for inspection purposes only.appendix iii: certificates and process detail form.....24 opinions and...

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1 1 of 24 Report Title Air Emissions Compliance Monitoring Emissions Report Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin, Park, Ennis Road, Limerick V94 NT63. Stack Emissions Testing Report Commissioned by Zinc Processors Limited Trading As Shannonside Galvanising Facility Name Zinc Processors Limited Trading As Shannonside Galvanising Contact Person Dermot O’ Brien EPA Licence Number P0650-03 Licence Holder Zinc Processors Limited Trading As Shannonside Galvanising Stack Reference Number A1-1 & A1-2 Dates of the Monitoring Campaign 08-08-2018 Job Reference Number SHGATL5080818 Report Written By Mr. Robert O’Brien Report Approved by Mark McGarry Stack Testing Team Mr. Robert O’Brien & Mr. Michéal Ryan Report Date 18-09-2018 Report Type Test Report Compliance Monitoring Version 1 Signature of Approver Operations Manager For inspection purposes only. Consent of copyright owner required for any other use. EPA Export 27-11-2018:03:52:32

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Page 1: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

1 of 24

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Zinc Processors Limited Trading As Shannonside Galvanising

Facility Name Zinc Processors Limited Trading As Shannonside Galvanising

Contact Person Dermot O’ Brien

EPA Licence Number P0650-03

Licence Holder Zinc Processors Limited Trading As Shannonside Galvanising

Stack Reference Number A1-1 & A1-2

Dates of the Monitoring Campaign 08-08-2018

Job Reference Number SHGATL5080818

Report Written By Mr. Robert O’Brien

Report Approved by Mark McGarry

Stack Testing Team Mr. Robert O’Brien & Mr. Michéal Ryan

Report Date 18-09-2018

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver Operations Manager

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EPA Export 27-11-2018:03:52:32

Page 2: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Contents

1.0 Executive Summary ................................................................................................................................................................................ 3 1.1 Overall aim of the monitoring campaign ................................................................................................................................................ 3 1.2 Summary of substances to be monitored at each emission point .......................................................................................................... 3 1.3 Special Requirements ............................................................................................................................................................................. 3 1.4 Summary of Results ................................................................................................................................................................................ 4 Emission Point Number: A1-1 ........................................................................................................................................................................... 4 Emission Point Number: A1-2 ........................................................................................................................................................................... 5 1.5 Operating Information ........................................................................................................................................................................... 6 Please reference Process Details as per Appendix III attached. ........................................................................................................................ 6 1.6 Monitoring Deviations ............................................................................................................................................................................ 6 1.7 Reference Documents ............................................................................................................................................................................ 6 1.8 Revision History ...................................................................................................................................................................................... 6 Part 2: Supporting Information ........................................................................................................................................................................ 7 Appendix I ......................................................................................................................................................................................................... 8 1.1 Monitoring Personnel ............................................................................................................................................................................. 8 1.2 Equipment Inventory .............................................................................................................................................................................. 9 Appendix II ...................................................................................................................................................................................................... 10 2.1 Stack Emission Point Reference: A1-1 .................................................................................................................................................. 10 2.1.1 Suitability of Sample Location: ........................................................................................................................................................ 10 2.1.2 Stack Diagram ................................................................................................................................................................................. 11 2.1.3 Stack Raw Data ............................................................................................................................................................................... 12 2.2 Stack Emission Point Reference: A1-2 .................................................................................................................................................. 19 2.2.1 Suitability of Sample Location: ........................................................................................................................................................ 19 2.2.2 Stack Diagram ................................................................................................................................................................................. 20 2.2.3 Stack Raw Data ............................................................................................................................................................................... 21 Appendix III: Certificates and Process Detail Form .................................................................................................................................... 24

Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.

All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.

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EPA Export 27-11-2018:03:52:32

Page 3: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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1.0 Executive Summary

1.1 Overall aim of the monitoring campaign

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified

in the site licence.

1.2 Summary of substances to be monitored at each emission point

Stack Name: A1-1

Total Particulate Matter

Chloride (as HCl)

Ammonium Chloride

Metals (Lead, Cadmium, Zinc)

Volumetric Flow Rate (Ref)

Stack Name: A1-2

Total Particulate Matter

Total Gaseous Organic Compounds

Volumetric Flow Rate (Ref)

1.3 Special Requirements

There were no special requirements

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EPA Export 27-11-2018:03:52:32

Page 4: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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1.4 Summary of Results

Emission Point Number: A1-1

Parameter Method Units Result MU +/- Limit O2 Ref.

