hazard statements precautionary statementssafety data sheet section 1: identification of the...
TRANSCRIPT
-
Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifierProduct Name • Starter Distillate 15XProduct Code • 1041.2 Relevant identified uses of the substance or mixture and uses advised againstRelevant identified use(s) • Flavor1.3 Details of the supplier of the safety data sheetManufacturer • DairyChem
9120 Technology DriveFishers, IN 46038United Stateswww.dairychem.com
Telephone (General) • 317-849-8400
1.4 Emergency telephone numberManufacturer • 800-424-9300 - CHEMTREC
Section 2: Hazards IdentificationEU/EECAccording to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixtureCLP • Specific Target Organ Toxicity Repeated Exposure 2 - H373DSD/DPD • Harmful (Xn)
R48/202.2 Label Elements
CLPDANGER
Hazard statements • H373 - May cause damage to organs - Lungs through prolonged or repeated exposure Precautionary statements
Prevention • P260 - Do not breathe mists, vapours, and/or spray.Response • P314 - Get medical advice/attention if you feel unwell.
Storage/Disposal • P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
DSD/DPD
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 1 of 19Page 1 of 19Page 1 of 19Page 1 of 19
-
Risk phrases • R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation.
2.3 Other HazardsCLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered
hazardous.DSD/DPD • According to European Directive 1999/45/EC this material is considered dangerous.
United States (US)According to: OSHA 29 CFR 1910.1200 HCS
2.1 Classification of the substance or mixtureOSHA HCS 2012 • Skin Irritation 2
Eye Irritation 2Specific Target Organ Toxicity Repeated Exposure 1
2.2 Label elementsOSHA HCS 2012
DANGER
Hazard statements • Causes skin irritationCauses serious eye irritationCauses damage to organs - Lungs through prolonged or repeated exposure
Precautionary statementsPrevention • Do not breathe mists, vapours, and/or spray.
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Wear protective gloves, clothing , and eye/face protection , .
Response • If on skin: Wash with plenty of water .Take off contaminated clothing and wash before reuse.If skin irritation occurs: Get medical advice/attention.Specific treatment, see supplemental first aid information.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.Get medical advice/attention if you feel unwell.
Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
2.3 Other hazardsOSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
Standard), this product is considered hazardous.
Section 3 - Composition/Information on Ingredients
3.1 Substances
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 2 of 19Page 2 of 19Page 2 of 19Page 2 of 19
-
• Material does not meet the criteria of a substance.
3.2 Mixtures
CompositionChemical Name Identifiers % LD50/LC50
Classifications According to Regulation/Directive Comments
Natural flavor Proprietary
0.998% TO 2%
Ingestion/Oral-Rat LD50 • 3310 mg/kgSkin-Rabbit LD50 • 1060 mg/kg
Inhalation-Rat LC50 • 11400 mg/m³ 4 Hour(s)
EU DSD/DPD: Annex VI, Table 3.2: R10; C; R35EU CLP: Annex VI, Table 3.1: Flam. Liq. 3, H226; Skin Corr. 1A, H314OSHA HCS 2012: Flam. Liq. 3; Acute Tox. 4 (skn); Eye Dam. 1; Skin Corr. 1B
NDA
2,3-Butanedione
CAS:431-03-8EINECS:207-069-8
0.98% TO 2%
Ingestion/Oral-Rat LD50 • 1580 mg/kg
