fluorine-free blue-green emitters for light- emitting ... · s1! fluorine-free blue-green emitters...
TRANSCRIPT
![Page 1: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/1.jpg)
S1
Fluorine-free Blue-green Emitters for Light-
Emitting Electrochemical Cells.
Sloane Evariste,a,b Martina Sandroni,a,c Thomas Rees,d Cristina Roldán-Carmona,e,f Lidon
Gil-Escrig,e Henk Bolink,e*Etienne Baranoff,d* and Eli Zysman-Colmang*
a Département de Chimie, Université de Sherbrooke, 2500 Boul. de l’Université, Sherbrooke, QC, Canada, J1K 2R1 b Sciences Chimiques, UMR 6226 CNRS - Université de Rennes 1, Campus de Beaulieu, Rennes Cedex, France 35042
c Current address CEMCA UMR CNRS 6521, Université de Bretagne Occidentale, 6 av. Victor Le Gorgeu, 29200 Brest, France
d School of Chemistry, University of Birmingham, Edgbaston, B15 2TT Birmingham, UK. [email protected] e Instituto de Ciencia Molecular, Universidad de Valencia, C/ Catedrático J. Beltrán 2, 46980 Paterna (Valencia), Spain. [email protected] f Department of Physical Chemistry and Applied Thermodynamics, Campus Rabanales, Ed. C3, University of Cordoba, 14014, Spain. g EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, UK, KY16 9ST, Fax: +44-‐1334 463808; Tel: +44-‐1334 463826; E-‐mail: eli.zysman-‐colman@st-‐andrews.ac.uk; URL: http://www.zysman-‐colman.com
SUPPORTING INFORMATION
Table of Contents: Pages : 1H and 13C NMR spectra of individual ligands S2-‐S7 1H and 13C NMR spectra of individual dimers S8-‐S9 1H and 13C NMR spectra of individual complexes S10-‐S21 Complete CVs of complexes 1-‐4 S22
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.This journal is © The Royal Society of Chemistry 2014
![Page 2: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/2.jpg)
S2
Figure S1. 1H NMR of L1 in CDCl3.
![Page 3: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/3.jpg)
S3
Figure S2. 13C NMR of L1 in CDCl3.
![Page 4: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/4.jpg)
S4
Figure S3. 1H NMR of L2 in CDCl3.
![Page 5: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/5.jpg)
S5
Figure S4. 13C NMR of L2 in CDCl3.
![Page 6: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/6.jpg)
S6
Figure S5. 1H NMR of L4 in CDCl3.
![Page 7: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/7.jpg)
S7
Figure S6. 13C NMR of L4 in CDCl3.
L4
![Page 8: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/8.jpg)
S8
Figure S7. 1H NMR of D1 in CDCl3.
![Page 9: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/9.jpg)
S9
Figure S8. 1H NMR of D2 in CDCl3.
![Page 10: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/10.jpg)
S10
Figure S9. 1H NMR of Complex 1 in CD3CN.
![Page 11: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/11.jpg)
S11
Figure S10. 1H NMR of Complex 1 (aromatic part) in CD3CN.
![Page 12: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/12.jpg)
S12
Figure S11. 13C NMR of Complex 1 in CD3CN.
![Page 13: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/13.jpg)
S13
Figure S12. 1H NMR of Complex 2 in CD3CN.
![Page 14: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/14.jpg)
S14
Figure S13. 1H NMR of Complex 2 (aromatic part) in CD3CN.
![Page 15: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/15.jpg)
S15
Figure S14. 13C NMR of Complex 2 in CD3CN.
![Page 16: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/16.jpg)
S16
Figure S15. 1H NMR of Complex 3 in CD3CN.
![Page 17: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/17.jpg)
S17
Figure S16. 1H NMR of Complex 3 (aromatic part) in CD3CN.
![Page 18: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/18.jpg)
S18
Figure S17. 13C NMR of Complex 3 in CD3CN.
![Page 19: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/19.jpg)
S19
Figure S18. 1H NMR of Complex 4 in CD3CN.
![Page 20: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/20.jpg)
S20
Figure S19. 1H NMR of Complex 4 (aromatic part) in CD3CN.
![Page 21: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/21.jpg)
S21
Figure S20. 13C NMR of Complex 4 in CD3CN.
![Page 22: Fluorine-free Blue-green Emitters for Light- Emitting ... · S1! Fluorine-free Blue-green Emitters for Light-Emitting Electrochemical Cells. Sloane Evariste,a,b Martina Sandroni,a,c](https://reader033.vdocument.in/reader033/viewer/2022050207/5f59e887997b53034901ea81/html5/thumbnails/22.jpg)
S22
Figure S21. Complete cyclic voltammetries for 1-‐4 recorded in deaerated CH3CN; supporting electrolyte TBAPF6 0.1 M. Working electrode: glassy carbon; counter electrode: Pt wire; reference electrode: SCE. The Fc+/Fc couple was used as an internal standard and the potential was then referred to SCE (E(SCE) = E(Fc+/Fc) + 0.38 V).