(%)

Moisture

Ref.(%) Compliant Blanks Date Time on Time off

Accreditation

Sampling Analysis

HCL EN 1911 mg.m-3 <0.191 0.009 10 N/a N/a Yes 0.1 08/08/2018 09:45 10:15 Yes Yes

NH4CL EN 14791 mg.m-3 <0.917 0.045 10 N/a N/a Yes 0.2 08/08/2018 09:45 10:15 No No

Lead EN 14385 mg.m-3 <0.06569 0.00231 2 N/a N/a Yes 0.00104 08/08/2018 10:24 10:56 Yes Yes

Cadmium EN 14385 mg.m-3 <0.00126 0.00004 0.01 N/a N/a Yes 0.00118 08/08/2018 10:24 10:56 Yes Yes

Zinc EN 14385 mg.m-3 <4.01578 0.14149 5 N/a N/a Yes 0.04216 08/08/2018 10:24 10:56 No No

Particulate Matter EN 13284-1 mg.m-3 5.41 0.58 5 N/a N/a No 0.61 08/08/2018 11:31 12:10 Yes Yes

Volumetric Flow Rate (Ref) EN 16911 m3.h-1 25,172 1,081 25,500 N/a N/a Yes N/a 08/08/2018 11:31 12:10 Yes N/a

Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)

Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2017.

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EPA Export 27-11-2018:03:52:32

Page 5: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Emission Point Number: A1-2

Parameter Method Units Result MU +/- Limit O2 Ref.

(%)

Moisture

Ref (%) Compliant Blanks Date Time on Time off

Accreditation

Sampling Analysis

Total Organic Compounds EN 12619 mg.m-3 30.8 1.12 150 N/a N/a Yes N/a 08/08/2018 14:40 15:09 No N/a

Particulate Matter EN 13284-1 mg.m-3 1.87 0.71 5 N/a N/a Yes 0.79 08/08/2018 14:55 15:30 Yes Yes

Volumetric Flow Rate (Ref) EN 16911 m3.h-1 13,958 985 18,800 N/a N/a Yes N/a 08/08/2018 14:55 15:30 Yes N/a

Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)

Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2017.

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EPA Export 27-11-2018:03:52:32

Page 6: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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1.5 Operating Information

Please reference Process Details as per Appendix III attached.

1.6 Monitoring Deviations

Stack Name: A1-1

Parameter Deviation

Total Particulate Matter Blank > 10% of ELV due to low ELV.

Hydrogen Chloride (as HCl) None

Metals (Lead, Cadmium, Zinc) None

Ammonium Chloride None

Volumetric Flow Rate (Ref) EN 16911 - in accordance with MID 16911-1

Stack Name: A1-2

Parameter Deviation

Total Particulate Matter Straight length before sample point <5 hydraulic diameters. Straight length after sample point <5 hydraulic diameters. Blank > 10% of ELV due to low ELV.

Total Gaseous Organic Compounds None

Volumetric Flow Rate (Ref) EN 16911 - in accordance with MID 16911-1. Straight length before sample point <5 hydraulic diameters. Straight length after sample point <5 hydraulic diameters

1.7 Reference Documents

Risk Assessment (RA) SOP 1011

Site Review (SR) SOP 1015

Site Specific Protocol (SSP) SOP 1015

1.8 Revision History

Revision Number Changes to the report

1 Original version of the report

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EPA Export 27-11-2018:03:52:32

Page 7: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Part 2: Supporting Information

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Zinc Processors Limited Trading As Shannonside Galvanising

Facility Name Zinc Processors Limited Trading As Shannonside Galvanising

Contact Person Dermot O’ Brien

EPA Licence Number P0650-03

Licence Holder Zinc Processors Limited Trading As Shannonside Galvanising

Stack Reference Number A1-1 & A1-2

Dates of the Monitoring Campaign 08-08-2018

Job Reference Number SHGATL5080818

Report Written By Mr. Robert O’Brien

Report Approved by Mark McGarry

Stack Testing Team Mr. Robert O’Brien & Mr. Michéal Ryan

Report Date 18-09-2018

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver Operations Manager

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EPA Export 27-11-2018:03:52:32

