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Introduction of the Dalian Institute of Chemical Physics (DICP), CAS Introduction of the Dalian Institute of Chemical Physics Introduction of the Dalian Institute of Chemical Physics (DICP), CAS (DICP), CAS Summer School on Surface Science & Catalysis August 13-25, UCSB/USA Summer School on Surface Science & Catalysis Summer School on Surface Science & Catalysis August 13 August 13 - - 25, UCSB/USA 25, UCSB/USA Xinhe BAO Xinhe BAO Dalian Institute of Chemical Physics, DICP the Chinese Academy of Sciences, CAS Tel: 0411 84686637, [email protected] http://www.fruit.dicp.ac.cn

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Page 1: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Introduction of the Dalian Institute of Chemical Physics (DICP), CAS

Introduction of the Dalian Institute of Chemical Physics Introduction of the Dalian Institute of Chemical Physics (DICP), CAS(DICP), CAS

Summer School on Surface Science & CatalysisAugust 13-25, UCSB/USA

Summer School on Surface Science & CatalysisSummer School on Surface Science & CatalysisAugust 13August 13--25, UCSB/USA25, UCSB/USA

Xinhe BAOXinhe BAODalian Institute of Chemical Physics, DICP

the Chinese Academy of Sciences, CASTel: 0411 84686637, [email protected]

http://www.fruit.dicp.ac.cn

Page 2: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Contents Contents Contents

IntroductionsIntroductionsthe Dalian Institute of Chemical Physics (DICP)the Dalian Institute of Chemical Physics (DICP)

the State Key Laboratory of Catalysis (SKLC)the State Key Laboratory of Catalysis (SKLC)

NanoNano--CatalysisCatalysisNanoNano--film: Quantum well statesfilm: Quantum well states

NanoNano--Particle: Quantum size effectsParticle: Quantum size effects

NanoNano--pore: Confinement effectspore: Confinement effects

Page 3: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

中国科学院大连化学物理研究所Dalian Institute of Chemical Physics, CAS中国科学院大连化学物理研究所Dalian Institute of Chemical Physics, CAS

Dalian1hr from BeijingDalianDalian

1hr from Beijing1hr from Beijing

Page 4: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

STRUCTURE:

Merit-based Academic Divisions:

Members: 700 inc.35 Foreign Members

Comprehensive National Research Institution:

90 Institutes, 1 University 1 Postgraduate SchoolTotal Staff : 50,000

STRUCTURE:STRUCTURE:

Merit-based Academic Divisions:

Members: 700 inc.35 Foreign Members

Comprehensive National Research Institution:

90 Institutes, 1 University 1 Postgraduate SchoolTotal Staff : 50,000

MISSIONS:

Scientific ResearchHigh Technology DevelopmentEducation and TrainingThink Tank of Science Policies

MISSIONS:

Scientific ResearchHigh Technology DevelopmentEducation and TrainingThink Tank of Science Policies

About the Chinese Academy of SciencesAbout the Chinese Academy of Sciences

Page 5: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

中国科学院大连化学物理研究所Dalian Institute of Chemical Physics, CAS中国科学院大连化学物理研究所Dalian Institute of Chemical Physics, CAS

Founded in 1949Founded in 1949Founded in 1949

Industrial Chem. Inst in 1952Industrial Chem. Inst in 1952Industrial Chem. Inst in 1952

Petroleum Inst. Of CAS in 1954Petroleum Inst. Of CAS in 1954Petroleum Inst. Of CAS in 1954

DICP of CAS in 1962DICP of CAS in 1962DICP of CAS in 1962

Spin-off:Lanzhou Inst.Shanxi Inst.No. 42 Inst.

SpinSpin--offoff::Lanzhou Inst.Lanzhou Inst.Shanxi Inst.Shanxi Inst.No. 42 Inst.No. 42 Inst.

