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1

HIGHLIGHT2D@GRENOBLE

hightlight_2D_summer2017_prop1_v5.indd 1 02/08/2017 09:55:06

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WE WOULD LIKE TO THANK EVERYONE WHO CONTRIBUTEDTO THESE HIGHLIGHTS.

COPYRIGHTSCOVER : ©FOTOLIA / BEHOLDEREYENANOART : ©IONELA ILIESCU / ©GEORGIANA IRINA GROZA

© JONATHAN QUINSON / © ALEXIS WARTELLE

DIRECTORS OF PUBLICATIONJOHANN CORAUXALAIN FONTAINE

DESIGN AND LAYOUTCELINE FIGUEIREDOJOHANN CORAUX

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HIGHLIGHT 2D@GRENOBLE

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Grenoble is a lively breeding ground for two-dimensional

(2D) materials – graphene, boron nitride, transition metal

dichalcogenides, ultrathin oxides, etc. This is one of the

very few places worldwide involving such a high number

of scientists (about 80). Overall about 10 large research

laboratories1 are concerned, all supported by Grenoble

Alpes University, and CEA, CNRS Grenoble INP, and INRIA,

spread over the two main campuses.

Several tens PhD students and (young) researchers benefit

there from very unique tools, that have become a trademark

of the Grenoble’s expertise in leading instrumentations,

noteworthy nanofabrication in clean rooms, extreme

cryogenics, high magnetic fields, optical spectroscopies,

and the synchrotron facility. Also characteristic of the

Grenoble labs performing programs on 2D materials, is

their broad scope, from biology and medicine, to materials

science, chemistry and physics.

The animation of our dynamic community is punctuated

by scientific events. The first one was held in 2012 already

gathering close to 100 participants, the second one in

2014 featuring Nobel Prize winner Kostya Novoselov,

the last two ones in Fall 2016 and Spring 2017 followed

by 150 active participants. Special care was paid during

these events regarding the integration of the Ph.D.

students and post-docs in the network, and they were for

this reason encouraged to present their research. These

events have been opportunities to invite leading European

experts, amplifying Grenoble’s international visibility and

promoting European collaborations; they are strengthen

local links, by sharing the views from local experts and

pushing the youngest scientists forward. The momentum

of our stimulating agenda has been boosted by the

already effective networks, LANEF and MINOS, two local

“laboratories of excellence” (so-called LABEX funded by the

French “Commissariat Général à l’investissement”), and

the 10 years-old, internationally profiled Nanosciences

Foundation.

The present booklet of highlights, issued by several of

the many local actors in different disciplines, is fully

representative of these animation efforts of the network.

It collects very recent research accounts, that we believe

faithfully reflects the diversity and activeness of our 2D

materials community. It gives a flavor of the numerous

publications (>70 in 2016) and several running national

and European programs (>10) for which Grenoble teams

are committed.

2D materials is a widely structuring topic in Grenoble, rich

of leading actors, and furthermore attracting forefront

experts – young and promising ones as well, thanks to

their permanent position opportunities based at the

University and/or at the National Center for Scientific

Research (CNRS) and Alternative Energies and Atomic

Energy Commission (CEA). Beside faculty members, senior

experts are also faculties and part of them are hosted in

the framework of Chairs of Excellence programs supported

by the local LABEXs and the Nanosciences Foundation.

The structuring of our community is at academic level

and beyond, thanks to CEA that contributes to interface

academic and technological researches with industrials,

and also thanks to start-up companies emerging from our

laboratories.

The pivotal local transformations of the University, one of

the few recently labelled by the government and awarded

an ambitious funding program, defines a new local

panorama. The 2D materials research theme bolsters up

as a strong and lively joint enterprise in Grenoble, with

cross-disciplinary motivations: its actors are willing to take

active part in this new context. They are key participants

in an emerging federative project addressing sustainable

nanoelectronics. They will strive to further promote the

attractiveness and visibility of Grenoble, with already

existing plans of training young scientists thanks to

research schools and international Ph.D grant funding

schemes.

Find recent news at http://2d.grenoble.cnrs.fr, and

join the discussion group : https://www.linkedin.com/

groups/8599271”?.

