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Page 1: Hydrogen RHIA & NAG

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Page 2: Hydrogen RHIA & NAG

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Hydrogen RHIA & NAGHydrogen: The smallest molecule, the biggest impact!7 October, 2021

Rick Claus – Sales Engineer Hydrogen

T: +31(0) 6 4887 05 28

E: [email protected]

Page 3: Hydrogen RHIA & NAG

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Introduction to Linde

→ The leading industrial gases and

engineering company

→ Formed in 2018 with the merger of

Linde AG and Praxair, Inc – two world-

class companies with nearly 140

years of shared history and successful

achievements

→ Proven critical project execution

knowledge in diverse geographies

→ Best-in-Class Safety Performance

OneLinde

Uniting with a shared Vision,

Mission and Strategic Direction,

and demonstrating our Values

and Behaviors in everything we

do

2 million+customersEstablishing a more diverse and

balanced portfolio

100+countriesEnabling strong, complementary positions in

all key geographies and end markets

$27 billionReported sales in 2020With 7% represented by hydrogen

~80,000employeesAchieving our full potential, individually

and collectively

6,500+active patent assets

worldwideLeading with innovative products, solutions

and technologies

→ Linde Gas Benelux is headquartered in

Schiedam

→ ~220 employees

→ Production facilities and offices in

Ijmuiden, Rotterdam Botlek ,

Eindhoven, Hedel, Dieren,

Grimbergen and Namen

Page 4: Hydrogen RHIA & NAG

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Hydrogen colors

H2 production from SMR

with emitted CO2

Grey Hydrogen

CO2

Grey H2 production with

CO2 removal, storage or

reuse

Blue Hydrogen

CO2

Co

lor/

Pro

cess

End

use

s

Brown Hydrogen Green Hydrogen

Electrolysis with renewable

energies without CO2

emissions

H2 production from coal

with emitted CO2

Existing

applicationsAll applications All applications

New

applications

in transition

Chemistry & Energy

CO2

Clean Hydrogen

Page 5: Hydrogen RHIA & NAG

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The hydrogen molecule

= Atomic number 1

= Atomic mass of 1.00797

= Great abundance in the universe

= Nuclear fusion in the sun

= Not a natural element on earth

= Produced via chemical processes

Number, data, facts

Properties of hydrogen

– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 1.013 bar (a) = 0.09 kg

– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 50 bar (a) = 4.1 kg

– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 200 bar (a) = 15.0 kg

– 1 m³ liquid hydrogen (LH2) at -253 ° C, 1.013 bar (a) = 70.8 kg

– 1 kg hydrogen corresponds to 33.33 kWh calorific value (= 3.3 l heating oil, 2.4 kg methane)

10/12/2021 Footer

Page 6: Hydrogen RHIA & NAG

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Supply concept gaseous hydrogen trailer

Main facts

6

Compression /

Trailer filling

Trailer

TransportStorage in

pressure vessel

➢ Power consumption

1-3 kWh/kg

➢ Fully automatic filling

process including

analysis

➢ ISO 14687 and

NEN-EN 17124

➢ Pressure 200-500 bar

➢ Load ca. 300-1100 kg

hydrogen

➢ High transport costs

because of rel. low

load.

➢ Technically relatively

simple

➢ Pressure 50-200 bar;

Density 4-15 kg/m3

➢ Length / height up to

approx. 20 m

Page 7: Hydrogen RHIA & NAG

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Supply concept gaseous hydrogen trailer

GH2 Trailer

7

0

100

200

300

400

500

0 200 400 600 800 1.000 1.200

bar

kg

Page 8: Hydrogen RHIA & NAG

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Supply concept GH2 trailer

On-site storage

Trailer change Mid. pressure tank High pressure tank

Exchange of empty trailers for full trailers

• Fast delivery• High supply pressures• Requires a lot of space• Extensive planning required

45 bar container (vertical / horizontal)• Small footprint (vertical)• Filling volume up to approx. 440 kg /

tank (115 m³ volume)• Height up to 21 m• Only when low pressure is required up

to approx. 20 bar

200 bar container (vertical / horizontal)• Small footprint, low height (approx.

