ion exchange resins product list - samyangtrilite.com · rate per apparent volume and less swelling...

No.1 Water Treatment Total Solution Provider

Ion Exchange Resins

Product List

3Ion Exchange Resins Product List

Samyang Corporation is the history of Ion Exchange Resins in Korea

In 1976, Samyang Corporation successfully

initiated localized production of IER in

South Korea by technical cooperation with

Mitsubishi Chemical Corporation, Japan.

In 2011, with successful development of

UPW (Ultrapure water grade) resins, we

are contributing to enhancing national

competitiveness in semiconductor/LCD

industries. In 2016, Asia's largest UPS (Uniform

Particle Sized) specialized IER (Ion exchange

resin) plant; Samyang Fine Technology

Corporation was founded. TRILITE is being

supplied to the global market and is receiving

rave reviews from the users.

No.1 Total Solution Provider

Samyang Corporation presents the full line-up of TRILITE Ion Exchange Resins from water treatment up to specialty

applications. Samyang develops Tailored resins optimized for customer needs, and provides differentiated

technical services such as on-site visit for trouble shooting, technical seminars, process diagnosis and design

consulting, etc. Also, Samyang R&D center offers various analysis services for IERs, and develops advanced

application technologies.

Locations (HQ, Plant, R&D Center of TRILITE)

Seoul(Head Office)

■ Technical sales force in 3 fields

- Demineralization/Ultrapure water

/Condensate polishing/Catalyst

- Food/Amino acids/Pharmaceuticals

- Wastewater/Chelating resins

/Purification

■ One Stop Service

- Analysis of IER

- Equipment diagnosis and design

support

- Technical seminars and

trouble shooting guides

Daejeon(R&D Center)

■ Analysis of IER

■ Recipe improvement of IER

■ New product development

- Tailored/Specialty resins

■ Application process

development

- Pilot test - Engineering data gathering - Process proposal

Gusan(UPS Resin Plant)

■ Samyang Fine Technology

(Joint venture with Mitsubishi

Chemicals)

■ Largest manufacturing capaicty

for UPS resins in Asia

■ Annual production capacity

- Cation 13,000㎘, Anion 7,000㎘

■ Product lines

- Uniform particle sized resins

- Chromatography resins

- Ultrapure water grade resins

(OLED, LCD application)

Ulsan (UPW/Tailored/Specialty

Resin Plant)

■ Technology licensed by

Mitsubishi Chemicals & Self-

development

■ Specialized production of

tailored resins

■ Production capacity

- Cation 3,500㎘, Anion 2,500㎘

■ Product line

- Ultrapure water grade for

semiconductor

- Tailored resins : food, catalyst,

pharmaceuticals

- Specialty resins: chelating resins,

synthetic adsorbents, refining of

chemicals

Samyang Corporation Ion Exchange Resin Team

TEL : +82 2 740 7732~6

E-mail : [email protected]

http://www.samyangtrilite.com

4 5Ion Exchange Resins Product List Ion Exchange Resins Product List

Uniformity of IER enlarges its Performance

TRILITE UPS resins are renowned in the industry for the consistent uniformity coefficient, which is directly

related to high performance. TRILITE UPS resins are manufactured by strict quality control to ensure optimized

size of the resins, enabling extremely even reactions. UPS resins give an extremely even exhaustion front

of resins in the vessel, hence the operating capacity is enhanced. Also, it has outstanding mechanical and

chemical stability, leading to remarkably low crush rate even after long-term use.

Samyang TRILITE represents Next Generation Ion Exchange Resin

TRILITE UPS resin has adopted state-of-the-art Droplet generating technology for polymerization, differentiated

from the prevailing mechanical sieving of polymers and conventional polymerization technology. Premium grade

TRILITE Ion Exchange Resins are manufactured from the newest UPS IER plant in the world. TRILITE satisfies high

quality standards; Uniformity coefficient of TRILITE is under 1.1 with high mechanical and chemical stability.

Higher Operating Capacity, Reduction of Rinse Volume

Longer Life Time of IER

Improved Kinetics, Fast Reaction Speed Excellent Physical & Chemical Strength+

(Raw Material Adjustment)

(Polymerization - Droplet Generator)

(Post-treatment – Functional group)

STM(Styrene Monomer)

DVB(Divinyl Benzene)

CH = CH₂ CH = CH₂

CH = CH₂

+

UPS(Uniform Particle sized) Technology

(Raw Material Adjustment)

(Polymerization - Agitation)

(Post-treatment – Functional group)

STM(Styrene Monomer)

DVB(Divinyl Benzene)

CH = CH₂ CH = CH₂

CH = CH₂

+

Conventional Technology

Gaussian resin gives diffused

exhaustion front

Gaussian Resin

UPS resin gives an extremely

even exhaustion front

UPS Resin

Next Generation IER, High Performance Low CostCutting-edge Technology Droplet Generator

(Packing)

60

50

40

30

20

10

0

UniformityCoefficient

1.1↓

200 400 600 800 1000

(Packing)

60

50

40

30

20

10

0200 400 600 800 1000

UniformityCoefficient 1.6↓

(%) (%)

(㎛) (㎛)

Lower Running Cost and Capital Expenditure

UPS Resin (Mixed)

Gaussian Resin (Mixed)

30

25

20

15

10

5

0

0 10 20 30 40 50 60 70 80 90 100 110 120

Co

nd

uc

tivi

ty

(㎲/㎝

)

Service Volume (Bed Volume)

25 50 75 100 125 150

1.5

1.3

1.1

0.9

0.7

Op

era

tin

g C

ap

ac

ity

(eq

/ℓ-R

esi

n)

Specific Flow Rate (SV)

UPS Resin (SAC)

Gaussian Resin (SAC)

6 Ion Exchange Resins Product List

SBA WBA

Classification of Ion Exchange Resin

SpecialtyAnion InertCation

SAC WACChelating

resins

Synthetic

adsorbents

For packed bed

system,

mixed bed polisher

Functional Group

Tailored Resin

UPS

(0.5 ~ 0.6mm)

Gaussian(L)

(0.425 ~ 1.2mm)

Chromatography

(0.2 ~ 0.3mm)

Particle Distribution, Size

Gaussian

(0.3 ~ 1.2mm)

Strongly acidic cation

Stronglybasic anion

Weakly acidic cation

Weaklybasic anion

Porous type

(Macropore)

Porosity

Gel type

(Micropore)

Micropore <100Å

Gel

Macropore 10Å<, <1000Å

Micropore

Water treatment · Softening / Demineralization

· Condensate polishing

· Nuclear power

Ultrapure water

Catalyst

Chromatography· Fructose / Glucose separation

· Amino acid separation / purification

· Acid purification

Food· Starch sugar refining

· Sugar refining

· Nucleic acid, Lysine separation /purification

Chelating resins· Secondary brine purification

· Wastewater treatment

Synthetic adsorbents

Ready to use mixed resins / Inert resins

Contents

Mixing, DryCatalystNucleic Acid,

Lysine, etcUPW

Crosslinkage

* Crosslinkage : Divinylbenzeze versus total monomers in weight/weight (%)

HighCrosslinkage

LowCrosslinkage


Classification by regeneration system

Co-current regeneration

system

Counter-current regeneration system

Water blocking system

Packed bed

Upflow system Downflow system

Gaussian Gaussian or L-type UPS IER

Service Regeneration

IER

FreeboardMiddle Distributor

IER

Freeboard

IER

FreeboardIER

Freeboard

Classification by IER layer

Single

bed

Layered

bed

Mixed

bed

SAC WAC SBA WBA

SAC

WAC

SBA

WBA

SAC

SBA

Typical power plant steam turbine loop and IER selection

Conden-sate

storage

SAC

SBA

Condensate polisher

Boiler

Reheater2nd

Superheater

1st Superheater

Evaporator Tube

Condenser

LP HeaterDeaeratorHP Heater

GeneratorLPTurbine

IPTurbine

HPTurbine

Raw waterMake-up demineralization system

SAC

WAC

SBA

WBA

SAC

SBADegasifier

Various types of water treatment systems (softening, demineralization) are adoptable according to the types

of IERs, service/ regeneration direction of solution and combination of IER towers. Appropriate system is

recommended under the conditions of raw water and required water quality.

TRILITE IER consists of the most efficient line-ups for various types of softening and demineralization of water. It

results in cost effective high performance of water treatment with remarkably high operating capacity and high

mechanical and chemical stability.