Skin-Rabbit LD50 • >5 g/kg
EU DSD/DPD: Self Classified: F+; R11; Xn; R20/22-T; R48/23; Xi; R36/37/38EU CLP: Self Classified: Flam. Liq. 2, H225; Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit. 2, H319; Skin Irrit. 2, H315; STOT RE 1 (Lungs), H372OSHA HCS 2012: Flam. Liq. 2; Acute Tox. 4 (orl); Acute Tox. 4 (inhl); Eye Irrit. 2; Skin Irrit. 2; STOT RE 1 (Lungs)
Common name: Diacetyl
Natural flavor Proprietary < 1%
Ingestion/Oral-Rat LD50 • 5620 mg/kgSkin-Rabbit LD50 • >20 mL/kg
Inhalation-Rat LC50 • 1600 ppm 8 Hour(s)
EU DSD/DPD: Annex VI, Table 3.2: F; R11 Xi; R36 R66 R67EU CLP: Annex VI, Table 3.1: Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336; EUH066OSHA HCS 2012: Flam. Liq. 2; Eye Irrit. 2A
NDA
Natural flavor Proprietary < 1%
Ingestion/Oral-Rat LD50 • >5 g/kg
Skin-Rabbit LD50 • >5 g/kg
EU DSD/DPD: Self Classified: Xi; R36/38EU CLP: Self Classified: Eye Irrit. 2, H319; Skin Irrit. 2, H315OSHA HCS 2012: Eye Irrit. 2A; Skin Irrit. 2
NDA
Natural flavor Proprietary < 1% NDA
EU DSD/DPD: Self Classified: R10; Xi; R37/38EU CLP: Self Classified: Flam. Liq. 3, H226; Skin Irrit. 2, H315; STOT SE 3: Resp. Irrit., H335OSHA HCS 2012: Flam. Liq. 3; Skin Irrit. 2; STOT SE 3: Resp. Irrit.
NDA
Natural flavor Proprietary < 1%
Ingestion/Oral-Rat LD50 • 1850 mg/kgSkin-Rabbit LD50 • >20 mL/kg
Inhalation-Rat LC50 • 28950 mg/m³
EU DSD/DPD: Annex VI, Table 3.2: F; R11; Xn; R20/22; Xi; R36/37EU CLP: Annex VI, Table 3.1: Flam. Liq. 2, H225; Acute Tox. 4, H332; Acute Tox. 4, H302; Eye Irrit. 2, H315; STOT SE 3: Resp. Irrit., H335OSHA HCS 2012: Flam. Liq. 2; Acute Tox. 4 (orl); STOT SE 3, Narc.; Eye Irrit. 2A; STOT SE 3: Resp. Irrit.
NDA
Natural flavor Proprietary < 1%
Ingestion/Oral-Rat LD50 • 2600 mg/kgSkin-Rabbit LD50 • 500 µL/kg
Inhalation-Rat LC50 • >4900 mg/m³ 4 Hour(s)
EU DSD/DPD: Annex VI, Table 3.2: C; R34EU CLP: Annex VI, Table 3.1: Skin Corr. 1B, H314 OSHA HCS 2012: Flam. Liq. 3; Skin Corr. 1B; Eye Dam. 1; Acute Tox. 3 (skn);
NDA
See Section 16 for full text of H-statements and R-phrases.
Section 4 - First Aid Measures
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 3 of 19Page 3 of 19Page 3 of 19Page 3 of 19
-
4.1 Description of first aid measuresInhalation • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing.
Skin • In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Take off contaminated clothing and wash before reuse. If irritation develops and persists, get medical attention.
Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention.
Ingestion • Do not use mouth-to-mouth method if victim ingested the substance.
4.2 Most important symptoms and effects, both acute and delayed• Refer to Section 11 - Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment neededNotes to Physician • All treatments should be based on observed signs and symptoms of distress in the
patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Section 5 - Firefighting Measures
5.1 Extinguishing mediaSuitable Extinguishing Media • LARGE FIRE: Water spray, fog or regular foam.
SMALL FIRES: Dry chemical, CO2, water spray or regular foam.Unsuitable Extinguishing Media
• No data available.
5.2 Special hazards arising from the substance or mixtureUnusual Fire and Explosion Hazards
• Containers may explode when heated.Some of these materials may burn, but none ignite readily.
Hazardous Combustion Products
• No data available.
