international society of electrochemistry · 2008. 8. 17. · simple preparation method of...

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Book of AbstractsNanostructured Materials in Electrochemistry:Biosciences and Molecular Electronics Applications

1 May to 4 May, 2007Dublin, Ireland

5th Spring Meeting of theInternational Society of Electrochemistry

Book of Abstracts – 5th Spring M

eeting of the International Society of Electrochemistry

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Book of Abstracts of the

5th Spring Meeting of the

International Society of Electrochemistry

Nanostructured Materials in Electrochemistry; Biosciences and Molecular Electronics Applications

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Book of Abstracts of the

5th Spring Meeting of the

International Society of ElectrochemistryNanostructured Materials in Electrochemistry; Biosciences and Molecular Electronics Applications

Dublin, Ireland1 – 4 May, 2007

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International Society of ElecrtochemistryAvenue Vinet 191004 LausanneSwitzerland

Copyright © 2007

All rights reserved. No part of this work may be reproduced, stored in retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without prior written permission of the Publisher.

No responsibility is assumed by the Publisher for any injury and/or damage to persons or property as a matter of product liability, negligence or otherwise, or from any use or operation of any methods, products, instructions or ideas contained in the material herein.

Printed in The Netherlands

v

Organising CommitteeChairmanTim McCormac, Ireland

Robert Forster, IrelandLo Gorton, SwedenOle Hammerich, DenmarkMarcin Opallo, PolandWolfgang Schuhmann, Germany

Local Organising Committee John Cassidy, Dublin Institute of TechnologyEithne Dempsey, Institute of Technology Tallaght DublinRobert Forster, Dublin City UniversityMike Lyons, Trinity College DublinEdmond Magner, University of Limerick

vi Acknowledgements Sponsors and Exhibitors

Agilent Technologies

Centre for Research In Electroanalytical Technology

DiagnoSwiss

Failte Ireland

IJ Cambria Scientific Ltd

Institute of Chemistry of Ireland

Institute of Technology Tallaght

Ivium Technologies

JPK Technologies

Materials and Surface Science Institute Centre for Spectroscopy

Nuclear Centre for Sensor Research

Nuclear Magnetic Resonance Institute

Science Foundation Ireland

The Electrochemical Society

Uniscan Instruments

Windsor Scientific/Ecochemie

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5th Spring Meeting of the International Society of Electrochemistry

Table of Contents

Invited LecturesSynthesis, Characterization, and Electrocatalytic Applications of Dendrimer-Encapsulated Nanoparticles PL-1

Heechang Ye and Richard M. Crooks

Micro Electrochemical Devices via Soft-Lithography: New Systems for Energy and Bioanalytical Applications PL-2

Ralph G Nuzzo

Engineering SERS Substrates for Bioelectrochemical Studies PL-3Philip N. Bartlett

Nanoparticles on surfaces for proteomic analysis PL-4J-P. Abid, J-M. Busnel, J. Gamby, J. Ji, B.H.Liu, Y. Liu, N. Lion, Y. Xue, P. Yang, M. Zhang, H. H. Girault

Single-molecule “Transistors” from Au-nanoparticles to Proteins and DNA in Electrochemical Environment PL-5

J. Ulstrup

Oral PresentationsFunctionalized Gold Surfaces of Polyfluorinated Dithiols as New Platform for Electronic Devices O-1

Claire Amato, Patrick Calas, Joseph Delhalle, Zineb Mekhalif

Voltammetry of Pores, Particles and Proteins – Towards Nanobioelectroanalytical Systems O-2

Damien W. M. Arrigan, Alfonso Berduque, Gregoire Herzog, Yvonne Lanyon

Development of nanoelectrode arrays for sensing applications O-3Ronan Baron, Biljana Šljukić, Xuan Dai, Gregory G. Wildgoose, Richard G. Compton

Simple Preparation Method of Multilayer Films Containing Pd Nanoparticles O-4

Li-Hua Bi, Timothy McCormac, Eithne Dempsey

Electrochemical Properties of a New Metallopolymer:Nanoparticle Nanocomposite Material. O-5

Jennifer L. Brennan, Robert J. Forster

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Synthesis and Characterization of Redox Active MnO2 Nanoparticles O-6Daniel Grohol, Poonam Singh, Tomasz Dziedzic, Jeff Yarger, Virgil Solomon, Daniel A. Buttry

Electrochemical Formation Of Ni Catalyst Nanoparticles on Thin Sio2 Layers for SWNT Growth O-7

Lukas Durrer, Ricardo Santos-Roque, Matthias Muoth, Christofer Hierold

Nanostructured (organo)silica thin films on electrodes O-8M. Etienne, D. Grosso, A. Quach, C. Sanchez, A. Walcarius

Nanobiosensor for amperometric capture of the metabolic profile of antiretroviral drugs O-9

Nicolette Hendricks, Immaculate Michira, Rachel Ngece, Richard Akinyeye, Amir Al-Ahmed, Anna Ignaszak, Tesfaye Waryo, Priscilla Baker, Emmanuel Iwuoha

Nano-electrochemistry on the AFM-Tip applied to live cells O-10Gerald Kada, Christine Kranz, Justyna Wiedemair, Jean-Francois Manson, Boris Mizaikoff

Multi-color Electrochromism of Nanoparticles of Prussian blue and Its Analogues O-11

Shigeo Hara, Tohru Kawamoto, Hisashi Tanaka , Madoka Tokumoto, Mami Yamada, Akihito Gotoh, Masato Kurihara, Masatomi Sakamoto

Electrochemical Properties of II-VI Quantum Dot Monolayers at Blocked Electrodes O-12

Gabriela Kissling, Christa Bünzli and David J. Fermín

Single molecule electronic behaviour of α, μ’–bis(6–mercaptohexyl) oligothiophenes and related compounds O-13

Edmund Leary, Horst Höbenreich, Simon J. Higgins, Harm van Zalinge, Wolfgang Haiss and Richard J. Nichols

