is 10148 (1982): positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1...

20
Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. इंटरनेट मानक !ान $ एक न’ भारत का +नम-णSatyanarayan Gangaram Pitroda “Invent a New India Using Knowledge” प0रा1 को छोड न’ 5 तरफJawaharlal Nehru “Step Out From the Old to the New” जान1 का अ+धकार, जी1 का अ+धकारMazdoor Kisan Shakti Sangathan “The Right to Information, The Right to Live” !ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता ह Bharthari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 10148 (1982): Positive list of constituents of polyvinyl chloride and its copolymers for safe use in contact with foodstuffs, pharmaceuticals and drinking water [PCD 12: Plastics]

Upload: others

Post on 22-Mar-2021

0 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

Disclosure to Promote the Right To Information

Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public.

इंटरनेट मानक

“!ान $ एक न' भारत का +नम-ण”Satyanarayan Gangaram Pitroda

“Invent a New India Using Knowledge”

“प0रा1 को छोड न' 5 तरफ”Jawaharlal Nehru

“Step Out From the Old to the New”

“जान1 का अ+धकार, जी1 का अ+धकार”Mazdoor Kisan Shakti Sangathan

“The Right to Information, The Right to Live”

“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता है”Bhartṛhari—Nītiśatakam

“Knowledge is such a treasure which cannot be stolen”

“Invent a New India Using Knowledge”

है”ह”ह

IS 10148 (1982): Positive list of constituents of polyvinylchloride and its copolymers for safe use in contact withfoodstuffs, pharmaceuticals and drinking water [PCD 12:Plastics]

Page 2: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,
Page 3: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,
Page 4: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS:10148 - 1982

Indian Standard POSITIVE LIST OF

CONSTITUENTS OF POLYVINYL CHLORIDE ( PVC ) AND ITS COPOLYMERS IN CONTACT

WITH FOODSTUFFS, PHARMACEUTICALS AND DRINKING WATER

(Second Reprint NOVEMBER 1997 )

UDC 678.743.22:621.798: 663/664 + 615.IJ.4: 614.8

0 Copyrjghr ; 1982

BUREAU OF INDiAN STANDARDS MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARC

NEW DELHI 110002

Gr 4 June ‘1982

Page 5: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

'IS:10148- EMI2

Indian Standard POSITIVE LIST OF

CONSTITUENTS OF POLYVINYL CHLORY.CjE (PVC ) AND ITS COPOLYMERS’IN CONTACT

WITH FOODSTUFFS, PHARMACEUTICALS AND DRINKING WATER

Plastics Sectional Committee, PCDC 12

Chairman

Lb K. J. BALAKRISRIQ A-10, Shantinagar, Cantonment, Kanpur

Mrmbcrr Representing

Da P. C. ANTOXY Indian Plastics Ltd, Bombay Sasr N. LFBIRLA ( Altmxatc )

SRSI A. S. ATHALYE All India Plastics Manukcturers’ Association, Bombay

SECBETABY ( AIPMA ) ( Alttrnofc ) DR P. K. BANEBJEE Polyolcfins Industries Ltd, Bombay SHRI A. T. BASAK Directorate General of Supplies and Disposals,

New Delhi SHRI B. B. RAI ( After&c)

SEBI K. J. BHA~T State Trading Corporation of India Ltd, New Delhi

SEBI BHAQWAN DASWANI ( Alttrnatr ) SHBI S. T. BHOJWANI Bright Brothers Ltd, Bombay

SHSI A. H. KHAN ( Alternate ) SHBI T. S. BIDDAPA National Organic Chemical Industries Ltd,

Bombay SERI J. K. VADODARIA ( Altcrnatc )

DB R. P. DAMBAL Indian Telephone Industries Ltd, Bangalore SFIRI G. V. RAO ( Alternate )

DB S. P. SINQE DHAKAREY Ministry of Defence (DGI) SEBI N. C. BoSE ( Altcrnatc )

SHBI 0. P. DHABUJA Export Inspection Council of’lndia, Calcutta SEBI hf. K. HNNIEBISHNAN ( AlWUtC )

SHBI DION FERNANDES Plastics & Linoleum Export Promotion Council, Bombay

SHRI K. RAXANI (Alternate )

( Continued on page 2 )

BUREAU OF INDIAN STANDARDS

This publication is protected under the Indian Copyright Act (XIV of 1957 ) and reproduction in whole or in part by any means except with wrirten pemkion of the

b publisher rhall be deemed to be an infringement of copyright under the said Act.

