interim progress report on ground-water research at

Interim Progress Report on Ground-WaterResearch at Robinson Forest

David R. Wunsch, Ph.D.Kentucky Geological Survey

University of Kentucky

January 25, 1995

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INTERIM PROGRESS REPORT ON GROUND-WATERRESEARCH AT ROBINSON FOREST

David R. Wunsch

Kentucky Geological SurveyOpen-File Report

OF-95-01

1995

INTRODUCTIONThe Kentucky Geological Survey (KGS) has been monitoring water resources and the

potential impacts of mining on land in and adjacent to Robinson Forest. Funding has beenprovided by the Vice President for Research and Graduate Studies and KGS. The opportunityto install ground-water-monitoring wells in a relatively undisturbed setting such as RobinsonForest has added significantly to the knowledge of ground-water resources in this area.Projected benefits of this research include enhancing our ability to aid other State agencieswith development and management of the ground-water resources in eastern Kentucky, aswell as providing information critical for the continuing process of upgrading ground-waterprotection strategies. Ultimately, this technical knowledge aids in an overall improvement in thequality of life for all inhabitants of eastern Kentucky.

This interim report outlines the progress made during the past 3 years, including specificmining-related issues.

REPORTS GENERATEDSeveral progress reports have been submitted previously to the UK administration that

covered periodic progress related to monitoring efforts at Robinson Forest. These include:

Ground-water monitoring at Robinson Forest, Progress Report, January 29, 1993, David R.Wunsch, Ph.D.

Surface water and seep water chemistry of the Big Millseat and Maple Hollow watersheds,Robinson Forest, June 21, 1993, Mary A. Arthur, Ph.D., and David R. Wunsch, Ph.D

Ground water research continues in Robinson Forest, David R. Wunsch, Ph.D., UK Research andGraduate Studies Newsletter, 1993.

WORK PERFORMEDA total of 10 wells have been installed by KGS personnel at the two sites within the forest

with funds provided by the University, Addington Resources, Inc., and KGS. Six wells wereinstalled at the Laurel Fork area, and four wells were installed at Clemons Fork. Purchase ofequipment, design of the monitoring network, and oversight of well construction were performedby KGS personnel. Cooperative agreements with the coal companies involved in the miningoperations led to the acquisition of geologic data, which include geologic cores and theirdescriptions. Addington Resources, Inc. performed the drilling for the monitoring wells. The UK

Department of Forestry cooperated in this project by collecting water-level measurements in wellsand stream discharges through the flumes.

Water samples were collected from each well for chemical analyses. Wells located in theLaurel Fork area were installed before active mining took place in order to collect hydrogeologicdata in a pre-mining condition. The wells were located in a remote and rugged area of the forest,which hindered data collection in times of bad weather. Also, the original mining plan dictated thatthis area would not be mined for approximately 5 years. However, a change in the mining plan ledto destruction of the wells in early 1993 after only two sets of water-quality samples were taken.

The wells in Clemons Fork have been sampled four times since their installation. Waterlevels were collected approximately every 2 weeks from July 1993 to the present. Flumes tomeasure surface-water discharge were installed and instrumented with digital data loggers in theClemons Fork water shed to measure stream discharge. Data from these gages used in thisreport were collected by Department of Forestry personnel.

During the spring of 1993 a series of ground-water seeps and unusual mineral precipitateswere discovered in the head of the Rich Hollow drainage basin. The scientific investigation of theseeps and associated mineral deposits required a significant amount of field work andchemical/mineral analyses. Field work included visits to the active mining pit to examine geologicstructures in the rock outcrops for evidence of faulting, fractures, and the possibility of subsidencedue to previous unmapped underground mining in the area. Geologic field data included thecollection of 35 fracture orientations, 8 measurements of cleat in coal, and descriptions offractures, slickensides, and subsidence features. These data were collected by geologists fromthe Coal and Minerals section of the KGS.

Sampling MethodsWater levels in wells were measured using a hand-held electric water tape. Water samples

from wells and springs were collected by personnel from the Water Resources Section andanalyzed by the Laboratory Services Section of the KGS. Parameters collected in the fieldincluded pH, electrical conductance (EC), temperature, and oxidation/reduction potential (Eh).Total and dissolved cations and anions were determined using ion chromatography, autotitrations,and Inductively Coupled Plasma Spectrophotometry (ICAP). Solid mineral samples were analyzedutilizing x-ray diffraction.

Field visits to investigate the seeps were made to the mined area adjacent to thenorthwest forest boundary. Measurements of fracture orientations and descriptions of geologicstructures

This model predicts that wells that obtain water from within a given region as shown on Figure Ihave a high probability of having a specific water type (facies). For example, the model showsthat

were made by geologists from the Coal Section of the KGS using a hand-held Brunton compass.A ground-water tracer study was performed to delineate the flowpath from a possible rechargesite located on the mine-spoil surface using sodium bromide (NaBr) and sodium chloride (NaCI)ground-water tracers. Water samples at suspected discharge points were collected using anISCO auto-sampling device and by manual collection.

Analytical ResultsThe well-construction diagnostics and all subsequent data collected from each well installed

in Robinson Forest have been entered into the Kentucky Aquifer Data Repository at theKentucky Geological Survey. The data for each well include location, depth, constructioncharacteristics, and water quality data collected from the well. The well records including theresults from the analyses of water samples, are contained in Appendix 1.

DISCUSSIONLaurel Fork Wells

Table I lists the depths of the opened (screened) intervals of the six wells installed at LaurelFork. One of the principal goals was to gather water-quality data from the wells in the Laurel Forktract to determine the ambient condition of ground water before mining occurred. This informationwould allow the assessment of the effects of mining on ground water in the forested watershedthat typifies the various Robinson Forest tracts. In addition, these data were used to evaluate aconceptual model of water quality (Figure 1) when topographic location, geology, and proximity tosurface water drainage are taken into account.

water from shallow wells is usually a Ca + Mg, HCO3 + SO4 type. The Laurel Fork wells showgood agreement with this model. The water types for all of the Laurel Fork data are plotted on thetrilinear diagram shown on Figure 2. The identification letter for each well minus the "AD" prefix isshown on the diagram. The two wells drilled to the shallowest depths, AD-N and AD-R (shown asN and R on Fig. 2), are both Ca-Mg-HCO3 water types as would be expected. Two other wellsdrilled to greater depths (wells AD-M and AD-O) are also Ca-Mg-HCO3 wells, and are consistentwith the predicted water types when elevation and well location with respect to the geologicsection are considered. Wells located at the lowest surface elevation (AD-P and AD-Q) and whichobtain water from the lowest elevations of all 6 wells, have Na as the major cation, as predicted. Inaddition, well AD-Q has the greatest proportion of chloride of all the wells, and also containssignificantly higher dissolved fluoride. These findings are consistent with the model presented byWunsch (1992). This information supports the use of predictive models for interpreting theoccurrence of water types in eastern Kentucky or other areas in similar geologic settings.

Clemons Fork WellsThe four wells in the Clemons Fork area of the forest provide an excellent opportunity for

long-term data acquisition related to forest hydrology and ground-water studies, as well asproviding a monitoring network for the adjacent lands that are to be mined by Arch Mineral Corp.and its subsidiaries.

Table 2 shows the well depth, elevation, and elevation of the screened interval forthe Clemons Fork Wells.

Hydrographs for the four wells in the Clemons Fork area are shown on Figures 3, 4, 5, and6. In these figures, the water column stored in the well, measured in feet, is shown on the 'Y' axisover a time interval, from July 1993 to May 1994. Monthly precipitation totals from the ForestryCamp's precipitation gage are shown in Figure 7. Wells UK-B- 1and UK-C- 1 are shallow wells, at

5

Figure 2. Trilinear diagram with water samples from Laurel Fork wells.

6

is blank.

Figure 4. Hydrograph for well UK-B-2.

8

Figure 5. Hydrograph for well UK-C- 1

9

Figure 6. Hydrograph for well UK-C-2,

10

Figure 7. Monthly precipitation for the Robinson Forest area,

11

depths of 48 and 44 feet, respectively. Well UK-C- 1 (Fig. 5) shows a sharp decline in water levelin the period of low precipitation during the fall months. The range of change is over 15 feet,which is typical of shallow wells in eastern Kentucky. Well UK-B- 1 (Fig. 3) shows a very steadyhydrograph because this well is artesian, and the linear portion of the curve from early October toMay 1994 represents the period when water in the well flowed out over the surface casing.

The hydrograph for well UK-B-2 (Fig. 4) indicates a somewhat delayed response tomonths with high precipitation totals, and the total range of variation is generally within 1 foot.This response is typical of a deep well (the depth of this well is 146 ft.) where the rock massbetween the ground surface and the water-producing zone tends to buffer pulses of rechargewater from precipitation events.

The hydrograph for well C-2 (Fig. 6) is not continuous due to false readings caused bycondensation in the well bore, which is a common occurrence. Presently, plans are being madeto install digital data loggers in all four wells in the Clemons Fork area, which should eliminate thisand other data-collection problems.

Water-quality data for samples collected from the Clemons Fork wells are plotted on the tri-linear diagram shown on Figure 8. The shallow wells, UK-B- 1 and UK-C- 1, are Ca-MG-HCO3type waters. The deeper wells, UK-B-2 and UK-C-2, have Na as the major cation, with HCO3 asthe major anion. These well data are consistent with the water types predicted for their locationtopographically and geologically by the conceptual model discussed previously.

Stage hydrographs for the flumes in Maple Hollow and Big Millseat are shown in Figures 9and 10. The hydrographs were created from weekly readings taken at each flume. Bothhydrographs indicate that, although there was significant precipitation in the summer and earlyfall (see Fig. 7), stream flow was minimal. Stream flow then increased significantly in the wintermonths and into 1994. These hydrographs most likely demonstrate the importance ofevapotranspiration and water demand by the heavy vegetative cover in the forest. In addition,spring and summer precipitation events tend to be short and intense (i.e., thunderstorms),whereas fall and winter events are related to cyclonic storms, which usually produce rainfallevents of significantly longer duration. Hydrographs for stream stages elevated by short, intenseprecipitation events tend to drop off quickly after the event has ceased. Hydrographs for streamselevated by longer precipitation events are more likely to sustain stream levels so that highstream stages will still be evident when measured weekly. Continuous data loggers are installedon each flume, and presently efforts are being made to manipulate the data stored on thesedevices to produce more continuous data strings.