Ion exchange resins for power plant are classified by applications: Make-up system, condensate polishing and

primary circuit for nuclear power plant.

Various combinations of demineralization are adoptable for Make-up system for power plant. For condensate

polishing plant (CPP), premium IERs are required with high operating capacity, high operating temperature and

mechanical and chemical stability.

For primary circuit in nuclear power plant, IERs are exposed to radiation. Use of high crosslinkage IERs with low

impurities, high mechanical and chemical stability is highly recommended.

TRILITE IERs own various supply references to domestic and foreign power plants hence contributing to

competitive power supply for customers, with stable quality control and on time delivery of resins.

Condensate polisher

Pressurized water reactor type nuclear power plant steam turbine loop and IER selection

Conden-sate

storage

Storagetank

SAC

SBA

Containment structure

Condenser

LP Heater

DeaeratorHP

Heater

GeneratorLPTurbine

HPTurbine

Raw water

Make-up demineralization system

SAC

WAC

SBA

WBA

SAC

SBA

SAC

SBA

SAC

Degasifier

Steam generator

Nuclear reactor

Primary circuit

Secondary circuit

Nuclear Grade

Containmentstructure

Softening / Demineralization Power Plants

Demineralization system and IER selection

2B2T (2Beds 2Towers) Cation Exchanger + Anion Exchanger

MC-08

MC-10

MA-12

MA-20

2B3TCation Exchanger + Degasifier + Anion Exchanger

MC-08

MC-10

MA-12

MA-20

Working MB (Mixed Bed)

MA-12(P)

MA-20(P)MC-08

MC-10

2B2T+MBP(Mixed Bed Polisher)

MC-08

MC-10

MA-12

MA-20

MA-12(P)

MA-10(P)MC-08

MC-10

2B3T+MBPMC-08

MC-10

MA-12

MA-20

MA-12(P)

MA-10(P)MC-08

MC-10

3B3T+MBPMC-08

MC-10

AW90

AW30L

MA-12(P)

MA-10(P)MA-12

MA-20

MC-08

MC-10

4B3T+MBP

WCA10LAW90

AW30L

MA-12(P)

MA-10(P)MC-08

MC-10

MA-12

MA-20

MC-08

MC-10

4B3T+MBP+CPP(Condensate polishing)

WCA10LAW90

AW30L

MA-12(P)

MA-10(P)

MA-10OH

MA-15OHMC-08

MC-10

MA-12

MA-20

MC-08

MC-10

MC-10H

MC-14H

※ Anion+(P) means Anti-clumping treatment on Anion resins which is recommended for MB and MBP system.

SAC SBA

SAC

SBA

SAC SBASAC

SBA

SAC SBADegasifier

SAC SBASAC

SBADegasifier

SAC

WAC

SBA

WBA

SAC

SBADegasifier

SACSBA

WBA

SAC

SBADegasifier

SAC

WAC

SBA

WBA

SAC

SBA

SAC

SBADegasifier Condenser


Uniform Particle sized SAC Resins Gel type

Grade MC-04 MC-04H MC-08 MC-08H MC-10 MC-10H MC-14 MC-14H

Matrix Polystyrene＋DVB(Divinylbenzene)

Functional group -SO₃-(Sulfonate)

Ionic form Na+ H+ Na+ H+ Na+ H+ Na+ H+

Specific gravity※ 1.16 1.13 1.28 1.20 1.32 1.22 1.36 1.32

Shipping weight※(g/ℓ) 790 750 845 800 850 805 865 815

Moisture retention (%) 57~67 65~70 43~49 50~56 38~44 45~51 31~37 37~43

Total capacity (eq/ℓ) 1.3↑ 1.2↑ 2.0↑ 1.8↑ 2.2↑ 2.0↑ 2.5↑ 2.4↑

Uniformity coefficient 1.1↓

Average diameter (㎛) 500±50 500±30 600±50 620±50 650±50 660±50 650±50 650±50

Operating temp (℃) 120↓

Operating pH range 0∼14

Swelling rate※ (Na＋→H＋)

9% 9% 8% 7%

Remarks

Low

Crosslinkage

Standard

Crosslinkage

High

Crosslinkage

Very High

Crosslinkage

High crosslinkage resin features the high resistance against oxidizing agents, high exchange rate per apparent volume and less swelling rate. However, it adversely has less exchange rate for large molecules, less regeneration efficiency and vulnerable to organic fouling. Low crosslinkage resin features higher regeneration efficiency, high resistance against organic fouling, small change in swelling rate and fast reaction rate. However, it adversely has low exchange capacity and vulnerable to oxidizing agents.

※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.

Applications

TRILITE MC-04(H) TRILITE MC-04(H) is a low crosslinkage UPS SAC resin which features fast exchange

reaction. It is widely applied to various chemical reactions such as catalysitc application

(Bisphenol-A, etc), separation and refining of nucleic acid and amino acid, etc.

TRILITE MC-08(H) TRILITE MC-08(H) is a standard crosslinkage UPS SAC resin. With its excellent regeneration

efficiency and less rinse volume consumption, high purity water can be produced

economically. It has outstanding mechanical and chemical stability, leading to low crush

rate even after long-term use. It is widely used for softening, demineralization and other

applications such as lysine, sugar and catalyst reaction.

TRILITE MC-10(H) TRILITE MC-10(H) is a high crosslinkage UPS SAC resin which features outstanding

mechanical and chemical stability. It is widely used for premium water treatments such as

Condensate polishing and post treatment for ultrapure water.

TRILITE MC-14(H) TRILITE MC-14(H) is a very high crosslinkage UPS SAC resin. It has outstanding mechanical

and chemical stability. It is widely used for premium application where extremely high

exchange capacity is required such as Primary circuit in nuclear power plants and etc.

Applications

TRILITE MA-12(OH) TRILITE MA-12(OH) is an UPS SBA resin (Gel Type 1) with TMA as functional group. It is supplied

either in Cl or OH forms. It features higher SiO2 removal and less ion leakage. With the fast reaction

rate, it is widely used for various applications such as MBP(Mixed bed polisher) in demineralization,

UPW and noble metal recovery.

TRILITE MA-10(OH) TRILITE MA-10(OH) is a high crosslinkage UPS SBA resin (Gel Type 1) with TMA as functional group.

It features outstanding mechanical and chemical stability, SiO2 removal and less ion leakage. It is

widely applied to Condensate polishing.

TRILITE MA-15(OH) TRILITE MA-15(OH) is a very high crosslinkage UPS SBA exchange resin (Gel Type 1) with TMA as

functional group. It features outstanding mechanical and chemical stability. It is widely applied

to premium water treatment applications such as Anion exchanger for UPW and Condensate

polishing.

TRILITE MA-20 TRILITE MA-20 is an UPS SBA resin (Gel Type 2) with DMEA as functional group. It features very

high regeneration efficiency and operating capacity. It shows outstanding performance when

used in packed bed system and pre-treatment single bed for demineralization.

Uniform Particle sized SBA Resins Gel type

Type Type 1 Type 2

Grade MA-12 MA-12OH MA-10 MA-10OH MA-15 MA-15OH MA-20

Matrix Polystyrene＋DVB

Functional group -N＋(CH₃)₃ (TMA, Trimethylammonium)

-N＋(CH₃)₂C₂H₄OH (DMEA,

Dimethylethanol-ammonium)

Ionic form Cl- OH- Cl- OH- Cl- OH- Cl-

Specific gravity※ 1.08 1.07 1.08 1.07 1.08 1.08 1.11

Shipping weight※ (g/ℓ) 670 660 675 665 705 670 700

Moisture retention (%) 49~55 62~70 43~49 59~65 39~45 54~62 45~51

Total capacity (eq/ℓ) 1.3↑ 1.0↑ 1.35↑ 1.0↑ 1.4↑ 1.2↑ 1.3↑


Average diameter (㎛) 580±50 620±50 550±50 590±50 600±50 630±50 590±50

Operating temp (℃) 80↓ 60↓ 80↓ 60↓ 90↓ 70↓ 40↓ (OH- form)60↓ (Cl- form)


Swelling rate※

(Cl-→OH-)24% 23% 22% 14%

Remarks Low

Crosslinkage

Standard

Crosslinkage

High

Crosslinkage

Standard

Crosslinkage



Strongly Acidic Cation Exchange Resins / Gaussian Gel type

Grade SCR04 SCR-B SCR10 SCR12



Ionic form Na+

Specific gravity※ 1.16 1.29 1.32 1.34

Shipping weight※ (g/ℓ) 780 830 850 855

Moisture retention (%) 57~67 43~50 35~45 33~39

Total capacity (eq/ℓ) 1.2↑ 2.0↑ 2.2↑ 2.3↑

Effective size (㎛) 400↑


Particle size (㎛) 300~1,200 (on 1,180㎛ < 5%, through 300㎛ < 1%)



Swelling rate※ (Na＋→H＋)

8% 8% 7% 6%

Remarks Low

Crosslinkage

Standard

Crosslinkage

High

Crosslinkage

Very High

Crosslinkage


Applications

TRILITE SCR04 TRILITE SCR04 is a low crosslinkage Gaussian SAC resin. It features fast reaction rate, and is

widely applied to catalytic purpose (Bisphenonl-A, etc.), separation and refining of nucleic

acids with larger M.W.