Haem Protein in Nonaqeous Solvents: Electrochemistry and Spectroscopy O-14S. Crilly, Z. Brusova, N. O’Reilly, E. Ivanova, S. Hudson, E. Magner

Layered Double Hydroxides-Enzyme nanohybrid materials applied to biosensor development O-15

Christine Mousty, Serge Cosnier, Claude Forano, Vanessa Prevot

A Spectroelectrochemical Approach to Complex Membrane Proteins O-16Renate L.C. Naumann, Marcel G. Friedrich, Vinzenz Kirste and Wolfgang Knoll

DNA Sensors in Selectively Modified Nanoporous Electrode Structures O-17Sebastian Neugebauer, Magdalena Gebala, Leonard Stoica, Gerhard Hartwich, Ulrich Müller, Martin Stelzle, Wolfgang Schuhmann

Electrochemiluminescent Metallopolymers for Detection of Biological Analytes O-18

Emmet J. O’Reilly, Lynn Dennany, Tia Keyes, Robert J. Forster

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Novel Electroactivities of Nanostructured Metallophthalocyanine – Single-Walled Carbon Nanotube Arrays at Gold Surfaces O-19

Kenneth I. Ozoemena and Duduzile Nkosi

Self-Assembled Monolayers at Electrodes in DNA and Protein Analysis O-20E. Palecek, V. Ostatna, V. Dorcak, M. Trefulka

Electrocodeposition of Nickel-Alumina Nanocomposite Films under the Influence of Static Magnetic Fields O-21

Ralf Peipmann, Andreas Bund

Synthesis, characterization and electrochemistry of redox-modified silica particles on platinum electrode surfaces O-22

Nicolas Plumeré, Bernd Speiser

Electrochemical Detection of Biological Reactions Using a Novel Nano-Bio-Chip Array O-23

Judith Rishpon, Tova Neufeld Rachela Popovtzer, and Yosi Shacham-Diamand

Use of crystalline proteins for templated electrodeposition O-24Daniel B. Allred, Sathana Kitayaporn, Mehmet Sarikaya, François Baneyx, Daniel T. Schwartz

Particle Size and Substrate Effects in Electrocatalysis: Carbon and Titania Supported Gold Particles O-25

Derek Pletcher, Jens-Peter Suchsland and Brian E. Hayden

Kinetics of oxygen reduction on gold nanoparticle/multi-walled carbon nanotubes hybrid electrodes in acid solution O-26

N. Alexeyeva, T. Laaksonen, K. Kontturi, F. Mirkhalaf, D.J. Schiffrin, K. Tammeveski

Development of an electrochemical immunosensor for West Nile virus O-27Hui Si Lim, Gui Wan Koh, Mary M. L. Ng and Chee-Seng Toh

Biological and Chemical Sensing Using Transmission Localized Surface Plasmon Resonance (T-LSPR) Spectroscopy O-28

Alexander Vaskevich, Tatyana A. Bendikov, Tanya Karakouz, Shirley Daube, Tamar Yelin, Aharon Rabinkov, Mila Eydelman, and Israel Rubinstein

Electrochemical aspects of nanostructure display technology based on titanium dioxide-attached viologen chromophores. O-29

Nick Vlachopoulos, Alain Briançon, David Corr, Christian Grave, Nigel Leyland, Martin Möller, Jarl Nissfolk, François Pichot and Michael Ryan

Nanoreactors in nature: Bioelectrochemical mechanisms O-30Alexander G. Volkov, Maya I. Volkova-Gugeshashvili and Albert J. Osei

Morphological evolution of polycrystalline Platinum during electrochemical roughening O-31

X. Wei, A. Reiner, E. Müller, A. Wokaun, G. G.Scherer

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Reflection anisotropy spectroscopy of DNA adsorbed at the Au(110)/electrochemical interface O-32

P. Weightman, C. I. Smith, M. C. Cuquerella, D. G. Fernig, C. Edwards and D. S. Martin

The Influence of the Electrode Material on the Single Molecule Conductance O-33

H. van Zalinge, W. Schwarzacher, R.J. Nichols

Label-free Dna-sensing using Gan Nanowires NanosensorChin-Pei Chen*1,2, Abhijit Ganguly2, Chen-Hao Wang2, Chih-Wei Hsu1, Yu-Kuei Hsu1, Kuei-Hsien Chen1,2, Li-Chyong Chen2 O-34

Poster PresentationsPreparation of Nanosized Electrode Arrays from Self-Assembled Monolayers. Comparison of Experimental and Theoretical Responses and Evaluation of Electroanalytical Detection Limits P-1

Serdar Abaci, Gunes Eroglu, Curtis Shannon

Nanoscale electroless deposition of magnetic alloys P-2Bernadette Ahern, Stephen Crowley, Lorraine Nagle, Declan Casey, Ken Reynolds, James Rohan, Fernando Rhen and Saibal Roy

LB film taste sensor using packaged measuring system P-3Masahiro Akiya,Yoshinobu Akimoto, Eiji Hirayama and Takamichi Hirata

Mixed Polyfluorinated Aminoterminated SAMs as New Platform for Biosensing P-4

Claire Amato, Cédric Volcke, Takashi Kakiuchi, Joseph Delhalle, Zineb Mekhalif, Patrick Calas

Gold Nanoparticle labels for Enhanced Electrochemical Immunoassay P-5Adriano Ambrosi, Arben Merkoçi, Anthony J. Killard, Salvador Alegret and Malcolm R. Smyth

Constant-distance scanning electrochemical microscopy (SECM) for visualization of glucosedehydrogenase/polymer spot using the enzyme mediated positive feedback mode P-6

Emad Mohamed Hussien Amine Aly, Monika Maciejewska, Wolfgang Schuhmann

Onset of crystalline order in 1-nonanethiol monolayers deposited from solution P-7

María José Capitán, Jesús Álvarez, Juan José Calvente and Rafael Andreu

Direct electron transfer kinetics in horseradish peroxidase electrocatalysis P-8Rafael Andreu, Elena E. Ferapontova, Lo Gorton and Juan José Calvente

