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Maria Dolores FIDELIBUS Politecnico di Bari +39 0805963373 Eemail [email protected] International Workshop TOWARDS SCENARIOS FOR URBAN ADAPTATION PLANNING Assessing seawater intrusion under climate and land cover changes in Dar es Salaam, Tanzania Session 1. Monitoring Urban Environmental Changes: Seawater intrusion MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION Rome, 22 th April 2013

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Page 1: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Maria Dolores FIDELIBUS Politecnico di Bari

+39 0805963373

Eemail [email protected]

International Workshop

TOWARDS SCENARIOS FOR URBAN ADAPTATION PLANNING Assessing seawater intrusion under climate and land cover changes in Dar es Salaam, Tanzania

Session 1. Monitoring Urban Environmental Changes: Seawater intrusion

MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

Rome, 22th April 2013

Page 2: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Working on conceptual models….

“Truth is much too complicated to allow anything but approximations”

John von Neumann, quoted in

Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder

Simplicity is the ultimate sophistication. Leonardo da Vinci

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 3: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Topics

•  Coastal aquifers: study of groundwater salinization –  Conceptual modelling

•  Looking for groundwater dynamics and source of salts –  Temperature and Electrical Conductivity logs –  Hydraulic measures –  Geochemical approach

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 4: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Selecting the suitable conceptual model…..

Selecting the suitable conceptual model …..…..

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 5: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Coastal karst aquifer

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 6: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Calcarenites, sands and clays (Pliocene-Quaternary); Calcarenites and marly calcarenites (Miocene);

Limestones and dolomitic limestones (Cretaceous)

Murge and Salento karstic coastal aquifers Schematic geological map

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 7: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

DOLINES

SINKHOLES

Murgia and Salento karstic coastal aquifers Structural features

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 8: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Brackish coastal springs Piezometric lines ( m a.s.l.)

Murgia

Mean recharge rate 47 m3/s

Hydraulic gradient 0.2 0/00

Salento

Mean recharge rate 28 m3/s

Hydraulic gradient 0.2 0/00

Murgia and Salento carbonate karstic coastal aquifers: piezometric map (m a.msl)

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 9: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

No. 107 Wells of the Monitoring net of Puglia Regional Government for the control of quantitative and qualitative status of groundwaters in karstic aquifers

MONITORING WELLS

Monitoring net (1st Level)

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 10: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Monitoring periods: I) 1995-1996; 2) winter 2007 end 2010

Dataset 1995-1996: no. 428 temperature (and EC, pH, Eh and O2) profiles (107 wells x 4 profiles)

Selected time horizon for geostatistical study: 107 profiles of winter 1995

Recharge areas

Coastal areas

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 11: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

The temperatures measured respectively at -5, -20, -30, -50, -70, -85, and -100 m AMSL, constitute no. 7 datasets.

The basic statistical analysis of each sub-set showed frequency distributions of bimodal type of the variable Temperature, indicating the presence of at least two distinct groups.

Cluster analysis, based on EC and T, allowed recognizing two main data populations, corresponding to the two contiguous aquifers.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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CLUSTER ANALYSIS

Page 12: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Frequency distribution

Variogram map

MURGE -20 m a.s.l

Direction: 135 Tolerance: 30 MURGE -20 m a.s.l

Direction: 45 Tolerance: 30

MURGE – Ordinary Kriging - Horizontal isotherm map (-20 m a.s.l.) VARIOGRAMS

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 13: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main recharge area

Main recharge area

Horizontal temperature section at -5 m a msl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 14: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: NW-SE (N135E) Salento: WNW-ESE (N115E)

T (°C)

Temperature at-5 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 15: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: NW-SE (N135E) Salento: WNW-ESE (N115E)

T (°C)

Temperature at -20 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 16: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: N125E Salento: N105E

T (°C)

Temperature -35 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 17: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: N115E Salento: N95E

T (°C)

Temperature -50 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 18: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: N115E Salento: isotropic?

For the Murgia aquifer, at -70 m AMSL, the range of the regional scale anisotropy jumps from 48 to 70 Km, indicating that the spatial continuity increases at depth.

