furnace data · 2019-11-17 · #1 a/s i qc sample i cone. limits i after i periodic i at icount asl...

FURNACE DATA

flR3i9006

-ff**.(j.

Flomr-nt File: ASFAST. GELtriotnent: An; Analyst:Pr i n t Ditn: Mnin+Suppl. Peak Storage: NonePrint: Calib. Curve+Elem. Params.

TNfTTRUMFNT: ?100 Technique: HGA Version: 7.10Wavelength: 193.7 Peak Slit: 0.70 LowSignal Type: Zeeman AA Signal Measurement: Peak Area

SnrnplF> Replimtess 2Standard R(?plicate»s: 2

CALIBRATION:Solutions 1 ID

1Calib. Blank 150Standard 1 1510S» nndai r! 2 520Standard 3 540Standard 4 S60Standard 5 S80Samplers _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _T'iluont Lnr^n^ion: 0Modifier #1 Location: 39ralihntion Units: ug/LCalibration Type: Linear

F-iinacf? Ti"i«=/T<-»mpr>rature» Program:St^p Tr?mp Rnrp Hold Gas -Flow Rea

1 110 2 30 2502' 120 2 5 250".' 1 00 €• 15 250•1 2200 03 0 ••~. 249IO 1 2 250

Tni<?ction T«=n-p: 120 Pipette

S*;>^p Art ion nnd Parameters1 Pipo» rJilut?nt + modifier 12 Run HGA stops 1 to End

- V » l_i A-' r .*. «• jr • m«r • i~r * *—* f • .*. tn *— • *»

Spike Replicates: Same as Sample

Cone 1 Location Volume Diluent Modifier1 Volume #1 #2

_ _ _ _ _ _ _ _ ! 0 10 2 210.001 40 1 11 220.001 40 2 10 240.001 4 0 4 8 260.001 4 0 6 6 280.001 4 0 8 4 2

_ _ _ _ _ _ _ _ ! _ _ _ _ _ _ _ _ 10 2 2

Modifier #2 Location:Sample Units: ug/L

d Gas Type u cASTER LABORATORIES

No1™ GFAA .- AS3S<^Norm DATE: DEC 2 11992No™ REVIEWER ^ 'Norm

Speed: 80V. Extraction System: Off

* spike * sample/std

CHECKS:Rr>-q 1 i hrnt ion Type: Completely RecalibrateLnrritions: Ho-1*1

•"tine. Abnvo CT 1 i brat ion Action: Print Message OnlyAlternate fnmple Volumes (uL) :Run Alternate Volume Blanks: No

Ro^nverv Mrnr-jrements: —• -^ ,-.2 uL of 100 ug/L Standard at Location 37 Gives 20.00 ug/L «..M"^sur<=> Rr.ri-'i-<~-r y on Samples: 2-40AM,< to oc ^n^nl^R; No % Recovery Limits: 85.00 to gljl <f 9 0 0 7

#1 A/S I QC Sample I Cone. Limits I After I Periodic I At ICount AslI Loc. I TD I Lower Upper ICalibl Check I End I Sample I

1 36 ICV . 45.00 55.00 X2 0 ICB -5.00 5. 00 Xi 3f. CCV 45.00 55.00 X X4 (7> CCB -5.00 5.00 XXRun Periodic OC Samples: 2,7,12,17,22,27,32Out of Limit Action: Print Message Only

Matrix ChF-ck Calculations:'.'. Difference for Dupls: No Locations:V. Re-cnv^ry for Spike: No Locations: Cone:

LANCASTER LABORATORIESGFAADATE:DEC2M992REVIEWER *

AR3I9008

LANCASTER LABORATORIESGFAADATE: DEC 2 1 1992REVIEWER •?»"/-? 77

Elc.piont File: ASFAST. GEL Element: As Wavelength: 193.7Dnte: 12/21/92 Time: 14:51 Slit: 0.70 LData File: AS35602.DAT ID/Wt File: 35602.IDW Lamp Current: 0Technique: HGA Calib. Type: Linear Energy: 62

As- ID: S0 Seq. No. : 00001 A/S Pos. : 0 Date: 12/21/92

Replicate 1 Time: 14:51Pe^k Area (A-s): 0.001 'Peak Height (A): 0.010P-u-kqr ound Pk Area (A-s): 0.012 Background Pk Height (A): 0.022niank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): 0.65

R<->pl icat.e? 2 ' Time: 14:54P<-~ik Ama (A-n): -0.001 Peak Height (A): 0.007Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.022Blnnk Corrected Pk Area (A-s): 0.000Concentration (ug/L ) : -0. 10

Menn Cone. (uq/L ): '0.27 SD: 0.530 RSD C •/.):"" 193. 76

Auto-zero performed.

Ac IP: S10 Seq. No.: 00002 A/S Pos.: 40 Date: 12/21/92

Replicate 1 Time: 14:56P<=nk Area (A-r,): 0.017 Peak Height (A): 0.043Pncknround Pk Area (A-s): 0.014 Background Pk Height (A): 0.026Blnnk. C.nr T <?«•-1 r>d Pk Area (A-s): 0.017Concentration (ug/L ): 10.30

R^plicatp- 2 Time: 14:58Peak Area (A-n): 0.018 Peak Height (A): 0.040BT-kqronp.f' Pk Area (A-s): 0.013 Background Pk Height (A): 0.022Blnnk Con<-~tr>d Pk Area (A-s): 0.018Concentration (ug/L ): 11.04

Mean Cone (uq/L ): 10.67 SD: 0.525 RSD (V.) :'' 4."~93 "

Standard number 1 applied. [10.00]Correlation coefficient: 1.00000 Slope: 0.0017 Int: 0.000

An ID: S20 Seq. No. : 00003 A/S Pos. : 40 Date: 12/21

R^rlicn*;o \ Time: 15:00 •*Peak Area (A-s): 0.029 Peak Height (A): 0.062 a p O j n n r> QBackground Pk Area (A-s): 0.012 Background Pk Height ( A) : 1*023 ? U U _>"T_..t. r*r - r-.r-i <-,ri PV Ai-oa (A-s): 0.029

As ID: S20 Seq. No.: 00003 A/S Pos.: 40 Date: 12/21/92

Replicate 1 Time: 15:00Pp-nk Area (A-s): 0.029 Peak Height (A): 0.062Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.023

nk Corrected Pk Area (A-s): 0.029centration (ug/L ): 16.81

Replicate 2 . Time: 15:02Peak Area (A-s): 0.026 Peak Height (A): 0.054Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.023Blnnk Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 15.10

LANCASTER LABORATORIESGFAADATE: .jjrpj i 1992

IEWERREVI

Mean Cone (ug/L ): .15.96 SD: 1.205 RSD ('/.): 7.55 '

ntandnrd number 2 applied. [20.00]Correlation coefficient: 0.98946 Slope: 0.0014 Int: 0.001

ID: S40 Seq. No.: 00004 A/S Pos.: 40 Date: 12/21/92

Replicate 1 " Time: 15:04eak Area (A-s): 0.051 Peak Height (A): 0.107rkqround Pk Area (A-s): 0.015 Background Pk Height (A): 0.028rnnk Corrected Pk Area (A-s): 0.051

Concentration (ug/L ): 35.80

i\\.' p

Replicate 2 _ Time: 15:06Penk Area (A-s): 0.053 Peak Height (A): 0.107Bnckqi oumi Pk Area (A-s): 0.014 Background Pk Height (A): 0.028Blank Corrected Pk Area (A-s): 0.053Concentration (ug/L ): 36.97

M-ean Cone (ug/L ): 36.38 SD: 0.826 RSD ('/.):" 2. 27

Standard n'mber 3 applied. [40.003Correlation coefficient: 0.99550 Slope: 0.0013 Int: 0.002

As ID: SG0 Seq. No.: 00005 A/S Pos.: 40 Date: 12/21/92

Replicate I Time: 15:09Peak Area (A-s): 0.077 Peak Height (A): 0.163BnckoTcund Pk Area (A-s): 0.017 Background Pk Height (A): 0.031Blnnk Corrected Pk Area (A-s): 0.077Concentration (ug/L ): 59.33

Replicate 2 . . . . . . . Time: 15:11Iak Area (A-s): 0.077 Peak Height (A): 0.146ckqrcurid PI: Area (A-s): 0.013 Background Pk Height (A): 0.029ank Corrected Pk Area (A-s): 0.077 -

Concentrati on (ug/L ): 59.58 -

l\ '.

•Mean Cone (ug/L ): 59.45 SD: 0.178 RSD-tlU {1 fl n o 1

d ri'i-^ber 4 applied. [60.001fTl

Ac ID: SO?1 Seq. No. : 00006 A/S Pos. : 40 Date: 12/21/92

P^plictite 1 Time: 15:13P<=nk Area (A-s): 0.105 Peak Height (A): 0.216Pn-knround Pk Area (A-s): 0.019 Background Pk Height (A): 0.034Plnnk Correc*p>d Pk Area (A-s): 0.105'-•;ncpn Nation (ug/L ): 82.25

R^plicnte 2 . Time: 15:15P~nk Area (A-s): 0.104 Peak Height (A): 0.206P-i^kground Pk Area (A-s): 0.015 Background Pk Height (A): 0.031Blnnk Corrected Pk Area (A-s): 0.104Concentration (ug/L ): 81.37

LANCASTER LABORATORIESGFAA ..— AS 3f& ZDATGrDEC 2 1 1992REVIEWO! 7»*r ?<?7

Mean Cone (uq/L ): 'Sl.Sl" *" SD: 0.621 RSD ('/.):' 0.76

Standard number 5 applied. 180.001Cot relation coefficient: 0.99904 Slope: 0.0013 , Int: 0.002

Calibration - Ci\ftOSER\ft<LFILES\ELEHENT\ftSFftST.6El8,103

DATAVEWBEDWTHANXBY:

\~isV

Corr. Coef.: 0(99904Slope: 8.BQ13Intercept; 0.002

0.0 Concentration

An ID: 1CV Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92

Replicate 1 Time: 15:18PonU Aren (Ac): 0.067 Peak Height (A): 0.140Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.029Blnnk Corror-»rd Pk Area (A-s): 0.067Concentration (ug/L ): 50.81

e 2 Time: 15:20Peak Area (A-s): 0.067 Peak Height (A): 0. 140 D n j Q ,-j . •Bn-knrnund Pk Area (A-n): 0.012 Background Pk Height W/JW 0.-W301 Im nr>\r Cni-rpr't ed Pk Area (A-s): 0.067

Replicate ..2 . . . Time: 15:15P<--nk Area (A-s): 0.104 Peak Height (A): 0.206Pnr-kqround Pk Area (A-s): 0.015 Background Pk Height (A): 0.031Plnnk Corrected Pk Area (A-s): 0.104Concentration (ug/L ): 81.37

LANCASTER LABORATORIESGFAA ..- A33/<^2PATE:DEC 2 I 1992REVIEWER ;*-/-? 7-7

Monn Cone (uq/L ): '81.81""'" SD: 0.621 RSD ('/.) : ' 0. 76

S*nndard number 5 applied. C80.00]Correlation coefficient: 0.99904 Slope: 0.0013 . Int: 0.002

MJDisplay Calibration - Ci \flOSER\ftft_FILES\ELEHENT\ftS FftST.fi EL0,105

ni

assLinearCo IT. Coef.: BSlope: 0.0013Intercept; 0.002

0,0 Concentration 00,00

Ac ID: ICV Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92

itp 1 Time: 15:18P«-nk Aion (A-c.): 0.067 Peak Height (A): 0.140B:v-kgi ound Pk Area (A-s): 0.013 Background Pk Height (A): 0.029PI mi!'. r->TTo~f.r>d Pk Area (A-s): 0.067Concentration (ug/L ): 50.81

Replicate 2 . .... Time: 15:20Peak Ar<"-a ( A • :>) : 0.067 Peak Height (A): 0.140Bnckqround Pk Area (A-n): 0.012 Background Pk Height (A): 0.030BJnnk Corrected Pk Area (A-s): 0.067

icentration (ug/L ): 50.78••.(

\h Cone (uq/L ): 50.79 SD: 0.024 RSD (*/.): 0.05

0^ cample ic within ranqe 45.00 - 55.00

ID: ICD Seq. No.: 00008 A/S Pos.: 0 Date: 12/21/92

As ID: ICB Seq. No. : 00008 A/S Pos. : 0 Date: 12/21/92

Time: 15:22Area (A-s): -0.002 Peak Height (A): 0.008

Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.020Blank Corrected Pk Area (A-s): -0.002Concentration (ug/L ): -3.48

e 2 Time: 15:24LANCASTER LABORATORIESGFAADATE: DEC 21 1992REVIEWER

k Aren (A-s): -0.000 Peak Height (A): 0.006Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.022Blnnk Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -1.58

M^ari Cone (ug/L ): -2 53 » SD: 1.343 RSDC/.): 53.05

DC sampl<= in within range -5.00 - 5.00

As ID: CRA Seq. No.: 00009 A/S Pos.: 1 Date: 12/21/92

Replicate 1 Time: 15:27Peak Area (A-s): 0.014 Peak Height (A): 0.033Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.023Blank Corrected Pk Area (A-s): 0.014Concentration (ug/L ): 9.83

R<->plir-3te 2 Time: 15:29P~ak Aren (A-s): 0.013 Peak Height (A): 0.032Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.025Blank Corrected Pk Area (A-s): 0.013Concentration (ug/L ): 8.78

Mean r0nc (uq/L ): r9i31---- SD: 0.741 RSDC/.): 7.96

As ID: CCV Seq. No.: 00010 A/S Pos.: 36 Date: 12/21/92

RT! icnt <-. l Time: 15:31P~nk Aron (A-s): 0.065 Peak Height (A): 0.144Background Pk Area (A-e): 0.016 Background Pk Height (A): 0.030Blank Corrected Pk Area (A-s): 0.065Concentration (ug/L ): 49.37

Replicato 2 Time: 15:33Penk Aren (A--s>: 0.065 Peak Height (A): 0.154Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.029Plank Corrected Pk Area (A-s): 0.065Concentration (ug/L ): 49.81

Mean Cone 'ug/L ): 49.59 „ \ SD: 0.318 RSDC/.): 0.

QC snnple is within range 45.00 - 55.00, t

As ID: CCB Seq. No. : 00011 A/S Pos. : 0 Date: 12/21/92

—— M,, 1 Time: 15:35 8R3I90I3

As- ID: CCB . Seq. No. : 00011 A/S Pos. : 0 Date: iz

Replicate 1 Time: 15:35Peak Area (A-s): 0.002 Peak Height (A): 0.007P-nckqr ound Pk Area (A-s): 0.011 Background Pk Height (A): 0.022Plank Corrected Pk Area (A-s): 0.002

«icentr^ition (ug/L >: -0.25

..licate -2 Time: 15:38Peak Area (A-s): 0.000 Peak Height (A): 0.007Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.022Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): -1.48

LANCASTER LABORATORIESGFAADATE: DEC 21REVIBM-P, 3

Mean Cone (ug/L ): -08£T"~ SD : 0.873 RSDC/.): 100;- 97.

OC sample ic within range -5.00 - 5.00

Ac ID: 1906933/512 Z ZZ*Z Seq. No- : ®®®12 A/S Pos.: 2 . Date: 12/21/92

Replicate 1 Time: 15:40Peal: Area (A-s): 0.002 Peak Height (A): 0.008Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.032Plank Corrected Pk Area (A-s): 0.002«centration (ug/L ) : 0. 02 . Corrected Cone (ug/L ): 0.1

, lir-ate 2 Time: 15:42P<-ak Aren (A-s): 0.000 Peak Height (A): 0.007Background Pk Area (A-s): 0.026 Background Pk Height (A): 0.033Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): -1.36 Corrected Cone (ug/L ): -6.8

Moan Cone (ug/L ): -0767? SD: 0.973 RSDC/.): 145779—rorreched Cone (ug/L ): -3.3

As ID: 19P6933/5I Seq. No. : 00013 A/S Pos. : 2 Date: 12/21/92zzzzzzReplicnte ! Time: 15:44r<-a!-. Area (As): 0.032 Peak Height (A): 0.054Pnckqrounrf Pk Area (A-s): 0.026 Background Pk Height (A): 0.034Plnnk Corrected Pk Area (A-s): 0.032Concentration (ug/L ): 23.45 Corrected Cone (ug/L ): 117.2

R^plicnte 2 Time: 15:47'-•-ak Aren (A-s): 0.027 Peak Height (A): 0.048Background Pk Area (A-s): 0.027 Background Pk Height (A): 0.034Blank Corrected Pk Area (A-s): 0.027Concentration (ug/L ): 19.50 Corrected Cone (ug/L ): 97.5

n Con.- (uq/L ): 21.48 . SD: 2.787 RSD C/.) : n[2.'98>rected Cone (ug/L ): 107.4

>ry is- -HrfrrT 10?. V£ f C^

ID: PRW 350 ODP>C$)"'rcr;>?bASeq. No-.: 00014 A/S Pos.: 30;^:' 7:2/21/92

Ac ID: PBW 3FO glOG>V,y *°?-' vSeq. No. : 00014 A/S Pos. : 3 Date: 12/21/92

Replicate 1 Time: 15:49P^ak Area (A-s): 0.000 Peak Height (A): 0.007Pncknround PI'. Area (A-s): 0.012 Background Pk Height (A): 0.024P-lnrik Corrected Pk Area (A-s): 0.000Concc-nti ntion (ug/L ): -1.22

Implicate 2 Time: 15:51P=ak Area (A-s): 0.002 Peak Height (A): 0.008Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.021Plank Corrected Pk Area (A-e): 0.002Concentration (ug/L ): 0.36

Mean Cone (ug/L ): -0T4*3T ' SD: 1.112 ' RSDC/.): 258.83

LANCASGFAA

REVIEWER

ID: PBW 350 P20- Seq. No.: 00015 A/S Pos.: 3 Date: 12/21/92PBWA 354 " ol-U

1 <o> Time: 15:54Peak Aren (A-s): 0.024 Peak Height (A): 0.060Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.027Blnnk Corrected Pk Area (A-s): 0.024Concentration (ug/L ): 17.28

Replicate 2 Time: 15:56Pf-ak Area (A-s): 0.026 Peak Height (A): 0.055Pnckqiound Pk Area (A-s): 0.014 Background Pk Height (A): 0.026Blnnk Corrected Pk Area (A-s): 0.026Concentration (ug.'L ): 19.11

Mean Cone (ug/L ): 18.19 SD: 1.294 RSDC/.): 91 12'

Recovery ic 93. I*/. 4*0?

Ac ID: LCSW 3D3 02^ CJ9 Seq. No.: 00016 A/S Pos.: 4 Date: 12/21/92LCSW loSt^M

R--.pl icnte 1 Time: 15:58Ponk Aren (A-s): 0.055 Peak Height (A): 0.105Pnckqround Pk Area (A-s): 0.013 Background Pk Height (A): 0.026Blnnk Corrected Pk Area (A-s): 0.054Concentration (ug/L ): 41.28

Replicate 2, _ Time: 16:00P-ak Area (A-s): 0.053 Peak Height (A): 0.104Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.027Blank Corrected Pk Area (A-s): 0.053Concentration (ug/L ): 40.04

__.,.. „..„..Mean Cone (uq/L ): 40.66 i SD: 0.873 RSDC/.): 2. l

Ac IP: fcW .Ti? <>-tt»v Seq. No.: 00017 A/S Pos.: 4 Date: 12/21/92

Replicate 1 Time: 16:03 ftR3l90i5Poak Are-i 'A-s): 0.079 Peak Height (A): 0.158

As ID: LCSW £53 03<> Seq. No. : 00017 A/S Pos. : 4 Date: 12/21/92LC$WA3S4<osu°*-l

Replicate 1 Time: 16:03Peak Area (A-s): 0.079 Peak Height (A): 0.158Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.028 ,

«mk Corrected Pk Area (A-s): 0.079 (jP t~re>«^«j *-*^($ic<=ntration (ug/L ): 60.82 TiT$«> l^-j13/iZ

Replicate 2 - Time: 16:05P^ak Area (A-s):. 0.082 Peak Height (A): 0.157Pnckqround Pk Area (A-s): 0.016 Background Pk Height (A): 0.028Blank Corrected Pk Area (A-s): 0.082concentration (ug/L ): 63.12

Mean Cone (ug/L ): 61.97 SD: 1.625 RSDC/.) : "2.62—

Recovery is -106. &'/. —————————————

Ac ID: l'-'08350 TAMMT Set?- No- : 00018 A/S Pos. : 5 Date: 12/21/92

Replicate 1 Timet 16:07

,>., A3?J7J<?2_DATE: DEC 21 199?REVIEWER

Peak Area (A-s): 0.000 Peak Height (A): 0.009ound Pk Area (A-s): 0.023 Background Pk Height (A): 0.043Corrected Pk Area (A-s): 0.000trnt ion (ug/L ): -1.46

Replicate 7 Time: 16:09Peal: Area (A-s): 0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.022 Background Pk Height (A): 0.044Blank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): 0.37

Mean Cone (ug/L ): -0.54" SD : 1.291 RSDC/.): 237r82""

A.c ID: Ice'8350 3AWAT A Seq. No. : 00019 A/S Pos. : 5 Date: 12/21/92

Roplicate 1 - _ Time: 16:12Peak Area (A-s): 0.028 Peak Height (A): 0.053Backqround Pk Area (A-s): 0.027 Background Pk Height (A): 0.046Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.35

Replicate 2 Time: 16:14Peak Area (A-s): 0.028 Peak Height (A): 0.049Backqround Pk Area (A-s): 0.028 Background Pk Height (A): 0.047Blnnk Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.65

n Cone (ug/L >: 20. 50 l SD: 0.214 RSD C/.) : 'T: 04r

Recovery ic

As ID: 1903351 Seq. No.: 00020 A/S Pos.: 6 H n OaJtSAJ ,2/21/92

As . ID: 1908351 TA/AfAr Seq. No. : 00020 A/S Pos. : 6 Date: 12/21/92

Replicate 1 Time: 16:16penk Area (A-s): -0.000 Peak Height (A): 0.007Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.031Plank Corrected Pk Area (A-s): -0.000'"once-ntration (ug/L ): -1.69

Replicate 2 .. Time: 16:18Pr=ak Area (A-s): 0.001 Peak Height (A): 0.007Ba-kground Pk Area (A-s): 0.016 Background F*k Height (A): 0.030Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.52

Mean Cone (uq/L ): ' SD : 0.823 RSDC/.): 74 47 ~

As ID: 1908351 AM^R / Seq. No. : 00021 A/S Pos. : 6 Date: 12/21/92

Replicate 1 Time: 16:21Pr>nk Area < A--s> : • fl. <?>?6 - Peak Height (A): 0.054 •Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.033Blank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 18.53

Replicate 2 Time: 16:23

ES .... _..u,

ASREVIEWER 7w?l?<j DATE:

REVIEWERPeak Area (A-s): 0.027 Peak Height (A): 0.050Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.035Blank Cor i <^^t.ed Pk Area (A-s): 0.027Concentration (ug/L ): 20.00

Mean Cone (ug/L ): 19.26 SD: 1.046 RSDC/.): ,57"43V-,

Recovery is i(M.. 5% -'{j

As ID: CCV Seq. No. : 00022 A/S Pos. : 36 Date: 12/21/92

Replicate 1 Time: 16:25P«ak Area (A-s): 0.067 Peak Height (A): 0.144Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.067Concentration (ug/L ): 51.01

Replicate 2 Time: 16:27P^ak Area (A-s): 0.065 Peak Height (A): 0.145Bnckqround Pk Area (A-s): 0.015 Background Pk Height (A): 0.029Plank Corrected Pk Area (A-s): 0.065Concentration (ug/L ): 49.41

M.-an Cone (ug/L )i 50/21" • • SD: 1.133 RSD C/.) : ' 2

QC cample in within range 45.00 - 55.00 " -f Oisf

A.c ID: CCQ Seq. No.: 00023 A/S Pos.: 0 ^ MDSter 4:2/21 /92

Ac ID: CCB Seq. No. : 00023 A/S Pos. : 0 Date: 12/21/92

Replicate 1 Time: 16:30Peak Aren (A-s): 0.003 Peak Height (A): 0.007Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.021

k Corrected Pk Area (A-s): 0.003ncentration (ug/L ): 0.87

Replicate 2 Time: 16:32Fr-ah Area (A-s): 0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.024Plank Corrected Pk Area (A-s): 0.002concentration (ug/L ): 0.39

Mean. Cone (ug/L ): !0T_uT" SD : 0.336 RSDC/. ): *~53 ."25 '

OC natrple is within range -5.00 - 5.00

Ac ID: 1908352R JAPAMT S Seq. No.: 00024 A/S Pos.: 7 Date: 12/21/92

Replicate 1 Time: 16:34Peak Area (A-s): 0.057 Peak Height (A): 0.098PnckqromH Pk Area ( A - s ) : 0.028 Background Pk Height (A): 0.049Blank Corrected Pk Area (A-s): 0.057Concentration (ug/L ): 42.99

Replicate 2 Time: 16:36Peal: Area (A-s): 0.057 Peak Height (A): 0.097Background Pk Area (A-s): 0.029 Background Pk Height (A): 0.051

LANCASTER LABOrGFAA £DATE:DEC 2 1 193Z

Blan!-. Collected Pk Area (A-s): 0.057 R V!r.WofJConcentration (ug/L ): 43.49

Mean Cone <'jg/L ): 43.27 SD: 0.353 RSD C/.) : -0. 82 .