11 m)• Filling volume up to approx. 300 kg /

tank (22 m³ volume)• High supply pressures

Page 9: Hydrogen RHIA & NAG

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Supply concept Liquid hydrogen trailer

Main facts

9

Liquefaction /

Trailer filling

LH2 Trailer

Transport

Cryogenic insulated tank

➢ Liquefaction at -253 °C

➢ Energy consumption

7-10 kWh / kg, including

nitrogen precooling

➢ Load approx. 3000-

3500 kg hydrogen

➢ Max. Pressure of 9

bar

➢ Proven technology

➢ Compact

(70 kg/m3)

LH2

Page 10: Hydrogen RHIA & NAG

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Supply concept Liquid hydrogen trailer

LH2 trailer / storage on site

10

40 ft – ~ 3000 kg load 44 ft – ~ 3500 kg load Up to 13 m in height, up

to ~ 5000 kg content

Page 11: Hydrogen RHIA & NAG

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The Linde product portfolio

Biomethane Reforming Leuna

• Green hydrogen from biomethane

via steam reformer

• CO2 reduction min. 50% *

2022: PEM electrolysis in Leuna

• 24 MW (4,800 Nm³) capacity

• World's largest PEM electrolysis plant

• CO2 reduction at least 75% *

GH2

GH2

GH2

LH2

Energiepark Mainz

− Green hydrogen via PEM electrolysis

(4 MW)

− CO2 reduction at least 75% *

Audi e-gas plant Werlte

• Pilot project power-to-gas with

alkaline electrolysis (6 MW)

• Linde has an acceptance agreement

• CO2 reduction at least 75% *

* inkl. Konditionierung und Transport

Chempark Dormagen

• 340 bar gaseous hydrogen

• TÜV sud certified green hydrogen

GH2

Page 12: Hydrogen RHIA & NAG

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ITM Power - relationship at a glance

First success story in green H2 partnership

▪ Construction of the worlds largest PEM electrolyzer 24mW at Linde’s industrial park at Leuna Chemical Complex, Germany

▪ Operational in 2022

▪ Supplying green gaseous and liquified H2, avoiding up to 40.000 MT CO2e per year

Page 13: Hydrogen RHIA & NAG

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Norled H2 ferry project, REN

MF HYDRA – World’s first LH2 driven ferry

MF HYDRA:• Length 82m

• Capacity 80 cars and 299 passengers

• LH2-tank capacity 4 tons

• PEM FC 400 kW

• Battery 1,5 MWh

L .Vartia

Page 14: Hydrogen RHIA & NAG

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Norled H2 ferry project, REN

MF HYDRA - Linde Engineering’s solution

• Linde Engineering to carry out the: development, Engineering,

Manufacturing, Installation and commissioning of Liquid

Hydrogen Fuel System

• Linde Engineering Scope of delivery :

I. LH2 Tanks

II. Water Bath Vaporizer

III. Piping

IV. Bunkering System

• Experience with DNV requirements and approval process

L .Vartia

Page 15: Hydrogen RHIA & NAG

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Linde Hydrogen Fueltech for hydrogen mobility

Decarbonize transportation.

Supply for H2 busses/trucks Supply for H2 forklift trucksSupply for H2 cars Supply for H2 trains

Compression(ionic compressor)

Pumping(cryo-pump)

Stand-alone dispenser(350/700 bar)

Integrated dispenser(700 bar mobile fueling)

Service/Maintenance(smart operation)

Linde subsidiary (100%), supplier of hydrogen infrastructure solutions

reliable H2 supplies through state-of-the-art fueling station systems

✓ >200 fueling stations installed worldwide

✓ Supplier of the world’s biggest hydrogen bus depot in California

✓ Supplier of the world’s first H2

station for passenger trains✓ >1.5 million fuelings of cars,

buses & forklifts

Tokyo

Page 16: Hydrogen RHIA & NAG

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About Linde Hydrogen FuelTech GmbH

Solutions and services to enable H2 mobility projects worldwide

About Linde Hydrogen FuelTech

Experience: +15 years of technology development

Products: H2-refueling systems (HRS) & services

Scope of work: Development of key components, process & system

design, manufacturing, installation & commissioning, after sales

services

Manufacturing Locations: Germany, Austria and China

7%

APAC

19%

74%EMEA

USA >200

Number of Linde HRS installed

Best in class - Out of experience!

