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    ORGANICS GRANULATIONBIO-FERTILIZER & VALUE-ADDED WASTE STREAMS

    31st Conference of the Institute for Briquetting and Agglomeration

    San Antonio, Texas, USA

    September 29th, 2009

    Presented by:

    Brett Rittenhouse, FEECO International

    [email protected]

    (920) 468-1000

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    Principles of Organics Granulation

    A Technical Overview of Fertilizer Production from Waste Streams

    FEECO INTERNATIONAL

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    FEECO OVERVIEW

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    WHO WE ARE

    Worldwide supplier of process equipment

    Specializing in Thermal Processing, Agglomeration,

    Material Handling, and Process Systems

    Founded in 1951 as Fertilizer Engineering and

    Equipment Company.

    By the 1960s, we had diversified into Mining, Minerals,

    Pulp & Paper, and Waste Recycling and becameFEECO International.

    Privately held company with about 80 employees

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    WHAT WE DO

    Collaborate with Customers Process Development

    Feasibility Analysis

    Pilot Plant Testing Financial Modeling

    Plant Design and Engineering

    Detailed Equipment and Plant Design

    Equipment and System Supply

    Project Management single equipment to turnkey supply

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    STRENGTHS OF OUR TEAM

    Engineering Staff from all major disciplines:

    Chemical/Process

    Mechanical

    Civil/Structural

    Environmental

    Electrical

    Customer-focused Project Management

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    LABORATORY SERVICES

    Our pilot plant can be set up for testing on a single piece of equipment or multiple

    pieces as a continuous process tying together agglomeration, drying, sizing, and

    recycling capabilities.

    Batch Testing/Feasibility

    Pilot Plant Testing (500-1000 lb/hr)

    Tolling Plant (24 hr Production Runs)

    Analytical Testing

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    The 30,000 View

    ORGANICS RECYCLING

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    RECYCLING?

    Recycling involves processing used materials into

    new products to prevent waste of potentially useful

    materials, reduce the consumption of fresh raw

    materials, reduce energy usage, reduce air and waterpollution, and lower greenhouse gas emissions.

    Wikipedia, September, 2009.

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    ORGANIC WASTE STREAMS

    Agricultural Waste (Manures, Composts)

    Industrial Waste

    DAF Sludge, Food Waste, Restaurant Waste

    Municipal Waste (Biosolids, Composts)

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    THE AG-WASTE DILEMMA

    Economic pressure pushing towards herd growth

    Prohibitively high land costs lead to herd growthwithout adequate land to dispose of waste

    Nutrient levels saturated on fields where it iseconomically viable to spread

    Excess nutrient run-off leads to surface andground water pollution

    Nutrient value of manure does not get fullyrealized

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    THE AG-WASTE OPPORTUNITY

    Source of macro and micro nutrients

    Nitrogen, Phosphorus, Potassium, Sulfur, Boron

    Source of Bio-Energy Production AnaerobicDigestion

    Organic industry as a growth market

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    WASTE TRANSFORMATION: THE NEED

    Fertilizer demand is increasing

    Despite recent setbacks, non-renewable

    fertilizer prices will continue to rise US production capacity is shrinking

    World food demand is increasing

    Increasing competition for land resources(development, energy crops, etc.)

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    THE ORGANIC FOOD INDUSTRY

    U.S. sales of organic food and beverages havegrown from $1B in 1990 to $20B in 2007,20.9% growth in 2006.

    U.S. sales of non-food organic products were$17.7B in 2006, 26% growth in 2006.

    Source: Organic Trade Association

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    FERTILIZERS FROM ORGANIC

    WASTES

    Generally considered a low-analysis fertilizer

    Macronutrient content < 10% by weight.

    Wide range of feedstocks:

    Slurries (80% solids)

    The drier feed material can be finely divided andrelatively dusty

    Limits application in the field.

    Traditional granulation approaches can be implementedto improve the handling, storage, spreading, andutilization characteristics of the material.

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    ORGANIC WASTE UTILIZATION -

    RECAP

    Major Driving Force: Growth!

