is there a need for the come-up time correction factor

Upload: b6d4n0

Post on 02-Jun-2018

218 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    1/7

    S H O R T C O M M U N I C A T I O N

    Is There a Need for the Come-Up Time Correction Factorin Balls Formula Method? A Critical Analysis

    Ricardo Simpson Sergio Almonacid

    Helena Nunez Alejandra Urtubia

    Arthur A. Teixeira

    Received: 3 November 2011 / Accepted: 15 January 2012/ Published online: 15 February 2012

    Springer Science+Business Media, LLC 2012

    Abstract A critical analysis of the correction factor for

    the come-up time (CUT) introduced by Dr. C. Olin Ball inhis Formula Method for thermal process calculations is

    described in this manuscript. In the General Method, the

    effect of the CUT is included in the calculated lethality

    value as long as numerical integration is carried out over

    the entire cold spot temperaturetime profile from the point

    when the steam is turned on. The hypothesis of this com-

    munication is that Balls Formula Method, just like the

    General Method, includes the effect of the CUT in its

    calculations. Balls Formula Method utilizes a curve fit-

    ting of the experimental timetemperature data regardless

    of where the time zero is placed within the come-up time.

    Therefore, the effect of the CUT is automatically included,

    because, as in the General Method, Balls Formula Method

    is fitting and managing experimental data. In addition, the

    regressed timetemperature data used for lethality calcu-

    lations are exactly the same independent of the time zero

    location. To evaluate the rationale of the CUT correction

    factor, computer-simulated timetemperature data and

    experimental runs were evaluated with time zero shifted to

    different locations (100, 70, 42, 20 and 0% of the CUT). In

    addition, the effect of the CUT (shape and length) wasstudied in terms of FHeating and Tg accuracy compared to

    the General Method. Independent of the time shift (the

    location of time zero), the calculations according to the

    Formula Method for total heating time (Pt? CUT) were

    always the same. This work states that it is not necessary to

    shift the location of time zero in Balls Formula Method

    because the calculations over the curve fitting timetem-

    perature data will always include the effect of the CUT

    regardless of where time zero is placed.

    Keywords Balls Formula Method Correction factor

    Come-up time effectiveness Thermal processing Processcalculation techniques

    List of Symbols

    B Balls effective processing time

    CUT Come-up time

    Fo Sterilizing value at 121.1 C

    Fp Process sterilizing value

    FHeating Process sterilizing value at the heating stage

    f Rate factor (related to slope of semi-log heat

    penetration curve)

    fh and fc Heating and cooling rate factors (related to

    slope of semi-log heat penetration curve)

    j Dimensionless lag factor j TRTTATRTIT

    jh and jc Heating and cooling lag factors

    Pt Operators process time (measured from the

    time when the retort reaches processing

    temperature (TRT) until the time when the

    steam is turned off)

    TA Extrapolated initial can temperature obtained

    by linearizing entire heating curve of a can

    R. Simpson (&) S. Almonacid H. Nunez A. UrtubiaDepartamento de Ingeniera Qumica y Ambiental, Universidad

    Tecnica Federico Santa Mara, P.O. Box 110-V, Valparaso,Chile

    e-mail: [email protected]

    R. Simpson S. Almonacid A. UrtubiaCentro Regional de Estudios en Alimentos Saludables (CREAS).

    CONICYT-REGIONAL. R06I1004, Blanco 1623, Room 1402,

    Valparaso, Chile

    A. A. Teixeira

    Department of Agricultural and Biological Engineering,

    University of Florida, Frazier Rogers Hall, P. O. Box 110570,

    Gainesville, FL 32611-0570, USA

    1 3

    Food Eng Rev (2012) 4:107113

    DOI 10.1007/s12393-012-9049-9

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    2/7

    Tg Temperature at the coldest point when cooling

    phase begins

    T Temperature

    IT Initial temperature

    TRT Retort temperature

    Tref Reference temperature, 121.1 C

    t Time

    Time zero In Balls procedure, the location of time zero

    has been shifted and starts when the time

    corresponds to 0.58 * CUT (e.g., if the

    CUT = 10 min, then time zero is located at

    5.8 minute of the regular time)

    tg Time in a thermal process corresponding to

    heat cut off and initiation of cooling phase

    z Temperature change necessary to alter the

    TDT by one log-cycle

    Introduction

    Thermal processing is an important method of food

    preservation used in the manufacture of shelf-stable

    sterilized foods. The basic function of a thermal process is

    to inactivate microorganisms to produce microbiologically

    safe products in sealed containers by applying heat

    treatment at temperatures well above the ambient boiling

    point of water in pressurized steam retorts (autoclaves).

