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Page 1: End Show Slide 1 of 31 Periodic Trends 6.3. End Show © Copyright Pearson Prentice Hall Periodic Trends > Slide 2 of 31 Trends in Atomic Size What are

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Periodic Trends 6.3

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Periodic Trends >

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Trends in Atomic Size

Trends in Atomic Size

What are the trends among the elements for atomic size?

6.3

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Periodic Trends > Trends in Atomic Size

The atomic radius is one half of the distance between the nuclei of two atoms of the same element when the atoms are joined.

6.3

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Periodic Trends > Trends in Atomic Size

Group and Periodic Trends in Atomic Size

In general, atomic size increases from top to bottom within a group and increases from right to left across a period.

6.3

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Periodic Trends >

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Ions

Ions

How do ions form? Knowing this helps us to understand the trend in ionic size.

6.3

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Periodic Trends > Ions

Some compounds are composed of particles called ions.

• An ion is an atom or group of atoms that has a positive or negative charge.

• A cation is an ion with a positive charge.

• An anion is an ion with a negative charge.

6.3

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Periodic Trends > Ions

Positive and negative ions form when electrons are transferred between atoms.

6.3

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Periodic Trends > Ions

Positive and negative ions form when electrons are transferred between atoms.

6.3

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Periodic Trends >

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Trends in Ionization Energy

Trends in Ionization Energy

What are the trends among the elements for first ionization energy, ionic size, and electronegativity?

6.3

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Periodic Trends > Trends in Ionization Energy

The energy required to remove an electron from an atom is called ionization energy.

• The energy required to remove the first electron from an atom is called the first ionization energy.

• The energy required to remove an electron from an ion with a 1+ charge is called the second ionization energy.

6.3

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Periodic Trends > Trends in Ionization Energy

Group and Periodic Trends in Ionization Energy: First ionization energy tends to increase from bottom to top within a group and increase from left to right across a period.

6.3

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Periodic Trends > Trends in Ionic Size

Trends in Ionic Size

During reactions between metals and nonmetals, metal atoms tend to lose electrons, and nonmetal atoms tend to gain electrons. The transfer has a predictable effect on the size of the ions that form.

6.3

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Periodic Trends > Trends in Ionic Size

Cations are always smaller than the atoms from which they form.

Anions are always larger than the atoms from which they form.

6.3

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Periodic Trends > Trends in Ionic Size

Relative Sizes of Some Atoms and Ions

6.3

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Periodic Trends > Trends in Ionic Size

Trends in Ionic Size

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Periodic Trends > Trends in Electronegativity

Trends in Electronegativity

Electronegativity is the ability of an atom of an element to attract electrons when the atom is in a compound.

In general, electronegativity values increase from bottom to top within a group. For representative elements, the values tend to increase from left to right across a period.

6.3

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Periodic Trends > Trends in Electronegativity

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1. Which of the following sequences is correct for atomic size?

a. Mg > Al > S

b. Li > Na > K

c. F > N > B

d. F > Cl > Br

6.3 Section Quiz

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6.3 Section Quiz

2. Metals tend to

a. gain electrons to form cations.

b. gain electrons to form anions.

c. lose electrons to form anions.

d. lose electrons to form cations.

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6.3 Section Quiz

3. Which of the following is the most electronegative?

a. Cl

b. Se

c. Na

d. I