Page 8: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Appendix I

1.1 Monitoring Personnel

Team Leader Name Robbie O Brien

System approval ASL Team Leader Approved

Technician Name Micheal Ryan

System approval ASL Technician Approved

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EPA Export 27-11-2018:03:52:32

Page 9: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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1.2 Equipment Inventory

ID Item of Equipment Used ID Item of Equipment Used ID Item of Equipment Used

ASLLK12EQ500 Pump ASLLK12EQ525 Horiba (PG-250) X ASLLK13EQ501 Vernier Calipers

ASLLK12EQ531 Pump ASLLK14EQ501 Horiba-PG 350 ASLLK14EQ503 Vernier Calipers

ASLLK12EQ532 Pump ASLLK14EQ512 Horiba PG250Y ASLLK14EQ507 Vernier Calipers

ASLLK12EQ533 Pump ASLLK16EQ508 Horiba- PG250z ASLLK17EQ533 Vernier Calipers

ASLLK12EQ534 Pump ASLLK17EQ515 Horiba 350 ASLLK18EQ506 Vernier Calipers

ASLLK12EQ535 Pump

ASLLK12EQ536 Pump

ASLLK12EQ537 Pump ASLLK12EQ526 Chiller ASLLK13EQ503 1kg weight

ASLLK12EQ538 Pump ASLLK14EQ513 Chiller ASLLK13EQ508 500g Hafner weight

ASLLK12EQ539 Pump ASLLK16EQ509 Chiller ASLLK13EQ509 500g Hafner weight

ASLLK12EQ540 Pump ASLLK18EQ505 Chiller ASLLK15EQ512 1kg weight

ASLLK12EQ541 Pump ASLLK16EQ511 1kg weight

ASLLK12EQ542 Pump ASLLK16EQ512 500g weight

ASLLK12EQ543 Pump ASLLK14EQ518 Velocity Meter ASLLK17EQ529 500g weight

ASLLK13EQ513 Pump ASLLK16EQ501 Velocity Meter ASLLK17EQ530 1kg weight

ASLLK13EQ514 Pump ASLLK17EQ508 Velocity Meter

ASLLK16EQ518 Pump ASLLK17EQ514 Velocity Meter

ASLLK16EQ519 Pump ASLLK18EQ504 Velocity Meter ASLLK13EQ504 G4

ASLLK17EQ509 Pump ASLLK13EQ515 G4

ASLLK17EQ510 Pump ASLLK15EQ501 G4

ASLLK17EQ525 Pump ASLLK14EQ500 FID ASLLK17EQ534 ST5

ASLLK17EQ526 Pump ASLLK16EQ502 FID ASLLK18EQ503 ST5

ASLLK17EQ522 Pump ASLLK17EQ517 FID

ASLLK17EQ523 Pump ASLLK17EQ535 Signal Cutter

ASLLK17EQ524 Pump ASLLK14EQ510 Digital Protractor

ASLLK14EQ511 Digital Protractor

ASLLK13EQ512 PCDD thermometer ASLLK15EQ505 Digital Protractor

ASLLK12EQ529 Calibrator ASLLK16EQ507 Digital Protractor

ASLLK14EQ502 Calibrator ASLLK17EQ528 Digital Protractor

ASLLK17EQ532 MF Meter ASLLK16EQ510 Measuring Tape ASLLK18EQ507 Digital Protractor

