ightly sweet odor. it is slightly - j.p. morgan · pdf fileemergency ightly sweet odor. it is...

Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name Monoethylene Glycol

Supplier J.P. Morgan Ventures Energy Corp.

383 Madison Avenue, 10th Floor

New York, NY 10017

Synonyms MEG, Ethylene Glycol, 1,2-Ethanediol, 1,2-Dihydroxyethane, EG, Glycol, Ethylene

Glycol Polyester Grade, High Purity Grade, Industrial Grade and Antifreeze Grade

Chemical Family Ethylene Glycol

Intended Use Multiple Uses Including Chemical Feedstock, Chemical Intermediate, Chemical

Component, Chemical Constituent

24 Hour

Chemtrec: 800-424-9300

Emergency

J.P. Morgan Technical Information: 212-834-5788

Numbers

California Poison Control: 800-222-1222

2. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Concentration ACGIH OSHA NIOSH Components (%) Exposure Limits Exposure Limits Exposure Limits Name/CAS No.

Ethylene Glycol 95 - > 99.9 100 mg/m3 Ceiling 50 ppm Ceiling 50 ppm Ceiling

107-21-1 Aerosol

Diethylene Glycol < 0.5 - 5

111-46-5 Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional for further information.

ACGIH - American Conference of Government Industrial Hygienists, OSHA - Occupational Safety and Health Administration, NIOSH - National Institute for Industrial Safety and Health, TWA - Time Weighted Average (8 hour average for ACGIH and OSHA, 10 hour average for NIOSH), STEL - 15 Minute Short Term Exposure Level, Skin - indicates potential for cutaneous absorption, Ceiling - Ceiling Level, Peak - Acceptable peak over the ceiling concentration for a specified number of minutes, IDLH - Immediately Dangerous to Life and Health

3. HAZARDS IDENTIFICATION

Emergency This product is a clear, colorless liquid with a slightly sweet odor. It is slightly

Overview

combustible. It is harmful or fatal if swallowed. Swallowing this material will result

in serious health hazard, potentially leading to collapse and death. Ingestion may

result in irritation of the mouth and digestive tract. May be irritating to the eyes, skin

and respiratory system.

Potential Acute Health Effects

Inhalation High aerosol concentrations may cause respiratory irritation.

Eye Contact May include mild eye irritation with tearing, pain or blurred vision.

Skin Contact May be mildly irritating to the skin. Not a sensitizer. Not expected to be a skin

absorption hazard.

Ingestion Ingestion may include inebriation, nausea and vomiting, metabolic acidosis and

CNS depression. Cardiopulmonary effects include tachycardia, hypertension,

severe metabolic acidosis with hyperventilation, hypoxia, congestive heart failure

and adult respiratory distress syndrome as well as renal failure. May also produce a

local irritation effect on the digestive system and cause pain and bleeding.

Potential Chronic Health Effects

Signs and Repeated or prolonged exposure may result in kidney damage. May produce

Symptoms

symptoms of central nervous system depression including headache, dizziness,

nausea, euphoria, loss of equilibrium, drowsiness, visual disturbances, fatigue,

unconsciousness and respiratory arrest.

of 8 Issue Date: November 1, 2006


Monoethylene Glycol J.P. Morgan Ventures Energy Corp

3. HAZARDS IDENTIFICATION

Carcinogenic None of the components present in this material in concentrations above 0.1% are

Potential

listed as known human carcinogens by OSHA, IARC and NTP.

Target Organs May cause damage to the kidneys or liver.

Conditions Individuals with lung disorders like asthma, kidney or liver disease may have

Aggravated by

increased susceptibility to exposure. Skin contact may aggravate an existing

Overexposure dermatitis. May cause central nervous system depression.

4. FIRST AID MEASURES

Inhalation Move the exposed person to fresh air. If not breathing, clear airways and give artificial

respiration. If breathing is difficult, humidified oxygen should be administered by

qualified personnel. Seek medical attention if breathing difficulties continue.

Eye Flush eyes with water for at least 15 minutes. Hold eyelids apart to ensure complete

irrigation of the eye. Remove contact lenses, if worn, after initial flushing. Do not use

eye ointment. Seek medical attention.

