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Fall 2016 Volume 15, Number 4
Journal ofUndergraduate
ChemistryResearch
ISSN: 1541-6003
A 1
Editoral Board
Dr. John T. Gupton III
Chairman of Chemistry Department at Richmond University, [email protected]
Dr. Willie L. Hinze
Professor Wake Forest University, [email protected]
Dr. Benjamin P. Huddle
Professor Roanoke College, [email protected]
Dr. Frank A. Settle Jr.
Professor Washington and Lee University, [email protected]
Dr. Henry D. Schreiber
Chemistry Department at Virginia Military Institute, [email protected]
Dr. Stanton Q. Smith
Chemistry Department at Virginia Military Institute, [email protected]
Dr. James E. Turner Sr.
Chairman Biology Department at Virginia Military Institute,[email protected]
ACKNOWLEDGMENTThe Journal of Undergraduate Chemistry Research wishes to acknowledge the support of the VMI Chemistry Departmentand the Virginia Military Institute for their support of this journal.
The Journal of Undergraduate Chemistry Research, ISSN: 1541-6003, is issued quarterly and indexed once peryear.Subscriptions price per year U.S.A.: institutional $ 120.00, individual $ 50.00 all other countries US $ 150.00. Claimsfor missing issues will not be honored after four months of issue date. Duplicate copies may not be sent due to the changeof address when the publisher was not notified in a timely manner. The Journal of Undergraduate Chemistry Researchcan be contacted via phone (540-464-7244), fax (540-464-7261) or e-mail ([email protected]) through Dr. Daniel Y. PharrEditor. No responsibility is assumed by this journal, editor, reviewers or sponsors for any injury and/or damage fromproducts, negligence, experiments, instructions or ideas contained in this journal that result in damage to persons or property.
Journal of Undergraduate Chemistry Research [email protected]
Dr. Daniel Y. Pharr Editor
Chemistry Department
Virginia Military Institute
Lexington VA 24450
phone (540-464-7244)
fax (540-464-7261)
email ([email protected])
A 2
Volume 15, Number 4 Fall 2016
Journal of Undergraduate Chemistry ResearchISSN: 1541-6003
CONTENTS
The Journal of Undergraduate Chemistry Research publishes papers of original research performed by undergraduates on all aspects of chemistryincluding analytical, organic, inorganic, physical, polymers and biochemistry. Articles about laboratory experiments to be used in the teaching of chemistryare not applicable. The Journal of Undergraduate Chemistry Research is issued quarterly and indexed once per year by Dr. Daniel Y. Pharr Editor,Chemistry Department, Virginia Military Institute, Lexington, VA 24450. Subscriptions price per year U.S.A.: institutional $ 120.00, individual $ 50.00 allother countries US $ 150.00. Claims for missing issues will not be honored after four months of issue date. Duplicate copies may not be sent due to thechange of address when the publisher was not notified in a timely manner. The Journal of Undergraduate Chemistry Research can be contacted via phone(540-464-7244), fax (540-464-7261) or e-mail ([email protected]) through Dr. Daniel Y. Pharr Editor. No responsibility is assumed by this journal,editor, reviewers or sponsors for any injury and/or damage from products, negligence, experiments, instructions or ideas contained in this journal thatresult in damage to persons or property. POSTMASTER: Send change of address to: Journal of Undergraduate Chemistry Research, Dr. Daniel Y. PharrEditor, Chemistry Department, Virginia Military Institute, Lexington VA 24450.
p-DICHLOROBENZENE-NAPHTHALENE EXCIPLEX ON Al2O
3
A.M. Nishimura†, Handolsam Chung*, Christopher C. Riba*, and K.A. Martin‡ ........................................................ 95
ENERGY TRANSFER IN NEAR-RESONANT SINGLET ELECTRONIC STATES:
NAPHTHALENE AND BIPHENYL ON Al2O
3
A.M. Nishimura†, Christopher C. Riba*, Handolsam Chung*, and K.A. Martin‡ ........................................................ 99
ENERGY TRANSFER IN NEAR-RESONANT SINGLET ELECTRONIC STATES WITH
NAPHTHALENE: BIPHENYL, 4-METHYLBIPHENYL, 4,4’-DIMETHYLBIPHENYL
AND p-TERPHENYL ON Al2O
3
A.M. Nishimura†, Handolsam Chung*, Christopher C. Riba*, and K.A. Martin‡ ........................................................ 103
EXPLORING THE USE OF ACETIC AND LEVULINIC ACIDS IN SOLID-PHASE
SYNTHESIS OF RENEWABLE FUEL PRECURSORS
Irina P. Smoliakova†, Calvin R. Henry*, and Andrew N. Owen* .................................................................................. 108
A TWO-DIMENSIONAL NMR STUDY OF DINITROBIS(2,2-BIPYRIDINE)
COBALT(III) CHLORIDE
Mark McClure† and Kennedi Stewart* ........................................................................................................................... 113
INHIBITION OF TYROSINASE ACTIVITY BY IMIDAZOLIUM IONIC LIQUIDS
Mark P. Heitz†, Kim W. Horn*, and Jason W. Rupp* ..................................................................................................... 117
INVESTIGATION OF STILBENES AS POTENTIAL INHIBITORS OF HUMAN
IMMUNODEFICIENCY VIRUS BY COMPUTATIONAL DOCKING
Massimo D. Bezoari† and Blake Schouest* .................................................................................................................... 122
Abstracts
A 3
Volume 15, Number 4
p-DICHLOROBENZENE-NAPHTHALENE EXCIPLEX ON Al2O3
When optically pumped, vapor deposited naphthalene molecules on the
surface of Al2O
3 exhibit a characteristic fluorescence that is spectroscopically
red-shifted and broad due to the amorphous character of the adlayer. Energy
transfer can occur if a molecule that has a higher electronic energy, such as
p-dichlorobenzene is made to percolate through the naphthalene adlayer.
This percolation can be induced by deposition of a p-dichlorobenzene/
naphthalene bilayer and by raising the temperature of the Al2O
3. When the
percolation occurs, the formation of p-dichlorobenzene-naphthalene exciplex
competes with that of the naphthalene excimer and results in the fluorescence
from the exciplex. Another effect that the percolation of the p-
dichlorobenzene has on the naphthalene adlayer is the induction of a disorder-
to-order transition in the naphthalene adlayer that results in a blue-shifted
molecular fluorescence. Finally, the percolation creates a surface film that
appears to be specularly reflective when the adlayer’s stoichiometric ratio
of p-dichlorobenzene to naphthalene is about 3 to 1.A.M. Nishimura†, Handolsam Chung*, Christopher C. Riba*, and K.A. Martin‡
†Department of Chemistry, Westmont College, Santa Barbara, CA 93108
‡Department of Chemistry, Point Loma Nazarene University, San Diego, CA 92106 USA
ENERGY TRANSFER IN NEAR-RESONANT SINGLET
ELECTRONIC STATES: NAPHTHALENE AND BIPHENYL ON
Al2O3
Controlled mixing of naphthalene and biphenyl was accomplished by
vacuum deposition of the two molecular adlayers on a cryogenically cooled
dielectric surface of Al2O
3. The surface was then heated and thermally
induced percolation of naphthalene into the biphenyl adlayer was made to
occur. Examination of the spectrally resolved desorption profile allowed
the assignment of the excited state complex that formed between the two
molecules.A.M. Nishimura†, Christopher C. Riba*, Handolsam Chung*, and K.A. Martin‡
Department of Chemistry, Westmont College, Santa Barbara, CA 93108, [email protected]
‡Permanent address: Department of Chemistry, Point Loma Nazarene University, San Diego, CA
92106 USA
ENERGY TRANSFER IN NEAR-RESONANT SINGLET
ELECTRONIC STATES WITH NAPHTHALENE: BIPHENYL,
4-METHYLBIPHENYL, 4,4’-DIMETHYLBIPHENYL AND p-
TERPHENYL ON Al2O3
Excited state complexes of molecules with near resonant electronically
excited states were formed by the percolation of donor and acceptor
molecules on a single crystal of Al2O
3. The energy donor was naphthalene
and the acceptor molecules were biphenyl, 4-methylbiphenyl, 4,4’-
dimethylbiphenyl and p-terphenyl. Surfaces of dielectric compounds such
as Al2O
3 that are chemically inert are ideal for the observation of surface
interactions and dynamics of the adsorbates as a function of temperature.