5.3 Advice for firefighters• Structural firefighters' protective clothing provides limited protection in fire situations
ONLY; it is not effective in spill situations where direct contact with the substance is possible.Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.Wear positive pressure self-contained breathing apparatus (SCBA).
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency proceduresPersonal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Wear appropriate
personal protective equipment, avoid direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Emergency Procedures • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Stay upwind. Keep out of low areas. Keep unauthorized personnel away. Ventilate closed spaces before entering.
6.2 Environmental precautions• Avoid release to the environment.
6.3 Methods and material for containment and cleaning upContainment/Clean-up • Stop leak if you can do it without risk.
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 4 of 19Page 4 of 19Page 4 of 19Page 4 of 19
-
Measures SMALL SPILLS: Take up with sand or other non-combustible absorbent material and place into containers for later disposal.LARGE SPILLS: Dike far ahead of spill for later disposal.
6.4 Reference to other sections• Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
Considerations.
Section 7 - Handling and Storage
7.1 Precautions for safe handlingHandling • Use only with adequate ventilation. Wear appropriate personal protective equipment,
avoid direct contact. Do not breathe mist, vapors and/or spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.
7.2 Conditions for safe storage, including any incompatibilitiesStorage • Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)• Refer to Section 1.2 - Relevant identified uses.
Section 8 - Exposure Controls/Personal Protection
8.1 Control parametersExposure Limits/Guidelines
Result ACGIH Canada Ontario Canada Quebec China Denmark
2,3-Butanedione(431-03-8)
STELs 0.02 ppm STEL Not established Not established Not established Not established
TWAs 0.01 ppm TWA Not established Not established Not established Not established
Natural flavor(Proprietary)
STELs 15 ppm STEL 15 ppm STEL 15 ppm STEV; 37 mg/m3 STEV 20 mg/m3 STEL Not established
TWAs 10 ppm TWA 10 ppm TWA 10 ppm TWAEV; 25 mg/m3 TWAEV 10 mg/m3 TWA10 ppm TWA; 25 mg/m3 TWA
Natural flavor(Proprietary)
STELs Not established Not established Not established 60 mg/m3 STEL Not established
TWAs 10 ppm TWA 10 ppm TWA 10 ppm TWAEV; 30 mg/m3 TWAEV 30 mg/m3 TWA10 ppm TWA; 31 mg/m3 TWA
Natural flavor(Proprietary)
STELs Not established Not established Not established 300 mg/m3 STEL Not established
TWAs 400 ppm TWA 400 ppm TWA 400 ppm TWAEV; 1440 mg/m3 TWAEV 200 mg/m3 TWA150 ppm TWA; 540 mg/m3 TWA
Natural flavor(Proprietary)
TWAs Not established 100 ppm TWA 100 ppm TWAEV; 303 mg/m3 TWAEV Not established100 ppm TWA; 300 mg/m3 TWA
STELs 100 ppm STEL Not established Not established Not established Not established
Exposure Limits/Guidelines (Con't.)Result Germany DFG Germany TRGS NIOSH OSHA
TWAs Not established
10 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 25 mg/m3 TWA AGW (The risk of damage to the embryo or fetus
10 ppm TWA; 25 mg/m3 TWA
10 ppm TWA; 25 mg/m3 TWA
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 5 of 19Page 5 of 19Page 5 of 19Page 5 of 19
-
Natural flavor(Proprietary)
can be excluded when AGW and BGW values are observed, exposure factor 2)
STELs Not established Not established 15 ppm STEL; 37 mg/m3 STEL Not established
Ceilings 20 ppm Peak; 50 mg/m3 Peak Not established Not established Not established
MAKs 10 ppm TWA MAK; 25 mg/m3 TWA MAK Not established Not established Not established
Natural flavor(Proprietary)
STELs Not established Not established 15 ppm STEL; 45 mg/m3 STEL Not established
TWAs Not established
10 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 31 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2)
10 ppm TWA; 30 mg/m3 TWA Not established
Ceilings 20 ppm Peak; 62 mg/m3 Peak Not established Not established Not established
MAKs 10 ppm TWA MAK; 31 mg/m3 TWA MAK Not established Not established Not established