Skin Remove contaminated shoes and clothing, and flush affected areas with large amounts

of water. If skin surface is damaged, apply a clean dressing and seek medical attention.

If skin surface is not damaged, clean affected area thoroughly with mild soap and water.

Seek medical attention if tissue appears damaged or if pain or irritation persists.

Launder or discard contaminated clothing.

Ingestion Immediately give two glasses of water and induce vomiting. Never give anything by

mouth to an unconscious person.. Seek medical attention.

Notes to The principal effects produced by ethylene glycols, especially by acute overexposure

Physician

from swallowing the liquid, are kidney injury and metabolic acidosis. Ethanol is antidotal

and should be administered early in the treatment. Ethanol decreases the metabolism

of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as

possible in the case of severe poisoning since the elimination half-life of ethylene glycol

is 3 hours. The patient should be monitored for metabolic acidosis. Use of appropriate

buffering solutions such as bicarbonate may be indicated. Hemodialysis may be

indicated for more complete elimination.

5. FIRE FIGHTING MEASURES

Flammability OSHA Classification (29 CFR 1910.1200): Combustible Liquid

Classification

NFPA Class-1IIA Combustible Liquid

NFPA Ratings: Health: 1, Flammability: 1, Reactivity: 0

Flash Point 116oC, 240

oF Closed Cup (Tagliabue (ASTM D-56))

Flammable Lower Limit: 3.2%

Limits

Upper Limit: 15.3%

Autoignition 398oC, 748oF

Temperature

Combustion Highly dependent on combustion conditions. May form carbon monoxide and carbon

Products

dioxide.

Fire and This material has a slight to moderate exposure hazard when exposed to heat and

Explosion

flame. Above the flash point, vapor-air mixtures are explosive within the flammable

Hazards

limits. A product container, if not properly cooled, can rupture in the heat of a fire.

Extinguishing Dry chemical, carbon dioxide, water spray or alcohol resistant foam is recommended.

Media

Water spray is recommended to cool or protect exposed materials or structures.

Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in

confined spaces. Water may be ineffective for extinguishment, unless used under

favorable conditions by experienced fire fighters. Water or foam may cause violent

frothing.




5. FIRE FIGHTING MEASURES

Fire Fighting Use water spray to cool fire-exposed containers and to protect personnel. Isolate

Instructions

immediate hazard area and keep unauthorized personnel out. Water spray may be

useful in minimizing or dispersing vapors and to protect personnel. Cool equipment

exposed to fire with water. Avoid spreading burning liquid with water used for cooling.

For fires beyond the incipient stage, emergency responders in the immediate hazard

area should wear bunker gear. When the potential chemical hazard is unknown, in

enclosed or confined spaces, or when explicitly required by regulations, a self-contained

breathing apparatus should be worn. Wear other appropriate protective equipment as

conditions warrant.

6. ACCIDENTAL RELEASE MEASURES

Protective Keep all sources of ignition and hot metal surfaces away from spill/release. The use of

Measures

explosion-proof electrical equipment is recommended. Stay upwind and away from

spill/release. Isolate immediate hazard area and keep unauthorized personnel out.

Wear appropriate protective equipment as conditions warrant per Exposure

Controls/Personal Protection guidelines.

Spill Stop the leak if it can be done without risk. Prevent spilled material from entering

Management

waterways, sewers, basements or confined areas. Contain release to prevent further

contamination of soils, surface water or groundwater. Clean up spill as soon as

possible using appropriate techniques such as applying non-combustible absorbent

materials or pumping. All equipment used when handling the product must be

grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-

sparking tools to collect absorbed material. Where feasible and appropriate, remove

contaminated soil. Dispose of contaminated materials in a manner consistent with

applicable regulations.

Reporting Report spills/releases as required, to appropriate local, state and federal authorities. US

Coast Guard and Environmental Protection Agency regulations require immediate

reporting of spills/release that could reach any waterway including intermittent dry

creeks. Report spill/release to the National Response Center at (800) 424-8802. In

case of accident or road spill, notify Chemtrec at (800) 424-9300.