Although the two drainage basins monitored by the flumes are similar in size and shape, theaverage base flow for Big Millseat (0.238 cfs) is nearly twice that for Maple Hollow (0.124 cfs).The

Figure 8. Trilinear diagram with water samples from Clemons Fork wells.

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W = UK-B- 1X = UK-B-2Y = UK-C-1Z = UK-C-2

Figure 9. Stream hydrograph for Maple Hollow

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Figure 10. Stream hydrograph for Big Millseat.

15

ground-water seeps discovered in Rich Hollow contribute water to the basin drainage measuredat Big Millseat; therefore, the higher discharge may be related to water coming from the seeps.

Origin of Ground-Water Seeps in Rich HollowFigure 11 shows a schematic map of the portion of Robinson Forest to be mined by Arch

Minerals Corp. In 1993, several diffuse ground-water seeps were identified in the Rich Hollow andadjacent drainage basins. All of the seeps appear at approximately the same elevation. Theapproximate locations of these seeps are shown on Figure 11. Seeps and springs are common inareas underlain by coal-bearing rocks (Kipp and Dinger, 1991). Local residents report thatground-water discharge near the location of the present seep in the Rich Hollow area hasoccurred for at least 40 years. However, no quantitative assessments were made or records keptto determine if the present flow is greater or less than in the past. Additionally, the degree ofmineralization associated with the water flowing from the seeps appears to be an unnaturalsituation. For example, ground-water samples from the seeps contains a much higher amount ofdissolved constituents than would normally be expected from ground water emanating from seepsor springs in an undisturbed setting such as Robinson Forest. The high concentrations of calcium,magnesium, and sulfate (see RICH HOLLOW SEEP samples, Appendix 1) suggest that the seepwater has been influenced by a near-surface disturbance, such as mining. A field reconnaissanceof Rich Hollow and the adjacent surface mining operations lends evidence that water stored in themine spoil is leaking through a coal seam into the unmined forest land within Rich Hollow. TheRich Hollow seep produces the highest flow, with a localized discharge of up to 5.0 gallons perminute. Excavation of the Rich Hollow seep outlet showed that the seep was flowing from a coalseam which is probably the Skyline sub-5 coal.

Figure 12 is a schematic cross section of line A-A’ shown on Figure 11. The cross-sectionpasses through the ridge that separates the mined area operated by Arch and the hillside in RichHollow where the seep appeared. The probable scenario for the occurrence of the seep in RichHollow is shown diagramatically on this figure. Water enters the mine spoil through variousavenues, which may include the feature labeled "Sediment Pond" (Figure 12). This feature mayfunction in a similar manner to an experimentally designed infiltration basin for this purpose at theStar Fire site, which is adjacent to the forest (Wunsch and others, 1992). This feature is a largedepression where surface-water drainage was directed from the mine spoil surface for sedimentcontrol. Large volumes of water flowed into this depression during precipitation events, but thepool of water that accumulated in the pond did not increase to any significant degree, indicatingthat water is infiltrating through this depression into the spoil below. Additional water may alsoenter the spoil along the contact between the spoil and the unmined bedrock highwall (Wunsch

16i n

Figure 11. Schematic location map for seeps and other features near theArch mining site. Cross section A-A: is shown on Figure12. Note: not to scale.

17

Figure 12. Schematic cross section along line A-K shown on Figure 11.Note: not to scale.

18

and others, 1992), but this for-in of infiltration. was not directly measured at this site.A saturated zone, or water table, has been established at the base of the spoil (Atkinson,

1993). If water accumulates in this area, sufficient hydraulic head may be present to force thewater to move through the lowest coal seam being mined (B), which may act like a drain. This"drain" effect is common in coal, for coal seams are commonly the most hydraulicallyconductive lithologies in the Appalachian Coal Field (Wunsch, 1992; Harlow and LeCain, 1991). Most coal beds have characteristic fractures called cleat, which transmit water moreeffectively than the other rocks occurring with the coal.

The seep is formed where the water escapes onto the hillside where the coal seam cropsout (D). Ground water stored in the unmined part of the ridge may migrate downward throughthe shallow fracture zone (C) and mix with the mineralized water moving through the coal seamfrom the spoil. This mixture of water with different chemical constituents probably produces anet water composition that is saturated with respect to several minerals, which results in themineral precipitation that is observed below the seep. These minerals form a coating on theforest floor, and in some areas a thick, hard crust has been produced.

Results of Field InvestigationsSeveral experiments were performed to ascertain if the scenario described above was an

accurate description of the geologic situation responsible for the occurrence of seeps in thenorthwest boundary of the forest. A ground- water trace was performed to determine if waterentering the mine spoil on Arch property was flowing through the ridge and discharging onto UKproperty at the Rich Hollow seep. The two tracer chemicals used, sodium chloride and sodiumbromide, are very conservative in the natural environment and act as excellent tracers(Whittemore, 1988). Both of the halide ions comprising these salts are usually found only in smallquantities in ground water at the elevations where the seeps occur in eastern Kentucky (Wunsch,1992), thus relatively small quantities were needed to perform the traces.

Bromide was introduced in late July 1993, followed by chloride in early August. Sampleswere collected until late October and early November, respectively. Data from the ground-watertraces are shown on Figure 13. For bromide, a significant spike indicating a positive trace couldbe demonstrated by a measured concentration of 1.0 mg/L or higher. For chloride, greater than10 mg/L would indicate a positive trace. It can be seen that no conclusive positive spikes wereobserved, suggesting that water entering the spoil in the pond on the Arch property probablydoes not discharge through the Rich Hollow seep, or at least not in the time interval of the tracedata collection.

However, after initiation of the trace, additional information obtained from the miningcompany shed new light on the hydrologic regime for the area bordering UK's property. During

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Figure 13. Ground-water trace data.

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the course of re-mining by Arch along the UK property line, deeper excavation took place in orderto extract coal from the Skyline sub-5 coal seam. The dashed line on Figure 11, which representsthe extent of the sub-5 coal, parallels the northern property line over most of the boundary, andalso reveals that the sub-5 is missing along a thin belt that parallels the UK property line. Theexcavation of the coal in this area essentially created a "trench" along the highwall that bordersthe Robinson Forest (Figure 12). This trench might influence ground-water flow to the extent thatwater entering the recharge pond may be captured by the trench. Depending on the geologicstructure of the base of the sub-5 coal, the water may discharge at a considerable distance fromwhere it would be anticipated to exit, and in a direction not easily determined from an inspectionof the ground surface. Therefore, the ground-water trace may not be reliable in determiningground-water flow directions in this case.

Subsequent to the ground-water trace experiments, the sediment pond was filled in with spoilin October 1993. In the spring of 1994, flow from the Rich Hollow seep was observed to be asmall fraction of what it had been during the previous year. This gradual decrease in flow, asopposed to an immediate reduction, suggests that an indirect hydrologic connection existedbetween water entering the spoil through the sediment pond and the Rich Hollow seep. Thecontinuation of flow in Rich Hollow after the pond was filled suggests that a large quantity of waterwas stored in the spoil, which provided flow to the seeps for several months. This large volume ofwater, in conjunction with the complicated spoil hydrology resulting from the buried trench alongthe UK property line, probably rendered the tracing tests ineffective in confirming a direct flowpathfrom the sediment pond to the seeps.

Chemical data collected from both the Arch mining area and the seeps suggest that thesource of the water that discharges from the seeps is in the mine spoil. A water sample collectedby KGS in 1993 from a monitoring well located in the spoil (identified in this report as Arch well D)shows that the water is highly mineralized. Chemical data from this sample are listed in Table 2,along with data from the same well sampled in 1990. The 1990 data are reported in a consultant'sreport prepared for Arch (Atkinson, 1990). Parameters common to both data sets show a highdegree of similarity, indicating that the water quality-data collected by KGS is probablyrepresentative of water derived from the minespoil at the Arch site.

In addition, these data are also comparable to water stored in spoil in nearby mined areas thathave been studied extensively (Wunsch and others, 1992).

Figure 14 is a trilinear diagram showing the chemical data for water samples from threeseeps and Arch well D, and data from three monitoring wells that obtain water from undisturbedcoal seams in the Laurel Fork tract. The diameter of the circle around the letter which representsthe location of the plotted chemical data is directly proportional to the total dissolved solids (TDS)calculated for the water sample. The water samples from the seeps and the sample from Archwell D plot very close together, whereas the undisturbed coal seam waters cluster into a separategroup. The samples drawn from wells in the undisturbed area have a lower proportion of sulfate,which is common to water derived from disturbed lands. In addition, the similarity of circle sizearound the seep samples and Arch well D suggest they each contain relatively high TDScompared to the samples from the undisturbed coal seams.

Additional evidence that the spoil is the source for the water discharging from the seeps canbe demonstrated by comparing the mineral saturation indices (IAP/K) to the mineralogicalmakeup of the mineral precipitates found at the seeps. Figure 15 shows the spectrograph for thex-ray analysis of a sample of mineral precipitate collected at the Rich Hollow seep. The precipitateconsists of a mixture of calcite (CaCO3), Alunite (KAl3(SO4)2(OH)6), and sodium calcium sulfatehydrate (Na2Ca5(SO4)6*3H2O), which is essentially an impure form of gypsum. Figure 16 showsthe saturation indices for these minerals calculated from chemical data from the samples shownon Figure 14. The data were modeled using the geochemical model PHREEQE (Parkhurst andPlummer, 1980). Negative saturation indices indicate that the sample is undersaturated withrespect to a given mineral. Positive indices indicate saturation, meaning that the mineral inquestion should precipitate. Indices at or near zero indicate equilibrium exists between themineral and the solution (water sample). The water samples from the seeps and Arch well D arevery similar. Each of these samples are saturated with respect to alunite, indicating that thismineral should precipitate from these solutions. The state of saturation with respect to calcite andgypsum is also similar among these samples, with the samples taken from Arch well D and RichHollow showing saturation with respect to calcite. The two samples derived from the undisturbedcoal seams are undersaturated with respect to all three minerals. These data show that the waterfrom the mine Is saturated or nearly saturated with respect to the minerals that comprise theprecipitates found at the seeps. Therefore, the mine spoil is the most likely source for themineral-laden water that produces the mineralization found at the seeps.