✓ Highest efficiency ~1,3 kWh/kg 1

✓ Highest reliability > 97% 2

✓ Highest safety Zero incidents at any HRS in operation

1 based on Ionic Compressor platform versions2 based on all Ionic Compressor based HRS commissioned in the last 24 months

Page 17: Hydrogen RHIA & NAG

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Making our world more productive

Enabling the energy transition

Page 18: Hydrogen RHIA & NAG

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Back-up slides

Page 19: Hydrogen RHIA & NAG

1910/12/2021 Footer

Safety precoutions

– PGS-35

– Hydrogen installations for delivering hydrogen to vehicles and equipment

– ATEX zone 0, 1 or 2

– Spark free tools

– Anti-static clothing

– Safety distances

– Flashback arrestor

Safety

Page 20: Hydrogen RHIA & NAG

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Linde’s capabilities today: experts in H2 production & handling technologies.

Well prepared – missing link closed for green H2 production.

ProductionDistribution & Storage End-useApplications

Industry

Feedstock

Transportation

Fuel

Power Generation

& Buffering

Industry Heat

SMR

Electrolysis

Combustion/heating

Compression

Purification

Recycling

LiquefactionGasification

Pipeline

Bulk Refuelling(De-) Hydrogenation

(Green) Power Procurement

‘Last Mile’ handling

Cavern

ΩCCUS Technologies

Processing ‘Last Mile’ distribution

Heating & Power

for Buildings

Processing

R CH2

Page 21: Hydrogen RHIA & NAG

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ITM Power - relationship at a glance

Jointly getting ready for market ramp-up in green H2

▪ ITM Power specialise in the manufacture of integrated hydrogen energy systems

▪ Founded in June 2001

▪ ~180 FTEs

▪ Factory for 1,000 MW annual output, with first phase of 300 MW p.a. production started 2021

Linde’s role:

▪ 20% minority share

▪ 50/50 JV with ITM Power on market & project development, feasibility studies, proposals & sales, and project mgmt. coordination relating to EPC projects in market segments mobility, refinery, steel, chemistry and other Power-2-X, and preferred supplier for Linde Gas

Page 22: Hydrogen RHIA & NAG

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Infrastructure

Unrivalled H2 network: global reach, strong local presence

1600+ Liquid and Gaseous H2 trailersOperation of 150+ steam methane

reformers and PSAs

Largest H2 liquefaction capacity in the world

with 170 tons/day

From production Through processing To storage and distribution

80+ electrolyzers installed

Joint Venture with ITM Power providing PEM

electrolysis plant solutions

Vast experience in H2 compression 40+

installed 1000+ km H2 pipeline

World leader in cryogenics. 20,000+ cryogenic tanks supplied*

Solutions for on-site production

* more than 20,000 cryogenic tanks for liquefied gases supplied since 1960

200+ Liquid and Gaseous H2 refueling stations

Page 23: Hydrogen RHIA & NAG

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Gearing up for clean hydrogen

How Linde supports customers and industry partners

Hydrogen production with electrolysis

Global green gas solutions at industrial scale using ITM

Power’s modular PEM electrolysis technology and Linde’s

world class EPC expertise and technologies.

Renewable energy storage

Experienced partner in the development of energy parks.

Operating the first commercial high-purity H2 cavern for

over a decade.

Hydrogen Refueling Stations

Highly efficient and fast fueling concepts for cars, trucks,

trains, forklifts and buses. Worldwide leader in installed H2

refueling stations.

Carbon capture, utilization and storage

Linde offers proven CCUS technologies and is part of

numerous R&D alliances to leverage government funding.

Industry feedstock

Trusted supplier of heavy industries, such as steel,

chemicals and refining, Linde is well equipped to support

the transition to a low carbon production.

Infrastructure

Over 1000 km of H2 pipeline. Decades of experience in

operating high-purity, high-pressure H2 pipelines. Largest

global hydrogen liquefaction capacity and distribution fleet of

liquid and gaseous trailers.

Page 24: Hydrogen RHIA & NAG

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Innovative business model.

Build-own-operate model for hydrogen production and filling or refueling station.

Supply contract

Linde Gas Customer

Planned compensation

(various models)

State-of-the-art production and

compaction technology

Investment, assembly

& Commissioning

Operation, service, maintenance

& Insurance

Back-up supply

& Logistics

Continuous &

safe H2 supply

Hydrogen plants:Production, Tailer filling & Refueling station

Supply connection (electricity, water, etc.)