T (°C)

Temperature at -70 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 19: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Main anisotropy axis direction Murge: N115E

T (°C)

Temperature at -85 m asl

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 20: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Temperature at-100 m a.s.l Main anisotropy axis direction Murge: N115E

T (°C) At the increase of the depth, the range of the local scale anisotropy decreases

Considering the contemporaneous increase of the regional anisotropy, this indicates an increase of anisotropy

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 21: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

A

A’

Main recharge area

Vertical temperature sections

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Page 22: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

. Thermal vertical section obtained by OK of data from profiles and horizontal OK grids.

The main vertical anisotropy axis has an inclination of 85°.

Groundwater flows horizontally through nearly vertical structures, which allow hydraulic connection between Murge and Salento.

Water balance studies indicate that Murgia aquifer recharges laterally the aquifer Salento with about 10 m3/s.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 23: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

TDS (g/l) -5 m s.l.m.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 24: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

TDS (g/l) -20 m s.l.m.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 25: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

TDS (g/l) -35 m s.l.m.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 26: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

.

TDS (g/l) -50 m s.l.m

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 27: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

.

TDS (g/l) -70 m s.l.m

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 28: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

.

TDS (g/l) -85 m s.l.m

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 29: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

TDS (g/l) -100 m s.l.m.

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 30: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Observation wells (Lago Rosso e Surbo) in Salento Peninsula

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 31: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

In a well completely screened in a phreatic groundwater, the distribution of water in depth mirrors the distribution of the groundwater in the aquifer.

The hydraulic head that can be measured in such conditions coincides with the Environmental Head or local Head ha defined by Lusczynski

z1

z3

z2

ts ha Sea level

Static level

Topographic surface

Salt water

Brackish water

Fresh water

Environmental head

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 32: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

z1

z3

z2

ts

ha Livello mare

Livello freatico

Piezometer open in salt water

Hydraulic Head (hd) expressed in fresh water equivalent to ts

Environmental head

Lusczynski - Equilibrium in presence of water with variable density

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 33: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 T D S ( g / l )

- 1 8 0

- 1 7 0

- 1 6 0

- 1 5 0

- 1 4 0

- 1 3 0

- 1 2 0

- 1 1 0

- 1 0 0

- 9 0

- 8 0

- 7 0

- 6 0

- 5 0

- 4 0

- 3 0

- 2 0

- 1 0

0

1 0

2 0

E e l

e v a t

i o n

( m a

. s . l .

)

L R o b s e r v a t i o n w e l l

1 9 7 4

1 9 9 6 Quota (m

a.s.l.)

Observation well LR TDS profiles 1974 and 1996

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Page 34: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

F r e s h w a t e r

T r a n s i t i o n z o n e

S a l t w a t e r

M i x e d w a t e r h a v i n g s a l i n i t y S b

Elevation (m

amsl

0 1 0 2 0 3 0 4 0 T D S ( g / l )

- 1 6 0

- 1 4 0

- 1 2 0

- 1 0 0

- 8 0

- 6 0

- 4 0

- 2 0

0

h b t

m . s . l .

z t

Z f t

Z x

0 1 0 2 0 3 0 4 0 T D S ( g / l )

- 1 6 0

- 1 4 0

- 1 2 0

- 1 0 0

- 8 0

- 6 0

- 4 0

- 2 0

0

z f

h t t

t m

Z b

t s

Z e q

m . s . l .

t m

h r d

r e f e r e n c e d e p t h , r d

Hsi hsi

Transition zone

Salt water

Fresh water

Theoric interface

Scheme of parameters, which can be obtained by an EC profile

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 35: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

OW SR

Thickness of salt water zx

Thickness of transition zone zt

Mean salinity Szb

Thickness of freshwater column zf

TDS g/L

Dep

th (m

am

sl)

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 36: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Observation Well SR

Hydraulic head ha

Top of transition zone

Theoric interface

Top of salt water

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Page 37: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

OW SR– Evolution of ts (salt water head) and variation of fresh water component

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Page 38: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