One explanation for the occurrence of the seeps along the sub-5 coal seam is that theyare related to previous underground mining. In this case, the mines could have weakened thesurrounding bedrock, or perhaps breached the hillside, creating an outlet for the water stored

22

Figure 14. Trilinear diagram showing water samples from three seeps,(C,H,and L) Arch well-D (D), and undisturbed coal seams (M,N. and R).

23

25

Figure 16. Saturation Indices (Log IAP/IQ for the seep minerals determined by the geochemical. model PHREEQE. -Indices greater than zero indicate supersaturation with respect

to the particular mineral. Indices less than zero indicate undersaturation. Indicesat zero are In equilibrium with the mineral. ASH, ARC, and RICH representsamples taken from the seeps. ARCHD is from Arch well D. AD-M and AD-R aresamples derived from undisturbed coal seams. -

within the spoil. Evidence of abandoned deep mines, such as mine entries in the northwest areaof the forest and "voids" encountered in the geologic core drilled for exploration purposes byArch (see Fig. 11) demonstrate that underground mining occurred in this area.

Geologists from the Coal Section of the KGS examined the active mining area to look forevidence of previous, unmapped deep mines. Geologic data such as frequency and distribution offractures, and geologic structures on the mine floor after the coal was removed were examined ina search for evidence of subsurface disturbance. However, these data were inconclusive as towhether or not the cracks observed along the mine were related to subsidence caused byabandoned deep mines.

The orientation of large surface cracks observed in the highwalls near the mine is inagreement with the direction of major, regional fractures measured In the active mine floor. All ofthese fractures trend approximately N100E to N300E. The orientation of a line roughly passingthrough the location of each seep generally coincides with the orientation of the fractures. Thissuggests that regional fractures may play a part in the occurrence and location of the seeps.Most likely, the intersection of regional fractures with the outcrop of the sub-5 coal creates ahighly fractured zone where measurable ground water can escape from the fractured coal seam.Further detailed study would be necessary to determine if these structural features do indeedcontrol the occurrence of seeps in this area. The occurrence of the ground-water seeps and theirgeochemical implications create an interesting and unique hydrogeologic feature which warrantsfurther study for scientific reasons.

SUMMARY AND FUTURE WORKGround -water-monitoring sites in Robinson Forest provide an excellent, and in some ways

unique, opportunity to collect hydrologic and geochemical data in eastern Kentucky. These datasupplement information from other ongoing KGS research projects and data bases. Plans forfuture work in the forested basins where monitoring wells and flumes are installed includecollecting more detailed information at shorter time intervals using advanced digital datacollection in the wells. In addition, water-quality data collected from the shallow soil zone wouldbe a welcome addition to our data needs, as well as providing input for modifying andcalibrating our present conceptual models. The accumulation of ground-water Informationcollected in Robinson Forest will provide important water-quality data that will benefit theresidents and industries operating in eastern Kentucky.

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REFERENCESAtkinson, L.C., 1990, Hydrological analysis of L.U.P. 90-1: Hydrologic Consultants, Inc.

Lakewood, Colorado. 19 p.,

Harlow, G.E., and LeCain, G.D., 1991, Hydraulic characteristics of, and ground-water flow in,coal-bearing rocks of southwestern Virginia: U.S. Geological Survey Open File Report91-250.

Kipp, J.A., and Dinger, J.S. 1991, Stress relief fracture control of ground-water movement inthe Appalachian Plateaus: Kentucky Geological Survey, ser. 11, Reprint 30, 11 p.

Parkhurst, D.L., Thorstenson, D.C., and Plummer, N.L., 1980, PHREEQE, a computer programfor geochemical calculations: U.S. Geological Survey Water-Resources Investigations report80-96, 210 p.

Whittemore, D.O., 1988, Bromide as a tracer in ground water studies: geochemistry andanalytical determination: Proceedings of the Ground Water Geochemistry Conference,National Water Well Association, Denver, Colorado, February 16-18, 1988.

Wunsch. D.R., Dinger, J. S., and Taylor, P. B., 1992, Design, construction, and monitoring ofthe ground-water resources of a large mine spoil area: Star Fire tract, eastern Kentucky.Kentucky Geological Survey, ser. 11, Report of Investigations, 16 p.

Wunsch, D. R., 1992, Ground-water geochemistry and its relationship to the flow system atan unmined site in the Eastern Kentucky Coal Field. Lexington, Kentucky, University ofKentucky, Ph.D. Dissertation, 268 p.

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SUBJECT TO CORRECTION OR REVISION WITHOUT NOTICENO WARRANTY IS EXPRESSED OR IMPLIED BY KGSNOT FOR PUBLICATION OR PROMOTION OF SERVICES

SELECTED HYDROGEOLOGIC SITES FROM KENTUCKY

KENTUCKY GEOLOGICAL SURVEY

UNIVERSITY OF KENTUCKY

228 MINING AND MINERAL RESOURCES BUILDING

LEXINGTON, KENTUCKY 40506-0107

DIRECTOR AND STATE GEOLOGISTDONALD C. HANEY

ASST. STATE GEOLOGIST FOR ADMINISTRATIONJOHN D. KIEFER

ASST. STATE GEOLOGIST FOR RESEARCHJAMES C. COBB

FOR FURTHER INFORMATION CONTACT BART DAVIDSON

WATER RESOURCES SECTION

PHONE 606-257-5500 OR 606-257-5863

29

KENTUCKY GEOLOGICAL SURVEY, WATER RESOURCES SECTION

SITE IDENTIFICATION AND LOCATIONRecord No: 00013990 Field Well No: UK-B-1 AKGWA Well No: 80001076.00Reporting Agency: KGS Site Reporter: DW Date: Aug/07/1992Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 373047.00 DEG.; West Longitude: 830840.00 DEG.Elevation In Feet: 1120.0 Observed At: GROUND LEVELTotal Depth: 48.0 FT Diameter: 2 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: Producing zone is in Breathitt Fm., shallow

fracture zone

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ARCHDate Started: Feb/20/1992 Date Completed: Feb/20/1992Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: 1.0 FT Completion Zone: BREATHITT FM

ANNULUS FILLING MATERIALSGravel Pack: SAND FILTER, Backfill: BENTONITE GROUTTop Seal: CONCRETE, Bottom Seal: BENTONITE

PUMP AND WELL HEAD FEATURESType: NO DATA, Power Supply: UNK VOLTSDischarge Rating: Intake Depth:Well Head Cap: LOCKING COVER Pitless Adapter: NOWater Treatment: NO Bypass Available: NA

CASING RECORDString Top String Bottom Inside Diameter Casing Material

0.00 FT 28.00 FT 2 IN PVC28.00 FT 38.00 FT 2 IN PVC SCREEN

*** SUBJECT TO CORRECTION OR REVISION WITHOUT NOTICE ****** NO WARRANTY IS EXPRESSED OR IMPLIED BY KGS ***

*** NOT FOR PUBLICATION OR PROMOTION OF SERVICES ***


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013990 Laboratory No: AKGWA Well No: 80001076.00Collector: Date Collected: Aug/18/1992 Military Time:Date Received: Aug/19/1992 Military Time:Laboratory: Analyst: Date: 28-Sep-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum < 15.00 µg/LDissolved Antimony < 37.00 µg/LDissolved Arsenic < 59.00 µg/LDissolved Beryllium < 1.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 4.00 µg/LDissolved Cobalt < -6.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 40.00 µg/LDissolved Lithium 8.00 µg/LDissolved MercuryDissolved Nickel < 18.00 µg/LDissolved Selenium < 67.00 µg/LDissolved Silver < 4.00 µg/LDissolved Tin < 73.00 µg/LDissolved Zinc < 3.00 µg/L

Total and Dissolved concentration data not listed on this report may beavailable for the following species. CR, GA, GE, MO, RB, TI, ZR, VA Total,Total Recoverable and Dissolved concentrations may also be available forany four additional determinations.

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WATER QUALITY ANALYSISRecord No: 00013990 Other ID NO: UK-B-1AKGWA Number: 80001076Collector: Date Collected: Mar/29/1993 Military Time: 18:06Date Received: Apr/02/1993 Military Time:Laboratory: Analyst: Date:May/07/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 90.00 mg/LTotal CarbonateTotal Sulfate 32.40 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.07 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 25.60 mg/LDissolved Magnesium 5.44 mg/LDissolved Sodium 5.68 mg/LDissolved Potassium < 0.08 mg/LDissolved Chloride < 1.00 mg/LDissolved SulfateDissolved Iron 5.210 m4/LDissolved Manganese 0.165 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.214 mg/LDissolved Strontium 0.270 mg/LDissolved Silica 19.68 mg/LDissolved FluorideDissolved Nitrate as Nitrogen < 0.023 mg/LDissolved Phosphorus < 0.08 mg/L

*** SUBJECT TO CORRECTION OR REVISION WITHOUT NOTICE ****** NO WARRANTY IS EXPRESSED OR IMPLIED BY KGS ****** NOT FOR PUBLICATION OR PROMOTION OF SERVICES ***

31


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013990 Laboratory No: AKGWA Well No: 80001076.00Collector: Date Collected: Mar/29/1993 Military Time: 18:06Date Received: Apr/02/1993 Military Time:Laboratory: Analyst: Date:7-May-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved AluminumDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper 6.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 7.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver 14.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc < 6.00 µg/L