Page 6: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

12 67150

174

8252

793

Academ.Pr of essorAssoc. Pr ofMi dd.Pr i m.Post doc.St udent s

Staff Members Staff Members Staff Members

227 254 254 295289390

476 498516

644730

793

0

200

400

600

800

1000

2002 2003 2004 2005

硕士博士合计

Graduate StudentsGraduate StudentsGraduate Students

51 Research Groups and Teams1500 Researchers

51 Research Groups and Teams51 Research Groups and Teams1500 Researchers1500 Researchers

Dimensions of Dalian InstituteDimensions of Dalian InstituteDimensions of Dalian Institute

Page 7: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Research Organizations of DICPResearch Organizations of DICP

National KeyProjects

Laboratory of Fuel CellLaboratory of Chemical LasersLaboratory of Materials

Applied Research

Applied Applied ResearchResearch

Laboratory of Analytical ChemistryLaboratory of Fine Chemicals

Laboratory of Chemical Engineering Laboratory of Applied Catalysis

Division of Bio-Technology

Laboratory of Analytical ChemistryLaboratory of Analytical ChemistryLaboratory of Fine ChemicalsLaboratory of Fine Chemicals

Laboratory of Chemical Engineering Laboratory of Chemical Engineering Laboratory of Applied CatalysisLaboratory of Applied Catalysis

Division of BioDivision of Bio--TechnologyTechnology

BasicResearch

BasicBasicResearch Research

State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Catalysis State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Molecular Dynamics

Spin-off CompaniesPesticide Intermediates Membrane TechnologyChromatographerFuel Cell Catalyst

SpinSpin--off Companiesoff CompaniesPesticide Intermediates Pesticide Intermediates Membrane TechnologyMembrane TechnologyChromatographerChromatographerFuel Cell Fuel Cell CatalystCatalyst

Page 8: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Fundamental Researches at DICP Fundamental Researches at DICP

H + D2

Ag on Si(111)7x7 and Al/Si(111) γ phase

Science 2Nature 1Agew. Chem 7JACS & PRL 11

Science 2Science 2Nature 1Nature 1AgewAgew. . ChemChem 77JACS & PRL 11JACS & PRL 11

1 National Science Award

2 National Invention Award

1 National Science Award1 National Science Award

2 National Invention Award2 National Invention Award

Page 9: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Quantized Transition States

Nature Nature ((20022002))Science (2003)Science (2003)

PRLPRL((20042004、、20052005))Int. Rev. Phys. Chem.(2004)Int. Rev. Phys. Chem.(2004)

Fundamental Researches in DICP Fundamental Researches in DICP

Science, March 2006

Page 10: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Sustainable Energy Resources Optimal UtilizationBio-Technologies

Sustainable Energy Resources Optimal UtilizationBio-Technologies

Applied Researches in DICP Applied Researches in DICP

Page 11: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Optimal Utilization of Natural GasOptimal Utilization of Natural Gas−− Production of Production of SyngasSyngas via Lowvia Low--cost Processcost Process−− SyngasSyngas Chemistry including FT and Oxygenate Synthesis Chemistry including FT and Oxygenate Synthesis −− Direct conversion of MethaneDirect conversion of Methane

Hydrogen EnergyHydrogen Energy−− Hydrogen Production from Natural Gas, Lower Alkanes Hydrogen Production from Natural Gas, Lower Alkanes

and and ResidResid as well as Methanol as well as Methanol −− Hydrogen Production via BioHydrogen Production via Bio--technology technology −− Separation of Hydrogen from Carbon Monoxide and Separation of Hydrogen from Carbon Monoxide and

Carbon Dioxide by membranesCarbon Dioxide by membranes

Fuel CellFuel Cell−− ProtonProton--Exchange Membrane Fuel Cell (PEMFC)Exchange Membrane Fuel Cell (PEMFC)−− Solid Oxide Fuel Cell (SOFC)Solid Oxide Fuel Cell (SOFC)−− Direct Methanol Fuel Cell (DMFC)Direct Methanol Fuel Cell (DMFC)−− Micro Fuel Cell and Micro SensorsMicro Fuel Cell and Micro Sensors