TRILITE SCR-B TRILITE SCR-B is a standard crosslinkage Gaussian SAC resin. It is widely applied to water

treatment such as softening and demineralization and other applications such as refining of

sugar/ starch sugar, amino acids separation, dehydration of organic solvents and catalyst for

various chemical reactions.

TRILITE SCR10 TRILITE SCR10 is a high crosslinkage Gaussian SAC resin. With high stability against oxidizing

agents, it is widely used for demineralization and condensate polishing.

TRILITE SCR12 TRILITE SCR12 is a very high crosslinkage Gaussian SAC resin. It is widely used for special

applications required high exchange capacity.

Applications

TRILITE CMP08 TRILITE CMP08 is a low crosslinkage Gaussian SAC resin, and is widely used in water

treatments such as softening and demineralization and special refining such as acid

catalyst, organic chemical reactions.

TRILITE CMP16 TRILITE CMP16 is a standard crosslinkage Gaussian SAC resin. With its excellent resistance to

organic fouling and superior decolorization, it is recommended for sugar applications such

as starch sugar refining. Also, it is used for demineralization, catalyst for various chemical

reactions and dehydration for organic solvents.

TRILITE CMP18 TRILITE CMP16 is a high crosslinkage Gaussian SAC resin. With its excellent resistance

to organic fouling and superior decolorization capacity, it is recommended for sugar

applications such as starch sugar refining. Also, it is used for demineralization required for

slightly higher exchange capacity, catalyst for various chemical reactions and dehydration

for organic solvents.

TRILITE CMP28 TRILITE CMP28 is a very high crosslinkage Gaussian SAC resin, which features higher

stability against oxidizing agents. It is widely used for water treatment, metal removals and

condensate polishing.

Strongly Acidic Cation Exchange Resins / Gaussian Porous type

Grade CMP08 CMP16 CMP18 CMP20 CMP28



Ionic form Na+

Specific gravity※ 1.19 1.27 1.3 1.31 1.35

Shipping weight※ (g/ℓ) 745 785 795 800 825

Moisture retention (%) 58~68 46~52 43~50 41~47 37~43

Total capacity (eq/ℓ) 1.2↑ 1.75↑ 1.8↑ 1.9↑ 2.05↑



Particle size (㎛) 300∼1,200 (on 1,180㎛ < 5%, through 300㎛ < 1%)



Swelling rate※ (Na＋→H＋) 9% 8% 8% 8% 6%

Remarks

Low

Crosslinkage

Standard

Crosslinkage

High

Crosslinkage

Very High

Crosslinkage

TRILITE CMP Series are porous type Gaussian SAC resin, has Polystyrene+DVB as matrix and Sulfonate as functional group. It is resistant to organic solvents, strong acids, strong alkalis, and reducing agents. The polymer matrix contains a large number of macropores. In comparison with gel type IERs, the porous type has faster reaction rate, superior decoloring properties, good resistance to organic fouling and high swelling and contraction strength. Since the macropores contain moisture, porous type resins have slightly lower exchange capacity per unit of apparent volume and higher exchange capacity per unit of weight than gel type resins of the same linkage. The relationship between crosslinkage and properties is the same as gel type resins.



Applications

TRILITE AMP14 TRILITE AMP14 is a low crosslinkage Gaussian SBA resin (Porous type 1), which is widely used

for demineralization, sugar and glycerin refining, and decolorization for other applications.

TRILITE AMP16 TRILITE AMP16 is mechanically and chemically stable, which is widely used for water

treatment with a large amount of organic contents, sugar solution and amino acids refining,

and for organic scavenger.

TRILITE AMP18 TRILITE AMP18 features outstanding SiO2 removal capacity and less ion leakage. It is widely

used for water treatment containing a large amount of organic contents MBP application.

TRILITE AMP24 TRILITE AMP24 is a low crosslinkage Gaussian SBAER (Porous type 2) with outstanding

reaction rate. It is widely used for refining corn starch, sugar refining, decolorization and

recovery of heavy metal.

TRILITE AMP26 TRILITE AMP26 is highly recommended for nucleic acid refining and others purposes such

as water treatment, sugar refining, decolorization and other refining process for amino acid.

TRILITE AMP28 TRILITE AMP28 features high exchange capacity and regeneration efficiency. It is widely

applied for water treatment containing a large amount of organic contents.

Strongly Basic Anion Exchange Resins / Porous type (Gaussian SBA Porous type)

Type Type 1 Type 2

Grade AMP14 AMP16 AMP18 AMP24 AMP26 AMP28

Matrix Polystyrene＋DVB Polystyrene＋DVB

Functional group-N+(CH₃)₃

(TMA, Trimethylammonium)-N+(CH₃)₂C₂H₄OH

(DMEA, Dimethylethanolammonium)

Ionic form Cl- Cl-

Specific gravity※ 1.10 1.09 1.11 1.09 1.11 1.12

Shipping weight※ (g/ℓ)

670 685 700 655 680 690

Moisture retention (%) 57∼67 49∼55 44∼50 54∼64 46∼52 40∼46

Total capacity (eq/ℓ) 1.0↑ 1.2↑ 1.3↑ 1.0↑ 1.2↑ 1.3↑

Effective size (㎛) 400↑ 400↑

Uniformity coefficient 1.6↓ 1.6↓

Particle size (㎛) 300~1,180 (on 1,180㎛ < 5%, through 300㎛ < 1%)

Operating temp (℃) 70↓ (OH- form)90↓ (Cl- form)

50↓ (OH- form) 70↓ (Cl- form)

Operating pH range 0∼14 0∼14

Swelling rate※ (Cl-→OH-)

24% 23% 19% 14% 13% 12%

Remarks

TRILITE AMP Series are Porous type Gaussian SAC resin, has Polystyrene+DVB as matrix and contains a large number of macropores. In comparison with gel type SBA IERs, they have faster reaction rate, superior decolonization capacity, excellant resistance to organic fouling and high stability to dramatic swelling and contraction of resins. TRILITE AMP Series features higher SiO2 removal, enables to produce high purity water. Since the macropores contain moisture, porous type resins have slightly lower exchange capacity per unit of apparent volume and higher exchange capacity per unit weight than gel type resins of the same crosslinkage. TRILITE AMP Series are superior in reaction rate in non-polar solution, and the difference between Type 1 and 2 are as the same as Gel type resins

※ The data for Specific gravity/Shipping weight/Swelling rate is for reference.

Strongly Basic Anion Exchange Resins / Gel type (Gaussian SBA Gel type)

Type Type 1 Type 2

Grade SAR10 SAR11 SAR12 SAR20 SAR21

Matrix Polystyrene＋DVB Polystyrene＋DVB

Functional group-N+ (CH₃)₃

(TMA, Trimethylammonium)-N+ (CH₃)₂C₂H₄OH

(DMEA, Dimethylethanolammonium)

Ionic form Cl- Cl-


Shipping weight※

(g/ℓ)685 690 680 700 650

Moisture retention (%) 43∼48 55∼65 48∼55 39∼45 55∼65


Effective size (㎛) 400↑ 400↑



Operating temp (℃)60↓ (OH- form)80↓ (Cl- form)

40↓ (OH- form)60↓ (Cl- form)

Operating pH range 0∼14 0∼14

Swelling rate※ (Cl-→OH-)

24% 35% 24% 12% 18%

Remarks

Gaussian SBA gel type 1 resin has Polystyrene-DVB matrix with TMA as functional group. Type 1 shows better chemical stability than Type 2 resins, and features higher SiO2 removal, less ion leakage and higher heat resistivity. With its less regeneration efficiency, it has lower operating capacity.