32


WATER QUALITY ANALYSISRecord No: 00013990 Other ID NO: UK-B-1AKGWA Number: 80001076Collector: DRW Date Collected: Jul/22/1993 Military Time: 14:00Date Received: Jul/23/1993 Military Time:Laboratory: KGS Analyst: HF Date:Sep/28/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium 26.20 mg/LTotal Magnesium 5.63 mg/LTotal Sodium 5.31 mg/LTotal Potassium 1.43 mg/LTotal Bicarbonate 104.00 mg/LTotal CarbonateTotal Sulfate 32.80 mg/LTotal Iron 5.670 mg/LTotal Manganese 0.168 mg/LTotal Boron < 0.023 mg/LTotal Barium 0.192 mg/LTotal Strontium 0.258 mg/LTotal Silica 20.64 mg/LTotal FluorideTotal Nitrate as Nitrogen 0.100 mg/LTotal Phosphorus 0.12 mg/LDissolved Calcium 25.40 mg/LDissolved Magnesium 5.46 mg/LDissolved Sodium 5.49 mg/LDissolved Potassium < 0.12 mg/LDissolved Chloride 1.64 mg/LDissolved SulfateDissolved Iron 5.310 mg/LDissolved Manganese 0.161 mg/LDissolved Boron < 0.02 mg/LDissolved Barium 0.190 mg/LDissolved Strontium 0.256 mg/LDissolved Silica 20.30 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.12 mg/L


33


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013990 Laboratory No: RFGW-01 AKGWA Well No: 80001076.00Collector: DRW Date Collected: Jul/22/1993 Military Time: 14:00Date Received: Jul/23/1993 Military Time:Laboratory: KGS Analyst: HF Date: 28-Sep-1993

Total Aluminum < 19.00 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal BromideTotal Cadmium < 6.00 µg/LTotal Cobalt < 12.00 µg/LTotal Copper < 7.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 7.00 µg/LTotal MercuryTotal Nickel < 49.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver 19.00 µg/LTotal Tin < 426.00 µg/LTotal Zinc 6.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium < 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium 5.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver 70.00 µg/LDissolved Tin < 426.00 µg/LDissolved Zinc < 5.00 µg/L


34


WATER QUALITY ANALYSISRecord No: 00013990 Other ID NO: UK-B-1AKGWA Number: 80001076Collector: Date Collected: Apr/05/1994 Military Time: 15:00Date Received: Apr/08/1994 Military Time:Laboratory: Analyst: Date:May/04/1994

Specific Conductance, Microsiemens/Cm pH,Standard Units Total Dissolved Solids TotalAcidity, Mg/L as CaC03 Total Alkalinity TotalHardness Noncarbonate HardnessTotal Calcium 21.40 mg/LTotal Magnesium 5.34 mg/LTotal Sodium 5.26 mg/LTotal Potassium < 1.21 mg/LTotal Bicarbonate 88.00 mg/LTotal CarbonateTotal Sulfate 31.90 mg/LTotal Iron 4.430 mg/LTotal Manganese 0.133 mg/LTotal Boron < 0.023 mg/LTotal Barium 0.175 mg/LTotal Strontium 0.245 mg/LTotal Silica 18.44 mg/LTotal Fluoride 0.06 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal Phosphorus < 0.12 mg/LDissolved Calcium 17.20 mg/LDissolved Magnesium 4.42 mg/LDissolved Sodium 4.51 mg/LDissolved Potassium < 0.12 mg/LDissolved ChlorideDissolved SulfateDissolved Iron 3.480 mg/LDissolved Manganese 0.112 mg/LDissolved Boron < 0.02 mg/LDissolved Barium 0.149 mg/LDissolved Strontium 0.205 mg/LDissolved Silica 15.14 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.12 mg/L


35


SITE IDENTIFICATION AND LOCATIONRecord No: 00013991 Field Well No: UK-B-2 AKGWA Well No: 80001077.00Reporting Agency: KGS Site Reporter: DWDate: Aug/07/1992Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 373047.50 DEG.; West Longitude: 830839.50 DEG.Elevation In Feet: 1120.0 Observed At: GROUND LEVELTotal Depth: 146.0 FT Diameter: 2 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: Producing zone is in Breathitt Fm., shallow

fracture zone

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ARCHDate Started: Feb/20/1992 Date Completed: Mar/17/1992Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: 20.0 FT Completion Zone: BREATHITT FM

ANNULUS FILLING MATERIALSGravel Pack: SAND FILTER, Backfill: BENTONITE GROUTTop Seal: CEMENT, Bottom Seal: BENTONITE

PUMP AND WELL HEAD FEATURESType: NO DATA, Power Supply: UNK VOLTSDischarge Rating: Intake Depth:Well Head Cap: LOCKING CAP Pitless Adapter: NOWater Treatment: NO Bypass Available: NA




36


WATER QUALITY ANALYSISRecord No: 00013991 Other ID NO: UK-B-2AKGWA Number: 80001077Collector: DRW Date Collected: Aug/18/1992 Military Time:Date Received: Aug/19/1992 Military Time:Laboratory: KGS Analyst: HF Date:Sep/28/1992

Specific Conductance, Microsiemens/Cm,pH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 368.00 mg/LTotal Carbonate < 1.00 mg/LTotal Sulfate 35.00 mg/LTotal IronTotal ManganeseTotal Boron <Total BariumTotal StrontiumTotal SilicaTotal Fluoride 0.75 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 21.10 mg/LDissolved Magnesium 3.65 mg/LDissolved Sodium 76.90 mg/LDissolved Potassium < 0.05 mg/LDissolved Chloride 2.94 mg/LDissolved SulfateDissolved Iron 0.076 mg/LDissolved Manganese 0.068 mg/LDissolved Boron 0.11 mg/LDissolved Barium 0.088 mg/LDissolved Strontium 35.000 mg/LDissolved Silica 0.11 mg/LDissolved Fluoride 0.75 mg/LDissolved Nitrate as Nitrogen <Dissolved Phosphorus < 0.05 mg/L


37


WATER QUALITY ANALYSISRecord No: 00013991 Other ID NO: UK-B-2AKGWA Number: 80001077Collector: DRW Date Collected: Mar/29/1993 Military Time:Date Received: Apr/02/1993 Military Time:Laboratory: KGS Analyst: HF Date:May/07/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal Potassium <Total Bicarbonate 490.00 mg/LTotal CarbonateTotal Sulfate 9.68 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal Strontium <Total SilicaTotal Fluoride 2.95 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal Phosphorus <Dissolved Calcium 1.65 mg/LDissolved Magnesium 0.34 mg/LDissolved Sodium 159.00 mg/LDissolved Potassium 0.12 mg/LDissolved Chloride 2.49 mg/LDissolved SulfateDissolved Iron 0.093 mg/LDissolved Manganese 0.011 mg/LDissolved Boron 0.16 mg/LDissolved Barium 0.031 mg/LDissolved Strontium 0.060 mg/LDissolved Silica 6.05 mg/LDissolved Fluoride 2.95 mg/LDissolved Nitrate as NitrogenDissolved Phosphorus 0.12 mg/L


38


WATER QUALITY ANALYSISRecord No: 00013991 1 Other ID NO: UK-B-2AKGWA Number: 80001077Collector: DRW Date Collected: Jul/22/1993 Military Time: 11:15Date Received: Jul/23/1993 Military Time:Laboratory: KGS Analyst: HF Date:Sep/28/1993

Specific Conductance, Microsiemens/Cm,pH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium 6.57 mg/LTotal Magnesium 8.16 mg/LTotal Sodium 205.00 mg/LTotal Potassium 8.72 mg/LTotal Bicarbonate 552.00 mg/LTotal CarbonateTotal Sulfate 27.00 mg/LTotal Iron 35.300 mg/LTotal Manganese 0.511 mg/LTotal Boron 0.209 mg/LTotal Barium 0.308 mg/LTotal Strontium 0.213 mg/LTotal Silica mg/LTotal FluorideTotal Nitrate as NitrogenTotal Phosphorus 0.49 mg/LDissolved Calcium 2.19 mg/LDissolved Magnesium 0.47 mg/LDissolved Sodium 190.00 mg/LDissolved Potassium < 0.12 mg/LDissolved ChlorideDissolved SulfateDissolved Iron 0.069 mg/LDissolved Manganese 0.007 mg/LDissolved Boron 0.21 mg/LDissolved Barium 0.035 mg/LDissolved Strontium 0.076 mg/LDissolved Silica 8.04 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.12 mg/L


39


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013991 Laboratory No: RFGW-01 AKGWA Well No: 80001077.00Collector: DRW Date Collected: Jul/22/1993 Military Time: 13:10Date Received: Jul/23/1993 Military Time:

Laboratory: KGS Analyst: HF Date: 28-Sep-1993

Total Aluminum 26.30 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal Bromide < 1000.00 µg/LTotal Cadmium 8.00 µg/LTotal Cobalt 27.00 µg/LTotal Copper 35.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 62.00 µg/LTotal MercuryTotal Nickel 66.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver 7.00 µg/LTotal Tin < 426.00 µg/LTotal Zinc 96.00 µg/LDissolved Aluminum < 1030.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium 22.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver < 6.00 µg/LDissolved Tin 426.00 µg/LDissolved Zinc < 4.00 µg/L


40


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013991 Laboratory No: 24400-01 AKGWA Well No: 80001077.00Collector: DRW Date Collected: Aug/18/1993 Military Time: 15:40Date Received: Aug/19/1993 Military Time:Laboratory: KGS Analyst: HF Date: 28-Sep-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 86.00 µg/LDissolved Antimony < 37.00 µg/LDissolved Arsenic < 59.00 µg/LDissolved Beryllium < 1.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 4.00 µg/LDissolved Cobalt < 6.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 40.00 µg/LDissolved Lithium 15.00. µg/LDissolved MercuryDissolved Nickel < 18.00 µg/LDissolved Selenium < 67.00 µg/LDissolved Silver < 4.00 µg/LDissolved Tin < 73.00 µg/LDissolved zinc < 3.00 µg/L

Total and Dissolved concentration data not listed on this report may beavailable for the following species. CR, GA, GE, MO, RB, TI, ZR, VA Total,Total Recoverable and Dissolved concentrations may also be availble for anyfour additional determinations.