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The Utilization of Carbon Nanotube Based Composite as Amperometric Biosensor Transducer P-9

Meliha Çubukçu, Suna Timur, Ülkü Anık Kırgöz

The Utilization of Vanadium Doped Zr-PILCs Nanocomposites For Electroanalytical Applications P-10

Meliha Çubukçu, İlyas Deveci, Nurgün Beşün, Suna Timur, Ülkü Anık Kırgöz

A Study on the Electrochemical Impedance Spectroscopy and Responds to Dopamine on Poly (Carbazole-co-p-Tolylsulfonyl pyrrole)-modified Carbon fiber microelectrodes P-11

Murat Ates, and A. Sezai Sarac

The Electrochemical Behavior of Poly (N-vinyl carbazole) formed on Carbon fiber microelectrodes: Responds to Dopamine P-12

Murat Ates, Koray Yilmaz, A.Sezai Sarac

Three – phase electrochemistry with an oil droplet punctured by a cylindrical microelectrode P-13

Mikolaj Donten, Fritz Scholz, Elzbieta Bak, Zbigniew Stojek

Nanostructured poly(methacrylate-aniline) hydrogel as immobilization matrix for electrochemical DNA biosensor P-14

Omotayo A Arotiba, Jasmina Martinovic, Amir Al Ahmed, Tesfaye Waryo, Anna Ignaszak, PGL Baker, Emmanuel Iwuoha

Synthesis and Characterization of Alloy vs. Core-Shell Catalysts and Abnormal Diffraction Effects P-15

E.A. Baranova, C. Bock, Y. Le Page, D. Ilin, B. MacDougall

Synthesis, Characterisation and Electrocatalytic Properties of Pt Nanoparticles P-16

Maryam Bayati, Jose M. Abad, Craig A. Bridges, Matthew J. Rosseinsky, David J. Schiffrin

Biosensor Failure Detection Via Neural Network Methodology P-17Ipek Becerik

Comparison of The Protective Properties 4-Nitrothiophenol and 4-Nitrobenzenediazonium Films Grafted on a ZnNi Coating Electrodeposited On Steel P-18

François Berger, Joseph Delhalle, Zineb Mekhalif

The Study of Influence of Counter Anion Type on Polymeric Film Morphology P-19

Krzysztof Bieńkowski, Krystyna Jackowska, Marek Szklarczyk

Oxide and hydroxide nanostructures embedded into Anodic Alumina Membranes prepared by means of electrogeneration of base P-20

P. Bocchetta, M. Santamaria and F. Di Quarto

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Modification of gold electrodes with metal ion phthalocyanines for the detection of biological thiols P-21

David Bogaert, Karolien De Wael, Laszlo Vincze, Annemie Adriaens

Characterization of Carbon Nanotube Modified Screen-Printed Electrodes P-22

Pablo Fanjul Bolado, Pedro José Lamas Ardisana, Paula Queipo, Agustín Costa García

Impedimetric genosensing using gold-streptavidin nanoparticles for signal amplification P-23

A.Bonanni, M.J Esplandiu, S. Alegret, M. del Valle

Photoelectrochemical Characteristics of CdTe Quantum Dot Modified Electrodes P-24

Christa Bünzli, Gabriela Kissling and David J. Fermín

Good’s Buffers Inert or not? An Electrochemical Study P-25Hans Buschop, Karolien De Wael, Lina De Smet, Hendrik A. Heering, Bart Devreese, Annemie Adriaens

Electrochemical detection of hydrogen peroxide with Rhodobacter capsulatus cytochrome c peroxidase at a gold electrode P-26

Karolien De Wael, Annemie Adriaens, Hans Buschop, Lina De Smet, Bart Devreese, Hendrik A. Heering

Electrochemical Studies of Single-Stranded DNA Self-Assembled Monolayers on Gold Electrode Surfaces P-27

Carlos R. Cabrera, Nelson E. Rivera-Vélez, Germarie Sánchez-Pomales, Lenibel Santiago-Rodríguez, and Joel Rivera-Gandia

Selective permeation of a liquid-like SAM of 11-amino-1-undecanethiol (AUT) on polycrystalline Au by redox probes P-28

José M. Campiña, Ana Martins, Fernando Silva

Characteristics of supercapacitor electrodes of Carbon black/PAN carbon nanofiber P-29

Duk-Rye Chang, Sung-Hwa Oh, Ho-Sung Kim

Electrochemical properties of supercapacitor electrodes of polyacrylonitrile nanofibers P-30

Duk-Rye Chang, Eun-Young Jeong, Ho-Sung Kim

Label-free Dna-sensing using Gan Nanowires Nanosensor P-31Chin-Pei Chen, Abhijit Ganguly, Chen-Hao Wang, Chih-Wei Hsu, Yu-Kuei Hsu, Kuei-Hsien Chen, Li-Chyong Chen

Are We On The Same Wavelength? Tuneable Photonic Crystal Structures As Highly Reproducible SERS Substrates P-32

Suzanne Cintra, Mamdouh Abdelsalam, Philip Bartlett, Jeremy Baumberg, Robin Cole, Sumeet Mahajan and Andrea Russell

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Corrosion Inhibition Of Stainless Steel By Using Ketone Based Resins P-33Nilgün Kızılcan, Kerim Çoban, Esma Sezer

Electrical properties of electrochemically deposited single bismuth nanowires P-34

T.W. Cornelius, M.E. Toimil-Molares, S. Karim, R. Neumann

A Theoretical Study on the Electronic Coupling between Azurin and Gold at Different Protein/Substrate Orientations P-35

Venkat Anurag Setty, Stefano Corni, Rosa Di Felice

Spectroscopic and Electrochemical Measurements of Cytochrome C at Gold Surfaces Modified with mixed SAMs. P-36

Suzanne Crilly, Edmond Magner

Development and electroanalytical properties of composite electrodes modified with ZrO2 nanogels P-37