Ac ID: 1°®83S2R2 2 2 Z Z Z Seq> No> : 00025 A/s Pos.: 7 Date: 12/21/92

Prr.pl jr-nte l Time: 16:38Prvak Aren (A-s): 0.082 Peak Height (A): 0.149Pacl-.qr ound PI: Area (A-s): 0.030 Background Pk Height (A): 0.054Plank Corrected Pk Area (A-s): 0.082Concentration (ug/L ): 62.93

Ropiicnte 2 Time: 16:40Pea!-. Aren (A-s): 0.085 Peak Height (A): 0.150Packqround Pk Area (A-s): 0.031 Background Pk Height (A): 0.051Plank Corrected Pk Arr>a (A-s): 0.085oncer, trati on (ug/L ): 64.95

an Cone (uq/L ): 63.94 SD: 1.428 RSD C/.) : 2. 231

cnvr-ry ir 103.5?." ' " •_ OM

Ac TP: 2008353D Seq. No. : 00026 A/S Pos. : *» ' - f t t w 12/21/92. : %*» ' -ftUttw 12/21

Ac ID: 1908353D J/\jv\fl/\-V D Seq. No.: 00026 A/S Pos.: 8 Date: 12/21/92

Replicate 1 Time: 16:43Peak Area (A-s): 0.002 Peak Height (A): 0.008Background Pk Area (A-s): 0.027 Background Pk Height (A): 0.049Plank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): -0.18

Replicate 2 Time: 16:45Peak Area (A-s): 0.002 Peak Height (A): 0.008Background PI: Area (A-s): 0.028 . Background Pk Height (A): 0.045Blank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): -0.17

Mean. Cone (ug/L ): *0rl8 "" SD: 0.013 RSD C/.) : •17T4_T*'',

Ac ID: 190S353D TAftftMT £, Seq. No.: 00027 A/S Pos.: 8 Date: 12/21 92

Replicat<= 1 Time: 16:47Peak Aren (A-s): 0.026 Peak Height (A): 0.052Packaround Pk Area (A-s): 0.030 Background Pk Height (A): 0.048Blank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 18.54

Replicate 2 Time: 16:49Peak Area (A-s): 0.030 Peak Height (A): 0.055Background Pk Area (A-s): 0.027 Background Pk Height (A): 0.048Blank Corrected Pk Area-< A-B>cr-0;-029Concentration (ug/L ): 21.62

Mean Cone (ug/L ): 20.08 SD: 2.178 RSD C/. > : *JL0.

Recovery in 101; Stfr/

^ ' \f FASTER LABORATORIESGFAADATE: BEC 2 1 W92REVIEWER -*~ <7

Ac ID: non354 AK^M Seq. No. : 00028 A/S Pos. : 9 Date: 12/21/92

1 Time: 16:52Pr>ak Area (As): 0.000 Peak Height (A): 0.006Bacl-.qi ound Pk Area (A-s): 0.017 Background Pk Height (A): 0.032Plank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): -1.49

Replicate 2 Time: 16:54Pr-ak Area (As): -0.001 Peak Height (A): 0.007Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.030Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -2.04

M~nn Cone 'uq/L ): ;-1.7T SD: 0.390 RSDC/.): _>2

Ac. ID: lr»P8354 Seq. No.: 00029 A/S Pos.: 9 Date: 12/21/92

R-plicate 1 Time: 16:56 ' H r v O , n n i r > —Area (As): 0.025 Peak Height (A): 0.ffm5i90l9^o,,ori ri- Area (A-e): 0.020 Background Pk Height (A): 0.035

As ID: 1908354 3"A(v/\p/V\ /\ Seq. No. : 00029 A/S Pos. : 9 Date: 12/21/92

Replicate 1 Time: 16:56Peak Area (A-s): 0.025 Peak Height (A): 0.054Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.035Blank Corrected Pk Area (A-s): 0.025

ncentration (ug/L ): 18.32

Replicate 2 Time: 16:58Peak Area (A-s): 0.028 Peak Height (A): 0.053Background Pk Area'(A-s): 0.018 Background Pk Height (A): 0.032Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.47

Mean Cone (ug/L ): 19.40 SD: 1.521 RSDC/.) : J7i.84,.

Recovery is tOSt OK- 17- &

As ID: 1908355 ZZZZZ2 Seq- N°' : 00030 A/S Pos- : 10 Date: 12/21/92

Replicate 1 Time: 17:00Peak Area (A-s): 0.001 Peak Height (A): 0.006Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.030Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.84

Replicate 2 Time: 17:02Peak Area (A-s): -0.002 Peak Height (A): 0.006Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.028Uank Corrected Pk Area (A-s): -0.002ncentration (ug/L ): -3.29

Mean Cone (ug/L ): "1*2357""- SD: 1.729 RSDC/.):

As ID: 1908355 22ZZZZ Seq* N°* '' 00031 A/S Pos' : 10 Date: 12/21/92

Replicate 1 Time: 17:05Peak Area (A-s): 0.028 Peak Height (A): 0.060Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.030

LANCASTER LABORATORIESGFAA ASDATE: DEC 2 i 1992REVIEWER

Blank Corrected Pk Area (A-s): 0.028Concentrntion (ug/L ): 20.70

Replicate 2. Time: 17:07Peak Area (A-s): 0.026 Peak Height (A): 0.061Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 19.25

an Cone (ug/L ): 19.98 SD:- 1.027 RSDC/.):

Rr>cQv°ry ir.

Ac IDs 1908356 Seq. No.: 00032 A/S Pos. : AR3 JD9$?20L2/21/92

As ID: 1308356 J"/\/Vli_T Seq' No' : 00032 A/S Pos. : 11 Date: 12/21/92

Replicate 1 Time: 17:09Peak Area (A-s): -0.001 Peak Height (A): 0.008Backqround Pk Area (A-s): 0.022 Background Pk Height (A): 0.038Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -2.02

Replicate 2 Time: 17:11Peak /*rea (A-s): 0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.038Blank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): -0.21

Mean Cone (ug/L ): •*&?$&• SD: 1.285 RSDC/.): O.T5r37 .

As ID: 1908356 J^MLT A Seq' No' : 00033 A/S Pos' : ii Date: 12/21/92


Replicate 2 Time: 17:16Peak Area (A-s): 0.030 Peak Height (A): 0.051Background Pk Area (A-s): 0.024 Background Pk Height (A): 0.040Blank Corrected Pk Area (A-s): 0.030 '•Concentration (ug/L ): 21.99

Mean Cone (ug/L ): 20.42 SD: 2.217 . RSD C/. ) fl

— -• •-...Recovery is lQ7. 7tt~ '


Replicate 1 Time: 17:18Peak Area ( A-s > :- • 0.-06S —— — ~ ——— - — - ——— Peak Height < A->-r~0: 134 —Backqround Pk Area (A-s): 0.014 Background Pk Height (A): 0.027Blank Corrected Pk Area (A-s): 0.066Concentration (ug/L ): 50.19


LANCASTER LABORATORIESGFAAJ?ATE:DEC 21REVIEWER /

Pr-ak Aina (A-s): 0.065 Peak Height (A): 0.142Par-kqi Dunci Pk Area (A-s): 0.016 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.065Concentration (ug/L ): 49.31

, _.-* -«- * .Mean Cone (ug/L ): <49. SD: 0.620 RSDC/.):

DC sample in within range 45.00 - 55.00 *~ «-&_._. f-'\

As ID: CCB Seq. No.: 00035 A/S Pos.: 0R R 3 loQ ^ J12/21/92



ank Corrected Pk Area (A-s): 0.001centration (ug/L >: -1.04

Replicate 2 Time: 17:24Peak Area (A-s): 0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.024Blank Corrected Pk Area (.A-s): 0.002Concentration (ug/L ): 0.32

Mean Cone (ug/L ): 5=0736" -• SD: 0.958 - RSDC/.): 2&&.®®~

QC sample is within range -5.00 - 5.00

As ID: 1908357 3~AfAL-F Seq. No. : 00036 A/S Pos. : 12 Date: 12/21/92

Replicate 1 Time: 17:27Peak Area (A-s): -0.000 Peak Height (A): 0.008Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.030Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -1.59

Replicate 2 Time: 17:29Peak Area (A-s): -0.001 Peak Height (A): 0.005Bacl'.ground Pk Area (A-s): 0.018 Background Pk Height (A): 0.029ank Corrected Pk Area (A-s): -0.001centration (ug/L ): -2.30

Mean Cone (ug/L >: £7*94* SD: 0.500 RSD( 7.) : r25i 72~:

As ID: 1908357 3AMLp A Seq. No. : 00037 A/S Pos. : 12 Date: 12/21/92

Replicate 1 Time: 17:31Pf=ak Aren (A-s): 0.028 • Peak Height (A): 0.050Background Pk Area (A-s): 0.021 Background Pk Height (A): 0.034Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.36

^-r-Hcn+o r Time: 17:33Peal: Area <A s): 0.027 Peak Height (A): 0.051Background Pk Area (A-s): 0.021 Background Pk Height (A): 0.032Blank Corrected Pk Area (A-s): 0.027Concentration (ug/L ): 19.73

LANCASTER LABORATORIESGFAA - ASDATEflEC 11 1991

n Cone (ug/L ): '20.04 SD: 0.446 RSD (7.) T Ssf"

Recovery is 1B9»OK fo«>i? __ Jci:OtJ>

As ID: 1908358 Seq. No.: 00038 A/S Pos.: 13 Date: 12/21/92

R<-nlicnte 1 Time: 17:35 _& R 3 ! 9 0 2 2

As ID: 1908358 rf_JM|_,T Seq. No. : 00038 A/S Pos. : 13 Date: 12/21/92


Replicate 2 Time: 17:37Poah Aiea (A-s): 0.001 Peak Height (A): 0.008Background Pk Area (A-s): 0.021 Background Pk Height (A): 0.039Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -1.12

^ ,Mean Cone (ug/L ): <~1V68 "'" SD: 0.789 RSDC/.): 46.~98

Ac ID: 1908358 CHUL-T A Sec*- No' : 00039 A/s Pos- : 13 Date: 12/21/92

Replicate 1 Time: 17:40Pf-ak Area (A-s): 0.028 Peak Height (A): 0.056Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.040Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.67

Replicate 2 Time: 17:42Pr=ak Area (A-s): 0.027 Peak Height (A): 0.054Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.039Blank Corrected Pk Area (A-s): 0.027Concentration (ug/L ): 19.80

Mean Cone (ug/L ): 20.24 SD: 0.617 RSDC/.): 2f.*0i

Recovery in HrPy. b1/. "*

Ac ID: 1908359 CHULp Seq. No.: 00040 A/S Pos.: 14 Date: 12/21/92

'Replicate 1 Time: 17:44 ' .1 Peak Ar-p-n (A-s): -0.001 Peak Height (A): 0.0071 Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.030Bl-ank Corrected Pk Area (A-s): -0.001

I Concentration (ug/L ): -2.61i1 Replicate 2 Time: 17:46Peak Area (A-s): 0.001 Peak Height (A): 0.007

1 Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.029I Blank Corrected Pk Area (A-s): 0.001! Concentrnt icn <ug/L- — ) -:-~0; 74 ——t

Mean Cone (ug/L ): f la fitf T * SD: 1.324 RSDC/.): 78.94

I AVCASTER LABORATORIES -.- •-. LABORATORIESi AS

2 i ««„ DATE:REVIEWER

As ID: 1908359 Seq. No.: 00041 A/S Pos.: 14 „ Dt<jft-. U2X2 1/92„ pDpt<jft-. U2X

Ac ID: 1908359 Set*- Mo- : 0004* "' A/S Pos. : 14 Date: 12/21/y2

Replicate 1 , Time: 17:48Peak Area (A -a): 0.026 Peak Height (A): 0.052Background PI: Area (A-s): 0.021 Background Pk Height (A): 0.032lank Corrected Pk Area (A-s): 0.026centration (ug/L ): 18.71

^Bla

WReplicate 2. Time: 17:51Peak Area (As): 0.024 Peak Height (A): 0.055Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.032Blank Corrected Pk Area (A-s): 0.024Concentration (ug/L ): 17.39

Mean Cone (ug/L ): 18.05 SD: 0.930 RSDC/. ) :

Recovery is J?»/f 2-

An ID: 1908981 ">,fVC Seq. No. : 00042 A/S Pos. : 15 Date: 12/21/92

Replicate 1 Time: 17:53Peak Area (A-s): 0.000 Peak Height (A): 0.007Backqround Pk Area (A-s): 0.025 Background Pk Height (A): 0.045Plank. Corrected Pk Area (A-s)r 0.000Concentrat inn (ug/L ): -1.45

Replicate 2 Time: 17:55Pr-ak Area (A-s): -0.000 Peak Height (A).: 0.008Backqround Pk Area (A-s): 0.026 Background Pk Height (A): 0.042

«nk Corrected Pk Area (A-s): -0.000centratit'n (ug/L ): -1.87

Mean Cone (ug/L ): lT SD: 0.297 RSDC/.): 17.87

Ac ID: 1908981 t>P*VY^ Seq. No. : 00043 A/S Pos. : 15 Date: 12/21/92

Replicate 1 Time: 17:57Peak Area (A-s): 0.029 Peak Height (A): 0.052Background PI: Area (A-s): 0.026 Background Pk Height (A): 0.046Blank Corrected Pk Area (A-s): 0.029Concentration (ug/L ): 21.15 V

Replicate 2 Time: 18:00P~ak Aren (A-s): 0.028 Peak Height (A): 0.049Packground Pk Aren (A-s): 0.025 Background Pk Height (A): 0.043Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.74

Mean Cone (ug/L ): 20.94 SD: 0.290 RSD (%) : *TfS8>!S>..r,

Recovery is

As ID: 1908982 Seq. No. : 00044 A/S Pos. : 16 Date: 12/21/92

licite 1 Time: 18:02

GFAA -DATE-.DEC 2 i 1991

:. • _ u v t-j

As ID: 1908982 ~3"S6>FL Seq. No. : 00044 A/S Pos. : 16 Date: 12/21/92


LANCASTER LABORATORIESGFAA -DATE: KC 2 1 ML

Peak Area (A-s): -0.001 Peak Height (A): 0.006Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.030Blank. Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -1.98

Replicate 2 Time: 18:04Peak Area (As): 0.001 Peak Height (A): 0.006Packqround Pk Area (A-s): 0.017 Background Pk Height (A): 0.032Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.73

Mean Cone (ug/L ): -•!: 35:- ' SD: 0.886 RSDC/.): 65.54

As ID: 1908982 TSg»PL A Seq. No. : 00045 A/S Pos. : 16 Date: 12/21/92


Replicate 2 Time: 18:08Pp>ak Area (A-s): 0.027 Peak Height (A): 0.049Background Pk Area (A-s): 0.021 Background Pk Height (A): 0.034Blank Corrected Pk Area (A-s): 0.027Concentration (ug/L ): 19.40

Mean Cone (uq/L ): 20.08 SD: 0.956 RSDC/.):

Recovery ic -J-erfi%-"*"" "

Ac ID: CCV Seq. No. : 00046 A/S Pos. : 36 Date: 12/21/92


Replicate 2 Time: 18:13Peak Area (A-s): 0.064 Peak Height (A): 0.122Backqround Pk Area (A-s): 0.016 Background Pk Height (A): 0.027Plank Correct <->d Pk Area (A-s): 0.064 ,Concentration (ug/L ): 48.56 " •

Mean Cone (ug/L ): *?%fT4<iP~~~" ''- SD: 1.645 RSDC/. > :O7*47*"''"

QC sample is within range 45.00 - 55.00 a DO I O n o r- __• *~0t»A ho I 9025

----- . , _ », _, n rx „ i „ . ^ -> l->\


Replicate 1 Time: 18:15Peak Area (A-s): 0.002 Peak Height (A): 0.006Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.022*k Corrected Pk Area (A-s): 0.002

entration (ug/L ): -0.04

LANCASTER LABORATORIESGFAADATE: tK 2 1J992REVIEWER «*-

Rerlicate 2 Time: 18:17Pn-ih Area (A-c): -0.002 Peak Height (A): 0.007Background Pk Area (A-c): 0.013 Background Pk Height (A): 0.022Blank Corrected Pk Area (A-s): -0.002Concentration (ug/L ): -2.98

~Moan Cone (uq/L ): ft-VSl SD : 2.076 RSDC/. ): "137. 45

r-.J '*, . -_


As ID: 19P8983 CR^M- Seq. No.: 00048 A/S Pos.: 17 Date: 12/21/92

Replicate 1 Time: 18:19Peak Area (A-s): 0.000 Peak Height (A): 0.005Backqround Pk Area (A-s): 0.023 Background Pk Height (A): 0.035

sk Corrected Pk Area (A-s): 0.000|entration (ug/L ): -1.23

Replicate 2 Time: 18:21P^ak Area (A-s): -0.001 Peak Height (A): 0.007Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.037Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -2.58

Mean Cone (ug/L ): -li. 91>" SD: 0.956 RSDC/.): 50.12

Ac ID: 19<?8983 CRCH~ A Seq> No' : 00049 A/s Pos' ! 17 Date: 12/21/92

Replicate 1 Time: 18:24Pr-ak Area (A-c.): 0.028 Peak Height (A): 0.050Ba^kqround PI: Area (A-s): 0.024 Background Pk Height (A): 0.039Elan): Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.27

Replicate 2 Time: 18:26Peak Area (A-c): 0.024 Peak Height (A): 0.049Background Pk Area (A-s): 0.022 Background Pk Height (A): 0.036Blank Corrected Pk Area (A-s): 0.024Concentration (ug/L ): 17.67

Cone (uo/L ): 18.97 SD: 1.842 RSD C/.) : '9T71 > _

~~" •>A'"3I1 3 _. f -Vff

As ID: 19F3984 Seq. No.: 00050 A/S Pos.: 18 Date: 12/21/92flR3i9026n^ni i r--, i Time: 18:28

Recovery is '1•»*'

ID: 1908984 ZrU Seq. No. : 00050 A/S Pos. : 18 Date: 12/21/92

Replicate 1 Time: 18:28Peak Area (A-s): -0.001 Peak Height (A): 0.006Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.027Blank Corrected Pk Area (A-s): -0.001

on (ug/L ): -2.28

Replicate 2 Time: 18:30Peak Area (A-s): -0.001 Peak Height (A): 0.006Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.028Plank Corrected Pk Area (A-s): -0.001

LANCASTER LABORATORIESGFAADATE: WC 2 i 1992REVIEWER

Concentration (ug/L ): 227"'

Mean Cone (ug/L ): -2.28 SD : 0.004 RSDC/.): 0.16

Ac ID: 1908984 CRCHF A Seq. No. : 00051 A/S Pos. : 18 Date: 12/21/92



Mean Cone (uq/L ): 18.31 SD : 0.713 RSDC/.):

Recovery in "

Ac ID: 1978985 CRTF6 Seq. No. : 00052 A/S Pos. : 19 Date: 12/21/92

Replicate 1 Time: 18:37P^ak Aren (A-c): -0.000 Peak Height (A): 0.006Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.022Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -1.89

R<->pli«-a*e 2 Time: 18:40PO=JU Area (A-s): 0.001 Peak Height (A): 0.007Background Pk Area (A-u): 0.014 Background Pk Height (A): 0.025Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -1.03

Moan Cone (ug/L ): -1746* "SD: 0.607 RSDC/.): 41,

Ac ID: l o.gSS Seq. No. : 00053 A/S Pos. : 19 Date: 12/21/92

R-plicnte 1 Time: 18:42 ft R 3 1 9 (12 ? 206r- -,->!. Ar-or, < A - n > : O. 025 Peak Height (A): 0.049

A3 ID: 1908985 CKTF0 A Seq' No' : 00053 A/S Pos. : 19 Date: 12/21/92


#nk Corrected Pk Area (A-s): 0.025centration (ug/L ): 17.93

Replicate 2 Time: 18:44Peak Area (A-s): 0.025 Peak Height (A): 0.048Backqround Pk Area (A-s): 0.017 Background Pk Height (A): 0.024Blank Corrected Pk Area (A-s): 0.025Concentr a tion -( ug/L ): 18. 21 ~

Mean Cone (ug/L ): 18.07 SD: 0.197 RSDC/.):

Recovery is WP-fe* 30,l{ *&

; LANCASTER LABORATORIESGFAADATE'-rp 2 1 1991REVI

As ID: 1908986 3"SBMT Seq. No. : 00054 A/S Pos. : 20 Date: 12/21/92

Replicate ] Time: 18:46Peak Area (A-s): 0.002 Peak Height (A): 0.008«kground Pk Area (A-s): 0.026 Background Pk Height (A): 0.044


Roplicate 2 Time: 18:49Peak Area% (A-s): -0.000 Peak Height (A): 0.011Background Pk Area (A-s): 0.028 Background Pk Height (A): 0.048Blnnk Correr-ted Pk Area (A-s): -0.000Concentration (ug/L ): -1.88

J* _. •„Mean Cone (ug/L ): '•0789'"* SD: 1.395 RSDC/.): 156.35

As ID: 1908986 JSBMT A Seq. No.: 00055 A/S Pos.: 20 Date: 12/21/92

Replicate 1 Time: 18:51Peak Area (A-s): '0.028 Peak Height (A): 0.051Background Pk Area (A-s): 0.029 Background Pk Height (A): 0.048Blank Corrected Pk Area (A-s): 0.028Concentration (ug/L ): 20.23


n Cone (ug/L >: 20.51 SD: 0.399 RSDC/.): -rr95* "Vs

in 4-®3Ca*

ID: 1008987 Seq. No. : 00056 A/S Pos. :"24« » ->ttaC.e3 12/21/92

As ID: 1908987 rTAMTF Seq. No. : 00056 A/S Pos. : 21 Date: 12/21/92

Replicate 1 Time: 18:55Peak Area (A-s): 0.000 Peak Height (A): 0.007Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.000'Concentration (ug/L ): -1.30

Replicate 2 Time: 18:58Peak Area (A-s): 0.000 Peak Height (A): 0.008Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.030Plank Corrected Pk Area (A-s): 0.000Concentration (ug/L >: -1.20

Mean Cone (ug/L ): -iY23''-~' SD: 0.071 RSDC/.): 5.64

As ID: 1908987 Jg,/V\fF A Seq- No' : 00057 A/s Pos. : 21 Date: 12/21/92


LANCASTER LABORATORIESGFAADATE9-C-

Blank Corrected Pk Area (A-s): 0.026 REVIEWER T*"-*"7 yConcentration (ug/L ): 19.11

Replicate 2 Time: 19:02Peak Area (A-s): 0.025 Peak Height (A): 0.051Backqround Pk Area (A-s): 0.021 Background Pk Height (A): 0.034Blank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 17.93

Mean Cone (ug/L ): 18.52 SD: 0.830 RSDC/.):

Recovery is



Replicate 2 Time: 19:07Peal: Area (A-s): 0.059 Peak Height (A): 0.125Backqround Pk Area (A-s): 0.019 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.059Concentration (ug/L ): 44.50

Mean Cone (ug/L ): 46£37 , , SD: 2. 646 RSDC/.):

QC cample is within range 45.00 - 55.00 • —

ID: CCB Seq. No.: 00059 ' A/S PosT? J1^ « -*u &a-te: 12/21/9'.


Replicate 1 Time: 19:09Peak Area (A-s): 0.001 Peak Height (A): 0.008Backqround Pk Area (A-s): 0.017 Background Pk Height (A): 0.026FUank Corrected Pk Area (A-s): 0.001

centration (ug/L ): -1.01

P plicate 2 Time: 19:11P^-tak Area (A-s): 0.000 Peak Height (A): 0.007Packqround Pk Area (A-s): 0.015 Background Pk Height (A): 0.022Blank Corrected Pk Area (A-s):. 0.000Concentration (ug/L ): -1.41

Mean Cone (uq/L ): fyxx*-. SD. 0> 284 RSDC/.): 23.54'"

OC sample is within range -5.00 - 5.00

As ID: 1908988 Cl-l|2.t?M Seq. No. : 00060 A/S Pos. : 22 Date: 12/21/92

P»plicate 1 Time: 19:13Peak Area (A-s): 0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.028 Background Pk Height (A): 0.044Blank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): -0.22

UWCAGTER LABORATORIESGFAA

« D A T E : D E C 2 1 W lREVIEWER

.....licate 2 Time: 19:16Peak Area (A--s): -0.001 Peak Height (A): 0.006Backqround Pk Area (A-s): 0.027 Background Pk Height (A): 0.042Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -2.36

Mean Cone (ug/L ): j"lT2§TT - SD: 1.515 RSDC/.): 117i 48

Ac ID: 1903988 Cf-lr^fA A Seq. No. : 00061 A/S Pos. : 22 .Date: 12/21/92

1 Time: 19:18Prak Area (A-s): 0.028 Peak Height (A): 0.049Backqround Pk Area (A-s): 0.029 Background Pk Height (A): 0.044Blank Corrected Pk Area (A-s): 0.027Concentration (ug/L ): 20.06

Replicate 2 Time: 19:20Peak Area 'A-s): 0.026 Peak Height (A): 0.051Background PI: Area (A-s): 0.030 Background Pk Height (A): 0.044Blank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 19.25

n Cone (ug/L ): 19.66 SD: 0.574 RSDC/.):'"2.-92"i

^^ o v e r y i r 4r9

ID: 1900989 Seq. No. : 00062 A/S Poe. : 23 Date: 12/21/92flR3l903(0

rato ! Time: 19:22 \

Ac ID: 1908989 UDnP Seq. No. : 00062 A/S Pos. : 23 Date:

Replicate 1 Time: 19:22Peak Area (A~s): 0.000 Peak Height (A): 0.009Backqround Pk Area (A-s): 0.017 Background Pk Height (A): 0.029Plank Corrected Pk Area (A-s): 0.000^oncerit ration (ug/L ) : -1.41

Replicate 2 Time: 19:25n°ak Area (A-s): -0.002 Peak Height (A): 0.005Backqround Pk Area (A-s): 0.021 Background Pk Height (A): 0.027Blank Corrected Pk Area (A-s): -0.002concentration (ug/L ): -2.86

Mean Cone (ug/L ): "f 2"T3J«, . SD: 1.021 RSDC/.): 47.89•t'

As ID: 1 08989 f UODf- /\ Set?- No« : 000S3 A/S Pos. : 23 Date: 12/21/92


Replicate 2 Time: 19:29Peak Area (A-s): 0.026 Peak Height (A): 0.048Backqround Pk Area (A-s): 0.020 Background Pk Height (A): 0.030Plank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 18.80 LANCASTER LABORATORIES

GFAA - ADATE'JJ.C I i mREVIEWER 7* 777

Mean Cone (ug/L ): 17.87 SD: 1.311

Recovery ic.