7. HANDLING AND STORAGE

Handling Avoid open heating or agitation that may generate vapors or mists. Bond and ground all

equipment when transferring from one vessel to another. Use non-sparking tools and

explosion-proof equipment.

Storage Use and store this material in cool, dry, well-ventilated areas away from sources of

ignition. Keep away from incompatible material.

Special Electrical equipment and fittings should comply with local fire codes.

Precautions

Portable Use only approved containers. Keep containers tightly closed.

Containers

Empty Empty containers retain liquid and vapor residues and can be dangerous. Do NOT

Container

pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat, flame,

Warning

sparks, static electricity or other sources of ignition; they may explode and cause injury

or death. Do not attempt to refill or clean containers since residue is difficult to remove.

Empty drums should be completely drained, properly closed and returned to the supplier

or a qualified drum reconditioner. All containers should be disposed of in an

environmentally safe manner in accordance with government regulations.




8. EXPOSURE CONTROL / PERSONAL PROTECTION

General Consider the potential hazards of this material, applicable exposure limits, job activities

Considerations

and other substances in the work place when designing engineering controls and

selecting personal protective equipment.

Engineering Use process enclosures, local exhaust ventilation or other engineering controls to

Controls

maintain airborne levels below the recommended exposure limits. An emergency eye

wash station and safety shower should be located near the work station.

Personal If engineering controls or work practices are not adequate to prevent exposure to

Protective

harmful levels of this material, personal protective equipment (PPE) is recommended. A

Equipment

hazard assessment of the work should be conducted by a qualified professional to

determine what PPE is required.

Respiratory When airborne concentrations are expected to exceed the established exposure limits

Protection

given in Section 2, use a NIOSH approved organic vapor respirator. Use a full-face

positive-pressure supplied air respirator in circumstances where air-purifying respirators

may not provide adequate protection. If internal combustion devices are used in an

enclosed space, carbon monoxide will be present in the exhaust. If the airborne

concentrations are above the occupational exposure limit for carbon monoxide, use a

positive pressure air-supplying respirator.

Eye Safety glasses equipped with side shields are recommended as minimum protection in

Protection

industrial settings. Chemical goggles should be worn during transfer operations or

when there is a likelihood of misting, splashing or spraying of this material.

Skin and Avoid skin contact. Wear long-sleeved fire-retardant garments while working with

Body

flammable and combustible liquids. Additional chemical-resistant protective gear may

Protection

be required if splashing or spraying conditions exist. This may include an apron, arm

covers, impervious gloves, boots and additional facial protection.

Hand Avoid skin contact. Use impervious gloves (e.g., PVC, neoprene, nitrile rubber). Wash

Protection

hands with plenty of mild soap and water before eating, drinking, smoking, using toilet

facilities or leaving work.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear, colorless Physical Form Liquid

Odor Slightly sweet Odor Threshold Not established

pH Neutral Vapor Pressure <0.1 psi 100oF, 38

oC

Vapor Density > 2 (air = 1) Boiling Point/Range 388oF/1989

oC

Percent Volatile 100% Partition Coefficient <3

Specific Gravity 1.15 @ 60oF Density 9.3 lb/gal @ 60

oF

Molecular Weight 62 Evaporation Rate Not established

Flash Point 240oF/116

oC Test Method ASTM 56

Explosive Limits 3.2% LEL, 15.3% UEL Autoignition 748oF/398oC

Temperature

Solubility in Water Essentially 100%

10. STABILITY AND REACTIVITY

Stability Stable under normal anticipated storage and handling temperatures and pressures.

Conditions to Avoid all possible sources of ignition.

Avoid

Incompatibility Avoid contact with strong oxidizing agents such as strong acids, alkalies, chlorine and

(Materials to

other halogens, dichromates or permanganates, which can cause fire or explosion.

Avoid)

Hazardous Carbon monoxide and carbon dioxide.

