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CREATING TOMORROW’S SOLUTIONS CREATING TOMORROW’S SOLUTIONS NEW HYBRID GENERATION OF ELASTIC ADHESIVES AND SEALANTS

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Creating tomorrow’s solutionsCreating tomorrow’s solutions

new hybrid generation oF elastiC adhesiVes and sealants

geniosil® –elastiC adhesiVes and sealants

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SiliconeS Are the traditional sealants – highly elas-tic and tough. They are not easy to paint and tend to discolor around the edges, which limits their use for facades.

PolyurethaneS Are characterized by their strength, which makes them ideal adhesives. Due to their reactive isocyanate components, the processor must carefully observe user guidelines.

hybridS Are silane-crosslinking organic polymers that combine properties typical of both silicones and polyurethanes. They are highly versatile as adhesives and seal-ants and easy and safe to use.

From Silicone to StP-e technologyWACKER silicones marketed as ELASTOSIL® are long-established high-quality construction sealants.

We are now expanding this product area with a balanced range of hybrid-based adhesives and sealants, marketed as GENIOSIL®. What distinguishes these products from the rest is their crosslink-ing mechanism – the so-called STP-E technology. The novel crosslinkers be-hind this technology, e.g. alpha-silanes, provide the products with properties that surpass those of conventional hybrid systems:

– A broad range of elasticity and strength – from low-modulus sealants to high-strength adhesives

– Rapid curing alongside a sufficiently long pot life

ELASTOSIL® and GENIOSIL® are registered trademarks of Wacker Chemie AG.

geniosil® –all PositiVe ProPerties Combined

reactive, moisture-curing adhesives and sealants have been an integral part of construction for decades. Silicones and polyurethanes are the best known, with hybrids increasing in popularity, too. compared to non-reactive, purely physically drying products – especially acrylate sealants – the reactive systems excel in reliably maintaining their function even in high-stress areas and outdoor applications.

– Exceptionally long shelf life– Tack-free surface without dirt pick-up– Particularly environmentally and user

friendly (tin-free and plasticizer-free)

SiliconeS

hybridS

PolyurethaneS

easy to process Paintable

high elasticity

environmentally/user friendly

high mechanical strength

rapid curing

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geniosil® adhesiVes and sealants:ideal For eVery aPPliCation

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1 | GENIOSIL® N25: Expansion joints on facades

> Page 6

2 | GENIOSIL® N35: Connection joints for stairs > Page 9

3 | GENIOSIL® N35C: Sealing and bonding of glass display cases > Page 11

4 | GENIOSIL® N45: Bonding of mirrors > Page 13

5 | GENIOSIL® N70: Bonding of cornices > Page 15

6 | GENIOSIL® W90: Under-tile waterproofing > Page 17

7 | GENIOSIL® W180: Waterproofing under patios

> Page 19

8 | GENIOSIL® W180 PLUS: Waterproofing flat roofs

> Page 21

GenioSil® n: non-sag, moisture-curing joint sealants and adhesives

GenioSil® W: free-flowing, moisture-curing, waterproofing liquid membranes

Product definition

a few examples of GenioSil®’s versatility:

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geniosil® n25 – the FaCade sealant

Processing benefits– One-part– Easy to process at 5 – 40 °C – Rapid curing– Adhesion to many different substrates

without primer – Solvent-free– Low environmental impact and safe– Virtually odorless– Long shelf life

Product benefits– High movement absorption (tested

according to ISO 11600 G&F)– Tack-free surface – Compatible with paints and plasters– Stable at temperatures from -40 °C

to +80 °C– UV and weathering resistant– Water-resistant– Non-corrosive

GenioSil® n25 is a neutral, one-part, low-modulus sealant for stress-com-pensation expansion joints in facade applications. it’s easy to process, can be plastered and painted after curing, and does not lead to discoloration around the edges.

applications– Expansion joints for facades (concrete

and stone)– All types of connection joints in

construction (windows, doors, etc.)

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geniosil® n35 – the all-PurPose sealant

Processing benefits– One-part– Easy to process at 5 – 40 °C – Rapid curing– Adhesion to many different substrates

without primer (glass, tiles, stone, plastic, wood and concrete)

– Solvent-free– Low environmental impact and safe– Odorless– Long shelf life

Product benefits– Tack-free surface– High-modulus elasticity– High strength– Paintable– Stable at temperatures from -40 °C

to +80 °C– UV and weathering resistant– Water-resistant– Non-corrosive

GenioSil® n35 is a neutral, one-part, elastic sealant for all types of joints in indoor and outdoor applications. once cured, it can be painted without problems. despite its elasticity, GenioSil® n35 is firm enough for fill-ing and bonding.

applications– Paintable indoor and outdoor

connection joints (ceiling, window and masonry connections)

– Filling in cracks and cavities– Highly elastic bonding

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geniosil® n35C –the inVisible adhesiVe and sealant

Processing benefits– One-part– Easy to process at 5 – 40 °C– Non-sag, no dripping – Rapid curing– Good adhesion to many substrates– Solvent-free– Low environmental impact and safe– Odorless