As ID: 1908990 Seq. No. : 00064 A/S Pos. : 24 Date: 12/21/92

Replicat" I Time: 19:32Peak Area (A-er): -0.002 Peak Height (A): 0.006Backgi ound Pk Area (A-s): 0.025 Background Pk Height (A): 0.039Plank Corrected Pk Area (A-s): -0.002Concentrat ion (ug/L ): -2.95

Replicate 2 Time: 19:34Peak Area 'A-s): 0.002 Peak Height (A): 0.007Packgnund Pk Area (A-s): 0.023 Background Pk Height (A): 0.036Plank Corrected Pk Area (A-s): 0.002^onc^nt r a t i r >n (ug/L ): -0.09

Mean Cone (ug/L ): ^1~ S'g" ""'•"• SD: 2.026 - RSDC/.): 13

A^ It1: 1 CT08990 Seq. No. : 00065 A/S Pos. : 24 Date: 12/21/92

Replicate 1 Time: 19:36 fl n Q I Q-fi-Q \' '"&*P*>ak Area (A-s): 0.027 Peak Height (A): 0. 048W n J ' "^ U ° '

ID: 1908990 -rcai Seq' No' : 00065 A/s Pos- : 24 Date: 12/21/92

Replicate 1 Time: 19:36Peak Area (A-s): 0.027 Peak Height (A): 0.048Packqround Pk Area (A-c): 0.025 Background Pk Height (A): 0.040

ril: Corrected Pk Area (A-s): 0.027ntration (ug/L ): 19.41

R'-plicate 2 . Time: 19:38Pr.gk Area (A-s): 0.025 Peak Height (A): 0.049Packqround Pk Area (A-s): 0.027 Background Pk Height (A): 0.038B.I ank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 18.44

Mean Cone (ug/L ): 18.92 SD: 0.682 RSDC/. )T~3r60"

Recovery is

Ac ID: 1908991 JCftLF Seq* N°'! 00066 A/S Pos- J 25 Date: 12/21/92

Replicate 1 . _ _. ____.._—— — - Time: 19:41P-ak Area (A-s): -0.001 Peak Height (A): 0.006Backqround PI: Area (A-s): 0.022 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -1.97

Time: 19:43Pf=ak Area (A-s): -0.000 Peak Height (A): 0.005Packqround PI: Area (A-s): 0.020 Background Pk Height (A): 0.029

Corrected Pk Area (A-s): -0.000-): -1;70 —

Mean Cone (ug/L ): -jl..'84 SD: 0.191 RSDC/.): 10.41

LANCASTER LABORATORIESGFAA AS 2?DATE: DEC & 11**REVIEWER 7

Ac ID: 1109991 "TSBl-F A\ Se<l- No- : ®®067 A/S Pos. : 25 Date: 12/21/92

Replicate 1 Time: 19:45Peak Area (A-c.): 0.027 Peak Height (A): 0.049Ptckqround PI: Area (A-s): 0.021 Background Pk Height (A): 0.032Blank Corrected Pk Area (A-s): 0.027Concent:ntion (ug/L ): 19.54

Replicate 2 Time: 19:47Pon): Area (A c): 0.026 Peak Height (A): 0.048Packqround Pk Area (A-E?): 0.020 Background Pk Height (A): 0.034

k Corrected Pk Area (A-s): 0.026^ntration (ug/L ): 19.16

v.-an. ,-Mean Cone (ug/L ): 19.35 SD: 0.271 RSD(X): 1.40

Recovery is M6. W. 0,% ._ ^

Ac ID: 1908992 f;Rf-|L"T s®q. No.: 00068 A/S Pos.: 26 Date: 12/21/92

Replicate 1 ' Time: 19:49Peak Area (A-s): 0.001 Peak Height (A): 0.008Background Fk Area (A-s): 0.025 Background Pk Height (A): 0.039Plank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.86

Replicate? 2 Time: 19:52Peak Area (A-s): 0.002 Peak Height (A): 0.008Background Pk Area (A-s): 0.024 Background Pk Height (A): 0.040Plank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): 0.25

Mean Cone (ug/L ): -aTscT 1 SD: 0.786 RSD(%): 260.90

As ID: 1908992 CRHLT A Se(3- No- : O®®&9 A/S Pos.: 26 Date: 12/21/92

Replicate 1 Time: 19:54Poak Area (A-s): 0.025 Peak Height (A): 0.052Packqround Pk Area (A-s): 0.027 Background Pk Height (A): 0.042PLank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 18.09


Mean Cone (ug/L ): 19.26 SD: 1.656 RSD C/. ) :-,...._- <

Recovery is _3Ss=fi3fo—

Ac ID: CrV Seq. No. : 00070 A/S Pos. : 36 Date: 12/21/92i

Replicate 1 Time: 19:58LANCASTER LABORATORIESGFAA AS M o 2_DATE-.BEC 2 1 \W

Peal: Area (A-s): 0.059 Peak Height (A): 0.127Background Pk. Area (A-s): 0.020 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.059Concentration (ug/L ): 45.16


™""Mr-nn Cone 'ug/L ): (45.34 SD: 0.256 RSDC/.):

'.y. rra»'ple i-. within range 45.00 - 55.00 _.

Ac ID: CCB Seq. No.: 00071 A/S Pos.: 0 A R Salt 3:032321/92


Replicate 1 Time: 20:03Peak Area (A-s): 0.001 Peak Height (A): 0.007Packqround Pk Area (A-s): 0.015 Background Pk Height (A): 0.021«r.k Corrected Pk Area (A-s): 0.001

centration (ug/L ): -0.58

R-plicate 2 Time: 20:05P"ak Area (A-s): 0.001 Peak Height (A): 0.007Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.025Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.59

Mean Cone (ug/L ): -0rS8: >--' SD : 0.006 RSDC/.): 0.95

OC sample is within range -5.00 - 5.00

As ID: 1908993 Se9- No' : 00072 A/s Pos. : 27 Date: 12/21/92


Replicate 2 Time: 20:09Peak Area (A-s): -0.002 Peak Height (A): 0.007Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.029«nk Corrected Pk Area (A-s): -0.002

centration (ug/L ) : -2. 89j__,«w

Mean Cone (ug/L ): .73 SD : 0.225 RSDC/.): 8.22

ID: 1908993 ^ - J F Seq> No' : 00073 A/S Pos.: 27 Date: 12/21/92

R<=plicat<=> 1 Time: 20:11Peak Area (A-s): 0.025 Peak Height (A): 0.051Packqround Pk Area (A-s): 0.021 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.025concentration (ug/L ): 18.38

LANCASTER LABORATORIESGS:AA - . ASDATE: DEC 2 i 1992REVIEWERReplicate 2 _ Time: 20:14

Pr>ak Area (A-n): 0.025 Peak Height (A): 0.049Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 17.82

f r f'-iffl \t0(r"

n Cone (uq/L ): 18.10 SD: 0.396 RSDC/.): '2. 18

>•;-.-. c o v e r y i c

As ID: CCV Seq. No.: 00074 A/S Pos.: 36 Date: 12/21/92

nopu^-jto 1 Time: 20:16

i Time: 20:11Pc-.nk Area (A-s): 0.025 Peak Height (A): 0.051Backqround Pk Area (A-s): 0.021 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 18.38

LANCASTER LABORATORIESGS-AA - AS 3 2-DATE: DEC 2 i 1992

n , . , ™ ,„ REVIEWER7^-7VyReplicate 2 Time: 20:14 /Peak Area (A-a): 0.025 Peak Height (A): 0.049 .Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.031Blank Corrected Pk Area (A-s): 0.025Concentration (ug/L ): 17.82

Mean Cone (uq/L ): 18.10 SD : 0.396 RSDC/.): 2.18

Recovery is 104.'2Xrr ^(0 > /£

As: ID: CCV Seq. No. : 00074 A/S Pos. : 36 Date: 12/21/92


Replicate 2 Time: 20:18Peak Area (A-s): 0.059 Peak Height (A): 0.122Backqround Pk Area (A-s): 0.020 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.059Concentration fug/L ): 44.79

Mean Cone (uq/L ): ,-45r<B3 -=T SD: 0.342 RSD(y.): 0.76

OC sample ic within range 45.00 - 55.00


Replicate 1 Time: 20:20Peal: Area (A-c): 0.002 Peak Height (A): 0.008Backqround Pk Area (A-s): 0.016 Background Pk Height (A): 0.026Blank Corrected Pk Area (A-s): 0.002Concentration (ug/L ): -0.12

Replicate 2 Time: 20:22Peak Area (A-s>: 0.000 Peak Height (A): 0.007Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.023Blank Corrected Pk Area (A-s): 0.000Concentration 'ug/L ): -1.33

Mean Cone (uq/L ): •'0.~72~*1"* SD: 0.860 RSDC/.): '1~18. "JA

QC cample is within range -5.00 - 5.00

8R3I9035

V ca. irietrT. SE^oot^AA. 3OO/4OOProtocol Repor

OPERATOR EAF 809 3812 BZDATE MON 21 DEC 1992BATCH Pb 9235604

QC PROTOCOL PARAMETERS LANCASTER LABORATORIESINSTRUMENT ID #381 2

TF THERE IS AN ERROR STOP BKG C^RR' BZQC SPIKE POSITION 52 ^RECOVERY LIMITS (%) 85 TO 115RECOVERY MINIMUM LIMIT (%) 40CORRELATION COEFFICIENT (r) 0.995OVERRAMGE VOLUME REDUCTION 1REPLICATE RSD LIMIT (%) 100.0

PROGRAM 3 Pb CLP

INSTRUMENT MODE ABSORBANCECALIBRATION MODE CONCENTRATIONMEASUREMENT MODE PEAK AREALAMP POSITION 6LAMP CURRENT (mA) 5SLIT WIDTH (nm) 0.5SLIT HEIGHT NORMALWAVELENGTH (nm) 283.3SAMPLE INTRODUCTION SAMPLER AUTOMIXINGTIME CONSTANT 0.05MEASUREMENT TIME (sec) 1.0REPLICATES 2BACKGROUND CORRECTION ONMAXIMUM ABSORBANCE 1.40

FURNACE PARAMETERSSTEP TEMPERATURE TIME GAS FLOW GAS TYPE READNO. (C) (sec) (L/min) COMMAND

1 220 20.0 3.0 NORMAL NO2 220 10.0 3.0 NORMAL NO3 500 20.0 3.0 NORMAL NO4 900 20.0 3.0 NORMAL NOf, 900 15.0 3.0 NORMAL NOtf 100 4.5 3.0 NORMAL NO7 100 2.0 3.0 NORMAL NO8 100 2.0 0.0 NORMAL NO9 2400 1.2 0.0 NORMAL YES10 2400 2.0 0.0 NORMAL YES11 2500 0.2 3.0 NORMAL NO12 2500 3.0 3.0 NORMAL NO13 100 12.9 3.0 NORMAL NO4 100 2.0 3.0 NORMAL NO

/IR3 19636'

SAMPLER PARAMETERSVOLUMES (/L)

SOLUTION BLANK MODIFIER

BLANK -- 30 6STANDARD 1 3 27 6STANDARD 2 6 2 4 6STANDARD 3 15 15 6STANDARD 4 24 6 6STANDARD 5 30 0 6SAMPLE 30 0 6

RECALIBRATION RATE 0RESLOPE RATE 0

MULTIPLE INJECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE 95INJECT RATE 8

QC PROTOCOL PARAMETERS LANCASTER LABORATORIES

QC STANDARD RATE 20 GFAA y "-- PB ^ ^QC INITIAL STANDARD POSITION 50 DATE: "EC 2 1 1992QC INITIAL BLANK POSITION 51 REVIEWERQC CONTINUING STANDARD POSITION 50QC CONTINUING BLANK POSITION 51QC STANDARD VOLUME (fl) 30QC STANDARD CONCENTRATION 20.00 PPBQC STANDARD LIMITS (%) 90 TO 110QC SPIKE RATE 1QC SPIKE VOLUME (/L) 12QC SPIKE CONCENTRATION 50.00 PPBMATRIX SPIKE CONCENTRATION 0.00 PPBINSTRUMENT DETECTION LIMIT 0.60 PPBREQUIRED DETECTION LIMIT 3.00 PPB

SAMPLE CONC 2RSD MEAN READINGSPPB ABS

BLANK 0.00 0.000 0.003 -0.003QC 21Dec92 12:20^ - CONCENTRATION LESS THAN IDL

STANDARD 1 5.00 9.7 0.026 0.028 0.025QC - rr 21Dec92 12:26

51(7STANDARD 2 10.00 0.9 0.054 0.053 0.054QC , 21Dec92 12:33

STANDARD 3 25.00 0.7 0.127 0.128 0.127QC ^>Ufr 21Dec92 12:40

J^*> DATA VERIFIEDSTANDARD 4 40.00 0.0 0.187 0.187 0.187 tji/rru AM v ov. -rrrinQC -or 21Dec92 12:46 VWIIHMIM A BY. £^K

STANDARD 5 50.00 0.3 0.221 0.220 0.221QC 21Dec92 12:53

HR3I9037

SAMPLE CONC %RSD MEAN READINGSPPB ABS

ICV 20.73 2.7 0.107 0.109 0.105QC 21Dec92 12:59

%R = 103.7

ICB -0.21 99.9 -0.001 0.001 -0.003QC '21Dec92 13:05

ABS = -0.001CONCENTRATION LESS THAN IDL

CRA 2.79 10.8 0.015 0.014 0.0168CCK(XA 21Dec92 13:12

QCSPIKE A 23.26 0.7 0.119 0.120 0.119QC 21Dec92 13:19

—— - —— LANCASTER LABORATORIESCCV 1 20.45 2.9 0.106 0.104 0.108 GFAA r** PB 3_T2-'«'QC 21Dec92 13:25 DATE: DEC 2 1 1992

%R = 102.3

CCB 1 -0.39 99.9 -0.002 0.000 -0.004QC . 21Dec92 13:31

ABS = -0.002_, _, I 2 1 I CONCENTRATION LESS THAN IDL

1904005/200 13.60 2.0 0.072 0.071 0.073C l-t>l 222 27 t 21Dec92 13:38

JSPIKE A 33.37 0.8 0.162 0.161 0.163C 21Dec92 13:45

%R = 98.8

PBW 354 021 -0.27 99.9 -0.001 -0.000 -0.003QC . 21Dec92 13:51^ . CONCENTRATION LESS ThVAN IDLVtyj J*

QCSPIKE A 20.47 0.2 0.106 0.106 0.106QC 21Dec92 13:58

%R = 102.4

LCSW/354 021 20.79 1.6 0.107 0.106 0.109QC 21Dec92 14:04

QCSPIKE A 41.91 0.8 0.194 0.195 0.193OC 21Dec92 14:11

%R r 105.6

190835U 2.87 13.2 0.015 0.017 0.014QC > N 21Dec92 14: 17

QCSPIKE A 20.59 1.0 0.106 0.107 0.106QC 21Dec92 14:24

/• .. < . VR _ QO Rl |\ \A\ A\ V Sol\ — OO.D

. 8351 -0.34 75.8 -0.002 -Q.001 -0.003QC 21Dec92 14:30 f -J?

CONCENTRATION LESS THAN IDL

flR3J9038

SAMPLE CONC %RSD MEAN READINGS

PPBQCSPIKE A 18.06 1.2 0.094 0.095 0.093QC 21Dec92 14:37

%R = 90 . 3

CCV2 21.03 '2.4 0.109 0107 0110 UMCASTER UBORATORIB%R = 105.1 GFAA r~ - F0

———— DATE: fl_C2_,992CCB 2 -0.63 60.6 -0.003 -0.002 -0.005 REVIEWERQC 21Dec92 14:50

ABS = -0.0035 AA<NK^ CONCENTRATION LESS THAN IDL

19U8352R 20.08 1.4 0.104 0.103 0.105QC *Zl±ii 21Dec92 14:56

QCSPIKE A 39.08*- 2.2 0.184 0.181 0.187QC •• 21Dec92 15:03

%R = 95-°1908353D 5.81 0.3 0.031 0.031 0.031

21Deo92 15:09QCSPIKE A 23.46 0.2 0.120 0.120 0.120QC 21Dec92 15:16

v %R =1908354 -0.27 40.6 -0.001 -0.001 -0.002QC A 21Dec92 15:22


QCSPIKE A 18.46 1.7 0.096 0.095 0.097QC 21Dec92 15:29

1908555- ^ -0.56 19.8 -0.003 -0.003 -0.003QC »*,-,-. 21Dec92 15:35

~* L z * * CONCENTRATION LESS THAN IDL

QCSPIKE A '21.25 0.2 0.110 0.110 0.109QC 21Dec92 15:42

%R =1908356 2.22 17.1 0.012 0.010 0.013QC 21Dec92 15:48

QCSPIKE A 20.87 0.1 0.108 0.108 0.108QC 21Dec92 15:55

%R = 93.2

CCV 3 21.82 1.3 0.112 0.111 0.113QC 21Dec92 16:01

%R = 109.1

CCB 3 -0.10 99.9 -0.001 0.001 -0.003 _.QC 21Dec92 16:07 __

ABS = -0.001CONCENTRATION LESS TH$lftI$Ij g Q 3 g

Vs. r-ian SE^eotrAA 3OQ/4OO Z&&m<5J.C fPirotoool ReE^oart

OPERATOR NSM 823 3812 BZDATE MON 21 DEC 1992BATCH Pb 9235605

QC PROTOCOL PARAMETERS

IF THERE IS AN ERROR STOPQC SPIKE POSITION 52RECOVERY LIMITS (%) 85 TO 115RECOVERY MINIMUM LIMIT (%) 40CORRELATION COEFFICIENT (r) 0.995OVERRANGE VOLUME REDUCTION 1REPLICATE RSD LIMIT (%) 100.0

PROGRAM 3 Pb CLP

INSTRUMENT MODE ABSORBANCECALIBRATION MODE CONCENTRATIONMEASUREMENT MODE PEAK AREALAMP POSITION 6LAMP CURRENT (mA) 5SLIT WIDTH (nm) 0.5SLIT HEIGHT NORMALWAVELENGTH (nm) 283.3SAMPLE INTRODUCTION SAMPLER AUTOMIXINGTIME CONSTANT 0.05MEASUREMENT TIME (sec) 1.0REPLICATES 2BACKGROUND CORRECTION ONMAXIMUM ABSORBANCE 1.40


1 220 20.0 -3.0 NORMAL NO2 220 10.0 3.0 NORMAL NO3 500 20.0 3.0 NORMAL NO4 900 20.0 3.0 NORMAL NO5 900 15.0 3.0 NORMAL NO6 100 4.5 3.0 NORMAL NO7 100 2.0 3.0 NORMAL NO8 100 2.0 0.0 NORMAL NO9 2400 1.2 0.0 NORMAL YES10 2400 2.0 0.0 NORMAL YES11 2500 0.2 3.0 NORMAL NO12 2500 3.0 3.0 NORMAL NO13 100 12.9 3.0 NORMAL NO14 100 2.0 3.0 NORMAL NO

f- -

SAMPLER PARAMETERSVOLUMES (/L)


BLANK — 30 6STANDARD 1 3 27 6STANDARD 2 6 24 6STANDARD 3 15 15 6STANDARD 4 24 6 6STANDARD 5 30 0 6SAMPLE 30 0 6

RECALIBRATION RATE 0RESLOPE RATE 0

MULTIPLE INJECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE 95INJECT RATE 8


QC STANDARD RATE 20QC INITIAL STANDARD POSITION 50QC INITIAL BLANK POSITION 51QC CONTINUING STANDARD POSITION 50QC CONTINUING BLANK POSITION 51QC STANDARD VOLUME (fL) 30QC STANDARD CONCENTRATION 20.00 PPBQC STANDARD LIMITS (%) 90 TO 110QC SPIKE RATE 1 DATA VERIFIEDQC SPIKE VOLUME (/L) 12 WITH AM Y nV.QC SPIKE CONCENTRATION 50.00 PPB VVIin/MMAbY.MATRIX SPIKE CONCENTRATION 0.00 PPBINSTRUMENT DETECTION LIMIT 0.60 PPBREQUIRED DETECTION LIMIT 3.00 PPB


BLANK 0.00 -0.003 -0.002 -0.004QC 21Dec92 '18:08-^ CONCENTRATION LESS THAN IDL

STANDARD 1 5.00 3.0 0.029 0.029 0.028QC <^fr 21Dec92 18:15

10.00 1.4 0.057 0.058 0.056QC /- 21Dec92 18:22

STANDARD 3 25.00 0.3 0.131 0.130 0.131 LANCASTER LARnpAiv-m.rv21Dec92 18:28 QFAA ^DU"ArORltl

STANDARD 4 40.00 0.4 0.191 0.190 0.191 °ATE: • v^22\^21Dec92 18:35

STANDARD 5 50.00 0.9 0.225 0.224 0.227QC 21Dec92 18:41

4

____-.. t

ftR3l90l*

SAMPLE CONC 2RSD ME*AN READINGS

20.69 1.8 0.111 0.113 0.110QC ' 21Dec92 18:48

%R = (103. j \

1CB 0.43 91.4 0.002 0.004 0.001QC 21Dec92 18:54

ABS = 0.002 .CONCENTRATION LESS THAN IDL

CRA 3.15 1.2 0.018 0.018 0.0189( CfsAA 21Dec92 19:00QCSPIKE A 23.60 0.3 0.125 0.125 0.124QC 21Dec92 19:07

%R = 102.3

CCV 1 20.16 2.9 0.109 0.107 0.111 . ...„.„-._.-.,__.«-,* n.,QC 21Dec92 19:14 LANCASTER LABORATORU*R - 7100.. J \GFAA PB

^- -'DATE- DEC 2 2 1992CCB 1 0.13 99.9 0.001 0.002 -0.001 De%/Ir.'IJIf.-DQC 21Dec92 19:20 REVIEWER

ABS = -0.000& CONCENTRATION LESS THAN IDL

1908357 0.20 17.3 0.001 0.001 '0.001QC 2lDec92 19:26

CONCENTRATION LESS VHAtf IDL

CSPIKE A 16.82 1.5 0.093 0.094 0.092QC H 21Dec92 19:33

%R = 84.1SAMPLE COW<50% OF SPIKE CONCENTRAT1

1908358 3.02 4.1 0.017 0.018 0.017QC ^ 21Dec92 19:39

QCSPfKE A 20.66 1.2 0.111 0.112 0.110QC 21Dec92 19:46

1908359 0.33 9.0 0.002 0.002 0.002QC 21Dec92 19:52

V CONCENTRATION LESS WN IDL

QCSPIKE A 18.25 1.0 0.100 0.099 0.101QC 21Dec92 19:59

*R = 91.2

1908981 3.61 3.6 0.021 0.020 0.021Qf 6 \Vi41"/> 21Dec92 20:06QCSPIKE A 20.48 1.8 0.111 0.109 0.112C W 21Dec92 20:12

%R = 84.4SAMPLE CONC <50* OF SPIKE CONCENTRAT,

A R3J

PPB ABS

1908982 . 0.63 29.7 0.004 0.003 0.00421Dec92 20:19

C \f'f?f>A

QCSPIKE A 17.59 0.9 0.097 0.096 0.097QC W 21Dec92 20:25

%R = 84.8SAMPLE COfiC <50% OF SPlfcE CONCENTRATION

CCV 2 20.76 1.3 0.112 0.111 0.113QC 21Deo92 20:32 LANCASTER LABORATORIES

CCB 2 0.18 99.9 0.001 0.003 -0.001 °ATE: DE C 2 2QC 21Dec92 20:38 REVIEWER *?ABS = o.ooo /


1908983 4.03 4.0 0.023 0.023 0.02421Dec92 20:44

QCSPIKE A 21.92 0.9 0.117 0.116 0.118QC 21Dec92 20:51

1908984 0.42 34.1 0.002 0.003 0.002QC 21Dec92 20:57f V CA\? A CONCENTRATION LESS\ THAX IDL

QCSPIKE A 18.29 0.2 0.100 0.100 0.100QC 21Dec92 21:04

%R = 91.4

1908985 0.21 69.8 0.001 0.002 0.001QC 21Dec92 21:10

CONCENTRATION LESS TfiAljK IDL

QCSPIKE A 21.16 0.6 0.114 0.114 0.113QC 21Dec92 21:17

1908986 3.57 3.5 0.021 0.021 0.02021Dec92 21:23

QC!SPIKE A 20.34 0.4 0.110 0.110 0.110QC H 21Dec92 21:30 lYl

XR = 83.8 (SAMPLE CONC <50% OF SPIKE CONCENTRATIO

1908987 0.08 99.9 0.000 0.001 -0.000QC 21Dec92 21:36

CONCENTRATION LESS\THAN/EDL

QCSPIKE A 17.26 1.1 0.095 0.096 0.094QC 21Dec92 21:43

XR = 86.3

CCV 3 20.88 1.0 0.112 0.112 0.113QC 21Dec92 21: 50

%R = I 104.V


CCB 3 0.09 99.9 0.001 0.002 -0.001QC 21Dec92 21:56

ABS - -0.000CONCENTRATION LESS THAN IDL

iytf8988 7.60 0.9 0.044 0.043 0.04421Dec92 22:02

QCSPIKE A 25.70 0.5 0.134 0.133 0.134QC 21Dec92 22:09

___

1908990 5.43 0.7 0.031 0.031 0.031QC / « 21Dec92 22:28

QCSPIKE A 23.44 1.2 0.124 0.125 0.123QC 21Dec92 22:35

%R = 90.0

1908991 0.13 99.9 0.001 0.001 .0.00021Dec92 22:41

fcf/A CONCENTRATION LESS TH^N IDL

QCSPIKE A 17.70 3.1 0.097 0.095 0.099QC . 21Dec92 22:48

*K = 88. 5

1900992 7.40 2.0 0.042 0.042 0.043. 21Dec92 22:55

QCSPIKE A 26.02 0.4 0.135 0.135 0.135QC 21Dec92 23:02

%R = 93.L

CCV 4 21.47 1.1 0.115 0.114 0.116QC 2lDec92 23:08 LANCASTER LABORATORIES

%R = 7 107 .j )QFAA PE- DATE- DEC 2 2 1992CCB 4 -0.06 99.9 -0.000 0.001 -0.001 UMIC-

QC 21Dec92 23:14 REVIEWERABS = -0.001

^ .* ., 5- CONCENTRATION LESS THAN IDL

19(18993 0.59 17.2 0.003 0.003 0.004QC 21Dec92 23:21

CONCENTRATION LESS

SPIKE A 19.10 0.4 0.104 0.104 0.104QC 21Dec92 23:27

%R = 95.5

A R-3-i 9


CCV 5 21.79 1.1 0.116 0.116 0.117QC 21Dec92 23:34 LANCASTER LABORATORIES%R = ( 108.Q v,-«« __ Jt —

5 0.02 99.9 0.000 0.001 -0.000 DATE: DEC 2 2 19J?QC 21Dec92 23:40 REVIEWER&tj

ABS = -0.001 ^CONCENTRATION LESS THAN IDL

* "*•"

AR3I90145

r- .i. *=<i. rn O |r* <=? cr 1~ t— f 3 O O / "£»- O O !Z ts *=• m .d=a. n«-• r~o "fcot~ o 1 Ft«~?