41


WATER QUALITY ANALYSISRecord No: 00013991 Other ID NO: UK-B-2AKGWA Number: 80001077Collector: DRW Date Collected: Apr/05/1994 Military Time: 15:40Date Received: Apr/08/1994 Military Time:Laboratory: KGS Analyst: HF Date:May/04/1994

Specific Conductance, Microsiemens/Cm 797 µSIEMpH, Standard Units 8.73 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium 1.42 mg/LTotal Magnesium 0.48 mg/LTotal Sodium 201.00 mg/LTotal Potassium 1.21 mg/LTotal Bicarbonate 542.00 mg/LTotal CarbonateTotal Sulfate 6.90 mg/LTotal Iron 0.330 Mg/LTotal Manganese 0.009 mg/LTotal Boron 0.023 mg/LTotal Barium 0.048 mg/LTotal Strontium 0.085 mg/LTotal Silica 10.46 mg/LTotal Fluoride 4.10 mg/LTotal Nitrate as Nitrogen 0.023 mg/LTotal Phosphorus 0.12 mg/LDissolved Calcium 3.97 mg/LDissolved Magnesium 0.96 mg/LDissolved Sodium 169.00 mg/LDissolved Potassium 0.12 mg/LDissolved Chloride 4.10 mg/LDissolved Sulfate 6.90 mg/LDissolved Iron 0.033 mg/LDissolved Manganese 0.019 mg/LDissolved Boron 0.11 mg/LDissolved Barium 0.050 mg/LDissolved Strontium 0.112 mg/LDissolved SilicaDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.12 mg/L


42


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013991 Laboratory No: RFGW-01 AKGWA Well No: 80001077.OCCollector: DRW Date Collected: Apr/05/1994 Military Time: 15:40Date Received: Apr/08/1994 Military Time:Laboratory: KGS Analyst: HF Date: 4-May-1994Total Aluminum 940.00 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal BromideTotal Cadmium < 6.00 µg/LTotal Cobalt < 12.00 µg/LTotal Copper < 7.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 22.00 µg/LTotal MercuryTotal Nickel < 49.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver 30.00 µg/LTotal Tin 426.00 µg/LTotal Zinc < 4.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium < 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium < 18.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver < 20.00 µg/LDissolved Tin < 426.00 µg/LDissolved Zinc < 4.00 µg/L

Total and Dissolved concentration data not listed on this report maybe available for the following species. CR, GA, GE, MO, RB, TI, ZR, VATotal, Total Recoverable and Dissolved concentrations may also beavailable for any four additional determinations.

43


SITE IDENTIFICATION AND LOCATIONRecord No: 00013989 Field Well No: UK-C-1 AKGWA Well No: 80001078.00Reporting Agency: KGS Site Reporter: DW Date: Aug/07/1992Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 373053.00 DEG.; West Longitude: 830804.00 DEG.Elevation In Feet: 1120.0 Observed At: GROUND LEVELTotal Depth: 44.0 FT Diameter: 2 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: Producing zone is in Breathitt Fm., Shallow

Fracture Zone

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ARCHDate Started: Mar/04/1992 Date Completed: Mar/04/1992Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: 13.0 FT Completion Zone: BREATHITT FM






44


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013989 Laboratory No: 24400-01 AKGWA Well No: 80001078.00Collector: DRW Date Collected: Aug/18/1992 Military Time:Date Received: Aug/19/1992 Military Time:Laboratory: KGS Analyst: HF Date: 28-Sep-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum < 15.00 µg/LDissolved Antimony < 37.00 µg/LDissolved Arsenic < 59.00 µg/LDissolved Beryllium < 1.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 4.00 µg/LDissolved Cobalt < 6.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 40.00 µg/LDissolved Lithium < 2.00 µg/LDissolved MercuryDissolved Nickel < 18.00 µg/LDissolved Selenium < 67.00 µg/LDissolved Silver < 4.00 µg/LDissolved Tin < 73.00 µg/LDissolved Zinc 7.00 µg/L


45


WATER QUALITY ANALYSISRecord No: 00013989 Other ID NO: UK-C-1AKGWA Number: 80001078Collector: DRW Date Collected: Mar/29/1993 Military Time:Date Received: Apr/02/1993 Military Time:Laboratory: KGS Analyst: HF Date:May/07/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 80.00 mg/LTotal CarbonateTotal Sulfate 35.90 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.07 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal PhosphorusDissolved Calcium 27.67 mg/LDissolved Magnesium 5.13 mg/LDissolved Sodium 5.14 mg/LDissolved Potassium < 1.28 mg/LDissolved Chloride < 1.00 mg/LDissolved SulfateDissolved Iron 8.000 mg/LDissolved Manganese 0.266 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.197 mg/LDissolved Strontium 0.184 mg/LDissolved Silica 21.60 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 1.28 mg/L


46


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013989 Laboratory No: RFGW-01 AKGWA Well No: 80001078.00Collector: DRW Date Collected: Mar/29/1993 Military Time:Date Received: Apr/02/1993 Military Time:Laboratory: KGS Analyst: HF Date: 7-May-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum < 32.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 4.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver 11.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc 7.00 µg/L

Total and Dissolved concentration data not listed on this report may beavailable for the following species. CR, GA, GE, MO, RB, TI, ZR, VA Total,Total Recoverable and Dissolved concentrations may also be availble for anyfour additional determinations.

47


WATER QUALITY ANALYSISRecord No: 00013989 Other ID NO: UK-C-1AKGWA Number: 80001078Collector: DRW Date Collected: Jul/22/1993 Military Time:Date Received: Jul/23/1993 Military Time:Laboratory: KGS Analyst: HF Date:Sep/28/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium 27.90 mg/LTotal Magnesium 5.11 mg/LTotal Sodium 5.11 mg/LTotal Potassium 1.64 mg/LTotal Bicarbonate 100.00 mg/LTotal CarbonateTotal Sulfate 35.20 mg/LTotal Iron 8.930 mg/LTotal Manganese 0.253 mg/LTotal Boron < 0.023 mg/LTotal Barium 0.201 mg/LTotal Strontium 0.173 mg/LTotal Silica 25.88 mg/LTotal FluorideTotal Nitrate as Nitrogen < 0.100 mg/LTotal Phosphorus < 0.12 mg/LDissolved Calcium 27.60 mg/LDissolved Magnesium 4.93 mg/LDissolved Sodium 5.09 mg/LDissolved Potassium < 1.21 mg/LDissolved Chloride 1.61 mg/LDissolved Sulfate 35.20 mg/LDissolved Iron 7.300 mg/LDissolved Manganese 0.240 mg/LDissolved Boron < 0.02 mg/LDissolved Barium 0.187 mg/LDissolved Strontium 0.173 mg/LDissolved Silica 22.25 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 1.21 mg/L


48


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013989 Laboratory No: RFGW-01 AKGWA Well No: 80001078.00Collector: DRW Date Collected: Jul/22/1993 Military Time:Date Received: Jul/23/1993 Military Time:

Laboratory: KGS Analyst: HF Date: 28-Sep-1993

Total Aluminum 1030.00 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal BromideTotal Cadmium < 6.00 µg/LTotal Cobalt < 12.00 µg/LTotal Copper < 7.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 4.00 µg/LTotal MercuryTotal Nickel < 49.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver < 6.00 µg/LTotal Tin < 426.00 µg/LTotal zinc 9.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium < 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium < 3.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver < 6.00 µg/LDissolved Tin < 426.00 µg/LDissolved Zinc 5.00 µg/L


49


WATER QUALITY ANALYSISRecord No: 00013989 Other ID NO: UK-C-1AKGWA Number: 80001078Collector: DRW Date Collected: Apr/05/1994 Military Time:Date Received: Apr/08/1994 Military Time:Laboratory: KGS Analyst: HF Date:May/04/1994

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium 17.80 mg/LTotal Magnesium 4.00 mg/LTotal Sodium 4.24 mg/LTotal Potassium < 1.21 mg/LTotal Bicarbonate 73.00 mg/LTotal CarbonateTotal Sulfate 33.20 mg/LTotal Iron 6.300 mg/LTotal Manganese 0.211 mg/LTotal Boron < 0.023 mg/LTotal Barium 0.135 mg/LTotal Strontium 0.120 mg/LTotal Silica 17.00 mg/LTotal Fluoride 0.06 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal Phosphorus < 0.12 mg/LDissolved Calcium 21.40 mg/LDissolved Magnesium 6.96 mg/LDissolved Sodium 5.65 mg/LDissolved Potassium < 0.12 mg/LDissolved Chloride 1.10 mg/LDissolved SulfateDissolved Iron 5.330 mg/LDissolved Manganese 0.203 mg/LDissolved Boron < 0.02 mg/LDissolved Barium 0.120 mg/LDissolved Strontium 0.295 mg/LDissolved Silica 15.93 mg/LDissolved Fluoride 0.06 mg/LDissolved Nitrate as NitrogenDissolved Phosphorus < 0.12 mg/L


50


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013989 Laboratory No: RFGW-01 AKGWA Well No: 80001078.00Collector: DRW Date Collected: Apr/05/1994 Military Time:Date Received: Apr/08/1994 Military Time:Laboratory: KGS Analyst: HF Date: 4-May-1994Total Aluminum 65.00 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal BromideTotal Cadmium < 6.00 µg/LTotal Cobalt < 12.00 µg/LTotal Copper < 7.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium < 3.00 µg/LTotal MercuryTotal Nickel < 49.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver 15.00 µg/LTotal Tin < 426.00 µg/LTotal Zinc < 4.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium < 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium 4.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver 8.00 µg/LDissolved Tin < 426.00 µg/LDissolved Zinc < 4.00 µg/L


51


SITE IDENTIFICATION AND LOCATIONRecord No: 00013988 Field Well No: UK-C-2 AKGWA Well No: 80001079.00Reporting Agency: KGS Site Reporter: DWDate: Aug/08/1994Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 373053.00 DEG.; West Longitude: 830804.00 DEG.Elevation In Feet: 1120.0 Observed At: GROUND LEVELTotal Depth: 141.0 FT Diameter: 2 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: Producing zone is in Breathitt Fm., shallow

fracture zone

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ARCHDate Started: Feb/25/1993 Date Completed: Mar/04/1992Construction Notes: HOLE DRILLED BUT COULD NOT BE COMPLETED 2/25/92

DUE TO CAVING.Drilling Method: AIR ROTARYDepth to Bedrock: 20.0 FT Completion Zone: BREATHITT FM.