ASLLK17EQ540 MF Meter ASLLK16EQ513 Measuring Tape

ASLLK17EQ541 MF Meter ASLLK16EQ514 Measuring Tape

ASLLK17EQ542 MF Meter ASLLK17EQ527 Measuring tape ASLLK12EQ522 Balance

ASLLK18EQ508 Measuring tape ASLLK12EQ544 Balance

ASLLK15EQ509 Balance

ASLLK12EQ507 Heated Line ASLLK15EQ510 Balance

ASLLK12EQ527 Heated Line ASLLK16EQ515 Thermocouple K type ASLLK17EQ537 Balance

ASLLK14EQ509 Heated Line ASLLK16EQ516 Thermocouple K type ASLLK17EQ538 Balance

ASLLK14EQ514 Heated Line ASLLK17EQ531 K type Thermocouple

ASLLK17EQ502 Heated Line ASLLK18EQ500 K type Thermocouple

ASLLK17EQ503 Heated Line ASLLK18EQ501 K type Thermocouple

ASLLK17EQ539 Heated Line ASLLK18EQ502 K type Thermocouple

ASLLK12EQ518 S type Pitot Tube ASLLK17EQ518 Stopwatch

ASLLK12EQ520 L Type Pitot tube ASLLK17EQ519 Stopwatch

ASLLK13EQ506 S type Pitot Tube ASLLK17EQ520 Stopwatch

ASLLK14EQ506 Pitot + thermocouple ASLLK17EQ521 Stopwatch

ASLLK16EQ506 S type Pitot Tube ASLLK18EQ509 Stopwatch

ASLLK16EQ517 S type Pitot Tube

ASLLK17EQ536 S type Pitot

ASLLK17EQ507 1 m S type & K type

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Page 10: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Appendix II

2.1 Stack Emission Point Reference: A1-1

2.1.1 Suitability of Sample Location:

General Information A1-1

Permanent/Temporary Permanent

Inside/ Outside Outside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring instruments

Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -

Platform has vertical base boards (approx. 0.25 m high) Yes -

Platform has chains / self-closing gates at top of ladders Yes -

There are no obstructions present which hamper insertion of sampling equipment

Yes -

Safe Access Available Yes -

Easy Access Available Yes -

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1

Select Option: 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement

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Page 11: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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2.1.2 Stack Diagram

Figure 1: A1-1

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Page 12: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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2.1.3 Stack Raw Data

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Page 13: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Title: Determination of Metals

Method: EN 14385

Client: Shannonside

Test Date: 08/08/2018 Temperature at Pump 22.7 Deg C

Test Time On: 10:24:15 Pressure at Pump 86.714 kPa

Test Time Off: 10:55 Air Volume at Pump 0.7571 m3

Laboratory Used: CLS Humidity at Pumps 0 %

Stack Name A1-1

Filter I.D. Y-362 Flow Uncertainty 1124 m3/hr

Stack Flow Rate 26178 m3.hr-1 Flow Uncertainty 4 %

Dry Volume of Air Sampled Metals 0.5989 Nm3

Dry Volume of Air Sampled Mercury

Moisture Content 0.00 %

Wet Volume of Air Sampled Metals 0.5989 m3

Wet Volume of Air Sampled Mercury 0 m3

Emission Limit Value 5 mg.m-3

Leak Check Results Result % Leak

Before Blank 0.09 cc/min 0.4

After Blank 0.09 cc/min 0.4

Before Sample 1 0.09 cc/min 0.4

After Sample 1 0.09 cc/min 0.4

Average Flow Rate 21 cc/min 0.4

Standard Maximum 0.42 cc/min 2%

Back Pressure 69 bar or kPa

Standard Criteria to be Met Result Standard Requirement

Angle of Flow Pass <15 Degrees Probe material Titanium

Negative Flow in the Stack Pass None Filter housing Titanium

Pitot Pressure Difference Pass >5Pa Positioning of filter Out Stack

Ratio of Flow Measurement Pass <3:1 Filter Size & Material 47mm Quartz

Stagnation Check Pass <10 Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point Pass > 5 Hydraulic Diameters

Straight length after sample point Pass > 5 HD from fan or bend / >2 from stack exit

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Page 14: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Sample Calculations

Filter Imp 1 & 2 Imp 3 Total Metal

ug / filter ug/L ug/L ug

Cadmium 0.5 0.5 0.5 0.8

Lead 38 3.2 0.3 39.3

Zinc 2300 250 25 2405.1

Run 1

Impinger 1 & 2 Total Volume (Incl Rinse) 410 mls

Impinger 3 Total Volume (Incl Rinse) 102 mls

Concentration Calculation

mg.m-3 Uncertainty

Cadmium 0.00126 0.000044

Lead 0.06569 0.002314

Zinc 4.01578 0.141485

Total Metals 4.08273 0.143844

Total Cd 0.00126 0.000044

Remaining Metals 4.08147 0.143800

Blank Calculations

Filter Impingers Total Metals Concentration

ug / filter ug/L ug mg.m-3

Cadmium 0.5 0.5 0.705 0.00118

Lead 0.5 0.3 0.623 0.00104

Zinc 15 25 25.250 0.04216

% of ELV

Total Metals 0.0444 0.8876

Blank < 10% of the Emission Limit Values Yes Yes / No

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Page 15: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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PITOT DATA SPECIFICATION

