ion exchange resins - · pdf file© 2007 rohm and haas company ier1 ion exchange resins...
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© 2007 Rohm and Haas Company IER1
ION EXCHANGE RESINS
Boiler feed waterDrinking water: removal of contaminantsRadioactive waste cleaningUltra-pure water for semiconductorsWaste treatment: recovery of metalsFood and beverage processingPharmaceuticals
© 2007 Rohm and Haas Company IER2
Resins
Uniform particle sizeAmberjet™
Standard particle sizeAmberlite™
Various polymersStyrenicAcrylicPhenolic
Different matricesGel typeMacroporous
Amberjet 4400
Amberlite IRA67
© 2007 Rohm and Haas Company IER3
Applications
Water treatment
Special applications
Industrial water treatmentBoiler feed water Nuclear powerCondensateRadioactive wasteUltra-pure waterDrinking waterHousehold softeningWaste water
CatalystsSeparationsPurificationsNutritionPharmacyBiotechnologies
© 2007 Rohm and Haas Company IER4
Industrial water treatment
Softening
Demineralisation
Mixed bed polishing
ADI standard plant
© 2007 Rohm and Haas Company IER5
Demineralisation
Boiler feed water withAmberjet resins
Quality0.1 to 1 µS/cmbefore polishing0.055 to 0.1 µS/cmafter polishing
© 2007 Rohm and Haas Company IER6
Amberpack™
Reverse flow regenerationtechnology
Compact systemEasy regenerationVery little waste98 % water recovery99.95 % salt rejectionHundreds of plants in service
© 2007 Rohm and Haas Company IER7
Advanced Amberpack™
With fractal distributionADI 60: 60 m3/h demineralisationADN for nitrate removalCompact and modular
ADI 60
© 2007 Rohm and Haas Company IER8
Polishing
After RO
After primary demin
After flash evaporation
Condensate polishing
Mixed bed technologyAmberjet resins
Amberpack Sandwich™No mixing, no backwash
Freeboard Collector
Feedwater
Treated water
Resin 1
Resin 2
Amberpack Sandwich
© 2007 Rohm and Haas Company IER9
Demineralisation
Mixed bed for electro-erosion machinesSpecial resin for this application onlyReady for useAmberlite MB9L
© 2007 Rohm and Haas Company IER10
Power
Boiler make-up water
Condensate polishing
Primary circuit
Secondary circuit
Radioactive waste treatment
Fuel storage pond
Nuclear and fossil-fuelled stations (EdF etc.)
© 2007 Rohm and Haas Company IER11
Condensate polishing
Unique resin combination:Amberjet 1500 + Ambersep 900
StableClean High ammonia capacityExcellent separability
© 2007 Rohm and Haas Company IER12
Household softening
Large and small producers of softeners use
Amberlite SR1LNaImac™ HP1110Na
Approved by French Health Authorityand many other authorities
In Europe, all dishwashers are equipped with a small softener using a resin like
Amberlite IR120FF Na
© 2007 Rohm and Haas Company IER13
Drinking water
• Point of useA growing market withImac HP333
Hardness removal cartridgesImac HP555
Selective nitrate removal
© 2007 Rohm and Haas Company IER14
Drinking water
• MunicipalAmberlite PWA5
Nitrate removalAmberlite PWA10
Boron removalAmberlite PWA2
Perchlorate removal
Advanced Amberpack™ADN in the UK
© 2007 Rohm and Haas Company IER15
Desalination
Boron removal after ROAmberlite PWA10Totally selective resinRemoves B only0.1 mg/L residual B99% + water recovery
Boron removal in Kziot
© 2007 Rohm and Haas Company IER16
Ultra-pure water
Amberjet UP and Amberlite UPdeveloped specifically for the semiconductor industry
Minor impurities in the water used for the production of wafers can create short-circuits and make the product unusable
Amberjet UP6040used in the final mixed bed polisher
It brings the last impurities down to ng/L (ppt) levels.
© 2007 Rohm and Haas Company IER17
Waste water solutions
Soil reclamationHeavy metals removal (Hg, Cd)
Ambersep GT74Amberlite IRC748
Removal of phenolAmberlite XAD4
Ammonium nitrate recoveryFertilizer plants
© 2007 Rohm and Haas Company IER18
Catalysis using ion exchange resins
Amberlyst 31, 131 & 121main catalysts used for Bisphenol A, one of the components of polycarbonate and epoxy resins.
Amberlyst 15Dry & 36DryFor the production of alkylphenols used in detergent formulations
Amberlyst 35catalyst used in the synthesis of octane improvers (petrol additives) such as MTBE, ETBE, TAME & iso-octane
© 2007 Rohm and Haas Company IER19
Chemical separations
Uranium miningAmberjet™ 4400 & Ambersep™ 920U
Soil reclamationHeavy metals removal (Hg, Cd)
Ambersep GT74Amberlite IRC748
Removal of phenolAmberlite XAD4
Ammonium nitrate recoveryFertilizer plants
PurificationsPhenolGlycolFormaldehyde
© 2007 Rohm and Haas Company IER20
Chemical separations (2)
Boron removalFrom magnesium brine
Amberlite IRA743
Calcium removal from brineChlor-alkali industry
Amberlite IRC747
Biodiesel purificationRemoval of potassium and sodium
Amberlite BD10Dry
© 2007 Rohm and Haas Company IER21
Metals
Many applicationsRinse water from plating bathsRecovery of metal catalystsChromic acid recyclingPickling baths recyclingRemoval of iron from chromic acidMetal catalyst recovery in plastics productionRecovery of gold from plating solutionsRecovery of silver
© 2007 Rohm and Haas Company IER22
Sugar & sweeteners
Calcium removal from beet juiceAmberlite FPC14 Na
De-ashing of liquid sugarAmberlite FPC22 H and FPA53
Colour removal from cane juiceAmberlite FPA98 Cl and FPA90 Cl
Purification of sweetenersGlucose, fructose, maltosePolyols
Chromatographic separationsAmberlite CR1310 & CR1320
High fructose syrup
© 2007 Rohm and Haas Company IER23
Beverages
Orange juice debitteringAmberlite FPX66
Water for breweriesDe-alkalisation, partial deionisation
Amberlite PWC13
Water for soft drinksRemoval of colour and natural organics
Amberlite PWA9
© 2007 Rohm and Haas Company IER24
Pharmaceutical applications
Resins as active ingredientsDuolite AP143 = cholestyramine
Blood cholesterol control
Amberlite IRP69 = sodium polystyrene sulphonate
Reduces blood potassium level
Resins as drug excipientsART (advanced release technologies)
A series of technologies and products– Tablet disintegrants– Taste-masking– Slow release
Amberlite IRP64Taste maskingControlled release of drugsNicotine loaded chewing gums
© 2007 Rohm and Haas Company IER25
Biotechnologies
Amberlite CobalamionPurification of Vitamin B 12 from fermentation broths
Amberlite XAD1600Non-ionic adsorbentSeparation of two or more similar species Production & purification of antibiotics
Amberzyme™ OxiraneEnzyme immobilisation
Amberchrom™ CG & XTAdsorptionReversed phase liquid chromatography Purification of proteins and peptides