1Néel Institute, National High Magnetic Field Laboratory (LNCMI), CEA Institute for Nanosciences and Cryogenics, CEA-Tech Electronics and Information

Technologies Laboratory (LETI), CEA-Tech Innovation Laboratory for Emerging Energies and Nanomaterials (LITEN), Laboratory for Physics and Modeling

of Condensed Matter (LPMMC), the Institute on Microelectronics, Electromagnetism (IMEP), Laboratory for Hyperfrequencies and Characterizations (LaHC),

Materials and Physical Engineering Laboratory (LMGP), Laboratory for Microelectronics Technologies (LTM), Interdisciplinary Physics Laboratory (LiPhy),

Molecular Chemistry Department (DCM), European Synchrotron Radiation Facility (ESRF), Laue-Langevin Institute (ILL), Jean Kuntzmann Laboratory INRIA

EditoTHE EDITORIAL COMMITTEEHervé Boukari, Claude Chapelier, Johann Coraux, Florence Duclairoir, Clément Faugeras, Alain Fontaine, Michael Holzinger, Matthieu Jamet

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Table of content

SYNTHESIS

ENERGY

STRUCTURAL PROPERTIES

ELECTRONIC DEVICES

ELECTRONIC PROPERTIES

OPTOELECTRONIC

SPINTRONICS

BIOMEDICAL

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Zigzag-edged carbon molecules

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A. ARTAUD, L. MAGAUD, K. RATTER, B. GILLES, V. GUISSET,P. DAVID,C. CHAPELIER, J. CORAUX

CONTACT

FIGURE

Top:

Middlle left:

Bottom left:

1 nm

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Van der Waals epitaxy of transitionmetal dichalcogenides

M. T. DAU, C. VERGNAUD, A. MARTY, C. BEIGNÉ, G. RENAUD, M. GAY, O. RENAULT, C. ALVAREZ, H. OKUNO, H. BOUKARI, T. LE QUANG, P. MALLET,J.-Y. VEUILLEN, L. HUDER, V. RENARD, C. CHAPELIER, P. POCHET, M. JAMET

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Van der Waals epitaxy of layered GaSe on 300 mm Si(001) wafers by MOCVD

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M. MARTIN, S. DAVID, J. MOEYAERT, S. LABAU, T. BARON

CONTACT

FIGURE

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A novel 2-step ALD route to monolayer MoS2

S. CADOT, H. OKUNO, O. RENAULT, M. FRÉGNAUX D. ROUCHON, E. NOBLOT,K. SZETO*, C. THIEULEUX*, L. VEYRE*, F. MARTIN, E. A. QUADRELLI*

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a) Process scheme b) TEM

c) XPS

d) Raman

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Highly-reduced graphene hydrogels for high power supercapacitors

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H. BANDA, D. ARADILLA, A. BENAYAD, Y. CHENAVIER,L. DUBOIS, F. DUCLAIROIR

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3D nanostructured platforms for super-capacitors: vertically oriented graphene nanosheets using ionic liquid electrolytesD. ARADILLA, M. DELAUNAY, M. BUHAGIAR, TAO LÉ,J.-M. GÉRARD, G. BIDAN

CONTACT

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Don’t be fooled bythe appearance of moirés

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Relative strainin twisted graphene layersL. HUDER, T. LE QUANG, A. ARTAUD, G. TRAMBLY DE LAISSARDIÈRE*,A. G. M. JANSEN, C. CHAPELIER, V. T. RENARD

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Modeling thermal expansionof 2D materialsF. CALVO, Y. MAGNIN*, S. LINAS*, V. BOUCHIAT

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Free-standing graphene and nanoscrolls facing nanofocused X-rays

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G. CHAHINE, C. SCHWARZ, N. BENDIAB, L. MARTY, F. JEAN,V. BOUCHIAT, G. RENAUD, M. BURGHAMMER, T. SCHULLI, J. CORAUX

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In situ observation of formation and migration of defects in a van der Waals heterostructure

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C. ALVAREZ, P. POCHET, T. M. DAU, C. VERGNAUD, A. MARTY,H. LE POCHE, M. JAMET, H. OKUNO

FIGURE

CONTACT

FUNDING

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Critical thickness goes 2D!B. C. MCGUIGAN*, H. T. JOHNSON*, P. POCHET

CONTACT

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Simulation of van der Waals vertical

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FIGURE

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Demonstration of gate-tunable transmission of quantum Hall edge channels in graphene

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K. ZIMMERMANN, A. JORDAN, F. GAY, K. WATANABE, T. TANIGUCHI*, Z. HAN*, V. BOUCHIAT, H. SELLIER, B. SACEPE

CONTACT

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FIGURE

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doping of graphene

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Epitaxial electrical contact to graphene on SiC

T. LE QUANG, L. HUDER, F. LIPP BREGOLIN, A. ARTAUD, H. OKUNO, N. MOLLARD, S. POUGET, G. LAPERTOT, A. G. M. JANSEN, F. LEFLOCH,E. F. C. DRIESSEN, C. CHAPELIER, V. T. RENARD