Name p0.83

Velocity [m/sec] 5 0.83

Velocity [m/sec] 10 0.83

Velocity [m/sec] 20 0.83

Velocity [m/sec] 30 0.83

Velocity [m/sec] 40 0.83

DUCT AND GAS SPECIFICATION

Name SHAN A1-1

Section Circular

Diameter [m] 0.74

Area [m2] 0.43

Port B [#] 2

Points P [#] 4

Density ρn [kg/m3] 1.286

Carbon dioxide CO2 [%] 0

Oxygen O2 [%] 20.9

Water vapor ratio rw [0;1] 0.01

Nozzle nz [mm] 5

Turbolence factor ft [sec] 9

DUCT FLOW RATE

Dry actual QVa [m3/h] 29743

Moist actual Q'Va [m3/h] 30044

Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 26178

Dry standard [Tnorm Pnorm] QVn [m3/h] 25916

AVERAGE VALUES

Total Points [#] 2

Velocity v'a [m/sec] 19.405

Stack temperature ta [°C] 37.794

Stack Static Pressure Pastatic [kPa] 100.459

Isokinetic Deviation DI [%] 1

Velocity at nozzle v'N [m/sec] 19.614

Probe temperature tprobe [°C] 124.255

Box temperature tbox [°C] 115.566

Stack Differential Pitot Pressure dPpitot [Pa] 326.544

Ambient Pressure Pamb [kPa] 100.29

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Page 16: For inspection purposes only.Appendix III: Certificates and Process Detail Form.....24 Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited

Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Title: Determination of Total Particulates

Method: EN 13284-1

Client: Shannonside Test Date: 08/08/2018 Temperature at Pump 20.611 Deg C

Test Time 11:31 Pressure at Pump 86.489 kPa

Laboratory Used: CLS Air Volume at Pump 0.7215 m3

Stack Name A1-1 Humidity at Pumps 0 %

Run I.D. 2 Filter Weight 2.8 mg

Filter I.D. 8-131 Front End Weight 0.3 mg

Moisture Content 0.00 % Stack Flow Rate 25172 Nm3/hr Flow Uncertainty 1081 m3/hr

Volume of Air Sampled 0.573 Nm3 Flow Uncertainty 4.3 %

Leak Check Results Result % Leak

Before Blank 0.19 l/min 0.9

After Blank 0.19 l/min 0.9

Before Sample 1 0 l/min 0.0

After Sample 1 0 l/min 0.0

Average Flow Rate 21 l/min 0.9

Standard Maximum 0.42 l/min 2%

Back Pressure 69 kPa

Standard Criteria to be Met Result Std. Requirement

Angle of Flow Pass <15 Degrees Probe material Stainless Steel

Negative Flow in the Stack Pass None Filter housing Stainless Steel

Pitot Pressure Difference Pass >5Pa Positioning of filter In Stack

Ratio of Flow Measurement Pass <3:1 Filter Size & Material 47mm Quartz

Stagnation Test Pass <10Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point Pass > 5 Hydraulic Diameters

Straight length after sample point Pass > 5 Hydraulic Diameters/ >2 from Bend

Sample Calculations

Blank (Filter and Front Wash Combined) 0.35 mg

Sample 1 (Filter and Front Combined) 3.1 mg

Volume of Air Sampled 0.573 Nm3

Blank Result 0.61 mg/Nm3

Sample Result 5.41 mg/Nm3

Uncertainty of Measurement 0.58 mg/Nm3

Emission Limit Value 5 mg/Nm3 Blank as Percentage of ELV 12.2 % Standard Requirement <10% ELV

Isokinetic Criterion Compliance

Isokinetic Variation 0.5 %

Allowable Isokinetic Range I -5 to + 15% %

Isokinetic Acceptable Yes -

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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PITOT DATA SPECIFICATION