Decomposition

Products


Material Safety Data Sheet Monoethylene Glycol J.P. Morgan Ventures Energy Corp

10. STABILITY AND REACTIVITY

Hazardous Will not occur

Polymerization

11. TOXICOLOGICAL INFORMATION Ethylene Glycol 107-21-1

Acute Toxicity: Dermal LD50 = 9530 mg/kg (Rabbit) Oral LD50 = 4700 - 13,400 mg/kg (Rat) Carcinogenicity: Ethylene glycol was not carcinogenic in two-year studies in rats and mice. This material is not classified as a carcinogen. Not listed by IARC, NTP or OSHA. Target Organs: If exposures are sufficiently high to cause accumulation of calcium oxalate crystals, kidney pathology may occur. In rats, crystal nephropathy has been seen after dietary administration of 500 mg/kg bwt/day for 16 weeks, whereas no effects were seen in rats that ingested 200 mg/kg bwt/day for 2 years or in several animal species that inhaled 12 mg/m

3 for 3 months. Human

exposures at occupational relevant concentrations are unlikely to cause crystal nephropathy. Developmental: Doses of ethylene glycol that result in high levels of the metabolite glycolic acid induce developmental/teratogenic effects in rats and mice, although at doses greater than those associated with kidney effects in rats. Human exposure is not expected to generate sufficient levels of glycolic acid; therefore, no developmental effects are expected in humans. Mutagenicity: Negative for genotoxicity both in vitro and in vivo tests.

Diethylene Glycol 111-46-6 Acute Data: Dermal LD50 = 11,900 mg/kg (Rabbit) Oral LD50 = 13,300 mg/kg (Mouse); 25,300 mg/kg (Rat) Carcinogenicity: No evidence of carcinogenicity was found with a chronic skin painting study in mice. No carcinogenic or tumor promoting effects in rats exposed up to 2.5% solutions in drinking water for 108 weeks. Older feed studies utilizing limited number of tissues but very high doses also provide no evidence of carcinogenicity. Not listed by IARC, NTP or OSHA. Target Organs: Diethylene glycol given to rats in the diet for two years caused bladder stones, tumors and kidney and liver damage. These effects were probably due to contamination with ethylene glycol and the bladder stones were formed from oxalate crystals. Developmental: Reproductive and developmental effects have been noted in animals following very large (>3000 mg/kg bwt/day) oral doses. However, comparable internal dose levels are not possible with dermal or inhalation exposures under normal conditions of use. Therefore, diethylene glycol is not considered a reproductive or developmental hazard except during very large oral doses.

12. ECOLOGICAL INFORMATION

Ecotoxicity 96 hours LC50: 22,810 mg/l (Rainbow trout)

96 hours LC50: 49,000 mg/l (Fathead minnow)

48 hours EC50: 41,000 mg/l (Daphnia magna)

48 hours EC50: 10,000 mg/l (Daphnia)

This material is not expected to be toxic to aquatic organisms.

Environmental Ethylene glycol is water soluble. It is mobile in soil, not likely to adsorb to sediment or

Fate

suspended particulate matter. It is not likely to volatize from surface waters or soils. It

has an environmental half-life of 0.35 to 24 days in soil, air, surface and ground water.

Undergoes photooxidation with hydroxyl radicals in air with a half-life of 8.3 to 83 hours.

Reported biodegradation studies show ethylene glycol with 97% biodegradation after

20 days and 96% biodegradation after 28 days. Biodegradable under aerobic

conditions. This material is not expected to bioaccumulate.



13. DISPOSAL CONSIDERATIONS

This material, if discarded as produced, is not a RCRA "listed" hazardous waste. However, it should be fully characterized for ignitability (D001) prior to disposal (40 CFR 261). Use which results in chemical or physical change or contamination may subject it to regulation as a hazardous waste. Along with properly characterizing all waste materials, consult state and local regulations regarding the proper disposal of this material.

Container contents should be completely used and containers should be emptied prior to discard. Container rinsate could be considered a RCRA hazardous waste and must be disposed of with care and in full compliance with federal, state and local regulations. Larger empty containers, such as drums, should be returned to the distributor or to a qualified drum reconditioner. To assure proper disposal of smaller empty containers, consult with state and local regulations and disposal authorities.

14. TRANSPORTATION INFORMATION

United States Department

Shipping Description: Environmentally hazardous substance, liquid, n.o.s.

of Transportation (Ethylene Glycol), 9, UN3082, III

(US DOT)

Shipping Name: Environmentally hazardous substance, liquid, n.o.s.

