gas chromatography tandem mass spectrometry (gc/ms ... · document rev. 1.7 - september 2016 1 nude...

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Document Rev. 1.7 - September 2016 1 Nude Nicotine Analytics 10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044 Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results: Customer Name: Date of Sample Receipt: Date of Analysis: Drip Club – 8-30-17 September 5 th , 2017 September 6 th , 2017 Analytical Compound: Description: CAS #: Limit of Detection: 2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL 2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL 3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL Scope of Method to be Performed: Diketone Trio Analysis: Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials. Product Name: External Lot Number: Results – Diacetyl: Results – Acetyl Propionyl: Results – Acetoin: Milkman – Strudelhaus N/A ND 50.66ug/mL ± 0.507ug/mL 165.9ug/mL ± 1.66ug/mL <LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement: GC/MS Operator and Analytical Report Prepared by: Signature & Date: J. Rubenstein

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Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 5th, 2017 September 6th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Strudelhaus N/A ND 50.66ug/mL ± 0.507ug/mL

165.9ug/mL ± 1.66ug/mL

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Churrios N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Crumbleberry N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Milky O’s N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Moonies N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Original Milkman N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10054 Mesa Ridge Ct #132 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Milkman / Drip Club November 1st, 2016 November 3rd, 2016

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Pudding N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 15th, 2017 September 17th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Hazel N/A 42.4ug/mL ± 0.424ug/mL

202.3ug/mL ± 2.023ug/mL

2328ug/mL ± 23.28ug/mL

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 5th, 2017 September 6th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman – Little Dipper N/A ND 99.5ug/mL ± 1.00ug/mL

184.3ug/mL ± 1.84ug/mL

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 5th, 2017 September 6th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman Delights – Pink2 N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 5th, 2017 September 6th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman Delights – Truffleberry N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 5th, 2017 September 6th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman Delights – Bubble Milk N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.

Document Rev. 1.7 - September 2016 1

Nude Nicotine Analytics

10064 Mesa Ridge Ct #1208 San Diego, CA 92121 www.nudenicotine.com [email protected] (858) 216-2044

Gas Chromatography Tandem Mass Spectrometry (GC/MS) Analysis Results:

Customer Name: Date of Sample Receipt: Date of Analysis:

Drip Club – 8-30-17 September 15th, 2017 September 17th, 2017

Analytical Compound: Description: CAS #: Limit of Detection:

2,3-Butanedione (diacetyl) Diketone 431-03-8 1.08ug/mL

2,3-pentanedione (acetyl propionyl) Diketone 600-14-6 1.26ug/mL

3-Hydroxy-2-butanone (acetoin) Ketone 513-86-0 1.01ug/mL

Scope of Method to be Performed: Diketone Trio Analysis:

Aliquot is diluted 10:1 with methanol containing a known amount of butyric-d7 acid as an internal standard. The aliquot is then capped, mixed, and injected into the GC/MS system. Analyte identification is confirmed by no less than 3 unique ion fragments by the mass selective detector. Results are quantitated utilizing a calibration curve generated from certified reference materials.

Product Name: External Lot Number:

Results – Diacetyl:

Results – Acetyl Propionyl:

Results – Acetoin:

Milkman Delights – Melon Milk N/A ND ND ND

<LOQ = Below limit of Quantitation / ND = Not Detected / 1ug/mL = 1ppm / 1000ug/mL = 1mg/mL

The above results are guaranteed accurate and precise to the best of our ability. Data has been checked and in accordance with Nude Nicotine’s approved analytical protocols. I certify that all results in this report are adherent to this statement:

GC/MS Operator and Analytical Report

Prepared by: Signature & Date:

J. Rubenstein

Document Rev. 1.7 - September 2016 2

Notes: Samples were received in good condition with factory seals intact. Chain of custody was properly maintained during the entirety of the sampling and receipt process. This document was drafted as a .pdf and contains two pages.