impacts of thermochemical hydrolysis on viscosity, biogas ... · impacts of thermochemical...
TRANSCRIPT
![Page 1: IMPACTS OF THERMOCHEMICAL HYDROLYSIS ON VISCOSITY, BIOGAS ... · IMPACTS OF THERMOCHEMICAL HYDROLYSIS ON VISCOSITY, BIOGAS & DEWATERABILITY Josh Gable MWEA 2018 Biosolids Conference](https://reader033.vdocument.in/reader033/viewer/2022042318/5f07cdd27e708231d41ed449/html5/thumbnails/1.jpg)
IMPACTS OF THERMOCHEMICAL HYDROLYSIS ON
VISCOSITY, BIOGAS & DEWATERABILITY
MWEA 2018 Biosolids ConferenceJosh Gable
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PRESENTATION FROM
20,000 FEET
About Centrisys/CNP
What is Thermo-Chemical Hydrolysis (TCHP) ?
Why hydrolyze your sludge?
How does Pondus TCHP work ?
Pros and Cons versus conventional hydrolysis techniques
Kenosha, WI Case Study
Assessing new projects – how to know what to expect
Conclusions
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CENTRISYS AND CNP
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WHAT IS THERMO-CHEMICAL
HYDROLYSIS?
Hydrolysis = Chemical decomposition of compounds by reacting with water
Thermal Hydrolysis = Accelerated chemical decomposition of compounds via added heat
Bust open sludge cells via high temp and pressure
300 to 320ºF under pressure for 30 min
Thermal Chemical Hydrolysis = Accelerated chemical decomposition of compounds via added heat and chemical
Bust open sludge cells via moderate heat and elevated pH
150 ºF for 2 hours with NaOH addition
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SO WHY HYDROLYZE ?
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SO WHY HYDROLYZE ?
1. Decrease Sludge Viscosity
Lower energy pumping and mixing
May enable higher solids loading to digester
2. Improve VS destruction rate and extent in Anaerobic
Digester
Generate more biogas
or Increase VS loading rate of digester(s)
3. Improve Sludge Dewaterability
Increase Cake %TS
Decrease Polymer Required
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HOW DOES PONDUS TCHP
WORK?
Chemical: 1.5 to 2.0 liters of caustic soda (50% concentration) is injected per 1 m3 of sludge
Initial pH 11+ but hydrolysis process breaks down the cell walls and releases internal organic acids which brings the pH of the flow stream back to 6.8-7.0
Detention time through the reactor and heat exchanger for 2 to 2.5 hours.
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HOW DOES PONDUS TCHP
WORK?
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HOW DOES PONDUS TCHP
WORK?
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PROS & CONS VERSUS
CONVENTIONAL SLUDGE
HYDROLYSIS
Thermal Hydrolysis CNP Pondus
Temperature 300-320°F 150°F
High Pressure Yes No
Chemical No Yes (50% NaOH)
%TS Process Feed > 10% TS 4-8% TS
Cell Degradation More complete destructionCell walls become porous, EPS is destroyed, soluble
COD release, most cell wall structure stays intact
Viscosity Reduction Similar for Both
Gas Production Upto 50% increase in gas production 20 to 30% increase typical
Sludge DewaterabilityIncreased Cake %DS, possible increase in polymer
useIncreased Cake %DS, decrease in polymer required
Cost Relatively higher Relatively lower
Foot Print Relatively higher Relatively lower
Supernatant color
Due to complete breakdown, denaturized proteins,
supernatant from dewatering tends to have yellow
color
Supernatant resembles normal digester supernatant
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PONDUS INSTALLATIONS
WORLD-WIDE
Waste Water
Treatment PlantYear Built
Capacity
WWTP [MGD]
Sludge Throughput
per Reactor
[gpm]
Notes
Gifhorn, German 2005 10 9.7 24h- activity
Ratekau, German 2007 5 1112h-activity, night
standby operation
Uelzen, German 2014 11 11.9 24h- activity
Nordhorn, German 2014 20 7.924h activity, sometimes
as pasterization in batch
Kenosha, USA 2016 28 23 24h- activity
Wolfsburg, German 2016 20 26 24hr- activity
Göppingen,
Germany2018 In Design/Construction
Löhne, Germany 2018 In Design/Construction
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KENOSHA, WI CASE STUDY
Digested Sludge HRT From 30+ Days to < 20 Days
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KENOSHA, WI CASE STUDY
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KENOSHA, WI CASE STUDY
