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Enhanced Oil Recovery delivering breakthrough solutions
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EOR Study for Permian Basin
Wei Long, Ph.D.
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Permian Basin
• Permian basin located in the west
Texas and southeast New Mexico.
• Estimated OOIP for Permian Basin
was ~106 Bbbl, 29 Bbbl has been
produced today from 1339 reservoirs,
with ~73% OOIP left behind, including
31 Bbbl mobile oil and 46 Bbbl
residual oil.
• The Permian Basin produced 17% of
the total US oil production, and it
contains an estimated 22% of the
proved oil reserves in the US.
• A reservoir database was established
by Railroad Commission of Texas
(RRC) with reservoir number and
district, production, etc. for Texas.
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Outline
Introduction
• Reservoir management for CO2 flooding
− Impact of heterogeneity, WAG ratio, CO2 slug size, and Oil gravity
• Reservoir management for surfactant
− Well stimulation and surfactant flooding
• Reservoir management for mobility control
− CO2 foam flooding
• Managing uncertainty
• Summary
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Reservoir model
• Geological data:
• Reservoir depth at -5500 ft
• Reservoir thickness from 40 ft
to 100 ft
• Averaging porosity = 0.12
• Averaging permeability, k =
150 md
• Wettability: oil wet to
intermediate wet
• Simulation data:
• Reservoir size: 1000 ft x 1000
ft x 100 ft
• Grid size: 10 x 10 x 10
• Well Data: • One producer and one injector with well distance around 1400 ft (5 spot 40 acres)
• Injector is controlled by surface rate with 500 stb/d of water or 1500 Mscf/d of CO2
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Reservoir heterogeneity
• Rock types: − Rock type 1: = 0.03, k = 9.4 mD, Sor = 0.35, Siw = 0.35
− Rock type 2: = 0.12, k = 150 mD, Sor = 0.2, Siw = 0.3
− Rock type 3: = 0.21, k = 459 mD, Sor = 0.15, Siw = 0.25
• Two reservoir heterogeneity are studied:
where 𝑣𝑑𝑝 =𝑘50 − 𝑘84.1
𝑘50
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PVT data
𝑀𝑀𝑃 = 15.998 × 𝑇 0.744206+0.0011038×𝑀𝑊 𝐶5+
• Cronquist correlation is employed to determine the minimum
miscible pressure where
and MMP = 1744 psi < Pinit = 3000 psi
• Averaging MW = 153, and MW C5+ = 128. According to the DOE
report for Permian basin:
API = 56, very light oil.
𝑀𝑊 𝐶5+ = 4247.99𝐴𝑃𝐼−0.87022
Elevation [ft] CO2 C1N2 C2C3 C4C5 C6P1 C6P2 C6P3
-5450 0.004 0.313 0.181 0.080 0.132 0.137 0.153
Elevation [ft] CO2 C1N2 C2C3 C4C5 C6P1 C6P2 C6P3
-5450 0.004 0.213 0.181 0.080 0.132 0.137 0.253
• MMP = 2311 psi < Pinit = 3000 psi
• Averaging MW = 197, MW C5+ = 176, and API = 39.
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Outline
• Introduction
Reservoir management for CO2 flooding
− Impact of heterogeneity, WAG ratio, CO2 slug size, and Oil gravity
• Reservoir management for surfactant
− Well stimulation and surfactant flooding
• Reservoir management for mobility control
− CO2 foam flooding
• Managing uncertainty
• Summary
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Sensitivity study - pressure impact on oil recovery
MMP MMP
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Sensitivity study - slug size impacts
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Reservoir management for CO2 flooding
• Reservoir management studies were performed to
investigate the sensitivity of API gravity, WAG ratio, Slug
size, and Vdp on the oil recovery to maximize the
recovery factor and net present value (NPV).
Factors: Scenario I Scenario II
API 56 39
WAG Ratio 0.69 3.44
Slug Size, % HCPV 0.4 2
Vdp, Dykstra-Parsons Coefficient 0.57 0.76
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Comparison between water and WAG flooding for API = 39
𝑣𝑑𝑝 = 0.57 𝑣𝑑𝑝 = 0.76
• More heterogeneous reservoir provides less benefits for CO2
flooding comparing to water flooding.