HP! RAT OR JAB B59 3012 BZ \'"HE WED 23 DEC 1992HMTCH Ph 9235807

QC PROTOCOL PARAMETERS -.„ , A«r>r»ATr»oiceLANCASTER LABORATORIESjr THERE is AN ERROR STOP INSTRUMENT ID #3812r.«: SPIte PORTION ' 52 BKGCORR: BZ!'.f;''.!JVERY LIMITS (7.) 85 TO 115l;:!cnVERY MINIMUM LIMIT (7.) 40f "RRELATION COEFFICIENT ( r-) O.995U'.'FRRANGE VOLUME REDUCTION 1F.T Ml CAT E RSD LIMIT (7.) 1OO.O

n\n(3RAM 26 Pb MBA

INSTRUMENT MODE ABSORBANCECALIBRATION MODE CONCENTRATION

• MEASUREMENT MODE PEAK AREALAMP POSITION 6LAMP CURRENT (mA) 5

, SLIT WIDTH (nm) 0.5SLIT HEIGHT NORMALWAVELENGTH (nm) 283.3SAMPLE INTRODUCTION SAMPLER AUTOMIXINGTIME CONSTANT O.O5MEASUREMENT TIME (BBC) 1.0 •REPLICATES - 1BACKGROUND CORRECTION ONMAXIMUM ABSORBANCE 1.40

FURNACE PARAME f ERBSIEF I P t-FERATURE TIME GAS FLOW GAS TYPE READ.NC. (C) (sec) (L/min) COMMAND

i --20-, 20.0 3.0 NORMAL NO2- ..'2O 1O.O 3.O NORMAL NO

:iOOl' ^ 2OYO "~" 3.0 NORMAL NO'1 VOO ;. 2O. O 3.0 NORMAL NC)'."i 700 J5.O 3.O NORMAL NO6 100 --— 4.5 • 3.0 NORMAL NO

100, 2.0 3.o NORMAL NOM 100,, _ 2.0 0.0 ' NORMAL NO

.'100 1.2 0.0 NORMAL YES10 .."4OO 2.O 0.0 NORMAL YES1 ! .' 00 O.2 3.O NORMAL NO!•;: .-f OO: 3.O 3.O NORMAL NO.1 . 10O 12.9 3.0 NORMAL NOi.l ">U 2.O 3.0 NORMAL NO

SR3190^6

SAMPLER PARAMETERSVOLUMES (r L)

SOLUTION BLANK MODIFIERBLAUI: -- 30 691 AlinARD „: 6 24 6;;?TrtUi'>f,r:;.n -::- 15 _ 15 6S IV-M-infiKO '1 24 6 6I' I "I I' 't iRI) ! • 30 .._ O 6•-ViMPI ,E 3O - O 6

RECALIRRATION RATE 0REBLOPE RATE 0

H'.IL! '.PI h IM.TECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE 95INJECT RATE £3

LiC PROTOCOL PARAMETERSLANCASTER LABORATORIES

!'! STANDARD RATE 2O PFAA PB $0*1ni INITIAL STANDARD POSITION 5O VafMtt y"* *-"<:. INITIAL BLANK POSITION 51 DATE: DEC 2 3 1992O!' CONTINUING STANDARD POSITION 50 REVIEWER /rM** * rin- CONTINUING BLANK POSITION 51"' STANDARD VOLUME (fL) 30i)' STANDARD CONCENTRATION 20.00 PPB'('. STANDARD LIMITS (7.) 9O TO 110<V SPIKE RATE Oin HPIKF VOLUME (fL) 12'" SPIKE CONCENTRATION 50.00 PPB' 1- > I RI X SPI KE CONCENTRAT1 ON 0 . OO PPBl".5TRUMENr DETECTION LIMIT 0.60 PPBt:1 Cill I RED DETECTION LIMIT 3.00 PPB

SAM' U _ CONC. XRSD Mf-AN READINGSPFB AF.<S

O.OO O.OO2 O.00223Dec92 16:O9CONCENTRATION LESS THAN IDL

: 5.OO O.0 0.O23 O.02323Dec92 16:13

1O.OO O.O 0.04' 0.04323Dec92 16:16

r.i! AM"M!':'.' 25. OO O.O O.liO O.11O23Dec92 16.19 DATAVERIFlEo

'•;.rA!.H:'nr:f i 40.00 o.o O.165 0.165H( 23Dec92 16:23

'• 50.00 0.0 . 0.194 O.194Hi 23Dec92 16:26

AR3190U7Z

COMC 7.R9D MEAN -r READ INGSPPB ABS

'CV 21.11 -O.O O.092 0.092nr: . 23Dec92 16s 29

7.R » 105.6 .

-O.12 O.O -O.OO1 -0.001"'' 23Dec92 16:32

ABS = • O.OOOfCONCENTRATION LESS THAN IDL

'' PA 2.15 0.0 0.0 i O 0.010'•"- 23Dec92 16:35

' LANCASTER LABORATORIE<.' - J 20.35 O. O 0.009 0.089 GFAA .r-,. pa 3£$.'" 23Dec92 16:39 -».__ •_ ^

7.R - 101.7 DAT& DEC 2 3 1992REVIEWER

' ' '' I O.03 O.O O.OOO O.OOO'"• 23Dec92 16:42

ABS = O.O01CONCENTRATION LESS THAN IDL

!':-'(>n TRIO 2.3B o.O • o.Oll. 0.0111 23Dec92 16:45

X INTERCEPT- 3-' '0'02B CORRCOEF: •SLOPE:ro.i7 o.o 0.044 • 0.044 YINTERCEPT: .0111

23Dec92 16:51 '

' •; ' IHVM ' ;. 1 3 . 06 0 . 0 O . O5 7 • 0 . 057" 23Dec92 'l6:54

,l9'.!B9H«>o 3. 1O O.O O.O.14 0.014f'C . 23Dec92 16:58

'. 9"';r?MAl 6.24 O.O O.O28 O.O28. ' X INTERCEPT' -*"'

•'"'jSB/AT 23DeC 17S01- C°RRCOEF: .17'.'R'?!Vjr 10.31 o.o 0.044 o.o44*f? '.p SLOPE:'!"; 6MT 23Dec92 17:O4 YINTERCEPT: .

l?"H',-fix, • 12.97 0.0 O.056 O.O56"1. 23Dec92. 17:072227i-?"'v'>.M'» -O". SO 0.0 -0.002 -0.002"' 23De?c92 17:10

CONCENTRATION LESS THAN IL)LV m* & £• -"•

' '"'""-l I 2.51 0.0 0.011 0.011'"- 23D c92 17:13

! •"•".!.' 5.39 0.0 O.O24 O.O24 ' : X INTERCEPT' *~ •Z_ _ 7 7 *-'- ec -^ : CORR co**"1' <«• j-|Drr ~ "* *''"'• I ' 8.11 o.o 0.036 0.036 «*.UPE;

"• 23Ue;c92 17:19

SAMI'i.f: CONC 7.RSD MEAN READINGS

ZZZZZ? "™!9''>'1l:iA4o 10.48 0.0 0.045 0.045•1C - 23DBC92 17:222 2 7 "" — ~ i*i x%t^oWu 13.98 o.o 0.061 o.06i XINTERCEPT: '7'5*% • 23DBC92 17:25 CORR COEF: '* Z 2 2 7 7 SLOPE-r?"-n6'l2 16.93 O.O O.074 O.O74 Oi__/rc.rifj ->3Dec92 ' 17-^9 YINTERCEPT: '^y^5222222,l1?04i:i64J. 19.33 O.O O.O84 0.084f'lf' • r^"T\*-i.»-.OO1"7«"IrOl:^1 ' , _,41 -_.-J«UeC V__, 1 / S O_i

22222?i-.?0'T)4\of 1.32 O.O 0.006 .0.006

1?'J!50<1>! t 5.O9 O.O O.O23 O.O23

r-'zl2za : 23Dec92 17!3B X INTERCEPT: --1. '?'.) 'r ? 1 M .» ( B . 34 0 . 0 0 . 037 0 . 037 CORR COEF: 'QC j 23Dec92 17:41 SLOPE: '

ZZZZZ 2f ' y.19M'-,. iaV : 11.54 O.O O.O50 0.050'•!(.; 23Dec92 17:44

(;('v "••' 2O.O2 O.O O.O87 0.087 l AMOAOTCO i AO«« A- ««,t-^ 17-48 LANCASTER LABORATORIES*"7.R = " 100.1 GFAA v~ PB

DATE: 0EC 2 , ,.-0.44 0.0 • -0.002 -O.OO2 RPV/IPWCR

23Dec92 17:51 REVIEWERABS = -O.O01

22777V CONCENTRATION LESS THAN IDL* — " i ^

1 ';>'.> :.>M'1\' no' 0.81 O.O O.O04 0.004Qt; ,,!, 23Dec92 17:54

is'osf i/]/\n t (3) ';'4.58 o.o 0.021 0.021 X INTERCEPT:•m: U 23DBC92 17:57 CORR COEF:

2 2 2 2 2 7? / V:' • SLOPE:lVor,04\'',' 8.32 0.0 0.037 O.O37 .('!f / 23Dec92 18:00

2222 2 21 /

_ .2222 2 Z11.52 O.O O.O5O 0.050

23Dec92 18:04

I'-o^o;,!-- -O.66 O.O -O.OO3 -O.OO3('•n 23Dec92 18:07

CONCENTRATION LESS THAN IDLZ22ZZ 7

.1'?0^>sji 2.00 O.O O.OO9 0.009(:)f. 23Dec92 18:10

fr"tr.>!M. 4.17 O.O O.O19 O.O19 X INTERCEPT: "/•i > ( . 23DBC92 18:13 CORR COEF: •

Z 2 2 2 Z _. SLOPE:1 '-"S-.'-l ij.28 0.0 0.028 0..028

23Dec92 18:16

AR3I90U-9

LANCASTER LABORATORIESGFAADATEOEC 2 i 1992REVIEWER

Element F i ! <? : SEFAST. GELElement: f7^ \: Analyst: MST

int Daf-->: Main+Suppl. Peak Storage: Nonent: Calib. Curve+Elem. Params.

INSTRUMENT: 5100 Technique: HGA Version: 7.10WavelengHi: 196.0 Peak Slit: 2.0 LowSignal T> pc : Zeeman AA — ---•-•--—-• Signal Measurement: Peak 'Area- -Read Time-: 5.0 Read Delay: 0.0 BOC Time: 3Sample Replicates: 2Standard Replicates: 2 Spike Replicates: Same as Sample_ _ « . _ _ _ _ . _ - . _ _ . _ _ _ — «_— _ _ - _ _ _ _ — _ _ _ — •__ — —. — _.— ,— — — _ — — — — — — — — — — — — .— — — — —.-— — — — — —— — — — — — — — — -

CALIBRATIC?!,':'Solutionr-

Calib. Bin:Standard 1Standard .:Standard '?Standard 4Standard 5Samples

ID

S0S5SI 5S25S40S50

Cone I LocationI

------I 05.001 4015.001 4025.001 4040.001 4050.001 40

Volume

2026101620

DiluentVolume

220161262

20 I 2

Modifier#11111111

Diluent L- cation: 0Modifier #1 Location: 39 Modifier #2 Location:Calibration Unite: ug/Lt Sample Units: ug/LCalibration Type: Linear

Furnace Tir"?/Temperature Program:

23456

Temp P 1-np Hold120 2 35130 2 10220 2 "5

line* 2 101800 0 , 32400 1 2

Gas Flow2502502502500

250

Read Gas TypeNormNormNormNormNormNorm

•:*:>-«/ "9L_JL

Inlection Temp: 120 Pipette Speed: 75'/. Extraction System: Off

SEQUENCE:Step Action and Parameters

1 Pipet diluent + modifier 1 * spike + sample/std2 Run HGA steps 1 to End

CHECKS:Recalibration Type: Completely RecalibrateLocations: Hone

Cone. Abovr> Calibration Action: Print Message OnlyAlternate Fample Volumes (uL):Run Alternate Volume Blanks: No

Recovery Measurements:1 uL of 2<7"2 ug/L Standard at Location 37 Gives 10.00 ug/LMeasure Recovery on Samples: 2-40Add to QC Samples: No 7. Recovery Limits: 85.0 to 115.0

GFAADATE:REVIEWER

OC:#1 A/S I QC Sample I Cone. Limits I After I Periodic!At I Count Asl

I Loc. I ID I Lower Upper ICalibI Check I End I Sample I1 36 ICV 18.00 22.00 X2 0 1CP -3.00 3.00 X3 36 C'JV 18.00 22.00 X X4 0 T C P -3.00 3.00 X XRun Periodic QC Samples: 2,7,12,17,22,27,32Out of Limit Action: Print Message Only

Matrix Checl: Calculations:*/. Difference for Dupls: No Locations:"/. Recovery for Spike: No Locations: Cone:

AR31905 I

PUS*• -!• L/ cl L t?

Replicate 1 Time: 12:46 JPeak Area <A-s): 0.002 Peak Height (A): 0.003

ckgrourH PI: Area (A-s): 0.002 Background Pk Height (A): 0.002nk Corrrrted Pk Area (A-s): 0.002

Se ID: F"W 354 021 f$W Seq. No.: 00002 A/S Pos.: 2 Date: 12/21/92

Replicate 1 Time: 12:51Peak Area (A-s): 0.003 Peak Height (A): 0.003BackgrounH I"k Area (A-s): 0.002 Background Pk Height (A): 0.002Blank Corror-ted Pk Area (A-s): 0.003

LANCASTER

LANCASTER LABORATORIESGFAADATEOEC 2 i 1992REVIEWER 7*+

f *Element F:'': SEFAST. GEL —- '•*•••**Element: Se , Analyst: MST 744 a p O j Qn CAPrint Datn: Main*Suppl. Peak Storage: None HnO| JUJPr-^nt: Celiv'. Curve*Elem. Params.

LANCASTER LABORATORIESGFAA SE ?JT<£ */DATE: DEC 2 iREVIEWE

Element File: SEFAST.GEL Element: Se Wavelength: 196.0Date: 12/21/92 Time: 12:56 Slit: 2.0 LData File: SE35601.DAT ID/Wt File: 35601.IDW Lamp Current: 0Technique: HGA Calib. Type: Linear Energy: 69

Se ID: SO •——• — —— -—— SeqT-No: : 00001———A-/S-Pos;~:—0————Dater



Mean Cone (ug/L ): .0761"- SD: 0.068 RSDC/.): 11.11


Se ID: r1"- Seq. No. : 00002 A/S Pos. : 40 Date: 12/21/92

Replicate-- 1 Time: 13:00Peak Aren (A-s): 0.014 Peak Height (A): 0.020Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.011Blank Corr^-rted Pk Area (A-s): 0.012Concentration (ug/L ): 5.49

Replicate ? Time: 13:03Peak Area (A-s): 0.012 Peak Height (A): 0.018Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): 0.009Concentration (ug/L ): 4.28

Mean Cone 'ug/L ): ..4. 88 SD: 0.858 RSDC/.): 17.

Standard number 1 applied. 15.00]Correlaticr: coefficient: 1.00000 Slope: 0.0021 Int:~0".

Se ID: F15«n -7.<anP\' Seq. No.: 00003 A/S Pos.: 40

Se ID: S15 Seq. No. : 00003 A/S Pos. : 40 Date: 12/21/92

Replicate 1 ^ Time: 13:05Peak Area (A-s): 0.035 Peak Height (A): 0.045Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.033

ncentro f. ion (ug/L ): 15.66

"Replica*^ 2 ....- Time: 13:07Peak Aren 'A-s): 0.035 Peak Height (A): 0.047Backgroun* Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blank Collected' Pk Area (A-s): 0.032Concentration (ug/L ): 15.40

LANCASTER LABORATORIESGFAADATE: DEC 2'REVIEWER "

Mean Cone- (ug/L ): 15/53- SD: 0.180 RSDC/.): 1.16 "

Standard number 2 applied. [15.00]Correlation coefficient: 0.99992 Slope: 0.0022 Int: -0.000

Se ID: S25 Seq. No.: 00004 A/S Pos.: 40 Date: 12/21/92

Replicate 1 Time: 13:10Peak Aren (A-s): 0.057 Peak Height (A): 0.074ackground Pk Area (A-s): 0.018 Background Pk Height (A): 0.017'ank Corrected Pk Area (A-s): 0.054ncentration (ug/L ): 25.15

Replicate 2 Time: 13:12Peak Aren (A-s): 0.057 Peak Height (A): 0.074Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.017Blank Corrected Pk Area (A-s): 0.055Concentration (ug/L ): 25.25

Mean Cone (ug/L ): 25.20 SD: 0.070 . RSDC/.)-: 0.28

Standard number'3 applied. [25.00]Correlation coefficient: 0.99996 Slope: 0.0022 Int: -0.000

Se ID: '"4Q- Seq. No.: 00005 A/S Pos.: 40 Date: 12/21/92

Replicat<- 1 Time: 13:15Peak Aren 'A-s): 0.092 Peak Height (A): 0.126Background Pk Area (A-s): 0.024 Background Pk Height (A): 0.026Blank Corrected Pk Area (A-s): 0.090Concentration (ug/L ): 41.13

i-

Replicate 2 . Time: 13:17Peak Area 'A-s): 0.093 Peak Height (A): 0.116

ckgrounr-! Pk Area (A-s): 0.027 Background Pk Height (A): 0.025bnk Corrected Pk Area (A-s): 0.090 _.oncentration (ug/L ): 41.48 __. f~*.'J-Z*

Mean Cone (ug/L ): 41'.'30' SD: 0.248 RSDC/.): 0.60

Standard n-smber.4 applied. [40.00] H R 3 j 9 0 5 kCorrelati'-r: coefficient: 0.99976 Slope: 0.0023 Int: -0.001

Se ID: !=' 0 Seq. No. : 00006 A/S Pos. : 40 Date: 12/21/92

Replicate 1 Time: 13:19Peak Area (A-s): 0.115 Peak Height (A): 0.153Background Pk Area (A-s): 0.029 Background Pk Height (A): 0.031Plank Corrected Pk Area (A-s): 0.113Concentration (ug/L ): 50.35

Replicate 2 ______ Time: 13:22Peak Area 'A-s): 0.114 Peak Height (A): 0.149Background Pk Area (A-s): 0.029 Background Pk Height (A): 0.031Blank Correi-ted Pk Area (A-s): 0.112Concentration (ug/L ): 49.92

LANCASTER LABORATORIESGFAA SEDATE:°rt 2 i 193?REVIEWER

Mean Cone (ug/L ): 50.'13 SD: 0.306 RSDC/.): 0.61

Standard number 5 applied. [50.00]Correlation coefficient: 0.99987 Slope: 0.0023 Int: -0.001

M Display HnbFatIonrrTT\fift~USBIWTIB.112n

DATA VERIFIEDWITH AN X BY:

LinearCOXT. Coef.: 0.99987Slope: B.BB23Intercept! -0.001


Se ID: lf-V Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92


Replicate 2 Time: 13s27Peak Area (A-s): 0.048 Peak Height (A): 0.058$ R 3 j 90 55Background rk Area (A-s): 0.017 Background Pk Height (A): 0.013

Se ID: ICV , Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92


,ank Corrected Pk Area (A-s): 0.044centration (ug/L ): 20.02

Replicate 2 Time: 13:27Peak Area <A-s): 0.048 Peak Height (A): 0.058Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.013Blank Corr<---ted Pk Area (A-s): 0.045Concentration (ug/L ): 20.41

Mean Cone (ug/L ): 20/21 SD: 0.277 RSDC/.): 1.37 '

OC sample is within range 18.00 - 22.00

Se ID: 1CB Seq. No.: 00008 A/S Pos.: 0 Date: 12/21/92


Replicate 2 Time: 13:32 LANCASTER LABORATORIES

GFAA SEJ*^/DATE: BEC 2 i 1992REVIEWER **t~* \

Peak Aren (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.24

Mean Cone (ug/L ): "0732"' SD: 0.116 RSDC/.): 35." 91 :


Se ID: 1'RA Seq. No. : 00009 A/S Pos. : 1 Date: 12/21/92

Replicate 1 Time: 13:34Peak Aren 'A-s): 0.013 Peak Height (A): 0.017Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.008Blank Coirreted Pk Area (A-s): 0.011Concentrntion (ug/L ): 5.18

Replicate 2 Time: 13:36Peak Aren (A-s): 0.014 Peak Height (A): 0.016Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.011

ank Cor i •-•cted Pk Area (A-s): 0.011ncentration (ug/L ): 5.39

Mean Cone (ug/L ): 5728 SD: 0.148 RSD C/.) : 2. 80" •

Se ID: CCV Seq. No. : 00010 A/S Pos. : 36 DaTe": 12/21/92

' ' ' • Time: 13:39

Se ID: CCV Seq. No.: 00010 A/S Pos.: 36 Date: 12/21/92

Replicate i Time: 13:39Peak Area <A-s): 0.045 Peak Height (A): 0.057Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.013Blank Corre-ted Pk Area (A-s): 0.043Concentration (ug/L ): 19.29

Replicate 2 Time: 13:41Peak Are^i (A-s): 0.048 , Peak Height (A): 0.061Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.045Concentration (ug/L ): 20.33

Mean Cone .'.ug/L ): i9r8i - SD: 0.732 RSDC/.): 3770" "

QC sample ir within range 18.00 - 22.00

Se ID: CI'B Seq. No. : 00011 A/S Pos. : 0 Date: 12/21/92


Replicate 7 Time: 13:46Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.30

LANCASTER LABORATORIESGFAADATE: DEC 21 1992

Mean Cone (ug/L ): * 0."39" " SD: 0.139 RSDC/.): '35.' 41

QC sample i r, within range -3.00 - 3.00

Se ID: PPW 354 021 ?gW Seq. No.: 00012 A/S Pos.: 2 Date: 12/21/92

Replicate ; "' " —-----~ Time:"" 13:48—"———.--.- —Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.004 Background Pk Height (A): 0.006Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -0.06

Replicate 2 Time: 13:51Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.006 Background Pk Height (A): 0.007Blank Corrected Pk Area (A-s): -0.000Concentrat i'->n (ug/L ): 0.25

Mean Cone (ug/L ): ~0,v*0 SD: 0I 221 RSDC/.): 227.46

Se ID: PBW 354 021 Seq. No. : 00013 A/S Pos. : 2

Se ID: PBW 354 021 P&WA Set*' No- : 0®013 A/S Pos. : 2 Date: 12/21/92

Replicate 1 Time: 13:53Peak Area (A-s): 0.025 Peak Height (A): 0.031Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.007• nk Corrected Pk Area (A-s): 0.022

centration (ug/L ): 10.11

Replicate 2 : . _: Time: 13:56Peak Area (A-s): 0.022 Peak Height (A): 0.029Background Pk Area (A-s): 0.009 Background Pk Height (A).: 0.008Blank Corrected Pk Area (A-s): 0.020Concentration (ug/L ): 9.04

Mean Cone 'ug/L ): 9.57 SD: 0.758 RSDC/.): 7.92

Recovery is 94. 85C '

Se ID: LCSW 354 021 LCSW Seq. No. : 00014 A/S Pos. : 3 Date: 12/21/92

Replicate 1 Time: 13:58Peak Area (A-s): 0.025 Peak Height (A): 0.032Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.008Blank Correeted Pk Area (A-s): 0.022Concentration (ug/L >: 10.25

Replicate 2 „ Time: 14:01Peak Area (A-s): 0.024 Peak Height (A): 0.032Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.008«nk Correeted Pk Area (A-s): 0.022


Mean Cone (ug/L ): 10:17" SD: 0.119 RSDC/.>:'_.'.

