eelectric energy harvesting through piezoelectric polymers formal design review don jenket, ii kathy...
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![Page 1: Eelectric Energy Harvesting Through Piezoelectric Polymers Formal Design Review Don Jenket, II Kathy Li Peter Stone](https://reader035.vdocument.in/reader035/viewer/2022062714/56649d5e5503460f94a3e595/html5/thumbnails/1.jpg)
EelectricEnergy Harvesting
Through Piezoelectric Polymers
Formal Design Review
Don Jenket, II
Kathy Li
Peter Stone
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March 11, 2004 Eelectric Formal Design Review
Presentation Overview
Project Goals
Choice of Materials
Choice of Processing Techniques
Device Architecture
Future Tests
Revised Timeline
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March 11, 2004 Eelectric Formal Design Review
Objective
DARPA Objective: Convert mechanical energy from a fluid medium into electrical energy. Fluid flow creates oscillations in an eel body Creates strain energy that is converted to AC
electrical output by piezoelectric polymers AC output is stored and/or utilized
3.082 Objective: Harness enough power from air flow to operate a L.E.D.
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March 11, 2004 Eelectric Formal Design Review
PVDF- Poly(vinylidene fluoride)
CC
H
H
F
F n
PropertiesChemically InertFlexibleHigh Mechanical Strength
ProductionReact HF and methylchloroform in a refrigerant gasPolymerization from emulsion or suspension by free radical vinyl polymerization
References: http://www.psrc.usm.edu/macrog/pvdf.htm, Accessed on: 3-9-04; Piezoelectric SOLEF PVDF Films. K-Tech Corp., 1993.
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March 11, 2004 Eelectric Formal Design Review
Piezoelectric PVDFMolecular Origin Fluorine atoms draw electronic density away from carbon and
towards themselves Leads to strong dipoles in C-F bonds
Piezoelectric Model of PVDF (Davis 1978) Piezoelectric activity based upon dipole orientation within
crystalline phase of polymer Need a polar crystal form for permanent polarization
Reference: Davis, G.T., Mckinney, J.E., Broadhurst, M.G., Roth, S.C. Electric-filed-induced phase changes in poly(vinylidene fluoride). Journal of Applied Physics 49(10), October, 1978.
-phase (piezoelectric)
-phase (anti-parallel dipoles)
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March 11, 2004 Eelectric Formal Design Review
Piezoelectric PVDFPoled by the Bauer Process Biaxially stretch film: Orients some crystallites with their polar axis
normal to the film Application of a strong electric field across the thickness of the film
coordinates polarity Produces high volume fractions of -phase crystallites uniformly
throughout the poled material
Electromechanic coupling factor 0.11
Young’s Modulus ~2,500 MPa
Melting Point 175º C
Depoling Temperature 90º C
Selected Properties of 40 m thick bioriented PVDF
Table courtesy of K-Tech CorporationReference: Piezoelectric SOLEF PVDF Films. K-Tech Corp., 1993.
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March 11, 2004 Eelectric Formal Design Review
Tensile Testing of PVDFCross-sectional Area of the Film Tested: 1 cm X 40 microns = 4 X 10-7 m2
Measured strain: .063Force at .063 strain: 3.95 lbs.