API = 39
WAG
Water
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Comparison between water and WAG flooding for 𝑣𝑑𝑝 = 0.57
API = 56 API = 39
• Lower API oil provides less benefits for CO2 flooding
comparing to high API gravity. 𝒗𝒅𝒑 = 𝟎. 𝟓𝟕
WAG
Water
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Impact of various reservoir management on oil recovery
API = 56
API = 39
Vdp = 0.57 Vdp = 0.76
Improved Recovery Improved Recovery
2 year CO2+1 year Water 13.31% 5.74%
10 year CO2+5 year Water 18.86% 9.44%
2 year CO2+5 year Water 11.78% 5.28%
10 year CO2+25 year Water 18.73% 9.13%
Vdp = 0.57 Vdp = 0.76
Improved Recovery Improved Recovery
2 year CO2+1 year Water 7.68% 2.28%
10 year CO2+5 year Water 13.07% 5.88%
2 year CO2+5 year Water 6.54% 2.05%
10 year CO2+25 year Water 10.39% 5.57%
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Reservoir economics
API = 56
API = 39
Value
Oil price $80 /bbl
Oil price
increase
10%
Royalty 12.5%
Discount
rate
15%
CO2 price $1 / Mscf
OPEX $1 /bbl
Federal tax
rate
32%
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improved [%] NPV [MM$] Improved [%]
Water only $26.41 - $23.72 -
2 year CO2+1 year Water $29.05 10.00% $23.51 -0.87%
10 year CO2+5 year Water $30.24 14.53% $24.11 1.66%
2 year CO2+5 year Water $29.23 10.70% $24.23 2.15%
10 year CO2+25 year Water $30.51 15.54% $24.33 2.60%
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improved [%] NPV [MM$] Improved [%]
Water only $29.66 - $26.63 -
2 year CO2+1 year Water $30.90 4.17% $25.49 -4.29%
10 year CO2+5 year Water $32.08 8.16% $26.13 -1.87%
2 year CO2+5 year Water $31.16 5.06% $26.30 -1.23%
10 year CO2+25 year Water $31.75 7.05% $26.36 -1.02%
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Reservoir economics
API = 56
API = 39
Value
Oil price $80 /bbl
Oil price
increase
10%
Royalty 12.5%
Discount
rate
15%
CO2 price $2 / Mscf
OPEX $1 /bbl
Federal tax
rate
32%
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improved [%] NPV [MM$] Improved [%]
Water only $26.41 - $23.72 -
2 year CO2+1 year Water $27.28 3.31% $21.74 -8.32%
10 year CO2+5 year Water $28.11 6.46% $21.98 -7.32%
2 year CO2+5 year Water $28.26 7.03% $23.26 -1.93%
10 year CO2+25 year Water $28.63 8.42% $22.45 -5.33%
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improved [%] NPV [MM$] Improved [%]
Water only $29.66 - $26.63 -
2 year CO2+1 year Water $29.13 -1.78% $23.72 -10.92%
10 year CO2+5 year Water $29.95 0.98% $24.00 -9.87%
2 year CO2+5 year Water $30.19 1.79% $25.33 -4.87%
10 year CO2+25 year Water $29.87 0.72% $24.48 -8.08%
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Summary
• Several factors needs to be assessed for CO2 flooding:
− Is CO2 source/pipeline available, and what is the corresponding
MMP pressure
− Is the MMP sufficiently below overburden pressure/FPP, can the
high injectivity be achieved to maintain the pressure
− Is the CO2 flood economic with or without reaching the MMP
− How much CO2 needs to be purchased and how much can be
recycled
− Numerical simulations can give a guidance for CAPEX & OPEX,
and identify the optimal slug size and best WAG ratio
− Surveillance practice to achieve the optimal performance is
necessary, no matter whether constant WAG ratio taped to high
ratio towards the end of the project, or monthly adjustment WAG
ratios based on the observed performance
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Outline
• Introduction
• Reservoir management for CO2 flooding
− Impact of heterogeneity, WAG ratio, CO2 slug size, and Oil gravity
Reservoir management for surfactant
− Well stimulation and surfactant flooding
• Reservoir management for mobility control
− CO2 foam flooding
• Managing uncertainty
• Summary
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0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
Pipeline PSI MCF/D CO2 Injection
West TX Field
Inj RateCO2
0.4% CnF Injection
7-23 thru 7-25
Injectivity enhancement – well stimulation
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Well stimulation and production enhancement
CnF Injection
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Surfactant mechanisms
𝑆𝑖𝑟 = 0 𝑊ℎ𝑒𝑛 𝛿 < 0.005 𝑚𝑁/𝑚
𝑆𝑖𝑟 = 0.3 ∗ 1 + log 𝛿 2.3 𝑊ℎ𝑒𝑛 0.005 𝑚𝑁/𝑚 < 𝛿 < 1 𝑚𝑁/𝑚 𝑆𝑖𝑟 = 0.3 𝑊ℎ𝑒𝑛 𝛿 > 1 𝑚𝑁/𝑚
𝑁𝑖 = 1.0 𝛿 < 0.005 𝑚𝑁/𝑚
𝑁𝑖 = 1.5 + log 𝛿 6 0.005 𝑚𝑁/𝑚 < 𝛿 < 1 𝑚𝑁/𝑚 𝑁𝑖 = 1.5 𝛿 > 1 𝑚𝑁/𝑚
• The residual oil saturation, water saturation and relative permeability will
change (Pope & Nelson, 1978) for Corey correlation:
𝑞𝑠𝑢𝑟 = 𝑞𝑚𝑎𝑥
𝑏 ∗ 𝐶𝑠𝑢𝑟1 + 𝑏 ∗ 𝐶𝑠𝑢𝑟
• Langmuir-type adsorption model is considered:
CMC = 2 g/L (0.2%)
• Questions:
− What is the surfactant concentration that we should inject?
