fuel reduction/epa reduction - shipserv cost... · fuel reduction/epa reduction ... 20 year history...

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401 E. Sonterra Blvd-San Antonio Texas USA 78205 Tel: +1 281-271-8500 Email: [email protected] Web: http://www.eurogearinc.com Date: May 11, 2015 Purchasing Dept Reference: SHIPSERV APPROVED VENDOR #235927 FUEL REDUCTION/EPA REDUCTION I hope you are doing well since my last email I sent to you. I took the liberty today to introduce our product and calculate the cost effective savings, benefits and solutions for your fleet of Vessels. Our product EG XTF fuel catalyst is manufactured here in the United States and has 20+ years of positive success with the Marine industry. I have attached a complete on site analysis (Carbon Mass Balance) Report for you to review and see our product findings from one of our clients PT Indo Mega Maritim. The EG XTF reduced their emissions by over 30% and Fuel Savings of over 7%. Based on an annual consumption/ vessel of 1,000,000 Gallons @ average $2.50/gallon our product will save your company an estimated $175,000/vessel per year . Our product does NOT change or alter the fuel properties or characteristics. Our product is OEM certified and safe for all applications. We can provide you with 1 barrel (55Gallons), which will treat 500,000 gallons. I hope you find our report to your satisfaction as a base line for your operations. We have many more technical documents to share with you for further research. I am here for any questions you may have so please call or email me your fuel consumptions and it will be our pleasure to prepare you a cost savings analysis. Thank you Sincerely, Gregory Gohrt, Euro Gear USA Petroleum +1-514-502-3126 [email protected]

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Page 1: FUEL REDUCTION/EPA REDUCTION - Shipserv Cost... · FUEL REDUCTION/EPA REDUCTION ... 20 year history XFT has never harmed a single engine and we are perfectly confident that it never

401 E. Sonterra Blvd-San Antonio Texas USA 78205

Tel: +1 281-271-8500 Email: [email protected] Web: http://www.eurogearinc.com

Date: May 11, 2015

Purchasing Dept Reference: SHIPSERV APPROVED VENDOR #235927 FUEL REDUCTION/EPA REDUCTION

I hope you are doing well since my last email I sent to you. I took the liberty today to introduce our product and calculate

the cost effective savings, benefits and solutions for your fleet of Vessels. Our product EG XTF fuel catalyst is manufactured

here in the United States and has 20+ years of positive success with the Marine industry. I have attached a complete on site

analysis (Carbon Mass Balance) Report for you to review and see our product findings from one of our clients PT Indo

Mega Maritim. The EG XTF reduced their emissions by over 30% and Fuel Savings of over 7%. Based on an annual

consumption/ vessel of 1,000,000 Gallons @ average $2.50/gallon our product will save your company an estimated

$175,000/vessel per year . Our product does NOT change or alter the fuel properties or characteristics. Our product is

OEM certified and safe for all applications. We can provide you with 1 barrel (55Gallons), which will treat 500,000 gallons.

I hope you find our report to your satisfaction as a base line for your operations. We have

many more technical documents to share with you for further research. I am here for any questions you may have so please

call or email me your fuel consumptions and it will be our pleasure to prepare you a cost savings analysis. Thank you

Sincerely,

Gregory Gohrt,

Euro Gear USA Petroleum

+1-514-502-3126

[email protected]

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401 E.Sonterra Blvd, San Antonio Texas, USA 78258 Tel: +1-281-271-8500 Email: [email protected] Whom it May Concern,

Many times we get asked the question “Is Xtreme Fuel Treatment safe for my engine?” or “Will XFT damage my engine like some other fuel additives will?”

The answer is this: XFT is perfectly safe for all engines, petrol (gasoline) and diesel. In its 20 year history XFT has never harmed a single engine and we are perfectly confident that it never will.

Here are some reasons that we know this to be a fact:

XFT has over 4 Billion Kilometres (2.5 Billion Miles) of operation.

XFT has over 65 Million hours of successful run time in engines.

In over 20 years there has never been a claim against XFT

Syntek Global does have a large insurance policy, but has never had to use it.