Gaussian SBA gel type 2 resin has Polystyrene-DVB matrix with DMEA as functional group. It features slightly lower chemical stability and less SiO2 removal capacity than type 1 resin. With its better regeneration efficiency, it has higher operating capacity and enables efficient operation.

※ The data for Specific gravity/Shipping weight/Swelling rate is for reference.

Applications

TRILITE SAR10 TRILITE SAR10 is a high crosslinkage Gaussian SBA resin (Gel type 1) with higher SiO2 removal

and less ion leakage. It is widely used for Anion exchanger and MBP for demineralization,

and also catalyst application and recovery of noble metals such as gold.

TRILITE SAR11 TRILITE SAR11 is a low crosslinkage Gaussian SBA resin (Gel type 1), and is widely used for

sugar refining with its excellent decolorization capacity.

TRILITE SAR12 TRILITE SAR12 is a standard crosslinkage Gaussian SBA resin (Gel type 1). It is widely used

for surface water treatment required for a large amount of organic contents and water

treatment for high pressure boilers.

TRILITE SAR20 TRILITE SAR20 is a Gaussian SBA resin (Gel type 2), and features high regeneration efficiency

and operating capacity. It is most widely used for water treatment, noble metal recovery and

other refining applications.

TRILITE SAR21 TRILITE SAR21 is a low crosslinkage Gaussian SBA resin (Gel type 2) and is widely used for

refining of glutamine acid, amino acid and other special applications.


Weakly Acidic Cation / Weakly Basic Anion Exchange Resins (WAC / WBA)

TypeWeakly Acidic Cation

Exchange ResinsWeakly Basic Anion Exchange Resins

Grade WCA10L AW20 AW30 AW30C AW90

Matrix Polyacrylate + DVB Polystyrene + DVB

Functional group-COOH

(Carboxylic acid)

Secondary

AmineTertiary Amine

Ionic form H+ Free Base



Moisture retention (%) 45~50 39~45 48~58 55~65 40~50


Effective size (㎛) 500↑ 400↑ 400↑ 400↑ UPS

Uniformity coefficient 1.4↓ 1.6↓ 1.6↓ 1.6↓ 1.1↓

Particle size (㎛) 425~1,200 300~1,200 300~1,200 300~1,200 550±50

Operating temp (℃) 120↓ 100↓ 60↓ 100↓ 60↓

Operating pH range 4~14 0~9 0~9 0~9 0~9

Swelling rate※ 60% 30% 20% 20% 20%


IER for Nuclear power plant (Nuclear grade)

Grade MCN116K MAN210K MMN316K MAPN440K


Functional group Sulfonic acid Trimethylammonium

MCN116K

+

MAN210K

Trimethylammonium

Ionic form H+ OH- OH-

Total capacity (eq/ℓ) 2.4↑ 1.2↑ 0.8↑

Moisture retention (%) 37~43 54~62 50~70

Shipping weight※ (g/ℓ) 815 670 670

Uniformity coefficient 1.1↓ 1.1↓ 1.4↓

Average diameter (㎛) 650±50 630±50425~1,200

(Particle size, ㎛)

△TOC 10↓ 10↓ 10↓ 10↓

Operating temp (℃) 120↓ 60↓ 60↓ 60↓

Operating pH range 0~14

※ The data for Shipping weight is for reference.

Applications

TRILITE MCN116K TRILITE MCN116K is a high crosslinkage UPS SAC resin and has polystyrene-DVB matrix with

sulfonic acid as functional group. It features excellent mechanical and chemical stability,

and low crush rate after long term use. It is widely used for premium water treatment such

as primary circuit for nuclear power plant.

TRILITE MAN210K TRILITE MAN210K is a high crosslinkage UPS SBA resin (Gel type 1) and has polystyrene-DVB

matrix with TMA as functional group. It features excellent mechanical/ chemical stability and

low crush rate after long term use. It is widely used for anion tower for nuclear power plant,

and under the standard operating conditions, it maintains less than △TOC 10ppb of outlet

water quality.

TRILITE MMN316K TRILITE MMN316K is a mixed resin of MCN116K and MAN210K by 1:1 exchange capacity ratio.

TRILITE MAPN440K TRILITE MAPN440K is a SBA resin (porous type) and has polystyrene-DVB matrix with TMA

as functional group. It features excellent mechanical/chemical strength and superior fluid

flow by high whole bead count. It is widely used for Crud-removal application in nuclear

power plants.

Applications

TRILITE WCA10L TRILITE WCA10L is a Gaussian WAC resin. Due to excellent ion exchange capacity, high purity

water can be produced economically. It features high mechanical and chemical stability

leading to low crush rate after long term use. It has high exchange capacity and regeneration

efficiency. It is widely applied in layered bed of water treatment systems combined with SAC

resins, and also used for Electrodeposition of paints, etc.

TRILITE AW20 TRILITE AW20 doesn’t have natural salt splitting capacity but high exchange capacity and

regeneration efficiency. It is widely used for refining of organic solvents with excellent

chemical stability, heat resisting capacity and mechanical strength against attrition loss.

TRILITE AW30 TRILITE AW30 features outstanding chemical stability, high resistance against organic

fouling and superior decolonization capacity. It is widely applied in layered bed of water

treatment systems combined with SBA resins, and also used for starch sugar refining.

TRILITE AW30C TRILITE AW30C has excellent chemical stability, mechanical strength against attrition loss,

and heat resistance, which enables treating high temperature of solutions. It has large

proportion of WBA and leads to high quality products from starch sugar refining.

TRILITE AW90 TRILITE AW90 is an UPS resin with high chemical stability, high resistance against organic

fouling and superior depolarization capacity. It is widely used for starch refining and Layered

bed water treatment system combined with SBA resins.


Ultrapure Water

Ultrapure water(UPW) system has an increasing role in electronics industries such as semiconductors, OLED,

LCD, etc. With the development of the relative industries, the quality control of ultrapure water has more

tightened up.

The following conditions are necessary to consistently produce ultrapure water.

- High uniformity coefficient of resins (1.1↓)

- High conversion rate of resins (H+, OH-)

- Strict control over TOC (Total organic carbon) and trace metal-ion through post-treatment on resins.

TRILITE UPW resins owns trustworthy supply reference to various ultrapure water systems from LCD(Samsung

Display, LG Display, etc.) to semiconductor(Samsung Electronics, SK Hynix, etc.) thus contributing to

competitiveness with customers with stable quality control and on time delivery.

TRILITE UPW resins are classified as: Primary application - UPR100 Series, Secondary application - UPR200

Series, and Final Polishing application – UPR300 Series.

Gradeseries

Representative Products

Cation Conversion

RateAnion Conversion Rate Outlet condition

(Feed water : Resistivity >17.5MΩ·cm,TOC<2ppb, SV=30)

H+(%) OH-(%) Cl-(%)

UPR100Series

UPRM100U 99.0↑ 90.0↑ 1.0↓ Resistivity >18.0MΩ·cm (in 30min)

UPR200Series

UPRM200U 99.0↑ 95.0↑ 1.0↓Resistivity >18.1MΩ·cm (in 30min)

△TOC<5ppb (in 120min)

UPR300Series

UPRM300U 99.9↑ 97.0↑ 0.1↓

Resistivity >18.2MΩ·cm (in 30min)△TOC<1ppb (in 180min)

Metal Impurity (ppm, as Dry Base)Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5

RawWater

Point of Use

Demineralization system for ultrapure water and IER selection

Outlet condition of TRILITE UPW Resins

Tank

Mixed-bed(UPRM100U)

Tank

TankHeat

Exchanger

UV-OX,etc

Final Polisher(UPRM300U)

Heat Exchanger

MF

AnionPolisher

(UPRA200U)

UF

UV-ST

UV-OX

① CationExchanger

④ AnionPolisher

⑤ Final Polisher

① CationExchanger

Degasifier

RO

② AnionExchanger

③ Mixed Bed

MDGor

VDGPre-Treatment

System

RO,etc

① Cation Exchanger : MC-08, MC-10

② Anion Exchanger : MA-12, MA-10, MA-15, MA-20, AW90

③ Mixed Bed Tower : UPRC100U, UPRC120U, UPRA100U, UPRA120U

④ Anion Polisher : UPRA200U, UPRA220U, UPRA240U, UPRA300U, UPRA320U, UPRA340U

⑤ Final Polisher : UPRM200U, UPRM220U, UPRM240U, UPRM300U, UPRM320U, UPRM340U

RawWater

Outletcondition

① Resistivity (MΩ·cm) ② TOC (ppb)