− How long do we need to inject?
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Impact of surfactant concentration on NPV
API = 56 API = 39
Surfactant price of $4/lb is used in the economic evaluation
CMC CMC
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Impact of surfactant injection time
API = 56 API = 39
3 g/L surfactant concentration with a price of $4 /lb
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Economic analysis for surfactant flooding
API = 56
API = 39
3 g/L concentration, 5 years surfactant injection, and $4 /lb were used
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improve% by WAG NPV [MM$] Improve% by WAG
2 year CO2+1 year Water $31.55 5.10% $26.48 7.64%
10 year CO2+5 year Water $30.23 -2.55% $25.75 2.72%
2 year CO2+5 year Water $34.25 11.65% $29.72 15.14%
10 year CO2+25 year Water $32.39 5.13% $27.43 6.23%
Vdp = 0.57 Vdp = 0.76
NPV [MM$] Improve% by WAG NPV [MM$] Improve% by WAG
2 year CO2+1 year Water $29.17 3.59% $24.14 6.67%
10 year CO2+5 year Water $28.83 -1.20% $23.48 1.88%
2 year CO2+5 year Water $31.57 9.83% $27.07 14.00%
10 year CO2+25 year Water $30.63 3.57% $25.03 6.98%
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Outline
• Introduction
• Reservoir management for CO2 flooding
− Impact of heterogeneity, WAG ratio, CO2 slug size, and Oil gravity
• Reservoir management for surfactant
− Well stimulation and surfactant flooding
Reservoir management for mobility control
− CO2 foam flooding
• Managing uncertainty
• Summary
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Overview of polymer flooding
• Polymer flooding is commonly used in the oil fields for mobility
control. A favorable mobility, M<1, is preferred especially for a very
heterogeneous reservoir to avoid early water/CO2 breakthrough
• The polymer flooding is limited by:
− Low water injectivity (WI)
− Stability issues
− Only limited to reservoir rock above 5 mD because polymer molecules
are large enough to plug the small pore throats
• In the simulation model, Langmuir adsorption model is used, and
the relative permeability change is not considered
𝑀 =𝑘𝑤/𝜇𝑤𝑘𝑜/𝜇𝑜
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CO2 foam
Viscosity
factor
Foam concentration [ppm]
500 1000 1500 2000 2500 3000
Rock 1
(9.4 mD)
1.2 1.4 1.8 2 2.5 3
Rock 2
(150 mD)
1.5 2.5 4 6 8.5 10
Rock 3
(459 mD)
2 5 10 20 30 45
• Studies show that different from the polymer, mobility reduction by
CO2 foam depends on permeability and oil saturation. At the low
permeability zone where the oil left behind, the mobility reduction is
decreased
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Reservoir management for CO2 foam
Impact of injected foam
concentration
Impact of injected foam time
API = 39, Vdp = 0.76, 2 years CO2 + 5 years water w/Foam
Foam price of $2 /lb is used in the economic analysis
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Managing uncertainty
• Technical factors/uncertainties, such as geological
uncertainty, reservoir pressure & temperature, and
salinity, will have a great impact on the actual enhanced
oil recovery
• Economical uncertainties such as the oil price, CO2
price, surfactant & polymer price, etc. will have a great
impact to identify the EOR opportunity and the economic
evaluation
• How to identify these uncertainties and how confident
are we for the improved oil recovery and economic
analysis for EOR flooding
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Uncertainty for oil recovery
API = 39, Vdp=0.76, 2 years CO2 + 5 years SP injection
• Technical factors/uncertainties, such
as the reservoir pressure,
temperature, and salinity, will have
a great impact on the enhanced oil
recovery
• Economical factors such as the oil
price, SP price, discount rate, etc.
will have a great impact on the
economic evaluation
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Managing uncertainty
Improvement [%] P10 50.20%
P50 32.51%
P90 13.96%
API = 39, Vdp=0.76, 2 years CO2 + 5 years SP injection
• How to identify the uncertainty and how confident are we for the
NPV and improved recovery by SP flooding?