The Magnuson-Moss Act (passed by the United States Congress) says that using a fuel treatment like XFT cannot affect your engineʼs warranty. Why? Because they know it will not harm your engine!

We do not change the fuel specifications so there are no warranty issues involved. This was proven through testing by the ASTM.

There have been hundreds of tests and studies done by independent laboratories, universities, and others. All were able to document the positive benefits, and none found any negative effects.

We hope this will serve as sufficient evidence that this productis extremely safe and also very effective. We are confident in ourproduct enough to put a money back guarantee on it as well.

XFT. Trusted because it works.

Sincerely,

John Winterholler

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Syntek Fuel Catalyst Evaluation For

Fuel Efficiency and Emissions Reductions With

PT. INDO MEGA MARITIM Utilizing

The Carbon Mass Balance Test Procedure

Performed and Compiled by:

Green Planet Emissions Consultants, LLC Member: SAE, TMC and A&WMA

July 2012

For:

Pt. Indo Mega Maritim and Syntek Global, Inc.

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C O N T E N T S Preface – Certification Page 3 Executive Summary Page 4-7 Introduction Page 7-8

AFR and Lambda Data Page 8 Test Method Page 8-16 Instrumentation Page 16 Test Results Page 16-17 Conclusion Page 17-18

Appendices Appendix I Engine Visual Inspection; Carbon Appendix II Exhaust Particulate and Fuel Graphs

Appendix III Carbon Mass Balance Compilation Sheets Appendix IV Raw Field Data Sheets Appendix V Carbon Footprint Data

Appendix VI Emissions Averages for Carbon Mass Balance Evaluation Appendix VII Carbon Mass Balance Base Equation

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EXECUTIVE SUMMARY The Syntek fuel borne catalyst manufactured and marketed by Syntek Global, Inc., is a fuel borne catalyst wherein the primary active ingredient is a soluble organo-metallic chemistry that helps to reduce ignition delay by improving combustion chamber mixing through improved molecular dispersion. The catalyst’s proprietary organo-metallic compound with the formula Fe(C5H5)2 is the prototypical metallocene, a type of organo-metallic chemical compound consisting of two cyclopentadienyl rings bound on opposite sides of a central soluble metal atom. Such organo-metallic compounds are also known as sandwich compounds. The rapid growth of organo-metallic chemistry is often attributed to the novelty arising from the discovery of the soluble metal crystalline structure and its many analogues. The proprietary organo-metallic derivative has many niche uses that exploit the unusual structure (ligand scaffolds, pharmaceutical candidates), robustness (anti-knock formulations, precursors to materials), and redox (reagents and redox standards). Such organo-metallic components and its derivatives are anti-knock agents used in the fuel for gasoline and diesel engines; they are safer than tetraethyl lead, previously used. Following discussions with Nick Caswell and Brian Caswell, Syntek representatives; Budhi Halim, MBA, MEng, FIMarEST, President and Director; Jovan Patriot, ST, MSc., Finance and Biz Developmen; and Denny Patriot, S.T., Assistant Fleet manager with PT. Indo Mega Maritim, it was determined that a fuel consumption analysis should be conducted utilizing a fuel tanker supply ship. The designated ship included in this study is the MT Patriot Ceria, which is a 7,000 ton fuel oil cargo ship equipped to deliver various fuel types to shallow port sites throughout the Indonesian islands. The MT Patriot Ceria utilizes Volvo engines for both vessel power and on board power generation. For the purpose of this evaluation, the port side generator, a Volvo TAMD123A engine, was evaluated using the Carbon Mass Balance fuel consumption analysis. To further document the carbon scavenging effects of the Syntek fuel catalyst, the no. 6 head was removed for both baseline and treated segments of the evaluation to quantitatively identify established carbon deposits with and without the Syntek fuel catalyst.

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Before further discussion, all Syntek fuel catalyst representatives would like to thank the crew of the MT Patriot Ceria without whose support this effort could not have been conducted and completed so professionally and responsibly. Their dedication and commitment provided flawless adherence to every detail of the required procedure so as to further the accuracy and viability of this evaluation.

An integral part of this evaluation is determining the Syntek fuel catalyst’s effect on marine application vessels fuelled with a no. 2 rated fuel oil. This vessel and its Volvo engines were of specific interest due to its location and primary use and mandatory load requirements relative to oceanic current and weather demands.