18.25

18.20

18.15

18.10

18.05

18.00

20

15

10

5

00.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0

(Mettler Toledo M300) hrs (Anatel A1000S20P) hrs

⑥ Particle (0.05㎛/㎖): None

(RION XP-L4W)

⑤ Metals (ppt)

Li Be Na Mg Al K Ca Ti Cr Mn Fe Co Ni Cu

< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

Zn Ga As Sr Mo Ag Cd Sn Sb Ba Au Pb Bi

< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

③ Total Silica (ppt) ④ Boron (ppt)

100

80

60

40

20

0

500

400

300

200

100

0

(HACH Series 5000 Silica Analyzer) hrs (Sievers UPW Boron Analyzer) hrs

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0


Ultrapure water for primary circuit UPR100 Series

Grade UPRC100U UPRA100U UPRC120U UPRA120U

MatrixUPS SAC Gel type UPS SBA Gel type1 UPS SAC Gel type UPS SBA Gel type1

Standard Crosslinkage High Crosslinkage

Ionic form H+ OH- H+ OH-


Moisture retention (%) 50∼56 62∼70 45~51 59∼65

Average diameter (㎛) 620±50 620±50 660±50 590±50

Uniformity coefficient 1.1↓ 1.1↓ 1.1↓ 1.1↓

Ionic conversion rate

H+(%) 99.0↑ - 99.0↑ -

OH-(%) - 90.0↑ - 90.0↑

Cl-(%) - 1.0 ↓ - 1.0 ↓

↓ ↓ ↓ ↓

Mixed ratio : 1:1 (Capacity ratio) Mixed ratio : 1:1 (Capacity ratio)

↓ ↓

Grade UPRM100U UPRM120U

Type Mixed resin

Outlet conditionResistivity > 18.0 MΩ·cm (in 30min.) Resistivity > 18.0 MΩ·cm (in 30min.)

Feed water : Resistivity >17.5MΩ·cm, TOC<2ppb, SV=30

Ultrapure water for secondary circuit UPR200 Series









Ionic conversion rate

H+(%) 99.0↑ - 99.0↑ -

OH-(%) - 95.0↑ - 95.0↑

Cl-(%) - 1.0 ↓ - 1.0 ↓

↓ ↓ ↓ ↓


↓ ↓


Type Mixed resin

Outlet condition

Resistivity >18.1MΩ·cm (in 30min.)△TOC<5ppb (in 120min.)

Resistivity >18.1MΩ·cm (in 30min.)△TOC<5ppb (in 120min.)


Ultrapure water for final polishing UPR300 Series









Ionic conversion

rate

H+(%) 99.9↑ - 99.9↑ -

OH-(%) - 97.0↑ - 97.0↑

Cl-(%) - 0.1 ↓ - 0.1 ↓

Metal Impurity (ppm, as Dry Base)

Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5

↓ ↓ ↓ ↓


↓ ↓


Type Mixed resin

Outlet condition

Resitivity >18.2MΩ·cm (in 30min.)△TOC<1ppb (in 180min.)

Resitivity >18.2MΩ·cm (in 30min.)△TOC<1ppb (in 180min.)


Ultrapure water system


Ion Exchange Resins used as a catalyst for various chemical reactions convert Batch operation into

Continuous operation, and maximize yield of final product based on high conversion rate of IERs.

The following are the advantages of IERs in catalyst applications :

- Easily separable from reaction system and cost effective with continuous reaction in column reactor.

- Unnecessary for regeneration or re-concentration, high reaction selectivity and less by-products

produced.

- Easy to be selected with low corrosive to system.

Also, the following disadvantage is taken care of disadvantages of catalyst IER for cation:

- Less heat stability compared to inorganic catalyst and slow reaction rate for macromolecules reactions.

TRILITE catalyst resins are optimized for catalyst applications with improved porosity and excellent ionic

conversion rate of resins. It shows fast reaction rate with maximized surface area and remarkable internal

diffusion speed, resulting in efficient reactions even in non-polar solvent. Also, it has outstanding mechanical

and chemical stability, and excellent elasticity of polymers. Hence, superior durability of resins can be

achieved even under the rapid volume changes and results in longer life time ultimately.

Applications

TRILITE SPC160H TRILITE SPC160H has very high whole bead count, high uniformity, excellent mechanical

and chemical stability. It is developed by modifying the properties of ionic forms

of TRILITE CMP16, which is used in the treatment of water with high temperature

or very high concentration of Chlorine. It is widely used for etherification, e.g.

Tetrahydrofuran(THF).

TRILITE SPC180H TRILITE SPC180H features stronger mechanical strength, higher surface area and higher

porosity than other resins. Its high diffusion rate into the inside of resins leads high

reaction performance. It is used for water treatment and catalyst applications such as

alkylation and etherification, e.g. 1,4-BDO, MMA.

TRILITE SPC320H TRILITE SPC320H has high exchange capacity, large specific surface area and high porosity.

It shows excellent adsorption and recovery capacity to metal ions such as Cu, V2O5, etc.

TRILITE SPC400H TRILITE SPC400H has large surface area and high porosity, and is widely used as an

Ethyhexylacrylate(EHA) catalyst and other acid catalyst applications.

TRILITE PCC40H TRILITE PCC40H is a low crosslinkage SAC resin with high reaction rate and mechanical

and chemical stability, and widely used as a catalyst for Bisphenol-A.

Strongly Acidic Cation Exchange Resins for Catalyst

Grade SPC160H SPC180H SPC320H SPC400H PCC40H

MatrixPolystyrene＋DVB

(Porous type)

Polystyrene＋

DVB

(Gel type)

Functional group -SO₃- (Sulfonate)

Ionic form H+ (H Conversion rate 99.9%↑)


Moisture retention 54∼60 53∼60 42~48 65∼75 57∼67







Swelling rate※ (Na＋→ H＋) 8% 8% 4% 10% 8%

Application Reaction Catalytic resins

Hydrolysis of

methyl acetateCH₃COOCH₃ + H₂O → CH₃COOH + CH₃OH PCC40H, MC-08H, CMP08LH

Esterification reaction RCOOH + ROH → RCOOR + H₂OPCC40H, MC-08H, CMP08LH,

SPC160H, SPC180H, SPC400LH

Synthesis of

methyl methacrylateSPC180H

Alkylation of phenol SPC320H

Synthesis of

bisphenol-APCC40H, CMP08LH

Methyl tertiary

butyl ether(MTBE)SPC160H

t-amyl methyl

ether(TAME)SPC160H, SPC180H

CH₂ = C CH₃OH → CH₂ = C H₂O

CH₃

COOH

CH₃

COOCH₃

+ +

OH OH

+ H₂CR

H CH₃

R

H

OH OHHO+

O

H₃C CH₃H₃C CH₃

H₂CCH₃

CH₃CH₃OH H₃C OMe

CH₃

CH₃

+

H₂CCH₂CH₃

CH₃CH₃OH H₃C OMe

CH₂CH₃

CH₃

+

※ The data for Shipping weight/ Swelling rate is for reference.

Catalyst


Chromatography 크로마토그래피 분리

Ion Exchange Resins for chromatography separation efficiently separate useful materials in various applications

such as high-purity separation of sugar solutions, e.g. Fructose/Glucose separation and sucrose recovery from

molasses, and acid purification, etc.

The following characteristics are required to be IERs for chromatography separation.

- Extremely high uniformity coefficient (1.1↓) and excellent separation capacity.

- Relatively small particle size for maximum separation efficiency with larger surface area per volume unit

of resins.

- Long life time with mechanical and chemical stability.

TRILITE Chromatography resins completely satisfy the above conditions, and enable the most efficient

separation capacity by various composition of crosslinkages(%), ionic forms and particle sizes.

The Following tables show major applications of UPS gel type cation exchange resins and UPS gel type 1 & 2

anion exchange resins, and the full line-up of TRILITE chromatography resins.

Types Ionic FormsRepresentative

ProductsMajor Applications

UPS SAC Gel type

Na MCK-50Glucose/Oligosaccharide separation, Maltose/Oligosaccharide separation

K MCK-52 Sucrose collection from Molasses

Ca MCK-55Fructose/Glucose separation, Fructose/Allulose separation, Fructose/Galactose separation

UPS SBAGel

type 1 Cl MA-13J Bio diesel purification process

type 2 Cl MA-23F Acid purification

Line-up for UPS SAC Gel Type product for high purity sugar refining is as below.

