hbr, new states
DESCRIPTION
HBr, new states. https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-210312ak.ppt. https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf. C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/HBr 74960_76000.pxp. https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf. H79Br+. - PowerPoint PPT PresentationTRANSCRIPT
HBr, new states
https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-210312ak.ppt
800x103
600
400
200
0
Rel
ativ
e In
ten
sity
/a.
u.
75.40x10375.3575.3075.2575.2075.15
Wavenumber /cm-1
0123456
Q
V1m-1) ?
H79
Br+
79Br
+
H+
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/HBr 74960_76000.pxp
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
400
300
200
100
0
x103
77.977.877.777.677.5x10
3
i3 Q
P
RS
O
S
E1
Q
F1 S
23456
V1
(m+3) Q
O
S
V1
(m+5) Q
V1
(m+6) Q
S
O
i3 Q
V1
(m+4) Q
P
F1 ???
S(2)?S(3)?S(4)?Q(0)
Q(1)
Q(2)Q(3)Q(4)
Q(2)Q(3)Q(4)Q(5)Q(6)
Q(7)Q(8)Q(9)Q(10)
P(2)P(3)P(4)P(5)P(6)P(7)
0123456789 01234567
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
81Br+
H81Br+
79Br+
H79Br+
H+
100
50
0
-50
x10
3
79.078.978.878.778.6x10
3
i3 Q
P
R
SOSE1
QF
1 S23456V
1
(m+3) QO
S
V1
(m+5) Q
V1
(m+6) Q
S
O
i3 Q
V1
(m+4) Q
P
F1 ???
S(2)?S(3)?S(4)?
Q(0)
Q(1)
Q(2)Q(3)Q(4)
Q(2)Q(3)
Q(4)Q(5)
Q(6)
Q(7)
Q(8)
Q(9)Q(10)
P(2)P(3)
P(4)P(5)P(6)P(7)
012345678901234567
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
500x103
400
300
200
100
0
-100
Rel
ativ
e in
ten
sity
/a.
u.
80.05x10380.0079.9579.9079.85
Wavenumber 2h /cm-1
Q
0123456
V1
(m+8)
H79
Br+
79Br
+
Atomic line
7
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 79800_80280.pxp
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
300
250
200
150
100
50
0
x103
80.4180.4080.3980.3880.3780.3680.35 x103
P
P
S
SS
S
OE
1
Q
R
R
i3 Qi
3 Q
I1 Q
V1
(m+9) Q
g3
Q? i
3 ?
V1
(m+10) Q
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)?
Q(1)?
Q(2)?
Q(3)?
Q(4)?
Q(5)?Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)?O(0)?O(4)?O(5)?P(9)?O?O?O?
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
V (m+11)?
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 80160_81880.pxp
81Br+
H81Br+
79Br+
H79Br+
H+
200
150
100
50
0
x10
3
80.8080.7580.7080.6580.6080.5580.50 x103
P
P
S
SS
S
OE1
Q
R
R
i3 Q
i3 Q
I1 QV
1
(m+9) Q
g3
Q? i
3 ?
V1
(m+10) Q
Q(0)
Q(1)
Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)?
Q(1)?
Q(2)?
Q(3)?Q(4)?
Q(5)?Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)? O(0)?O(4)?O(5)?P(9)? O?O?O?
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
V (m+11)?
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 80160_81880.pxp
81Br+
H81Br+
79Br+
H79Br+
H+
60
40
20
0
-20
-40
x10
3
81.7581.7081.6581.60 x103
P
PS
SS
SOE1
QRRi
3 Qi
3 QI1 QV
1
(m+9) Qg
3
Q? i
3 ?V
1
(m+10) Q
Q(0)
Q(1)
Q(2)Q(3)Q(4)Q(5)Q(6)
Q(7)?
Q(1)?Q(2)?Q(3)?Q(4)?Q(5)?Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)?O(0)?O(4)?O(5)?P(9)?O?O?O?
Q(0)
Q(1)Q(2)Q(3)
Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
V (m+11)?https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 80160_81880.pxp
81Br+
H81Br+
79Br+
H79Br+
H+
200
150
100
50
0
-50
-100
x103
84.3684.3584.3484.3384.3284.3184.30x10
3
V (m+11) ?V (m+12) ?
V (m+15) ?
V (m+13) ?
K1
E1
j3
H1
H+
H81
Br+
H79
Br+
79Br
+
81Br
+
l3Ql
3R
l3SE (v'=3)?