ANNULUS FILLING MATERIALSGravel Pack: SAND FILTER, Backfill: BENTONITE GROUT

Top Seal: CONCRETE, Bottom Seal: BENTONITE

PUMP AND WELL HEAD FEATURES

Type: NO DATA, Power Supply: UNK VOLTSDischarge Rating: Intake Depth:Well Head Cap: LOCKING CAP Pitless Adapter: NOWater Treatment: NO Bypass Available: NA




52


WATER QUALITY ANALYSISRecord No: 00013988 Other ID NO: UK-C-2AKGWA Number: 80001079Collector: DRW Date Collected: Aug/18/1992 Military Time: 10:00Date Received: Aug/19/1992 Military Time:Laboratory: KGS Analyst: HF Date:Sep/28/1992

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 226.00 mg/LTotal CarbonateTotal Sulfate 35.90 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.49 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 21.00 mg/LDissolved Magnesium 3.86 mg/LDissolved Sodium 62.90 mg/LDissolved Potassium < 0.05 mg/LDissolved Chloride 4.40 mg/LDissolved SulfateDissolved Iron 0.070 mg/LDissolved Manganese 0.130 mg/LDissolved Boron 0.08 mg/LDissolved Barium 0.143 mg/LDissolved Strontium 0.366 mg/LDissolved Silica 19.25 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.05 mg/L


53


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013988 Laboratory No: 24400-01 AKGWA Well No: 80001079.00Collector: DRW Date Collected: Aug/18/1992 Military Time: 10:00Date Received: Aug/19/1992 Military Time:Laboratory: KGS Analyst: HF Date: 28-Sep-1992Total Aluminum 0.00 µg/LTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 15.00 µg/LDissolved Antimony < 37.00 µg/LDissolved Arsenic < 59.00 µg/LDissolved Beryllium < 1.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 4.00 µg/LDissolved Cobalt < 6.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 40.00 µg/LDissolved Lithium < 11.00 µg/LDissolved MercuryDissolved Nickel < 18.00 µg/LDissolved Selenium < 67.00 µg/LDissolved Silver < 4.00 µg/LDissolved Tin < 73.00 µg/LDissolved Zinc < 3.00 µg/L


54


WATER QUALITY ANALYSISRecord No: 00013988 Other ID NO: UK-C-2AKGWA Number: 80001079Collector: Date Collected: Mar/29/1993 Military Time: 09:56Date Received: Apr/02/1993 Military Time:Laboratory: Analyst: Date:May/07/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 118.00 mg/LTotal CarbonateTotal Sulfate 32.40 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.08 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 29.40 mg/LDissolved Magnesium 4.79 mg/LDissolved Sodium 10.80 mg/LDissolved Potassium < 0.08 mg/LDissolved Chloride < 1.00 mg/LDissolved SulfateDissolved Iron 0.583 mg/LDissolved Manganese 0.142 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.257 mg/LDissolved Strontium 0.315 mg/LDissolved Silica 21.35 mg/LDissolved Fluoride 0.08 mg/LDissolved Nitrate as Nitrogen 0.030 mg/LDissolved Phosphorus < 0.08 mg/L

*** SUBJECT TO CORRECTION OR REVISION WITHOUT NOTICE***

*** NO WARRANTY IS EXPRESSED OR IMPLIED BY KGS ****** NOT FOR PUBLICATION OR PROMOTION OF SERVICES ***

55


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013988 Laboratory No: AKGWA Well No: 80001079.00Collector: Date Collected: Mar/29/1993 Military Time: 09:56Date Received: Apr/02/1993 Military Time:Laboratory: Analyst: Date: 7-May-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum < 32.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium 257.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper 20.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 5.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver 8.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc 17.00 µg/L


56


WATER QUALITY ANALYSISRecord No: 00013988 Other ID NO: UK-C-2AKGWA Number: 80001079Collector: Date Collected: Mar/30/1993 Military Time: 09:15Date Received: Apr/02/1993 Military Time:Laboratory: Analyst: Date:May/10/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 118.00 mg/LTotal CarbonateTotal SulfateTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.08 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal PhosphorusDissolved Calcium 29.40 mg/LDissolved Magnesium 4.79 mg/LDissolved Sodium 10.80 mg/LDissolved Potassium < 0.08 mg/LDissolved ChlorideDissolved SulfateDissolved Iron 0.583 mg/LDissolved Manganese 0.142 mg/LDissolved Boron < 0.04 mg/LDissolved BariumDissolved Strontium 0.315 mg/LDissolved Silica 12.11 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.08 mg/L


57


WATER QUALITY ANALYSISRecord No: 00013988 Other ID NO: UK-C-2AKGWA Number: 80001079Collector: Date Collected: Jul/22/1993 Military Time: 09:50Date Received: Jul/23/1993 Military Time:Laboratory: Analyst: Date:Sep/28/1993

Specific Conductance, Microsiemens/Cm pH,Standard Units Total Dissolved Solids TotalAcidity, Mg/L as CaC03 Total Alkalinity TotalHardness Noncarbonate HardnessTotal Calcium 31.30 mg/LTotal Magnesium 6.07 mg/LTotal Sodium 14.50 mg/LTotal Potassium 3.37 mg/LTotal Bicarbonate 124.00 mg/LTotal CarbonateTotal SulfateTotal Iron 10-300 mg/LTotal Manganese 0.226 mg/LTotal Boron 0.023 mg/LTotal Barium 0.332 mg/LTotal Strontium 0.348 mg/LTotal Silica 39.14 mg/LTotal FluorideTotal Nitrate as Nitrogen 0.712 mg/LTotal Phosphorus 0.22 mg/LDissolved Calcium 32.20 mg/LDissolved Magnesium 6.22 mg/LDissolved Sodium 14.40 mg/LDissolved Potassium 0.12 mg/LDissolved Chloride 2.12 mg/LDissolved SulfateDissolved Iron 3.510 mg/LDissolved Manganese 0.156 mg/LDissolved Boron 0.02 mg/LDissolved Barium 0.255 mg/LDissolved Strontium 0.351 mg/LDissolved Silica 23.96 mg/LDissolved FluorideDissolved Nitrate as Nitrogen 3.150 mg/LDissolved Phosphorus < 0.12 mg/L


58


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013988 Laboratory No: AKGWA Well No: 80001079.00Collector: Date Collected: Jul/22/1993 Military Time: 09:50Date Received: Jul/23/1993 Military Time:

Laboratory: Analyst: Date: 28-Sep-1993

Total Aluminum 4530.00 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic < 50.00 µg/LTotal Beryllium 332.00 µg/LTotal BismuthTotal Bromide 3.89 µg/LTotal Cadmium < 6.00 µg/LTotal Cobalt < 12.00 µg/LTotal Copper < 7.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 10.00 µg/LTotal MercuryTotal Nickel < 49.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver < 6.00 µg/LTotal Tin < 426.00 µg/LTotal Zinc 27.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium 255.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium 4.00.µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver < 6.00 µg/LDissolved Tin < 426.00 µg/LDissolved zinc 14.00 µg/L

Total and Dissolved concentration data not listed on this report may beavailable for the following species. CR, GA, GE, MO, RB, TI, ZR, VA Total,,Total Recoverable and Dissolved concentrations may also be available forany four additional determinations.

59


WATER QUALITY ANALYSISRecord No: 00013988 Other ID NO: UK-C-2AKGWA Number: 80001079Collector: Date Collected: Apr/05/1994 Military Time: 12:15Date Received: Apr/08/1994 Military Time:Laboratory: Analyst: Date:May/04/1994

Specific Conductance, Microsiemens/Cm pH,Standard Units Total Dissolved Solids TotalAcidity, Mg/L as CaC03 Total Alkalinity TotalHardness Noncarbonate HardnessTotal Calcium 21.40 mg/LTotal Magnesium 14.70 mg/LTotal Sodium 31.70 mg/LTotal Potassium 8.49 mg/LTotal Bicarbonate 141.00 mg/LTotal CarbonateTotal Sulfate 33.30 mg/LTotal Iron 50.400 mg/LTotal Manganese 0.914 mg/LTotal Boron < 0.023 mg/LTotal Barium 0.477 mg/LTotal Strontium 0.299 mg/LTotal Silica 68.23 mg/LTotal Fluoride 0.10 mg/LTotal Nitrate as Nitrogen 0.032 mg/LTotal Phosphorus < 0.12 mg/LDissolved Calcium 13.70 mg/LDissolved Magnesium 3.09 mg/LDissolved Sodium 29.90 mg/LDissolved Potassium < 0.12 mg/LDissolved ChlorideDissolved SulfateDissolved Iron 0.235 mg/LDissolved Manganese 0.063 mg/LDissolved Boron < 0.02 mg/LDissolved Barium 0.139 mg/LDissolved Strontium 0.192 mg/LDissolved Silica 15.32 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.12 mg/L


60


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013988 Laboratory No: AKGWA Well No: 80001079.00Collector: Date Collected: Apr/05/1994 Military Time: 12:15Date Received: Apr/08/1994 Military Time:Laboratory: Analyst: Date: 4-May-1994Total Aluminum 24.10 µg/LTotal Antimony < 51.00 µg/LTotal Arsenic 117.00 µg/LTotal Beryllium < 2.40 µg/LTotal BismuthTotal BromideTotal Cadmium 14.00 µg/LTotal Cobalt 37.00 µg/LTotal Copper 32.00 µg/LTotal IodideTotal Lead < 71.00 µg/LTotal Lithium 58.00 µg/LTotal MercuryTotal Nickel 138.00 µg/LTotal Selenium < 129.00 µg/LTotal Silver 8.00 µg/LTotal Tin < 426.00 µg/LTotal Zinc 156.00 µg/LDissolved Aluminum < 19.00 µg/LDissolved Antimony < 51.00 µg/LDissolved Arsenic < 50.00 µg/LDissolved Beryllium < 2.40 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 6.00 µg/LDissolved Cobalt < 12.00 µg/LDissolved Copper < 7.00 µg/LDissolved IodideDissolved Lead < 71.00 µg/LDissolved Lithium 5.00 µg/LDissolved MercuryDissolved Nickel < 49.00 µg/LDissolved Selenium < 129.00 µg/LDissolved Silver 6.00 µg/LDissolved Tin < 426.00 µg/LDissolved Zinc < 4.00 µg/L


