hydrophobic and hydrophilic
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Hydrophobic and hydrophilic forces are interactions that serve to keep chemical
groups positioned close to one another. Hydrophobic is water-repelling and Hydrophilic is
water-loving.
Hydrophobic interactions are created because of the uncharged nature of the involved
chemical groups. An example of such a chemical group is CH. All the bonds around the
carbon atom are occupied. !he chemical group is described as being non-polar. !hus" a water
molecule#a polar molecule#is unable to establish an association with the non-polar
chemical group. !his tends to create instability in the network of water molecules" and so is
undesirable. !he repulsive force of the surrounding water molecules acts to force
hydrophobic regions into an association with like regions. !he effect tends to be theformation of a hydrophobic $pocket$ or $envelope$ in a protein or a carbohydrate molecule or
matrix. How soap works is a good explanation of hydrophobic and hydrophilic. !here two
ends on a molecule of soap. %ne of them is hydrophilic end and that end loves the water but
keeps away from hydrocarbons" &A molecule that only contain hydrogen and carbons'" and
the oils and fats. !he other part is hydrophobic and keeps away from the water but grabs on
to the dirt and oil" etc. !hen the oil and fats" etc. can be easily washed away. Hydrophilic
interactions are possible with polar chemical group. (ater is polar because oxygen is far
more electronegative than hydrogen and thus the electrons involved in an oxygen-hydrogen
bond spend more time in proximity to the oxygen atom. )ecause of this une*ual electron
sharing" the oxygen atom takes on a partial negative charge and the hydrogen atom a partial
positive charge. +n addition" the bonds in a water molecule cancel each other out. %ther polar
groups can then form ionic type bonds with water.
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,ome examples of Hydrophilic are water" milk" soap" wool" hair" and cellulose &the
main constituent of paper" wood" and cotton'. ,ome of the examples of Hydrophobic are oil"
waxes" fats" all fatty acids" and the hydrophobic end of the soap.
,urfactants" or surface active agents" are amphiphilic molecules that contain a polar
head group and a non polar tail group" as shown in igure . !he hydrophobic group is
typically a linear or branched alkyl chain while the head group of the surfactant molecule can
be either a non ionic" cationic" or anionic group. )ecause of the distinct differences between
these regions of the molecule" surfactants like to reside at interfaces.
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!he structure of a surfactant molecule has two distinct parts. !he hydrophilic head is
polar and likes to come into contact with an a*ueous phase. !he hydrophobic tail is non polar
and resists interactions with an a*ueous phase.
/eference
. http011www.nnin.org1education-training1k-2-teachers1nanotechnology-
curriculum-materials1water-race-hydrophobic-3
2. https011researchthetopic.wikispaces.com1!he4difference4between4hydrophobi
c4and4hydrophilic45art42. http011www.encyclopedia.com1doc162-73893329:.html
7. http011www.che.ufl.edu1unit-ops-lab1experiments1;icelles1;icelles-
manual237.pdf