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 81600_84360.pxp
81Br+
H81Br+
79Br+
H79Br+
H+
500
400
300
200
100
0
-100
x10
3
84.6084.5584.5084.4584.4084.35x10
3
6p
Q
6p
O
6p
S
V (m+16)
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 84340_85420.pxp
81Br+
H81Br+
79Br+
H79Br+
H+
500
400
300
200
100
0
x10
3
86.085.885.685.485.2x10
3
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
C:\REMPI\Advanced data\HBr\HBr REMPI TOF\Processing Spectra/ HBr 85140_86000.pxp 81Br+
H81Br+
79Br+
H79Br+
H+
Improvements from JL:
See: https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdfAndhttps://notendur.hi.is/jil3/work/HBr/PPT-210312ak.pdfi.e:
https://notendur.hi.is/jil3/work/HBr/Overview%20HBr.pdf
https://notendur.hi.is/jil3/work/HBr/PPT-210312ak.pdf
https://notendur.hi.is/jil3/work/HBr/PPT-210312ak.pdf
https://notendur.hi.is/jil3/work/HBr/PPT-210312ak.pdf
70
65
60
55
50
45
40
x103
80.6580.6480.6380.62 x103
P
PS
S
S
SOE1
Q RRi
3 Qi3 QI1 QV
1(m+9) Qg
3 Q? i
3 ? V1
(m+10) Q
Q(0)
Q(1)
Q(2)
Q(3)
Q(4)Q(5)Q(6)Q(7)?
Q(1)?
Q(2)?
Q(3)?
Q(4)?
Q(5)?Q(6)?
P(1)?P(3)?
P(5)?
P(6)?
P(7)?P(8)?
O(0)?O(4)?O(5)?P(9)?
O?O?O?
Q(0)
Q(1)
Q(2)Q(3)
Q(4)Q(5)Q(6)Q(7)
Q(0)?
P(2)?
H79
Br+
79Br
+81Br
+H
81Br
+H
+
V (m+11)?
Strange spectrum!
https://notendur.hi.is/agust/rannsoknir/papers/HBr/jms90-152-81.pdf
300
200
100
0
x103
80.4080.3980.3880.3780.36 x103
P
P
S
SS
S
OE
1 Q
R
R
i3 Qi3 Q
I1 Q
V1
(m+9) Q
g3
Q? i
3 ?
V1
(m+10) Q
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)
Q(7)?
Q(1)?
Q(2)?
Q(3)?
Q(4)?
Q(5)?Q(6)?
P(1)?P(3)?P(5)?
P(6)?
P(7)?P(8)?O(0)?O(4)?O(5)?P(9)?O?O?O?
Q(0)Q(1)Q(2)Q(3)Q(4)Q(5)Q(6)Q(7)
Q(0)?P(2)?
H79
Br+
79Br
+
81Br
+
H81
Br+
H+
V (m+11)?
k3P1(1)(v´=0)
https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PXP_260312ak.pxp
H79Br+
H81Br+
79Br+
81Br+
H+
4 178It ought to be possible to
add J´=9 peak
?
80.386x103
80.384
80.382
80.380
80.378
80.376
80.374
80.372
Waven
um
ber 2
hv/c
m-1
76543210
J'
120
100
80
60
40
20
E
cm
-1
Te=80386 ± 0.174 cm-1
Bv=8.0511 ± 0.0178 cm-1
Dv=0.00026382 ± 0.00032 cm-1
http://notendur.hi.is/agust/rannsoknir/rempi/Presentation-010311jl.ppt
( )2 3 4 5 6 7 8
For k k3P1(1)(v´=0)
Slight butsignificant Icrease. What state could be causing this shift?
This fit assumes first peak to correspond to J´=0 instead of J´=1 (for k3P1(1)(v´=0) )
Try to find W12 from the line shift
WV(m+8)=9.29 WV(m+9)=9.29
Exp Calc
V v’=m+8V v’=m+9
The interaction between k3P1(1)(v´=0) and V1-(0+)(m+8)(m+9)
http://notendur.hi.is/agust/rannsoknir/rempi/Presentation-010311jl.ppt
Significant increase
79Br/H79Br81Br/H81Br
79Br H79Br
http://notendur.hi.is/agust/rannsoknir/rempi/Presentation-010311jl.ppt
1 2 3 4 5 6 7 8
Corrected scale
1 2 3 4 5 6 7 8
Corrected scale