Energy Researches in DICPEnergy Researches in DICP

Page 12: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

S resistant

OxygenOxygen

H2

WGS

PSAMembrane

Air

Key Techniques to PolygenerationKey Techniques to Polygeneration

PSAPSAMembraneMembrane

AirAir

CleaningCleaningGasifierGasifier ChemicalChemicalSynthesisSynthesis TurbineGenerator/

SOFC

MethanolDieselOlefinsEthanol

MethanolMethanolDieselDieselOlefinsOlefinsEthanol Ethanol

SeparationStorageFuel Cell

SeparationSeparationStorageStorageFuel CellFuel Cell

氧气

H2

H2

Page 13: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Resources Resources Resources

GasGasMethaneMethane

芳烃和氢芳烃和氢Benzene、H2

含氧化合物含氧化合物Alcohols, Ethers,

ProductsProducts

油油 品品Gasoline、Diesel

Fuel CellFuel CellSOFCSOFC

H2H2 COCO22Cap.Cap.

SyngasSyngas

Utilization of Natural Gas & CoalUtilization of Natural Gas & Coal

烯烯 烃烃Ethylene, Propylene

MethanolMethanol

Coal/Bio-Future ?

Coal/BioCoal/Bio--Future Future ??

Page 14: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

SyngasCoal-basedSyngas

Coal-basedFeFe

Gasoline 、Diesel

Gasoline 、Diesel

ICC。。。ICC。。。

SyngasGas-basedSyngasGas-based

CoCoDiesel、Waxes

Diesel、Waxes

DICPSinopecDICPSinopec

3000 tons/yr3000 tons/yr

Gas to Liquid (GTL)Gas to Liquid (GTL)Gas to Liquid (GTL)

Pilot test in NingboPilot test in Ningbo

Page 15: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

C2 Oxygenates from SyngasC2 Oxygenates from C2 Oxygenates from SyngasSyngas

CO + H2C2Oxygenates

EtOH

AcOOEt

AcOOH

Hydrogenation

OxygenationCO Conv. 56.4%

Selec. 73.5 wt%

Coal & GasCoal & Gas

Economic.(BP) :Present Tech. 2500~2800 RMB/ton Eth.Economic.Economic.((BPBP)) ::Present Tech. 2500Present Tech. 2500~~2800 RMB/ton Eth.2800 RMB/ton Eth.

Page 16: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

The unique pore size allows the selective conversion to olefins

and excludes heavier compounds

3.8 Angstroms

0%

40%

80%

0.75 1.00 1.25 1.50

Ethylene / Propylene Ratio

Wt.%

Yie

ld (C

arbo

n B

asis

)

C2= + C3=

C3= C2=

Methanol to Olefins Methanol to Olefins (MTO)(MTO)

Page 17: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Pilot and Demo of the MTO processPilot and Demo of the MTO processPilot and Demo of the MTO process

Shanxi Coal Company Shanxi Coal Company (( 86million RMB86million RMB))Sinopec Sinopec LeyangLeyang Eng. Comp.Eng. Comp.((Tech Design Tech Design ))DICP DICP ((Catalyst & ProcessCatalyst & Process))

乙烯+丙烯

乙烯

丙烯

转化率

反应温度

10

20

30

40

50

60

70

80

90

100

12:43

16:00

18:30

20:30

22:301:0

04:0

08:0

012

:0014

:0016

:3018

:0021

:3023:3

0 2

:304:00

5:30

7:4513

:0016

:0022

:001:00

10:00

11:30

14:15

18:230:0

06:0

08:3

511:3

013

:3016

:0018

:3021

:302:00

3:03

6:00

9:00

13:00

16:20

23:00

2:30

9:00

11:00

13:15

14:45

16:30

18:30

21:002:0

05:0

08:3

013

:00

日期、时间

转化

率、

选择

性(

%)