In particular, the purpose for this evaluation was to determine the effects of the Syntek fuel catalyst on particulate emissions, as well as unburned hydrocarbons, carbon monoxide, carbon dioxide and oxides of nitrogen. Further, this fuel

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consumption evaluation was conducted in an attempt to compare fuel consumed for a baseline (untreated) operational segment to the fuel consumed during the treated (Syntek fuel catalyst) operational segment of the evaluation. The method utilized to determine fuel consumption is the Carbon Mass Balance test procedure which will hereafter be referred to as the CMB. It is previously discussed in the Preface section of this document. As important, concurrent studies performed to determine the effectiveness of Syntek fuel catalyst in the reduction of carbon buildup on internal engine components, visual soot (smoke) levels and various other pertinent areas of operation are described in this report. It is understood that reductions in harmful carbon buildup will demonstrate the relationship between carbon accumulation and catalytic oxidations, which will dramatically reduce the carbon development and component adherence in the combustion chamber. This document will summarize the decisions outlined as part of the evaluation paradigm utilized to assess the effectiveness of the Syntek fuel catalyst in the daily operation of marine vessel engines. This document will also outline the necessary steps utilized to initiate and conduct the baseline and treated segments of the fuel catalyst test.

A baseline test was conducted after which the test engine’s fuel source was treated by introducing the fuel catalyst, at a ratio of 1:5000, from 209 litre drums containing the Syntek fuel catalyst into the test engine’s bulk fuel storage tank. At a later date, the catalyst treated fuel test was then repeated following the same parameters. The results are contained within the body of this report.

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A baseline test (untreated) was conducted on February 22, 2012 using the CMB test procedure. The Syntek fuel catalyst did not arrive in Indonesia until shortly after the baseline test was performed. The catalyst was held at the dock until such time as the MT Patriot Ceria returned to dock, wherein the catalyst was loaded onto the ship. Actual Syntek fuel catalyst treatment began on March 27, 2012. The catalyst treated segment of the treated phase of the evaluation took place on July 11, 2012 wherein the same process was then repeated (Syntek fuel catalyst treated) following the same parameters. The results are contained within this report. The data showed that the improvement in fuel consumption was 7.0%, during steady state testing, using the CMB test procedure. The treated engine also demonstrated a large percentage reduction in soot particulates, in the range of 31%, and reductions in harmful exhaust related carbon fractions. Carbon dioxide reductions, based upon the measured reduction in fuel consumption, are also substantial. Other quantitative improvements coinciding with the implementation of the catalyst are discussed in further detail in the “Conclusion” section of this report.

INTRODUCTION Baseline (untreated) fuel efficiency tests were conducted on the selected test vessel on February 22, 2012, employing the CMB test procedure. Syntek Global supplied the Syntek fuel catalyst in 209 litre drums wherein the fuel catalyst was utilized to dose/treat the fuel storage tank for the generator set (port side) utilized throughout the course of this evaluation at a treatment ratio of 1:5,000. The test unit was then operated on Syntek fuel catalyst treated fuel for nearly 1,600 hours in order to achieve the complete conditioning period, which is

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documented in many laboratory and field studies as a requirement for effective catalytic oxidation stabilization. Tests conducted provide critical documentation, which proves that equipment operated with less than sufficient operating hours with the catalyst demonstrate lower fuel consumption improvements because of the catalytic stabilization effects that take place while using the Syntek fuel combustion catalyst. The Syntek fuel catalyst treated test procedure was performed on July 11, 2012, wherein the engine tests were repeated, reproducing all engine parameters. The final results, along with the data sheets, are contained within this report.