. .._

Page 6: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS :10148-1982

( Conhuedffom page I )

Members

SHRI M. S. FRABCTS

Repyeenting

Central Institute of Plastics Engineering and Tools, Madras

SHRI CHANDRAKANT B. GARWARE SHRI H. S. SIJRI ( Alternate )

Garware Synthetics Pvt Ltd, Bombay

SHRI A. GEIO~H National Test House, Calcutta SHRI S. M. LAHIRI ( Alterngtc )

SHRI S. K. JAIN Hoechst Dyes & Chemicals Ltd, Bombay SARI K. A. T. VARCRESE ( Altrrnate)

DR S. P. MANX Railway Board ( Ministry of Railways ) SHRI N. KRISHNANPPA ( Alternuts )

SH~I P. R. MAHALIXGAM SHRI S. S. GATTANI ( Alternate)

SHEI P. R. MALEAN

SHRI S. R. SINQH (‘Alternate ) SERI R. C. MISHRA

SARI G. L. ANAND (Alternate )

SHRI A. K. BASU ( Alternate ) SIIRI S. MXIRA

DR B. R. C. ANAND (Alternate ) SARI K. R. NARASIMHAN

Dx S. LAKSRMANAN ( Alternate ) SrIRl V. NIJI7AWAN

SERI A. K. GUPTA ( Alternate ) SHRI M. S. RAMA~IURTHI

Metal Box Ltd, Calcutta

Union Carbide India Ltd, Calcutta

Polychem Limited, Bombay S>IRI C. U. KHANDHXRIA ( Alternate )

SHRI 0. P. RATRA National Buildings Organization, New Delhi

SITXI D. A. REVS Kosmek Plastics Manufacturing Ltd, Bombay SHKI 0. P. BAN~RJEE ( Alternafe )

Snrtr R. SAXTIIANAM The Alkali & Chemical Limited, Caicutta

Corporation of India

Chemicals & Plastics ( India ) Ltd, Madras

Development Commissioner, Small Scale Indus- tries, New Delhi

Bharat Heavy Electricals Ltd, Bhopal

Calico Chemicals ( Plastics and Fibres Division), Bombay

SHRI D. JAIX (Alternate) DR P. R. SESHAN

SHHI A. K. RAY ( Alternate )

Indian Petrochemicals Vadodara

Corporation Ltd,

S14rc1 P. P. SHARMA Directorate General of Technical Development, New D&i

SHRI N. K. AUARWAL ( Alternate ) DR J. VAID Peico Electronics & Electricals Ltd, Pune

DR S. P. BFlIl,E ( Alternate ) DR S. P. VOIIRA Bakelite Hylam Ltd, Hyderabad

‘Sam Y. V. CHUTAL ( Alferncfe) SHRI M. S. SAX>.NA, Director Gem ral, IS1 ( Ex-ojicio Member )

Birector ( P&C ) ( Secretary )

( Continued on page 15 )

2

Page 7: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : 10148 - 1982

Indian Standard POSITIVE LIST OF

CONSTITUENTS OF POLYVINYL CHLORIDE (PVC) AND ITS COPOLYMERS IN CONTACT

WITH FOODSTUFFS, PHARMACEUTICALS AND DRINKING WATER

0. FOREWORD

0.1 This Indian Standard was adopted by the Indian Standards Institution on 13 May 1982, after the draft finalized by the Plastics Sectional Committee had been approved by the Petroleum, Coal and Related Products Division Council.

0.2 Plastics are now being used on a large scale for packaging of foodstuffs and pharmaceuticals. Where direct contact occurs between the packed commodity and the plastics, the high-molecular-mass polymer itself does not pose a toxic hazard being inert and essentially insoluble in food. There is, however, a likelihood that some transfer will occur of polymer additives, adventitious impurities, such as monomers, catalyst remnants and residual polymerisation solvents and of low molecular mass polymer fractions from the plastics into the packaged material with consequent toxic hazard to the consumers. The occurrence of acute toxicity due to plastics materials in contact with food is most unlikely, since only trace quantities of potentially toxic materials are likely to migrate. However, the accumulation of these toxic materials with time may lead to hazards which may be serious.