Since the electronically excited states of molecules are sensitive functions
of intermolecular interactions, the spectral changes that occurred during
the temperature ramp are reported.A.M. Nishimura†, Handolsam Chung*, Christopher C. Riba*, and K.A. Martin‡
Department of Chemistry, Westmont College, Santa Barbara, CA 93108, [email protected]
‡ Department of Chemistry, Point Loma Nazarene University, San Diego, CA 92106 USA
EXPLORING THE USE OF ACETIC AND LEVULINIC ACIDS IN
SOLID-PHASE SYNTHESIS OF RENEWABLE FUEL
PRECURSORS
Two successful methods for attachment of acetic and levulinic acids to
Merrifield and Wang resins were developed. In the first method, the acids
were converted to the corresponding sodium salts using NaHCO3. These
salts were reacted with Merrifield resin in the presence of n-Bu4NBr resulting
in the attachment of the acids to the resin through an ester bond. The second
method utilized diisopropylcarbodiimide as a coupling agent and 4-
dimethylaminopyridine as a catalyst to achieve attachment of the acid
through an ester bond. The formation of the ester bond was proven by IR
spectroscopy. An in situ NMR ester cleavage procedure with CF3CO
2H was
developed to estimate the yield of the resin-bound esters. The yields
calculated using this method were in good correlation with the yields
determined for isolated hydrolysis products. Attempts to extend the carbon
chains of the formed esters by treatment with LDA and ethyl acetate were
unsuccessful.Irina P. Smoliakova†, Calvin R. Henry*, and Andrew N. Owen*
Chemistry Department, University of North Dakota, Grand Forks, ND 58202,
A TWO-DIMENSIONAL NMR STUDY OF DINITROBIS(2,2-
BIPYRIDINE)COBALT(III) CHLORIDE
The compound [Co(bipy)2(NO
2)
2]Cl was synthesized and analyzed by two-
dimensional NMR techniques. The centers and multiplicities of the 1H
resonances were identified using a homonuclear J-resolved spectrum, and
assignment of the 13C resonances was achieved using a heteronuclear
correlation spectrum. Through this combination, it was possible to assign
all of the 1H and 13C resonances in this compound.Mark McClure† and Kennedi Stewart*
Department of Chemistry and Physics, The University of North Carolina at Pembroke, Pembroke,
NC
INHIBITION OF TYROSINASE ACTIVITY BY IMIDAZOLIUM
IONIC LIQUIDS
The effect of ionic liquids (ILs) on the enzyme/substrate reaction between
mushroom tyrosinase/L-3,4-dihydroxylphenylalaine (L-dopa) activity was
studied using UV-Vis absorbance spectroscopy. The conversion of the L-
dopa substrate by tyrosinase was measured in 50 mM phosphate buffer at
pH = 6.8 and in the presence of buffer solutions that included one of each of
seven ionic liquids that included the 1-ethyl-3-methylimidazolium cation
(Im21
+) paired with nitrate (NO3
-), trifluoromethanesulfonate (TFMS-),
methylsulfate (MeSO3-), and bis(trifluoromethylsulfonyl)imide (Tf
2N-), the
1-butyl-3-methylimidazolium cation (Im41
+) paired with chloride (Cl-) and
[MeSO3]-, and the 1-hexyl-3-methylimidazolium cation (Im
61+) paired with
Cl-. The tyrosinase/L-dopa kinetics that were determined in 50 mM
phosphate buffer were used to establish a baseline reaction rate. Change in
absorbance was measured as a function of time to determine the initial
reaction rates that were in turn used to calculate the Michaelis-Menten kinetic
parameters. Comparison to the buffer activity allowed for the calculation of
relative enzymatic activity. Experimental results indicate that the enzyme
activity was inhibited by the ionic liquid in all cases and that the relative
activity ranged from 0.1 to 0.9. Increasing the IL cation chain length
decreased the relative activity through increased hydrophobic interactions.
Within a series for a given cation the effect of anion structure on relative
activity followed a pattern that was related to anion size and degree of
fluorination. For anions associated with Im21
+, the inhibition effectiveness
order observed was [NO3]- < [MeSO
3]- < [TFMS]- < [Tf
2N]-. With Im
41+ we
observed that Cl- < [MeSO3]-.
Mark P. Heitz†, Kim W. Horn*, and Jason W. Rupp*
Department of Chemistry and Biochemistry, The College at Brockport, SUNY, 228 Smith Hall, 350
New Campus Drive, Brockport, NY, 14420, [email protected]
INVESTIGATION OF STILBENES AS POTENTIAL INHIBITORS
OF HUMAN IMMUNODEFICIENCY VIRUS BY
COMPUTATIONAL DOCKING
The interaction between intercellular adhesion molecule-1 (ICAM-1) and
lymphocyte function-associated antigen-1 (LFA-1) has been implicated in
the dissemination of human immunodeficiency virus (HIV) within the
infected host. In the present study, computational chemistry in the form of
docking studies was used to identify small molecule compounds that bind
ICAM-1 and inhibit interaction with LFA-1. Using AutoDock™ Vina,
resveratrol (a known inhibitor) and other stilbene derivatives were docked
to ICAM-1 to identify their modes of interaction and postulate candidate
drugs that might be more effective inhibitors. In the present study, a
hydrophobic binding pocket within ICAM-1 was identified. Additionally,
several stilbene derivatives with hydroxyl and methoxy substituents were
shown to bind ICAM-1 with stronger affinity than resveratrol, suggesting
alternative therapies to limit HIV/AIDS progression in infected hosts.Massimo D. Bezoari† and Blake Schouest*
The Louisiana Scholars’ College at Northwestern State University, 175 Sam Sibley Dr., Natchitoches,
LA 71497, [email protected]
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Author Index Volume 11-15
Anderson, Stephen
, Danielle Mazza, Tiffany Simons, Adam
Toth
REDUCING UNSATURATED
ORGANIC COMPOUNDS VIA
TRANSFER HYDROGENATION USING
WILKINSON’S CATALYST AND
ISOPROPANOL, (11) 59
, Daniel Ferrante *, Sahar Sheikh*, and Jill
Tracey*
REDUCTION OF CYCLIC ALKENES
AND KETONES VIA TRANSFER
HYDROGENATION USING
WILKINSON’S CATALYST AND
ISOPROPANOL, (15) 44
Ball, David W.
, Lisa M. Ina
NITRATED DIBORANE AS A
POSSIBLE HIGH ENERGY-DENSITY
MATERIAL SOME SURPRISING
RESULTS, (15) 12
Basu, Swarna
, Shelby O’Riley, Cassie M. Zerbe, Joseph
Antonides, Matthew G. Gabrielson, and Alex
R. Doudt
ROLE OF METAL IONS ON
QUADRUPLEX DNA DETECTION
CAPABILITIES OF PORPHYRINS, (15)
16
Beran, Kyle A.
, Mihai Urichianu
IDENTIFYING THE [M+2]+ PEAK
OBSERVED WITH NITROGEN-BASED
MALDI MATRICES: A THEORETICAL
INVESTIGATION, (15) 88
Bezoari, Massimo D.
, Blake Schouest
INVESTIGATION OF STILBENES
AS POTENTIAL INHIBITORS OF
HUMAN IMMUNODEFICIENCY
VIRUS BY COMPUTATIONAL
DOCKING,, (15) 122
Blank, Natalia F.
, Shelbie D. Holland*, William P. Day*,
Jerry P. Jasinski
SYNTHESIS AND CHARACTERIZA-
TION OF TWO NEW N,N’-
BIS(PHENYLIMINO)ETHANES, (12) 1
, Regan Steen
INVESTIGATION OF Fe-TAML
CATALYZED OXIDATIVE DEGRADA-
TION OF IBUPROFEN, (15) 21
Blanton, James R.
, Robert W. Clark
ASYMMETRIC SYNTHESES
UTILIZING CROWN ETHERS WITH
CHIRAL APPENDAGES AS PHASE
TRANSFER CATALYSTS, (11) 73
, Robert W.Clark*
SYNTHESIS AND UTILIZATION OF
TWO-CENTER PHASE TRANSFER
CATALYSTS ON ADJACENT
CARBONS OF A CHIRAL BACKBONE,
(12) 24
Blauch, David N.
, Chang Yang*, and Kevin C. Peters*
MECHANISTIC STUDY OF
HYDROGEN EVOLUTION IN
AQUEOUS PYRIDINIUM ION/
PYRIDINE SOLUTIONS BY CYCLIC
VOLTAMMETRY, (12) 86
Caputo, Gregory A.
, Angela L. Picciano*, and Sarah Misenko*
FLUORESCENCE METHOD FOR
INVESTIGATION OF MEMBRANE
PERMEABILIZATION IN GRAM-
POSITIVE BACTERIA, (14) 12
Carr, Jeremy M.