Name p0.83

Velocity [m/sec] 5 0.83

Velocity [m/sec] 10 0.83

Velocity [m/sec] 20 0.83

Velocity [m/sec] 30 0.83

Velocity [m/sec] 40 0.83

DUCT AND GAS SPECIFICATION

Name SHAN A1-1

Section Circular

Diameter [m] 0.74

Area [m2] 0.43

Port B [#] 2

Points P [#] 4

Density ρn [kg/m3] 1.286

Carbon dioxide CO2 [%] 0

Oxygen O2 [%] 20.9

Water vapor ratio rw [0;1] 0.01

Nozzle nz [mm] 5

Turbolence factor ft [sec] 9

DUCT FLOW RATE

Dry actual QVa [m3/h] 27494

Moist actual Q'Va [m3/h] 27772

Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 25172

Dry standard [Tnorm Pnorm] QVn [m3/h] 24920

AVERAGE VALUES

Total Points [#] 2

Velocity v'a [m/sec] 17.937

Stack temperature ta [°C] 25.895

Stack Static Pressure Pastatic [kPa] 100.474

Isokinetic Deviation DI [%] 0.5

Velocity at nozzle v'N [m/sec] 18.039

Probe temperature tprobe [°C] 124.379

Box temperature tbox [°C] 89.513

Stack Differential Pitot Pressure dPpitot [Pa] 282.834

Ambient Pressure Pamb [kPa] 100.29

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Title: Determination of Inorganic Compounds

Method: EN1911 EN14791

Test Date: 07/08/2018

Test Time Started: 09:45 09:45

Test Time Finished: 10:15 10:15

Laboratory Used: CLS

Stack Reference: A1-1

Leak Check Results HCL NH4CL

Prior to test: 0 0 l/min

Post Test: 0 0 l/min

Sample Volume Flow Rate: 2.09 2.09 l/min

Standard Requirement: <2 <2 %

Test Result: 0.0 0.0 %

Test Status Pass / Fail Pass / Fail

Reference Details

Stack Moisture Content 0 %

Calibration Details HCL NH4CL

Pump Number: ASLLK17EQ525 ASLLK17EQ524

Calibration Unit: ASLLK17EQ542 ASLLK17EQ542

Calibration Rate Before Test: 2.1 2.1 l/min

Calibration Rate After Test: 2.1 2.1 l/min

Average sample Volume: 2.1 2.1 l/min

Sample Test Time: 30 30 minutes

Pump Gas Temperature: 21 21 OC

Pump Sample Pressure: 101.3 101.3 kPa

Actual Sample Volume: 0.063 0.063 m3

Normalised Gas Volume: 0.058 0.058 Nm3

Normalised Wet Gas Volume: 0.058 0.058 Nm3

Sample Details HCL NH4CL

Impinger Solution DI Water 0.1N H2SO4

Solution ID Number: Run 1 Run 1

Blank Identification Number: Run 1 Run 1

Impinger Material PTFE PTFE

Breakthrough Occurred No No

Transport Temp meets Standard Yes Yes

Analysed Within Specified Timeframe Yes Yes

Transport Container Airtight Yes Yes

Exposed to Sunlight No No

Calculations HCL NH4CL

Laboratory Result Imp 1 / 2 0.06 0.4 ug/ml

Laboratory Result Imp Final 0.05 0.1 ug/ml

Impinger Final Volume Imp 1 / 2 122 115 ml

Impinger Final Volume Imp Final 70 74 ml

Combined Concentration 0.0 0.1 mg

Factor 1.028 1

Concentration 0.0 0.1 mg

Air Sample Volume 0.058 0.058 Nm3

Emissions Concentration 0.191 0.917 mg.m-3

Uncertainty 0.009 0.045 mg.m-3

Licence Limits 10 10 mg.m-3

Blank Calculation HCL NH4CL

Laboratory Impinger / Rinse Result 0.05 0.1 ug/ml

Factor 1.028 1 -

Blank Concentration 0.1 0.2 mg.m-3

% of Licence Limit 1.1 2.0 %

Field Blank <10% ELV Yes Yes mg.m-3

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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2.2 Stack Emission Point Reference: A1-2

2.2.1 Suitability of Sample Location:

General Information A1-2

Permanent/Temporary Permanent

Inside/ Outside Outside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring instruments

Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -

Platform has vertical base boards (approx. 0.25 m high) Yes -

Platform has chains / self-closing gates at top of ladders Yes -

There are no obstructions present which hamper insertion of sampling equipment

Yes -

Safe Access Available Yes -

Easy Access Available Yes -

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1.