320

370

420

470

520

570

620

温度

(C

完全再生

不完全再生(改变O2)

Page 18: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

((DirectDirect))

DimethylDimethyl Ether (DME) and its Manufacture Ether (DME) and its Manufacture

O

C

CH

HH

HHHDEM

Coal & Gas (CH4)

CH

HH

H CO

HHH2

SyngasSyngasSyngas

(Dehydro)((DehydroDehydro))

OCH

HH

H

Methanol (CH3OH)

CO((IndirectIndirect))

熔 点 (℃) -141 气化热(-20℃,KJ/Kg) 410.2

沸 点 (0.1Mpa,℃) -24.8 自燃温度(℃) 235临界压力(MPa) 5.37 临界温度(℃) 126.9临界密度(Kg/m3) 0.271 爆炸极限(℃) -41相对密度 1.59 燃烧热(MJ/Kg) 31.75密度(0.5Mpa时,Kg/m3) 670 生成热(KJ/mol) -183

Page 19: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

“Poly-DME-DMM” _Diesel Substitution““PolyPoly--DMEDME--DMMDMM”” __Diesel SubstitutionDiesel Substitution

42 105 152-315

0 <24 65

28 41 76

DMM DMM2 DMM3-8

BP, oF

Flash Pt., oF

Cetane No.

Dimethoxymethane(DMM)

Dimethyldioxymethylene(DMM2)

Poly-Dimethoxymethane(DMMx)

DME

• Most suitable DME analog

• Can be blended with diesel without engine modifications

• Low emissions in engine testing

• Made from methanol, DME and formaldehyde via low temperature catalytic distillation reactor with acidic catalyst

DMMDMM33--88

Page 20: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Development of PE Fuel CellDevelopment of PE Fuel CellDevelopment of PE Fuel Cell

2000

2002

2003.8

2003.10

150kwH2/Air

30KWH2/O2

75KWH2/Air

90KWH2/Air

100KWH2/Air

100KWH2/Air

2003.12

2004

FUEL CELL ENGINEFUEL CELL ENGINE

Page 21: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Hydrogen Related Researches in DICPHydrogen Related Researches in DICPHydrogen Related Researches in DICP

TransformationTransformationTransformation UtilizationUtilizationUtilization

StorageStorageStorage

DistributionDistributionDistribution

ManufactureManufactureManufacture

CO2 Sequest.COCO2 2 SequestSequest..

Risk evaluationFundamental research, DICP

Risk evaluationRisk evaluationFundamental research,Fundamental research, DICPDICP

Metal hydrides, Shanghai, BeijingCarbon nanotube, Shenyang

Metal polymer, DICP

Metal hydrides,Metal hydrides, Shanghai, BeijingShanghai, BeijingCarbon Carbon nanotubenanotube,, ShenyangShenyang

Metal polymer,Metal polymer, DICPDICP

Reforming of Methane, Methanol

Gasoline, Diesel DICP

Reforming of Reforming of Methane, Methanol Methane, Methanol

Gasoline, Diesel Gasoline, Diesel DICPDICP

Electric vehiclePortable power

Distributed power stationDICP, Shengli

Tsinghua, Tongji

Electric vehicleElectric vehiclePortable Portable ppowerower

Distributed Distributed power stationpower stationDICP, DICP, ShengliShengli

Tsinghua, Tsinghua, TongjiTongji

Fuel cellCombustionDICP, Shengli

Beijing companies

Fuel cellFuel cellCombustionCombustionDICP, DICP, ShengliShengli

Beijing Beijing companiescompanies

No current research activityNo current research activityNo current research activity

Page 22: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Strategy of Bio-Technology in DICP Strategy of Bio-Technology in DICP

Platform of System Biology

Proteomics

Metabonomics

Interomics(action)

Platform of System BiologyPlatform of System Biology

ProteomicsProteomics

MetabonomicsMetabonomics

Interomics(actionInteromics(action))

Cell TherapyStem Cell Eng.