, Caroline Benjamin, Dexter Dean, Paige
Lathem, Quintarious Perdue, Chasity Ward
SOLVENT EFFECTS IN THE
FORMATION OF STRYKER’S
REAGENT FROM COPPER(II)
ACETATE, (11) 81
Castillo-Chará, Jairo
, Tecarla S Ikard
CALCULATION OF MOLECULAR
PROPERTIES OF THE [Au2-C
60-Au
2]n- (n
= 0, 1, 2, 3) MODEL COMPLEXES
USING THE B3LYP/LANL2DZ
METHOD, (15) 1
, Tecarla S Ikard
CALCULATION OF VERTICAL
ELECTRON AFFINITIES AND
VERTICAL DETACHMENT ENERGIES
FOR THE [Au2-C
60-Au
2]n-(n = 0, 1, 2, 3)
COMPLEXES USING THE B3LYP/
LANL2DZ METHOD, (15) 6
Chapman, Douglas A.
, Heather E. Bailey
SPECTROSCOPIC AND COMPUTA-
TIONAL STUDY OF THE METHANOL-
CYCLOHEXANE AZEOTROPE, (11) 98
Chen, N.;
, Mark Waguespack, Ozuem Oseji, Eric
May, Madhumi Mitra
HPLC ANALYSIS OF PHY-
TOPLANKTON PIGMENTS IN
MARYLAND COASTAL BAYS, (11) 119
Chinni, Rosemarie C.
, Daniel Kwasniewski, and Ryan Cupo
HIGH PRESSURE LIQUID
CHROMATOGRAPHY DETERMINA-
TION OF ADDITIVES IN VARIOUS
DRINKS, (13) 21.
, Devon Kline, and Alexander Roche
PENNY ANALYSIS USING LASER-
INDUCED BREAKDOWN SPECTROS-
COPY (LIBS), (14) 83
Coffield, James E.
, Norman V. Duffy, Michael D. Hoops, and
Rory Z. Beck
ANALYSIS OF THE THERMAL
LOSS OF CO FROM cis
DICARBONYLBIS
(DIORGANODITHIOCARBAMATO)IRON(II)
COMPLEXES, (12) 7
Craig, P.R.
, Kevin J. Bowman, Teresa E. Rosson
pH DEPENDENT BINDING OF THE
CADMIUM CHELATOR O-[2-[BIS(2-
HYDROXYETHYL)AMINO]ETHYL]
DITHIOCARBONATE, (11) 123
Covey, Tracy M.
, Angela G. Lopez*, An H. Tran*, Anthony
J. Tran*, and Wheeler C. Crawford
METHANESULFONIC ACID
CATALYZED SYNTHESIS OF
DINITROCHALCONES AND THEIR
CYTOTOXICITIES IN CANCER
CELLS, (13) 18
Diallo, Mamadou C.
, Quynh T. Ly*, Kristen E. Bashaw*, and
Zachary Highland*
REACTION OF PENTACYCLO-
UNDECANE-8,11-DIONE WITH
ALCOHOLS AND IMPACT OF
ALCOHOL STRUCTURE ON THE
FORMATION OF OXA-BIRDCAGE
DIKETALS, (13) 15
Dorko, M.J.
, Joseph C. Collins
THEORETICAL INVESTIGATION
OF BERYLLIUM SULFIDE AS AN
ALTERNATIVE HYDROGEN
STORAGE MATERIAL, (11) 127
Duffy, Norman V. ;
, Colin Jack, Michael D. Hoops, Aloysius
F. Hepp,
THERMOGRAVIMETRIC
ANALYSIS OF CIS-DICARBONYLBIS
(DITHIOCARBAMATO)IRON(II)
COMPLEXES, (11) 11
, Nathaniel M. Barker*, Matthew W.
Logan*, and James E. Coffield LIGAND
EXCHANGE BETWEEN THE
DITHIOCARBAMATES AND
THIOSELENOCARBAMATES OF
Fe(III) AS STUDIED BY PROTON
NMR1, (13) 60
, Nathaniel M. Barker*, Matthew W.
Logan*, Kathryn Stankiewicz*, and James E.
Coffield
LIGAND EXCHANGE BETWEEN
THE DITHIOCARBAMATES OF Fe(III)
AND In(III) OR Ga(III) AS STUDIED BY
PROTON NMR, (15) 84
Estes, Donald;
, Lea Blau, Sarah Guigui, and Nili Seleski,
BASE STACKING IN
DEOXYOLIGONUCLEOTIDE
DUPLEXES, (11) 15
Fazal,Md Abul,
, Krista Barzen-Hanson*
STUDIES ON THE EFFECTS OF
OXIDATIVE MODIFICATIONS IN
HUMAN SERUM ALBUMIN ON ITS
INTERACTIONS WITH MAGNETIC
IRON (III) OXIDE NANOPARTICLES,
(12) 79
Flynn, N.
, J.C. Ray, and S. Anaya
EFFECT OF AMINO ACID AND
CARBOHYDRATE CONTENT ON
ACRYLAMIDE PRODUCTION IN
RUSSET POTATO CULTIVARS, (15) 71
Foroozesh, Maryam
, Quan Jiang, Jayalakshmi Sridhar, Jiawang
Liu, Brandan Dotson*, and Erika McClain*
DESIGN, SYNTHESIS, AND
EVALUATION OF CARBAZOLE
ANALOGS AS POTENTIAL
CYTOCHROME P450 INHIBITORS,
(12) 89
, Quan Jiang, Jayalakshmi Sridhar, Jiawang
Liu, Minaruzzaman, Brandan Dotson*, and
Erika McClain*
DESIGN, SYNTHESIS, AND
EVALUATION OF A FAMILY OF
PROPARGYL PYRIDINYL ETHERS AS
POTENTIAL CYTOCHROME P450
INHIBITORS, (12) 92
Franz, Andreas H.
, Amelia Watson, Sven Hackbusch, and
Vyacheslav V. Samoshin
REVERSAL OF DIASTEREO-
SELECTIVITY – CATALYST- AND
SOLVENT-EFFECTS ON THE
STEREOCHEMICAL OUTCOME IN
THE ACYLATION OF SEVERAL
TRANS-1,2-SUBSTITUTED
CYCLOHEXANOLS, (13) 29.
, Gurbir Gudial*, and Ilona Serebnitskaya
ISOLATION AND CHARACTERIZA-
TION OF TWO POLYPHENOLS FROM
STRAWBERRIES, (15) 25.
Frielle, Thomas
,Katelyn E. Moore, Mark E. Mason, Stacy
L. Crum, and Susan Zbegner
PROTECTIVE ROLE OF
γγγγγ-GLUTAMYL TRANSPEPTIDASE
IN THE CELLULAR RESPONSE TO
REACTIVE OXYGEN SPECIES, (12) 68
Gee, David J.
, L. Kate Wright, Jonathan Zimmermann,
Kayla Cole, Karen Soule
GRANULOCYTE MACROPHAGE
COLONY-STIMULATING FACTOR
DOES NOT SUPPORT ROLLING OF
PROMYELOCYTIC LEUKEMIC
CELLS UNDER FLOW, (11) 66
Hahn, Insu Frank
,Fanchon P. Laster, Samuel Y. Hahn, and
Terry L. Anderson
RAPID QUANTITATIVE METHOD
FOR SALICIN FROM A WILLOW
TREE BY ATTENUATED TOTAL
REFLECTANCE (ATR) FOURIER
TRANSFORM INFRARED (FT-IR)
SPECTROMETER, (12) 72
Hargittai, Balazs;
, Heather L. Rust, KaLynn M. Kline,
Heather J. Harteis, Michele R.S. Hargittai,
THE INFLUENCE OF PROLINE ON
THE FOLDING OF CONOTOXINS, (11)
34
Heitz, Mark P.
, Michael G. Nicholson
USING RATIOMETRIC PROBES TO
ESTIMATE AQUEOUS NANODOMAIN
ACIDITY, (14) 54
, Leeza M. Kerr*, Shane Colvin*, and
Stephen A. Godleski†
SYNTHESIS AND CHARACTERIZA-
TION OF ALKYLTRIPHENYL-
PHOSPHONIUM CHLORIDE IONIC
LIQUIDS: WATER SOLUBILITY
COMPARED TO TRIHEXYL
(TETRADECYL)PHOSPHONIUM
CHLORIDE, (15) 40
, Kim W. Horn, and Jason W. Rupp
INHIBITION OF TYROSINASE
ACTIVITY BY IMIDAZOLIUM IONIC
LIQUIDS,, (15) 117
Holland, J.A.;
, Antonio Cardozo
INVESTIGATION OF BASE-TRIPLE
REQUIREMENTS FOR THE
FORMATION OF AN INTRAMOLECU-
LAR RNA TRIPLE HELIX, (11) 112
Jensen, Elizabeth
, Marissa Saladin
DETERMINATION OF PHYSICAL
PROPERTY TRENDS OF
ALKYLAMMONIUM METAL
BROMIDE LIQUID CRYSTALS, (13) 26.
Jones, Cecil L.