LANCASTER LABORATORIESGFAA SE#*0/DATE: DEC 21 1992REVIEWER Tt^my

Se ID: L-'SW 354 021 LLS Se9- No' : 00015 A/s Pos- : 3 Date: 12/21/92

Replicate ! Time: 14:03Peak Area (A-s): 0.042 Peak Height (A): 0.053Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.039Concentration (ug/L ): 17.79

Replicate 2 Time: 14:06Peak Area (A-s): 0.047 Peak Height (A): 0.061«kground Pk Area (A-s): 0.012 Background Pk Height (A): 0.013

nk Corro-ted Pk Area (A-s): 0.044centration (ug/L ): 19.86

Mean Cone 'ug/L, ): 18.83 SD: 1.463 RSD(%): 7.77

Recovery is 86. 6* AR3I9058 '

Se ID: 1S08350 -TAM«AT Seq. No. : 00016 A/S Pos. : *

Replicate 1 Time: 14:08Peak Area (A-s): 0.003 Peak Height (A): '0.004Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Carrie-ted Pk Area (A-s): 0.000Concentration (ug/L ): 0.47

Replicate 2 Time: 14:11Peak Area (A-s): 0.002 Peak Height (A): 0.003Background PI: Area (A-s): 0.011 Background Pk Height (A): 0.012Blank Conc?'~ted Pk Area (A-s): -0.000Concentration (ug/L ): 0.28

Mean Cone 'ug/L ): 0.37 SD: 0.133 RSDC/.): 35.84

Se ID: n08350 "3/\fV\(V\7 A Seq* No> : ®0®17 A/S Pos- : 4 Date: 12/21/92

Replicate I Time: 14:13Peak Area (A-s): 0.021 Peak Height (A): 0.015Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.018Concentration (ug/L ): 8.39

Replicate 2 Time: 14:16Peak Area <A-s): 0.020 Peak Height (A): 0.015Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Blank Correeted Pk Area (A-s): 0.018Concentration (ug/L ): 8.31

Mean Cone (ug/L ): 8.35 SD: 0.057 RSDC/.): 0.6-*" f

Recovery in 79.8 (outside of specified limits)

Se ID: 1908351 3AMMF Secl- No. : 00018 A/S Pos. : 5 Date: 12/21/92

Replicate l Time: 14:18

LANCASTER LABORATOR1GFAADATE: DEC 2 i 199?REVIEWER _> 7V

Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.011Blank Corircted Pk Area (A-s): -0.000Concentrntion (ug/L ): 0.22

Replicate 2 Time: 14:21Peak Area (A-s): 0.002 Peak Height (A): 0.003Background f'k""Area~"{ A-s ) :~ 0*010" ~ ' BacKgroururTlt Height" C A7~:~0: 01 1~ ~"Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.24

Mean Cone (ug/L ): *0. 23 SD: 0.010 RSDC/.): 4.

Se ID: 1908351 Seq. No.: 00019 A/S Pos.: 5 Date: 12/21/92

Replicate 1 Time: 14:23 fi R'3 1 9 U j5Peak Area (A-s): 0.018 Peak Height (A): 0.014

1 "•"•> n = u^_-,,,nd Pk Heiaht (A): 0.013

Se ID: 1?08351 3A/V\fV\F A Secl' No- ' 00019 A/S Pos. : 5 Date: 12/21/92

Replicate 1 , Time: 14:23Peak Area '.A-s): 0.018 Peak Height (A): 0.014

ckgrourid Pk Area (A-s): 0.012 Background Pk Height (A): 0.013nk Coneeted Pk Area (A-s): 0.015

ricentrat i mi (ug/L ) : 7. 02

Replicate 2 ;; _ ; ,..._..._. - Time: 14:26Peak Area (A-s): 0.019 Peak Height (A): 0.014Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.013Blank Coriccted Pk Area (A-s): 0.016Concentration (ug/L ): 7.46

Mean Cone (ug/L ): 7.24 SD: 0.313 RSDC/.): '4732" k

Recovery ie 70ri'Jl (outside of specified limits)

Se ID: in08352R JAWMT S Seq. No.: 00020 A/S Pos.: 6 Date: 12/21/92

Replicate 1 .. Time: 14:28Peak Area (A-s):. 0.022 Peak Height (A): 0.017Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.013Blank Correeted Pk Area (A-s): 0.020Concentration (ug/L ): 9.09

Replicate 2 - Time: 14:31Peak Area (A-s): 0.023 Peak Height (A): 0.017ckground Pk Area (A-s): 0.017 Background Pk Height (A): 0.016nk Cor i r-^ted Pk Area (A-s): 0.021


1 a

^ ron

Mean Cone (ug/L ): "97231" SD: 0.282 RSDC/.): 3704

Se ID: 1908352R 2 2 Z Z Z Z Seq' Uo' ' 00021 A/s Pos-: 6 Date: 12/21/92

Replicate 1 . . . Time: 14:33Peak Area 'A-s): 0.036 Peak Height (A): 0.028Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.018Blank Coti^eted Pk Area (A-s): 0.033Concentration (ug/L ): 15.18


LANCASTER LABORATORIESGFAADATE:j)EC 2REVIEWER

Peak Area (A-s): 0.040 Peak Height (A): 0.029Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.016lank Corrected Pk Area (A-s): 0.037ncentrntion (ug/L ): 16.95

Mean Cone <ug/L ): 16.06 SD: 1.257 RSDC/.): 7*78*3

• ' P~Recovery :- 67.7% (outside of specified limits) — *

Tr. >~<~v geq> No. : 00022 A/S Pos. : 36 Date-.

Se ID: CCV Seq. No. : 00022 A/S Pos. : 36 Date: 12/21/92



Mean Cone (ug/L ): 19.55* SD: 0.563 RSDC/.): 2.88,

QC sample ir within range 18.00 - 22.00

Se ID: r<~B Seq. No. : 00023 A/S Pos. : 0 Date: 12/21/92

Replicate 1 Time: 14:43Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Correeted Pk Area (A-s): 0.001Concentration (ug/L ): 0.69

Replicate 2 Time: 14:45Peak Area 'A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.21

Mean Cone < ug/L ): 0.45 SD: 0.340 RSDC/.): 75.59

QC sample ir within range -3.00 - 3.00

Se ID: l?W8353D 3AMMT D Seq. No. : 00024 A/S Pos. : 7 Date: 12/21/92

Replicate ! Time: 14:47Peak Area (A-s): 0.002 Peak Height (A): 0.003Background PI: Area (A-s): 0.010 Background Pk Height (A): 0.011Plank Corr<-"-ted Pk Area (A-s): -0.000 .Concentration (ug/L ): 0.33

Replicate 2 Time: 14:50Peak Area 'A-s): 0.003 Peak Height (A): 0.003Background PI: Area (A-s): 0.013 Background Pk Height (A): 0.012

LANCASTER LABORATORIESGFAADATE:DEC 2 i 1992

Blank Corrr'-'ed Pk Area (A-s): O. 000 REVIEWER 1 *?7c7i t ~"Concentration (ug/L ) : 0. 39 -

Mean Cone 'ug/L ): 0:'3l" SD: 0.041 RSDC/.): 11T3-T'flR3i906i

A /C Doe. . "7 r\->^-<=. 1O/O1 /QO

Se ID: 19(Z>8353D JAf^ffl'TASeq No- s 00025 A/S Pos. : 7 Date: 12/21/92

Replicate 1 Time: 14:52Peak Area (A-s): 0.019 Peak Height (A): 0.016gckground Pk Area (A-s): 0.015 Background Pk Height (A): 0.013


Replicate 2 :; Time: 14:55Peak Aren (A-s): 0.023 Peak Height (A): 0.018Background ? 1- Area (A-s): 0.016 Background Pk Height (A): 0.013Blank Corrected Pk Area (A-s): 0.020Concentr at i "n (ug/L ): 9.29

Mean Cone (ug/L ): 8.57 SD: 1.025 RSDC/.): 11/96 '

Recovery is 82. "I'JT (outside of specified limits)

Se ID: 1908354 TAWF/A Seq. No. : 00026 A/S Pos. : 8 Date: 12/21/92

Replicate J Time: 14:57Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.013Blank Corrected Pk Area (A-s): -0.001Concentr n t inn (ug/L ): 0.02

Replicate 2 .. - Time: 15:00Peak Area (A-s): 0.003 Peak Height (A): 0.003gckground Pk Area (A-s): 0.011 Background Pk Height (A): 0.012

nk Corrected Pk Area (A-s): 0.001centratic'n (ug/L ): 0.66

Mean Cone (ug/L ): 0:34- SD : 0.455 RSDC/.): 134.54

Se ID: ! 9!?8354 JA^PM A SeQ- No- : 00027 A/S Pos. : 8 Date: 12/21/92

Replicate 1 •_•_ Time: 15:02Peak Area (A-s): 0.018 Peak Height (A): 0.014Background PI: Area (A-s): 0.014 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.015Concentration (ug/L ): 7.13

Replicate ? .. . - Time: 15:05Peak Area 'A-s): 0.019 Peak Height (A): 0.016Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.013Blank Correeted Pk Area (A-s): 0.016Concentration (ug/L ): 7.55

Mean Cone 'ug/L ): 7.34 SD: 0.293 RSDC/.): 3. 99

Recovery in 70. 05i (outside of specified limits)

LANCASTER LABORATORIESGFAADATE: DEC 21 1992REVIEWER - ~>

Se ID: r"»8355 Q . Seq. No.: 00028 A/S Pos.: 9 DaKl? 31p92G£?_:Q .Till jljU v«C?

Se ID: 1908355 222222 Set*- No- : 00028 A/S Pos.: 9 Date: 12/21/92

Replicate 1 Time: 15:07Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Corr-^ted Pk Area (A-s): -0.001Concentration (ug/L ): 0.02

Replicate 2 • _ _ Time: 15:09Peak Aren (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -0.01

Mean Cone 'ug/L ): 0."00 * SD: 0.022 RSDC/.): 2506731'

Se ID: 1°08355 222222 Secl- No- : 00029 A/S Pos.: 9 Date: 12/21/92


Replicate 2 Time: 15:14Peak Area (A-s): 0.029 Peak Height (A): 0.036Background Pi; Area (A-s): 0.014 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.026Concentration (ug/L ): 11.89

Mean Cone (ug/L ): 11.67 SD: 0.306 RSD C/.) : "'

Recovery ir 116'."7"% (outside of specified limits)

Se ID: 1908356 JAMLT Seq. No.: 00030 A/S Pos.: 10 Date: 12/21/92

Replicate ! Time: 15:17Peak Area 'A-s): 0.004 Peak Height (A): 0.003Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): 0.79

Replicate 2 Time: 15:19Peak Area (A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): -0.001Concentrati"n (ug/L ): 0.05

Mean Cone 'ug/L ): l'0.~42< SD: 0.523 RSDC/.): 123/98

Se ID: 1908356 JAMLT A Seq. No. ; 00031 A/S Pos. : 10 Date: 12/21/92


DATF- nr-

Se ID: 1908356 ---„.,„. A Seq. No.: 00031 A/S Pos.:AReplicate 1 Time: 15:22Peak Area (A-s): 0.019 Peak Height (A): 0.014Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.014

LANCASTER LABORATORIESGFAA SEJtjj,/

Blank Cor re-ted Pk Area (A-s): 0.016 REVIEWERConcentration (ug/L ): 7.59

Replicate 2 Time: 15:24Peak Area (A-s): 0.022 Peak Height (A): 0.016Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.019Conceritra 1.1 nr» (ug/L ): 8778

Mean Cone (ug/L ): 8.19 SD: 0.845 RSDC/.): 10.32"

Recovery in 77?&Y. (outside of specified limits)

Se ID: 1908357 ~3/\W\L.f Seq. No. : 00032 A/S Pos. : 11 Date: 12/21/92

Replicate 1 .. Time: 15:26Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.012

nk Cori^cted Pk Area (A-s): 0.000centration (ug/L ): 0.46

Replicate 2 .. Time: 15:29Peak Area 'A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.28

Mean Cone (ug/L ): "0.37 SD: 0.130 RSDC/.): 35:06-

Se ID: 19C98357 JAMLF A Sec«- No' : 00033 A/s Pos- s ii Date: 12/21/92

Replicate ! Time: 15:31Peak Area (A-s): 0.021 Peak Height (A): 0.016Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.014Blank Cor:'-•-ted Pk Area (A-s): 0.018Concentration (ug/L ): 8.49

Replicate 2 ___ _ _ _ Time: 15:34Peak Area '.A-s): 0.021 Peak Height (A): 0.016Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.015Blank Conevted Pk Area (A-s): 0.018Concentration (ug/L ): 8.3.4

n Cone (ug/L ): 8.41 SD: 0.110 . RSDC/.): 1*-31_ .* &

Recovery ir 80."42 (outside of specified limits) ' '"•


' ' ' Time: 15:36



Replicate 2 Time: 15:39LANCASTER LABORATORIESGFAA SE

REVIEWER1^

Peak Aren (A-s): 0.046 Peak Height (A): 0.056Background Pk Area (A-s): 0.020 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.043Concentration (ug/L ): 19.44

Mean Cone (ug/L ): ISrBT7" SD: 0.524 RSD C/.) : . 65 "'

QC sample is within range 18.00 - 22.00

Se ID: CCB Seq. No. : 00035 A/S Pos. : 0 Date: 12/21/92

Replicate 1 Time: 15:41Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.010Blank Correeted Pk Area (A-s): -0.000Concentration (ug/L ): 0.24

Replicate 2 Time: 15:43Peak Area '.A-s): 0.001 Peak Height (A): 0.003Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -0.21

Mean Cone (ug/L ): |0.02 - SD: 0.316 RSDC/.): 1636:01

QC sample ir; within range -3.00 - 3.00

Se ID: 1908358 CHULT Seq. No. : 00036 A/S Pos. : 12 Date: 12/21/92

Replicate 1 Time: 15:46Peak Area 'A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.37

Replicate 2 Time: 15:48Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L )s 0.10 —

__Mean Cone 'ug/L ): 0723 SD: 0.191 RSDC/.): 6l,40_

Se ID: 1 08358 Sec*- No' : 00037 A/s Pos.: 12

Se ID: 5908358 Q(_|y LT A Sef*' No- : 02>2>37 A/S Pos.: 12 Date: 12/21/92

Replicate- 1 Time: 15:50Peak Area (A-s): 0.025 Peak Height (A): 0.020Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012

ank Corrected Pk Area (A-s): 0.022ncentration (ug/L ): 10.16

Replicate 2 . Time: 15:53Peak Are=a (A-s): 0.021 Peak Height (A): 0.018Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.011Blank Ccr: -cted Pk Area (A-s): 0.019Concentration (ug/L ): 8.65

GFAADATE: DEC 2 1 1992REVIEWER - ^

Mean Com- (ug/L ): 9.40 SD: 1.070 RSD C/.) : "TT/37 .

Recovery dr 917W" '

Se ID: 1908359 CHULR Seq. No. : 00038 A/S Pos. : 13 Date: 12/21/92

Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009

ank Corrected Pk Area (A-s): 0.001centration (ug/L ): 0.63

Replicate 2 - Time: 15:57Peak Area 'A-s): 0.002 Peak Height (A): 0.004Backgrourr' Pk Area (A-s): 0.010 _____ Background Pk Height (A): 0.011Blank Corr^eted Pk Area (A-s): -0.000Concentrnti~n (ug/L ): 0.29

Mean Cone (ug/L ): 0."4'<T SD: 0.242 RSDC/.): 527*25""-^ % '

Se ID: 1^08359 CHULF A Secl' No- : 00039 A/S Pos. : 13 Date: 12/21/92

Replicate ! Time: 16:00Peak Aren (A-s): 0.024 Peak Height (A): 0.017Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Con--ted Pk Area (A-s): 0.021Concentration (ug/L ): 9.77

Replicate :; Time: 16:02Peak Area 'A-s): 0.023 Peak Height (A): 0.018Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blan': Corrected Pk Area (A-s): 0.021Concentration (ug/L ): 9.48

Cone 'ug/L ): 9.63 SD: 0.206 RSDC/.):

Recovery ir 91.~6X ' "

Se ID: tonrc Seq. No.: 00040 A/S Pos.: 14

Time: 16:05

Pe ID: lr'08981 "\ Setl' No. : 00040 A/S Pos. : 14 Date: 12/21/92

Replicate 1 Time: 1S:05Peak Area (A-s): 0.003 Peak Height (A): 0.004Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Plnnk Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.48

Replicate ';•. Time: 16:07Peak Art?-) (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.013Blank COT i •-•"ted Pk Area (A-s): -0.000Concentra V i'in (ug/L ): 0.16

Mean Cone 'ug/L ): • orSS*"' SD: 0.222 RSDC/.): 6970IT

LANCASTER LABORATORIESGFAA

REVIEWER

Se ID: 1908981 * Seq* N°' * 00041 A/S Pos. : 14 Date: 12/21/92

Replicate 1 Time: 16:10Penk Aren (A-s): 0.021 Peak Height (A): 0.017Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.015Blank Correeted Pk Area (A-s): 0.019Concentration (ug/L ): 8.65

Replicate 2 Time: 16tl2Peak Aren 'A-s): 0.019 Peak Height (A): 0.015Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.015Blank Corrected Pk Area (A-s): 0.017Concentrnt i on (ug/L ): 7.83

Mean Cone (ug/L ): 8.24 SD: 0.583 RSD C/. ) :

Recovery ie 79»,2Xr— (outside of specified limits)

Se ID: 1908982 J$6FL Seq. No. : 00042 A/S Pos. : 15 Date: 12/21/92

^ I Time: 16:15Peak Aren (A-s)s 0. 002 Peak Height (A): 0.003Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.012Blank Competed Pk Area (A-e): -0.000Concentration (ug/L ): 0.32

Replicato 2 Time: 16:17Peak Area <A-B): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.012Blank Coi i ----ted Pk Area (A-s): -0.000Concentration (ug/L ): 0.34 '" —

Mean Cone (ug/L ): *'0?33--— SD: 0.014 RSDC/.) : '4711

———————————————————————————————————————————————————————— ^ .Q,-.- ————Se ID: 1908982 Seq. No. : 00043 A/S Pos. : 15 Date: 12/21/92

Se ID: 1 08982 > Set*' No- : 00043 A/S Pos. : 15 Date: 12/21/92



Replicate 2 Time: 16:22Peak Area 'A-s): 0.021 Peak Height (A): 0.017Backgroun-1 Pk Area (A-s): 0.016 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.018Concentration (ug/L ): 8.36

Mean Cone (ug/L ): 8.60 SD: 0.338 RSD C/.) : •'3"."93

Recovery i.e 82.*75£: (outside of specified limits)

Se ID: 1908983 CRCH- Seq. No.: 00044 A/S Pos.: 16 Date: 12/21/92


LANCASTER UBO_RATOR«-SGFAADATE: DEC 21 <992REVtB

Peak Area (A-s): 0.003 Peak Height (A): 0.003ckground Pk Area (A-s): 0.011 Background Pk Height (A): 0.011nk Corrected Pk Area (A-s): 0.001


Replicate 2 Time: 16:27Peak Area < A -s) s__0 _002_ __ _ Peak Height (A): 0.003_Background Pk "Area (A H 0r~0i'2~" Background*~Pk""HeTgKt"" I A) :" i3.~0"l.r~~Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): 0.06

Mean Cone (ug/L ): 0r39* ~ SD: 0.466 RSDC/.): 119.79

Se ID: 1908983 CRCH- A Seq. No.: 00045 A/S Pos.: 16 Date: 12/21/92



9.33 SD: 1.128 RSDC/.): 12."09'>

jjSe ID: rr~V Seq. No. : 00046 A/S Pos. : 36 Dat£:11 r2'/2_,7S2



Replicate 2 Time: 16:37Peak Are-i (A-s): 0.048 Peak Height (A): 0.059Background Pk Area .A-s): 0.017 Background Pk Height (A): 0.015Blank Corrected Pk Area (A-s): 0.045Concentration (ug/L ): 20.49

Mean Cone 'ug/L ): "20.~31 SD: 0.243 RSDC/.): l7'20" ":


Se ID: C'CB Seq. No. : 00047 A/S Pos. : 0 Date: 12/21/92

Replicate 1 Time: 16:39Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Correeted Pk Area (A-s): -0.000Concentration (ug/L ): 0.28

LANC/GFAADATE:D_C2H»2REVIEWER *"*>- X

Replicate 2 Time: 16:41Peak Aren (A-s): 0.002 Peak Height (A): 0.003BackgrourH Pk Area (A-s): 0.010 Background Pk Height (A): 0.011Blank Con <- "ted Pk Area (A-s): -0.001Concentration (ug/L ): 0.08

Mean Cone 'ug/L ): "0r±8"" SD: 0.141 RSDC/.): 78.90

QC sample i.: within range -3.00 - 3.00

Se ID: 1908984 CRCH F Seq. No.: 00048 A/S Pos.: 17 Date: 12/21/92

Replicat" 1 Time: 16:44Peak Aren 'A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.008Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.51


Mean Cone (ug/L ): r0TS_T" ' SD: 0.015 RSDC/.):


- - . - - - - . - « flR3J9069|

Se ID: 197)8984 £ f | _ j /\ Seq. No. : 00049 A/S Pos. : 17 Date: 12/21/92

Replicate 1 .= Time: 16:48Peak Area (A-s): 0.019 Peak Height (A): 0.014ekground Pk Area (A-s): 0.009 Background Pk Height (A): 0.011nk Corrected Pk Area (A-s): 0.016


Replicate 2 ", Time: 16:51Peak Area 'As): 0.024 Peak Height (A): 0.019Background PI: Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Corr--ted Pk Area (A-s): 0.022Concentration (ug/L ): 10.04

Mean Cone (ug/L ): 8.77 SD: 1.796 RSDC/.): 20.49

Recovery ic 82/5/T ' (outside of specified limits)

Se ID: 1908985 CRTF B Seq. No.: 00050 A/S Pos.: 18 Date: 12/21/92

Replicate 1 „ .. Time: 16:53Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.006 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): 0.12

Replicate 2 " ~ Time: 16:56Peak Area (A-s): 0.002 Peak Height (A): 0.003

kground Pk Area (A-s): 0.007 Background Pk Height (A): 0.010nk Corrected Pk Area (A-s): -0.000

LANCASTER LABORATORIESGFAA SEDATE: BEC 2 1 1992REVIP

Concentrat i "n (ug/L ): 0.13

Mean Cone 'ug/L ): '0.~T2 SD: 0.009 RSDC/.): 7.71

Se ID: 1908985 CRTPB A Seq. No. s 00051 A/S Pos. : 18 Date: 12/21/92

Replicate- 1 —-- — • - - - - — - — ——— - Time: 16:58~Peak Area 'A-s): 0.022 Peak Height (A): 0.030Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.010Blank Cori<-"-ted Pk Area (A-s): 0.020Concentration (ug/L ): 9.04

Replicate 2 ^ Time: 17:01Peak Area (A-s): 0.022 Peak Height (A): 0.028Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.009*ank Corir-^-ted Pk Area (A-s): 0.020

icentration (ug/L ): 9.12,-.. "


Recovery ir 89.57. ""

JO; 08986 Seq. No.: 00052 A/S Pos.: 19 Date: 12/21/92

Se ID: 1908986 CTSB/ T Seq. No. : 00052 A/S Pos. : 19 Date: 12/21/92

Replicate 1 Time: 17:03Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.013Blank Corrected Pk Aree (A-s): 0.000•Concentration (ug/L ): 0.49

Replicate ?. Time: 17:06Peak Area (A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.013Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.29

Mean Cone (ug/L ): 0.39"" SD: 0.141 RSDC/.): 35.74?