    Excessive heat treatment should be avoided because it is

    detrimental to food quality and underutilizes the capacity

    of the plant.

    The first procedure to calculate thermal processes was

    developed by Bigelow [5] in the early part of the 20th

    century and is usually known as the General Method. The

    General Method makes direct use of the timetemperature

    history at the coldest point within a sealed food container to

    obtain the lethality value of a thermal process. The lack of

    programmable calculators or personal computers until the

    latter part of the 20th century made this method very time-

    consuming, tedious and impractical for most routine

    applications, and it soon gave way to methods offering

    shortcuts. In response to this need, a semi-analytic method

    for thermal processing calculations was developed and

    proposed to the scientific community by Ball [2]. This

    method is the well-known Balls Formula Method, and it

    works in a different way from the General Method. Balls

    Method makes use of the difference between retort and

    cold spot temperatures, which decays exponentially over

    process time, after an initial lag period. Therefore, a semi-

    logarithmic plot of the temperature difference over time

    (after the initial lag) appears as a straight line that can be

    described mathematically by a simple formula that is

    related to lethality requirements by a set of tables that must

    be used in conjunction with the formula [2]. With the

    advent of computers and personal computers, several

    software programs were developed to facilitate the use of

    Balls Formula Method.

    In the decades since Balls Formula Method was

    developed, several questions have arisen regarding itsaccuracy and universality. One possible problem relates to

    the assumption in the method that the semi-logarithmic plot

    of the temperature difference over time (after the initial

    lag) gives a straight line. The question that arises is whe-

    ther the formula, which was derived for a cylindrical

    container, is still relevant today, when sterilized foods are

    packaged in a wide variety of containers in various shapes

    (retortable pouches, trays, etc.). An answer to this doubt

    was found by Carslaw and Jaeger [6], who showed that the

    semi-logarithmic plot is applicable to different geometries

    (rectangular, oval shape, spheres, cones, etc). Another

    potential drawback in Balls Formula Method is that thesemi-logarithmic plot of the temperature has been derived

    for two extreme cases: (a) the perfect mixing of a liquid

    (forced convection) and (b) homogeneous solids (pure

    conduction), when in fact most foods are intermediate to

    these extremes [15]. However, several empirical and the-

    oretical studies [11, 19] have shown that the accuracy of

    the semi-logarithmic plot fits experimental timetempera-

    ture data independent of the heterogeneity of the food

    preparation and also independent of the fact that the retort

    temperature is not instantly raised; this latter phenomenon

    is known as come-up time (CUT).

    The problem with Balls Formula Method arises not in

    its application, which has proven to be sound, but in a

    conceptual error: the addition of the 42% correction factor.

    When Dr. Olin Ball derived his Formula Method, he

    hypothesized that the effect of the CUT was not considered

    in the calculations, based on the assumption that the for-

    mula did not take into account the time required to bring

    retort to actual processing temperature. Consequently, a

    correction factor was added [3]. According to [3], this

    period must have some time value as a part of the process.

    This value may be expressed in per cent of the actual

    length of time consumed Thus, the correction factor of

    42% of the CUT was added to the procedure.

    The hypothesis of this communication is that Balls

    Formula Method, like the General Method, includes the

    effect of the CUT in its calculations, regardless of where

    the time zero is placed within the CUT. Therefore, there is

    no need for a correction factor, and the time zero should

    not be shifted.

    The objectives are to offer a critical analysis of the

    correction factor for the CUT introduced by Dr. C. Olin

    108 Food Eng Rev (2012) 4:107113

    1 3

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    3/7

    Ball in his Formula Method and to show that operators

    process time (Pt) is always the same, regardless of how

    much come-up time is taken into account.

    Fundamentals and Methodology

    The F-value of a given thermal process (lethality) is the

    sum of the lethality achieved during heating and the

    lethality delivered during cooling; it can be expressed as

    follows:

    FProcess FHeating FCooling 1

    FProcess

    Ztg

    0

    10TTref

    z dt

    Zttg

    10TTref

    z dt 2

    As shown in Eq.1, FProcess has been separated as the

    sum of theF-value for the heating stage and the F-value for

    the cooling stage. This analysis will evaluate the accuracyof Balls Formula Method in calculating lethality during

    heating (FHeating) and evaluate the accuracy of its

    prediction of the final cold spot temperature reached at

    the end of heating (Tg).

    Balls Formula Method for calculating the process time

    at a given retort temperature is based on a mathematical

    equation for the straight-line portion of the temperature

    time profile at the can cold spot when plotted on inverted

    semi-log graph paper (assuming finite cylindrical cans) [2].