Controlling Deliver

Cell TherapyCell TherapyStem Cell Eng.Stem Cell Eng.

Controlling Deliver Controlling Deliver

Drug & TargetsChem. Fingerprints

Bio. Fingerprints

Drug & TargetsDrug & TargetsChem. FingerprintsChem. Fingerprints

Bio. FingerprintsBio. Fingerprints

BioMass Conv.

Methane Activ.

Alga Energy

BioMassBioMass ConvConv..

Methane Methane ActivActiv..

Alga EnergyAlga Energy

Bio-MaterialsBioBio--MaterialsMaterialsIndu. BioTechInduIndu. . BioTechBioTechChinese Med.Chinese Med.Chinese Med.

Protein with DNAProtein with DNA

Protein with RNAProtein with RNA

Protein with ProteinProtein with Protein

Protein with Metabolic Protein with Metabolic ProductsProducts

GCGC--MSMS--LCLC--NMRNMR

Fingerprint of Meta. Prod.Fingerprint of Meta. Prod.

Meta. Controlling & NetworksMeta. Controlling & Networks

MetabonomicsMetabonomics

Page 23: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

BiomassResidue HarvestingEnergy Crops

Sugar PlatformEnzymatic HydrolysisLignin Products

Thermochem. Platform

PyrolysisGasification

ProductsFuels, chemicalsMaterialsHeat & Power

Biorefineries

1MW BGPG Power Plant from CAS1MW BGPG Power Plant from CAS

Biodiesel from CASBiodiesel from CAS

Biomass Utilization at DICPBiomass Utilization at DICP

Cat..

Page 24: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Dalian National Lab of Clean EnergyDalian National Lab of Clean EnergyDalian National Lab of Clean Energy

National Eng. Cent.National Eng. Cent.National Eng. Cent.

State Key Lab.State Key Lab.State Key Lab.

Research Cent of DICPResearch Cent of DICPResearch Cent of DICP

Oil & Gas Conver.Oil & Gas Oil & Gas ConverConver..

Fuel Cell & hydrogenFuel Cell & hydrogenFuel Cell & hydrogen

Bio-EnergyBioBio--EnergyEnergy

Solar EnergySolar EnergySolar Energy

Energy EnvironmentEnergy EnvironmentEnergy Environment

Strategic & evalu.Strategic & Strategic & evaluevalu..

Energy FundamentEnergy FundamentEnergy Fundament

Energy Demo

SINOPEC、BP、Gov.

Energy DemoEnergy Demo

SINOPECSINOPEC、、BPBP、、Gov.Gov.

International Co.

BP、CNRS、BASF

International Co. International Co.

BPBP、、CNRSCNRS、、BASFBASF

SinopecSinopecSinopec

PetroChinaPetroChinaPetroChina

Gov. ProgramGov. ProgramGov. Program

Enterprises Enterprises Enterprises

FoundationFoundationFoundation

Page 25: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Catalysis researches at DICPCatalysis researches at DICP

National KeyProjects

Laboratory of Fuel CellLaboratory of Chemical LasersLaboratory of Materials

Applied Research

Applied Applied ResearchResearch

Laboratory of Analytical ChemistryLaboratory of Fine Chemicals

Laboratory of Chemical EngineeringLaboratory of Applied Catalysis

Division of Bio-Technology

Laboratory of Analytical ChemistryLaboratory of Analytical ChemistryLaboratory of Fine ChemicalsLaboratory of Fine Chemicals

Laboratory of Chemical EngineeringLaboratory of Chemical EngineeringLaboratory of Applied CatalysisLaboratory of Applied Catalysis