, Harshavardhan Kenche, Brittany Bush*
and Racheal Daniels*
INDIRECT MEASURE OF
CATALASE ACTIVITY FROM THE
MUSCLE TISSUE OF A MERLANGIUS
MERLANGUS, (13) 64
Kennedy, Sarah A.
, Ashley M. Blystone*, Justin M. Jones*,
Helen M. Boylan
QUANTIFICATION OF 4-
ETHYLPHENOL IN BELGIAN STYLE
BEERS BY GAS CHROMATOGRAPHY-
MASS SPECTROMETRY, (12) 4
King, Daniel
, Andy Davisson, Katie Speidel, Jason
Stegink,
A COMPUTATIONAL APPROACH
TO UNDERSTANDING CROP DISEASE
RESISTANCE AND SUSCEPTIBILITY,
(11) 20
,Kim Cleary*, Scott Fenstermacher*,
Brayton Kiedrowski*, Ben Hayes*, Olivia
Auell*, Caroline Chow*, Erik Hayes,
THE EFFECTS OF ACUTE
EXERCISE AND MEAT FASTING/
FEASTING ON URINARY 3-
METHYLHISTIDINE BY LIQUID
CHROMATOGRAPHY – MASS
SPECTROMETRY, (14) 36
Kostecka, Keith
, Bryce Wolfe, and Aniya Vazquez
DETERMINATION OF CADMIUM IN NON-
ORGANICALLY GROWN BATAVIAN,
BUTTERHEAD, CHINESE, ICEBERG,
LOOSELEAF AND ROMAINE
LETTUCES USING ATOMIC
ABSORPTION SPECTROSCOPY (AAS),
(15) 74
, Lyba Zia
ABILITY OF BRASSICA RAPA TO
PHYTOREMEDIATE CADMIUM, (15)
79
Law, Neil,A.
, Brendan L. Mitchell, Marcus D. Tuttle,
Matthew D. Maynard, Norman V. Duffy,
THERMOGRAVIMETRIC
ANALYSIS OF SALICYL-
HYDROXAMIC ACID-BASED
METALLACROWNS: A NEW
TECHNIQUE FOR METALLACROWN
CHARACTERIZATION, (11) 4
Lee, Nancy E.
, Ugne Aleknaite, Virgnia Liu, Kathleen
Thomas, Daisy Bourassa, Richard Gurney,
STUDY OF SOLVENT-FREE
ASYMMETRIC REDUCTION OF 1-
ACETONAPHTHONE, (11) 78
Lisic, Edward C.
, Amanda Werlein*, Amanda Koch*, and
Jennifer Conner*
SYNTHESIS AND ANTI-MICROBIAL
STUDIES OF A SERIES OF 3-FORMYL-
CHROMONE THIOSEMICARBAZONE
LIGANDS AND THEIR Cu(II)
COMPLEXES INCLUDING THE
POTENT AKT INHIBITOR [Cu(FC-
TSC)Cl2], (12) 96
, Rebecca Lampley*, Bradley McGill*,
Amanda L. Koch*, and Jennifer D Conner
Cu(II) AND Pd(II) 6-METHYLPYRIDINE-2-
CARBOXALDEHYDE-THIOSEMI-
CARBAZONE COMPLEXES:
POTENTIALLY POTENT
TOPOISOMERASE IIA INHIBITORS,
(14) 25
, Erik Hoy*, Megan Monteen*, Erica
Stoner*, Bradley C. McGill*.
SYNTHESIS OF A SERIES OF 5-
FORMYL-2-FURAN SULFONIC ACID
THIOSEMICARBAZONE AND
SEMICARBAZONE COMPOUNDS, (14)
30
Ma, Yinfa
, Tiffany Ramsey, Chuan Wang,
REMOVAL EFFICIENCY OF
SULFAMETHOXAZOLE IN WATER
SAMPLES USING NANOMATERIALS,
(11) 27
McClure, Mark
, Sandra Buffkin
ASSIGNMENT OF 1H AND 13C
RESONANCES IN ααααα-cis
[Co(ampy)2(NO
2)
2]NO
3, (11) 63
, Brianna Locklear*
A TWO-DIMENSIONAL NMR
STUDY OF DINITROBIS(1,10-
PHENANTHROLINE) COBALT(III)
CHLORIDE, (14) 44
, Kennedi Stewart
A TWO-DIMENSIONAL NMR
STUDY OF DINITROBIS(2,2-
BIPYRIDINE)COBALT(III)
CHLORIDE,, (15) 113
Mechelke, Mark F.
, Addison A. Dumke, and Sarah E.
Wegwerth
DESIGN AND SYNTHESIS OF A
POTENTIAL CHEMOTHERAPEUTIC
AGENT USING GONIOTHALAMIN AS
A NATURAL PRODUCT TEMPLATE,
(12) 47
, Jason T. Brethorst*, Carina Crookston*,
Courtney Klinkhammer*, Brittany N.
Miller*, Curtis Payne*, Makenzie
Pillsbury*, Christina R. Ringsmuth*, and
Moriah Traut*
DESIGN AND SYNTHESIS OF A
NOVEL ALPHA-METHYLENE
LACTONE CHEMOTHERAPEUTIC
AGENT, (13) 12
, Katy Platt, and Connor Pribula
CHEMOTHERAPEUTIC DRUG
DESIGN: AN EFFICIENT SYNTHESIS
OF 4-SUBSTITUTED ALPHA-
METHYLENE-GAMMA-LACTONES,
(15) 63
, Sarah Hopfner, Natalie McIntire, and
Nathanial Cherry
CHEMOTHERAPEUTIC AGENTS
FROM NATURAL PRODUCT
TEMPLATES: THE DESIGN AND
SYNTHESIS OF NOVEL INDANONE
ANALOGUES, (15) 67
Miller, Eric T.
, Kristal J. Benally*, Shawn D. GreyEyes*,
and Jason T. McKenzie*
DETERMINATION OF OXALATE
ION DOPANT LEVEL IN
POLYPYRROLE USING FT-IR, (13) 5
, Daniel Ellis, Duran Charles, Jason
McKenzie
FABRICATION OF A RETINAL
PROSTHETIC TEST DEVICE USING
ELECTRODEPOSITED SILICON
OVER POLYPYRROLE PATTERNED
WITH SU-8 PHOTORESIST (14) 96
Mugweru, Amos
, Monika Mihalenkova, Elizabeth Cronin,
Marc Iuliucci
ANALYSIS OF ELECTROCHEMI-
CALLY ENZYME DRIVEN DRUG
METABOLISM OF DICLOFENAC
USING GAS CHROMATOGRAPH
MASS SPECTROMETRY, (12) 36
Mushrush, George W.;
, Quyen DeRoule, Nelson Castillo,
Michele Lussos, Carolyn Nguyen, Hoang O.
Nguyen, Jessica Sheen, Worknesh Terkik,
Phung Vo,
STORAGE STABILITY AND
LUBRICITY OF SOY, CORN AND
CANOLA-DERIVED BIODIESEL
BLENDED WITH PETROLEUM-
DERIVED DIESEL, (11) 30
, Mahmoud Eljack, Hunfa Asghar, Isa Abu
El Hawa, Arturo Ruiz, Jennifer To, Steve
Yopa
ARGAN OIL AND ITS METHYL
ESTERS AS PETROLEUM DIESEL
BLENDING STOCKS, (12) 41
Nishimura, A.M.
, Hannah E. Ryan, Shanan Lau, Bradley B.
Bauer, , K.A. Martin and
EFFECT OF WATER ON THE
EXCIMER FLUORESCENCE DECAY
RATE CONSTANT OF NAPHTHALENE
ON ALUMINA, (11) 90
, Shanan Lau, Hannah E. Ryan, Bradly B.
Baer, K.A. Martin
LASER INDUCED FLUORESCENCE
DECAY OF 1-METHYL-, 1-METHOXY-
AND 1-ETHYLNAPHTHLENE ON
ALUMINA DURING TEMPERATURE
PROGRAMMED DESORPTION, (11)
107
, Hannah E. Ryan, Shanan Lau, Bradly B.