    This method of data transformation is a straightforward

    mathematical technique and allows Balls Formula Method

    to take on a simple expression that obeys standard heatconduction and convection theory within certain con-

    straints [7,8,13]. There are abundant data in the literature

    showing the accuracy of the Balls procedure for heat

    transfer in a mixed mode for heterogeneous foods (con-

    ductionconvection) and for packaged foods other than

    standard cylindrical cans.

    The equation that Ball derived for the straight-line

    heating curve can be expressed as follows [2, 13]:

    t f log jTRTIT

    TRTT

    3

    Where: j TRTTATRTITEquation3 has been critically analyzed by Merson et al.

    [13]. As was shown by Datta [7], the latter expression is

    valid not only for finite cylinders but also for arbitrary

    shapes (rectangular, oval shape, infinite slab, etc.). The

    main limitation is that for food heated by conduction, the

    expression is only valid for heating times beyond the initial

    lag period (when the Fourier number[ 0.6). Although in

    the majority of sterilized food products, the heat transfer

    process is not strictly conduction or forced convection, as

    mentioned, Eq.3has proven to be practically useful when

    the heating rate (fh) and the heating lag (jh) parameters are

    obtained experimentally.

    Correction Factor for Come-Up Time According

    to the Scientific Literature

    Given that Eq.3 theoretically considers that TRT (retorttemperature) is instantly reached, the Ball procedure

    introduced the correction factor (42% of the CUT)

    assuming that the contribution of the CUT in the F-value

    calculation was not taken into account. Ball [2] experi-

    mentally determined a value of 42% for the contribution of

    the CUT period to the total effect of cumulated lethality [8,

    13]. This value is generally considered conservative [8].

    Figure1 depicts graphically the classical way that Dr. Olin

    Ball incorporated this CUT correction factor in his calcu-

    lation of the effective process time (B).

    The operators process time at retort temperature (Pt) for

    a commercial operation is measured from the time whenthe retort reaches processing temperature (TRT), to the

    time when the steam is turned off and the cooling water is

    supplied. In Balls Formula Method, the effective process

    time (B) is the sum of the operators process time and 42%

    of come-up time, as follows:

    B P t 0:42CUT 4

    Over the years, researchers have attempted to reveal the

    real impact or effect of the CUT in the total cumulated

    lethality. The factor of 42% is generally regarded as a

    conservative estimate and is applicable only to batch retorts

    with a linear heating profile. Although the lethal effects ofthe CUT at the product center of a container are small for

    most canned food products, thin-profile plastic packages

    processed under steamair or water spray could experience

    a more significant lethal effect from the CUT. Merson et al.

    [13] mention that it is incorrect to assume that the heating

    Fig. 1 Graphical representation of the correction factor in Balls

    procedure

    Food Eng Rev (2012) 4:107113 109

    1 3

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    4/7

    medium surrounding the can is suddenly raised to

    processing temperature. Spinak and Wiley [16] found

    that the CUT effectiveness varied from 3577%.

    Ramaswamy [14], using thin-profile retort packages and

    two retort temperature profiles, one linear and the other

    logarithmic, showed that the traditional 42% CUT was

    appropriate for the former, but that for the latter the values

    were twice as large. Except for package thickness, otherfactors had only a small influence on the CUT. For other

    types of retorts, initial conditions and venting procedures,

    abundant literature is available [1, 4, 9, 10, 17, 20]. As

    shown, although the scientific literature has addressed

    Balls inclusion of the CUT correction factor, none has

    addressed the central conceptual flaw analyzed in this

    manuscript, which states that the correction factor is not

    necessary to perform the correct calculations when using

    Balls Formula Method.

    Correction Factor for Come-Up Time Under Critical

    Scrutiny

    As stated by Dr. Olin Ball in his original work and later

    confirmed by several authors, there is no doubt that the

    CUT length and shape effectively contribute to the lethal

    effect. In addition, as reported by different authors, their

    contributions will vary with package geometry, size, etc.

    [14, 16]. However, the real question is to understand

    whether or not this effect is considered in Balls Formula

    Method.

    The hypothesis of this communication is that Balls

    Formula Method, like the General Method, takes into

    account the effect of the CUT in its calculations, regardless

    of where the zero time line is placed within the come-up

    time (see Fig.1).

    Supporting this argument is the fact that Balls Formula

    Method requires the experimental data to be fit to a curve.