Division of BioDivision of Bio--TechnologyTechnology

BasicResearch

BasicBasicResearch Research

State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Catalysis State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Molecular Dynamics

Page 26: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

InternationalAdvisory

Committee

Director of SKLCProf. Can Li

Academic CommitteeChair: Prof. Michel Che

Co-chairs: Prof. Mingyuan HeProf. Xinhe Bao

Catalytic ChemistryProf. Wenjie Shen

Nano & interfacial CatalysisProf. Xinhe Bao

Molecular Catalysis & In-situ StudiesProf. Can Li

Membrane Catalysis& Catalytic MaterialsProf. Weishen Yang

Organo-InorganicCatalytic MaterialsProf. Qihua Yang

Theoretical CatalysisProf. Weixue Li

Laboratory for Environmental Catalysis and TechnologyLaboratory for Applied Catalysis and Natural Gas ConversionLaboratory for Fine ChemicalsNational Center for Catalytic Technology Development

Cooperated with applied research labs.

the State Key Laboratory of Catalysis (SKLC)the State Key Laboratory of Catalysis (SKLC)the State Key Laboratory of Catalysis (SKLC)

Page 27: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

•• Energy CatalysisEnergy CatalysisFuel Cell, Hydrogen production, C1 Chemistry, PhotocatalysisFuel Cell, Hydrogen production, C1 Chemistry, Photocatalysis, ,

•• Environmental CatalysisEnvironmental CatalysisNOxNOx redutionredution, VOCs oxidation and , VOCs oxidation and ultraultra--deep desulfurization and denitrogenationdeep desulfurization and denitrogenation

•• Catalysis for Fine Chemicals and Chiral Products Catalysis for Fine Chemicals and Chiral Products Asymmetric synthesis, selective oxidation and hydrogenationAsymmetric synthesis, selective oxidation and hydrogenation

•• Nanocatalysis and Advanced Catalytic MaterialsNanocatalysis and Advanced Catalytic MaterialsAu, Ag and noble metals, CO oxidationAu, Ag and noble metals, CO oxidation

•• InIn--situ, dynamic, timesitu, dynamic, time--resolved characterizationsresolved characterizations•• Theoretical catalysisTheoretical catalysis

The present research Activities

Page 28: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Catalyst Characterizations

In-situ characterization FT-IR, NMR, UV Raman, Laser Raman, TPSR, TGA-DTA, ...

Dynamics and kinetics PEEM, Time-resolved Spectroscopy, LISF, TPD-Mass,, ...

Structures of real catalysts XRD, SEM, TEM, EDX, BET, ...

Atomic, molecular and nano scale Multi Nano-Probe, HREELS, XPS, AES, LEED,

Page 29: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

UV Resonance Raman Spectroscopic Studies on Catalysis

UV Resonance Raman Spectroscopic UV Resonance Raman Spectroscopic Studies on CatalysisStudies on Catalysis

hv Raman Spectra

Achievements: Example 1

Page 30: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Non-oxidative Aromatization of Methane NonNon--oxidative Aromatization of Methane oxidative Aromatization of Methane

6CH6CH4 Ben + 9H24 Ben + 9H2Mo/ZSM-5Mo/ZSM-5

chemicalschemicalschemicalsEng.Eng.Eng.

02468

101214

1993 1999 2001 2003

芳烃收率

Page 31: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Oxygen Production:100%oxygen permeation selectivity

High oxygen permeation

Continuous production of oxygen.