Baer, K.A. Martin
LASER INDUCED FLUORESCENCE
RESONANCE ENERGY TRANSFER OF
9,10-DIHYDROPHENANTHRENE AND
9-FLUORENONE ON ALUMINA
DURING TEMPERATURE PRO-
GRAMMED DESORPTION, (11) 116
, Hannah E. Ryan*, Shanan Lau*
FORMATION OF THE MIXED
EXCIMER OF 1- AND 2-METHYL-
NAPHTHALENE ON ALUMINA
DURING TEMPERATURE PRO-
GRAMMED DESORPTION, (12) 21
, Nicole K. Grabe, Brandon D. Driver,
Shanan Lau
FORMATION OF ISOTOPICALLY-
MIXED EXCIMERS OF METHYL-
NAPHTHALENES BY VAPOR
DEPOSITION ON ααααα-ALUMINA , (12) 43
, Marcus B. Anthony, Brandon D. Driver,
Nicole K. Grabe, and K.A. Martin
EFFECT OF SIMPLE ALIPHATIC
ALCOHOLS ON THE LASER-
INDUCED EXCIMER FLUORES-
CENCE DECAY OF 2-METHYLNAPH-
THALENE ON ααααα-ALUMINA DURING
TEMPERATURE PROGRAMMED
DESORPTION, (12 51
, Nicole K. Grabe, Marcus B. Anthony, and
K.A. Martin
EFFECT OF CIS- AND TRANS-
DECALIN ON THE LASER-INDUCED
EXCIMER FLUORESCENCE DECAY
OF 2-METHYLNAPHTHALENE ON ααααα-
ALUMINA DURING TEMPERATURE
PROGRAMMED DESORPTION, (12) 61
, Melissa A. Shew, Rachel J. DeHoog, and
K.A. Martin
EFFECT OF WATER ON THE
LASER INDUCED EXCIMER
FLUORESCENCE DECAY OF 2-
METHYLNAPHTHALENE AND
NAPHTHALENE ON ααααα-ALUMINA
DURING TEMPERATURE PRO-
GRAMMED DESORPTION, (13) 34.
, Melissa A. Shew, Rachel J. DeHoog, and
K.A. Martin
EFFECT OF 1-CHLORO-PENTANE
ON THE ENERGY TRANSFER FROM
NAPHTHALENE TO 2,6-DI-
METHYLNAPHTHALENE ON ααααα-
ALUMINA DURING TEMPERATURE
PROGRAMMED DESORPTION, (13) 45
, Rachel J. DeHoog*, Melissa A. Shew*,
Xianzhang Geng*, and K.A. Martin‡
THE EFFECT OF ENHANCED
ADLAYER ORDERING BY 1-
CHLOROALKANES ON THE ENERGY
TRANSFER FROM NAPHTHALENE
TO 2-ETHYLNAPHTHALENE ON Al2O
3
DURING TEMPERATURE PRO-
GRAMMED DESORPTION, (14) 20
, Xianzhang Geng*, Rachel J. DeHoog*,
Andrew D. Olson*, and Trevor M. Ban*
EFFECT OF NAPHTHALENE
ADLAYER ON THE DESORPTION
ENERGIES OF A HOMOLOGOUS
SERIES OF 1-CHLOROALKANE ON α-
ALUMINA, (14) 47
, Xianzhang Geng, Karli R. Holman, and
K.A. Martin
EFFECT OF A HOMOLOGOUS
SERIES OF ALKANES ON THE
DISORDER-TO-ORDER TRANSITION
OF NAPHTHALENE ON ααααα-ALUMINA,
(14) 63
, Christopher C. Riba*, Jonathan B.
Cleek*, Jonathan J. Wong*, Blake D.
Fonda*, and Andrew D. Olson*
EFFECT OF VOLATILE OCTANE
ISOMERS ON THE DISORDER-TO-
ORDER TRANSITION OF NAPHTHA-
LENE ON Al2O
3, (15) 36
, Handolsam Chung, Christopher C. Riba,
and K.A. Martin
p-DICHLOROBENZENE-
NAPHTHALENE EXCIPLEX ON Al2O
3,,
(15) 95
, Christopher C. Riba, Handolsam Chung,
and K.A. Martin
ENERGY TRANSFER IN NEAR-
RESONANT SINGLET ELECTRONIC
STATES: NAPHTHALENE AND
BIPHENYL ON Al2O
3,, (15) 99
, Handolsam Chung, Christopher C. Riba,
and K.A. Martin
ENERGY TRANSFER IN NEAR-
RESONANT SINGLET ELECTRONIC
STATES WITH NAPHTHALENE:
BIPHENYL, 4-METHYLBIPHENYL,
4,4’-DIMETHYLBIPHENYL AND p-
TERPHENYL ON Al2O
3,, (15) 103
Park, Han Jung
, Wittmann S. Murphy
A STUDY OF THE
PHOTOACOUSTIC EFFECT IN SF6 AT
HIGH CONCENTRATIONS AND AT
TRACE DETECTS IN N2, (14) 90
Parra, Ruben D.
, Valentina Djordjevic
EXPLORING THE POTENTIAL OF
HALOGEN BONDING INTERACTIONS
IN THE DEVELOPMENT OF NOVEL
PROTEIN TYROSINE KINASE
INHIBITORS, (14) 93
Pfennig, Brian W.
, Aubrey R. Paris
PYRAZINE AND A PYRAZINE-
MODIFIED CYANOFERRATE
COMPLEX IN THE ELECTROCHEMI-
CAL AND PHOTOCHEMICAL
REDUCTION OF CARBON DIOXIDE
TO METHANOL, (14) 86
Pharr, Daniel Y.,
, Aaron Hickman
ENHANCEMENT EFFECTS OF
SURFACTANTS ON THE DC PLASMA
ANALYSIS OF P-BLOCK ELEMENTS,
PART I: GALLIUM AND INDIUM, (11)
54
, Aaron Hickman
ENHANCEMENT EFFECTS OF
SURFACTANTS ON THE DC PLASMA
ANALYSIS OF P-BLOCK ELEMENTS,
PART II: GERMANIUM, SILICON, TIN,
AND TELLURIUM, (11) 102
, Aaron Hickman
ENHANCEMENT EFFECTS OF
SURFACTANTS ON THE DC PLASMA
ANALYSIS OF P-BLOCK ELEMENTS,
PART III: ANTIMONY, ARSENIC, AND
BISMUTH , (12) 28
Piatt, Joseph J.
, Erica M. Patterson
OCCURRENCE OF PHARMACEU-
TICALS IN ONSITE WASTE
TREATMENT SYSTEMS IN
WAUKESHA COUNTY, (13) 55
Potts, Gretchen E.
, Sarah A. Hensley*
STOICHIOMETRIC DETERMINA-
TION OF 1-(2-PYRIDYLAZO)-2-
NAPHTHOL COMPLEXATION WITH
Pb(II) BY MASS SPECTROMETRY, (13)
74
Prak, Dianne J. Luning
, M. Hope Jones*
DEVELOPING SURROGATE
MIXTURES FOR ALTERNATIVE JET
FUELS FROM n-TETRADECANE AND
ISODODECANE, (14) 50
Richter, Robert C.
, and Andre James*
DIRECT MERCURY ANALYSIS AS A
SCREENING TOOL FOR MERCURY IN
BABY FOOD, (14) 1
, Adam Zayed, and William Lawrence
THE USE OF MICROWAVE-
ASSISTED EXTRACTION FOR
ENCAPSULANT QUALITY CONTROL
OF COMMERCIAL SOLAR CELL
MODULES, (14) 69
, Melissa Rangel, and Brittany House
EVALUATION OF COMMERCIAL
TATTOO INKS FOR POTENTIAL
TOXICITY USING SEM/EDS AND ICP-
MS, (14) 78
Rodriguez, Kenneth R.
, Anthony E. Jones*, and Barbara Belmont
EVALUATION OF FREEZE DRIED
ALOE VERA AND NOPAL CACTUS
FOR POSSIBLE HEALTH TREAT-
MENTS BY COMPARISON OF
ANTIOXIDANT PROPERTIES AND
FREE RADICAL INHIBITION, (13) 67
Samoshin, Vyacheslav V.
, Vincent A. DiMassa, Irina A. Dotsenko,
Yu Zheng, and Patrick Batoon
EXPLORATION OF trans-2-(1,2,3-
TRIAZOLYL)-CYCLOHEXANOL
DERIVATIVES AS POSSIBLE pH-
TRIGGERED MOLECULAR
SWITCHES, (14) 73
Santiago, Manuel F.