Select Option: 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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2.2.2 Stack Diagram

Figure 2: A1-2

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2.2.3 Stack Raw Data

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Title: Determination of Total Particulates

Method: EN 13284-1

Client: Shannonside Test Date: 08/08/2018 Temperature at Pump 16.889 Deg C

Test Time 14:55 Pressure at Pump 91.796 kPa

Laboratory Used: CLS Air Volume at Pump 0.5188 m3

Stack Name A1-2 Humidity at Pumps 0 %

Run I.D. 1 Filter Weight 0.53 mg

Filter I.D. 8-122 Front End Weight 0.3 mg

Moisture Content 0.00 % Stack Flow Rate 13958 Nm3/hr Flow Uncertainty 985 m3/hr

Volume of Air Sampled 0.4428 Nm3 Flow Uncertainty 7.1 %

Leak Check Results Result % Leak

Before Blank 0 l/min 0.0

After Blank 0 l/min 0.0

Before Sample 1 0 l/min 0.0

After Sample 1 0 l/min 0.0

Average Flow Rate 14.765 l/min 0.0

Standard Maximum 0.2953 l/min 2%

Back Pressure 69 kPa

Standard Criteria to be Met Result Std. Requirement

Angle of Flow Pass <15 Degrees Probe material Stainless Steel

Negative Flow in the Stack Pass None Filter housing Stainless Steel

Pitot Pressure Difference Pass >5Pa Positioning of filter In Stack

Ratio of Flow Measurement Pass <3:1 Filter Size & Material 47mm Quartz

Stagnation Test Pass <10Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point No > 5 Hydraulic Diameters

Straight length after sample point No > 5 Hydraulic Diameters/ >2 from Bend

Sample Calculations

Blank (Filter and Front Wash Combined) 0.35 mg

Sample 1 (Filter and Front Combined) 0.83 mg

Volume of Air Sampled 0.4428 Nm3

Blank Result 0.79 mg/Nm3

Sample Result 1.87 mg/Nm3

Uncertainty of Measurement 0.71 mg/Nm3

Emission Limit Value 5 mg/Nm3 Blank as Percentage of ELV 15.8 % Standard Requirement <10% ELV

Isokinetic Criterion Compliance

Isokinetic Variation 1.7 %

Allowable Isokinetic Range I -5 to + 15% %

Isokinetic Acceptable Yes -

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Name p0.83

Velocity [m/sec] 5 0.83

Velocity [m/sec] 10 0.83

Velocity [m/sec] 20 0.83

Velocity [m/sec] 30 0.83

Velocity [m/sec] 40 0.83

DUCT AND GAS SPECIFICATION

Name SHAN A1-2

Section Rectangular

Size [m]x[m] 0.700 x 1.140

Area [m2] 0.797

Port B [#] 2

Points P [#] 4

Density ρn [kg/m3] 1.286

Carbon dioxide CO2 [%] 0

Oxygen O2 [%] 20.9

Water vapor ratio rw [0;1] 0.01

Nozzle nz [mm] 8

Turbolence factor ft [sec] 9

DUCT FLOW RATE

Dry actual QVa [m3/h] 14942

Moist actual Q'Va [m3/h] 15093

Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 13958

Dry standard [Tnorm Pnorm] QVn [m3/h] 13818

AVERAGE VALUES

Total Points [#] 2

Velocity v'a [m/sec] 5.254

Stack temperature ta [°C] 19.99

Stack Static Pressure Pastatic [kPa] 100.551

Isokinetic Deviation DI [%] 1.7

Velocity at nozzle v'N [m/sec] 5.346

Probe temperature tprobe [°C] 19.27

Box temperature tbox [°C] 19.547

Stack Differential Pitot Pressure dPpitot [Pa] 24.898

Ambient Pressure Pamb [kPa] 100.574

SAMPLED VOLUMES

Elapsed time et [hh:mm:ss] 00:30:00

Total encoder impulses [#] 43236

Standard Volume [Tnorm Pnorm] Vgn [m3] 0.4428

Moist Volume at stack conditions V'ga [m3] 0.4824

Volume at dgm conditions Vdgm [m3] 0.5188

Gas meter temperature tgm [°C] 16.889

Gas Meter Pressure Pdgm [kPa] 91.796

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Document No: SHGATL5080818 Licence Number: P0650-03 Visit No: 3 Licence Holder: Zinc Processors Ltd. Year: 2018 Facility Location: Drombana, Co.Limerick Office: Limerick Version No: 1

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Appendix III: Certificates and Process Detail Form

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