Veronica Sima, Cecilia Cristea, Florina Lapadus, I.O. Marian, Robert Sandulescu

Nanostructure nickel hydroxide modified electrodes for urea determination P-38

Marcelo R. Silva, Marcio Vidotti, S. Córdoba de Torresi, L.H. Dall’Antonia

Layer-by-layer films of polyaniline and polysaccharide for biomaterial application P-39

Eliana França, Vitor L. Martins, Aneli M. Barbosa, Valtencir Zucolotto, Dyovani Coelho, Jarem R. Garcia, Karen Wohnrath, Luiz H. Dall´Antonia

Surface modification of a silicon substrate by Pt nanoparticles and study of the new electrochemical properties P-40

Isabelle Darolles, Eric Mahe, Didier Devilliers

Electrochemiluminescent Monolayers on Metal Oxide Electrodes: Detection of Amino Acids P-41

Lynn Dennany, Emmet J. O’Reilly, Tia E. Keyes, Robert J. Forster

Manufacturing of Semiconductor – Oxide Nanocomposites Based on Indium Phosphide P-42

A.I. Dikusar, P.G. Globa, S.P. Sidelinikova, E. Monaico, I.M. Tiginyanu

A cholesterol biosensor based on magnetic nanoparticles P-43Rodica Doaga, Timothy McCormac, Eithne Dempsey

Improved safety behavior of LixCoO2 encapsulated by cobalt phosphate nanoparticle for lithium ion battery P-44

Chil-Hoon Doh, Angathevar Veluchamy, Dong-Hoon Kim, Hye-Min Shin, Dae-Hee Oh, Bong-Soo Jin, Seong-In Moon

Nano layer Co3(PO4)2 coated LixCoO2 for High performance lithium-ion battery P-45

Chil-Hoon Doh, Dong-Hoon Kim, Hye-Min Shin, Dae-Hee Oh, Bong-Soo Jin, Seong-In Moon, Angathevar Veluchamy

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Synthesis and Electrochemical Evaluation of La1-xSrxCoO3 Cathode Material for Zinc Air Batteries Application P-46

Seung-Wook Eom, Se-Young Ahn, Yang-Kook Sun

Electron Transfer in Substituted Polynuclear Platinum Derivatives. Spectroelectrochemical and Theoretical Studies P-47

Alberto Albinati, Samantha Bruzzone, Fabrizia Fabrizi de Biani, Carla Guidotti, Piero Leoni, Gabriele Manca, Lorella Marchetti, Piero Zanello

Towards label free DNA sensing through semiconducting nanowires P-48G. Faglia , C. Baratto, E. Comini, M. Ferroni, G. Sberveglieri

Orientation of a Self-Assembled Monolayer of Decanethiol on Au(110) as monitored by Reflection Anisotropy Spectroscopy P-49

C.I. Smith, T. Farrell, P. Harrison and P. Weightman

Ac-Electrogravimetry Characterization of Poly[Pd(3-Mesalen)] Electroactive Thin Films P-50

J. Fonseca, C. Freire, C. Moura

Development of a biocatalytic fuel cell working in physiological conditions P-51

Kevin Foster, Paul Kavanagh, Peter Jenkins, Susan Boland and Dónal Leech

In-situ probing of dynamic nano-structural change of electrodeposits in course of oscillatory growth using SERS P-52

Kazuhiro Fukami, Shuji Nakanishi, Yoshitaka Sawai, Kei Murakoshi and Yoshihiro Nakato

Electrochemical detection of DNA hybridization using antinomycin D and redox mediators P-53

Magdalena Gebala, Leonard Stoica, Sebastian Neugebauer, Wolfgang Schuhmann

Electropolymerization and characterization of 2,2 Dimethyl (3,4- propylenedioxythiophene) P-54

Aslı Gençtürk, A.Sezai Saraç, Hans-Detlev Gilsing, Burkhard Schulz

Carbon Paste Electrodes Modified with a new Phenothiazine Derivative Adsorbed on Zeolite and on Mineral Clay for Nadh Oxidation P-55

Delia Gligor, Florina Balaj, Andrada Maicaneanu, Liana Muresan, I.C. Popescu

Development of a CNT paste electrode Os2+/3+ polymer-mediated biosensor for determination of glucose in alcoholic beverages P-56

Lo Gorton, Federico Tasca, Riccarda Antiochia

Development of an electrochemical alcohol oxidase biosensor based on carbon nanotube modified carbon film electrodes P-57

Carla Gouveia-Caridade, Rasa Pauliukaite, Christopher M.A. Brett

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Role of Rigidness of the Matrix in Electrochemical Matrix Synthesis of Interpolymer Complexes of Polyaniline with Polysulfonic Acids of Various Nature P-58

O.L. Gribkova, A.A. Nekrasov, T.V. Eremina, V.F. Ivanov, A.A. Isakova, V.A. Tverskoj, A.V. Vannikov

The Role of Pt-Ru-Pd Nanopartıcles Dıspersed on Poly(3-Methyl) Thiophene Conductıng Polymer on the Electrooxıdatıon of Methanol P-59

S. Güney, I. Becerik

The Electrocatalytic Behaviour of Oxygen Reduction Reaction at Nano Size Conducting Polymer Electrodes Modified by New Water-Soluble Cobalt Phthalocyanine Derivatives P-60

Sevgi Güney, Sönmez Arslan, Ipek Becerik, Ismail Yilmaz

Conductive Cantilevers and Supports for Combined Atomic Force and Scanning Electrochemical Microscopy P-61

H. Haschke, P.L.T.M. Frederix, M.R. Gullo, T. Akiyama, P. Bosshart, N. de Rooij, U. Staufer and A. Engel

Theory vs Experiment: Electrochemical and DFT-Studies of Substituted Thiophenes P-62

Mohammed Al-anber, Bianca Milde, Wasim Alhalasah, Heinrich Lang and Rudolf Holze

Nafion-methylene blue functional membrane and its application in biochemical sensing P-63