, Mallory L. Hacker, and Cara A. Clouse
PYRIMIDINE DEGRADATION IN
PSEUDOMONAS MENDOCINA ATCC
25411, (11) 45
Schreiber, Henry D.;
, Timothy V. Johnson,
CHEMICAL CONTROL OF
PAPERWHITE (NARCISSUS TAZETTA
cv. ZIVA) GROWTH AND FLOWER-
ING, (11) 1
, Andrew H. Jones, Amy M. Swink,
Corinne M. Lariviere, and Taylor D. Godsey
SPECTROPHOTOMETRIC
CHARACTERIZATION OF
ALUMINUM-ANTHOCYANIN
COMPLEXES IN A MODEL SYSTEM
FOR FLORAL COLORATION, (11) 37
, Ruthann P. Hodges*
SPECTROSCOPIC pH DETERMINA-
TION of Hydrangea Sepals WITH ACID-
BASE INDICATORS, (13) 8
Keyword Index Volume 11-15
Absorbance, (12) 72
Acetic acid, (15) 108
Acetylenes, (12) 89, 92
Activation energy, (15) 36
Achiral Catalyst, (13) 29
Acid-base indicator, (13) 8
Acrylamide, (15) 71
Activity, (13) 64
Activation energy, (14) 47, 63, (15) 95, 99
Acylation, (13) 29
5-alkylidenemalonates, (11) 70
α-conotoxins, (11) 34
Agricultural model, (11) 24
Agrimoniin, (15) 25
Akt Inhibitor, (12) 96
Alcohol, (11), 1; (13) 15; (14) 40
Alkylammonium metal bromides, (13) 26
Aloe Vera, (13) 67
Alpha-methylene, (15) 67
Alpha-methylene-gamma-lactones, (15) 63
Aluminum, (11) 37
Amino acid, (15) 71
2-(aminomethyl) pyridine, (11) 63
Ampy, (11) 63
Amyloids, (12) 56
Analytical figures of merit, (12) 4
Anisotropic effect, (11) 94
Anthocyanidin, (11) 37
Anthocyanin, (11) 37
Antimicrobial, (14) 12
Antimony, (12) 28
Antioxidants, (13) 67
AOT, (14) 54
Argan oil, (12) 41
Aromatic interaction, Peptide, (11) 94
Atomic absorption, (15) 48
Atomic spectroscopy, (14) 83, (15) 74, 79
Arsenic, (12) 28
Asymmetric, (11) 78
Asymmetric induction, (11) 73, (12) 24
ATR-FT-IR, (12) 72
AutoDock™ Vina, (15) 122
Azeotrope, (11) 98
Baby Food, (14) 1
Base stacking, (11) 15
Base-Triple, (11) 112
Beer, (12) 4
Beryllium sulfide, (11) 127
β-hairpin, (11) 94
Binding energy, (11) 127
Biodiesel, (11) 30, (12) 41, (12) 83
Biphenyl, (15) 99, 103
2,2-bipyridine, (15) 113
Bismuth, (12) 28
Bluing, (11) 37
Bouncing frequencies, (15) 1
Brettanomyces, (12) 4
Bromophenol blue, (13) 8
B3LYP, LANL2DZ(15) 1, 6
Butylmethypyrrolidinium, (12) 75
B-vitamins, (13) 21
Cadmium, (11) 123, (15) 74, 79
Cadmium selenide, (15) 48
Caffeine, (13) 21
Cancer, (12) 47, (13) 12, (15) 63, 67
Canola oil, (11) 30
Carbazoles, (12) 89
Carbohydrate, (15) 71
Carbonated beverages, (13) 21
Carbon dioxide, (14) 86
Catalase, (13) 64
Casuarictin, (15) 25
Chelation, (11) 123
Chemical education research (CER), (14) 83
Chemiluminescence assays, (13) 40
Chiral, (11) 78
Chiral crown ether, (11) 73, (12) 24
1-chloroalkane,(14) 47
1-chlorohexane, (11) 107
Choline hydroxide, (12) 83
Circular Dichroism, (13) 50
Claisen-Schmidt Condensation, (13) 18
Click reaction, (14) 73
Cl-NERF, (14) 54
Clusters, (11) 127
CO2 Reduction, (14) 86
Cobalt(III), (11) 63
Cobalt(III) chloride, (15) 113
Cobalt complexes, (14) 44
Competitive Chelation, (12) 56
Computational, (11) 20
Conformational analysis, (11) 84
Computational chemistry, (12) 33, (13) 71
Conformational equilibrium, (13) 1
Conformational transmitters, (14) 73
Copper, (11) 4
Copper(I) hydride, (11) 81
Core/shell, (15) 48
Corn oil, (11) 30
Costunolide, (15) 63
COSY, (14) 44, (15) 113
Coumarin, (15) 67
Curcumin, (12) 56
Cyclic ketones, (11) 70
Cyclic voltammetry, (12) 86
Cyclohexane, (11) 98
Cyclohexenone, (12) 47
Cytochrome P450, (12) 36, 89, 92
Cytotoxicity, (13) 18
DC Plasma, (11) 54, 102, (12) 28
Decafluoro-n-pentane-1,5-diol, (11) 84
Decay rate constants, (11) 90, 107, 116, (12) 21,
(12) 43, 51, 61
Degradation, (11) 45
Deposition, (11) 90, 107, 116, (12) 21, (12) 43,
51, 61
Desorption,(14) 47, 63, (15) 36, 95, 99
Deuterated ionic liquid, (12) 75
Diabetes, (13) 67
Dicationic catalyst, (12) 24
p-Dichlorobenzene, (15) 95
Diclofenac, (12) 36
Differential scanning calorimetry, (12) 16
DFT, (11) 98, (15) 88
DFT calculations, (15) 12
9,10-dihydrophenanthrene, (11) 116
Diimine Crystal Structure, (12) 1
Diimine Synthesis, (12) 1
4,4’-dimethylbiphenyl, (15) 103
Dimethyl carbonate, (12) 65
Dimethylformamide, (12) 16
2,6-dimethylnaphthalene, (13) 45
Dinitrochalcones, (13) 18
Direct exposure probe, (13) 74
Disorder-to-order transition, (15) 36
Disulfide bridges, (11) 34
Dithiepins, (11) 49
Dithiocarbamate, (11) 11, (12) 7, (13) 60, (15) 84
DM-NERF, (14) 54
Docking, (14) 93
Dopant level determination, (13) 5
DNA stability, (11) 15
Drug design, (14) 93
DSC, (13) 26
EDS, (14) 78
Edge-to-face orientation, (11) 94
Electrodeposition, (14) 96
EIE, easily ionized elements, (11) 54, 102, (12)
28
Elemental analysis, (11) 123
Electrolytic booster, (12) 19
Energetic materials, (13) 71
Energy drinks, (13) 21
Energy transfer, (13) 45, (14) 20
Engine efficiency, (12) 19
Enhanced water, (13) 21
Enol ether, (12) 47
Enzyme inhibitors, (12) 89, 92
Enzyme Kinetics, (15) 117
Enzyme Metabolism, (12) 36
Ester, (14) 59
Ethanol, (11) 1
4-ethylphenol, (12) 4
1-ethylnaphthalene, (11) 107
2-ethylnaphthalene, (14) 20
EVA, (14) 69
Exercise, (14) 36
Excimer, (11) 90, 107, (12) 51, 61, (13) 34, 45,
(14) 20
Exciplex, (15) 95, 99, 103
Extraction, (12) 4, (14) 69
Factor Analysis, (12) 11
FAME, (12) 41
Fasting, (14) 36
Fe-TAML, (15) 21
Sherlock, Terrence P.
, Laura Stewart, Justin Ryan, and Janelle
Santarsiero
DEVELOPING NOVEL CHEMICAL
FINGERPRINTS OF RED WINE WITH
HIGH PERFORMANCE LIQUID
CHROMATOGRAPHY, (14) 59
Shuford, Kevin L.
,Dustin C. Buller*
EFFECTS OF ETHANOL ON ION
TRANSPORT IN THE NAVMS
VOLTAGE-GATED SODIUM
CHANNEL: A MOLECULAR
DYNAMICS STUDY, (14) 40
Siderhurst, Matthew S;
, Allison E. Glick and Roman J. Miller
METHOD DEVELOPMENT FOR
ELEMENTAL ANALYSIS OF FOLIAR
BLUEBERRY (VACCINIUM
CORYBOSUM L.) SAMPLES, (11) 24
Silverstein, Todd P.
, Katie Hansen, and Andrew Zimmerman
CAN SUNSCREEN GIVE YOU SKIN
CANCER? MONITORING THE TiO2-
CATALYZED PHOTOGENERATION
OF H2O
2 USING THE LUMINOL/
HORSERADISH PEROXIDASE
CHEMILUMINESCENCE ASSAY, (13)
40
Smoliakova, Irina P.
, Calvin R. Henry, and Andrew N. Owen
EXPLORING THE USE OF ACETIC
AND LEVULINIC ACIDS IN SOLID-
PHASE SYNTHESIS OF RENEWABLE
FUEL PRECURSORS,, (15) 108
Strout, Douglas L.
, Carrie Sanders
RESONANCE EFFECTS ON THE
KETO-ENOL TAUTOMERISM OF
ALIPHATIC, AND AROMATIC
COMPOUNDS, (12) 33
, Tae’Ja Privott*, and Kasha Casey
STRUCTURAL PROPERTIES OF
HIGH-ENERGY N8C
4 MOLECULES:
CYCLIC TETRAMERS OF NCN, (13) 71
Swartling, Daniel J.
, Casey J. McCormick, Jungwun Hwang,
NEW DISCOVERIES IN THE
KNOEVENAGEL SYNTHESIS OF 5-
ALKYLIDENE MELDRUM’S ACIDS,
(11) 70
Tatko, Chad D.
