. Gill, R.J. Gutmann]

    Planarity across the die is important for photolithography processes,which projects a pattern of light onto the wafer surface

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    Principle of CMP Process

    [Borst, Grill and Gutmann 2002, pg. 48]

    A slurry consisting of chemical regents and abrasive particles isdispensed to create a lubricating layer between the pad surface andthe wafer. The slurry contains chemicals that react with the wafersurface, and abrasive particles that impact the wafer surface toachieve mechanical removal.

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    CMP Process Parameters

    The wide array of parameters and the competing interactionof effects makes CMP a difficult process to model andpredict

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    CMP Abrasives

    The choice of slurry abrasive particle (vary in size, shape andhardness) is vital for achieving the desired removal rate andsurface roughness of a material.

    CeO2, ZrO2 and SiO2 in high pH solutions are commonly used topolish silicon oxide, and Al2O3 is most commonly used for metal

    (Cu W, AL) CMP.

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    CMP- material removal

    Chemical-mechanical planarization chemical reactionandmechanical energycombined to achieve material removal fromhigh regions on the wafer surface, leaving the low regionsrelatively untouched

    [Borst, Grill and Gutmann 2002, pg. 49]

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    CMP Process Models

    Fluid mechanics-based:

    2-step removal process=

    chemical modification offilm surface layerfollowed by abrasion ofthe modified layer

    Contact mechanics-based:

    30-40mm thickliquid slurry film

    Combination of pressure and velocity

    Lubricatinglayer

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    CMP - Process

    Surface roughness nano-finish achievable

    AFM scan before polished

    AFM scan after polished

    Nanometer-scale scratches observed

    High roughness and scratchingcaused by large mechanicalabrasion. Low roughness andscratching suggest the presenceof a protective layer

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    CMP - SPCR

    Solid phase chemical reaction (SPCR)

    [Chen, Shu and Lee 2003] J. of Matl Proc Techn, 140 (2003) 373-78

    Chemical passivation layer generated: process ofinducing and removing the chemical passivation layerthru force of action

    Silicon wafer as substrateand BaCo3 as abrasive

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    CMP Machines

    - self-leveling upper head with both rotational and linear(both vertical for loading and unloading and horizontalfor oscillating) motions, which holds a wafer or wafercoupon of any shape from 0.25 to 4,

    - mechanically applied servo-controlled normal loadprogrammable from 5 to 500 N thus producing contactpressures from 0.05 to 500 psi,

    - self-leveling spring-loaded upper holder with passiverotation, which holds a conditioner or another specimenfrom 0.5 to 4.25,

    - either rotational or orbital lower platen for a polishingpad from 1 to 9. - slurry feeding and draining.

    Example:

    (source: http://www.cetr.com/Brochures)

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    Electrochemical Machining (ECM)

    A controlled anodic electrochemical dissolutionprocess of the workpiece (anode) with the tool(cathode) in an electrolytic cell, during an electrolysis

    process

    (source: http://www.unl.edu/nmrc/ecm1/ecm1.htm)

    Scheme of electrochemical machining (ECM) process

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    Principle of ECM (1)

    An electrochemical anodic dissolution process inwhich a direct current with high density and lowvoltage is passed between a workpiece and a pre-shaped tool (the cathode).

    At the anodic workpiece surface, metal is dissolvedinto metallic ions by the deplating reaction, and thusthe tool shape is copied into the workpiece.

    A relatively new and important method of removingmetal by anodic dissolution and offers a number ofadvantages over other machining methods.

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    Principle of ECM (2)

    Example:electrochemical reactions during ECM of ironin sodium chloride (NaCl) electrolyte

    At the anode (+):

    At the cathode (-) :

    electrolysis has involved thedissolution of iron from theanode, and the generation ofhydrogen at the cathode. Noother actions take place atthe electrodes.

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    Principle of ECM (3)

    Metal removal is effected by a suitably shaped toolelectrode, and the parts thus produced have thespecified shape, dimensions, and surface finish.

    ECM forming is carried out so that the shape of thetool electrode is transferred onto, or duplicated in, the

    workpiece.

    High accuracy in shape duplication and high rates of

    metal removal, effected at very high current densities ofthe order 10 100 A/cm2, at relative low voltage from 8to 30 V, while maintaining a very narrow machining gap(of the order of 0.1 mm) by feeding the tool electrode inthe direction of metal removal from the work surface,with feed rate from 0.1 to 20 mm/min.