    Demand Side NeedsRising Fertilizer Costs

    Trade ImbalancesLocal and Secure Source of Nutrients

    Supply Side Needs

    Increasing Disposal Problems

    Environmental RegulationNeed for safe (and profitable?) means ofNutrient

    Recycling

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    FERTILIZERS FROM ORGANIC

    WASTES

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    Granulation Process Approaches

    ORGANICS GRANULATION

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    ORGANIC GRANULATION SYSTEMS

    1. Mixer Drum Dryer Granulation

    a. Pin Mixer

    b. Paddle Mixer

    2. Mixer Pan Pelletizer Drum Dryer

    Granulation

    3. Dry Pellet Mill & Crumbler

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    MIXER DRYER GRANULATION

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    MIXER DRYER GRANULATION

    Mixer selection based on feedstock analysis

    Pin mixer for finely divided particles (chicken

    litter, compost, etc.) Pug Mill/Paddle Mixer for sludges, pastes, and

    filter cakes.

    Dewatered liquid manures from centrifuge, DAF

    effluent

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    PIN MIXERS

    Used as pre-conditioning unit or stand-alone agglomerator

    One Rotor with Radial Pins

    Multiple Feeds

    Fluid Ports in Top Cover

    Relatively High Speed Turbulent Mixing Action

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    PIN MIXER BASICS

    Turbulent action of the mixer provides thorough mixing of

    liquid (binder), raw feed, and recycle

    Reduces the amount of liquid required for agglomeration

    Allows high liquid levels without over-wetting Reduces chances of segregation due to density differences

    in feed materials

    Reduces the chances of selective agglomeration

    Up to 90% of binder liquid can be added in mixer with 10%reserved for finish processing (if necessary)

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    PIN MIXER BASICS

    Mechanical work compacts the agglomerate through work between

    the pins and shell and interaction with each other

    Improved crush strength, Less attrition

    With a retention time of seconds, the mixer delivers to a finishingpelletizer (if necessary) nuclei that are properly moistened, have

    adequate density, and are thoroughly mixed with binders, recycle, and

    multiple raw materials

    Can increase on-size product up to 95% (when coupled with Pan

    Pelletizer)

    Can increase capacity of pelletizing disc or drum (nuclei formation in

    mixer)

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    PIN MIXER BASICS

    Mixer may be required for agglomeration to

    occur in pelletizing disc or drum:

    Chemical reaction (Phosphoric Acid Spray)

    Reduce moisture level in sludges by mixing with dry

    recycle

    Intimately mix liquid with raw feed (compost)

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    PIN MIXER

    High speed, Multiple feed screws

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    PIN MIXER

    Internal view, during fabrication

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    PADDLE MIXER/PUG MILL

    Slower speed, double shaft, mixing paddles

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    MIXER DRYER GRANULATION

    Advantages:

    Mixer offers moisture control of granulation process

    Simple, closed system

    Minimal waste. Off-spec product recycled in granulation loop

    Easy binder addition in mixing step

    Optimization includes evaluation of:

    Pin arrangement

    Pin tip speed

    Retention time (function of equipment sizing and mixer speed)

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    MIXER DRYER GRANULATION

    Disadvantages:

    Oftentimes a tight moisture window in pin mixer granulation limits

    control

    Material handling can be challenging for wet, sticky feed

    Require finely divided feedstock pre-grinding/de-lumping may

    be necessary

    Limitations on achievable granule crush strength (feedstock

    specific)

    Small diameter granule productionMight be desired for greens grade product

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    PAN GRANULATION

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    PAN GRANULATION - FUNDAMENTALS

    Feed from Pin Mixer fed through

    articulating feed chute

    Competition betweengravitational and centrifugal

    forces resulting segregation by

    size in tumbling bed

    Small particles at bottom of bed

    and travel furthest

    Largest particles remain inkidney shaped area on top of

    bed

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    PAN GRANULATION - FUNDAMENTALS

    Trajectories defined

    by particle size

    Optimization:

    Spray locations

    Scraper locations

    Pan Inclination

    Rotational Speed

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    PAN GRANULATION

    Advantages:

    Very good control over granule size

    Improved product quality polishing on disc

    Flexible with binder addition

    Disadvantages:

    Open system odor, housekeeping, dust, etc.