Se ID: 1908986 JSBMT A Seq- No-: 00053 A/S Pos.: 19 Date: 12/21/92

Replicate I Time: 17:08Peak Area (A-s): 0.019 Peak Height (A): 0.014Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.016Blank Correeted Pk Area (A-s): 0.017Concentration (ug/L ): 7.78


Mean Cone (ug/L ): 8.59 SD: 1.152 RSDC/.): "isT

Recovery is 82I'0Xir" (outside of specified limits)

LANCASTER LABORATORIESGFAADATE:OEC 21 W9ZREVIEWER

Se ID: ' 08987 3"&MTF Seq. No.: 00054 A/S Pos.: 20 Date: 12/21/92

Replicate 1 Time: 17:13Peak Area 'A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.012Blank Corrf -ted Pk Area (A-s): 0.000Concentration (ug/L ): 0.52

Replicate ?. Time: 17:16Peak Aroa (A-s): 0.003 Peak Height (A): 0.004Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.42

Mean Cone (ug/L ): ''0747 SD: 0.065 RSDC/.):

Se ID: 192)8987 Seq. No. : 00055 A/S Pos. : 20,' Date: 12/21/92

Replicate I Time: 17:18 ftR31907l--- n__i. u^-i r,K4- f * Y . fTi pi 1 Q

-"^ -i '-. '• - «yo_o/ —-,_ .-r — r »f<4« NO. :J B/v\ I \~ n



fplicate 2 .. . _. Time: 17:21Peak Areni 'A-s): 0.021 Peak Height (A): 0.018Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.013Blank Cori^-ted Pk Area (A-s): 0.019Concentration (ug/L >: 8.77

Mean Cone 'ug/L ): 9.14 SD : 0.525 RSDC/.): 5.75

Recovery ie 86. 7X '"

Se ID: 1°08988 CHRDfA Seq- NO. : 00056 A/S Pos. : 21 Date: 12/21/92

Replicate 1 „ .. Time:. 17:23Peak Area 'A-s): 0.004 Peak Height (A): 0.004Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): 0.92



W?aan Cone (ug/L ): . 0775" SD: 0.237 RSD C/.) : '"3T745

Se ID: 1908988 CHRP/A f\ Se(?' No< : 00057 A/S Pos.: 21 Date: 12/21/92


LANCASTER LABORATORIESGFAA SEDATE: DEC 21 m

Blank Corrected Pk Area (A-s): 0.018 REVIEWER 2z^ ? y«-/Concentrat i-m (ug/L ): 8.13

Replicate ? Time: 17:31Peak Area 'A-s): 0.020 Peak Height (A): 0.013Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.014Blank Corrected Pk Area (A-s): 0.017Concentration (ug/L ):'7.95~""

m Cone 'ug/L ): 8.04 SD: 0.130 RSD C/.) : *_T62C .

Recovery ic 72.9 (outside of specified limits) *>r 4

Se .ID: CCV Seq. No. : 00058 A/S .Pos. : 36

Renlicate 1 „ .,-_ Time: 17:33

Se ID: rev Seq. No.: 00058 A/S Pos.: 36 Date: 12/21/92

Replicate 1 Time: 17:33Peak Aren 'A-s): 0.049 Peak Height (A): 0.061Background Pk Area (A-s): 0.019 Background Pk Height (A): 0.014Blank Correr-ted Pk Area (A-s): 0.046Concentration (ug/L ): 20.94

Replicate 2 Time: 17:36Peak Area (A-s): 0.049 Peak Height (A): 0.059Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.013Blank Cor*'-~ted Pk Area (A-s): 0.046Concentration (ug/L ): 20.96

^ J*r~" •*•* *•Mean Cone 'ug/L ): r20T§5 ' SD: 0.014 RSDC/.): 0.07-

QC sample iB within range 18.00 - 22.00

Se ID: CCB Seq, No.: 00059 A/S Pos.: 0 Date: 12/21/92

Replicate 1 Time: 17:38Peak Aren (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.53

Replicat" 2 Time: 17:40Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Correeted Pk Area (A-s): -0.000Concentration (ug/L ): 0.17

' -• -r~,Mean Cone (ug/L ): T0r35- SD: 0.255 RSDC/.): 73.56 '

QC sample ie within range -3.00 - 3.00

Se ID: 1908989 CHRPF Seq. No.: 00060 A/S Pos.: 22 Date: 12/21/92

Replicate 1 Time: 17:43Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.33

UNCASTERUBORATOR.ESSE^.21B-

REVIEWER 55 7 yy

Replicate 2 Time: 17:45Peak Area (A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.008Blank Cor r ented Pk Area (A-s): -0.000Concentration (ug/L ): 0.13 • • - •

_—Mean Cone (ug/L ): 0.723" SD: 0.144 RSD C/. )

Se ID: 1908989 arTM*? s«?q. No.: 00061 A/S Pos.: 22 : Qlr2/pl/92

Se ID: 19'38989 CHl /pF A Seq> No' : 00061 A/S Pos. : 22 Date: 12/21/92

*Replicate 1 Time: 17:48Peak Area 'A-s): 0.025 Peak Height (A): 0.018Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.011

ank Corrected Pk Area (A-s): 0.022ncentra'ion (ug/L ): 10.24

Replicat^ .1 ;.: ... Time: 17:50Peak Aren 'A-s): 0.024 Peak Height (A): 0.018Backgroun^ Pk Area (A-s): 0.011 Background Pk Height (A): 0.011Blank Cor: -cted Pk .Area (A-s): 0.022Concentr-o.t i on (ug/L ): 10.09

Mean Cone (ug/L ): 10.17 SD: 0.108 RSD C/.) : fi'?06" •

Recovery i r. 99.*3%

Se ID: 1908990 J5BLT Seq. No.: 00062 A/S Pos.: 23 Date: 12/21/92


Replicate 2 ,-, _ _: .. . Time: 17:55Peak Area 'A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.011

ank Corrected Pk Area (A-s): -0.001ncentration (ug/L ): 0.07

Mean Cone (ug/L ): f0;-34 SD: 0.383 RSD (7.) : 1T0T96

Se ID: 1308990 J$6i-T A Secl- No- : 000&3 A/S Pos.: 23 Date: 12/21/92


2 : Time: 18:00Peak Aren 'A-s): 0.019 Peak Height (A): 0.013Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.014Blank Coii-eted Pk Area (A-s): 0.016Concentration (ug/L ): 7.47

LANCASTER LABORATORIES.: GFAA

DATE: DEC 2 1REVIEWER

an Cone (ug/L ): 7.12 SD: 0.496 RSDC/.): 6.97

Recovery ir 67.7V. (outside of specified limits) —-

Se ID: 19B8991 n Seq. No.: 00064 A/S Pos.: 24 IflpR<6 I1

Se ID: 1908991 J"S6LF Setl- No. : 00064 A/S Pos. : 24 Date: 12/21/92

Replicate- 1 "~ _"" ' " "~ ~"~_"___ Time:~18:03———~~Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.24

Replicate 2. Time: 18:05Peak Arm 'A-s): 0.002 Peak Height (A): 0.004"nckground Pk Area (A-s): 0.011 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentr-it * on (ug/L ) : 0. 14 '

Mean Cone (ug/L ): 0.-J.9 SD: 0.068 RSD < */.) : ~36--02 -• ,-f

Se ID: 1908991 JS6LF A Seq. No.: 00065 A/S Pos.: 24 Date: 12/21/92

Replicate 1 Time: 18:08Peak Area (A-s): 0.023 Peak Height (A): 0.017Background Fk Area (A-s): 0.014 Background Pk Height (A): 0.015Blank Coneeted Pk Area (A-s): 0.021Concentration (ug/L ): 9.52

Replicate 2 Time: 18:10Peak Area (A-s): 0.018 Peak Height (A): 0.014Background Fk Area (A-s): 0.013 Background Pk Height (A): 0.015Blank Corrected Pk Area (A-s): 0.015Concentration (ug/L ): 7.11

Mean Cone (ug/L ): 8.32 SD: 1.701 RSDC/.): 20

Recovery ir 81J35I (outside of specified limits)

Se ID: 1908992 CP.HLT Seq. No. : 00066 A/S Pos. : 25 Date: 12/21/92

Replicate 1 Time: 18:13Peak Aren (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.011Blnnk CotT--ctr>d Pk Area (A-s): 0.000Concentr nt i r.-n (ug/L ): 0.37

Replicat" ? Time: 18:15Peak Aren 'A-s): 0.003 Peak Height (A): 0.003Sackgro-.ir-.d Pk Area (A-s): 0.009 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): 0.000Concentration (ug/L ): 0.45

Mean Cone (ug/L ): 0.-41- SD: 0.060 RSDC/.): 14T57""-

LANCASTER LABORATORIESGFAA SEDATEflEC 2 1 WttREVIEWER

Se ID: 1 08992 Seq. No. : 00067 A/S Pos. : 25 '©aH.'e:1 12721792

Se ID: 1 08992 CRHLT A See«- No- : 000&7 A/S Pos. : 25 Date: 12/21/9:

Replicate ! Time: 18:18Peak Aren (A-s): 0.021 Peak Height (A): 0.018Background Pk Area (A-s): 0.012 Background Pk Height (A): 0.011lank Correeted Pk Area (A-s): 0.019


Replicate ."! Time: 18:20Peak Aren (A-s)s 0.025 Peak Height (A): 0.027Background Pk Area (A-s): 0.011 Background Pk Height (A): 0.012ninnk Collected Pk Area (A-s): 0.023Concentration (ug/L ): 10.37

Mean Cone (ug/L ): 9.50 SD: 1.235 RSDC/.): f3.*00

Recovery i rr gST^X*"

Se ID: n2>8993 CRMLF Seq. No.: 00068 A/S Pos.: 26 Date: 12/21/9:

Replicate 1 „ Time: 18:23Peak Area (A-s): 0.004 Peak Height (A): 0.004Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.008 \Blank Cor i ected Pk Area (A-s): 0.001Concentration (ug/L ): 0.83

Replicate 2 Time: 18:25Peak Area (A-s): 0.001 Peak Height (A): 0.004Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010lank Collected Pk Area (A-s): -0.002'oncentration (ug/L ): -0.35

Mean Cone (ug/L ): '0724'" SD: 0.836 RSD C/.) :

Se ID: n08993 CRMLp A Seq. No. : 00069 A/S Pos. : 26 Date: 12/21/9

Replicate l Time: 18:27Peak Aren (A-s): 0.022 Peak Height (A): 0.020-Background Pk Area -(A-s): 0.012 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): 0.020Concentration (ug/L ): 9.16

Replicate 2 Time: 18:30Peak Ar -.-s 'A-s): 0.025 Peak Height (A): 0.022Background Fk Area (A-s): 0.012 Background Pk Height (A): 0.013Blank Corrected Pk Area (A-e): 0.022Concentration (ug/L ): 10.27

Mean Cone (ug/L ): 9.71 SD: 0.782 RSD (7.) : '67 05"

Recovery i: 94.8%

e ID: CCV Seq. No. : 00070 A/S Pos. : 36 Date: 12/21/c.

Replicate 1 Time: 18:32 . £?57

LANCASTER LABORATORYGFAA

REVIEWER

Se ID: CCV Seq. No.: 00070 A/S Pos.: 3b uave; o.^/^x, _,..


LANCASTER LABORATORIES

DATE:Dfc 21REVIEWER ?*£-?</<.

Peak Aren (A-s): 0.050 Peak Height (A): 0.062Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.015Blank COT T <--cted Pk Area (A-s): 0.047Concentration (ug/L ): 21.33

Replicatr 2 Time: 18:35Peak Area (A-s): 0.048 Peak Height (A): 0.060Backgru'ui'i Pk Area (A-s): 0.017 Background Pk Height (A): 0. 0J 4Blank Coii ected Pk Area (A-s): 0.046Concentration (ug/L ): 20.54

Mean Cone (ug/L ): '20794 SD: 0.559 RSDC/.): 2.67

QC sample- is within range 18.00 - 22.00

Se ID: CCB Seq. No.: 00071 A/S Pos.: 0 Date: 12/21/92

Replicate 1 ' Time: 18:37Peak Aren (A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.007 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): 0.34

Replicate 2 Time: 18:39Peak Are-3 (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentrntion (ug/L ): 0.16

Mean Cone (ug/L ): '0r_>5 SD: 0.124 RSD (7.): 49.34


RASTER LABORATORIESUP/\/\ Q|

REVIEWER ? 7.

fiR319077

Element File: SEFAST.GELElement: Se ,, Analyst: MST 744Print Data: Main+Suppl. Peak Storage: NonePrint: Calib. Curve+Elem. Params.

in

•INSTRUMENT: 510,0 Technique: HGA Version: 7.10

velength: 196.0 Peak Slit: 2.0 Lowgnal Type: Zeeman AA Signal Measurement: Peak Area

ead Time: 5.0 Read Delay: 0.0 BOC Time: 3Sample Replicates: 2Standard Replicates: 2 Spike Replicates: Same as Sample

CALIBRATION:Solutions

Calib. BlankStandard 1Standard 2Standard 3Standard 4Standard 5Samples

S0S5S15S25S40S50

Diluent Location:

ID Cone 1 Location1

_ _ _ _ _ _ _ _ _ _ !5.00115.00125. 00140. 00!50. 001

_ _ _ _ _ _ _ _ _ _ ! _ _ .0

Modifier #1 Location: 39 ModifierCalibration Units:Calibration Type:

04040404040

Volume

202610162020

DiluentVolume

2201612622

Modifier#11111111

#2 Location:

#2

ug/L Sample Units: ug/LLinear

Furnace Time/Temperature Program:Step 1 Temp Ramp Hold

1 1 120 2 352 1 130 2 10

k 3 1 220 2 5P 4 1 1150 2 105 1 1800 0 36 12400 1 , 2

Injection Temp: 120

Gas Flow Read Gas Type250 Norm250 Norm250 Norm250 Norm0 * Norm

250 NormPipette Speed: 75% Extraction System: Off


1 Pipet diluent +• modifier 1 * spike * sample/std2 Run HGA steps 1 to End

CHECKS:Recalibration Type: Completely RecalibrateLocations: None

Cone. Above Calibration Action: Print Message OnlyAlternate Sample Volumes (uL):Run Alternate Volume Blanks: No

Recovery Measurements:1 uL of 200 ug/L Standard at Location 37 Gives 10.00 ug/LMeasure Recovery on Samples: 2-3Add to QC Samples: No 7. Recovery Limits: 85.0 to 115.0

LANCASTER LABORATORIESGFAADATE:DEC21 1992

^

AR319078

._ 35 icV 18.00 22.00 X2 ~0 ICB -3.00 3.00 X3 36 CCV 18.00 22.004 0 CCB -3.00 3.00Run Periodic QC Samples: 2,4Out of Limit Action: Print Message Only

Matrix Check Calculations:7. Difference for Dupls: No Locations:7. Recovery for Spike: No Locations: Cone:

LANCASTER LABORATORIESGFAADATES

AR319079


• — — — — — — — — — — — _ — _ — .— -_ — — _ — _ ___ ___._,___ — — ___ — — — - _ - _ _ _ _ _ _ _ , _ , _ _ — -. — — — — —__ — — -.____,__«. — —.__». — _ _ _ _ _ _ — -

ID: S0 Seq. No.: 00001 A/S Pos.: 0 Date: 12/21/92

Replicate 1 Time: 20:24Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.007 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.19

Replicate 2 • Time: 20:27Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.011Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.14

Mean Cone (ug/L ): ""-'0.17' SD: 0.039 RSD (7.): 23.69



Replicate 1 Time: 20:29Peak Area (A-s): 0.014 Peak Height (A): 0.017Background Pk Ar.ea (A-s): 0.011 Background Pk Height (A): 0.009



Mean Cone (ug/L ): r5Y28" SD: 0.255 RSD( 7.) :""47'83"

Standard number 1 applied. C5.003Correlation coefficient: 1.00000 Slope: 0.0024 Int: -0.000


Replicate 1 .! Time: 20:34Peak Area (A-s): 0.036 Peak Height (A): 0.047Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.012Blank Correeted Pk Area (A-s): 0.034Concentration (ug/L >: 14.41


nk Corrected Pk Area (A-s): 0.035centration <ug/L ): 15.04 L/.I I CASTER LABORATORIES

GFAA SE3J ^DATE: DEC 2 1 1992 q . ftffrl nREVIEWER?~>-K* I 91T8U



Replicate 2 Time: 20:36Peak Area (A-s): 0.038 Peak Height (A): 0.049Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.035Concentration (ug/L ): 15.04 LANCASTER LABORATORIES

GFAADATE: DEC 2 1 1992REVIEWER rt -ty?

Mean Cone (ug/L ): T4772T SD: 0.449 RSD (7.) : 3.05

Standard number 2 applied. [15.00]Correlation coefficient: 0.99998 Slope: 0.0023 Int: 0.000




Mean Cone (ug/L ): , 23.98T v SD: 0.612 RSDC/.) :*"_»!• 55 "

Standard number 3 applied. C25.00]Correlation coefficient: 0.99963 Slope: 0.0022 Int: 0.000



Replicate 2 Time: 20:45Peak Area (A-s): 0.090 Peak Height (A): 0.116Background Pk Area (A-s): 0.023 Background Pk Height (A): 0.024Blank Correeted Pk Area (A-s): 0.088 ,.Concentration (ug/L ): 39.25 '"-

Moan Cone (ug/L )t 38.8"6 SDi 0.554 RSDC/.) s 'T. 43'n pQ $ QQR I

Standard number 4 applied. t40.00] H l\ o l J u u--.-__ i _4. ., „„ „„„.,•-p-i r-i ent ; n.99957 Slope: 0.0022 Int: 0.001


Replicate 1 Time: 20:48Peak Area (A-s): 0.111 Peak Height (A): 0.144Background Pk Area (A-s): 0.029 Background Pk Height (A): 0.029y.ank Corrected Pk Area (A-s): 0.109

icentration (ug/L ): 50.00

Implicate 2 Time: 20:50Peak Area (A-s): 0.112 Peak Height (A): 0.137Background Pk Area (A-s): 0.031 Background Pk Height (A): 0.029Blank Corrected Pk Area (A-s): 0.110Concentration (ug/L ): 50.33 LANCASTER LABORATORIES

: GFAA: DATE:DEC 21 1992

REVIEWER

Mean Cone (ug/L ): 50..1&,.-. - SD: 0.235 RSD (7.) : s0i,-4'JF

Standard number 5 applied. [50.003Correlation coefficient: 0.99982 Slope: 0.0022 Int: 0.001

"{Display Calibration - C;\flOSER\flOILES\ELEHEHT\SEFftST.fiEL0,109

LinearCorr. Coef.: B.999BZSlope: B.BB22Intercept; B.BB1


Se ID: ICV Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92


nk Corrected Pk Area (A-s): 0.047centration (ug/L ): 21.35 _ ..

Replicate? 2 Time: 20:55Peak Area (A-s): 0.047 Peak Height (A): 0.060Background Pk Area (A-s): 0.018 Background Pk Height (A): CBlank Correeted Pk Area (A-s): 0.045

Se ID: ICV Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92



Mean Cone (ug/L ): 20177~T SD: 0.822 RSDC/.): 3.'~96


Se ID: ICB Seq. No.: 00008 A/S Pos.: 0 Date: 12/21/92


Replicate 2 Time: 21:00 LANCASTER LABORATORIESGFAADATE: DEC 2 i miREVIEWER

Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): -0.06

Mean Cone (ug/L ): '0705 SD: 0.159 RSD (7.) : '"3T1. 32


Se ID: CRA Seq. No.: 00009 A/S Pos.: 1 Date: 12/21/92



Mean Cone (ug/L ): 5.10 """ " SD: 0.834 RSDC/.): 'l6 ,35.




Replicate i Time: 21:07Peak Area (A-s): 0.049 Peak Height (A): 0.067Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.014



Mean Cone (ug/L ): 2in_T ' " SD: 0.297 RSDC/.):


Se ID: CCB Seq. No.: 00011 A/S Pos.: 0 Date: 12/21/92



Correeted Pk Area (A-s): 0.001(ug/L ) : 0. 12

LANCASTER LABORATORIESGFAA SEjj- 7DATE: DEC 2 1 W9IREVIEWER •fc- /' y

Mean Cone (ug/L ): "0735""" " SD: 0.325 RSD (7.): 92.35


Se ID: 1908984 Seq. No.: 00012 A/S Pos.: 2 Date: 12/21/920 /OiLCReplicate 1 VV-**r Time: 21:17

Peak Area (A-s): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Correeted Pk Area (A-s): -0.000Concentration (ug/L ): -0.49

Replicate 2 Time: 21:19Peak Area (A-s): 0.003 Peak Height (A): 0.004Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): 0.000« centration (ug/L ): -0.19

n Cone (ug/L ): -0734* SD: 0.212 RSD ( 7.) :


Replicate- -. 1 • Time: 21:22


Replicate 1 Lx WUn - Time: 21:22Peak Area (A-s): 0.024 Peak Height (A): 0.018Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.022Concentration (ug/L ): 9.67


I -it >«

Mean Cone (ug/L ): 10.04 SD: 0.522 RSD (7.) : 5.19

Recovery is 103.97.


-

\


Replicate 2 Time: 21:29 ,Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.001Concentration (ug/L ): -0.73

Mean Cone (ug/L ): c_»r§<f~* ' SD : 0.268 RSD (7.): 49.30

LANCASTER LABORATORIESGFAA „DATE:--C211»REVIEWER

Se ID: 1900991 Seq. No. : 00015 A/S Pos. : 3 Date: 12/21/92

Replicate 1 Time: 21:32Peak Area (A-E3): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A)*: 0.009Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.51

Replicate 2 Time: 21:34Peak Area (A-c): 0.002 Peak Height (A): 0.004Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.49

Mean Cone (ug/L ): -0.50 SD: 0.019 RSD( 7. ) : '"3772"- -

Recovery is 0.5% (outside of specified limits)


Replicate 1 • Time: 21:37Peak Area (A-s): 0.047 Peak Height (A): 0.063ackground Pk Area (A-s): 0.015 Background Pk Height (A): 0.014

nk Corrected rPk Area (A-s): 0.045centration (ug/L ): 20.20


Mean Cone . (ug/L ): 20.05 SD : 0.217 RSD( 7. ) : JT.08 "

QC sample is within range 18. 00 - 22. 00

Se ID: CCB Seq. No. : 00017 A/S Pos. : 0 Date: 12/21/92


Replicate 2 Time: 21:44Peak Area (A-s): 0.003 Peak Height (A): 0.004

ckground Pk Area (A-s): 0.011 Background Pk Height (A): 0.012nk Corrected Pk Area (A-s): 0.000centration (ug/L ): -0.21

Mean Cone (ug/L ): -0.Tgf ' SD : 0.028 RSD ( 7. ) : "T I 73•*iQC sample is within range -3.00 - 3.00

LAr -CASTfn LABORATORIESGFAADATG: DEC 2 i 1992REVIEWER

Se ID: BLANK 356 001 Seq. No.: 00018 A/S Pos.: 4 Date: 12/21/92

Replicate 1 Time: 21:46Peak Area (A-s): 0.002 Peak Height (A): 0.003Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.58

licate 2 Time: 21:48k Area (A-s): 0.003 Peak Height (A): 0.004

ckground Pk Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.001 *;:••£*'•Concentration (ug/L ): -0.05 • °'

Mean Cone (ug/L ): £07SF—" SD: 0.376 ft Ffc3c|<9G83&0.57*e .. ......................^ .........................

Element Filp: SEFAST.GELElement: So Analyst: MST 744Print Data: Main+Suppl. Peak Storage: NonePrint: Cnlib. Curve+Elem. Params.