0.3 Initially the Sectional Committee responsible for the preparation of this standard had prepared three codes of practice for safe use of polyvinyl chloride ( IS: 728%1974* ), polyethylene ( IS : 7277-19741) and styrene polymers (IS : 7961-1976:) in contact with foodstuffs, pharmaceuticals and drinking-water. Taking cognizance of the pressing need to monitor the quality of plastics intended to come in contact with foodstuffs, pharmaceuticals and drinking water which could not be done on the basis of standard codes of practice, the Committee decided to

*Code of practice for safe use of polyvinyl chloride (PVC) and its copolymers in contact with foodstuffs, pharmaceuticals and drinking water.

*Code of practice for safe use of polyethylene in contact with foodstuffs, pharmaceu- tical ‘and drinking water.

SCode of practice for safe use of styrene polymers in contact with foodstuffs, pharmaceuticals and drinking water.

3 L

Page 8: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS:10148- 1982

prepare the following series of Indian Standards dealing with various aspects of plastics for food contact applications:

IS : 9833-I$81 List of pigments and colourants for use in plasticsin contact with foodstuffs, pharmaceuticaIs and drinking water;

IS : 9845-1981 Method of analysis for the determination of specific and/or overall migration of constituents of plastics materials and articles intended to come into contact with foodstuffs;

IS : 10 I4 l-l 982 Positive list of constituents of polyethylene in contact with foodstuffs, pharmaceuticals and drinking water;

IS : 10142-1982 Specification for styrene polymers for its safe use in contact with foodstuffs, pharmaceuticals and drinking water;

IS: 10146-1982 Specification for polyethylene for its safe use in contact with foodstuffs, pharmaceuticals and drinking water;

IS: 10148-1982 Positive list of constituents of polyvinyl chloride (PVC) and its copolymers in contact with food- stuffs, pharmaceuticals and drinking water;

IS : 10149-1982 Positive list of constituents of styrene polymers in contact with foodstuffs, pharmaceuticals and drinking water;

IS : 10151-1982 Specificattin for polyvinyl chloride ( PVC ) and its copolymers, for its safe use in contact with food- stuffs pharmaceuticals and drinking water; and

IS : 10171-198’2 Guide on suitability of plastics for food packaging.

Eventually the three codes of practice would be withdrawn with the publication of the product specification along with the corresponding positive list for the three plastics. Standards for other plastics for food contact applications like polypropylene and unsaturated polyester resins svhich are under preparation are expected to follow the same pattern, lamely, a product specification with a corresponding positive list. It is loped that this set of Indian Standards for plastics considered safe for hod contact applications would help the statutory bodies to effectively nonitor the quality of plastics for this end use.

4

Page 9: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

Is : 10148 - 1982

0.4 The list of additives prescribed in these positive lists are based on the information available through published literature like British Plastics Federation Reports, London ( English); FDA Regulations, USA; and other national legislation reports.

1. SCOPE

1.1 This standard covers positive list of constituents of PVC, namely, the polymers, copolymers, manufacturing residues and necessary additives which may be regarded as safe for use, when properly processed in contact with foodstuffs, phamaceuticals and drinking water and when present in the prescribed limits of concentration.

1.2 The positive list does not purport to establish the suitability of the, ingredient singly in a particular foodstuff from other than toxicological considerations.

2. TERMINOLOGY

21 Polyvinyl Chloride - shall mean:

4

b)

the homopolymers of vinyl chloride;

copolvmers containing at least 50 percent by mass of vinyl chloride with one or several of the following monomers:

1)

2)

3)

4)

5)

6)

7)

8)

9)

10)

vinylidene chloride;

acrylonitrile;

styrene and substituted styrene;

butadiene;

ethylene;

propylene;

divinyl benzene;

vinyl acetate;

maleic, fumaric, itaconic, crotonic, acrylic and methacrylic acids ( MUX limit of 8 percent by mass of all these monomers); and

esters of maleic, itaconic, crotonic, acrylic and methacrylic acids with saturated monohydric aliphatic alcohols;

5

Page 10: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : 10148 - 1982

c) mixtures of homopolymers of vinyl chloride with one or several of the copolymers indicated in (b); and

d) mixtures of several copolymers indicated in (b).