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Y. HENNI, H. P. OJEDA COLLADO*, K. NOGAJEWSKI, M. R. MOLAS,G. USAJ*, C. A. BALSEIRO*,M. ORLITA, M. POTEMSKI, C. FAUGERAS

CONTACT

KEY PUBLICATION

FIGURE

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Charge carrier puddles in graphene

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S. SAMADDAR, S. C. MARTIN, I. YUDHISTIRIA*, S. ADAM*, J. CORAUX,B. GRÉVIN, H. COURTOIS, C. B. WINKELMANN

FIGURE

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Tuning the valley quantum state of 2D

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J. R. WALLBANK1, D. GHAZARYAN1, A. MISRA1, Y. CAO1, J. S. TU1, B. A. PIOT, M. POTEMSKI, S. PEZZINI2, S. WIEDMANN2, U. ZIETLER2, T. L. M. LANE1, S.V. MOROZOV1,3,4, M. T. GREENAWAY5, L. EAVES1,5, A. K. GEIM1, V. I. FAL’KO1, K.S. NOVOSELOV1, A. MISHCHENKO1

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Electronic structureof van der Waals-based two-dimensional materials probed at the atomic scaleT. LE QUANG, V. CHERKEZ, P. MALLET, J.-Y. VEUILLEN

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Tuning valley polarization in aWSe2

A. BOGUCKI*, K. NOGAJEWSKI, P. KOSSACKI*, M. POTEMSKI

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of dark intravalley excitons in transition metal dichalcogenidesA. O. SLOBODENIUK, D. M. BASKO

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Exciton-phonon relaxation bottleneck and radiative decay of thermal exciton reservoir in two-dimensional materialsA. O. SLOBODENIUK, D. M. BASKO

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Defect-bound states, electronic doping and strain in single-layer MoS2

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S. DUBEY, S. LISI, G. NAYAK, F. HERZINGER, K. WATANABE*, T. TANIGUCHI*, L. MARTY, J. RENARD, N. BENDIAB, J. CORAUX, V. BOUCHIAT, V.-D. N’GUYEN, L. MAGAUD, T. LE QUANG, V. CERCHEZ, P. MALLET, J.-Y. VEUILLEN

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Single photon emitters in 2D crystals

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M. KOPERSIK*, K. NOGAJEWSKI, A. ARORA, V. CHERKEZ, P. MALLET,J.-Y. VEUILLEN, J. MARCUS, P. KOSSACKI*, M. POTEMSKI

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Brightening of dark excitons in monolayers of semiconducting transition metal dichalcogenides

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M. R. MOLAS, C. FAUGERAS, A. O. SLOBODENIUK, K. NOGAJEWSKI,M. BARTOS*, D. M. BASKO, M. POTEMSKI

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1)

2)

3)

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Unconventional spin texturein graphene /cobalt hybridsA. D. VU, J. CORAUX, G. CHEN*, A. T. N’DIAYE*,A. K. SCHMID*, N. ROUGEMAILLE

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Enhancement of the perpendicular magnetic anisotropy of cobalt-graphene heterostructuresH. X. YANG, A. D. VU, A. HALLAL, N. ROUGEMAILLE, J. CORAUX, G. CHEN*, A. K. SCHMID*, M. CHSHIEV

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Tailoring magnetic insulator proximity effects in graphene: first-principles calculationsA. HALLAL, F. IBRAHIM, H. X. YANG, S. ROCHE*, M. CHSHIEV

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Graphene as an active material for in vitro and in vivo neuro-electronics

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C. DELACOUR, F. VELIEV, A. BOURRIER, V. BOUCHIAT

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Electronicrecording port

Probes, fluidicmanipulation port

Opticalmonitoring port

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Medical use of graphene as a «smart skin» for improved wound-healing technology

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HIGHLIGHT 2D@GRENOBLE

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COPYRIGHTSCOVER : ©FOTOLIA / BEHOLDEREYENANOART : ©IONELA ILIESCU / ©GEORGIANA IRINA GROZA

© JONATHAN QUINSON / © ALEXIS WARTELLE

DIRECTORS OF PUBLICATIONJOHANN CORAUXALAIN FONTAINE

DESIGN AND LAYOUTCELINE FIGUEIREDOJOHANN CORAUX

2013, JULY 2014, FEBRUARY

NANOART CONTESTLEAD BY THE NANOSCIENCES FUNDATIONMORE INFORMATION : WWW.FONDATION-NANOSCIENCES.FRSECTION «NANOART»

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2015, JANUARY 2017, APRIL

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HIGHLIGHT 2D@GRENOBLE

FONDATION NANOSCIENCES

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