AFR and Lambda Readings The MEXA series Horiba analyzers can simultaneously measure air/fuel ratio (AFR) and the excess air ratio (Lambda). The output readings of a Horiba Lambda tester directly coorelate with what is considered to be traditional AFR readings. In practice, a reading of around 1 (one), in airomtic fuels, equals overall stoichiometry. <1 is considered an exhaust rich environment, while >1 is considered an exhaust lean environement. Mathematically, when Lambda is multiplied by the known stoichiometric AFR of the fuel being used, absolute AFR is quantified. However, it is not possible to determine the stochiometric air fuel ratio without knowing the absolute fuel composition. Without knowing absolute fuel composition, AFR and Lambda trends can be monitored as long as the fuel being evaluated is consistent in all segments of the monitoring process. The AFR and Lambda readings observed during the emissions collection process on the MT Patriot Ceria clearly identified an exhaust “leaning“ environment. Baseline AFR and Lambda readings denoted exhaust stoichiometry in the range .60 to .70. Comparatively, the catalyst treated segment of the evaluation identified AFR and Lambda readings in the range of .70 to .75. The data clearly denotes a trend in exhaust emissions identifying a more lean post combustion environment.

TEST METHOD

CMB is a procedure whereby the mass of carbon in the exhaust is calculated as a measure of the fuel being burned. The First Law of Thermodynamics clearly states that “energy can neither be created nor destroyed. In any process, the total energy of the universe remains the same (Laws of Thermodynamics).” Energy can only change form. The fundamental basis for the CMB test procedure is to measure the form of energy (carbon) as it exits in the exhaust stream. Since the amount of energy lost in a steady state process cannot be greater than the amount of energy gained, measured exhaust carbon can only be reduced if the volume of fuel to the engine is reduced. If the volume of fuel is reduced to the engine to produce the same load, then the net increase is only a result of heat gained through improved combustion. The “Law of Conservation of

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Energy has become the most secure of all basic laws of science; at present, it is unquestioned (Laws of Thermodynamics).”

The elements measured in this test include the exhaust gas composition, its temperature and the gas flow rate calculated from the differential pressure and exhaust stack cross sectional area. The CMB is central to the both US-EPA (FTP and HFET) and Australian engineering standard tests (AS2077-1982).

However, in the case of a stationary generator set, load displacement is equal to the accuracy and repeatability of a dynamometer. As such, this type of test engine can be effectively loaded to demonstrate fuel consumption trends and potential. The CMB formula and equations employed in calculating the carbon flow are supplied, in part, by doctors’ of Combustion Engineering at the university and scientific research facility level. The CMB test procedure follows a prescribed regimen, wherein every possible detail of engine operation is monitored to insure the accuracy of the test procedure. Cursory to performing the test, it is imperative to understand the quality of fuel utilized in the evaluation. As important, the quality of fuel must be consistent throughout the entirety of the process.

Fuel density and temperature tests are performed for both the baseline and treated segments of the evaluation to determine the energy content of the fuel. A .810- .910 Precision Hydrometer, columnar flask and fuel temperature tester were utilized to determine the fuel density for each prescribed segment of the evaluation. Next, and essential to the CMB test procedure, is test equipment that is mechanically sound and free from defect. Careful consideration and equipment screening is utilized to verify the mechanical stability of each piece of test equipment. Preliminary data is scrutinized to disqualify all equipment that may

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be mechanically suspect. Once the equipment selection process is complete, the CMB test procedure takes only a few short minutes to perform (pending required data collection requirements). Once the standards are met and the decision is made to test a certain piece of equipment, pertinent engine criteria needs to be evaluated as the CMB procedure continues.

When the selection process is complete, engine RPM is increased and locked in position. This allows the engine fluids, block temperature, and exhaust stream gasses to stabilize. Data cannot be collected when there is irregular fluctuation in engine RPM and exhaust constituent levels. Therefore, all engine operating conditions must be stable and consistent.

In many cases, an aftermarket throttle position lock, a factory installed throttle lock and/or a cruise control unit are utilized, as a few methods to secure engine RPM. However, this application relies on governor controlled generator speed to affix RPM, wherein load to the desired application was set at 50 kw and 105 to 110 amps. Should the engine RPM fluctuate erratically and uncontrollably, the test unit would be disqualified from further consideration.

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Next, engine RPM and fluid temperatures are monitored throughout the CMB evaluation. As important, exhaust manifold temperatures are monitored to insure that engine combustion is consistent in all cylinders. It is imperative that the engine achieve normal operating conditions with no mechanical mishaps before any testing begins. The Volvo engine tested on this vessel exhibited similar exhaust readings, from cylinder to cylinder, during both fuel consumption test segments. Such conditions identify an efficient test engine for the CMB.

