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Energy Diagrams: Drawing it Out

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Energy Diagram Parts Potential Energy of the reactants Potential Energy of the products Activation Energy E – the amount of energy required to reach the transition state or activated complex from the reactant Transition State, T s (Activated Complex) – when bonds break and form and reactants become products Enthalpy,  H – science word for heat, Energy of products – energy of reactants

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Page 1: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Energy Diagrams: Drawing it Out

Page 2: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Why are we learning this?

Energy diagrams show how a reaction works.

Energy diagrams display The energy of reactants and products The energy needed for a reaction to occur The energy absorbed or released due to

reaction

Page 3: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Energy Diagram Parts Potential Energy of the reactants Potential Energy of the products Activation Energy E – the amount of energy

required to reach the transition state or activated complex from the reactant

Transition State, Ts (Activated Complex) – when bonds break and form and reactants become products

Enthalpy, H – science word for heat, Energy of products – energy of reactants

Page 4: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products  

 

 

  

Page 5: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products  

 

 

  

Page 6: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products    

 

  

Page 7: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products    

 

  

Page 8: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products    

Potential Energy 

  

Page 9: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products    

Potential Energy 

  

Page 10: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products     max

Potential Energy high  low  

Page 11: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products     max

Potential Energy high  low  Kinetic Energy

Page 12: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products     max

Potential Energy high  low  Kinetic Energy

high min low

Page 13: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Potential and Kinetic Energy Changes during a CollisionEndothermic  Reactants Activated Complex Products     max

Potential Energy high  low  Uphill- endothermic! Kinetic Energy

high min low

Page 14: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Putting Pieces TogetherTransition State, Ts

Energy

Reaction

Reactants

Products

Activation Energy of forward reaction, EF

EF = Ts - ReactantsEnthalpy of forward reaction, HF

HF = Products - Reactants

Page 15: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Putting Pieces TogetherTransition State, Ts

Energy

Reaction

Reactants

Products

Activation Energy of reverse reaction, ER

ER = Ts - ProductsEnthalpy of forward reaction, HR

HR = Reactants - Products

Page 16: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Types of Energy Diagrams Endothermic – the reaction absorbs heat so

H is positive The reactants have less potential

energy than the products

A + B

AB

H > 0

A - - - B

Page 17: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Types of Energy Diagrams Exothermic – the reaction releases heat so

H is negative The reactants have more potential

energy than the products

A + B

ABH < 0

A - - - B

Page 18: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Types of Energy Diagrams Catalysts lower the activation energy of a

reaction by finding an alternate route. However, the change in heat, or enthalpy is the same.

A + B

ABH < 0

Blue without Catalyst

Green with Catalyst

A - - - B

Page 19: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Try it together

50

100

150

200

250

Use the numbers to find:

What is EF?

What is HF?

What is HR?

What is ER?

Page 20: Energy Diagrams: Drawing it Out. Why are we learning this? Energy diagrams show how a reaction works.…

Pick the slow and fast reaction

Ea Ea

Slow Fast- low Ea