3. REQUIREMENTS

3.1 Basic Resin-The polymers and copolymers defined in 2.1(a) and 2.1(b) shall be made in such a way that they contain no ingredients , or residues of ingredients used in their manufactureother than those listed in 3.1.1 and 3.2 to 3.8.4.

3.1.1 The following may be added to polyvinyl chloride (PVC), provided percent by mass content of vinyl chloride of the mixture is at least equal to 50 percent and they conform to the concerned specification:

a) homo and copolymers of monomers mentioned in 2.1(a) and 2.1(b);

b) chlorinated polyolefines with a maximum chlorine content of 56 percent by m‘iss;

c) copolymers of butyl acrylic and vinyl pyrrolidone ( with 95 percent by mass of butyl acrylate ); and

d) polyurethanes of molecular mass 40 000 to 100 000 obtained from:

1) 2) 3)

4)

5)

6)

di-isocyanate 1, 6 hexane;

di-isocyanate 2, 4 toluene;

di-isocyanate 2, 6 toluene and their mixtures;

butane dihydric alcohol 1, 4;

polyester resulting from the action of adipic acid on a glycol; and

addition compounds of propylene or ethylene oxide and/or ethylene with ethylene glycol or poly propylene-glycol or glycerine or trimethylol propane or pentaerythritol or sorbitol.

NOTE - These products should be free from isocyanates and primary amines.

3.2 Catalyst -The total residues of catalyst and their decomposition products shall be not more than 0.25 percent by mass of the finished polymer. The residues of the following catalysts may be present:

a) Benzoyl peroxide;

b) Aliphatic acid ( Ca to Cr, ) peroxide;

c) tert-Butyl perbenzoate;

6

Page 11: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS :10148-1982

d) Azo-bis-iso-butyronitrile, azobis cyclohexyl carboxynitrile and azo-dis 2’4 dimethyl valeronitrile;

e) p-tcrt-Butyl perpivalate;

f) Methyl ethyl ketone peroxide;

g) Persulphates of ammonium and potassium;

h) Percarbonates of the structure RI 0 COO00 CORs where R, and Rs are alkyl, aryl alkylaryl, alkoxy. alkoxy alkyl or halogen substituted alkyl, aryl, alkylaryl, alkoxy or alkoxy alkyl ( C, to Cr, );

j) Cycloalkyl ( C, to C, ) peroxy dicarbonate;

k) bis-4-tert-Butyl cyclohexyl-peroxydicarbonate;

m) Acetyl cyclohexyl sulphonyl peroxide;

n) Peresters of the structure RI COOOR, where RI and Rs are alkyl, aryl, alkylaryl, alkoxy, or halogen substituted alkyl, aryl alkylaryl, or alkoxy ( C) to Cl,, );

p) Mixed peroxide percarbonates of structure Rr 0 COOOOCRs where RI and Rs are alkyl, aryl, alkylaryl or alkoxy,or halogen substituted alkyl, aryl, alkylaryl, alkoxy ( CZ to C,, ); and

q) Hydrogen peroxide.

3.3 Polymerization Inhibitors - The residue of the polymerization inhibitors shall not exceed 0.01 percent by mass of the finished polymer.

3.4 Emulsifying Agents -The total residues of emulsifying agents shall be not more than 3.0 percent by mass of the finished polymer. The residues of the following emulsifying agents may be present:

a) Alkyl, aryl and alkylaryl sulphates of sodium, potassium and ammonium, the alkyd group containing Cl, to C,,;

b) Alkyl, aryl and alkylaryl sulphonates of sodium, potassium and ammonium, the alkyl group containing C,, to C,,;

c) Alpha hydroxy octadecane sodium sulphonate;

d) Sodium, potassium and ammonium salts of sulpho-succinic acid and its mono and di-esters with saturated monophydric aliphatic alcohols Cc to C,,;

e) Sodium, potassium and, ammonium salts of saturated aliphatic acids above Cr.

f) Esters of sorbitol or of sorbitan with saturated or unsaturated aliphatic acids above C,;