Once engine fluid levels have reached normal operating conditions the CMB study may begin. The above photograph shows that all necessary and pertinent equipment is being properly and securely positioned preparatory to performing the CMB test. It should be noted that any deviation in RPM or temperature (either fluid or exhaust), would cause this unit to be eliminated from the evaluation due to mechanical inconsistencies.

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Once all of the mechanical criteria are met, data acquisition can commence. It is necessary to monitor the temperature and pressure of the exhaust stream. CMB data cannot be collected until such time as the engine exhaust temperature has stabilized. Exhaust temperature is monitored carefully for this reason.

Once the exhaust temperature has stabilized, the test unit has reached its peak operating temperature. Exhaust temperature is critical to the completion of a successful evaluation, since temperature changes identify changes in load and RPM. As previously discussed, RPM and load must remain constant during the CMB study.

When all temperatures are stabilized, and desired operating parameters are achieved, it is time to insert the emissions sampling probe into the generator exhaust testing port utilized in this study. The probe has a non-dispersive head, which allows for random exhaust sampling throughout the cross section of the exhaust.

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While the emission-sampling probe is in place, and data is being collected, exhaust temperature and pressure are monitored throughout the entirety of the CMB procedure. The previous photograph shows the typical location of the exhaust emissions sampling probe.

While data is being collected, exhaust pressure is monitored, once again, as a tool to control load and RPM fluctuations. Exhaust pressure is proportional to load. Therefore, as one increases or decreases, so in turn does the other. The CMB test is unique in that all parameters that can, and will, have a dramatic effect on fuel consumption in a volumetric test, are controlled and monitored throughout the entirety of the evaluation. This ensures the accuracy of the data being collected. Exhaust pressure is nothing more than an accumulation of combustion events that are distributed through the exhaust matrix.

The above photograph shows one method in which exhaust pressure can be monitored during the CMB test procedure. In this case, exhaust pressure is ascertained through the use of a Magnahelic gauge. The same process is utilized to determine air inlet quantity to the generator set, This type of stringent regime further documents the inherent accuracy of the CMB test procedure. At the conclusion of the CMB test, a soot particulate test is performed to determine the engine exhaust particulate level. This valuable procedure helps to determine the soot particulate content in the exhaust stream. Soot particulates are the most obvious and compelling sign of pollution. Any attempt to reduce soot particulates places that industry in a favorable position with global environmental policy and the general public.

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The above photograph demonstrates a typical method in which soot particulate volume is monitored during the CMB test. This method is the Bacharach Smoke Spot Test. It is extremely accurate, portable, and repeatable. It is a valuable tool in smoke spot testing when comparing baseline (untreated) exhaust to catalyst treated exhaust.

Finally, the CMB data being recorded on the field data sheets is collected through a non-dispersive, infrared analyzer. Equipment such as this is EPA approved and CFR 40 rated. This analyzer has a high degree of accuracy and repeatability. It is central to the CMB procedure in that it identifies baseline carbon and oxygen levels relative to their change with catalyst treated fuel in the exhaust stream. The data accumulated is highly accurate as long as the criteria leading up to the accumulation of data follows the same echelon of accuracy.

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For this reason, the CMB test is superior to any other test method utilized. It eliminates a plethora of variables that can adversely effect the outcome and reliability of any fuel consumption evaluation.

The above photograph identifies one type of analyzer used to perform the CMB test. The analyzer is calibrated with known reference gases before the baseline and treated test segments begin. The data collected with this analyzer is then computed wherein the carbon data from the baseline segment of the evaluation is compared to the carbon data accumulated from the catalyst treated segment of the evaluation. Critical to this computation is the energy (carbon) contained within the raw diesel fuel. A fuel consumption performance factor is then calculated from the data. The baseline performance factor is compared with the catalyst treated performance factor. The difference between the two performance factors identifies the change in fuel consumption during the CMB test procedure.

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Note: Essential to performing the CMB test procedure is the method in which the task for dosing fuel is performed. It is critical to the success of the CMB procedure to insure that the equipment evaluated be given meticulous care and consideration to advance the process of testing.