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    Common Uses for ECM

    Duplicating, drilling and sinking operations in themanufacture of dies, press and glass-making moulds,turbine and compressor blades for gas-turbine engine,the generation of passages, cavities, holes and slots in

    parts, and the like

    Electrochemical sinking operation

    NC electrochemical contouring usingsimple-universal tool-electrode

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    ECM Machining System

    the machine itself the power supply

    the electrolyte circulation system the control system

    ECM die sinking machine tool (courtesy AEG-Elotherm-Germany)

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    Operating Parameters of ECM

    Working voltage between the tool electrode(cathode) and workpiece (anode)

    Machining feed rate

    Inlet and outlet pressure of electrolyte (orflow rate)

    Inlet temperature of electrolyte

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    Typical parameters and conditions of ECM

    Power supply -

    Type: Direct Current

    Voltage: 5 to 30 V (continue or pulse)

    Current: 50 to 40,000 A

    Current Density: 10 to 500 A/cm2 [ 65 to 3200 A/in2]

    Electrolyte -Type and Concentration

    Most used: NaCl at 60 to 240 g/l [ to 2 lb/gal]

    Frequently used: NaNO3

    at 120 to 480 g/l [1 to 4 lb/gal ]

    Less Frequently used: Proprietary Mixture

    Temperature : 20 to 50o C [68 to 122oF]

    Flow rate: 1 l/min/100A [0.264 gal/min/100A]

    Velocity : 1500 to 3000 m/min [5000 to 10,000 fpm]

    Inlet Pressure: 0.15 to 3 MPa [22 to 436 psi]

    Outlet Pressure: 0.1 to 0.3 MPa [15 to 43.6

    Frontal Working Gap : 0.05 to 0.3mm [0.002 to 0.012 in]Feed rate: 0.1 to 20mm/min [0.004 to 0.7 in/min

    Electrode material: Brass, Copper, Bronze

    Tolerance -2-dimensional shapes: 0.05-0.2 mm

    [0.002- 0.008 in]

    3-dimensioanl shapes: 0.1mm [0.004 in]

    Surface Roughness (Ra) 0.1 to 2.5 mm

    [4 to 100 microinches]

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    ECMed Parts

    Examples of machined parts byECM (AEG-Elotherm-Germany)

    Examples of machine parts after deburring(AEG-Elotherm-Germany)

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    Summary of ECM

    The rate of material machining depend on workpiecematerial, is equal from 1,200 to 2,500 mm3 for each1,000A of power supply

    The accuracy of ECM depend on shape and dimensions of

    machining workpiece and approximately from 0.05 mm to0.3 mm at using continuous current, and from 0.02 mm to0.05 mm at using pulse ECM;

    The surface roughness of machined surface is decreasingwith increasing machining rate (for typical materials),approximately from Ra=0.1 mm to Ra= 2.5 mm;

    ECM generates no residual stress into material ofworkpiece; and there is no tool wear.

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    Nano Machining:

    Micro Machining:

    A work material removed process by cutting tools under

    micro scales. That is the cutting parameters used are in

    micrometer scales: 1 ~ 999 mm depth of cut or 1 ~ 999 mm

    undeformed chip thickness.

    A work material removed process by cutting tools under

    nano scales. That is the cutting parameters used are in

    nanometer scales: 1 ~ 999 nm depth of cut or 1 ~ 999 nm

    undeformed chip thickness.

    Non-conventional Precision Machining

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    Precision Finishing (1)

    Precision grinding involved a maximumprecision to about 1.0 mm and expected toreach 100nm

    SPDT (single-point diamond turning), UPDG(ultra-precision diamond grinding), ELIDgrinding (electrolytic in-process dressing), etc.

    Applications to optical and electronicindustries

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    Precision Finishing (2)

    SPDT, UPDG processes are similar in thatchips of usually small size

    Capable of producing surfaces with mirrorfinishing w/o polishing

    Using specially designed machine tools of

    high rigidity with air bearing spindles

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    SPDT vs. UPDG

    Major problems is the appearance ofsubsurface defects in the form ofmicrocracks

    SPDT is performed on very soft ductilemetals, e.g. pure copper, while UPDGusually performed on very hard brittle

    materials, e.g. glasses and ceramics.

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    Ductile Mode Machining

    Especially for brittle materials, is a machining processthat work materials are removed by dislocation orplastic deformation rather than cracks propagation.That is, the cutting process is dominated bydislocation rather than flaw extension.

    Comparison with brittle fracture:

    Easy controlling of machining process; Free of cracks;

    Smoother surface.