, Caleb J. Uitvlugt, Jin Sung, Caleb M.
Mutschler, Daniel B. Meyer,
AROMATIC INTERACTIONS OF
NAPHTHYLALANINE IN A TWELVE
AMINO ACID PEPTIDE, (11) 94
Thomasson, Kathryn A.
, Nicole Ann Larson, Ka Xue Xiong, Rahul
Nori, Tsvetan Aleksandrov, and Akongnwi
C. Jungong
RELATIVE BINDING ENERGIES OF
NICOTINAMIDE ADENINE
DINUCLEOTIDE TO PROTEINS, (15)
51
Tirla, Cornelia
, Thomas Dooling, Shanna Harrelson ,
Rachel B. Smith, Donella Hunt*,
Christopher McKee*
USING IR SPECTROSCOPY TO
DETERMINE BIODIESEL CONVER-
SION, (12) 83
Vaden, Timothy D.,
, Timothy M. Hall, Dean G. Horacek, and
Aurora Musilli
COMPETITIVE COPPER (II)
CHELATION BY HISTIDINE,
HISTIDINE-RICH PEPTIDES, AND
CURCUMIN, (12) 56
Vander Griend, Douglas A.
, Daniel Kwabena Bediako*
DETAILED SPECTROSCOPIC AND
THERMODYNAMIC CHARACTER-
IZATION OF NICKEL(II) COMPLEXES
WITH METHYL/PYRIDINE ATTAINED
VIA FACTOR ANALYSIS, (12) 11
VonRue, Isaac
, Benjamin Foreman*, and Joseph
Monaghan*
THERMOREVERSIBLE GELATION
OF POLYCAPROLACTONE IN
DIMETHYLFORMAMIDE, (12) 16
Wade, Edmir O.
, Joseph J. Kawa
DEVELOPMENT OF A DITHIEPIN
FRAMEWORK FOR NOVEL HOST
MOLECULES, (11) 49
, Ryan J. McGuire*, and Joseph J. Kawa*
CONFORMATIONAL ANALYSIS OF
DITHIANES AND DIOXANES USING
VT-NMR AND EXCEL SIMULATIONS,
(13) 1
Weisshaar, Duane E.
, Bethany D. Kaeming*, Connor R.
Lamberson, Gary W. Earl
SOLVENT EFFECTS ON
METHYLATION OF PRIMARY
AMINES WITH DIMETHYL
CARBONATE, (12) 65
, Nicole J. Altena, Rachel S. Anderson,
Riley P. McManus, Austin R. Letcher,
Mathew E. Amundson*, and Gary W. Earl
SYNTHESIS OF N,N-BUTYL-D9-
METHYLPYRROLIDINIUM
BIS(TRIFLUORO-METHANE-
SULFONYL)IMIDE, (12) 75
, Kimberly M. Stallings*, Jacob L.
Dancler*, and Barrett E. Eichler
AN IMPROVED METHOD FOR
ATOMIC ABSORPTION ANALYSIS OF
CdSe/ZnS CORE/SHELL QUANTUM
DOTS, (15) 48
White, Shawn
, Paul Hanson*
REGARDING CLAIMS OF
IMPROVED EFFICIENCY IN
INTERNAL COMBUSTION GASOLINE
ENGINES BY THE ADDITION OF
HYDROGEN AND OXYGEN GAS
MIXTURES, (12) 19
, James (Skippy) Sanders*, Carol Kay
Lindsay*, Catherine Stailey*, and Samuel
Kadavakollu†
DETERMINATION OF FATTY ACID
PROFILES OF COMMERCIALLY
AVAILABLE COOKING OILS BY
ACID-CATALYZED
TRANSESTERIFICATION, (14) 17
Williams, Joseph E.
,Casey B. Senechal*
A NEW POLYMORPH OF MALEIC
ANHYDRIDE, (14) 34
Xue, Liang
, Arlen Guillen, Manali Aggrawal, and
Jiayu Xue
TOPOLOGICAL CHARACTERIZA-
TION OF OXODG CONTAINING G-
QUADRUPLEXES VIA THERMAL
DIFFERENCE SPECTRA AND
CIRCULAR DICHROISM, (13) 50
Yang, Thao
, Cheng Her*, Andrew R. Lynch*, Ronald
J. White*, Ming Wang*, and William M.
Westler
SHORT PROLINE-SUBSTITUTED
MUC1 MUCIN PEPTIDES CAN BIND
TO MOUSE MUC1 MONOCLONAL
ANTIBODY REVEALED AS
REVEALED BY STD NMR, (14) 5
Zoellner, Robert W.
, Katrina C. Martin
COMPLETE CONFORMATIONAL
ANALYSES OF
TETRAFLUOROETHANE-1,2-DIOL,
HEXAFLUORO-PROPANE-1,3-DIOL,
OCTAFLUORO-n-BUTANE-1,4-DIOL,
AND DECAFLUORO-n-PENTANE-1,5-
DIOL, (11) 84
Flowers, (11) 1
Flower color, (11) 37
Fluorene, (11) 116
9-fluorenone, (11) 116
Fluorescence, (11) 90, 107, 116, (12) 21, (12) 43,
(12) 51, 61, (13), 45, (14) 12, 20
Fluorescence spectroscopy, (15) 16
Foliar micronutrients, (11) 24
Formylchromone-thiosemicarbazone, (12) 96
5-Formyl-2-furan sulfonic acid, (14) 30
Free-Radical, (13) 67
Free radical photogeneration, (13) 40
FT-IR, (13) 5
Fuel additives, (12) 19
Fuel Lubricity, (11) 30
Gallium, (11) 54, (15) 84
GC-FID analysis, (12) 83
GC-MS, (12) 4, (14) 17
Gas Chromatography, (14) 17
Gel, (12) 16
Gel content, (14) 69
Geometries, (15) 1, 6
Germanium, (11) 102
γ-glutamyl transpeptida, (12) 68
Glutathione, (12) 47, (12) 68, (13) 12, (15) 63,
67
Goniothalamin, (12) 47, (13) 12
G-quadruplex, (15) 16
G-quadruplex DNA, (13) 50
Gram-positive bacteria, (14) 12
Granulocyte macrophage colony-stimulating
factor (GM-CSF), (11) 66
Green chemistry, (15) 21
Groundwater, (13) 55
Halogen bonding, (14) 93
Hartree-Fock, (11) 84
Heptane, (14) 63
Heteroaromatic aldehydes, (11) 70
Heterocyclic rings, (13) 1
Hexafluoropropane-1,3-diol, (11) 84
Hexane, (14) 63
High energy materials, (15) 12
High Performance Liquid Chromatography, (11)
27, 119, (13) 21, (14) 59
HIV, (15) 122
HL-60, (11) 66
HOMO-LUMO, (15) 1
HOMO-LUMO energy difference, (15) 6
Host Molecules, (11) 49
Human serum albumin, (12) 79
Hydrangea, (13) 8
Hydrogen bonding, (14) 93
Hydrogen peroxide, (12) 68
Hydrogen storage, (11) 127
Hydrogen ion reduction, (12) 86
Hydrolase, (15) 51
Hydrotreated renewable fuels, (14) 50
Hydrophobic effect, (11) 15
Ibuprofen, (15) 21
ICP-MS, (14) 78
Imidazolium, (15) 117
Imine Condensation, (12) 1
Indanone, (15) 67
Indium, (11) 54, (15) 84
Infrared Spectroscopy, (12) 83
Inhibitor Protein, (11) 20
Inhibitors, (14) 93, (15) 117
Interaction energies, (15) 1
Ionic Liquid, (14) 96, (15) 40, 117
Ion channel, (14) 40
IR, (11) 98
Iron, (11) 11, (12) 7, (13) 60, (15) 84
Isomerase, (15) 51
Isopropanol, (11) 59, (15) 44
Job’s method, (11) 123
J-resolved, (15) 113
Keto-enol tautomerism, (12) 33
Kinases, (14) 93
Knoevenagel condensation, (11) 70
Lactic acid, (14) 59
Lactone, (13) 12
Laser, (14) 83, 90
Laser induced fluorescence, LIF, (11) 90, 107,
116, (12) 21, (12) 43, (12) 51, 61, (13) 34,
45, (14) 20
LCMS, (13) 55; (14) 36
Lead(II), (13) 74
Lettuce, (15) 74
Levulinic acid, (15) 108
LIBS, (14) 83
Lifetimes, (11) 90, 107, 116, (12) 21, 51, 61
Ligand exchange, (13) 60, (15) 84
Ligase, (15) 51
Line shape simulations, (13) 1
Lipid Profile, (14) 17
Liquid crystals, (13) 26
Lyase, (15) 51
Magnetic nanoparticles, (12) 79
MALDI, (15) 88
MALDI-TOF mass spectrometry, (15) 25
Malic acid, (14) 59
Maleic Anhydride, (13) 34
Maryland Coastal Bays, (11) 119
Mass Spectrometry, (12) 56, (13) 74
Meldrum’s acid, (11) 70
Melting temperature, (11) 15
Merrifield resin, (15) 108
Mass Spectrometry, (14) 17
Membrane active, (14) 12
Membrane permeability, (14) 12