Product benefits– Highly transparent and non-yellowing– Tack-free surface– Permanent elasticity– Paintable– Stable at temperatures from -40 °C to

+80 °C– UV and weathering resistant– Water-resistant– Non-corrosive

GenioSil® n35c is a crystal-clear, neutral, one-part adhesive/sealant for all types of permanently flexible bonding and jointing. the product’s predominant feature is its high transparency, which is permanent and renders joints and adhesive seams almost invisible.

applications– Transparent joints and bonding– Decorative construction– Glass display cases– Interior glazing

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geniosil® n45 – the all-PurPose assembly adhesiVe

Processing benefits– One-part– Easy to process at 5 – 40 °C– Non-sag paste – Rapid curing, develops strength fast– Adhesion to many different substrates,

good initial adhesion– Solvent-free– Low environmental impact and safe

(tin-free)– Odorless– Excellent shelf life

Product benefits– High strength and good elasticity– Tack-free surface– No stains – Paintable– Can be sanded– Stable at temperatures from -40 °C

to +80 °C– Non-corrosive– Weathering-resistant– Water-resistant

GenioSil® n45 is a neutral, one-part, flexible adhesive with a broad range of construction, industry, household and hobby applications. it’s reliable, strong and safe, but still sufficiently flexible to act as a joint sealant if required.

applications– Stress-free structural bonding

(metals, wood, plastics except PE, PP and PTFE, and silicones)

– Bonding of mirrors– Weld sealing– All types of adhesive joints– Filling in cracks and cavities

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geniosil® n70 – the high-strength adhesiVe

Processing benefits– One-part– Easy to process at 5 – 40 °C– Rapid curing, develops strength fast– Excellent adhesion to almost all

substrates without primer– Good initial adhesion– Solvent-free– Low environmental impact and safe

(tin-free and plasticizer-free)– Odorless– Outstanding shelf life

Product benefits– Broad range of applications– High-strength yet elastic– Tack-free surface– Paintable– Can be sanded– Stable at temperatures from -40 °C

to +80 °C– No bleeding, no staining – Non-corrosive– Weathering-resistant

GenioSil® n70 is a neutral, one-part, elastic adhesive that has exception-ally good adhesion and high strength. With GenioSil® n70, many things that used to be affixed with nails and screws can now be bonded. the product is a valuable helper in construction, the household and many recreational activities.

applications– All types of stress-free bonding (wood,

metal, plastics, tiles and gypsum plasterboards)

– Bonding, replaces mechanical fixation – Filling in cavities

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geniosil® w90 – the brushable all-PurPose waterProoFing For VertiCalsurFaCes

Processing benefits– One-part and solvent-free– Readily applied with roller or brush in

only two steps– Short drying time, tack-free surface– Excellent adhesion to many substrates

even without primer– Good crack-bridging– Easy to process at 5 – 40 °C– Virtually odorless– Long shelf life

Product benefits– Excellent resistance to chemicals– Good UV and weathering resistance– Water-vapor permeable– Exceeds requirements of DIN 18195– Free of phthalate plasticizers

GenioSil® W90 is a ready-to-use, thixotropic waterproofing liquid mem-brane for construction applications not regulated by standards. it features excellent adhesion to a wide range of substrates, high elasticity and good crack-bridging.

applications– Under-tile waterproofing– All-purpose waterproofing of dome

lights, guttering and pipe passages– Waterproofing of cracks in roofs and

walls– Sealing of indoor and outdoor

connections– Waterproofing of interior and exterior

basement walls

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geniosil® w180 – the selF-leVeling waterProoFingFor horiZontal surFaCes

Processing benefits– One-part and solvent-free– Readily applied with roller or airless

spray gun in just two layers– Short drying time, tack-free surface– Excellent adhesion to many substrates

even without primer– Good crack-bridging– Easy to process at 5 – 40 °C– Virtually odorless– Long shelf life

Product benefits– Excellent resistance to chemicals– Good UV and weathering resistance– Water-vapor permeable– Exceeds requirements of DIN 18195– Free of phthalate plasticizers

GenioSil® W180 is a rollable and sprayable waterproofing liquid mem-brane for construction applications not regulated by standards. thanks to its low viscosity, it’s easy to roll on and offers optimal waterproofing properties on the most versatile of substrates.

applications– Waterproofing of balconies, patios and

roofs– Under-tile waterproofing– Moisture barrier under floor screeds– Potting compound for expansion and

movement joints– Waterproofing of interior and exterior

basement walls

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geniosil® w180 Plus – the waterProoFing For sPeCial demands

Processing benefits– One-part and solvent-free– Readily applied with roller or airless

spray gun in just two layers– Short drying time, tack-free surface– Excellent adhesion to many substrates

even without primer– Good crack-bridging– Easy to process at 5 – 40 °C– Long shelf life