Jun Hong, Ali Akbar Moosavi-Movahedi, Hedayatollah Ghourchian

Nanostructured Pd-AAM composite membranes P-64R. Inguanta, S. Piazza, C. Sunseri

Electrochemical Deposition of Thin Polypyrrole Films on Silicon Substrates P-65

C.M. Intelmann, V. Syritski, D. Tsankov, K. Hinrichs, J. Rappich

Adsorption kinetics of ATP anion on Bi(111) single crystal plane electrode P-66A. Jänes, E. Lust

Mediated enzyme electrochemistry for biocatalytic fuel cells P-67Kevin Foster, Paul Kavanagh, Peter Jenkins, Susan Boland and Dónal Leech

Carbon assisted heat-treatment for synthesis of Li4Ti5O12 nanoparticles P-68Chunhai Jiang, Itaru Honma, Haoshen Zhou

Copper Nanostructured/ Modified SnO2 Electrodes – Preparation, Surface Characterization and Electrochemical Behavior P-69

Maria Jitaru, Gabriel Oltean, Mariana Toma and Romulus Jitaru

Nanostructured Anode Oxides for Electrooxidation of Formaldehyde P-70Maria Jitaru and Romulus Jitaru

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Molecule and Ion Transport inside of Carbon Nanotubes P-71Oleg N. Kalugin and Vitaly V. Chaban

Photoelectrochemical properties of GaN nanodots P-72Takashi Kato, Inho Im, Katsushi Fujii, and Takafumi Yao

Enhancement of Rate Capability of Layered LiNi1/3Mn1/3Co1/3O2 Materials for Li Secondary Batteries P-73

Hyun-Soo Kim, Mingzhe Kong, Ke-Tack Kim, Seong-In Moon, and Woo-Seong Kim

Electrochemical Studies of Unit Cell for IT-SOFC P-74Ho-Sung Kim, Sun-Il Park, Duck Rye Chang, Jong-Ho Lee

Redox properties of Colloidal CdTe Quantum Dots P-75Gabriela Kissling, Christa Bünzli and David J. Fermín

Interactions between phosphorus dendrimers and heparin P-76Barbara Klajnert, Jean-Pierre Majoral, Maria Bryszewska

Pore-Spanning Bilayer Lipid Membranes P-77Slavoj Kresák, Wolfgang Knoll, Renate Naumann

Discharge Characteristics of Polypyrrole/Silver Vanadium Oxide Composite Used for Lithium Primary Batteries P-78

Yogesh K. Anguchamy, Jong-Won Lee, Branko N. Popov

Composite galvanic coatings with ceramic nanoparticles for industrial applications: the cases of copper, nickel, bronze on metallic substrates P-79

Maria Lekka, Caterina Zanella, Pier Luigi Bonora

Nanostructures Prepared via Electrodeposition at a Liquid-Liquid Interface Controlled Synthesis and Physical Properties Investigation of Metal/Polymer Nanocomposites P-80

Katerina Lepkova, Jason Clohessy, Vincent J. Cunnane

Electrosynthesis of Bilayer Coatings Based on Azulene and Prussian Blue P-81Cecilia Lete, Stelian Lupu, Mariana Marin, Nicolae Totir, A.C. Razus

First Principles Study on a Single Molecular Diode P-82Yanwei Li, Leilei Lu, Jinhuan Yao, Geping Yin

Electrochemical Constructions of the Nano-Micro Structured CaP Coatings on Titanium and Its Interaction with Protein P-83

Changjian Lin, Hui Wang, Ren Hu and Ye Qing

Sugar Sensing electrode based on PANI/NiOx composite P-84Xiao-Xia Liu, Xu-Yuan Peng, Pei-Jie Hua, King Tong Lau, Dermot Diamond

Assemblies of dendrimers and proteins on electrodes for biosensing applications P-85

E. Lojou and P. Bianco

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Photoelectrochemical and photocatalytic properties of nanocrystalline TiO2 electrodes P-86

H.G. Oliveira, D.C. Nery, M.P. Paschoalino, Claudia Longo

Dimethyl Ether Electro-Oxidation With Interdigitated Microarray Electrodes P-87

Leilei Lu, Geping Yin, Yunzhi Gao

Electrchemical Preparation and Characterization of Hybdrid Inorganic-Organic Materials for Electrochemical Sensing P-88

Stelian Lupu, Cecilia Lete, Mariana Marin

Electrochemical behaviour of biochemically active compounds on Bi(hkl) | base electrolyte interface P-89

E. Lust, H. Kasuk, A. Jänes, G. Nurk, S. Kallip, V. Grozovski

New Nanostructured CU-containing Polymer System as Catalysts for O2 Electroreduction P-90

Tatiana V. Magdesieva, Alexander V. Dolganov, Alexander V. Yakimansky, Mikhail Ya. Goikhman, Irina V. Podeshvo, Vladislav V. Kudryavtsev

Electrochemistry and Electrocatalysis of Horseradish Peroxidase (HRP) and Hemin in Organic Media P-91

Zuzana Brusova, Edmond Magner

CV-SECM at a confined disk ultramicroelectrode P-92Eric Mahé, Didier Devilliers

Simple Size-Sorting of Magnetic Nanoparticles P-93Pawel Majewski, Pawel Krysiński

Rotating Disk Electrode as a Tool for Porosity and Catalytic Activity Determinations of Electroactive Polymer Films P-94

Valery V. Malev, Oleg V. Levin

Towards Nano-patterned DSA® P-95Christine Malmgren, Joakim Bäckström, Håkan Olin

Surface Immobilised Cyclodextrins: Molecular Recognition at Interfaces P-96Colm Mallon, Zoe Piknomenou, Robert J. Forster and Tia E. Keyes

An Evaluation of the Performance of a Microbial Fuel Cell Using Different Electrochemical Techniques P-97

A. Manohar, F. Mansfeld, O. Bretschger, K.H. Nealson

Probing the Electronic Properties of Soluble Carbon Nanotubes by Electrochemistry P-98

Demis Paolucci, Matteo Iurlo, Massimo Marcaccio, Francesco Paolucci

Label free genonanosensor based on carbon nanotubes. P-99G. Marrazza, F. Berti, I. Palchetti, L. Lozzi, S. Santucci, G. Faglia, G. Sberveglieri