Lower Uniformity coefficient (1.05~1.10) thanother resins for chromatographic separation→ Excellent separation efficiency

Higher physical & chemical strength→ Longer life time

+

Crosslinkage Ionic form

Average Particle size

210~220㎛ 283~295㎛ 305~328㎛ 340~350㎛

5% KMCK-22M

(305㎛)

MCK-22K

(346㎛)

6%

NaMCK-30

(220㎛)

MCK-30J

(295㎛)

MCK-30L

(328㎛)

MCK-30K

(350㎛)

KMCK-32

(213㎛)

MCK-32J

(288㎛)

MCK-32L

(320㎛)

MCK-32K

(345㎛)

CaMCK-35

(210㎛)

MCK-35J

(283㎛)

MCK-35L

(315㎛)

MCK-35M

(305㎛)

MCK-35K

(340㎛)

8%

NaMCK-50

(215㎛)

KMCK-52

(215㎛)

CaMCK-55

(210㎛)

MCK-22 Series (Chromatography cation resins)

Grade MCK-22M MCK-22K

Matrix & Functional group Polystyrene + DVB, -SO₃- (Sulfonate)

Ionic form K+ (K Conversion rate 98%↑)

Shipping weight※ (g/ℓ) 815

Moisture retention (%) 47~52 (K form), 59~64 (H form)

Total capacity (eq/ℓ) 1.6↑

Average diameter (㎛) 305±15 346±15



Grade MCK-30 MCK-30J MCK-30L MCK-30K


Ionic form Na+


Moisture retention (%) 52~56





Grade MCK-32 MCK-32J MCK-32L MCK-32K


Ionic form K+ (K Conversion rate 98%↑)









Grade MCK-35 MCK-35J MCK-35M MCK-35L MCK-35K


Ionic form Ca2+ (Ca Conversion rate 98%↑)



Total capacity (eq/ℓ) 1.6↑ 1.7↑

Average diameter (㎛) 210±10 283±15 305±15 315±15 340±15



Grade MCK-50 MCK-52 MCK-55


Ionic form Na+ K+ (K Conversion rate 98%↑)

Ca²+ (Ca Conversion rate 98%↑)




Average diameter (㎛) 215±10 215±10 210±10


Strongly Basic Anion Exchange Resins for Chromatography

Type Type 1 Type 2

Grade MA-13J MA-13F MA-23F

Matrix & Functional group Polystyrene + DVB, TMAPolystyrene + DVB,

DMEA

Ionic form Cl-




Average diameter (㎛) 300±15 230±10 230±10



Typical process of Starch sugar refining and fructose/glucose separation

CMP18

AMP24SCR-Bor

CMP18

AW30or

AW30C

Counter-current

pH 5~6

5㎲/㎝↓

CocurrentpH 8~9

20㎲/㎝↓

pH 4~6

2㎲/㎝↓

Bx 45

CV Max 0.05

2nd Ion exchanger(for fructose)

Concentration

Mixing

High fructose syrup

Activatedcarbon

Filtration

90~97% HFS

42% HFS

55% HFS

Isomerization by enzyme

Concentration3rd Ion exchanger(for high fructose)

Fructose /Glucose Separation

CMP18

AMP24SCR-Bor

CMP18

AW30or

AW30C

Counter-current

pH 5~6

5㎲/㎝↓

CocurrentpH 8~9

20㎲/㎝↓

pH 4~6

2㎲/㎝↓

Bx 35~40

CV Max 0.05

Enzyme liquefaction, saccharification

Activated carbon1st Ion exchanger

(for glucose)

Corn syrup

Glucose

Emulsion of starch Filtration

ConcentrationConcentration

Starch(Corn)

Ion Exchange Resins used as food applications need for strict control and management of impurities and

foreign substances in manufacturing process, and are registered as food grade between countries with

necessary permits as a Food additive. Also, Halal certificates are required for Islamic countries.

The primary food applications for IERs are sugar refining, starch sugar refining and nucleic acid, lysine

separation/purification, etc. Unlike water treatment applications, there are other variables affecting operation

yields such as total organic contents or viscosity and adsorption capacity to specific materials, hence

customized tailored resins optimized for specific operating conditions are recommended.

TRILITE food application IERs are optimized for various domestic and overseas food processes, and contribute

to enhance competitiveness to customers by continuous technical consultation and product improvements.

Porous type reins are recommended for starch sugar production with higher viscosity and less reactivity of liquid

rather than Gel type resins. TRILITE AW30C (WBA 99%↑) is recommended when the treated liquid temperature is

high (60℃↑) or there is worry about isomerization reaction.

TRILITE MCK-50 Series is receiving rave reviews from users with outstanding uniformity of resins and superior

mechanical and chemical stability to any other resins in the industry.

Food

Fructose(90~97%)

Glucose(80~90%)

Fructose (42%)

Glucose (52%)

Other sugars(6%)

pH 4~6

2㎲/㎝↓

Bx 40

CV Max 0.05

AW30

AMP24

CMP18

(Mixture) (Separation)

MCK-55


Sugar refining, Nucleic acid/Lysine adsorption resins

TypeSugar refining resins

Gel type 1 Porous type 1 Porous type

Grade SAR11 AMP14 ASP10

Matrix Polystyrene＋DVB Polystyrene＋DVB Polyacrylate + DVB

Functional group -N+ (CH₃)₃ (TMA, Trimethylammonium) Quaternary Ammonium

Ionic form Cl- Cl- Cl-




Effective size (㎛) 400 400


Particle size (㎛) 300~1,200 (on 1,180㎛<5%, through 300㎛<1%) 400~1,250

Operating temp (℃)60↓ (OH- Type)

80↓ (Cl- Type)

70↓ (OH- Type)

90↓ (Cl- Type)

40↓ (OH- Type)

80↓ (Cl- Type)

Operating pH range 0~14 0~14

Swelling rate※ (Cl-→ OH-) 35% 25% 25%

TypeNucleic Acid adsorption resins

Lysine adsorption

resin

Gel SAC Porous type 2 UPS Gel SAC UPS Gel SAC

Grade NAC-4 AMP26N MC-04NH MC-08LS


Functional group -SO₃- (Sulfonate)-N+ (CH₃)₂C₂H₄OH

(DMEA)-SO₃- (Sulfonate) -SO₃- (Sulfonate)

Ionic form Na+ Cl- H+ Na+

Shipping weight※ (g/ℓ) 780 680 750 845

Moisture retention (%) 57∼67 46∼52 65~70 43~49


Effective size (㎛) 450↑ 400↑ UPS UPS


Particle size (㎛) 300∼1,200 300∼1,200 500±50 600±50

Operating temp (℃) 120↓ 50↓ (OH- Type)

70↓ (Cl- Type)120↓ 120↓

Operating pH range 0~14 0∼14 0∼14 0~14

Swelling rate※ (Cl-→ OH-) 8% 13% 9% 9%

※ The data for Shipping weight/Swelling rate is for reference.

Refined Sugar

White Sugar

Brown Sugar

Cane raw sugar refining process Sugar refining process with A/C Sugar refining process without A/C

Cane B Sugar (Raw sugar) C Sugar (Raw sugar)

Extraction Carbonation, Filtration Carbonation, Filtration

FiltrationDecolorization by IER

(SAR11 or AMP14)

Decolorizationby IER (2 steps)

(ASP10 + AMP14)

Crushing Affination, Melting Affination, Melting

Carbonation Activated carbon

Concentration,Crystallization

Concentration, Crystallization

Concentration, Crystallization

A Sugar B Sugar C SugarRefined Sugar

White Sugar

Brown Sugar

Typical process of nucleic acid adsorption / separation process

Typical process of lysine adsorption / separation process

AMP26N MC-08LSNAC-4

orMC-04NH

AMP26N

Cultivation of microorganism

Cultivationof yeast

CrystallizationCrystallization

Broth withlysine

Extraction of nucleic acids

EvaporationEvaporation

Adsorption & separation

with IER

Decompositionof nucleic acids

Neutralization, Filtration

Adsorption & separation

with IER

Adsorptionof nucleic acids

Separationof GMP, IMP

Concentration Adsorption of lysine

2,000~3,000 I.U.

3,000~4,000 I.U.

800~1,000 I.U.

800~1,000 I.U.