61

62


SITE IDENTIFICATION AND LOCATIONRecord No: 00013996 Field Well No: AD-M AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRW Date:Jan/01/1991Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372512.00 DEG.; West Longitude: 831140.00DEG.Elevation In Feet: 1450.0 Observed At: TOP OF CASINGTotal Depth: 315.0 FT Diameter: 2 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Jan/01/1991 Date Completed: Jan/03/1991Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: HAZARD 8







WATER QUALITY ANALYSISRecord No: 00013996 Other ID NO: AD-MAKGWA Number:Collector: DRW Date Collected: Oct/01/1992 Military Time:Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date:Nov/13/1992

Specific Conductance, Microsiemens/Cm 525 µSIEMpH, Standard Units 6.86 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 290.00 mg/LTotal CarbonateTotal Sulfate 57.80 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.14 mg/LTotal Nitrate as Nitrogen 0.130 mg/LTotal PhosphorusDissolved Calcium 40.10 mg/LDissolved Magnesium 20.70 mg/LDissolved Sodium 20.60 mg/LDissolved Potassium 0.08 mg/LDissolved Chloride 1.58 mg/LDissolved SulfateDissolved Iron 0.057 mg/LDissolved Manganese 0.462 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.091 mg/LDissolved Strontium 0.223 mg/LDissolved Silica 23.96 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.08 mg/L


63


WATER QUALITY ANALYSISRecord No: 00013996 Other ID NO: AD-MAKGWA Number:Collector: DRW Date Collected: Feb/09/1993 Military Time: 18:53Date Received: Feb/12/1993 Military Time:Laboratory: KGS Analyst: HF Date:Mar/29/1993

Specific Conductance, Microsiemens/Cm 500 µSIEMpH, Standard Units 6.90 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 256.00 mg/LTotal CarbonateTotal Sulfate 54.00 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.16 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 44.40 mg/LDissolved Magnesium 24.40 mg/LDissolved Sodium 14.20 mg/LDissolved Potassium 0.19 mg/LDissolved Chloride < 1.00 mg/LDissolved SulfateDissolved Iron 0.278 mg/LDissolved Manganese 0.342 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.077 mg/LDissolved Strontium 0.227 mg/LDissolved Silica 31.40 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.19 mg/L


64


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013996 Laboratory No: 24400-01 AKGWA Well No:Collector: DRW Date Collected: Feb/09/1993 Military Time: 18:53Date Received: Feb/12/1993 Military Time:Laboratory: KGS Analyst: HF Date: 29-Mar-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum < 32.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 22.00 µg/LDissolved MercuryDissolved Nickel 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin 0.83 µg/LDissolved Zinc 23.00 µg/L


65

66


SITE IDENTIFICATION AND LOCATIONRecord No: 00013995 Field Well No: AD-N AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRWDate: Jan/01/1991Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372509.00 DEG.; West Longitude:831145.00 DEG.Elevation In Feet: 1560.0 Observed At: TOPOF CASINGTotal Depth: 131.0 FT Diameter: 2.0 INProducing Zone: Formation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Jan/01/1991 Date Completed: Jan/03/1991Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: SKYLINE 7







WATER QUALITY ANALYSISRecord No: 00013995 Other ID NO: AD-NAKGWA Number:Collector: DRW Date Collected: Oct/01/1992 Military Time: 12:45Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date:Nov/13/1992

Specific Conductance, Microsiemens/Cm. 414 µSIEMpH, Standard Units 6.84 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 211.00 mg/LTotal CarbonateTotal Sulfate 60.60 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal FluorideTotal Nitrate as Nitrogen 0.220 mg/LTotal PhosphorusDissolved Calcium 27.10 mg/LDissolved Magnesium 20400 mg/LDissolved Sodium 4.98 mg/LDissolved Potassium < 0.08 mg/LDissolved Chloride 2.10 mg/LDissolved SulfateDissolved Iron 1.740 mg/LDissolved Manganese 0.359 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.076 mg/LDissolved Strontium 0.215 mg/LDissolved Silica 11.60 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.08 mg/L


67


. TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013995 Laboratory No: 24400-01 AKGWA Well No:Collector: DRW Date Collected: Oct/01/1992 Military Time: 12:45Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date: 3-Nov-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal Selenium 96.00 µg/LTotal SilverTotal TinTotal ZincDissolved Aluminum 710.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 7.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc 8.00 µg/L


68


SITE IDENTIFICATION AND LOCATIONRecord No: 00013994 Field Well No: AD-O AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRW Date: Jan/01/1991Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372515.00 DEG.; West Longitude: 831145.00 DEG.Elevation In Feet: 1560.0 Observed At: TOP OF CASINGTotal Depth: 320.0 FT Diameter: 2 INProducing Zone: Between HAZ 8&9 Formation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Jan/01/1991 Date Completed: Jan/03/1991Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: HAZARD8/9






69


WATER QUALITY ANALYSISRecord No: 00013994 Other ID NO: AD-0AKGWA Number:Collector: DRW Date Collected: Oct/01/1992 Military Time: 11:55Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date:Nov/13/1992

Specific Conductance, Microsiemens/Cm 414 µSIEMpH, Standard Units 7.08 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 345.00 mg/LTotal CarbonateTotal Sulfate 17.20 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.09 mg/LTotal Nitrate as Nitrogen 0.580 mg/LTotal PhosphorusDissolved Calcium 34.10 mg/LDissolved Magnesium 13.00 mg/LDissolved Sodium 10.20 mg/LDissolved Potassium 0.38 mg/LDissolved Chloride 2.24 mg/LDissolved SulfateDissolved Iron 0.302 mg/LDissolved Manganese 0.065 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.112 mg/LDissolved Strontium 0.168 mg/LDissolved Silica 16.70 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.38 mg/L


70


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013994 Laboratory No: 24400-01 AKGWA Well No:Collector: DRW Date Collected: Oct/01/1992 Military Time: 11:55Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date: 13-Nov-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 556.00 µg/LDissolved Antimony > 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper 22.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 15.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 82.80 µg/LDissolved Zinc 19.00 µg/L


71


WATER QUALITY ANALYSISRecord No: 00013994 Other ID NO: AD-OAKGWA Number:Collector: DRW Date Collected: Feb/10/1993 Military Time:14:55Date Received: Feb/12/1993 Military Time:Laboratory: KGS Analyst: HF Date:Mar/29/1993

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal Calcium < 37.30 mg/LTotal Magnesium 14.70 mg/LTotal SodiumTotal PotassiumTotal BicarbonateTotal CarbonateTotal SulfateTotal Iron 0.013 mg/LTotal Manganese 0.089 mg/LTotal Boron < 0.036 mg/LTotal Barium < 0.078 mg/LTotal StrontiumTotal SilicaTotal FluorideTotal Nitrate as NitrogenTotal Phosphorus 0.74 mg/LDissolved Calcium 37.30 mg/LDissolved Magnesium 14.70 mg/LDissolved Sodium 10.20 mg/LDissolved Potassium 0.74 mg/LDissolved Chloride 22.80 mg/LDissolved Sulfate 22.30 mg/LDissolved Iron 0.013 mg/LDissolved Manganese 0.089 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.112 mg/LDissolved Strontium 0.174 mg/LDissolved SilicaDissolved Fluoride 0.12 mg/LDissolved Nitrate as NitrogenDissolved Phosphorus 0.74 mg/L


72



Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 40.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 14.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved SeleniumDissolved Silver < 5.00 µg/LDissolved Tin < 82.80 µg/LDissolved Zinc < 6.00 µg/L


73

74


SITE IDENTIFICATION AND LOCATIONRecord No: 00013993 Field Well No: AD-P AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRWDate: Jan/01/1991Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372510.00 DEG.; West Longitude: 831150.00DEG.Elevation In Feet: 1370.0 Observed At: TOPOF CASINGTotal Depth: 320.0 FT Diameter: 211 INProducing Zone: Between HAZ 5&6 Formation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF-ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Jan/01/1991 Date Completed: Jan/03/1991Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: HAZARD5/6







WATER QUALITY ANALYSISRecord No: 00013993 Other ID NO: AD-PAKGWA Number:Collector: Date Collected: Oct/02/1992 Military Time: 10:35Date Received: Oct/05/1992 Military Time:Laboratory: Analyst: Date:Nov/13/1992

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 316.00 mg/LTotal CarbonateTotal Sulfate 13.90 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.40 mg/LTotal Nitrate as Nitrogen 0.260 mg/LTotal PhosphorusDissolved Calcium 7.62 mg/LDissolved Magnesium 2.29 mg/LDissolved Sodium 98.20 mg/LDissolved Potassium 0.42 mg/LDissolved Chloride 2.15 mg/LDissolved SulfateDissolved Iron 0.142 mg/LDissolved Manganese 0.031 mg/LDissolved Boron 0.05 mg/LDissolved Barium 0.147 mg/LDissolved Strontium 0.269 mg/LDissolved Silica 8.96 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.42 mg/L


75


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013993 Laboratory No: AKGWA Well No:Collector: Date Collected: Oct/02/1992 Military Time: 10:35Date Received: Oct/05/1992 Military Time:Laboratory: Analyst: Date: 13-Nov-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 70.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic 78.00 µg/LDissolved Beryllium 147.00 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper 5.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 8.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc 12.00 µg/L

Total and Dissolved concentration data not listed on this report maybe available for the following species. CR, GA, GE, MO, RB, TI, ZR, VATotal, Total Recoverable and Dissolved concentrations may also be availablefor any four additional determinations.