Natural flavor(Proprietary)
TWAs Not established
400 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 1500 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2)
400 ppm TWA; 1400 mg/m3 TWA
400 ppm TWA; 1400 mg/m3 TWA
Ceilings 800 ppm Peak; 3000 mg/m3 Peak Not established Not established Not established
MAKs 400 ppm TWA MAK; 1500 mg/m3 TWA MAK Not established Not established Not established
Natural flavor(Proprietary)
TWAs Not established
100 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 1); 310 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded
100 ppm TWA; 300 mg/m3 TWA
100 ppm TWA; 300 mg/m3 TWA
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 6 of 19Page 6 of 19Page 6 of 19Page 6 of 19
-
when AGW and BGW values are observed, exposure factor 1)
Ceilings 100 ppm Peak; 310 mg/m3 Peak Not established Not established Not established
MAKs 100 ppm TWA MAK; 310 mg/m3 TWA MAK Not established Not established Not established
Exposure Control Notations
ACGIH •2,3-Butanedione (431-03-8): Carcinogens: (A4 - Not Classifiable as a Human Carcinogen) •Natural flavor (Proprietary): Carcinogens: (A4 - Not Classifiable as a Human Carcinogen) Germany TRGS •Natural flavor (Proprietary): Skin: (skin notation) Germany DFG •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) | Skin: (skin notation)
Exposure Limits Supplemental
ACGIH •Natural flavor (Proprietary): TLV Basis - Critical Effects: (eye and upper respiratory tract irritation; pulmonary function) •Natural flavor (Proprietary): TLV Basis - Critical Effects: (eye, skin and upper respiratory tract irritation) •2,3-Butanedione (431-03-8): TLV Basis - Critical Effects: (lung damage (bronchiolitis obliterans-like illness)) •Natural flavor (Proprietary): TLV Basis - Critical Effects: (eye and upper respiratory tract irritation) •Natural flavor (Proprietary): TLV Basis - Critical Effects: (upper respiratory tract irritation)
8.2 Exposure controlsEngineering Measures/Controls
• Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal Protective EquipmentRespiratory • If occupational limits are exceeded, use a NIOSH/MSHA approved
chemical/mechanical respirator designed to remove a combination of particulate and organic vapor. Observe OSHA regulations (29 CFR 1910.134) for respirator use. Prolonged exposure to vapors may cause lung disease.
Eye/Face • Wear chemical splash safety goggles.Skin/Body • Wear appropriate gloves.
Environmental Exposure Controls
• Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Follow best practice for site management and disposal of waste.
Key to abbreviations
ACGIH = American Conference of Governmental Industrial Hygiene STEL =Short Term Exposure Limits are based on 15-minute exposures
MAK =Maximale Arbeitsplatz Konzentration is the maximum permissible concentration STEV = Short Term Exposure Value
NIOSH = National Institute of Occupational Safety and Health TWAEV = Time-Weighted Average Exposure Value
OSHA = Occupational Safety and Health Administration TWA =Time-Weighted Averages are based on 8h/day, 40h/week exposures
Section 9 - Physical and Chemical Properties
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 7 of 19Page 7 of 19Page 7 of 19Page 7 of 19
-
9.1 Information on Basic Physical and Chemical PropertiesMaterial Description
Physical Form Liquid Appearance/Description A yellow to green liquid with the odor and flavor of butter.Color Yellow to green. Odor Butter odor.Taste Butter Odor Threshold No data availableGeneral Properties Boiling Point No data available Melting Point/Freezing Point No data availableDecomposition Temperature No data available pH 3Specific Gravity/Relative Density = 1 Water=1 Water Solubility Appreciable 10 to 99 %Viscosity No data available Explosive Properties No data availableOxidizing Properties: No data available Volatility Vapor Pressure No data available Vapor Density No data availableEvaporation Rate No data available Flammability Flash Point No data available UEL No data availableLEL No data available Autoignition No data availableFlammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available