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Synchrotron X-ray Studies of Surface and Bulk Structure of Cathode Materials for Lithium-Ion Batteries P-100

J. McBreen, X.Q. Yang, W.S. Yoon, K.Y. Chung, and H.S. Lee

Development of Stable Dehydrogenase-based Bioanodes P-101Shelley D. Minteer

Electrochemically Deposited Hydroxyapatite Coatings Implanted with N4+ Ions P-102

M.S. Đošić, V.B. Mišković-Stanković, M.Z. Šiljegović, B.M. Jokić, J.D. Stojanović

Conducting polymer-supported platinum nanoparticles produced using a friendly chemical synthesis P-103

Carlos Sanchís, Horacio J. Salavagione, Emilia Morallón

Inkjet Printing: Novel Fabrication Approach for Sensors based on Conducting Polymer Nanoparticulate Ink P-104

Aoife Morrin, Karl Crowley, Orawan Ngamna, Gordon G. Wallace, Anthony J. Killard, and Malcolm R. Smyth

Nano-Cauliflowers: A Nanostructured Polyaniline-modified Screen-printed Electrode with a Self-assembled Polystyrene Template and its Application in an Amperometric Enzyme Biosensor P-105

Xiliang Luo, Aoife Morrin, Anthony J. Killard, Malcolm R. Smyth

Composite coatings with improved corrosion behavior obtained by electrolytic codeposition of copper with Al2O3 nanoparticles P-106

Ionut Zamblau, Simona Varvara, Ionel Catalin Popescu, Liana Maria Muresan

Nanoarchitecture of self-assembled gold cubes P-107Donald Fitzmaurice, Kirill Nikitin and Lorraine Nagle

Modified Oxide Graphite as Special Electroactive Material P-108 E.A.Nizhnikovsky, V.S.Poluboyarinov, V.V.Frol´chenkov, and A.V.Fesenko

Laccase - syringaldazine modified carbon - silicate composite electrode for dioxygen reduction P-109

Wojciech Nogala, Ewa Rozniecka, Jerzy Rogalski, Marcin Opallo

A Novel method for Microfabrication without photolithography P-110Samaneh Nouraei, Sudipta Roy

Redox polymer mediation of enzymes for amplified amperometric detection of DNA hybridization P-111

Joanna Hajdukiewicz, Paul Kavanagh, Anna Nowicka, Zbigniew Stojek and Dónal Leech

Carbon Paste Electrode Containing Organically Modified MCM-41; Application for Detection of Ferrocyanide P-112

Reza Ojani, Jahanbakhsh Raoof and Shahla Fathi

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A Sensor for Nitrite; Using a Carbon Paste Electrode Modified with Copper (II) Hexacyanoferrate (III) P-113

Reza Ojani, Jahanbakhsh Raoof and Banafsheh Norouzi

Electrochemical Preparation of Platinum Nano-Wires and Their Application to Electrocatalysts for PEM Fuel Cells P-114

Hiroshi Okura, Shinnosuke Koji, Masaaki Shibata

Silicate confined ionic liquid modified electrode for anion preconcentration and biocatalysis P-115

Adam Lesniewski, Joanna Niedziolka, Juliette Sirieix-Plenet, Laurent Gaillon, Frank Marken, Jerzy Rogalski, Marcin Opallo

Evidences of Opened Structures Formation During the Oxidation of Conducting Poly(o-Aminophenol) P-116

D. Paredes, R. Ortíz, M. Choy, Y. Matínez, J.M. Ortega

Electrochemical relaxation loop, conformational energy and conformational memory. (Is brain memory stored by polymeric conformations?) P-117

TF. Otero and F. Santos

Blood Lead Analysis Using Nanostructured Screen-Printed Carbon Electrodes P-118

Graciela Martínez Paredes, María Begoña González García, Agustín Costa García

Electronic sensor application of SWCNT network devices P-119Jonghyurk Park, Min-Baek Lee, Byung-Yang Lee, Seung-Hun Hong, PingAn Hu, Andrea Ferrari, Bill Milne, Sunglyul Maeng

Monolayer synthesis of the ordered organic surface on a gold substrate P-120Ž. Petrović, M. Metikoš-Huković, and R. Babić

Mesoporous Pt/Ru electrodes for direct methanol micro-fuel cells P-121G.A. Planes, G. Garcçia, J.L. Rodríguez, E. Pastor

Electrochemical Synthesis of Au Nanostructures in Modified Electrodes with Dendrimers and SAMs P-122

P.M.R. Paulo, A.S. Viana

Silver Nanoparticles Obtained by Electrosynthesis in Aqueous Media under Protection of a Mix of Stabilizers P-123

Aurora Petica, Magdalena Lungu, Liana Anicai

Nitrogenated nanocrystalline diamond, a new electrode material P-124Yu V. Pleskov, M.D. Krotova, V.G. Ralchenko, A.V. Saveliev, I.I. Vlasov

Functional properties and topography of glucose biosensor based on poly(amidoamine) dendrimers P-125

V. Polohová, M. Šnejdárková, L. Svobodová, T. Hianik

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Gold Surfaces Modified with Enzyme Microstructures for Simultaneous Glucose and Glutamic Acid Monitoring P-126

Laura Muresan, Mihaela Nistor, S. Gaspar, Elisabeth Csoregi and I.C. Popescu

Highly Active Carbon-Based Catalysts for Oxygen Reduction Reaction P-127Branko N. Popov

Modelling of non-linear reaction-diffusion processes of amperometric polymer-modified electrode P-128

G. Rahamathunissa, L.Rajendran

Electrocatalytic Oxidation and Voltammetric Determination of Sulfite at the Surface of Carbon Paste Electrode Spiked With a New Ferrocene Derivative P-129

Jahan Bakhsh Raoof, Reza Ojani and Hassan Karimi-Maleh

Electrocatalytic Determination of L-Cysteine at the Surface of Ferrocenedicarboxylic Acid Modified Carbon Paste Electrode P-130