Membrane protein, (13) 40
Mercury Analysis, (14) 1
Mesophase, (13) 26
Metabolism, (12) 89, 92
Metabolite, (14) 36
Metal carbonyl, (11) 11, (12) 7
Metal Ions, (12) 56
Metallacrown, (11) 4
Metallamacrocyle, (11) 4
Methanesulfonic Acid, (13) 18
Methanol, (11) 98, (14) 86
1-methoxynaphthalene, (11) 107
Methylation, (12) 65
4-Methylbiphenyl (4-phenyltoluene), (15) 103
Methylene, (13) 12
Methyl Esters, (11) 30
3-methylhistidine, (14) 36
1-methylnaphthalene, (11) 107, (12) 21, (12) 43
2-methylnaphthalene, (12) 21, (12) 43, 51, 61,
(13) 34
Methylpyridine, (12) 11
6-methylpyridine-2-carboxaldehyde, (14) 25
Michael addition, (11) 73
Microemulsions, (14) 54
Microwave, (14) 69
MIC studies, (12) 96
Middle Distillate, (11) 30
Mixed excimer, (12) 21, (12) 43
Molecular mechanics, (15) 51
Molecular Modeling, (11) 20
Molecular orbitals, (15) 6
Molecular pH-switches, (14) 73
[M+2]+ mass peak, (15) 88
Muc1 antibody recognition epitope, (14) 5
Mucin peptide, (14) 5
Mucin peptide-antibody interactions, (14) 5
Multi-site catalyst, (12) 24
Nano-materials, (11) 27
Naphthalene, (11) 90, 107, 116, (13) 34, 45, (14)
20; (14) 47, 63, (15) 36, 95, 99, 103
Nearest-neighbor (NN), (11) 15
Nervous system, (13) 40
Nickel, (12) 11
Nitrated diborane, (15) 12
Nitrogen, (13) 71
Nitrogen-based matrices, (15) 88
Nopal Cactus, (13) 67
NMR, (11) 63; (14) 44, (15) 25, 40
Nuclear factor–kappa B, (15) 63, 67
Nuclear factor–kB, (12) 47
Octafluoro-n-butane-1,4-diol, (11) 84
Octane, (14) 63, (15) 36
Organic blueberry farm, (11) 24
Organic synthesis, (12) 89, 92
Organo-sulfur, (11) 49
Oxa-birdcage diketals, (13) 15
Oxalate, (13) 5
Oxidative degradation, (15) 21
Oxidative stress, (12) 79
Oxidoreductase, (15) 51
Oxygen heterocycles, (13) 15
Paperwhites, (11) 1
PAN , (13) 74
Parallel plate flow chamber, (11) 66
Pellet, (13) 5
Pentacycloundecane-8,11-dione, (13) 15
Pentane, (14) 63
Petroleum diesel, (12) 41
pH, (11) 123, (13) 8, (14) 54
Pharmaceuticals, (13) 55
Phase transfer catalyst, (11) 73, (12) 24
Phenolic, (13) 67
Phosphonium, (15) 40
Photoacoustic, (14) 90
Photoresist, (14) 96
Photosynthetic pigments, (11) 119
Photolysis, (14) 86
Phytoplankton, (11) 119
Phytoremediation, (15) 79
Picoline, (12) 11
pKa, (14) 54
Polycaprolactone, (12) 16
Polygalacturonase, (11) 20
Polymorph, (14) 34
Polyphenols, (15) 25
Polypyrrole, (13) 5, (14) 96
Porphyrins, (15) 16
Potatoes, (15) 71
Prochiral reduction, (11) 73, (12) 24
Proline, (11) 34
Propargyl pyridinyl ethers, (12) 92
Prosthesis, (14) 96
Protein Docking, (15) 122
Protein folding, (11) 34
Proton NMR, (13) 60, (15) 84
Protonation mechanism, (15) 88
Pseudomonas mendocina, (11) 45
PTK, (14) 93
Pyridine, (12) 11
Pyridinium ion, (12) 86
Pyrimidine, (11) 45
1-(2-pyridylazo)-2-naphthol, (13) 74
Pyrazine, Electrolysis, (14) 86
PXRD, (13) 26
Quaternization, (12) 65
Quantum chemical calculations, (15) 16
Quantum dots, (15) 48
Raman, (11) 98
Reaction rate, (11) 81
Reactive oxygen species, (12) 68, 79, (13) 40; 64
Reduction, (11) 59, (11) 78, (15) 44
Resonance, (12) 33
Resonance energy transfer, RET, (11) 116
Resonance frequency, (14) 90
Resveratrol, (15) 122
Retina, (14) 96
Reversal of Diastereoselectivity, (13) 29
Reverse Micelles, (14) 54
Ring expansion, (11) 49
RNA Triplex, (11) 112
Russet cultivar, (15) 71
Salicin, (12) 72
Salicylhydroxamic acid, (11) 4
Salix, (12) 72
Sanguiin H6, (15) 25
Saturation Transfer Difference NMR
Spectroscopy (STD NMR), (14) 5
SEM, (14) 78
Semicarbazones, (13) 30
Sepals, (13) 8
Septic systems, (13) 55
Sesquiterpene lactones, (15) 63
Silicon, (11) 102, (14) 96
Simulation, (14) 40
Sivvu, (12) 11
Skin cancer, (13) 40
SN2, (12) 65
Sodium borohydride, (11) 78
Solid-phase extraction, (13) 55
Solid state, (11) 78
Solid-state synthesis, (15) 108
Solvent, (11) 81
Solvent Dependence, (13) 29
Solvent effect, (12) 65
Solvent free, (11) 78
Soxhlet, (13) 67
Soybean oil, (11) 30
Spectrophotometric Titration, (12) 11
Spectroscopy; (12) 56
Spectroscopy and Metals, 15(3) 74
Square wave voltmmetry, (12) 36
Stability, (11) 112
Standard quantitative curve, (12) 72
Stems, (11) 1
Stilbene, (15) 122
Stoichiometry, (11) 123
Stryker’s reagent, (11) 81
Substituted Chalcones, (13) 18
Suicide inhibition, (12) 89, 92
Sulfamethoxazole, (11) 27
Sulfur hexafluoride, (14) 90
Surfactants, (11) 54, 102, (12) 28
Surrogate fuel, (14) 50
Synthesis, (12) 75, (15) 40
Synthetic paraffinic kerosene, (14) 50
Tartaric acid, (14) 59
Tattoo Ink, (14) 78
Tellurium, (11) 102
Temperature programmed desorption, TPD, (11)
107, (12) 21, (12) 43, 51, 61, (13) 34, 45,
(14)20; (14) 47, 63, (15) 36, 95, 99, 103
Tetrafluoroethane-1,2-diol, (11) 84
Thermal Difference Spectra, (13) 50
Thermal Denaturation, (11) 112
Thermodynamics, (12) 19
Thermogravimetric Analysis, (11) 4, 11, (12) 7
Thermoreversible, (12) 16
p-Terphenyl (1,4-diphenylbenzene), (15) 103
Thioselenocarbamates, (13) 60
Thiosemicarbazone, (14) 25, (14) 30
Tin, (11) 102
Topoisomerase IIa, (14) 25
Toxicity, (14) 78
TPD, (12) 21, 51, 61, (13) 34, 45; (14) 47, (15)
36
Trace detect, (14) 90
trans-2-aminocyclohexanols, (14) 73
Transferace, (15) 51
Transfer hydrogenation, (11) 59, (15) 44
Transesterification, (12) 83, (14) 17
2HYY, (14) 93
2-methylheptane, (15) 36
2,2-dimethylhexane, (15) 36
2,2,2-trimethylpentane, (15) 36
Two-dimensional NMR, (15) 113
UV Thermal Denaturation, (13) 50
Vaccinium corymbosum L., (11) 24
Van’t Hoff analysis, (11) 15
Vapor deposition, (13) 34
Vegetable Oil, (12) 83
Vertical detachement energies, (15) 6
Vertical electron affinities, (15) 6
VT-NMR, (13) 1
Wang resin, (15) 108
Water, (11) 90, (13) 34
Water solubility, (15) 40
Wilkinson’s catalyst,(11) 59, (15) 44
Willow, (12) 72
Wine, (14) 59
Xanthate, (11) 123
Zinc, (14) 34
Journal of Undergraduate Chemistry Research
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