300~400 I.U. 200~

300 I.U.100~150 I.U.

500~600 I.U. < 45 I.U. < 45 I.U.2,000~3,000 I.U.

< 100 I.U. < 100 I.U.3,000~4,000 I.U.

400~1,000 I.U. 400~1,000 I.U.

General sugar processes are classified into the production of raw sugar and refined sugar. Raw sugar manufacturing

process doesn’t need IERs, but the refined sugar requires IERs necessarily. For refined sugar process, it is also

distinguished between the combination use of IERs & activation carbon and the use of two different types of

IERs. Without using activated carbon, there are large amount of colorants to be removed by IER. In such a case,

it is recommended to use the combination with TRILITE ASP10, which has the outstanding feature of enhanced

decolorization capacity and long life time with excellent resistance to organic fouling of resins.

Nucleic acids, one of the popular food additives, are

flavor enhancers and used as a seasonings. IERs are

used for adsorption, separation and concentration of

nucleic acids. TRILITE AMP26N and NAC-4 are Tailored

resins with high performance and long life cycle.

Ion Exchange Resins are used for separation and

purification of amino acids, constituents of protein.

Lysine as a feed nutrition additive is the most

commercialized amino acids. TRILITE MC-08LS is

a Tailored UPS resin with outstanding adsorption

capacity, mechanical and chemical stability.

※ GMP : Guanosine MonoPhosphate ※ IMP : Inosine MonoPhosphate ※ Lysine : an essential amino acid


CLR-08

Ca²+ 0.01ppm↓

Mg²+ 0.01ppm↓

Sr²+ 0.02ppm↓

Ba²+ 0.01ppm↓

Grade Functional Group Features Applications

CLR-08 Iminodiacetate

- Much greater selectively for

multivalent ions

(Ca2+, Mg2+, Sr2+, etc.) from very

highly concentrated monovalent

ions(Na+, etc.)

- Less leakage of multivalent ions

• Secondary brine purification• Selective removal of bivalent ions • Removal and recovery of heavy

metals / rare metals from

wastewater

CLR-09Aminomethyl

phosphonate

- slightly higher operating capacity

than CLR-08

- slightly more leakage of

multivalent ion than CLR-08

• Secondary brine purification• Selective removal of bivalent ions

CLR-10 Thiouronium- Much greater selectivity for

mercury(Hg)• Mercury removal in wastewater

CLR-20 Polyamine

- Much greater selectivity for

heavy metals except alkali metal

ions(Na+, K+, etc) and alkaline earth

metal ions(Ca2+, Mg2+, etc)

• Separation of heavy metals from

alkali metal ions and alkaline earth

metal ions

CLR-B3 Glucamine

-Much greater selectivity for

boron(B) from highly concentrated

anions

• Boron Polisher for UPW• Boron removal from wastewater

CLR-F Aminophosphonate

- Much greater selectivity for

fluoride(F) even from low

concentration

• Fluoride removal in wastewater

CLR-N Triethylamine- Much greater selectivity for nitrate

than anion resins • Nitrate removal

TRILITE Chelating resins are used for various applications and processes. Total solution service can be provided

by optimized proposal for process retrofit and resin analysis. The professional consultation can be provided;

Preliminary technical review → Pilot plant test → Gathering engineering data →Optimized design proposal →

further Scale-up of the facility.

TRILITE Chelating resins are supplied to domestic and foreign customers for secondary brine purification

application, and proved its’ competiveness to equivalent resins.

Typical chloro-alkali process

Salt saturation

Dechlorination

Primary brine purification

Gas liquid separation

Secondary brine

purification

Ion exchange membrane

electrolysis cell

Vaporization

Salt

Chlorine

Hydrogen

Water

Secondary brine purification

50% NaOH

Typical process of removing heavy metal from waste water

The above diagram depicts a waste water treatment system with TRILITE Chelating resins which selectively

removes metal ions. As the environmental regulations are more strictly controlled, there is tendency for the

increasing wastewater treatment cost. TRILITE Chelating resins can be an alternative solution to the high cost

of wastewater treatment.

Waste water containingvarious heavy metal

(If mercury is not present)

Waste water containingvarious heavy metal(If mercury is present)

CLR-10(Mercury removal)

Neutralization coagulation settlement treatment

CLR-20(Heavy metal removal)

Type Chelating resins

Grade CLR-08 CLR-09 CLR-10 CLR-20 CLR-B3 CLR-F CLR-N


Functional groupIminodia-

cetateAminomethyl-phosphonate

Thiouronium Polyamine GlucamineAmino-

phosphonateTriethylamine

Ionic form Na+ Na+ H+ OH- Free base Al³+ Cl-

Total capacity (eq/ℓ)

Cu2+ 0.5↑

Ca2+ 0.4↑Ca2+ 0.6↑ 1.1↑

4mol↑as copper

0.6eq/ℓas boron↑

11g↑ as fluorine

1.0↑

Particle size (㎛) 400~1,000 400~1,000 300~1,250 400~1,250 300~1,250 300~1,000 300~1,250

Equivalent

· Lewatit TP208

· Amberlite IRC718

· Diaion CR11· Purolite S930

· Lewatit TP260

· Amberlite IRC747

· Purolite S940

· Eporous-Z7· Purolite S924

· Diaion CR20

· Eporous MX-8C

· Diaion CRB03

· Amberlite IRA743

· Purolite S108

· Eporous-K1· READ-F

· Amberlite IRA996

· Purolite A520E

CLR-10 (Optional)

CLR-20

Sandfilter

Activated carbon

filter

P

P

P

M M

Waste water containing

heavy metal

Waste waterstorage pit

Neutralizing reaction pit

Clarifier

Dischargingor

recycling

pH adjusting pitChelating resin towerpH adjusting pit

Neutralizingagent

Neutralizingagent

Neutralizingagent

Coagulant

M

Chelating Resins

In contrast to typical Ion exchange resins, the chelating resin selectively separates and removes a metal ion with a

functional group that can form a chelate (complex) with the metal ion. Chelating resins with various functional groups

are used in the following applications.


The reaction mechanism of synthetic adsorbents and experimental apparatuses

Synthetic Adsorbents

Synthetic adsorbents are non-functionalized resins with controlled pore size distribution and large surface

area. While the primary application of synthetic adsorbents is to adsorb various organics by Van der Waals

forces, it can be used in various applications such as decolorization of liquid chemical, separation and

purification of proteins and antibiotics, purification of medical supplies and refining semiconductor chemicals.

The above diagram depicts the necessary test for the choice of Synthetic adsorbents. In general, the test is

preceded with TRILITE GSH-20 for adsorption and elution of target material first. To find out proper synthetic

adsorbent, re-test it with other types of synthetic adsorbents according to selectivity to M.W and elution rate of

target material.

The following table shows the features of major TRILITE Synthetic adsorbents.

Type Product Feature

Aromatic standard type GSH-20

Relatively large pore radius, hence appropriate for

adsorption of large molecules (> 1,000mw). Easily elutes

and separates the target material.

Aromatic special type

GSP-25 Very large surface area and small pore radius, hence

appropriate for adsorption of small molecules (<1,000mw)

and exclusion of large molecules.GSP-50

Aromatic chemically modified GSP-07

Substituted bromine turns out very high hydrophobicity

resulting very high selectivity to non-polar molecules.

Large amount of eluent may be required due to very high

adsorption force.

It can be can be used for solution with high density due to

high specific gravity.

The following table shows general tendency and guideline for choosing Synthetic Adsorbents.

Type Case and General Tendency Guideline

Selectivity

(molecular

weights)

Adsorption of all materials from solution containing

large amount of organics (mw > tens of thousands)GSH-20 > GSP-07 > GSP-25> GSP-50

Adsorption of material from solution with large amount

of organic content (mw < 1,000)GSP-50 > GSP-25 > GSH-20 > GSP-07

Adsorption of materials (mw< several thousands) GSP-07 > GSP-50 > GSP-25 > GSH-20

ElutionElution tends to decrease with small pore radius and

large adsorption force. GSH-20 > GSP-25 > GSP-50 > GSP-07

Feeding solution

Eluent

Detector

Purewater

Regenerant

Fraction collector


Pure water

Column

Ready to use mixed resin / Inert resin


Type Styrene TypeChemically Modified

Styrene Type

Grade GSH-20 GSP-25 GSP-50 GSP-07

Chemical structure

CH2－CH－

－CH₂－CH－CH₂－CH－

CH₂－CH－ Br

－CH₂－CH－CH₂－CH－

Specific surface area (㎡/g) 750↑ 1,100↑ 1,000↑ 600↑

Pore volume (㎖/g) 1.0~1.5 1.2~1.6 0.9~1.1 0.8~1.0

Pore radius (Å) 50~80 45~55 30~50 50~70

Particle size (㎛) 315~1,250 250~700 250~700 250~700

Equivalent Diaion HP20 Diaion SP825 Diaion SP850 Diaion SP207

Applications

TRILITE GSH-20 Widely used in refining of pharmaceuticals and natural extracts, since these are suitable

for adsorbing large molecules because of their relatively large pore sizes and superior

adsorption/ desorption. GSH20 is widely used in various industrial applications,

especially adsorption, desalting and Decolorization of natural products and small

proteins.