Applications of Mixed Ion & Electron Applications of Mixed Ion & Electron Conductivity Oxygen Permeable MembraneConductivity Oxygen Permeable Membrane

Air (O2+N2)

Oxygen depleted N2

O2

MIECM

制氧Oxygen production

烃类的部分氧化Partial oxidation of hydrocarbons

甲烷氧化耦联Oxidative coupling of methane

烃类的氧化脱氢Oxidative dehydrogenation of hydrocarbons

Dense ceramic Dense ceramic membrane with membrane with mixed oxygen mixed oxygen

ionic and ionic and electronic electronic

conductivityconductivity

烃类的选择氧化Selective oxidation of hydrocarbons

Membrane Reactor:Combining reaction and air separation into a reactor

Increasing yield and selectivity by controlling oxygen species

Being energy efficient and relatively safe to operate

Avoiding formation of hot spots

Achievements: Example 3

Page 32: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Applied, 37%

MOST, 20%

NSFC, 16%Fund for S

KL12

%

CAS, 15%

Composition of the Research ProjectsComposition of the Research ProjectsComposition of the Research Projects

Applied, 37%Fundamental, ~ 63%

MOST: Ministry of Sci. & Tech.CAS: Chinese Academy of Sciences

Page 33: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Budgets for Research in past yearsBudgets for Research in past yearsBudgets for Research in past yearsMi

ll ion

1999 2000 200320022001

16

471013

1922

2004 2005

Page 34: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

Scientific bases for renewable energy, environmental begin, human health and better life, and optimized utilization of resources Design and synthesis of more active and selective catalysts including based nano materialsEssential correlation through heterogeneous, homogeneous and enzymatic catalysis. Biocatalysis may play more and more role insynthesis chemistry.In-situ, dynamic, spatial and time-resolved characterization together with theoretical calculation may eventually reveal the nature ofcatalysis and make catalysis a scienceCatalysts with desired functions could be designed and synthesized based on the fundamental understanding

Researches to be focused

Page 35: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

DICP’s Activities in International Collaboration

DICPDICP’’ss Activities in International Activities in International CollaborationCollaboration

Page 36: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

DICPDICP

Dispatch and Acceptance Dispatch and Acceptance of Researchersof Researchers

Domestic and oversea Domestic and oversea OrganizationsOrganizations

Contract ResearchesContract Researches

Domestic and oversea Domestic and oversea Enterprises Enterprises

Joint ProjectsJoint Projects

Domestic and oversea Domestic and oversea EnterprisesEnterprises

Joint Research CentersJoint Research Centers

Universities and EnterprisesUniversities and EnterprisesGovernment OrganizationsGovernment Organizations

Research Collaboration in DICP Research Collaboration in DICP Research Collaboration in DICP

Page 37: Introduction of the Dalian Institute of Chemical Physics ... · Dalian Institute of Chemical Physics, CASDalian Institute of Chemical Physics, CAS Founded in 1949Founded in 1949 Industrial

International and National Research International and National Research Organizations at DICPOrganizations at DICP

National Eng. Center

National Eng. National Eng. CenterCenter

Membrane Sci. & Tech. CatalysisHydrogen and Fuel Cell

Membrane Membrane SciSci. & Tech. . & Tech. CatalysisCatalysisHydrogen and Fuel CellHydrogen and Fuel Cell

International Joint Labs

International International Joint Labs Joint Labs

China-France Joint Lab. on Catalysis

CAS-BP Energy Innovation Laboratory (EIL)

CAS-MPG Partner Groups

DICP-Sumsung Joint Lab. on Fuel Cell

DICP-Lilly Program on Analysis and Fine Chemicals

ChinaChina--France Joint Lab. on CatalysisFrance Joint Lab. on Catalysis

CASCAS--BP BP Energy Innovation Laboratory (EIL)Energy Innovation Laboratory (EIL)

CASCAS--MPG Partner GroupsMPG Partner Groups

DICPDICP--SumsungSumsung Joint Lab. on Fuel CellJoint Lab. on Fuel Cell

DICPDICP--Lilly Program on Analysis and Fine ChemicalsLilly Program on Analysis and Fine Chemicals

State KeyLaboratory

State KeyState KeyLaboratoryLaboratory

State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Catalysis State Key Laboratory of Catalysis State Key Laboratory of Molecular DynamicsState Key Laboratory of Molecular Dynamics