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KENOSHA, WI CASE STUDY
- REDUCED TWAS VISCOSITY
TWAS
Hydrolyzed TWAS
(LTWAS)
0
10,000
20,000
30,000
40,000
50,000
0 10 20 30 40 50 60
Ap
pa
ren
t V
isc
os
ity (
mP
a.s
)
Stir RPM
TWAS
NaOH dosing alone
PONDUS TCHP Treatment
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KENOSHA, WI CASE STUDY
- VS LOADING & DESTRUCTION
0
50
100
150
200
0
10
20
30
40
50
60
70
80
Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec
VS
Lo
ad
ing
(lb
s/d
ay-1
000 c
f)
Vo
lati
le S
olid
s R
ed
ucti
on
(%
)
2016 VSR
2017 VSR
2016 VS Volumetric Loading
2017 VS Volumetric Loading
Estimated Kenosha VS
Loading Rate, Pre-PONDUS
Estimated Kenosha VS
Loading Rate, Pre-PONDUS
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KENOSHA, WI CASE STUDY
- BIOGAS PRODUCTION
100,000
120,000
140,000
160,000
180,000
200,000
220,000
240,000
Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec
Bio
gas
Pro
du
cti
on
of
Pri
ma
ry A
Ds (
cfd
)
2017
2016
2012
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KENOSHA, WI CASE STUDY
- DIGESTED SLUDGE DEWATERABILITY
22%
23%
24%
25%
26%
27%
28%
29%
30%
20 25 30 35 40 45
Ca
ke
So
lids (
% T
S)
Polymer Dosage (lb/dry ton)
PONDUS Treatment
Prior PONDUS Treatment
Polymer Reduction
Cake Dryness
Improvement
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A RECAP – WHY HYDROLYZE WITH
1. Decrease Sludge Viscosity
Lower energy pumping and mixing
May enable higher solids loading to digester
2. Improve VS destruction rate and extent in Anaerobic Digester
Generate more biogas
or Increase VS loading rate of digester(s)
3. Improve Sludge Dewaterability
Increase Cake %TS
Decrease Polymer Required
4. Improve Sludge Dewaterability
VFA Production
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VOLATILE FATTY ACID
PRODUCTION / RELEASE
pH VFA Ammoniappm ppm
Rock River WRRFRock River TWAS 7.0 484 50 Rock River LTWAS (Lab) 6.7 4,159 638 Kenosha WRRFKenosha TWAS 6.7 - 60 Kenosha LTWAS 7.1 5,517 813 Kenosha LTWAS(Lab) 6.9 5,017 640
NEARLY 10 FOLD INCREASE IN VFA
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ASSESSING NEW PROJECTS –
HOW TO KNOW WHAT TO EXPECT
CNP can offer experience-based performance guarantee in many cases
Sometimes testing done upfront
Lab-simulated Pondus
+ Soluble COD and VFA Testing• Provide estimates for SCOD and VFA Production
• 1 month from start to finish
• $100 to $1,000
+ Biological Methane Potential (BMP) Test• Provides estimated additional gas production
• 2-3 months from start to conclusion
• $2000 - $4000
or BMP with daily GC Testing• Can be used to generate kinetic rate constants for biomass degradation
specific to source
• $10,000 - $15,000
• 4-6 months from start to conclusion
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CONCLUSIONS
At 6% DS into process - PONDUS TCHP can provide estimated 65% VSD at 17 Days HRT
Holding digester capacity constant, biogas generation should be expected to increase by >25%
2 to 3% point increase in digested sludge dewaterability
20 to 30% reduction in sludge dewatering polymer requirement
Decreased sludge viscosity makes higher solids digestion more practical
Reduce pumping and mixing energy, wear, and tear
Lab testing can be completed as necessary to evaluate potential benefit
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GIVE CREDIT WHERE CREDIT IS DUE
Dr. Dünnebeil – Pondus GmbH
Kenosha Water Utility
Dr. Zhongtian “John” Li – CNP
Dr. Hiroko “Yoshi” Yoshida – Centrisys/CNP
Dr. Kopp – Kläranlagen Beratung Kopp
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DISCUSSION
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THANK YOU FOR YOUR QUESTIONS
AND INTEREST
Josh Gable
262-705-3064
Glenn Hummel
586 353-2242
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Thank you for your
attention and interest!
CNP - Technology Water and Biosolids
CorporationA division of Centrisys Corporation
9535 58th Place | Kenosha, WI 53144 USA
P +1 (262) 764 3651 | F +1 (262) 764 8705
Discovery more at CNP-
Tec.comA division of Centrisys
Corporation
Melissa Arnot, P.E.
E-mail: [email protected]
Kenosha Water Utility
Director of Operations
262.653.4339 phone
262.653.4340 fax