76


WATER QUALITY ANALYSISRecord No: 00013993 Other ID NO: AD-PAKGWA Number:Collector: Date Collected: Feb/og/1993 Military Time: 17:40Date Received: Feb/12/1993 Military Time:Laboratory: Analyst: Date:Mar/29/1993

Specific Conductance, Microsiemens/Cm,pH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 555.00 mg/LTotal CarbonateTotal Sulfate 61.40 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal FluorideTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 22.30 mg/LDissolved Magnesium 5.87 mg/LDissolved Sodium 187.00 mg/LDissolved Potassium 0.34 mg/LDissolved Chloride 4.93 mg/LDissolved SulfateDissolved Iron 0.252 mg/LDissolved Manganese 0.095 mg/LDissolved Boron 0.06 mg/LDissolved Barium 0.406 mg/LDissolved Strontium 0.831 mg/LDissolved Silica 13.28 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.34 mg/L


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TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013993 Laboratory No: AKGWA Well No:Collector: Date Collected: Feb/09/1993 Military Time: 17:40Date Received: Feb/12/1993 Military Time:Laboratory: Analyst: Date: 29-Mar-1993

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 37.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 10.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc 10.00 µg/L


78


SITE IDENTIFICATION AND LOCATIONRecord No: 00013997 Field Well No: AD-Q AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRWDate: Jan/01/1991Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372500.00 DEG.; West Longitude: 831200.00DEG.Elevation In Feet: 1225.0 Observed At: TOPOF CASINGTotal Depth: 340.0 FT Diameter: 2 INProducing Zone: MAGOFFIN Formation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Jan/01/1991 Date Completed: Jan/03/1991Construction Notes:Drilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: BELOW MAGOFFIN


PUMP AND WELL HEAD FEATURESType: NO DATA, Power Supply: UNK VOLTSDischarge Rating: Intake Depth:Well Head Cap: LOCKING COVER. Pitless Adapter: NOWater Treatment: NO Bypass Available: NA

CASING RECORDString Top String Bottom inside Diameter Casing Material



79


WATER QUALITY ANALYSISRecord No: 00013997 Other ID NO: AD-QAKGWA Number:Collector: DRW Date Collected: Oct/01/1992 Military Time:Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: HF Date:Nov/13/1992

Specific Conductance, Microsiemens/Cm 3290 µSIEMpH, Standard Units 8.23 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 1260.00 mg/LTotal CarbonateTotal Sulfate 12.00 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 1.20 mg/LTotal Nitrate as Nitrogen < 0.100 mg/LTotal PhosphorusDissolved Calcium 6.68 mg/LDissolved Magnesium 1.76 mg/LDissolved Sodium 567.00 mg/LDissolved Potassium 0.68 mg/LDissolved Chloride 400.00 mg/LDissolved SulfateDissolved Iron 0.089 mg/LDissolved Manganese 0.011 mg/LDissolved Boron 0.18 mg/LDissolved Barium 0.233 mg/LDissolved Strontium 0.443 mg/LDissolved Silica 4.36 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.68 mg/L


80


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013997 Laboratory No: 24400-01 AKGWA Well No:Collector: DRW Date Collected: Oct/01/1992 Military Time:Date Received: Oct/05/1992 Military Time:Laboratory: KGS Analyst: UNK Date: 13-Nov-1992Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal Cadmium < 7.00 µg/LTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 211.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium <Dissolved Cobalt < 11.00 µg/LDissolved Copper 12.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 54.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc < 6.00 µg/L


81


WATER QUALITY ANALYSISRecord No: 00013997 Other ID NO: AD-QAKGWA Number:Collector: DRW Date Collected: Feb/10/1993 Military Time: 12:00Date Received: Feb/12/1993 Military Time:Laboratory: KGS Analyst: HF Date:Mar/29/1993

Specific Conductance, Microsiemens/Cm. 3155 µSIEMpH, Standard Units 8.44 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 1210.00 mg/LTotal Carbonate 2.00 mg/LTotal Sulfate 11.70 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 1.94 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 5.10 mg/LDissolved Magnesium 1.52 mg/LDissolved Sodium 700.00 mg/LDissolved Potassium 1.60 mg/LDissolved Chloride 494.00 mg/LDissolved SulfateDissolved Iron 0.080 mg/LDissolved Manganese 0.010 mg/LDissolved Boron 0.19 mg/LDissolved Barium 0.305 mg/LDissolved Strontium 0.506 mg/LDissolved Silica 6.11 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 1.60 mg/L


82



Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 244.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium < 70.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Zinc < 6.00 µg/L


83


SITE IDENTIFICATION AND LOCATIONRecord No: 00013992 Field well No: AD-R AKGWA Well No:.00Reporting Agency: KGS Site Reporter: DRWDate: Feb/lo/1993Hydrological Site Type: WATER WELL Water Use: MONITORINGCounty: BREATHITT State: KY Quadrangle: NOBLENorth Latitude: 372517.00 DEG.; West Longitude:831140.00 DEG.Elevation In Feet: 1380.0 Observed At: TOP OF CASINGTotal Depth: 154.0 FT Diameter: 2 INProducing Zone: HINDMAN COALFormation: BREATHITTHouseholds Served: Persons Served:General Comments: LAUREL FORK TRACT OF ROBINSON FOREST; ABANDONED OR

DESTROYED IN 1994

WELL CONSTRUCTION METHODS AND FEATURESDrilled By: ADDINGTONDate Started: Aug/01/1991 Date Completed: Aug/01/1991Construction Notes: SAND PACK INTERVAL BETWEEN 94 AND 154 FEETDrilling Method: AIR ROTARYDepth to Bedrock: Completion Zone: HAZARD #9






84


WATER QUALITY ANALYSISRecord No: 00013992 Other ID NO: AD-RAKGWA Number:Collector: Date Collected: Oct/01/1992 Military Time: 15:35Date Received: Oct/05/1992 Military Time:Laboratory: Analyst: Date:Nov/13/1992

Specific Conductance, Microsiemens/CmpH, Standard UnitsTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 184.00 mg/LTotal CarbonateTotal SulfateTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal FluorideTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 36.00 mg/LDissolved Magnesium 15.30 mg/LDissolved Sodium 12.90 mg/LDissolved Potassium < 0.08 mg/LDissolved ChlorideDissolved SulfateDissolved Iron 0.213 mg/LDissolved Manganese 0.305 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.076 mg/LDissolved Strontium 0.131 mg/LDissolved Silica 24.81 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus < 0.08 mg/L


85


TRACE ELEMENTS WATER QUALITY ANALYSISRecord No: 00013992 Laboratory No: AKGWA Well No:Collector: Date Collected: Oct/01/1992 Military Time: 15:35Date Received: Oct/05/1992 Military Time:Laboratory: Analyst: Date: 13-Nov-1992

Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved Aluminum 67.00 µg/LDissolved Antimony < 53.00 µg/LDissolved Arsenic < 78.00 µg/LDissolved Beryllium < 1.70 µg/LDissolved BismuthDissolved BromideDissolved Cadmium < 7.00 µg/LDissolved Cobalt < 11.00 µg/LDissolved Copper 4.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved Lithium 16.00 µg/LDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved Selenium < 96.00 µg/LDissolved Silver < 5.00 µg/LDissolved Tin < 0.83 µg/LDissolved Z~nc 14.00 µg/L


86


WATER QUALITY ANALYSISRecord No: 00013992 Other ID NO: AD-RAKGWA Number:Collector: DRW Date Collected: Feb/10/1993 Military Time: 13:05Date Received: Feb/12/1993 Military Time:Laboratory: KGS Analyst: HF Date:Mar/29/1993

Specific Conductance, Microsiemens/Cm 346 µSIEMpH, Standard Units 6.56 SUTotal Dissolved SolidsTotal Acidity, Mg/L as CaC03Total AlkalinityTotal HardnessNoncarbonate HardnessTotal CalciumTotal MagnesiumTotal SodiumTotal PotassiumTotal Bicarbonate 171.00 mg/LTotal CarbonateTotal Sulfate 22.60 mg/LTotal IronTotal ManganeseTotal BoronTotal BariumTotal StrontiumTotal SilicaTotal Fluoride 0.13 mg/LTotal Nitrate as NitrogenTotal PhosphorusDissolved Calcium 29.60 mg/LDissolved Magnesium 13.20 mg/LDissolved Sodium 10.60 mg/LDissolved Potassium 0.11 mg/LDissolved Chloride 1.64 mg/LDissolved SulfateDissolved Iron 0.788 mg/LDissolved Manganese 0.278 mg/LDissolved Boron < 0.04 mg/LDissolved Barium 0.083 mg/LDissolved Strontium 0.125 mg/LDissolved Silica 30.16 mg/LDissolved FluorideDissolved Nitrate as NitrogenDissolved Phosphorus 0.11 mg/L


87

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Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved AluminumDissolved AntimonyDissolved Arsenic < 78.00 µg/LDissolved BerylliumDissolved BismuthDissolved BromideDissolved CadmiumDissolved CobaltDissolved Copper < 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved LithiumDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved SeleniumDissolved SilverDissolved TinDissolved Zinc 21.00 µg/L




Total AluminumTotal AntimonyTotal ArsenicTotal BerylliumTotal BismuthTotal BromideTotal CadmiumTotal CobaltTotal CopperTotal IodideTotal LeadTotal LithiumTotal MercuryTotal NickelTotal SeleniumTotal SilverTotal TinTotal ZincDissolved AluminumDissolved AntimonyDissolved Arsenic <Dissolved BerylliumDissolved BismuthDissolved BromideDissolved CadmiumDissolved CobaltDissolved Copper 3.00 µg/LDissolved IodideDissolved Lead < 55.00 µg/LDissolved LithiumDissolved MercuryDissolved Nickel < 42.00 µg/LDissolved SeleniumDissolved SilverDissolved TinDissolved Zinc 21.00 µg/L

Total and Dissolved concentration data not listed on this report maybe available for the following species. CR, GA, GE, MO, RB, TI, ZR, VATotal, Total Recoverable and Dissolved concentrations may also beavailable for any four additional determinations.

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interim progress report on ground-water research at

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