7

Page 12: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS :10148- 1982

g) Calcium, sodium, potassium and ammonium salts of hydroxylic fatty acids C,, to C&e and their sulphonyl or acetyl derivatives;

h) Products of condensation of ethylene oxide with monobasic aliphatic acids CI, to C1, and their ammonium sulphates;

j) Products of condensation of ethylene oxide with monohydric aliphatic alcohols Cl, to Czo and their sodium and ammonium sulphates;

k) Products of condensation of ethylene oxide with alkylphenols having alkyl groups C, and above and their sodium and ammonium sulphates;

m) Products of condensation of ethylene oxide with alkyl and dialkyl amines Cr to Ceo;

n) Fatty alcohols Cr, to C,,; and

p) Alkyl, aryl, alkylaryl, acyl, polyethoxy ethanol and their sulphate.

3.5 Suspension Agents - The total residues shall not be more than 1.0 percent by mass of the finished polymer. The residues of the following may be present:

a) Gelatine,

b) Methylcellulose,

c) Hydroxyethylcellulose

d) Hydroxypropyl methylcellulose,

e) Sodium carboxymethylcellulose,

f) Methylethylcellulose,

g) Polyvinyl alcohol ( having a viscosity of at least 4 centipoise at 20°C in 4 percent aqueous solution ),

h) Polyvinyl pyrrolidone and copolymers of vinyl pyrrolidone with vinyl ethers or esters, and

j) Copolymers of vinyl alkyl ( C, to C,z ) ethers with maleic acid or ally1 alcohol.

3.6 Chain Transfer Agents - The total residues shall not constitute more than O-5 percent by mass of the finished polymer. The residues of the following may be present:

a) Trichloroethylene,

b) Perchloroethylene,

8

Page 13: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : lOids - lw2

c) trans Dichloroethylene,

d) Isobutylene,

e) Xylene, and

f) Chloroform.

3.7 Miscellaneous Additives - The residues of the following additives may be present:

a) Calcium carbonate,

b) Sodium carbonate and bicarbonate,

c) Calcium chloride,

d) Sodium chloride,

e) Organopolysiloxanes,

f) Calcium and sodium phosphates and phosphoric acid,

g) Sodium dialkylsulphonimides up to a maximum of 0.05 percent by mass of the finished polymer,

h) Aluminium sulphate,

j) Magnesium sulphate,

k) Sodium sulphate,

m) Calcium acetate, and

n) Sodium sulphite and sodium hydrogen sulphite.

3.8 Auxiliary Items for Working

3.8.1’ Plasticizers -The following plasticizers may be present to the uses for which the total migration in foodstuffs including oils and fats does not exceed the maximum permitted in the standard extraction tests:

a) PhthuffzteJ:

1) Double phthalates of aliphatic alcohol ( C, to GO) and their mixtures,

2) Phthalates of butyl-benzyl alcoho1,

3) Diphenyl phthalate,

4) Cyclohexyl phthalate, and

5) Diethyl phthalate.

9

Page 14: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

1s .: 10148 - 1982

I$) Adijates:

1) Di-( normal-octyl )-adipate, 2) Di-( di-methyl-hexyi )-adipate, 3) Di-( P-ethyl-hexyl )-adipate, and 4) Di-iso butyl adipate.

c) Sebacates:

1) Di-( normal-octyl )-sebacate, 2) Di-( di-methyl-hexyl )-sebacate, 3) Di-( 2-ethyl-hexyl )-sebacate, and 4) di-n-butyl sebacate.

d) Aselates

1) Di-n-octyl-azelate, 2) Di-dimethyl-hexyl-azelate, 3) Di-2-ethyl-hexyl-azelate, and 4) Di-n-hexyl azelate.

e) ( 2-ethyl-hexyl )-diphenyl-phosphate.

f) Citrates:

1) Acetyl-tributyl-citrate, 2) Stearyl ( mono, di, tri ) citrate, 3) iso Propyl (mono) citrate, and 4) Triethyl citrate.

g) Esters of alkylsulphonic acids of phenol and,‘or cresol C,, to C,a.

h) Polyesters obtained from diacids like adipic, azelaic, glutaric, sebacic, succinic acids and polyols ( excluding ethylene-glycol and 1, 3 propylene glycol). The terminal groups may be esterified.

j) Bis (ethyl-2 hexoxy carbonyl methylthio ) di-m-octyl tin.

k) Di-n-octyltin-s-bis, iso octyl marcapto acetate.

m) Epoxidized oils.

n) Glycerol, pure and glycerol triacetate.

