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Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol University Rama VI Road, Bangkok [email protected] http://nanotech.sc.mahidol.ac.th

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Page 1: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Electronic Nose Application for Essential Oil

Tanakorn OsotchanCapability Building Unit for NanoSceince and NanotechnologyFaculty of Science, Mahidol UniversityRama VI Road, [email protected]://nanotech.sc.mahidol.ac.th

Page 2: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

DefinitionAn essential oil is a concentrated, hydrophobic liquid containing volatile aroma compounds from plants. Essential oils are also known as volatile, ethereal oils or aetherolea, or simply as the "oil of" the plant from which they were extracted, such as oil of clove.

An oil is "essential" in the sense that it carries a distinctive scent, or essence, of the plant

Essential oils are generally extracted by distillation. Other processes include expression, or solvent extraction.

Page 3: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Utilizations An essential oil is used in perfumes, cosmetics, soap and other products, for flavoring food and drink, and for scenting incense and household cleaning products.

In recent decades with the popularity of aromatherapy, this essential oil plays an importance part of the branch of alternative medicine.

Page 4: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Use of Essential Oil

Page 5: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Demand for Essential Oils (India)

Year

Home Demand

1993-94 1994-95 1995-96 1996-97 1997-98

10.1 11 12.1 13.3 14.5

Year Demand for export (000 tones )

Total demands (000 tones )

93-94 94-95 95-96 96-97 97-98

1.2 1.6 2

2.6 3.4

11.3 12.4 14.1 15.9 17.9

Page 6: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Indian earning

Items Quantity (tones )

Values ( Rs )

Sandalwood Lemongrass Jasmine / tuberose concentrate Peppermint Eucalyptus Davana Palmorose Cedarwood Cardamon Clove oil

15 185

- 73

17.5 0276 0.295 0.677

- -

57.10 53.50 24.40 22.30 2.40 1.90 0.09 0.09

4.411 0426

Items Quantity (tones) Values ( Rs )

Bergamot mint Citrenella oil java Ceranium oil Japanese mint oil Linalol oil Peppermint oil Rose oil Spearmint

20 600 30

2500 50 40

0.01 80

30 800 300

4500 120 100 10

240

Page 7: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Page 8: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Melaleuca alternifolia.

monoterpene hydrocarbon

oxygenated monoterpene

Page 9: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Tasmanian lavender oil

Page 10: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (HPLC-GC)

Journal of Chromatography A, 936 (2001) 1–22

Page 11: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Multidimensional gas chromatography (MDGC)

Page 12: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Multidimensional gas chromatography (MDGC)

Page 13: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

GCxGC comprehensive two-dimensional gas chromatography

Page 14: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Vetiveria zizanioides(vetiver) oil by GC–MS

Page 15: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

vetiver

Page 16: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

vetiver

Page 17: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Essential oils (GC)

Journal of Chromatography A, 936 (2001) 1–22

Page 18: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Electronic Nose

Array of varieties of gas sensorsGas flow system; measure and recovery cyclesPrecondition of response signal; moisture & temperature Feature classification; principal componentAlgorithm to identify; neural network

Page 19: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coffee

JOURNAL OF FOOD COMPOSITION AND ANALYSIS (2001) 14, 513-522

Page 20: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coffee

JOURNAL OF FOOD COMPOSITION AND ANALYSIS (2001) 14, 513-522

Page 21: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coffee

JOURNAL OF FOOD COMPOSITION AND ANALYSIS (2001) 14, 513-522

Page 22: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coffee

JOURNAL OF FOOD COMPOSITION AND ANALYSIS (2001) 14, 513-522

Page 23: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Perfume

Sensors and Actuators B 92 (2003) 222–227

Page 24: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Perfume

Sensors and Actuators B 92 (2003) 222–227

Page 25: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Perfume

Sensors and Actuators B 92 (2003) 222–227

Page 26: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Perfume

Sensors and Actuators B 92 (2003) 222–227

Page 27: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Cassia (Cinnamomum cassia), thyme (Thymus vulgaris)and oregano (Origanum vulgare) essential oils

Commercialmodified food starches named Hi Cap 100 (derived fromwaxy maize), Capsul E (derived from tapioca), Encapsul855 (tapioca dextrin, corn dextrin) and N LOK (foodstarch modified with corn syrup added) obtained fromthe National Starch&Chemical (Hamburg, Germany)were used as encapsulating agents.

Page 28: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Hi Cap 100 (derived fromwaxy maize), Capsul E (derived from tapioca), Encapsul 855 (tapioca dextrin, corn dextrin), N LOK (food starch modified with corn syrup added)

Page 29: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Hi Cap 100 (derived fromwaxy maize), Capsul E (derived from tapioca), Encapsul 855 (tapioca dextrin, corn dextrin), N LOK (food starch modified with corn syrup added)

Page 30: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Hi Cap 100 (derived fromwaxy maize), Capsul E (derived from tapioca), Encapsul 855 (tapioca dextrin, corn dextrin), N LOK (food starch modified with corn syrup added)

Page 31: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Hi Cap 100 (derived from waxy maize), Capsul E (derived from tapioca), Encapsul 855 (tapioca dextrin, corn dextrin), N LOK (food starch modified with corn syrup added)

Page 32: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Microencapsulated flavours by electronic nose

Food Chemistry 92 (2005) 45–54

Page 33: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coriander (Coriandrum sativum L.)

Eur Food Res Technol (2007) 225:367–374

Page 34: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coriander (Coriandrum sativum L.)

Eur Food Res Technol (2007) 225:367–374

Page 35: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coriander (Coriandrum sativum L.)

Eur Food Res Technol (2007) 225:367–374

Page 36: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coriander (Coriandrum sativum L.)

Eur Food Res Technol (2007) 225:367–374

Page 37: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Coriander (Coriandrum sativum L.)

Eur Food Res Technol (2007) 225:367–374

Page 38: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Rose

Plant Physiology, December 2001, Vol. 127, pp. 1383–1389

rose (cv Fragrance Cloud) 1: 3-hexen-1-ol acetate, 2: n-hexyl acetate, 3: 2-phenylethyl alcohol, 4: citronellol, 5: 2-phenylethyl acetate, 6: citronellyl acetate,7: neryl acetate, 8: germacrene D

Arabidopsis (ecotype Colombia)fatty acid degradation products

Page 39: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Olive oils Geographical origin

Analytica Chimica Acta 567 (2006) 202–210

Page 40: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Olive oils Geographical origin

Analytica Chimica Acta 567 (2006) 202–210

Page 41: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 42: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 43: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 44: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 45: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 46: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 47: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153

Page 48: Electronic Nose Application for Essential Oil Tanakorn Osotchan Capability Building Unit for NanoSceince and Nanotechnology Faculty of Science, Mahidol

Cretan Lemon Seasonal Variation

J. Agric. Food Chem. 2002, 50, 147-153