effect wood surface
TRANSCRIPT
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Effect of Wood Surface on Wood
Adhesive
Wood as an Adherend
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Adhesion
Adhesive – a substance capable of holding
materials together by surface attachment
Adherend – a substrate held to another substrateby an adhesive
Adhesives bond substrates together via chemical
interactions and/or mechanical interlocking
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Surface Properties: Wetting
Regardless of adhesion mechanism, optimal adhesion is
dependent upon effective contact of adhesive and
adherend; contact is dependent upon Surface Wetting phenomenon.
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Surface Energy: “Bond Breaking”
Bonds broken to create surfaces=“excess energy
in the surface” or “surface energy”
Surface does not exist of itself: It must be part ofan interface (two substances or phases)
Liquid-vapor, liquid-solid interactions result from
dispersion forces and hydrogen bonds
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Surface Energy vs. Surface Tension
Strictly, surface energy DOES NOT equal surface
tension
HOWEVER, it is generally impractical to measureprecise values, especially for solids
THUS, the terms “surface energy” and “surface
tension” are often taken as synonymous, exceptin theoretical treatments
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Wood Adherend Variables
A number of wood characteristics can affect the
performance of an adhesive. These
characteristics may be called “wood adherendvariables.”
The “top five” wood adherend variables are
described in the following slides, but notnecessarily in priority order.
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Wood Adherend Variables
1. PorosityWood is a porous cellular
solid
Flow of resin into pores,followed by curing,
improves the “mechanical
interlocking” mechanism of
adhesion.
Note that porosity varies in
the three principal planes
of wood structure.
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Wood Adherend Variables
2. Surface RoughnessSurface roughness is related
to porosity and to surface
preparation (machining)Smoother surfaces are
generally better for bonding,
e.g., knife planed vs. sawn
Smooth surface allows formore intimate contact of
adjacent substrates via a thin
glue lineRoughness: Macroscopic
and Microscopic
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Wood Adherend Variables
3. Wood DensityLower density woods are
generally easier to bond
due to their greaterdegree of porosity
% wood failure (a
measure of adhesive
bond quality) decreaseswith increasing wood
densityLow, medium, and high density oak
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Wood Adherend Variables
4. Wood Moisture ContentWood is hygroscopic!
MC too low or too high
will impede adhesion A MC range of 6-14% is
optimal for many wood
adhesives
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Wood Adherend Variables
5. Surface ChemistryOxidation by exposure to air or
heating (drying or friction from
machining) results in poor
wetting
Contamination by airborne
particles, dirt, grease, etc. has a
negative effect on surfaceproperties
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Wood Adherend Variables
5. Surface Chemistry, continuedExtractives may be driven
to surface by drying;many are hydrophobic,may inhibit reactions ofadhesives, or blockmicropores
In extreme cases, woodswith high extractivescontent (>20%) may benon-bondable
If adhesive cannot wet the
surface, the substrate cannot be
adhesively bonded.
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Surface Properties of Wood
Wood surface should be smooth, flat, and free of
machine marks and other surface irregularities,
including planer skips and crushed, torn andchipped grain.
The surface also should be free of burnishes,
exudates, oils, dirts and other debris.(because adhesives bond by surface attachment,
the physical and chemical conditions of the
adherend’s surface)
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Overdrying and overheating deteriorates the physical
condition of the wood (forcing the extractives to diffuse to
the surface)Wood surfaces can be chemically inactivated with
respect to adhesion by airborne chemical contaminants,
hydrophobic and chemically active extractives from the
wood.e
The deterioration of physical and chemical also can
interfere with the cure and resulting cohensive strength
of the adhesive.
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Extractive on Surfaces
Extractive on wood surfaces are the principal physical
and chemical contributors to surface inactivation, hence
to poor wettability by adhesives.
Resinous and oily exudates are hydrophobic ( repelwater)
The acidity of extractives can interfere the chemical cure
of adhesives. (the acid may accelerate the cure of analkaline phenolic adhesive, causing the adhesive to gel
prematurely and reducing the ability to wet, flow and
penetrate
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knife and Abrasive Planed
SurfacesWood should be surfaced to remove extractives and
other physical and chemical contaminants.
Experience and testing have proven that a smooth, knifecut surface is best for bonding.
The crushed and burnished surface inhibits adhesive
wetting and penetration.
Damaged surfaces are inherently weak and result in
poor bond strenght.
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Veneer SurfacesWood properties of veneer are essentially no different
from those lumber however manufacturing processes
change physical and chemical surface.
Peeling of log will resulted in loose side and tight side ofthe veneer.
Drying veneer to very low moisture content levels at very
high temperatures and drying at moderate temperatures
for prolonged periods, inactives surfaces, causing poor
wetting veneer hence poor bonding.