10

Page 15: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : 10148 - 1982

p) Glycerol esters of saturated and unsaturated natural fatty acids.

q) Triethylene and polyethylene ( Mol mass greater than 400 ) glycols.

r) P-tert-Butylphenyl salicylate.

3.8.2 Stabilizers - The following stabilizers may be present in the finished polymers to the extent of permitted limits:

a) Organic derivatives of tin:

1) 2) 3)

4)

Acid-butyl-thiostanic ( maximum 0.5 percent ),

Di-n-octyl-tin-di-laurate,

Di-n-octyl-tin-di-makate,

Di-( n-octyl ) bis ( methyl-1-heptyl ) oxy-carbonyl-methyl-thio tin,

5) Di-( n-octyl ) bis ( methyl-1-heptyl ) oxy-carbonyl-phenyl-thio tin,

6) Bis ( ethyl, 2-hesoxy-carbonyl-methyl-thio ) di-n-octyl tin,

7) Bis ( ethyl, 2-hexoxy-carbonyl-phenyl-thio ) di-n-octyl tin, and

8) Di-n-octyl ( tin s-s’ bis iso-octylmercapto acetate ).

The above organic salts of tin may be used up to a maximum total dose of I.5 percent of which the content of di-n-octylic derivatives of tin are at least 95 percent. If these derivatives of tin are used, the maximum doses of the other liquid auxiliary items should be limited to 1.5 percent on the whole. The use of plasticizers is then not allowed.

b) Calcium, zinc and magnesium salts of aliphatic mono and polyacids, saturated or not.

NOTE - The finished product should not cont&n more than 1 percent of zinc.

c) Di-phenyl-thio-urea, Max 1 percent by mass; and 2-phenyl-indol, Max 1 percent by mass.

d) Manganese compounds:

1) Manganese hydroxide; and

2) Manganese salts of aliphatic mono and polyacids, saturated or not.

e) Epoxidized oils:

Soya Linseed

: with maximum a percent] of oxirane and iodine : with maximum 10 percent

Castor : with maximum 5 percent value 6 at Max

11

Page 16: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

.IS : 10148 - 1982

Groundnut Safflower

Limits to be agreed upon.

f) Di-epoxy-cycle-dodecene, and

Tri-epoxy-cycle-dodecene.

NOTE - The epoxicized products mentioned in (e) and (f) are limited t 5 percent on the whole.

d

h)

_i)

4

ml

4

P)

9) r)

The epoxidized resins obtained from 4-4’ dihydroxy diphenyj alkane ( hisphenol A ) and from epichlorohydrme with a mass per epoxy equivalent value greater than 175 in so far as they meet the specifications concerning them.

Stearate, palmitate and myristate of lithium.

Polyvinyl-ethyl-ether.

N, N’-di-stearyl and/or palmityl-ethylene-diamine ( maximum 1 percent ).

Sodium compounds carbonates phosphates, polyphosphates, stearates, laurates, oleates, myristates, ricinoleates.

Esters of p-amino-crotonic acid with mono or dibasic alcohols.

Sorbitol, manitol, pentaerythritol and their esters with the fatty acids and sorbitan.

Hexanetriol.

Di-terd-butyl-fi-cresol:

2-4 dinoylphenyl, di ( 4-mono-nonylphenyl ) phosphite with a maximum 20 percent content of di-tio-octyl-nonyl-phenyl phosphite and products of oxidation.

Thio-bis ( methyl-tert-butyl-n-phenol ) otherwise called 4,4’ - Thio-bis ( 6-tcrt-butyl-m-cresol ).

NOTE - The above three products are limited to a total of O-5 percent.

s) 4,4’ di-hydroxy-di-phenyl propane.

