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EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump

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Page 1: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

EOS FireTransient Absorption Spectrometer

Transient Absorption of TPP with ns Pump

Page 2: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Experiment Details• Sample: Tetra-Phenyl-Porphyrin (TPP)• Solvent: Toluene

• Laser / OPA: NT242 by Ekspla @ 1 kHz• Pulse duration: 3-6 ns

• Pump energy: 2 µJ

• Pump wavelength: 355 nm• Ground state absorbance: 0.04@355nm

• Measurement time: 20 min

Page 3: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Ground State Absorption Spectrum of TPP in Toluene

Page 4: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

TPP Dynamic Surface with Kineticand Spectral Slices in Surface Xplorer Software

Page 5: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Dynamic Surface of TPP (Bird’s Eye View)

Page 6: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Dynamic Surface of TPP (3D View)

Page 7: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Transient Kinetics & Spectra of TPP in Toluene

Page 8: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Rise Time of TPP in Toluene

Page 9: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Experiment Details• Sample: Tetra-Phenyl-Porphyrin (TPP)• Solvent: Toluene

• Laser / OPA: NT242 by Ekspla @ 1 kHz• Pulse duration: 3-6 ns

• Pump energy: 0.3 µJ

• Pump wavelength: 355 nm• Ground state absorbance: 0.04@355nm

• Measurement time: 60 min

Page 10: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Ground State Absorption Spectrum of TPP in Toluene

Page 11: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

TPP Dynamic Surface with Kineticand Spectral Slices in Surface Xplorer Software

Page 12: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Dynamic Surface of TPP (Bird’s Eye View)

Page 13: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Transient Kinetics & Spectra of TPP in Toluene

Page 14: EOS Ekspla TPP 355nm - Ultrafast Systemsultrafastsystems.com/download/eos-fire/EOS... · EOS Fire Transient Absorption Spectrometer Transient Absorption of TPP with ns Pump. Experiment

Rise Time of TPP in Toluene