Jahan-Bakhsh Raoof, Reza Ojani and Hadi Beitollahi

GRAVI-Chips: Disposable Nanofluidic Electrochemical Cells for Fast Analysis P-131

Patrick Morier, Christine Vollet, François Vulliet, Frédéric Reymond and Joël Rossier

Electrochemical synthesis of nanoparticles: nucleation, growth and ultrasonic detachment P-132

David Ritson, Richard Nichols, David J Schiffrin

Electroless deposition of nanotubes P-133James Rohan, Declan Casey, David Fleming and Simon Lawrence

Stability of Substituted 4-Bromobenzene and 4-Nitrobenzene Groups Electrochemically Grafted at Carbon Electrode Surface P-134

A.A. Rostami and M. Khoshroo

In-situ Synchrotron X-ray Absorption Studies of Electrochemically Deposited ZnO Nanostructures P-135

B. Illy, B. Ingham and M.P. Ryan

Electrochemical Preparation of an Ideally-Structured Porous Silicon Rugate Filter P-136

M.S. Salem, M.J. Sailor, T. Sakka, Y.H. Ogata

Fluorescent films of dansyl derivatives: preparation, voltammetric and AFM characterization P-137

Stela M.M. Leite, José G. Silva Jr., Josealdo Tonholo, Adriana Santos Ribeiro

Synthesis and Characterization of Polyaniline-Sulfonated Phthalocyanine Thin Films P-138

Grzegorz Milczarek, Aleksander Ciszewski

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Simulation of the cathodic delamination process of coatings on metal surfaces P-139

H.Satori

Electrosynthesis of Ni/Al-hydrotalcite: study of the growth on electrode surface P-140

Erika Scavetta, Adriana Mignani, Lorella Guadagnini, Barbara Ballarin, Irene Carpani, Domenica Tonelli

Lipopeptide Nanopores As Voltage Sensors In Planar Lipid Bilayers P-141L.V. Schagina, O.S. Ostroumova, Ph.A. Gurnev, V.V. Malev

Thin Layer Electrolytic Co9S8 for Lithium Power Sources P-142E. Shembel, R. Apostolova, D. Striga

Evaluation of activated 4-nitrothiophenol modified Au electrodes as potential interface for biosensing applications P-143

Stefanie Schwamborn, Leonard Stoica, Sebastian Neugebauer, Wolfgang Schuhmann

Composite materials based on polythiophenes and metal nanoparticles P-144L. Pigani, R. Seeber, F. Terzi, C. Zanardi, V. Martina, B. Zanfrognini, T. Ääritalo, J. Lukkari

Ionic transport studies on conductivity behaviour of polymer electrolytes containing NH4PF6 P-145

Jitender Paul Sharma, S.S. Sekhon

Supercapacitor Electrode from Carbon Fiber/Conducting Polymer Nano-Composites P-146

Ashok K. Sharma, Jong-Huy Kim, and Yong-Sung Lee

Interface Resistance Between Nanostructured Thin Layers of Electrochemicaly Active Materials and Metallic Substrate P-147

V. Redko, V. Khandetskyy, E. Shembel, T. Pastushkin, O. Redko

Electrodeposition of Gold and Silver Nanoparticles of Controlled Size and Interparticle Spacing: Application to Single Nanoparticle SERS P-148

Eoin Sheridan, Obianuju Inya-Agha, Tia Keyes and Robert Forster

Synthesis and Characterization of Peo Blend P(Tmc) Solid Polymer Electrolyte P-149

P.C. Barbosa, L.C. Rodrigues, M.M. Silva, M.J. Smith

Sol-Gel Derived Poly(ε-Caprolactone)/Siloxane Biohybrids with Application in Electrochemistry P-150

S.C. Nunes, V. de Zea Bermudez, M.M. Silva, M.J. Smith, D. Ostrovskii, L.D. Carlos

Sputtered PtIr thin films for bioengineering and electrocatalytic application P-151

E. Slavcheva, G. Genske, G. Topalov, U. Schnakenberg, W. Mokwa

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An aptamer-based QCM biosensor P-152Maja Šnejdárková, Lenka Svobodová, Vladimíra Polohová, Tibor Hianik

Nanostructured electrode materials obtained from fluorine containing electrolytes of manganese with additives of copper(II) or lithium ions P-153

G. Sokolsky, N. Ivanova, S. Ivanov, Ye. Boldyrev

Rose Bengal Monolayer based on High Quality Bilayer for Molecular Device P-154

Gyeong Sook Bang, Ja-Ryong Koo, Jonghyurk Park, Hyoyoung Lee

(Opto)electrochemistry of PbS NC’s deposited onto ITO substrates P-155M. Stein, A. Bund, S.G. Hickey, A. Eychmüller

Detection of low-molecular-weight pesticides by an acetylcholinesterase-based SPR biosensor P-156

Lenka Svobodová, Maja Šnejdárková, Vladimíra Polohová, Hana Vaisocherová, Jiří Homola

ITO nanoparticles – silicate – polyallylamine film modified electrode for ABTS2- - Laccase system immobilisation P-157

Katarzyna Szot, Joanna Niedziolka, Frank Marken, Jerzy Rogalski, Marcin Opallo

Sum-Frequency Generation spectroscopy at the electrochemical interface of a synthesized stellar dust cyanoethylene molecule adsorbed on Au(111) P-158

C. Humbert, B. Busson, A. Gayral, C. Six, A. Tadjeddine

Oxygen reduction on nanostructured gold electrodes P-159Margus Nurmik, Ave Sarapuu, Kaido Tammeveski

A Novel Photosensitization System: Electron Donor and Photosensitizer Incorporated into TiO2 Gel Matrix P-160

Shuxin Tan, Christophe Roussel, Bin Su, Baohong Liu, Hubert Girault

A Mediator-Type Nanocomposite Biosensor Based on Bacterial Cells P-161Dilek Odacı, Ülkü Anık Kırgöz, Suna Timur