(Ethylene Glycol) Transportation of Hazard Class and Division: 9 Dangerous Goods (TDG) ID Number: UN3082 Canada

Packing Group: PGIII

Label: Class 9

Placard: Class 9

Reportable Quantity: 5000 lb

Emergency Response Guide: 171

MARPOL III Status: Not a DOT Marine Pollutant per 49 CFR 171.8

International Maritime

Shipping Description: UN3082, Environmentally hazardous substance,

Organization liquid, n.o.s. (Ethylene Glycol), 9, III

International Maritime Shipping Name: Environmentally hazardous substance, liquid, n.o.s. Dangerous Goods Code (Ethylene Glycol)

(IMO/IMDG)

Hazard Class and Division: 9

UN Number: 3082

Label: Class 9

European Agreements

Shipping Name: Environmentally hazardous substance, liquid, n.o.s.

Concerning the (Ethylene Glycol)

International Carriage by Hazard Class: 9 Rail (RID) and by Road Packing Group: III (ADR)

International Civil Aviation Shipping Name: Environmentally hazardous substance, liquid, n.o.s.

Organization / (Ethylene Glycol)

International Air UN/ID Number: UN3082 Transport Association Hazard Class/Division: 9

(ICAO/IATA)

Packing Group: III

15. REGULATORY INFORMATION

United States Federal Regulatory Information EPA TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act

(TSCA) Inventory of 8 Issue Date: November 1, 2006


15. REGULATORY INFORMATION

EPA SARA 302/304 This material contains the following chemicals subject to reporting under the

Emergency Planning

Superfund Amendments and Reauthorization Act of 1986 (SARA): Product is

and Notification

not listed as an extremely hazardous substance

EPA SARA 311/312 Acute Health: Yes

(Title III Hazard

Chronic Health: Yes

Categories)

Fire Hazard: No

Pressure Hazard: No

Reactive Hazard: No

EPA SARA Toxic

Component

CAS Number Concentration

RQ

Chemical Notification

Ethylene Glycol

107-21-1 > 95 %

5000 lb

and Release

The reportable quantity for this material is 5000 lb.

Reporting (40 CFR

372) and CERCLA

Reportable Quantities

(40 CFR 302.4)

EPA CWA and OPA This product is not classified as an oil under Section 311 of the Clean Water

Act (CWA) and Oil Pollution Act of 1990 (OPA).

Canadian Regulatory Information

DSL/NDSL Inventory This product and/or its constituents are listed either on the Domestic

Substances List (DSL) or the Non Domestic Substances List (NDSL).

Workplace Hazardous D2B - Materials Causing Other Toxic Effects - Toxic Material

Materials Information

System (WHMIS)

Hazard Class

European Union Regulatory Information

Labeling Product is dangerous as defined by the European Union Dangerous

Substances / Preparations Directives

Symbol

Xn Harmful

Risk Phrases R22

Harmful if swallowed.

Safety Phrases S2

Keep out of the reach of children.

California Proposition 65

This product does not contain a chemical known to the State of California to cause cancer, birth defects, or

other reproductive harm.

Carcinogen Identification by International Agency for Research on Cancer

Group 1 Carcinogenic to

Humans

Group 2A Probably Carcinogenic

to Humans

Group 2B Possibly Carcinogenic

to Humans

Group 3 Not Classifiable

16. OTHER INFORMATION

Prepared By J.P. Morgan Ventures Energy Corp. 383 Madison Avenue, 10th Floor New York, NY 10017

Precautionary DANGER! Label

This product is harmful or fatal if swallowed. Swallowing this material will result in serious health hazard, potentially leading to collapse and death. Ingestion may result of 8 Issue Date: November 1, 2006


16. OTHER INFORMATION

in irritation of the mouth and digestive tract. May cause liver and kidney damage. May be irritating to the eyes, skin and respiratory system.

In case of contact, wash skin with soap and water. Immediately remove contaminated clothing, including shoes. Destroy or wash clothing before reuse. If swallowed, give 2 glasses of water and induce vomiting. Seek medical attention.

The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. of 8 Issue Date: November 1, 2006

ightly sweet odor. it is slightly - j.p. morgan · pdf fileemergency ightly sweet odor. it is...

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