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Collaboration with the Organizations in EuropeCollaboration with the Organizations in Europe

Joint Lab of Catalysis with CNRS

Joint Lab of Catalysis with CNRS

Metabolomics for Traditional Chinese Medicine

Catalysis

Metabolomics for Traditional Chinese Medicine

Catalysis

MPG-CAS Partner Group

DFG-NSFC Fuel Cell Program

DICP-BASF INCON project

DICP-Bayer Project

MPG-CAS Partner Group

DFG-NSFC Fuel Cell Program

DICP-BASF INCON project

DICP-Bayer Project

CAS-BP Clean Energy Program

DICP-Cambridge Training Project

CAS-BP Clean Energy Program

DICP-Cambridge Training Project

Gene Technique with Uni. of Aarhus

Oligosaccharides with TCM-denmark

Gene Technique with Uni. of Aarhus

Oligosaccharides with TCM-denmark

PEM Fuel Cell with Lund Institute of Technology

Sino-Swedish Workshop on FC

PEM Fuel Cell with Lund Institute of Technology

Sino-Swedish Workshop on FC

Fuel Cell Testing, Safety and Quality AssuranceCarbon Dioxide Capture via Hydrogen Energy TechnologySOFC Stack Technology for Operation at 600℃

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THE PARTNERSHIP FOR INTERNATIONAL RESEARCH AND EDUCATION AT THE UNIVERSITY OF CALIFORNIA

ELECTRON CHEMISTRY AND CATALYSIS ELECTRON CHEMISTRY AND CATALYSIS

AT INTERFACESAT INTERFACES

Alec M. Wodtke, DirectorDepartment of Chemistry and BiochemistrySanta Barbara, CA 93106-9510Phone: (805) 893-8085Fax: (805) 893-4120E-mail: [email protected]

Xueming Yang, Foreign Program CoordinatorState Key Laboratory for Chemical Reaction DynamicsDalian Institute of Chemical Physics457 Zhongshan Rd.Dalian, Liaoning 116023, P. R. ChinaE-mail: [email protected]

Cooperation Partner between UCSB and DICP Cooperation Partner between UCSB and DICP Supported by NSFSupported by NSF

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Special funds for international cooperation and exchange

(1 million RMB per year for travel and accommodation, i.e. student, postdoctoral researcher )

Special funds for scientific symposia in DICP(1 million RMB per year for scientific program & costs)

Open grants and projects for joint research

Special funds for international cooperation and exchange

(1 million RMB per year for travel and accommodation, i.e. student, postdoctoral researcher )

Special funds for scientific symposia in DICP(1 million RMB per year for scientific program & costs)

Open grants and projects for joint research

To Enhance Comprehensive Cooperation at DICP

To Enhance Comprehensive Cooperation at To Enhance Comprehensive Cooperation at DICP DICP

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DICP Symposium ( I ) on Catalysis Future directions of catalysis science and technology, (October 16-18, 2003)

DICP Symposium (Ⅱ) on Marine Biotechnology, (October 15-16 2003)

DICP Symposium (III) on Science & Technology of Nano-Catalysis, (May 26-27, 2004)

DICP Symposium (IV) on Molecular Dynamics (July 20-23, 2004)

DICP Symposium (V) on Microscale Separation and Analysis, (December 12-15, 2004)

DICP Symposium (VI) on Separation and Detection of Biomolecules, (August 12-15, 2004)

DICP Symposium (VII) on Modern Separation / Analytical Chemistry

and Metabonomics (April 19-20, 2005)

DICP Symposium (VIII) on Separation and

Detection of Bio-Molecules (July 28-29,2005)

DICP Symposium (V) on Chemical Physics of

Materials (June 1-3, 2006)

DICP SymposiumDICP SymposiumDICP Symposium

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Thank for AttentionThank for Attention

Welcome to DICPWelcome to DICP