OW SR – Evolution of TDS in 40 years

0,5 g/l 1 g/l

2 g/l

30 g/l

40 g/l

TDS between 40 and 42 g/l TDS 42 G/L or higher

42 g/l

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 39: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Theoric interface indicates that the aquifer is subject to over-exploitation

Fresh water column and salt water column are virtual:

True salinity is shown by profiles

0 1 0 2 0 3 0 4 0 T D S ( g / l )

- 2 0 0

- 1 6 0

- 1 2 0

- 8 0

- 4 0

0

E l e v

a t i o n

( m a . s

. l . )

L R o b s e r v a t i o n w e l l 1 9 7 4 1 9 9 6

1 9 7 4 1 9 9 6

Theoric interface

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Page 40: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

OW LR

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Page 41: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

OW LR

0,5 g/l

10 g/l

20 g/l

30 g/l

35 g/l

40 g/l

1 g/l 0,5 g/l

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 42: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Mechanism of salinization induced by overexploitation

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 43: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Scheme of an observation well for the monitoring of freshwater-seawater equilibrium

Salt water

Trans. zone

Fresh water

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 44: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Groundwater salinisation may derive, beside from seawater intrusion, either from other natural salt sources or from human impact.

Natural salt sources:   Present seawater

  Salt waters of marine origin

  Evaporite salts

  Sea spray….

Human impact   Irrigation practices and land use

  Infiltration of polluted or saline surface waters (rivers, ponds, lagunes, salt works)

  Infiltration from landfills or injection of municipal wastewaters…….

ORIGIN OF SALINIZATION

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Page 45: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Simplified geological map : 1:Limestone and dolomitic limestones (Cretaceous); 2: Calcarenites and marly calcarenites (Miocene); 3: Calcarenites, sands and clays (Pliocene-Quaternary). Traces of geological section.

Salt waters …..

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Page 46: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Sinkholes Morpho-tectonic elements Hydrographic net Hydrological divide Doline

DEM m amsl

Cretaceous basement top (m amsl)

(Pumping waters)

22th April 2013 MONITORING SEAWATER INTRUSION IN THE COASTAL AQUIFER OF APULIA REGION

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Page 47: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

Chemical composition of salinized groundwaters almost never matches the composition outlined by the conservative mixing between freshwater and seawater.

Cl- (meq/l)

SO4=

(meq

/l)

?

?

?

The deviation from non-reactive mixing (dilution line) can be due either to •  the water-rock interaction processes triggered by mixing process or to •  the intervention of a salt source or a saline fluid of marine origin chemically different from present seawater. In most cases water-rock interactions overlap the effects of more than one salt source

How to recognize other sources of salinization?

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Page 48: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

•  Minor constituents are mostly enriched with respect to present seawater.

•  Sr/Cl ratio of saline waters is mostly higher than modern seawater: carbonate rock-water interaction is the main source of Sr, which can be used as relative age tracer. •  Li/Cl is highest in thermal waters confirming to be a useful pathfinder for hydrothermal systems

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Page 49: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

•  Saline waters show 14C activities lower than those found in recent seawater. These differences may indicate both age variations and chemical interaction with the host rock. •  Salt waters have δ13C values either depleted or enriched with respect to recent seawater:, indicating contributions from dissolution of marine carbonates, organic carbon and sulphate reduction. •  Determination of the real age is complicated by several possible sources of carbon that influence the 14 C values, besides the process of decay.

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* Barbieri Mr., Barbieri Mz., Fidelibus M.D., Morotti M., Sappa G., Tulipano L., (1999). First results of isotopic ratio 87Sr/86Sr in the characterization of seawater intrusion in the coastal karstic aquifer of Murgia (Southern Italy). Proc. of 15th Salt Water Intrusion Meeting, Gent (Belgium),

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Page 51: International Workshop TOWARDS SCENARIOS FOR URBAN ... · Fractals, Chaos, Power Laws: Minutes from an Infinite Paradise, by Manfred Schroder Simplicity is the ultimate sophistication

A never ending process…

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