9.2 Other Information• No additional physical and chemical parameters noted.
Section 10: Stability and Reactivity
10.1 Reactivity• No dangerous reaction known under conditions of normal use.
10.2 Chemical stability• Stable under normal temperatures and pressures.
10.3 Possibility of hazardous reactions• Hazardous polymerization will not occur.
10.4 Conditions to avoid• No data available.
10.5 Incompatible materials• No data available.
10.6 Hazardous decomposition products• No data available.
Section 11 - Toxicological Information
11.1 Information on toxicological effectsComponents
Acute Toxicity: Ingestion/Oral-Rat LD50 • 3310 mg/kg; Inhalation-Rat LC50 • 11400 mg/m³ 4 Hour(s); Skin-Rabbit
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 8 of 19Page 8 of 19Page 8 of 19Page 8 of 19
-
Natural flavor (0.998% TO 2%) Proprietary
LD50 • 1060 mg/kg;Irritation: Eye-Rabbit • 5 mg 30 Second(s)-Rinse • Mild irritation; Skin-Rabbit • 525 mg-Open • Severe irritation;Reproductive: Ingestion/Oral-Rat TDLo • 700 mg/kg (18D post); Reproductive Effects:Effects on Newborn:Behavioral
Natural flavor (< 1%) Proprietary
Acute Toxicity: Ingestion/Oral-Rat LD50 • 2600 mg/kg; Inhalation-Rat LC50 • >4900 mg/m³ 4 Hour(s); Skin-Rabbit LD50 • 500 µL/kg;Irritation: Eye-Rabbit • 990 µg • Severe irritation; Skin-Rabbit • 495 mg-Open • Severe irritation;Multi-dose Toxicity: Inhalation-Rat TCLo • 23 mg/m³ 24 Hour(s) 30 Day(s)-Continuous; Brain and Coverings:Recordings from specific areas of CNS; Blood:Changes in erythrocyte (RBC) count; Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:True cholinesterase
2,3-Butanedione (0.98% TO 2%) 431-03-8
Acute Toxicity: Ingestion/Oral-Rat LD50 • 1580 mg/kg; Behavioral:Somnolence (general depressed activity); Behavioral:Convulsions or effect on seizure threshold; Inhalation-Rat TCLo • 224 ppm 1 Hour(s); Lungs, Thorax, or Respiration:Structural or functional change in trachea or bronchi; Skin-Rabbit LD50 • >5 g/kg;Irritation: Skin-Rabbit • 500 mg 24 Hour(s) • Moderate irritation;Multi-dose Toxicity: Inhalation-Mouse TCLo • 200 ppm 5 Day(s)-Intermittent; Lungs, Thorax, or Respiration:Structural or functional change in trachea or bronchi; Biochemical:Metabolism (intermediary):Effect on inflammation or mediation of inflammation; Related to Chronic Data:Death in the Other Multiple Dose data type field;Mutagen: Unscheduled DNA synthesis • Ingestion/Oral-Rat • 1500 mg/kg
Natural flavor (< 1%) Proprietary
Acute Toxicity: Ingestion/Oral-Rat LD50 • 5620 mg/kg; Inhalation-Rat LC50 • 200 g/m³; Behavioral:Somnolence (general depressed activity); Lungs, Thorax, or Respiration:Acute pulmonary edema; Gastrointestinal:Changes in structure or function of salivary glands; Skin-Rabbit LD50 • >20 mL/kg;Irritation: Eye-Human • 400 ppm
Natural flavor (< 1%) Proprietary
Acute Toxicity: Ingestion/Oral-Rat LD50 • >5 g/kg; Skin-Rabbit LD50 • >5 g/kg;Irritation: Skin-Rabbit • 500 mg 24 Hour(s) • Moderate irritation;Reproductive: Ingestion/Oral-Rat TDLo • 12600 mg/kg (42D male); Reproductive Effects:Paternal Effects:Testes, epididymis, sperm duct
Natural flavor (< 1%) Proprietary Irritation: Skin-Rabbit • 500 mg 24 Hour(s) • Moderate irritation
Natural flavor (< 1%) Proprietary