INSTRUMENTATION Precision state of the art instrumentation was used to measure the concentrations of carbon containing gases in the exhaust stream, and other factors related to fuel consumption and engine performance. The instruments and their purpose are listed below:

Measurement of exhaust gas constituents HC, CO, CO2 and O2, by Horiba MEXA series infrared analyser.

Note: The Horiba MEXA series emissions analyzer is calibrated with the same reference gas for both the baseline and treated segments of the evaluation.

Temperature measurement: Fluke Model 52K/J digital thermometer. Exhaust differential pressure: Dwyer Magnahelic. Ambient pressure: Brunton ADC altimeter/barometer and NOAA. Exhaust gas sample evaluation of particulate: Bacharach True Spot smoke meter.

TEST RESULTS

Fuel Efficiency A summary of the CMB fuel efficiency results achieved, in this test program, is provided in the following tables and appendices. See Table I, and Individual Carbon Mass Balance Compilation Sheets in Appendix III. Table I provides the final test results for the test vessel included in this evaluation, before and after Syntek fuel catalyst treatment (See Graph II, Appendix II, Exhaust Particulate and Fuel Graphs).

Table I

Test Segment Miles/Hrs. Fuel Change by %

MT Patriot Ceria Treated 1,600 hrs. - 7.0%

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The computer printouts of the calculated CMB test results are located in Appendix III, Carbon Mass Balance Compilation. The raw engine data sheets used to calculate the CMB are contained in Appendix IV, Raw Field Data Sheets. The CMB sample calculation is located in Appendix VII, Carbon Mass Balance Base Equation, of this final report. The raw data sheets, and Carbon Mass Balance sheets show, and account for, the environmental and ambient conditions during both segments of the evaluation.

Soot Particulate Tests Concurrent with CMB data extraction, soot particulate measurements were conducted. The results of these tests are summarized in Table II. Reductions in soot particulates are the most apparent and immediate. Laboratory testing indicates that carbon and solid particulate reductions occur before observed fuel reductions. Studies show that a minimum 400 to 500 hours of Syntek fuel catalyst treated engine operation are necessary before the conditioning period is complete. Then, and only then, will fuel consumption improvements be observed. For the purpose of this evaluation, observed stack soot accumulation had diminished significantly between baseline and treated segments of the evaluation.

Table II

Fuel Type Soot Density Particulates .838 to .837 Untreated 34.46 mg/m3 Treated 23.48 mg/m3

- 31.0% Average (Absolute) - 31.0%

The reduction in soot particulate density (the mass of the smoke particles) was reduced by 31% after fuel treatment and engine conditioning with the Syntek fuel catalyst (See Graph 1 Appendix II). Concentration levels were provided by a Bacharach Smoke Spot Tester. Conclusion The carefully controlled engineering standard test procedures utilizing the Carbon Mass Balance test procedure conducted on this marine vessel provide clear evidence of reduced fuel consumption in the range of 7.0%. It should be noted that engine testing under an applied load (generator set) clearly represents an ideal testing condition, which simulates the preferable testing

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conditions of a dynamometer. As important, engine design and determinate test protocol (CMB) can, and will, produce data equal to, or equivalent to, data collected utilizing other methods of determining fuel consumption levels. Further conclusions utilizing the CMB test procedure identify a 31% reduction in smoke particulates In addition to the fuel consumption analysis, a detailed compilation of carbon emissions reductions were determined. The study documented a significant reduction in annual C02 emissions of 716 metric tonnes. Reductions in Nitrogen, Methane and other combustion related gases/solids were also observed (see Appendix V, Carbon Footprint Data and Appendix VI, Emissions Averages). Additional to the fuel economy improvements measured and a reduction in soot particulates, data collected manifests a significant reduction, over time, in engine related abrasive carbon build up. Carbon reductions of this magnitude will be realized through decreased maintenance costs achieved through lower contaminant levels in the engine lubricating oil, which is a result of more complete combustion of the fuel. Engine wear rates can be reduced as a result of less carbon build-up in the combustion area (see Appendix I, Engine Visual Inspection). Finally, overall exhaust stoichiometry identified an empirical leaning trend, wherein AFR and Lambda baseline readings averaging .65 improved to a catalyst treated average of .75. The weight and volume of evidence and the empirical nature of the data supplied during this evaluation identifies a major paradigm change in base generator operations in favor of the organo-metallic chemistry incorporated into the test procedure. The clear abundance of positive conclusions is not only compelling but revealing. When one clearly internalizes the shear volume of compiled evidence and data, the fuel catalyst evaluated on this marine generator clearly improved the quality of operation and environmental conditions for not only ship operators, but the general public at large.