    Because of this, the linear regression of the heat penetra-

    tion data always fits the same experimental data indepen-

    dent of the location of time zero. Thus, when calculating

    the heating lethality (FHeating), the CUT effect is always

    considered. Possibly, a real concern should be the qual-

    ity of the accuracy of Eq.3 in terms of goodness of fit

    during the heating stage, depending on the CUT shape and

    length and the value of fh. Although substantial empirical

    evidence has shown a high correlation when fitting the

    straight-line portion of the temperaturetime profile to

    experimental data, this evidence is tested here using several

    computer-based experiments.

    In order to evaluate the effect of time shift on the pre-

    diction of operators process time (Pt), several experiments

    were conducted. The implications of the time zero location

    (time shift) were investigated for a cylindrical container

    with an inner diameter of 83 mm and a height of 106 mm.

    Computer simulations were executed for an FP of 6 min

    under the following operating conditions: (a) retort tem-

    perature of 120 C; (b) initial temperature of the product at

    20 C; (c) CUT of 10 min; and (d) thermal diffusivity of

    1.7E - 7 m2/s. Three different shapes of CUT were ana-

    lyzed: (a) linear, (b) convex and (c) concave.

    Next, the time zero location was analyzed for an

    experimental run of a tuna fish product in a cylindricalcontainer with an inner diameter of 83 mm and a height of

    41 mm under the following operating conditions: (a) retort

    temperature of 117 C, (b) initial temperature of the

    product at 31 C and (c) CUT of 29 min. This analysis was

    conducted to test and validate the hypothesis. The chosen

    product was a classical practical example of a heat con-

    duction food.

    In addition, the time zero location was analyzed for a

    simulated and an experimental run of a retortable pouch

    (rectangular shape). In the case of the simulated run, the

    dimensions of the pouch were 25 mm width and 300 mm

    length under the following operating conditions: (a) retorttemperature of 125 C, (b) initial temperature of the

    product at 20 C and (c) CUT of 10 min. In the case of the

    experimental run, the dimensions of the pouch were 10 mm

    width and 80 mm length under the following operating

    conditions: (a) retort temperature of 120 C, (b) initial

    temperature of the product at 11 C and (c) CUT of 6 min.

    To further test and validate the hypothesis, these experi-

    ments were devised also to consider products packaged in

    new container formats such as retortable pouches.

    Comparisons Among Lethality Calculations at the End

    of the Heating Stage (FHeatingand Tg)

    Calculations of the lethality reached at the end of heating

    (FHeating), andTgfor different products and retort processes

    were carried out using Balls Formula Method and com-

    pared with those calculated by the General Method. To

    examine a wide variety of food products and CUT lengths,

    fh times ranging from *20 to *160 min [18] were

    selected and CUT times from 5 to 30 min were chosen

    [12].

    Data Generation and Computer Search

    Heat penetration data were generated by computer software

    (C??) that executed an explicit finite difference solution to

    the general heat conduction equation for a finite cylinder.

    The calculations for F-value, according to the General

    Method, were performed at the geometric center (cold spot)

    using Simpsons numerical integration rule with a time

    interval of 30 s. In the case of Balls Formula Method

    calculations (B, FHeatingand Tg), timetemperature data up

    to the end of heating that were generated by the

    110 Food Eng Rev (2012) 4:107113

    1 3

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    5/7

    aforementioned software were fitted with Eq. 3 to obtain

    the heat penetration parameters fh and jh (for different

    locations of time zero).

    Results and Discussion

    Simulated and experimental runs consistently demonstratedthat independent of the time zero location, the obtained

    results for operators process time (Pt) were always the

    same (Tables1, 2, and 3). In addition, computer experi-

    ments carried out for a wide range of fh values

    (20160 min) also proved the accuracy of Balls Formula

    Method in relation to FHeatingand Tg.

    Time Shift

    Table1 shows the results for operators process time (Pt) for

    different CUT contributions, from 0 to 100%, where 100%

    contributionmeans that thetime zero was not shifted. In everycase, independent of the contribution or CUT shape (linear,

    concave or convex), the operators process time was exactly

    the same, meaning that independent of the time zero location,

    the contribution of theCUT is strictly taken into account in the

    FHeating calculation by Balls Formula Method. In addition,

    experiments for different container sizes and geometries were

    performed and showed the same results.

    Table2 shows the results for operators process time

    (Pt) for different CUT contributions for an experimental

    run of a tuna fish product. Again, independent of the

    contribution of the CUT, the operators process time wasthe same. In this experimental run, the shape of the CUT is

    not only arbitrary but also unusually long, as depicted in

    Fig.2. As was anticipated, the Pt was always the same,

    regardless of the different CUT contributions.