Acute Toxicity: Ingestion/Oral-Rat LD50 • 1850 mg/kg; Behavioral:Somnolence (general depressed activity); Lungs, Thorax, or Respiration:Dyspnea; Inhalation-Rat LC50 • 28950 mg/m³; Skin-Rabbit LD50 • >20 mL/kg;Irritation: Skin-Rabbit • 460 mg-Open • Mild irritation;Tumorigen / Carcinogen: Skin-Mouse TDLo • 110 g/kg 9 Week(s)-Intermittent; Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Skin and Appendages:Other:Tumors
GHS Properties Classification
Acute toxicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
Skin corrosion/IrritationEU/CLP • Data lacking OSHA HCS 2012 • Skin Irritation 2
Serious eye damage/IrritationEU/CLP • Data lacking OSHA HCS 2012 • Eye Irritation 2
Skin sensitizationEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
Respiratory sensitizationEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
Aspiration HazardEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
CarcinogenicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 9 of 19Page 9 of 19Page 9 of 19Page 9 of 19
-
Germ Cell MutagenicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
Toxicity for ReproductionEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
STOT-SEEU/CLP • Data lacking OSHA HCS 2012 • Data lacking
STOT-REEU/CLP • Specific Target Organ Toxicity Repeated Exposure 2 OSHA HCS 2012 • Specific Target Organ Toxicity Repeated Exposure 1
Potential Health EffectsInhalation
Acute (Immediate) • Product is irritating and possibly detrimental to the respiratory system. Inhalation symptoms may include sore throat, coughing, dullness, and unconsciousness.
Chronic (Delayed) • Prolonged exposure to high concentrations may cause lung disease (bronchiolitis obliterans).
SkinAcute (Immediate) • Product is irritating to the skin.Chronic (Delayed) • No data available.
EyeAcute (Immediate) • Product is irritating to eyes.Chronic (Delayed) • No data available.
IngestionAcute (Immediate) • Product is harmful if swallowed. Symptoms of ingestion may include sore throat and
abdominal pain.Chronic (Delayed) • No data available.
OtherChronic (Delayed) • NIOSH has reported that employees exposed to butter flavorings containing diacetyl
are at risk of developing occupational lung diseases and that in one instance, similar illnesses have been found among employees handling flavorings that contain diacetyl.
Key to abbreviationsLC = Lethal ConcentrationLD = Lethal DoseTC = Toxic ConcentrationTD = Toxic Dose
Section 12 - Ecological Information
12.1 Toxicity• Material data lacking.
12.2 Persistence and degradability• Material data lacking.
12.3 Bioaccumulative potential• Material data lacking.
12.4 Mobility in Soil• Material data lacking.
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 10 of 19Page 10 of 19Page 10 of 19Page 10 of 19
-
12.5 Results of PBT and vPvB assessment• No PBT and vPvB assessment has been conducted.
12.6 Other adverse effects• No studies have been found.
Section 13 - Disposal Considerations
13.1 Waste treatment methodsProduct waste • Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
Section 14 - Transport Information
14.1 UN number
14.2 UN proper shipping name
14.3 Transport hazard class(es)
14.4 Packing group
14.5 Environmental hazards
DOT NDA Not Regulated NDA NDA NDA
IMO/IMDG NDA Not Regulated NDA NDA NDA
IATA/ICAO NDA Not Regulated NDA NDA NDA
14.6 Special precautions for user
• None specified.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
• Data lacking.
Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications • Acute, Chronic
State Right To KnowComponent CAS MA NJ PA
2,3-Butanedione 431-03-8 Yes Yes Yes
Natural flavor Proprietary No Yes No
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
InventoryComponent CAS Canada DSL Canada NDSL China EU EINECS EU ELNICS
2,3-Butanedione 431-03-8 Yes No Yes Yes No
Natural flavor Proprietary Yes No Yes Yes No
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 11 of 19Page 11 of 19Page 11 of 19Page 11 of 19
-
Natural flavor Proprietary Yes No Yes Yes No
Natural flavor Proprietary Yes No Yes Yes No
Natural flavor Proprietary Yes No Yes Yes No
Natural flavor Proprietary Yes No Yes Yes No
Natural flavor Proprietary Yes No Yes Yes No
Inventory (Con't.)Component CAS Japan ENCS Korea KECL TSCA
2,3-Butanedione 431-03-8 Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
Natural flavor Proprietary Yes Yes Yes
AustraliaLaborAustralia - Work Health and Safety Regulations - Hazardous Chemicals Requiring Health Monitoring • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Australia - High Volume Industrial Chemicals List • Natural flavor Proprietary • Natural flavor Proprietary Not Listed • Natural flavor Proprietary • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Australia - List of Designated Hazardous Substances - Classification • Natural flavor Proprietary C R10, R35 • Natural flavor Proprietary C R34 • Natural flavor Proprietary F, Xi R11, R36, R66, R67 • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary F, Xn, Xi R11, R20/22, R36/37
EnvironmentAustralia - National Pollutant Inventory (NPI) Substance List • Natural flavor Proprietary 10 tonne/yr Threshold category 1 • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary 10 tonne/yr Threshold category 1
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 12 of 19Page 12 of 19Page 12 of 19Page 12 of 19
-
• 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Australia - Ozone Protection Act - Scheduled Substances • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Australia - Priority Existing Chemical Program • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
CanadaLaborCanada - WHMIS 1988 - Classifications of Substances
• Natural flavor Proprietary
B3, E (including 10-80% [Available data does not allow a precise evaluation of the threshold concentration from which solutions meet the B3 criterion], >80%); D2B (3-10%)
• Natural flavor Proprietary B3, D1B, E • Natural flavor Proprietary B2 • 2,3-Butanedione 431-03-8 Not Listed
• Natural flavor Proprietary Uncontrolled product according to WHMIS classification criteria
• Natural flavor Proprietary Not Listed • Natural flavor Proprietary B2, D2B
Canada - WHMIS 1988 - Ingredient Disclosure List • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • 2,3-Butanedione 431-03-8 1 % • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 %
EnvironmentCanada - CEPA - Priority Substances List • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 13 of 19Page 13 of 19Page 13 of 19Page 13 of 19
-
• Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
EuropeOtherEU - CLP (1272/2008) - Annex VI - Table 3.2 - Classification (OBSOLETE) • Natural flavor Proprietary R10 C; R35 • Natural flavor Proprietary C; R34 • Natural flavor Proprietary F; R11 Xi; R36 R66 R67 • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary F; R11 Xn; R20/22 Xi; R36/37
EU - CLP (1272/2008) - Annex VI - Table 3.2 - Concentration Limits (OBSOLETE)
• Natural flavor Proprietary 10%
-
• Natural flavor Proprietary Not Listed • Natural flavor Proprietary S:(2)-9-16-24-26-33
GermanyEnvironmentGermany - Water Classification (VwVwS) - Annex 1 • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Germany - Water Classification (VwVwS) - Annex 2 - Water Hazard Classes
• Natural flavor Proprietary ID Number 93, hazard class 1 - low hazard to waters (>25%)
• Natural flavor Proprietary ID Number 483, hazard class 1 - low hazard to waters
• Natural flavor Proprietary ID Number 95, hazard class 1 - low hazard to waters • 2,3-Butanedione 431-03-8 Not Listed
• Natural flavor Proprietary ID Number 1679, hazard class 1 - low hazard to waters • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary ID Number 1607, hazard class 1 - low hazard to waters
Germany - Water Classification (VwVwS) - Annex 3 • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