Product benefits– Hardwearing surface – Excellent tear strength– Outstanding elasticity– Plasticizer-free– Water-vapor permeable– Good UV and weathering resistance– Exceeds requirements of DIN 18195

used just like GenioSil® W180, GenioSil® W180 PluS features unique product properties for con-struction applications not regulated by standards. For highly stressed areas such as flat roofs, GenioSil® W180 PluS offers reliable waterproof-ing and guarantees a hardwearing surface after curing.

applications– Waterproofing of flat roofs– Waterproofing of patios and balconies– Waterproofing of interior and exterior

basement walls

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teChniCal ProPerties oF geniosil® n and geniosil® w

GenioSil® n Product Properties

GenioSil® n25 GenioSil® n35 GenioSil® n35c GenioSil® n45 GenioSil® n70

color White/gray/black White/gray/black Transparent White/gray/black White/gray/black/ beige/brown

density iSo 1183-b

[g/cm³] 1.3 1.5 1.0 1.6 1.6

Skin-formation time 23 °c/50% rh

[min] 40 30 40 40 15

Shore a hardness iSo 868

25 35 40 50 80

tensile strength iSo 37-rod1

[n/mm²] 1.4 2.2 1.5 1.7 3.1

elongation at break iSo 37-rod1

[%] 500 600 300 400 100

tear strength iSo 34-c

[n/mm] 7 12 6 9 13

Modulus at 100% elongation iSo 37-rod1

[n/mm²] 0.4 0.7 0.6 1.1 3.0

GenioSil® W Product Properties

GenioSil® W90 GenioSil® W180 GenioSil® W180 PluS

color Gray Gray Gray

consistency Spreadable Self-leveling Self-leveling

density iSo 1183-b

[g/cm³] 1.5 1.4 1.3

Viscosity, brookfield, spindle 7, 50 min -1

[mPa s] 10,000 7,000 7,000

Skin-formation time 23 °c/50% rh

[min] 45 45 45

through-cure time, 1-mm layer 23 °c /50% rh

[h] 3 3 3

Shore a hardness iSo 868

30 28 68

crack-bridging, a5, 23 °c en 1062-7

[mm] 6 5 2

tensile strength iSo 37-rod1

[n/mm²] 1.7 1.1 2.1

elongation at breakiSo 37-rod1

[%] 570 450 180

tear strengthiSo 34-c

[n/mm] 8.5 8.8 16.6

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WACKER   AT A GLANCE

CREATING TOMORROW’S SOLUTIONS

SILTRONICis one of the world’s leading producers of hyperpure silicon wafers, supplying many major chip manufacturers. Siltronic devel-ops and produces wafers up to 300 mm in diameter at facilities in Europe, the USA and Asia. Silicon wafers form the basis of state-of-the-art micro and nanoelectron-ics used, for example, in computers, tele-communications, motor vehicles, medical technology, consumer electronics and control systems.

WACKER SILICONESis a leading supplier of complete silicone-based solutions that comprise products, services and conceptual approaches. As a provider of solutions, the business divi-sion helps customers press ahead with innovations, exploit global markets fully, and optimize business processes to reduce overall costs and boost pro duc tiv-ity. Silicones are the basis for products offering highly diverse properties for vir-tually unlimited fields of application, rang-ing from the automotive, construction, chemical, electrical engineering and elec-tronics industries, through pulp and paper, cosmetics, consumer care and textiles, to mechanical engineering and metal processing.

WACKER POLYMERSis the global leader for high-quality bind-ers and polymer additives. This business division’s activities encompass construc-tion chemicals and functional polymers for lacquers, surface coatings and other industrial applications, as well as basic chemicals, i. e. acetyls. Products such as dispersible polymer powders, disper-sions, solid resins, powder binders and surface coating resins from WACKER POLYMERS are used in the construction,

automotive, paper and adhesives industries, as well as by manufacturers of printing inks and industrial coatings.

WACKER POLYSILICONhas been producing hyperpure silicon for the semiconductor and photovoltaics industries for over 50 years. As one of the largest global manufacturers of poly crys-tal line silicon, WACKER POLYSILICON supplies leading wafer and solar-cell manufacturers.

WACKER BIOSOLUTIONSuses advanced biotech processes to offer innovative and tailored solutions and biotech products for the life science sector. Its products include pharmaceutical proteins, cyclodextrins and fermentation-grade cysteine. Organic intermediates, acetylacetone and PVAc solid resins complete the portfolio. The division focuses on de-veloping customized solutions for growth sectors such as food additives, pharma-ceutical actives and agro chemicals.

WACKERis a technology leader in the chemical and semiconductor industries and a worldwide innovation partner to customers in many key global sectors. With 15,900 employees, WACKER generated sales of € 4.3 billion in 2008. Germany accounted for 22% of sales, Europe (excluding Germany) for 23%, North and South America for 20% and Asia-Pacific, including the rest of the world, for 35%. Head quartered in Munich, Germany, WACKER has 27 production sites worldwide and a global network of over 100 sales offices.

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wacker Chemie aghanns-seidel-Platz 481737 münchen, germanytel. +49 89 62 79-0Fax +49 89 62 [email protected]

www.wacker.com

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