    Labor intensive

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    PELLET MILL PROCESS - OVERVIEW

    Raw Manure

    Unloading

    Manure

    Drying

    Size

    Reduction

    Steam

    ConditioningPellet Mill Crumbling

    ClassifyingFines

    On-size

    Product

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    PELLET MILL PROCESS

    Physical Product Differences

    Crumble vs. Spherical Product

    Energy UsageReduction in drying gas requirements

    Increase in electrical requirements (pellet mill)

    Reliability & Maintenance

    Careful with high silica feedstocks

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    BIO-FERTILIZER PLANT - EMISSIONS

    Gas Treatment

    Feedstock specific

    Particulate

    Wet scrubbing

    Form of Nitrogen in feedstock?

    Fuel Source? Biogas may involve SOx scrubbing

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    SELECTION OF AGGLOMERATION

    EQUIPMENT

    Parameters of Particulate Feed

    Size and Shape

    Moisture Content

    Material Characteristics

    Material Sensitivities (heat,pressure, reactivity, etc.)

    Bulk Characteristics

    Binding Characteristics

    Parameters of Agglomerated

    Product

    Size and Shape

    Strength

    Green Strength

    Final (cured) Strength

    Structure

    Source: Pietsch, Wolfgang Agglomeration in Industry, Vol 2

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    Parameters of Agglomeration

    Method

    Batch or Continuous Operation

    Capacity Requirements

    Wet or Dry Operation Space and Energy Requirements

    Investment and Operating Costs

    Site, Supply, Environment,

    Infrastructure

    Relative location to suppliers and

    customers (raw materials,

    additives/binders, energy)

    Site accessibility and transportation

    facilities

    Climatic conditions

    Availability of skilled and other labor

    Availability of support functions

    Regulations (EPA, OSHA, etc.)

    Source: Pietsch, Wolfgang Agglomeration in Industry, Vol 2

    SELECTION OF AGGLOMERATION

    EQUIPMENT

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    BIO-FERTILIZER PROCESSING

    CONSIDERATIONS

    Raw Feed Handling Feedstock specific

    Dewatering Mechanical (presses, centrifuges, etc.)

    Advanced separation with polymers

    On-farm or Centralized Plant?

    Bio-security concerns

    Feed Conditioning

    Seed pellets formed in paddle mixer with wet feed and dry recycle Pin or paddle mixer used to blend multiple feed streams

    Binder?

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    Agglomeration Seed pellets grown on disc pelletizer

    Seed pellets grown in rotary drum dryer or agglomerating drum

    Binder?

    Drying Rotary drum, fluid bed, etc.

    Pathogen Reduction (Time & Temperature)

    Product cooling & storage

    Rotary cooler, dryer cooling hood, fluid bed, etc.

    Gas Processing Thermal oxidation, exhaust gas scrubbing, PM capture

    BIO-FERTILIZER PROCESSING

    CONSIDERATIONS

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    OVERALL MASS BALANCE: ADVANCED MANURE

    MANAGEMENT

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    FEECO BIO-FERTILIZER PROCESS

    FLOW

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    FEECO BIO-FERTILIZER PROCESS

    FLOW

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    INORGANIC NUTRIENT

    FORTIFICATION

    Pipe Reactor

    Sulfuric Acid

    Phosphoric Acid

    Biosolids

    Manure

    Organic Waste

    Ammonia Fortified Granular Product

    Benefits of Fortification :

    Chemical Heat Release Utilization

    Customized grade product

    Improved margins, larger markets

    Pug Mill

    Potash

    Drying/Agglomeration

    Plant

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    FEECO BIO-FERTILIZER PLANT, HOG

    MANUREPlant aerial view

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    THANK YOU!