TRILITE GSP-25 These have much larger surface area and a narrower, more uniform pore-size distribution

TRILITE GSP-50 than GSH-20. They offer nearly one and half times the surface area of GSH-20. With

large surface area and narrower pore radius, it selectively adsorbs small molecules and

excludes larger molecules. This grade is recommended for adsorption, desalting and

decolorization.

TRILITE GSP-07 With high hydrophobicity, TRILITE GSP-07 has higher selectivity for non-polar molecules

than standard aromatic adsorbents, due to its chemically bonded bromine to the

aromatic rings. It is suitable for upward flow and batch processes due to its high specific

gravity but also for treatment of heavy liquid such as purification of hydrogen peroxide

in electric and electronic industry.

Targetmolecules

Pore radius (Å)

Specific surface

area(m2/g)


Ready to use mixed resins / Inert resins

Ready to use mixed resins produce high purity water in a more convenient way. Up to the usage of water

volume, they are widely used for cartridges or pressure vessels which do not require a complicated

regeneration process.

Inert resins is a non-functionalized resin developed for use as an upper layer in packed bed system, used to

enhance separation of cation and anion exchange resins prior to regeneration.

Primary application for TRTILITE SM210 is in Wire EDM applications. It features outstanding amount of treated

water compared to other ready to use mixed resins in the market. TRILITE SM300 used after RO(Reverse

osmosis) in Make-up systems, results in treated water quality close to that of Ultrapure water (Resistivity >

10.0MΩ·cm).

Type Ready to use mixed resins Inert resins

Grade SM210 SM300 TR70 TR30

Matrix Polystyrene＋DVB Polyethylene Polystyrene＋DVB

Functional group Mixed resin -

Shipping weight (g/ℓ) ※ 700 500 725

Particle size (㎛) 300~1,200 (Uniformity coefficient : 1.6↓) 1,200~1,800 700~900

Operating temp., (℃) 50↓ 90↓ 100↓

Ionic formH+ (H% 99%↑)

OH- (OH% 90%↑)

H+ (H% 99%↑)

OH- (OH% 95%↑)The specific gravity

is lower than that of

water, it locates as

top layer within an

IER tower, keeping

the layers compact,

preventing any loss

of active finer resins

and improving

the regenerant

distribution

efficiency.

The specific gravity

lies in the middle of

that of cation resins

and anion resin.

It forms a border

between them. It

eases separation

of cation and anion

resins, preventing

any counter

regeneration hence

improving the purity

of treated water.

Operating capacity※

(eq/ℓ)

0.45↑

(Feed water : CaCO3

400ppm + NaCl

100ppm, SV=12)

-

Outlet condition

Resistivity >5.0MΩ·cm

(Feed water : normal

water)

Resistivity >10.0MΩ·cm

(Feed water : RO outlet)

※ The data for Specific gravity and Operating capacity is for reference.

Cartridge polisher for wire-cutting

Pressure vessel polisher for RO unit

Technical services

Purchasing TRILITE means more than just a stable supply of high quality products. Our technical sales team

is subdivided into three specialized groups, and provides professional Total solutions as per the various

applications requested by customers. And, also R&D center located in Daejeon provides analysis service of

resins with state-of-the-art facilities and other Pilot tests upon requests.

.exe

English version download

Our R&D Center located in Daejoen provides resin

analysis service for used resins and resins for

replacement. Multiperspective analysis examines

various fouling and performance of resins for the

most efficienct operation of facilities.

Ion exchange resin analysis

TriAngleTM is calculation software designing water

treatment system with ion exchange resins. User

friendly interface of the program supports economic

design of required resin quantity for the towers, as

per the various applications.

Ion exchange resin design program

TriAngleTM

Professional engineers of Samyang Corporation

provide facility diagnosis and optimised retofit

proposals along with trouble shooting guidelines for

the problematic facility.

Facility diagnosis and retrofit proposal

Samyang Corporation provides process development

service for various applications of IERs, including Lab.

Test and Pilot test.

Customised process development services using various IERs

Analysis report

Applying for IER analysis

IER analysis

processConduct of analysis

Receiving of request and

samples

1 2

3 4

Samyang Corporation | Ion Exchange Resin Team

· TEL : +82 2 740 7732~6 · E-mail : [email protected] · http://www.samyangtrilite.com

NaOH

TR70

IER

Freeboard

Regenerant

Service

TR30 Middle distributor

SAC

SBA

RegenerantSpent

HCl

Packed bed Triobed

Freeboard

36 Ion Exchange Resins Product List

1. Handling

Protective equipment must be used to protect eyes and skin, and resins must be handled in a place with good

ventilation. Eye-wash facilities are recommended at the work spot. When resins are spilled on the floor, they

are very slippery and may cause a person to fall. Avoid exposure to high temperature, sparks, flames, etc. Also,

avoid contact or mixing with oxidizing agents such as nitric acid because ion exchange resins can explode on

contact with nitric acid.

2. Storage

Resins should be stored in dry, cool and dark places where proper ventilation system is installed. The storage

container and bag of fiber drum should be tightly closed to prevent intrusion of impurities and drying of resins.

Do not store resins near oxidizing agents. At high temperature, rapid degradation of resins may occur, and

below 0℃, freezing of resins may occur which may cause physical breakage.

Factors affecting quality of resins in storage

Humidity

The ion exchange resin consists of about 50% water. When the dried resin comes in contact with moisture

again, the resins may crack due to osmotic shock.

Freeze and Defrost

Sudden freezing and defrosting of resins can take place and this may have a physical effect on the ion

exchange resin.

(Note: Freezing and defrosting should be avoided especially for Porous type.)

Abrupt temperature change

Sudden temperature changes can cause cracks on the surface of the ion exchange resin and cause

physical deterioration.

Physical shock

Over loading of resins on pallet for transport and storage should be avoided. Care should be taken as ion

exchange resins are susceptible to physical shock.

3. Disposal

Unused resins may be discarded in the landfill or by incineration following local regulations and the cautions

mentioned above. A suitable fitted furnace is necessary for incineration because SOX, NOX, COX and others will

be generated from the incineration.

Used resins may also be land-filled or incinerated as long as they contain no toxic or poisonous material such

as heavy metals. Resin can only be discarded, as above, after removal of poisonous material.

● The contents in this catalog might be changed without previous notice.

Quality assurance / Packing

TRILITE Ion Exchange Resins assure strict quality management under ISO9001 Quality Assurance System.

TRILITE is granted for its qualification in accordance with international certificate authorities, Halal for Islamic

countries and Veritas for nuclear plant.

TRILITE Ion Exchange Resins are supplied in various types of packaging, 25ℓ PE bag, 1,000ℓ bag (supersack),

5~7ft3 fiber drums and others to ensure customer preference when handling resins. Systematic manuals for

shipment and container loading assure minimization of any probable damage to products while transporting.

The work footages are shared with customers in real-time for customer satisfaction.

Basic analysis

Optional analysisSampling

Periodical analysis

Qualitytest

Customer

ISO9001

Process analysis

Keeping samples(for 4years)

Producthopper

DB

Y N

Bulk density

H/OH Conversion rate

Osmotic shock stability

Moisture retention

Resistivity

Friability

Particle distributionExchange capacity

ΔTOC

Whole bead count

25ℓ PE bag1,000ℓ

Ton bag50ℓ

Plastic drum5 or 7ft3

Fiber Drum

Palletizing, container loading

Loading Backwash Displacement

Measuring

May 2018 Edition

Cautions on Use of Ion Exchange Resins

Shipping COA (From DB) Packing

37Ion Exchange Resins Product List

ion exchange resins product list - samyangtrilite.com · rate per apparent volume and less swelling...

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