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Appendix I

Engine Visual Inspection; Carbon

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Prior to the implementation of this test procedure, it was determined that a more profound study be conducted relative to the type and amount of residue build up on critical internal engine, combustion related components. This element of the test paradigm required a process wherein one engine head (no. 6 cylinder, port engine) would be disassembled allowing for a quantitative observational analysis of contaminant volumes. This process would allow for an assessment of progress while using the Syntek fuel catalyst. The following attached pictures are as identified: Pictures taken subsequent to baseline testing February 22, 2012:

Baseline Piston and Cylinder

Baseline Piston and Cylinder The pictures clearly identify a heavy, oily, carbonaceous build up. The abrasive nature of solid carbon deposits between the piston crown and thrust ring can exacerbate blow-by issues by propagating a condition referred to as “bore polishing.” Further, carbon build up in this critical area makes it difficult for

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compression pressures to augment fire ring containment by diminishing pressure assist behind the top fire ring chamfer. Pictures taken subsequent to Syntek Catalyst testing July 11, 2012:

Catalyst Treated Piston and Cylinder

Catalyst Treated Piston and Cylinder Wiped Clean with Shop Towel The catalyst treated segment of this evaluation presented a noticeable change, opposite to that which was noted during the baseline segment of this evaluation. Oily residue and tenacious carbon build up had significantly diminished. Metal contact surfaces on the side of the piston were now apparent. Yellow, brown, or slightly red discoloration is normal when using organo-metallic fuel chemistries.

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The residue is Ferric Oxide and is critical to the conductivity of combustion related events. The yellowish coating documents the nature of catalytic oxidation and its relevance to improved combustion and combustion continuity. Carbon solids are abrasive complex structures that exacerbate wear, not only on combustion related components, but in areas of the engine that require lubrication. Carbon escapes the combustion chamber through a process referred to as “blow-by” and enters the engine lubrication oil reservoir. These abrasive carbon solids are then transferred to critical sites of lubrication, under pressure, with a similar impact of sand paper on polished lubricating surfaces. Any reduction in carbon solids in the lubricating system will help negate the adverse affects of premature engine wear.

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Appendix II

Exhaust Particulate and Fuel Graphs

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Soot/Particulate Graph; Expressed in mg/m3

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Fuel Consumption Graph; Expressed in g/sec.

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Appendix III

Carbon Mass Balance Compilation Sheets

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Appendix IV

Raw Field Data Sheets

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Appendix V

Carbon Footprint Data

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Calculation of Greenhouse Gas Reductions

Assumptions: Vessel Fleet Average (Estimate)

* Fuel Type = Diesel Oil *Annual Fuel Usage = 1,000,000 gallons, or 3,800,000 litres *Average 7.0% reduction in fuel usage with Syntek fuel catalyst. Discussion:

When fuel containing carbon is burned in an engine, there are emissions of carbon dioxide (CO2, methane (CH4), nitrous oxide (N20), oxides of nitrogen (NOx), carbon monoxide (CO), non methane volatile organic compounds (NMVOC's) and sulfur dioxide (SO2). The amount of each gas emitted depends on the type and quantity of fuel used (the "activity"), the type of combustion equipment, the emissions control technology, and the operating conditions.