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    High hardness

    High strength

    Good fracture toughness High wear resistance

    Good chemical stability

    Good thermal stability

    Characteristics ofBrittle Materials

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    A transition in the chip formation from brittle to ductile

    as the depth of cut decreases to very small

    Grinding brittle materials in a ductile manner early in

    1954 by King and Tabor The first systematic studies of grinding ductility in 1979

    by Swain

    Other experiments of single grit abrasion tests on many

    brittle materials including semiconductors, glasses andadvanced ceramics

    Grinding of Brittle Materials

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    Form/Dimensional

    Accuracy < 0.1um

    Surface Roughness

    < 10 nm

    Nano Precision Machining

    Toshiba ULG 100C Diamond Turning Machine

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    Silicon (111) Wafer:

    3 inches Diameter

    0.5 mm Thickness

    Single Crystal Diamond Tool (orSPDT):

    Rake Angle 0

    Nose Radius 0.3 mm

    Cutting Edge Radius 40 nm

    Cutting Conditions:

    Spindle Rotation Speed 1000 rpm

    Nanomachining experimental setup

    on an ultra-precision machine tool

    Nano Surface Machining by SPDT

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    (photos of silicon wafer surfaces)

    (a)Diamond turning surface (b) Original polished surface

    Mirror Surface Finishing

    Mirror surface finish of hard and brittle material can be possible

    when material removal taking place thru plastic deformationratherthan fracture

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    Aspheric glass lens

    Spherical mirror Mirror finish by diamond turning

    Machining of aspheric glass mould

    Mirror Finished Products

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    ELID Grinding (1)

    Schematic illustration of ELID grinding [Lim et al, 2002]

    The wheel is continuously dressed while the part is machined The difference between ELID and conv. Grinding is the applicationof a current during grinding. Applications incl. grinding of silicon wafer, nano surface finishingon difficult-to-machine materials, e.g. glasses, ceramics, etc.

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    ELID Grinding (2)

    Set-up of the continuous ELID of a metal-bonded diamond wheel[Shaw 1996]

    The bond is depleted continuously by a pulsed d.c. power

    supply, enabling optimum protrusion at all timesProcess applicable to grinding of either electrical conducting ornon-conducting work materials but only with metal-bondedwheels

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    ELID Grinding (3)

    Schematic diagram of the experimental set-up

    [Lim et al, 2002]

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    NUS Experimental Setup

    Machine tool: Deckel Maho DMU50V 5 Axis

    Grinding wheel: #325,#1200,#4000 @3000rpm

    Feed Rate : 100~600mm/min

    Dressing Current : Duty ratio 10~60% @90V

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    Principle of ELID Grinding

    Cast-iron bonding material for holding the diamond particles is removed

    by the electrolysis during in-process dressing and fresh diamond particles

    protrude out for grinding.

    Super fine diamond grit (grit size up to #150,000)

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    Without ELID(0.3795mm) With ELID (Ra 0.1491mm)

    Effect of ELID

    Grinding conditions: Feedrate: 500mm/min

    Spindle: 3000rpm

    Electric power: 0%, 30%@90V

    Wheel : CIB-D wheel #1200

    Silicon afe plana i ation b

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    Workpiece

    Tool

    dynamometer

    Wheel

    Electrode

    Highly efficient due to high removal rate

    Uniform ground surface across the wafer

    Relatively low cost involved in this process

    Silicon wafer planarization byELID Grinding

    Ra 3nm (10nm required)

    Multi-process Miniature Machine Tool

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    Multi-process Miniature Machine Toolfor-machining

    Multi purpose machine toolfor micro machining

    (-turning, -milling, -

    drilling, -EDM, -ECM)

    Working area :

    200100100mm

    (Resolution 0.1 m)

    DI water /Oil for EDM

    medium

    Design of motion controller

    6.5 micron Hole1.5 mm length shaft

    Contact: Dr. A.S. Kumar,[email protected], MicroTool

    Interchangeable

    spindle unit

    Micro WEDG

    MicroEDMMicro Milling

    Micro Turning

    Micro WEDM

    On MachineMeasurement

    mailto:[email protected]:[email protected]
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    References

    1. C.L. Borst, W.N. Gill and R.J. Gutmann, Chemical-Mechanical Polishing of Low Dielectric ConstantPolymers and Organosilicate Glasses, KluwerAcademic Publishers,, Boston,2002

    2. M. C. Shaw, Principles of Abrasive Processing,Clarendon Press, Oxford, 1996

    3. C.C. Chen, L.S. Shu and S.R. Lee, J. of MaterialsProcessing Techn, 140(2003), pp.373-78

    4. ECM, http://www.unl.edu/nmrc/ecm1/ecm1.htm5. H.S. Lim, K. Fathima, et al., Intl J. of Machine Tool &Manufacture, 42 (2003) pp935-43.

    http://www.unl.edu/nmrc/ecm1/ecm1.htmhttp://www.unl.edu/nmrc/ecm1/ecm1.htm