INSTRUMENT: 5100 Technique: HGA Version: 7.10Wavelength: 196.0 Peak Slit: 2.0 LowSignal Typ": Zeeman AA Signal Measurement: Peak AreaRead Time: 5.0 Read Delay: 0.0 BOC Time: 3Sample Replicates: 2Standard R-- plicates: 2 Spike Replicates: Same as Sample

CALIBRAT1','!!:Solutior.r

#2Calib. BinsStandard 1Standard 2Standard 2<Standard -1Standard GSamplesDiluent Location: 0Modifier #1 Location: 39 Modifier #2 Location;Calibration Units: ug/L Sample Units: ug/LCalibration Type: Linear

Furnace Tine/Temperature Program:

ID

C04 7 x

S5S15S25S40550

Cone 1 Location1

_ _ _ _ _ _ _ _ _ _ ! 05.001 4015.001 4025.001 4040.001 4050.001 40

_ - _ - . _!_, _ _ »

Volume

f /%2026101620•301

DiluentVolume

220161262•7

Mod:)#11111111

Step123456

Tenp Pamp Hold12?> 2 35131? 2 10220 2 5

115G1 2 1018010 0 324P>C» 1 2

Gas Flow2502502502500

250

Read

*

Gas TypeNormNormNormNormNormNorm

BKQ.CCRa:B2 ? 6 M1

Injection Temp: 120 Pipette Speed: 75JC Extraction System: Off


1 Pif--t diluent + modifier 1 * spike •»• sample/std2 Run HGA steps 1 to End

CHECKS:Recalibr.-;*. ion Type: Completely RecalibrateLocationr: None

Cone. Ab•••-•»•• Calibration Action: Print Message OnlyAlternate Tnmple Volumes (uL):Run Alternate Volume Blanks: No

Recovery Measurements:1 uL of 7100 ug/L Standard at Location 37 Gives 10.00 ug/LMeasure Roeovery on Samples: 2-40Add to QC Samples: N'J 7. Recovery Limits: 85.0 to 115.0

SR3I9087

QC:#1 A/S I QC Sample I Cone. Limits I After I Periodic I At I Count Asl

I Loc. I ID 1 Lower Upper I Calib I Check !Endl Sample I1 36 ICV 18.00 22.00 X

0 ICB „ -3.00 3.00 XCCV 18.00 22.00 X X

0 C C B ' -3.00 3.00 X XRun Periodic QC Samples: 2,7,12,17,22,27,32Out of Limit Action: Print Message Only

Matrix Check Calculations:*/. Difference for Dupls: No Locations:7. Recovery for Spike: No Locations: Cone: DATA VERIFIED

WITH AN X BY;

LANCASTER LABORATORIESGFAA SEDATE: DEC 2 2 1992REVIEWER

flR3J9088


'Se !_D: S0 Seq. No. : 00001 A/S Pos. : 0 Date: 12/2


Replicate 2. Time: 22:40Peak Aren <A-s): 0.003 Peak Height (A): 0.004Background Pk Area (A-s): 0.007 Background Pk Height (A): 0.011Blank Coireeted Pk Area (A-s): 0.000Concentration (ug/L ): 0.68

'wi H fe +*

9

* *'Mean Cone (ug/L ): Z&l. SD: 0.002 \ RSD*< % t 0 . 29,'




Replicate 2. Time: 22:45Peak Area '.A-s): 0.015 Peak Height (A): 0.018Background PI: Area (A-s): 0.010 Background Pk Height (A): 0.008Blank Con«-'-ted Pk Area (A-s): 0.012Concentration (ug/L ): 5.47

..Mean Cone (ug/L ): $ 5. 38*"' SD: 0.122 . fRSDC/.): 2.27

Standard number 1 applied. [5.00]Correlation coefficient: 1.00000 Slope: 0.0023 t Int: 0.000

Se ''ID: S15 Seq. No. : 00003 A/S Pos. : 40 Date: 12/21/92

Replicate ! Time: 22:47Peak Area <A-s): 0.037 Peak Height (A): 0.047Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.034Concentra*. i m (ug/L ): 14.72

Replicate 2 Time: 22:50Peak Area <A-s): 0.034 Peak Height (A): 0.044Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.012Blank Correeted Pk Area (A-s): 0.032 •Concentration (ug/L ): 13.64 LANCASTER LABOR ATORI

DATH: DEC 2 2 1932

Se &ID: 515 Seq. No. : 00003 A/S Pos. : 40 Date: 12/21/92

Replicate 3 Time: 22:47Peak Area <A-s): 0.037 Peak Height (A): 0.047Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.012lank Corrected Pk Area (A-s): 0.034centration (ug/L ): 14.72

Replicate 2 ; Time: 22:50Peak Area (A-s): 0.034 Peak Height (A): 0.044Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.012Blank Correeted Pk Area (A-s): 0.032Concentration (ug/L ): 13.64 LANCASTER LABORATORIES

GFAAOATH: DEC 22 1932

•if ".•=}! Wjlp ».-,,-..., -r*~-n •ir lWW.'W WMean Cone (ug/L ): f i<U_ijf SD: 0.766 * RSD(7.): 5.40

Standard nun-ber 2 applied. [15.00]Correlation coefficient: 0.99977 Slope: 0.0022 Int: 0.000

Se * ID: S25 Seq. No. : 00004 A/S Pos. : 40 Date: 12/21/92


Corrected Pk Area (A-s): 0.053ion (ug/L ): 23.88

Replicate 2 Time: 22:54Peak Area <A-s): 0.058 Peak Height (A): 0.076Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.017Blank Correeted Pk Area (A-s): 0.055Concentration (ug/L ): 25.07

.__ — «•»„.Mean Cone (ug/L ): £.24. 47.*' SD: 0.844 / RSD<%)<r-3r45-

Standard rvj^ber 3 applied. [25.00]Correlation coefficient: 0.99983 Slope: 0.0021 Int: 0.000


Replicate ! Time: 22:57Peak Area (As): 0.090 Peak Height (A): 0.119Background Pk Area (A-s): 0.024 Background Pk Height (A): 0.026Blank Correeted Pk Area (A-s): 0.087Concentration (ug/L ): 40.32

Replicate 2 Time: 22:59Peak Area (A-s): 0.091 Peak Height (A): 0.123•ground Pk Area (A-s): 0.021 Background Pk Height (A): 0.025

k Correeted Pk Area (A-s): 0.088entratirn (ug/L ): 40.75

Mean Cone 'ug/L ): > 40.54;. SD: 0.303 RSD<%):flRI IStandard number 4 applied. [40.00] HIIW •

Correlation coefficient: 0.99990 Slope: 0.0022 Int: 0.000

Se ID: £50 Seq. No. : 00006 A/S Pos. : 40 Date: 12/21/92

Replicate ! Time: 23:01Peak Area (A-s): 0.109 Peak Height (A): 0.146Background Pk Area (A-s): 0.025 Background Pk Height (A): 0.029Blank Ccrroeted Pk Area (A-s): 0.107Concentration (ug/L ): 48.97

Replicate 2 Time: 23:04Peak Aren (A-s): 0.110 Peak Height (A): 0.145Background Pk Area (A-s): 0.027 Background Pk Height (A): 0.030Blank Correeted Pk Area (A-s): 0.107Concentration (ug/L ): 49.05

LANCASTER LABORATORIESGFAA SEn/'~~: DEC 2 2 1992

J •«"•» — ' ——— "• -mwHftMean Cone 'ug/L ): ? 49.01' SD: 0.055 ' RSD ( 7.) : 0.$

Standard nti-iber 5 applied. [50.00]Correlation coefficient: 0.99983 Slope: 0.0021 Int: 0.001

Display Calibration - C;\ftOSER\flft_FILES\ELEHENT\SEFftST.6ELQ.107i

LinearCorr. Coef.: B.99983Slope: 8.BB21Intercept; B.BB1


A R 3 1 9

Se ID~: ICV-'* Seq. No. : 00007 A/S Pos. : 36 Date: 12/21/92

Replicate • 1 Time: 23:07Peak Area (A-s): 0.051 Peak Height (A): 0.068Background Pk Area (A-s): 0.013 Background Pk Height (A): 0.016Blank Corrected Pk Area (A-s): 0.048Concentration (ug/L ): 22.06

Replicate 2. Time: 23:09Peak Area (A-s): 0.050 Peak Height (A): 0.066Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.015Blank Corrected Pk Area (A-s): 0.047Concentration (ug/L ): 21.64

. ..- .nr, n«7 < -

Mean Cone <ug/L_ ): * "2'i.4 SS*'"" SD: 0.298 RSDC2T

QC sample i" within range 18.00 - 22.00

ID: ICB Seq. No. : 00008 A/S Pos. : 0 Date: 12/21/92

Replicate ! Time: 23:11Peak Area (A-s):-0.005 Peak Height (A): 0.004Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): 0.002Concentr at i r-n (ug/L ): 0.74

Replicate T. Time: 23:14 LANCASTER LABORATORIESGFAADATE: OEC 2 2 199ZREVIEWER

Peak Aren (A-s): 0.004 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.009Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L ): 0.18

• »,— ' - • i - » fMean Cone !ug/L ): f 0. 46$T SD : 0.399 RSDJ7.):

QC sample in within range -3.00 - 3.00

Se ID: CRA Seq. No. : 00wwy A/ia ros. : x ua\.e: j

Replicate 1 Time: 23:16Peak Area (As): 0.015 Peak Height (A): 0.019Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.009P.lank Corree.t,F?d Pk Area (A-s): 0.012Concentration (ug/L ): 5.40

Replicate 2 Time: 23:19Peak Area (A n): 0.015 Peak Height (A): 0.020Packground Pk Area (A-s): 0.010 Background Pk Height (A): 0.009Blank Correr-t^d Pk Area (A-s): 0.012Concentration (ug/L ): 5.39

Moan Cone (uq/L ): „• S.-39* SD: 0.004 RSDC/.): 0."06""


Replicate 1 Time: 23:21Peak Area (A c): 0.049 Peak Height (A): 0.067Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.015Blank Corrected Pk Area (A-s): 0.046Concentration (ug/L ): 21.21


Mean Cone '.uq/L ): > 2l! 50 ' SD: 0.411 RSD( 7.) r~l-.-9i

QC sample in within range 18.00 - 22.00

Se ^ID: CCB Set*. No.: 00011 A/S Pos.: 0 Date: 12/21/92

Replicate 1 Time: 23:26Peak Area (A-e): 0.003 Peak Height (A): 0.004Background Fk Area (A-s): 0.007 Background Pk Height (A): 0.009Blank Correeted Pk Area (A-s): 0.001Concentration (ug/L ): 0.10

Replicate 2 Time: 23:28Peak Area (A c): 0.003 Peak Height (A): 0.004Background PI: Area (A-s): 0.009 Background Pk Height (A): 0.010Blank Corre^*^d Pk Area (A-s): 0.001 LA'VfP/vConcentratic.;i (ug/L ): 0.01 _";'Mt-AoTER LABORATnnir-«

Gr/\/\ J ' IURIES

Mean Cone (ug/L ): *0. 05^ SD: 0.064

QC sample in within range -3.00 -3.00

So ID: l apsi'. , jeq. No. : 0P012 A/S Pos. : 2 Date: 12/21/92

Replicate 1 r Time: 23:30 ' 'Poak H<Mnht (A): 0.003 fl R { Q (\ Q


•'• "»r»»~0Hl-»Se ID: 1908331$; [JS&LF Seq. No. : 00012 A/S Pos. : 2 Date: 12/21/92

plicate 1 Time: 23:30ak Area (A-s)j 0.002 Peak Height (A): 0.003

Background Pk Area (A-s): 0.008 Background Pk Height (A): 0. 01jZ)Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.44

Replicate 2 Time: 23:33Peak Area (A-s): 0.003 ' Peak Height (A): 0.003'Background Pk Area (A-s): 0.008 Background Pk Height (A): 0. 010Blank Corrected Pk Area (A-s): -0.000Concentration (ug/L ): -0.32

Mean Cone (ug/L ): .-•0_gj|12i'i SD: 0.O85 $RSDTXTr-!-22w49-"' * '" ".J*J<v''-K-

Se 'iD: 19089.91 TS|3UF Seq. No.: 00013 A/S Pos.: 2 Date: 12/21/92


Replicate 2 Time: 23:38ak Area (A-s): 0.020 Peak Height (A): 0.015kground Pk Area (A-s): 0.010 Background Pk Height (A): 0.012ank Corrected Pk Area (A-s): 0.018


Mean Cone (ug/L ): W8V5-r'v SD: 0.359 RSD(7.-)":-4.-37?-

Recovery in 86.07.

Se ID: PBS 356 001 Seq. No.: 00014 A/S Pos.: 3 Date: 12/21/92222222


Replicate 2 Time: 23:43 ~—^Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.008 Background Pk Height (A): 0.011Blank Corrected "Pk Area (A-s): 0.000Concentration (ug/L ): -0.25

Mean Cone (ug/L ): -0.26 SD: 0.009 RSDC/. )^ 3. 46

LA?:~A3TER LABORATORIESe;--A SE; DfCt'r"DtC22im

REVIEWER

Se ID: PB3 356 001 Seq. No.: 00015 A/S Pos.: 3 Date: 12/21/92222222

Replicate 1 Time: 23:46Peak Area (A-s): 0.019 Peak Height (A): 0.025Background Pk Area (A-s): 0.010 Background Pk Height (A): 0.010Blank Corrected Pk Area (A-s): 0.017.Concentration (ug/L ): 7.42

Replicate 2 Time: 23:48Peak Area (A-s): 0.023 Peak Height (A): 0.029Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.013Blank Cor:o~ted Pk Area (A-s): 0.020Concentration (ug/L ): 9.05

Mean Cone (ug/L ): 8.24 SD: 1.151 RSDC/.): 13.

Recovery in 84.97. (outside of specified limits)

Se ID: LCSS /50 Seq. No.: 00016 A/S Pos.: 4 Date: 12/21/92zzzzzzReplicate 1 Time: 23:51Peak Area (A-s): 0.033 Peak Height (A): 0.044Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.012Blank Corrected Pk Area (A-s): 0.030Concentration (ug/L ): 13.79 Corrected Cone (ug/L ): 689.

Replicate 2 Time: 23:53Peak Area (A-s): 0.032 Peak Height (A): 0.045Background Pk Area (A-s): 0.014 Background Pk Height (A): 0.012Blank Corrrrrted Pk Area (A-s): 0.030Concentration (ug/L ): 13.63 Corrected Cone (ug/L ): 681.

Mean Cone 'ug/L ): 13.71 SD: 0.114 RSDC/.): 0. £ 3Corrected Cone (ug/L ): 685.

Se ID: LCSS /5JZ| _ _ _ _ Seq. No.: 00017 . A/S Pos.: 4 Date: 12/21/92

Replicate 1 Time: 23:56Peak Area (A-s): 0.064 Peak Height (A): 0.094Background Pk Area (A-s): 0.016 Background Pk Height (A): 0.020Blank Cori^rted Pk Area (A-s): 0.061Concentration (ug/L ): 28.10 Corrected Cone (ug/L ): 1405.

Replicate 2 Time: 23:58Peak Area 'A-s): 0.059 Peak Height (A): 0.085Background Pk Area (A-s): 0.017 Background Pk Height (A): 0.018Blank Conreted Pk Area (A-s): 0.057Concentrati'in (ug/L ): 26.16 Corrected Cone (ug/L ): 1308.

Mean Cone (ug/L ): 27.13 SD: 1.373 RSD (7.) :Corrected Cone (ug/L ): 1357.

Recovery in- 134.37. (outside of specified limits)

- ranuBORATon,

flR3l9fl,95f • rt>

'

Se ID: 1907608 -» •» "j -» -y •» Seq. No.: 00018 A/S Pos.: 5 Date: 12/21/92££££££Replicate 1 Time: 00:01Peak Area (A-s); 0.004 Peak Height (A>: 0.005Background Pk Area (A-s): 0.047 Background Pk Height (A): 0.031lank Corrected Pk Area (A-s): 0.001ncentration (ug/L ): 0.36



Se ID: 1307608 Z Z Z Z Z Z Seq. No.: 00019 A/S Pos.: 5 Date: 12/22/


Replicate 2 -_ Time: 00:08Peak Area (A-s): 0.023 Peak Height (A): 0.030Background Pk Area (A-s): 0.053 Background Pk Height (A): 0.033Blank Corrected Pk Area (A-s): 0.021Concentration (ug/L ): 9.36

n Cone (ug/L ): 8.25 SD: 1.564 RSDC/.): 18.95

Recovery in 80.4% (outside of specified limits)

Se ID: 1737608D Z Z Z Z Z ZSecl- No- : 00020 A/S Pos.: 6 Date: 12/22/9:5

Replicate ! = Time: 00:10Peak Area (A-s): 0.004 Peak Height (A): 0.005Background Pk Area (A-s): 0.041 Background Pk Height (A): 0.041Blank Corrected Pk Area (A-s): 0.001Concentration (ug/L >: 0.15


Mean Cone 'ug/L ): -0.03 SD: 0.260 RSDC/.): 851. 2C

Se ID: 1'->2>7608D Seq. No. : 00021 A/S Pos. : 6 Date: 12/22/ 2

Reolicate 3 Time: 00:15• k Area 'A-s): 0.023 Peak Height (A): 0.033

kground Pk Area (A-s): 0.045 Background Pk Height (A): 0.041

LANCASTER LABORATORIESSE Iftef

!9096f "*"

Se ID: 1907608D Seq. No.: 00021 A/S Pos.: 6 Date: 12/22/ 2ZZZZZ Z


LANCASTER LABORATORIESGFAA SEDATS: DEC 2-*,

Blank Corrected Pk Area (A-s): 0.021Concentration (ug/L ): 9.29

Replicate 2 Time: 00:18Peak Area 'A-s): 0.021 Peak Height (A): 0.028Background Pk Area (A-s): 0.041 Background Pk Height (A):Blank Correeted Pk Area (A-s): 0.018 [^>Concentration (ug/L ): 8.14

Mean Cone (ug/L ): 8.71 SD: 0.813 RSD (7.) : 9.33

Recovery ic, 87. 47.

Se ID: CCV~~**? Seq. No. : 00022 A/S.Pos. : 36 Date: 12/22/92

Replicat^ 1 Time: 00:20Peak Area (A-s): 0.045 Peak Height (A): 0.055Background Pk Area (A-s): 0.015 Background Pk Height (A): 0.013Blank Cor:neted Pk Area (A-s): 0.042Concentration (ug/L >: 19.37

Replicatr 2 Time: 00:23Peak Area (A-s): 0.048 Peak Height (A): 0.057Background Pk Area (A-s): 0.018 Background Pk Height (A): 0.015Blank Corrreted Pk Area (A-s): 0.045Concentration (ug/L ): 20.77

._—,.. <»•*•!».«£> f - >•

Mean Cone (ug/L ): 20". 07*? SD: 0.990 RSDC/.): 4. 94

QC sample ia within range 18.00 - 22.00

Se ' ID: rCB Seq. No.: 00023 A/S Pos.: 0 Date: 12/22/92

Replicate 1 Time: 00:25Peak Area (A-s): 0.003 Peak Height (A): 0.004Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.011Blank Connoted Pk Area (A-s): -0.000Concentration (ug/L ): -0.28

Replicate 2 Time: 00:27Peak Area (A-s): 0.003 Peak Height (A): 0.003Background Pk Area (A-s): 0.009 Background Pk Height (A): 0.011Blank Coi i r.~ted Pk Area (A-s): 0.000Concentration (ug/L ): -0.21 ,

• '-ran-*!?** i '"rW|~'''*»B* .,___Mean Cone (ug/L ): -9.24 SD: 0.046 RSD(7.): 18.96''

*

QC sample i r: within range -3.00 -3.00 n l n n n-> 'ft R 3 i 9 o 9 /

'?B * »- _ _ *-j

\V <=n i-- ± *=*. i-n S f=n=«. c_ -fc r— *=i 3 O O .<•" "^ O O

G| C R" i-" r-> IT o cr cor 1 IFt <=> F* ca r•- "fc

OPERATOR NSM 823 7BO3 RPDATF MOW 71 DEC 1992PATCH TL 9235606


IF THERE IS AN ERROR STOPQC "SPIKE POSITION 52RECOVERY LIMITS (7.) 85 TO 115RECOVERY MINIMUM LIMIT (7.) 40CORRELATION COEFFICIENT (r) 0.995OVFRRANRF VOM (ME REDUCTION 1 LANCASTER LABORATORIES

INSTRUSV3ENTID#2803

BKGCORR: BD

PROGRAM ? Tl CLP

INSTRUMENT MODE ABSORBANCE: CALIBRATION MODE CONCENTRATION

MEASUREMENT MODE PEAK AREALAMP POSITION 4LAMP CURRENT (mA) 3SLIT WIDTH (nm) O.5SLIT HEIRHT NORMALWAVFI .FNRTH (nm) 276.8SAMPLE INTRODUCTION SAMPLER AUTOMIXING

; TIME CONSTANT O.OSMEASUREMENT TIME (sec) 1.0RFPLICATFR 2BACKGROUND CORRECTION ON

FURNACE PARAMETERS^lEF TEMPERATURE TIME GAS FLOW GAS TYPE READMR. /n> (see) (L/min) COMMAND

.1 2 2O 2P5.0 3.0 NORMAL NO2 22O 15.0 3.O ' NORMAL NO•* 400 10.0 3.0 NORMAL NO'1 700 15.0 3.0 NORMAL NO

700 20.0 3.0 NORMAL NOA 100 3.0 3.0 NORMAL NO7 100 2.0 3.0 NORMAL NOP, I oO 2.0 0.0 NORMAL NO<? 7600 1.3 0.0 NORMAL YES10 ?600 7.0 O.O NORMAL. YES11 r?'iOO O.P5 3.O NORMAL. NO12 26OO 4.O 3.0 NORMAL NO1'. 100 17."=; 3.0 NORMAI NOU! loo f=!.0 3.0 NORMAL NO

SAMPLER PARAMETERSVOI LIMES (fL)


PI AMI- — • 20 5STANDARD 1 2 J8 5STANDARD ? .5 15 5STANDARD 3 10 1O 5STANDARD 4 15 5 5

SAMPl E 20 0 5

RECALIBRATION RATE 0RESI OPE RATE 0

MULTIPLE INJECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE 95INJECT RATE 1O


QC STANDARD RATE 20OC INITIAI STANDARD POSITION 50OH INITIAL BLANK POSITION 51QC CONTINUING STANDARD POSITION 50OC CONTINUING BLANK POSITION 51OC STANDARD VOLUME (fL. ) 2Onn STANDARD CONCENTRATION 4O.O ppbOC STANDARD LIMITS (7.) 90 TO 110QC SPIKE RATE 1Qf" SPIL'E VOLUME (fL) 4QC SPIKE CONCENTRATION 10O.O ppb DATA VERIFIEDMATRIX SPIKE CONCENTRATION 0.0 ppb WITH AM Y DVf _-xJ?INSTRUMENT DETECTION LIMIT 1.2 PPb VVIIH AIM X BYI 3^PEON I RED DETECTION LIMIT 10.O ppb

SAMPI F CONC 7.RSD MEAN READINGSppb ABS

E'l AN!1 O.O -0.OO2 -O.O02 -O.OO1OF 71Dpr92 19:54

CONCENTRATION LESS THAN I HI

STANI'-ARI) 1 Jn.O O.A O.O37 O.O37 O.037Of. - / 21Dec92 2O:01

? 25.0 O.5 O.O89 O.OB9 O.O8921Dec92 20:O7

50.0 1.5 O.168 O. 17O O.I 6621Dec92 20:14

LANCASTER LABORATORYSTANDARD 4 75.0 1.6 0.725 O.227 0.222 RpAA ' ""'WniCwQC .., 21Dec92 20:21 A.J '""DATE; 2 2 199Z

APT. s 100.0 1.8 0.288 0.291 0.284 REVIEWER21Dec92 2O:27 *

SR3I9099

SAMPLE CONC V.RSO MEAN READINGSppb ARS

•4O.7 2.4 0..14O 0.147 O.I 37

C . ^ """ 21D(?c92 20:33' • "/.R = (10.1 .99\

I CB -~O.R 99.9 -O.O03 O.OOO -O.OO6OC * 21. Dec 92 20S40

ABS = -O.OO3CONCENTRATION LESS THAN I DL

10,8" 5.8 0.040 O.O39 O.O42:. . 21Dec92 2O:46

OCSP1KF A 31.8 2.3 0.111 0.109 0.1 13QC " ". - 2lDec92 20:53

'- 7.R = 104.8

CHV 1 42-6 O.5 O.I 45 O.J45 0.146Qr 2iDec92 s>r»: 59 LANCASTER LABORATORIES7.R =CCB 1 -D.I 99.9 -O.OOO -O.OO2 0.001 DATE.'jfffjjgQC 21Dec92 21:05 REVIEWER .„„-,„ .

ABS = -0.001 A - A /i.J-7)^ ; CONCENTRATION LESS THAN ID!....

.354 O71 O,3 99.9 O.OOJ -O.OO3 O.OO5: '-" - 21DPC92 7t : 1.2

CONCENTRATION LESS THAN/1 HI

OCSPTI-rE A 27.6 3.5 O.O81 0.079 0. 083OC - 21Dec92 21: 18

I CSW 354 0-] 51.2 3.4 0.171 0.175 0.167QC , , , , /y •' , 21Dec92 21:24

OCSPII-:F A 77.6 2.2 O.231 O.235 O.22Or 21Dec92 21:31

•/.R = 132.2^ .". - fiR FA I LCD-; — nrrTAT TV

l^oR^sri (). 1 99.9 O.OOO "O.Of>3 — O.OO2OC " """"" 21D<?e92 21:37

CONCENTRATIOfJ I ESS THftN IDL

QCFPII F A 22.1 1.9 O.079 O.O7R O.O8OQC - - 21Dec92 21:44

^. - V.R = 1 1 0 . 3

19OR351 O.1 R4.4 O.OOO O.OO1 O.OOOHC : 21Dec92 21:50

C A CONCENTRATION LESS THAN IDL

FSF'II-F A 73.4 0.7 O.084 O. 084 0.083QC W 21 Dec 92 21:57

"/.R = 1 37. 2.SAMPLE CONC ',50V. OF

SAMPLE CONC 7.RSD MEAN READINGS/r ft PFb ABSJ WMy^

1C'OB352R 53.1 1.9 O.I 76 O.I 78 0.1.74

QC Z Z Z Z Z Z 2iDec 92 22: °3nCQPlKE A 77.8 1.4 0.232 0.230 0.234QC 21Dec92 22:10

•/.R = 123.'T1 FAT I CD • PFFFTtT PY

43.7 0.5 O.I 49 O.I 48 O.I 49

NCASTER LABORATORIESX3FAA

HCB 7 -0.1 99.9 -O.OOO O.OO1 -0.001 nATF- UFf 9 9WQ7utt' ~nr '?