3.8.2.1 Lead, dialkyl tin ( C, and higher ) compounds may be permitted to be used in unplasticized PVC pipes when the finished polymer isintended for use in contact with drinking water. When tested by specific methods the quantities of lead, dialkyl tin ( measured as Sn ) and any other

12

Page 17: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : 10148 - 1982

toxic substance extracted from the internal walls of the pipe shall not exceed the following limits in the test solution:

Lead ( first extraction )

Lead ( third extraction )

Dialkyl tin ( C, and higher ) ( third extraction )

Other toxic substances ( third extraction )

1 PPm 0’3 ppm

O-02 ppm

O-01 ppm

NOTE 1 -The other toxic substances that are likely to be extracted are di-n-octyl-tin-s-s’ bis iso-octyl mercapto acetate and butyl stearate.

NOTE 2 -Conformity with the requirements of this clause shall ensure that the recommendations of the World Health Organization, 1963, concerning toxic

.’ constituents of drinking water are not excec ded.

3.8.3 Lubricants - The following lubricants may be permitted:

a) Aliphatic fatty acids, saturated or not ( C, to Cm );

b) Aliphatic alcohols ( C, to Cse );

c) Fatty alcohols with at least 12 atoms of carbon, with a maximum of 3 percent;

d) Amides of oleic, palmitic, myristic, stearic, ricinoleic and linoleic acids with a maximum of 0.3 percent;

e) Natural waxes;

f) Microcrystalline waxes, pa.ra%n and paraffin oil containing less than 0.1 ppm of noxious pJolycyclic aromatic hydrocarbons;

g) Polyethylene waxes;

h) Esters of montanic acids with glycol or 1, 3 butane dihydric alcohol;

j) Esters of saturated aliphatic acids ( Cl2 to C& ) with monovalent saturated aliphatic alcohols ( C,, to C,, ) with a maximum of 3 percent;

k) Esters of glycerine with fatty acids, saturated or, not, with a maximum of 3 percent;

m) Esters of polyethyleneglycol;

n) Esters of polypropyleneglycol;

p) Polyethylene and polypropyleneglycols;

13

Page 18: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

IS : 10148 - 1982

q) Esters of sorbitol and sorb&an with fatty acids, saturated or nor c, to Go;

r) Edible vegetable oils;

s) Products of condensation of ethylene oxide with fatty acids C, to C&,; and

t) Butyl stearate.

3.8.4 Other Additives - Copolymers, polyblends and terpolymers of styrene acrylonitrile, butadiene, and esters of acrylate, methacrylate to a maximum of 20 percent by mass of the finished polymer. i

14

Page 19: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

Is:10148 - 1982

( Continued from page 2 )

Plastics in Food Packaging and Allied Industries Subcommittee, PCDC 12: 12

CO?WL?b?r

SHBI D. S. CHADHA

Representing

Central Committee for Food Standards (Director- ate General of Health Services ), New Delhi

Mmbers

SHRI B. ANANDASWAMY Central Food Technological Research Institute ( CSIR ), Mysore

DR P. K. BAKERJEE Polyolefins Industries Ltd, Bombay SHRI V. DORAIRAJ ( Alternate )

SERI S. T. BHOJWANI Bright Brothers Ltd, Bombay SHRI A. H. KHAN ( Alternate)

?&RI T. S. BIDDAPA National Organic Chemicals Industries Ltd, Bombay

SHRI J. K. VADODARIA ( Alternate ) SHRI P. V. DATAR Polychem Ltd, Bombay

SHRI C. U. KIIANDKERIA ( Alternate ) DR S. S. GOTHOSEAR Drugs Controller ( India ), New Delhi

SHRI D. S. CHADHA ( Altmate ) SHHI D. JAIN The Alkali & Chemicals Corporation of India

Ltd, Calcutta SHRI S. K. JAIN Hoechst Dyes & Chemicals Ltd, Rombay

SHRI K. A. T. VARGHESE ( Alternate ) SHRI R. KALIDAS Chemicals & Plastics ( India ) Ltd, Madras

SHRI S. S. GATTANI ( Alternate ) SHRI K. R. NARASIMHAN Metal Box India Ltd, Calcutta

DH S. LARS~MANAN ( Alternate ) SERI P. V. NARAYANAN Indian Institute of Packaging, Bombay

SHRI G. S. PURUSHOT- ( Alternate ) ‘DR N. P. RAO Defence Institute of Food Preservation & Storage,

New Delhi SHRI V. K. MATEUP. ( Alternate )