Elastic Modulus Calculated: 2.56 GPa
E = -1
Clamp
Rubber
PVDF
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March 11, 2004 Eelectric Formal Design Review
Electrodes and WiresDesired Properties Electrodes
High Conductivity Flexibility Won’t oxidize
Wires Ease of Attachment Flexibility
The Process Attach Electrodes using RF Magnetron Sputtering Sputter 40 nm thick Gold electrodes on sample Attach 3 mil copper wire with silver paste
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March 11, 2004 Eelectric Formal Design Review
Schematic of Sputtering
Vacuum Pump
Vacuum Pump
Main Chamber
Load-Lock Chamber
Sample Holder; Sample faces down
Sample Holder Rotates
Sputter Guns
Load-Lock Arm
Adapted From: Twisselmann, Douglas J. The Origins of Substrate-Topography-Induced Magnetic Anisotropy in Sputered Cobalt Alloy Films . MIT Doctoral Thesis, February, 2001
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March 11, 2004 Eelectric Formal Design Review
Sputtering Apparatus
Load-Lock Chamber
Vacuum Pump Main Chamber
Sample Holder
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March 11, 2004 Eelectric Formal Design Review
Sputtering Target
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March 11, 2004 Eelectric Formal Design Review
“Eel Tail” Schematic
Top View
Side View Front View
Cu Wire
6-10 cm
2 cm
6-10 cm 2 cm
0.04 mm
Cu Wire
Silver paste
Gold Electrode
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March 11, 2004 Eelectric Formal Design Review
Air Flow Testing of Eel TailFor cost purposes, used unpoled PVDFThickness of PVDF film: 74 m.Can visually inspect eel oscillations Wave forms Estimate flexure and strain
Tested 2 cm by {5,6,7,8,9,10} cm tails
Fan PVDF
Copper “Fin”
Length= 5-10 cm
2 cm
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March 11, 2004 Eelectric Formal Design Review
Air Flow Testing of Eel Tail
2cm x 6cm PVDF
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March 11, 2004 Eelectric Formal Design Review
Air Flow Testing of Eel Tail
2cm x 10cm PVDF
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March 11, 2004 Eelectric Formal Design Review
Piezoelectric Response in Air Flow
2cm x 6cm Piezoelectric PVDF
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March 11, 2004 Eelectric Formal Design Review
Estimation of Piezoelectric Response
V = 3/8 * (t/L)2 * h31 * z,
t= thickness; L = Length; z = bending radius and
h31 = g31*(c11 + c12)+ g33*c13
g31 = 6*10-12/11o [V*m/N] c11 = 3.7 GN*m-2 L = 6 cm
g33 = -0.14 [V*m/N] c12 = 1.47 GN*m-2 t = 40 m
z = 3 cm c13 = 1.23 GN*m-2
Equation taken from: Herbert, J.M., Moulson, A.J. Electroceramics: Materials, Properties, Applications. Chapman and Hall: London, 1990.
Piezoelectric Constants taken from: Roh, Y. et al. Characterization of All the Electic, Dielectric and Piezoelectric Constants of uniaxially oriented poled PVDF films. IEEE Transactions on Ultrasonics, Ferroelectics and Frequency Control. 49(6) June 2002.
If we model the tail as a cantilever:
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March 11, 2004 Eelectric Formal Design Review
Estimation of Piezoelectric Response
Estimated voltage: 0.7322 VVoltage Measured in Air Field: 0.207 VVoltage required to bias Ge-doped diode: 0.2 VSources of Error in EstimationCantilever does not account for oscillationWave form of eel is not a cantilever; looks
more like a sinusoid.
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March 11, 2004 Eelectric Formal Design Review
Rectifier Design
ACin
Reference: http://www.mcitransformer.com/i_notes.html
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March 11, 2004 Eelectric Formal Design Review
Proposed Integrated Design
Fan
RectifierStorage Circuit
Electronics Housing
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March 11, 2004 Eelectric Formal Design Review
Future ResearchDynamic Mechanical Testing (DMA) - ?OscilloscopeQuantified wave forms (peak amplitude)Frequency
Continued Air Stream TestingPossible water system (time permitting)Environmental Protection stiffens the eelUnderstanding vortex shedding
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March 11, 2004 Eelectric Formal Design Review
Project Timeline
2/10 2/17 2/24 3/2 3/9 3/16 4/1 4/6 4/13 4/20 4/27 5/4 5/11Electroded piezoelectronic sampleObtain PVDFInvestigate electrode technologyAttach electrodes to PVDFPreliminary measurementsBuild PrototypeElectronic CircuitryEnvironmental ProtectionConstruct Housing/BarrierTest PrototypeAir testingOutput measurementOptimizing PrototypeBuild Prototype IIOptimizing CircuitryTest protoype IIInvestigate water (time permitting)Prepare DemoFinal Presentation