Influence of Organic Solvents on the Inhibition by Paraoxon of the Immobilized Acetylcholinesterase P-162

Graziella Liana Turdean, Ionel Catalin Popescu

Characterization of SIROF for neural electrostimulation – design and material considerations P-163

A. van Ooyen, E. Slavcheva, W. Mokwa, U. Schnakenberg

Electrochromic electrodes modified by mixed nanoparticles of Ni/Co/Cd(OH)2 nanoparticles P-164

Marcio Vidotti, Susana I. Córdoba de Torresi

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A Raney Nickel electrode revisited P-165Marco Villa, Paolo Nelli, Giovanni Zangari

High Activity of Electrocatalysts Deposited on CNT-based Electrode for Direct Methanol Fuel Cell P-166

C.-H. Wang, H.-C. Hsu, S.-T. Chang, C.-C. Chen, C.-P. Chen, H.-Y. Du, H.-C. Shih, L.-C. Chen, K.-H. Chen

Micro- to Macro-Porous Silicon Formation by Means of Metal Particle Enhanced HF Etching P-167

Shinji Yae, Makoto Abe, Naoki Fukumuro, Hitoshi Matsuda

The Electrochemical Impedance Spectroscopy of Poly (N-vinylcarbazole) onto Carbon fiber microelectrodes in different solutions and methods P-168

Koray Yilmaz, Murat Ates, and A.Sezai Sarac

Fabrication of Ordered Nanoporous Garphitic C3N4 as an Efficient Catalyst Support for Direct Methanol Fuel cell P-169

Sohee Hwang, Min Sik Kim and Jong-Sung Yu

Functionalization of Single-Wall Carbon Nanotubes: a new promising nanomaterial for neurotransmitters detection P-170

Daniela Zane, Marta Feroci, Antonella Curulli, Angela De Nardo

Influence of surface specifications and chemical contents on electrochemical capacitor performance of manganese oxide P-171

Alireza. Zolfaghari, Fatemeh Ataherian, Mehdi Ghaemi

Invited Lectures

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PL-15th Spring Meeting of the International Society of Electrochemistry

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Engineering SERS Substrates for Bioelectrochemical Studies

Philip N. Bartlett*, School of chemistry, University of Southampton, Southampton, SO17 1BJ, UK

*[email protected]

Templated electrochemical deposition through close packed monolayers of unform polystyrene colloidal particles followed by dissolution of the template produces structured thin films containing an array of interconnected spherical segement voids. The diameters and organisation of these voids replicate the diameter and packing of the colloidal particles used to form the template and the thickness of the film is controlled by the charge passed to deposit the film. It is thus possible to simply and predictably control the geometry of the film. These structured metal films have interesting magnetic [1], superconducting [2] and optical properties [3] that are determined by their precise geometry. Using templates with diameters between 450 and 1200 nm we are able to produce surfaces that show significant enhancement in surface enhanced Raman spectroscopy (SERS). We have investigated the origins of this surface enhancement by varying the film thickness, template sphere diameter and looking at the angular dependence. We find that the intensity of the SER spectra varies with all of these factors indicating that the precise geometry of the structured surface and the excitation of surface plasmons is important. In contrast to electrochemically roughened surfaces the intensity of the SERS spectra on the structured surface is reproducible from place to place across the surface and from sample to sample. This is a significant potential advantage. The structured surfaces are also robust and stable under laboratory conditions and ideally suited as electrodes for electrochemical SERS experiments. Visible excitation laser sources commonly used in SERS experiments can cause photochemical reactions on the surface as well as fluorescence from the adsorbed molecules, such problems are prevalent in the study of biomolecules. A way to circumvent this possibility is the use of Near Infra-Red (NIR) laser sources. This demands appropriate design of substrates for NIR-SERS in order to obtain the maximum enhancement. Results will be presented for a series of adsorbed analytes and biologically relevant molecules. References [1] P. N. Bartlett, M. A. Ghanem, I. S. El Hallag, P. de Groot, A. Zhukov, J. Mater.

Chem., 13, 2003, 2596. [2] A. A. Zhukov, E. T. Filby, M. A. Ghanem, P. N. Bartlett and P. A. J. de Groot,

Physica C, 404, 2004, 455. [3] P. N. Bartlett, J. J. Baumberg, S. Coyle and M. Abdelsalem, Faraday Discuss., 125,

2004, 117. [4] S. Mahajan, M. Abdelsalam, Y. Suguwara, S. Cintra, A. Russell, J. Baumberg and

P. Bartlett, Phys. Chem. Chem. Phys., 9, 2007, 104.

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Single-molecule “Transistors” from Au-nanoparticles to Proteins and DNA in Electrochemical Environment

J. Ulstrup

Department of Chemistry, Building 207, DTU, DK-2800 Lyngby, Denmark

Scanning tunnelling microscopy (STM) to molecular resolution in aqueous solution under substrate and tip double potential control (in situ STM) is established and has recently been extended in our group to ionic liquid media. In situ STM extends beyond imaging, and offers two kinds of tunnelling “spectroscopy”, the tunnelling current/bias voltage relation at constant electrochemical overpotential, and the tunnelling current/overpotential relation at constant bias voltage. These are equivalent to the current/bias and current/gate voltage relations of molecular transistors. In contrast to reported cases of single-molecule transistors, in situ STM-based molecular transistor function operates at room temperature in condensed matter environment. The accessibility of a chemical redox centre in the molecule is crucial in this respect. In situ STM-tunnelling spectroscopy with “on-off” ratios up to two orders of magnitude is established in our group, with transition metal complexes and a redox metalloprotein (Pseudomonas aeruginosa azurin) as prime targets. New results apply to Coulomb blockade effects in Au-nanoparticles (1.6 nm) and to redox-marked oligonucleotides. These quite different systems display molecular electronic amplification features that, however, differ in details of the physical mechanisms. Some perspectives of this will be noted.

cover_07.pdf01-prelims.pdf02-invited.pdf

international society of electrochemistry · 2008. 8. 17. · simple preparation method of...

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