ABS = -ro REVIEWERCONCENTRATION LESS THAN ID

1 9( 1R353D -0 .2 99 . 9 -0 . OO 1 -0 . OOO -0 . 00 1OC 21Dec92 22:29

CONCENTRATION LESS THAN

KF A 22-9 5.O O.O82 O.O85 O.O79QC 21Dec92 22:35

7.R = 114.7

190R354 1.1 89.1 O.O04 0.006 O.O01QC _ _ 21Dec92 22:41


OCSPTI-F A 73.7 4.8 O.O85 O.O87 O. O82QC W 21DPC92 22:48

•/.R = 118.2SAMPLE CONC <5QV. OF SPIKE CifNCENTRATIOt

19OR'%55 -O.3 99.9 -O.O01 O.OO1 -O.OO3QC 21Ppc92 22:54

CONCENTRATION LESS THAN IDI

QCSPIKF A 21.8 1.5 0.078 O.O79 O.O78QC • .... 21D*=c92 23:01

•/.R = 1O9. 1

1 •'• ^ "'56 -O.2 99.9 -O.OO1 -O.OO2 O.OOOrtC 21 Dec 92 23:07

CONCENTRATION LESS THAN IDL.

QCSPIKE A 22.4 4.0 O.OBO O.O83 0.078QC 21Dec92 23: 14

7.R = 112.1

57 -O.3 99.9 -O.OO1 O.OO7 -O.OO4QC 21Dec92 23:2O


QCSPU-F A 23. h _ 1.7 O.OR4 O.O83 O.O85OC W 2lD«?c92 23:26

7.R = 117.9SAMPLE CONC <5OV. OF SPIKE C

aICEIMTFATtn

319)0)

CONC V.RRD MEAN READINGSpph ABS

r-f~^' 3 45.7 1.3 0.155 O.I56f a 21 Dec92 23:33 LANCASTER LABORATORIES

•/.R = 114.2

DATE: KC22 MRREVIEWER^^^

\i"- i -si 171 Sper'cr'bf* ^ 3 *.„> O .X «...* <-..* \

~ C3 CT C3 1 R! 65? pa C3" I""* "t

OPERATOR RSR 171 2803 BDDATE TLJE 22 DEC 1992BATCH TL 9235701


TF THERE IS AN ERROR STOPQC SPIKE POSITION ' 52RECOVERY LIMITS C/.) 85 TO 115RECOVERY MINIMUM LIMIT C/.) 4OCORRELATION COEFFICIENT <r) 0.995OVFRRANBE VOLUME REDUCTION 1REPLICATE RSD LIMIT (7.) 10O.O

LANCASTER LABORATORIESINSTRUMENT ID #2803

PFHHRAM 2 TI CLP . BKG CORR: BD

INSTRUMENT MODE ABSORBANCECALIBRATION MODE CONCENTRATIONMEASUREMENT MODE PEAK AREALAMP POSITION 4LAMP CURRENT (mA) 3SLIT WIDTH (nm) O.5SLIT HEIGHT NORMAL .WAVELENGTH (nm) 276.8SAMPLE INTRODUCTION SAMPLER AUTOMIXINGTIME CONSTANT O.O5MEASUREMENT TIME (sec) l.OREPI I GATES 2BACKGROUND CORRECTION ON

A

EURNACE PARAMETERS^lEP TEMPERATURE TIME GAS FLOW GAS TYPE READNfi. (O (SRC) (L/min) COMMAND

1 770 25.O 3.0 NORMAL NO2 220 15.O 3.0 NORMAL NO

40O 1O.O 3.0 NORMAL NO4 7OO 15.O 3.O NORMAL NO5 7OO 2O.O 3.O NORMAL NOA 100 3.O 3.0 NORMAL NO

100 2.0 3.0 NORMAL NOP. lc>0 2.0 O.O NORMAL NO9 7600 1.3 0.0 NORMAL YES10 7600 7.0 O.O NORMAL YES11 7600. 0.5 3.O NORMAL NO1? 260O 4.O 3.0 NORMAL NO '''-3 \.13 100 12.5 3.O NORMAL NO ' '"Jk

NORMAL NO .r, 3 | g . ..——_————————————————————————— —— ———— —— T*rTt \f I J I {J <J

SAMPLER PARAMETERSVOLUMES (fL)


ANK — 2O 5STANDARD 1 2 18 5STANDARD 2 " 5 15 5RTANHARH 3 10 10 5STANDARD 4 15 5 5STANDARD 5 :: 20 0 5SAMPI E ., ' 70 0 5

REGAL IRRATION RATE 0RESLOPE RATE O

MULTIPLE INJECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE. 95INJECT RATE JO


QC STANDARD RATE 2OQC INITIAL STANDARD POSITION 5OOC INITIAL BLANK POSITION . 51.QC CONTINUING STANDARD POSITION 5OQC CONTINUING BLANK POSITION 51QC STANDARD VOLUME (fL) 2OQC STANDARD CONCENTRATION 40.0 ppb t/coi-irnnc STANDARD LIMITS (7.) 90 TO 110 DATAVtRlrltUoc SPIKE RATE , i WITH AN X BY:QC SPIKE VOLUME (fL) 4QC F5PEKE CONCENTRATION 1OO.O ppbMATRIX SPIKE CONCENTRATION O.O ppb .INSTRUMENT DETECTION LIMIT 1.2 pph .RFOIIIRED DETECTION LIMIT 1O.O ppb

SAMPLE CONC 7.RSD MEAN READINGSpph ABS

F:l ANL O.O 0.016 0.016 O.O 15r:ic 22Df=c92 01: 19

CONCENTRATION LESS THAN IDI,

cilANDAPr.' 1 1G.O 1 1 . 1 O.O43 O.O4O O.O46QC , 22De?c92 01:25

7 25.0 1.7 O.O98 O.O99 O.O97 . AMpACTPR LABORATORIES

5o.o o.o 0.173 0.173 0.174 DATE:• 22Dec92 01:39 REV,EWER

ANDARD 4 75.0 1.9 0.242 O.239 0.245QC/ _, ., 22Dec92 01:46

10O. O 3.4 O.3O2 0.310 0.295 „. «QC 22Dec92 01:52 ft R 3 I 9 i 0 U

m :>'•' ''

SAMPLE CONC 7.RSD MEAN READINGSppb ABS

ICV 38.Pi 1.8 0.141 0.143 0.139QC 22Dec92 01: SB

7.R = 96. 1

ICB -2.2 61.7 -O.O10 -0.014 -O.O05QC 22Dec92 O2iO4

ABS « -O.OO5CONCENTRATION LESS THAN IDL

CRA . 8.6 3.6 0.037 O.O38 O.O36QC • 22Dec92 O2:ll

QCSPIKE A 31.3 2.4 O.I 19 O.121 O.I 17QC 22Dec92 02s17

7.R = 113.4

CCV 1 38.4 2.7 0.140 O. 138 O. 143 . AMr.ACTnD • AD/IRA™-..,-,*or 2Dec92 02»24 LANCASTER LABORATORIESGFAA TL 'DATE: DEC 22 M

CCB 1 -1.1 33.1 -O.OO5 -O.O06 -O.OO4 RpWIC\A/pn x»h,QC 22Dec92 O2:30 ncvicvv«=n /TP<

ABS = O.OOOCONCENTRATION LESS THAN IDL

CHULT190835P -O.O 99.9 -O.OOO -O.OO4 O.OO4-QC 22DBC92 02:36

CONCENTRATION LESS THAN IDICHULT A

QCSPIKE A 22.2 4.7 O.O89 O.O86 O.092QC 22Dec92 O2s43

7.R = lll.OCHULF ————

1908359 -O.4 37.3 -O.OO2 -O.OO1 -O.002QC 22Dec92 02a 49

CONCENTRATION LESS THAN IDLCHULF A : '& : '-

QCSFIKE A 19.9 5.4 . O.O81 0.084 O.'O77QC ' 22Dec92- 02:56

7.R = 99.5

19OR9R1 O.3 . 29.1 O.OO1 O.OO2 O.OO1QC 22Dec92 O3:O2


QCSPH E A 20. 8 6.5 O.OR4 O.080 O.O88QC 22Dec92 03:09

7.R » 104. 1

190R9O7 0.7 99.9 O.OO3 -O.OOO O.OO6OC 22Dec92 O3:15

CONCENTRATION LESS THAN IDIJ56FLA

QCRPIKF A 22.2 2.2 O.O88 O.09O O.OB7QC 22Dec92 03:22

7.R = HO. 88R3i9i05


CRCH-B3 -O. J. 99.9 -O.OO1 O.OO1 -O.O02

QC 22D<?c92 03:28CONCENTRATION LESS THAN IDL/

CRCH- A ' ' /riCSPTKF A 71.3 1.2 O.OB5 0.086 0.085nc: 22Den92 O3:35

7.R = _106.4

CCV 2 39.6 2.B O.I 44 O.I 41 0.147 AEsrvaATfiniFfiQC 22Dec92 O3:4l LANCASTER LABORATORIS.S

7.R = 99.0

-O.7 45.1 -O.O03 -O.OO4 -O.O02 DATE". Q£Q 2 2x199222Dec92 03:47 REVIEWER fi.T>(- t"-lABS = O.OO2CONCENTRATION LESS THAN IDL

1 90RP84 0.4 99.9 O.O02 O.OO3 O.OOOQC 22Dec92 03:53

CONCENTRATION LESS THAN IDL.CRCHF A

QCSPIKE A 20.9 1.9 O. OB4 O.O83 O.O85QC 22D(?c92 04:00

7.R = 104.3.

-O.2 99.9 -0.001 -0.OO2 O.OOOQC 22Dec92 04:06

CONCENTRATION LESS THAN IDI.CRTT& A

QCSPUF A 21.2 2.6 O.OB5 O.OB4 O.OS7QC 22Dec92 04:13

7.R .= 106.2

}90R'7RA 0.7 22.5 O.003 O.OO3 O.O02QC . 22Dec92 O4:19

CONCENTRATION LESS THAN IDIJS6W A •••"

Hf;SPTLF A 23.4 4.O O.O93 O.O9O O. O95QC : W 22Df?c92 04:26

7.R = U6.B ,SAMPLE CONC <5O7. OF SPIKE CONCENTR AT

J&MTF19099R7 0.7 95.2 O.OO3 O.OO5 0.001QC 22De>c92 04:32


;:i(-.P:F- TLF A 21.8 3.9 0. 087 O.089 0. OB5QC 22Dec92 04:38

7.R = 1OB.7

19Of?9nR 0.6 33.5 0.002 0:OO2 O.OO3QC. . 22De?c92 04:44

CONCENTR AT I ON 'LESS THAN ID!CHRDW A

QCSP I L F. A 21.3 5.6 0 . OB5 0 . OB? 0 . -OR9OC 22Dec92 O4i

7.R = 106,\l5i flR3l9!06

SAMPI F CONC 7.RSD MEAN READINGSppb . ABS

CCV 3 42.1 1.3 O.151 O.ISO O.153QC 22Dec92 04:57

•/.R = _K)5.3.

o.o o.ooi o.ooi o.ooi 25S*™" ""QC 22Dec92 05:04 REVIEWER fbG-

ABS = O.O06CONCENTRATION LESS THAN IDL

CHRDF1908989 0.9 38.3 0„OO4 0.OO5 O.OO3QC 22Dec92 OS:10

CONCENTRATION LESS THAN ICHRDF A

QCSPIK E A . 21.4 4.3 O.OS6 O.O83 0.O88QC 22Dec92 05:16

7.R = 106. 8

1908990 0.9 99.9 O.OO4 O.OOO 0.O08QC 22Dec92 05:23

CONCENTRATION LESS THAN IDIJSBLTA

QCSPIK F A 21.7 3.2 0.O87 0.089 0.085QC 22De?c92 05:29

7.R = 108.7JS6LF ~~

190B991 O.2 99.9 O.OO1 O.OO3 -0.OO1QC 22Dec92 05:36

CONCENTRATION LESS THAN IDLJS6LF A

QCSPIKE A 21.7 0.6 0.087 0.087 0.087QC 22Dec92 05:42

7.R = 108.5CRHLT ' —

1908992 O.B. 99.9 O.O03 O.OOI O.OO6QC 22Dec92 05:48 <L.

CONCENTRATION LESS THAN IDLCRHLT A

QCSPIKE A 23.9 3.8 O.O94 O.O92 0.O97QC W 22Dec92 05:55

7.R = 119.3SAMPLE CONC <507. OF SPIKE CONCENTRATI

190R<39r. O.9 65.7 O.OO4 O.OO2 O.OO6QC 22Dec92 O6:O1

CONCENTRATION LESS THAN IDLCRHLF A

QCSP ] I F (« 22. 9 1.9 O. O91 O. O9O 0. O92QC 22Dec92 O6:08

7.R = 11 14.6

CCV 4 43.5 1.3 0.155 0.154 0.157QC 22Dec92 06:14

7.R = IPS. 7

CfB 4 1.1 11.8 0.005 O.OO4 0.005 • i"?wQC 22Dec92 O6:21 ""

ABS = 0.010 flR3!9i07CONCENTRATION LESS THAN IDL.

\t"* i <=i n f=ns c=:±;t f f 3 O O / -4- O O

jl Ft o f=* CD i-" Hb

OPERATOR RD6 114 28O3 BDDATE , TUE 22 DEC 1992BATCH TL 92357O4


IF THERE IS AN ERROR ' STOPQC SPIKE POSITION 52RECOVERY LIMITS (7.) 85 TO 115RECOVERY MINIMUM LIMIT (7.) 40CORRELATION COEFFICIENT (r) O.995nVFRRANGE VOLUME REDUCTION 1REPLICATE RSD LIMIT (7.) 1OO.O

LANCASTER LABORATORIESINSTRUMENT ID #2803*? T1 CL F1BKGCORR: BD

INSTRUMENT MODE ABSORBANCECALIBRATION MODE CONCENTRATIONMEASUREMENT MODE v PEAK AREALAMP POSITION 4LAMP CURRENT (mA) 3 .jSLIT WIDTH (nm) O.5 .SLIT HEIGHT NORMAL '•'-.- •'"'•''•WAVELENGTH <nm) 276.8SAMPLE INTRODUCTION SAMPLER AUTOMIXINGTIME CONSTANT 0.05MEASUREMENT TIME (sec) l.O:

1 REPLICATES 2 j^BACKGROUND CORRECTION ON fl v


1 220 25.0 3.0 NORMAL NO2 720 15.0 3.0 NORMAL NO

400 "10.0 3.0 NORMAL NO4 700 15.0 3.0 • NORMAL ' NO5 7OO; 2O. O 3.O NORMAL NO6 tOO 3.O 3.O NORMAL NO7 10O • 2.O 3.0 NORMAL NO8 100 2.O 0.0 NORMAL • NO

26OO 1.3 O.O NORMAL YES10 2600 2.O O.O NORMAL YES11 . 2600 0.5 3.0 NORMAL NO17 260TO 4.0 3.0 NORMAL NO13 100 1.2.5 3.0 NORMAL NO14 100 5.0 3.0 ' NORMAL NO -fl R J ?3$ Q 8

SAMPLER PARAMETERSVOLUMES (fL)

SOU IT I ON BL ANK MOD IFIER

BL ANK — 2O " 5STANDARD 1 2 IB 5STANDARD 7 5 1 5 5STANDARD 3 1O 1O 5STANDARD 4 15 5 5STANDARD 5 2O 0 5SAMPLE ; 20 _ . . 0 5

REGAL I BRAT I ON RATE ORESLOPE RATE O

MULTIPLE INJECT NO HOT INJECT YES PRE INJECT NOTEMPERATURE 95INJECT RATE 1O


QC STANDARD RATE 20QC INITIAL STANDARD POSITION 50QC INITIAL BLANK POSITION 51 n&TA V/CRIClcnOC CONTINUING STANDARD POSITION 5O UAIA VERIFIEDQC CONTINUING BLANK POSITION 51 WITH AN X BY:QC STANDARD VOLUME (/L) 20PC STANDARD CONCENTRATION 4O.O ppbQC STANDARD LIMITS (7.) 90 TO 110DO SPIKE RATE 1OC SPIKE VOI LJME (fl.) 4QC SPIKE CONCENTRATION 10O.O ppb 'MATRIX SPIKE CONCENTRATION 0.0 ppb . :INSTRUMENT DETECTION LIMIT 1.2 ppb . •.?••»REQUIRED DETECTION LIMIT 1O.O ppb -

SAMPLE CONC 7.RSD MEAN '• READINGS

Bl ANK O.O O.019 0.017 O.022QC ' 22Dec92 17:09

CONCENTRATION LESS THAN IDI.<r//r.

STANDARD l 1O.O 1.9 O.O46 O.O47 O.O4622Dec92 17:16

STANDARD ? 25. o 5.7 o.io4 o.i OB o.ioo LANCASTER LABORATORIES"r'<S5? . 22Dec92 17=23 GFAASTANDARD 3 5O.O 0.5 0.188 0.189 0.187 DATE: DEC 2 3

22Dec92 17!29SIANOARD '1 75.0 O.6 0.263 0.262 0.264

22DPC92 17:36

STAND API i r. 1 00.0 O.9 O.329 0.327 O.331QC 22Dec92 17:42

SAMPLE CONC 7.RSD MEAN READINGSppb . ABS

;V 42.0 O.3 O. 161 O.161 0.1.6122Dec92 17:497.R = /104.9 .

TCB 0.8 41.O O.OO4 0.003 O.OO5QC ' 22Dec92 17:55

ABS = 0.010CONCENTRATION LESS THAN IDI

ORA ' 10.8 O.2 O.O5O O.O50 O.O5OQC : 22Dec92 18:01

QCSPIKE A 31.9 0.3 0.128 0.127 O. .1.28QC 22Dec92 18:OS

7.R = 105.5

ccv 1 42.8 1.1 • 0.164 o.i62 0.165 LANCASTER LABORATORIES

•/.ft = (?Q6'.? ATE; DEC 23 1992CCB 1 0.5 99.9 0.002 O.OOO O.OO4 REVIEWERQC 22Dec92 18:21

ABS = O.OO8CONCENTRATION LESS THAN IDL

3AMMT D083530 __. 1.0 92'. 4 0.005 0.002 0.008

22Dec"92 18:27CONCENTRATION LESS THAI\/DL

OCSPTkE A 23.1 3.7 O.O97 O.O95 0. l.OOQC W 22Dec92 18:33

7.R = 115.3SAMPLE CONC <5O7. OF SPIKE CONCENTRATIOh

.1908354 0.7 R8.5 0. OO.3 O. O06 O. OO 1QC 22Dec92 18:40

CONCENTRATION I..ESS TH Xi IDIJAOAPM A

QCSPJNE A 21.5 4.6 O.O92 O.O95 O.089QC 22Dec92 18:46

22222219OB355 1.1 25.5 O.OO5 O.OO6 O.O04QC 22Dec92 18:53222222 CONCENTRATION LESS THA

OCSPIhE A 23.2 0.1 0.097 0.097 0.098QC W 22Dec92 18:59

7.R = 115.9-SAMPLE CONC <5O7. OF SPIKE CONCENTRATIOI

B .Sfr 1.3 O.O O.OO6 O.O06 O.OO6QC 22Dec92 19:O5

j"AN\LT AQCRF' 11- F A 23.4 4. B O. O9B 0. 1 01 0. O95QC ' 22Dec92 19:12

7.R = -11.0.4


1 90B357 - 1 . O 67 . 8 -O . 005 -O . 007 -O . 002QC 22Dec92 19:18

CONCENTRATION LESS B/AN IDLA

QCSPIKE A 20.6 O.B O.O88 0.089 0.088QC 22Dec92 19:25

7.R «= 1 03 . 0

CCV 2 41.9 2.4 0.161 O. 164 0.158 • A »,/%_«•«-•-..«QC 22Dsc92 19=31 LANCASTER LABORATORIES

7.R = (j 04.8 \ GFAA TL S <7 bv-jCCR 2 -0.4 77.2 -O.OO2 -O.OO3 -O.OOIDATE: DEC Z 3 1992

1 /njQC 22Dec92 19:38 REVIEWER/fyABS = 0.004CONCENTRATION LESS THAN IDL

PBS 356 003 0.4 26.6. 0.002 0.002 O.OOIQC 22Dec92 19:44"

CONCENTRATION LESS THAN ID,

QCSP1 HE A 2O.O 2.2 O.O86 O.O88 O.O85QC ' 22De?c97 19:50

7.R = 100.2

LCSS 356 003/X5O.2 0.9 O.I 89 O.I 87 O. 1.90QC x '-> 22Dec92 19:57

1*6$OOSPlkF A 70.7 0.2 0.250 0.250 0.251QC 22Dec92 2O:03

7.R = ' _102. 2

190RRR4 1.5 2.6 0.007 O.007 .O.OO7QC . ^ 22Dec92 20:09

QCRPIfE A 20.9 4.3 O.089 0.087.1. O.O92QC . 22DPC92 20: 16

7.R = 97.0

190B£:r-.'4D 0.4 99.9 O.O02 O.OO3 O.OOOQC 22Dec92 20:22

I*0& CONCENTRATION LESS T

OCSPH-E A 2O.Z 5.4 O.OB7rcc

1908B84R 41.4 O.7 0.159 0.16O 0.158QC 22Dec92 20:35" ofe>

A 61.2 O.5 O.222 0.221Qr 22Dec9I

7.R =

CCV 3 43.3 1.4 0.166 O. 167 0.164 *'C* .»OC 22DBC92 20:48 ft R I Q I f T

7.R = / 108.3 "\ H HO I 3 1 i I

MERCURY DATA

12

JL t_>

LANCASTER LABORATORIESCV HGDATE: DEC < * 1992

OPERATOR 049 3998

DATE 12 22 92

BATCH NO. 0821 0494

LANCASTER LABORATORIES\ sTBKG

DATAVERlHiBPROGRAM 29 Ho .WITH AN X BYl

INSTRUMENT MODE ABSORBANCE

CALIBRATION MODE CONCENTRATION

MEASUREMENT MODE INTEGRATION

LAMP POSITION 1

LAMP CURRENT (mA) 4

SLIT WIDTH (nm) 0.5

WAVELENGTH (nm) 253.7

FLAME AIR-ACETYLENE

SAMPLE INTRODUCTION AUTO NORMAL

DELAY TIME 75

TIME CONSTANT 0.05

MEASUREMENT TIME (sec) 3.0

REPLICATES 3

BACKGROUND CORRECTION ON

RINSE RATE i LANCASTER LABORATORYRINSE RATE 1 ^

RINSE TIME (sec) 10.0 DATE: OEC V 2AN ALYST:

RECALIBRATION RATE 0

RESLOPE RATE o LANCASTER LABORATORIESINSTRUMENT ID #3 ,8

13

SAMPLE :CONC 7.RSD MEAN READINGS

UNITSUG/L)

PLANK o.oo o.ooo o.ooi o.ooo o.ooo O?oo(3>. oicTiSTANDARD 1 0.20 7.1 0.005 0.006 0.005 0.005

-STANDARD 2 0.5O 4.2 O.013 O.O13 O.O13 O.O 14

STANDARD 3 1.OO 1.9 0.027 0.026 0.027 0.027

STANDARD 4 2.50 1.0 0.065 0.065 0.065 0.066

STANDARD 5 5.00 0.1 0.130 0.130 0.130 0.130

2.5O<<:|/ 2.53 0.5 0.066 0.066 0.066 0.066

O.OO K-f) 0.05 14.5 O.OOI O.OOI 0.002 O.OOI

0 . 20 C i A. 0.21 13.6 O . OO6 O. OO5 0.006 O . OO5

l.OO^ti/ 1.02 1.0 0.027 0.027 0.027 0.027

0.00 CCfb 0.05 34.9 0.001 O.OO2 O.OOI O.OOIJf" 3560821001 ?6Ub 0 . 05 7.7 0 .001 0. 001 0.001 0 . 001-3560821 OO 1 . l|,f <>1 . 02 1.4 0. 027 0. 027 0. 027 0. 028•3"AKvt/OT908350 0.06 O.O 0.002 0.002 O.O02 O.O02

,/ A'*-* ^/ 1908351 O.05 11.5 0.001 O.002 0.001 0.001

/ 190835 2~^ I . 01 1.1 0. 027 0 .027 0. 027 ' 0 .027

~~f 190B353 b 0.08 6.5 0 .002 0.002 0.002 0. 002

1908354 0.07 8.7 O.O02 0 . O02 O.OO2 O.O02<, 1 222227190B355 O.O6 9.O O.OO2 O.OO2 O.OOI O.OOI,/1 908356 0.07 28.9 O.O02 0.002 O.OOI 0 . OO2

TA»M-?/1 90835 7 0.06 11.3 0.002 0.001 0.002 0.001

1 . 00 (LV 1 . 02 0 .4 0 . 027 0 . 027 0 . 027 0 . 027

O.OOCtfi O.O6 17.9 0.002 O.OOI 0.002 0.002

LANCASTER LABORATORIECV HG s-s-7DATE: DEC * 2 1992ANALYST: C b

LANCASTER LAB06AT&RIEA R 3 i 9 I I i,INSTRUMENT ID # 399?

1 * ' ' KGCORR; BD

LANCASTER LABORATORICV HG 3S-?DATE: DEC 2 2 mANALYST:LANCASTERINSTRUMENT IDBKG CORR: BD

SAMPLE CONC . 7.RSD MEAN READINGS

UNITSUG/L1

/ C HuL-rr-190B35B O.O7 25.5 O.002 0.001 0.002 0.002

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