REPRESENTATIVE Bhabha Atomic Research Centre, Bombay Dn B. R. ROY Central Food Laboratory, Calcutta SHRI K. C. SAH Union Carbide India Ltd, Calcutta

SH~I Y. NIJHAWAN ( Altcraatc ), DR N. SEN Hindustan Lever Ltd, Bombay DR P. R. SESHAN Indian Petrochemicals Corporation Ltd, Vadodara

SHRI A. K. RAY (Alternate) SHRI P. P: SHARMA Directorate General of Technical Development,

New Delhi SHRI N. K. AGARWAL ( Alternate )

SHRI L. SHETR Bakelite Hylam Ltd, Hyderabad SFIRI G. K. SRIXIVASAN ( Alternate)

SERI 0. P. SRIVASTAVA Defence Food Research Laboratory, Mysore SHRI A. N. SRIVASTAVA ( Alternate )

15

Page 20: IS 10148 (1982): Positive list of constituents of polyvinyl chloride … · 2018. 11. 15. · 1.1 This standard covers positive list of constituents of PVC, namely, the polymers,

BUREAU OF INDIAN STANDARDS

Headquartsrs: Manak Bhavan, 9 Bahadur Shah Zafar Marg, NEW DELHI 110002 Telephones: 323 0131,323 3375,323 9402 Fax : 91 11 3234062,91 11 3239399, 91 11 3239382

Central Laboratory :

Plot No. 20/9, Site IV, Sahibabad Industrial Area, Sahibabad 201010

Regional Offices:

Telegrams : Manaksanstha (Common to all Offices)

Telephone

6-77 00 32

Central : Manak Bhavan, 9 Bahadur Shah Zafar Marg, NEW DELHI 110002 32376 17

*Eastern : l/14 CIT Scheme VII M, V.I.P. Road, Maniktola, CALCLflTA 700054 337 86 62

Northern : SC0 335-336, Sector 34-A, CHANDIGARH 160022 60 36 43

Southern : C.I.T. Campus, IV Cross Road, CHENNAI 600113 23523 15

tWestem : Manakalaya, E9, Behind Mar01 Telephone Exchange, Andheri (East), 832 92 95 MUMBAI 400093

Branch Omces::

‘Pushpak’, Nurmohamed Shaikh Marg, Khanpur, AHMEDABAD 380001

SPeenya Industrial Area, 1 st Stage, Bangalore-Tumkur Road, BANGALORE 560058

5501348

839 49 55

Gangotri Complex, 5th floor, Bhadbhada Road, T.T. Nagar, BHOPAL 462003 55 40 21

Plot No. 6263, Unit VI, Ganga Nagar, BHUBANESHWAR 751001 40 36 27

Kalaikathir Buildings, 670 Avinashi Road, COIMBATORE 641037 21 01 41

Plot No. 43, Sector 16 A, Mathura Road, FARIDABAD 121001 8-28 88 01

Savttri Complex, 116 G.T. Road, GHAZIABAD 201001 a-71 1996

5315 Ward No.29, R.G. Barua Road, 5th By-lane, GUWAHATI 781003 541137

5-8-56C, L.N. Gupta Marg, Nampally Station Road, HYDERABAD 500001 201083

E-52, Chitaranjan Marg, C-Scheme, JAIPUR 302001 37 29 25

1171418 8, Sarvodaya Nagar, KANPUR 208005 21 68 76

Seth Bhawan, 2nd floor, Behind Leela Cinema, Naval ffishore Road, 23 89 23 LUCKNOW 226001

NIT Building, Second Floor, Gokulpat Market, NAGPUR 440010 52 51 71

Patfiputra Industrial Estate, PATNA 800013 26 23 05

Institution of Engineers (India) Building 1332 Shivaji Nagar, PUNE 411005 32 36 35

T.C. No. 1411421, University P. 0. Palayam, THIRUVANANTHAPURAM 695034 621 17

*Sales Office is at 5 Chowringhee Approach, P.O. Princep Street, CALCUTTA 700072

tSales Office is at Novelty Chambers, Grant Road, MUMBAI 400007

*Sales Cffice is at ‘F’ Block, Unity Building, Narashimaraja Square, BANGALORE 560002

271085

309 65 28

222 39 71

Printed at Printograph, New Delhi (INDIA).