The International Greenhouse Partnerships Office section of the Federal Government Department of Science Industry and Technology has produced a workbook outlining how to calculate the quantities of greenhouse gas emissions and is accepted internationally as the accepted approach. The workbook illustrates an example of how to calculate the mass of CO2 for example on page 21, Table 3.1 and Example 3.1: The CO2 produced from burning 100 litres of diesel oil is calculated as follows:

* the CO2 emitted if the fuel is completely burned is 2.716 kg CO2/litre (see Appendix A, Table A1)

* the oxidation factor for oil-derived fuels is 99% (see Table 3.1) Therefore, the CO2 produced from burning 100 litres of fuel is: 100 litres x 2.716 kg CO2/litre x .99 = 268.88 kg

Based on the above calculations, the Greenhouse gas reductions for C02 are as follows:

Test Data Fuel Usage kg CO2

per Oxidation System CO2 System CO2 Basis litres litre fuel Factor kg tonnes

"Baseline" 3,800,000 2.716 0.99 10,217,592 10,218 "Treated" 3,534,000 2.716 0.99 9,502,361 9,502 C02 reductions with Syntek fuel catalyst 715,231 716

The reduction of C02 greenhouse emissions in the amount of 716 tonnes (789 U.S. tons) is significant! Carbon Dioxide accounts for approximately 99.6% of the total greenhouse gas emissions produced. In other words, when diesel oil is burned in an internal combustion engine, the CH4 and N20 emissions contribute less than 0.4% of the greenhouse emissions. This low level is typical of most fossil fuel combustion systems and often is not calculated.

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However, by way of additional information, the reduction in CH4 and N20 are calculated as follows: CH4 Emissions Reduction

* the specific energy content of the fuel is 36.7 MJ/litre (see Table A1), so the total energy in 100 litres is 3,670 MJ, or 3.67 GJ

* the CH4 emissions factor for diesel oil used in an internal combustion engine is 4.0 g/GJ (see Table A2) so the total CH4 emitted is 3.67 x 4 = 18.0g

"Baseline" [18.0g/100 litres] x [3,800,000] x [1kg/1000g] = 684 kg "Treated" [18.0g/100 litres] x [3,534,000] x [1kg/1000g] = 636 kg CH4 Reduction = 48 kg N2O Emissions Reduction

* the N2O emissions factor for diesel oil used in an internal combustion engine is 1,322 g/GJ so the total N2O emitted is 3.67 x 0.6 = 2.7 g

"Baseline" [2.7g/100 litres] x [3,800,000] x [1kg/1000g] = 103 kg "Treated" [2.7g/100 litres] x [3,534,000] x [1kg/1000g] = 95 kg N2O Reduction = 8 kg

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Appendix VI

Emissions Averages for Carbon Mass Balance Evaluation

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The averages for all emissions monitored during the Carbon Mass Balance test procedure are tabulated and are included in Table III. They are as follows:

Table III Overall Average Feb. 22 to July 11, 2012:

HC C02 O2 C0 Baseline: 19.1 ppm 3.19% 18.49% .13% Treated: 7.0 ppm 3.04% 20.08% .20% Pct. Change: - 63% - 4% + 8% + 53% The data for the entirety of the evaluation clearly shows reductions in carbon emissions with an increase in oxygen levels. NOTE: In general, carbon monoxide levels are very sensitive to load change. During the course of the treated segment of this evaluation, generator load temperature and pressure were influenced by a cooler testing climate.

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Appendix VII

Carbon Mass Balance Base Equation

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Assumptions: C8H15 and SG = 0.78

Time is Constant

Load is Constant

Data: Mwt = Molecular Weight pf1 = Calculated Performance Factor (baseline)(1)

pf2 = Calculated Performance Factor (treated)(2)

PF1 = Performance Factor (adjusted for baseline exhaust mass)(1)

PF2 = Performance Factor (adjusted for treated exhaust mass)(2)

T = Temperature (°F) F = Flow (exhaust CFM) SG = Specific Gravity

F = Volume Fraction

VFC02

VF02

VFHC

VFCO

= "reading" 100

= "reading" 100

= "reading" 1,000,000

= "reading" 100

Equations:

Mwt = (VFHC)(86)+(VFCO)(28)+(VFCO2)(44)+(VFO2)(32)+[(1-VFHC-VFCO-VFO2- VFCO2)(28)]

pf1 or PF1 = ___________2952.3 x Mwt___________

89(VFHC)+13.89(VFCO)+13.89(VFCO2)

PF1 or PF2 = pf x (T+460)

F

Fuel Economy:

Percent Increase (or Decrease) = (PF2 - PF1 ) x 100

PF1

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