• 2,3-Butanedione 431-03-8 ID Number 5649, hazard class 2 - hazard to waters • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary ID Number 6106, hazard class 1 - low hazard to waters • Natural flavor Proprietary Not Listed
United StatesLaborU.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - OSHA - Specifically Regulated Chemicals • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 15 of 19Page 15 of 19Page 15 of 19Page 15 of 19
-
• Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
EnvironmentU.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities • Natural flavor Proprietary 5000 lb final RQ; 2270 kg final RQ
• Natural flavor Proprietary 5000 lb final RQ; 2270 kg final RQ
• Natural flavor Proprietary 5000 lb final RQ; 2270 kg final RQ • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 16 of 19Page 16 of 19Page 16 of 19Page 16 of 19
-
U.S. - CERCLA/SARA - Section 313 - Emission Reporting • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - RCRA (Resource Conservation & Recovery Act) - Basis for Listing - Appendix VII • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary Included in waste stream: F039 • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - RCRA (Resource Conservation & Recovery Act) - Phase 4 LDR Rule - Universal Treatment Standards • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary 0.34 mg/L (wastewater); 33 mg/kg (nonwastewater) • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - RCRA (Resource Conservation & Recovery Act) - U Series Wastes - Acutely Toxic Wastes & Other Hazardous Characteristics • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
• Natural flavor Proprietary waste number U112 (ignitable waste) • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
United States - CaliforniaEnvironmentU.S. - California - Proposition 65 - Carcinogens List • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 17 of 19Page 17 of 19Page 17 of 19Page 17 of 19
-
• 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - California - Proposition 65 - Developmental Toxicity • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL) • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - California - Proposition 65 - Reproductive Toxicity - Female • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - California - Proposition 65 - Reproductive Toxicity - Male • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
United States - PennsylvaniaLaborU.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List • Natural flavor Proprietary (including water solutions)
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 18 of 19Page 18 of 19Page 18 of 19Page 18 of 19
-
• Natural flavor Proprietary • Natural flavor Proprietary • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3-Butanedione 431-03-8 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed
15.2 Chemical Safety Assessment• No Chemical Safety Assessment has been carried out.
Section 16 - Other Information
Relevant Phrases (code & full text)• H225 - Highly flammable liquid and vapour
H226 - Flammable liquid and vapourH302 - Harmful if swallowedH314 - Causes severe skin burns and eye damage.H315 - Causes skin irritationH319 - Causes serious eye irritationH332 - Harmful if inhaledH336 - May cause drowsiness or dizzinessH372 - Causes damage to organs through prolonged or repeated exposure.EUH066 - Repeated exposure may cause skin dryness or cracking.R10 - Flammable.R11 - Highly flammable.R20/22 - Harmful by inhalation and if swallowed.R34 - Causes burns.R35 - Causes severe burns.R36 - Irritating to eyes.R36/37 - Irritating to eyes and respiratory system.R36/37/38 - Irritating to eyes, respiratory system and skin.R36/38 - Irritating to eyes and skin.R37/38 - Irritating to respiratory system and skin.R48/23 - Toxic: danger of serious damage to health by prolonged exposure through inhalation.R66 - Repeated exposure may cause skin dryness or cracking.R67 - Vapours may cause drowsiness and dizziness.
Revision Date • 20/May/2019Preparation Date • 31/October/2014Disclaimer/Statement of Liability
• The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.
Key to abbreviationsNDA = No Data Available
Starter Distillate 15XStarter Distillate 15XStarter Distillate 15XStarter Distillate 15X
Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Preparation Date: 31/October/2014Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019Revision Date: 20/May/2019
Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012EU DSD/DPD, EU CLP, OSHA HCS 2012
Page 19 of 19Page 19 of 19Page 19 of 19Page 19 of 19