NPV [MM $] P10 33.40
P50 27.69
P90 23.10
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High level questions for EOR
• What is the current oil saturation?
− If the residual oil saturation of the current flooding zone is very high, then
using CO2 or surfactant is recommended
• What is the reservoir description such as heterogeneity and
porosity/permeability?
− An early CO2/WAG breakthrough indicates a very heterogeneous
reservoir and mobility control (either CO2 foam or polymer) is highly
recommended to improve the sweep efficiency; if the permeability is very
small then the use of polymer needs to be cautious
• What is the oil API gravity or viscosity?
− “CO2 flooding becomes very inefficient if the oil viscosity increases
above 10 cp; SP/ASP becomes less efficient above 200 cp; polymer
flooding has been used up to 1000 cp”
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Thank you
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Comparison of breakthrough between CO2 and water flooding
• The more heterogeneous of the reservoir, the earlier breakthrough
of the CO2 than water, and the less benefits of CO2 flood.
API = 56 API = 39
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When do we expect a positive cash flow?
0.4 HCPV (2 years) CO2 injection
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Guidance for Rel Perm with surfactant
𝑆𝑖𝑟 = 0 𝑊ℎ𝑒𝑛 𝛿 < 0.005 𝑚𝑁/𝑚
𝑆𝑖𝑟 = 0.3 ∗ 1 + log 𝛿 2.3 𝑊ℎ𝑒𝑛 0.005 𝑚𝑁/𝑚 < 𝛿 < 1 𝑚𝑁/𝑚 𝑆𝑖𝑟 = 0.3 𝑊ℎ𝑒𝑛 𝛿 > 1 𝑚𝑁/𝑚
𝑆𝑤𝑛 = 𝑆𝑤 − 𝑆𝑖𝑤
1 − 𝑆𝑖𝑤 − 𝑆𝑜𝑤
𝑘𝑟𝑤 = 𝑘𝑟𝑤𝑜 𝑆𝑤𝑛
𝑁𝑤
𝑘𝑟𝑜 = 𝑘𝑟𝑜𝑜 1 − 𝑆𝑤𝑛
𝑁𝑜
𝑘𝑟𝑖𝑜 = 𝑘𝑟𝑖
𝑜 + 1 − 𝑘𝑟𝑖𝑜 0.3 − 𝑆𝑖𝑟 /0.3
𝑁𝑖 = 1.0 𝑊ℎ𝑒𝑛 𝛿 < 0.005 𝑚𝑁/𝑚
𝑁𝑖 = 1.5 + log 𝛿 6 𝑊ℎ𝑒𝑛 0.005 𝑚𝑁/𝑚 < 𝛿 < 1 𝑚𝑁/𝑚 𝑁𝑖 = 1.5 𝑊ℎ𝑒𝑛 𝛿 > 1 𝑚𝑁/𝑚
• According to Pope & Nelson (1978), the residual oil saturation, water
saturation and relative permeability will change when the interfacial tension
is lowered:
where the exponents of Corey
correlation can be calculated:
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Adsorption model for surfactant
𝑞𝑠𝑢𝑟 = 𝑞𝑚𝑎𝑥
𝑏 ∗ 𝐶𝑠𝑢𝑟1 + 𝑏 ∗ 𝐶𝑠𝑢𝑟
• Langmuir-type adsorption model is considered:
q is the adsorption, Csur is the surfactant concentration in water,
and b is the initial slope of the isotherm.
qmax is salinity dependent where:
𝑞𝑚𝑎𝑥 = 𝑞𝑚𝑎𝑥0 + 𝑎 ∗ 𝐶𝑠𝑎𝑙
• Our study used: qmax0 = 200 µg/g, a = 1.0e-5, b = 0.1
• Critical miscible concentration, CMC = 2 g/L (0.2%)
• Questions:
− What surfactant concentration should we inject?
− How long do we need to inject?
− What’s the economic benefit of surfactant flooding?
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Economics for CO2 foam flooding
API = 39, Vdp = 0.76, 2 years CO2 + 5 years water w/Foam, Foam price of $2 /lb
NPV Improvement Oil Recovery Improvement
[MM$] [%] [%] [%]
2 year CO2+1 year Water $25.49 7.61% 63.51% 13.82%
10 year CO2+5 year Water $24.83 3.06% 61.82% 7.05%
2 year CO2+5 year Water $26.87 7.84% 63.19% 13.43%
10 year CO2+25 year Water $24.94 2.02% 60.53% 5.12%