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TRANSCRIPT
HTS activities at Deutsche Nanoschicht and BASF
Michael Baecker, Ron Feenstra, Martina Falter, Jan Kunert, Brygida Wojtyniak, Jan Bennewitz; Deutsche Nanoschicht GmbH
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Outline
Companies and structure
Deutsche Nanoschicht
BASF SE
BASF New Business
Product and process development
Performance
Key R&D factors
Ic development
Up-scaling
Expanded Pilot Line (EPL)
Conclusion
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Deutsche Nanoschicht GmbH
Founded in November 2011 by Dr. Michael Bäcker in succession of Zenergy Power
In June 2013 BASF New Business GmbH acquired all shares of Deutsche Nanoschicht
Located in Rheinbach, Germany
45 employees (chemists, physicists, engineers, technicians, workers)
Expertise in HTS wires, chemical solution deposition, ceramic functional layers, ink-jet-
printing, epitaxial growth
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BASF SE The Chemical Company
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Annual report 2013
Income from operations
before special items
(million €)
Sales
(million €)
BASF SE The Chemical Company
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Annual report 2013
BASF Group employees by region; total: 112,206
Global Know-How Verbund BASF New Business
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Thanks to our close cooperation with numerous partners from science and business
worldwide, we have created an international and interdisciplinary Know-How Verbund.
Science Relations and Innovation Management Approx. 10,650 employees
in research and
development
worldwide
Know-How Verbund with
about 600 excellent
universities, research
institutions and companies
To generate new business areas for BASF, BNB invests…
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BNB – Business Build up
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Building up growth fields with clear path to reach > €500 million sales
Dedicated organization in well-defined growth fields
► Clear milestone plan
► Innovation Business Units with marketing, sales and technology functions
► Collaborations along the innovation value chain with industry partners and experts
Business
Build-up
BVC
Scouting &
Incubation
BASF New Business
e-power
organic electronics
High Temperature Superconductors are key element of Growth Field E-Power Management
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Power Generation: Conversion efficiency
High Temperature Superconductors
Perovskite Solar Cells
Grid: Transmission efficiency
High Temperature Superconductors
Grid: Storage
Batteries
Thermal Storage
Power-to-Gas
Industry: Consumption efficiency
High Temperature
Superconductors
Buildings: Consumption efficiency
Solid State Cooling
BNB – IBU E-Power Management
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BASF New Business
Head of IBU
Marketing
Sales
Technology
• R&D
• Pilot production
BASF SE Process Research &
Chemical Engineering
Technology platform:
• Chemical Solution Deposition
• Inorganic Thin Films
IBU: Innovative Business Unit
Product and process development
All-solution Coated Conductors Approach
Advantages
highest throughput (deposition rates)
lowest investment
lowest energy consumption
low raw material costs
Favourable for energy applications
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Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Key success factors
Industrial cooperation partners
VDM metals for textured substrates
Honeywell Specialty Chemicals for coating solutions
Process improvements
Substrate optimization
Understanding of growth processes
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VDM metals
Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Industrial cooperation with VDM metals
Large scale manufacturing
Joint development
Continuous improvement
High reproducibility
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with curtesy of VDM metals
Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Industrial cooperation with
VDM metals
Continuous improvement
Optimization of heat treatment
and rolling conditions to
avoid single tilted grains
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Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Industrial cooperation with VDM metals
Continuous improvement
Optimization of
surface treatment
before coating
15 as received after surface treatment
Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Understanding of growth processes
Homogeneous nucleation
Fast growth
16 Confocal laser microscopy SEM
Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
20cm out of 10m sample
1000nm HTS layer thickness
Ic = 275 A/cmw (77K, sf)
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Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
20cm out of 10m sample
1000nm HTS layer thickness
Ic = 275 A/cmw (77K, sf)
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Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
20cm out of 10m sample
1000nm HTS layer thickness
Mechanically structured tapes
Ic = 600 A/cmw (30K, 1T)
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Product and process development
Recent improvement of Ic in continuously processed all-solution
Coated Conductors with industrial raw materials
Measurement of inter/intra granular current
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Jc(Heff=0)
Hpeak
Intra-granular JcG determined from
fully flux-penetrated state (77 K)
Jc = 1.8 MA/cm2
JcG = 2.3 MA/cm2
Jc / JcG = 0.7-0.8
strong GB meandering
SuST 24 (2011) 062001
Product and process development
Up-scaling – Expanded Pilot Line (EPL)
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Lab processing Expanded Pilot Line
Product and process development
Up-scaling – Expanded Pilot Line (EPL)
EPL construction until mid 2015
Planned capacity > 200km technical HTS wire
Start sampling for customer projects end 2015
Key success factors
Engineering team in-house
Construction and programming in-house
Robust non-vacuum technology
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Conclusion
HTS is key element of IBU e-power management
Integration of Deutsche Nanoschicht completed
Significant performance increase in 2014
Joint laboratory with KIT (B. Holzapfel) started in 10/2014
Up-scaling on track
Discussion with potential customers ongoing
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