    Table3 shows the results for operators process time

    (Pt) for different CUT contributions for both a simulated

    run and an experimental run of a retortable pouch. As was

    observed in Tables1 and2, the operators process time was

    the same, independent of the contribution of the CUT.

    Accuracy of the Formula Method on FHeatingand Tg

    Table4 shows the calculations for FHeating and Tg by the

    General Method and by Balls Formula Method. Experi-

    ments were selected to represent most, if not all, of the

    Table 1 Prediction of

    operators process time (Pt)

    using different time zero

    locations for a linear, concave

    and convex CUT

    a Standard contribution of

    come-up time (42%) introduced

    in Balls Formula Method

    % of CUT fh jh B (min) Pt (min)

    Linear CUT (min) 100 55.5 2.33 92.0 82.0

    70 55.5 2.06 89.0 82.0

    42a 55.5 1.84 86.2 82.0

    20 55.5 1.67 84.0 82.0

    0 55.5 1.51 82.0 82.0Concave CUT (min) 100 55.4 2.14 97.6 87.6

    70 55.4 1.89 94.6 87.6

    42a 55.4 1.68 91.8 87.6

    20 55.4 1.53 89.6 87.6

    0 55.4 1.41 87.6 87.6

    Convex CUT (min) 100 55.4 2.41 100.6 90.6

    70 55.4 2.13 97.6 90.6

    42a 55.4 1.90 94.8 90.6

    20 55.4 1.73 92.6 90.6

    0 55.4 1.59 90.6 90.6

    Table 2 Prediction of

    operators process time (Pt)

    using different zero time

    locations for an experimental

    run of tuna fish product

    a Standard contribution of

    come-up time (42%) introduced

    in Balls Formula Method

    CUT (min) % of CUT fh jh B (min) Pt (min)

    29 100 30.9 4.43 81.0 52.0

    70 30.9 2.32 72.3 52.0

    42a 30.9 1.26 64.2 52.0

    20 30.9 0.79 57.8 52.0

    0 30.9 0.51 52.0 52.0

    Food Eng Rev (2012) 4:107113 111

    1 3

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    6/7

    processes that occur in industrial practice [18]. Independent

    of product and can dimensions, characterized by a widerange offh, and CUT length, the estimation ofFHeatingand

    Tg by the General Method and the Formula Method is

    practically the same. The results confirm that there is a high

    correlation when fitting the straight-line portion of the

    temperaturetime profile to experimental data.

    This work has shown that Balls Formula Method can be

    as accurate as the General Method at the heating stage and

    that it always takes the come-up time into account. Thus,

    there is no need for correction factors or shifting time zero

    because the parameters in Eq.3 have been estimated from

    a regression analysis of the experimental data through thestraight-line segment of the heat penetration curve. The

    graphical location of the experimental timetemperature

    data points is a direct result of the length and shape of the

    temperature time profile during the come-up time. Thus, if

    the regression generates an adequate goodness of fit

    (implicitly confirmed by the results of Table4), the

    F-value calculations by the Formula Method will be as

    accurate as the General Method. The accuracy over the

    heating curve has been shown repeatedly with both

    experimental temperaturetime data as well as data gen-

    erated by computer models. However, prudence dictates

    further testing of the goodness of fit of Eq. 3 in new orunusual cases, such as new packages (retort pouches,

    shallow trays) and/or new autoclaves with different forms

    of heat exchange media and venting procedures.

    As was hypothesized, operators process time, FHeatingand Tg are independent of the time zero location. The

    Table 3 Prediction of

    operators process time (Pt)

    using different time zero

    locations for both a simulated

    run and an experimental run of a

    retortable pouch

    a Standard contribution of

    come-up time (42%) introduced

    in Balls Formula Method

    % of CUT fh jh B (min) Pt (min)

    Simulated CUT 10 (min) 100 12.4 3.73 25.0 15.0

    70 12.4 2.14 22.0 15.0

    42a 12.4 1.27 19.2 15.0

    20 12.4 0.85 17.0 15.0

    0 12.4 0.58 15.0 15.0

    Experimental CUT 6 (min) 100 6.6 2.47 24.0 18.0

    70 6.6 1.32 22.2 18.0

    42a 6.6 0.74 20.5 18.0

    20 6.6 0.47 19.2 18.0

    0 6.6 0.31 18.0 18.0

    Fig. 2 Experimental run for a tuna fish product packaged in a

    cylindrical can with a diameter of 83 mm and a height of 41 mm

    Table 4 Calculations of heating lethality (FHeating) andTgthrough Balls Formula Method and General Method for a wide variety of processes

    with fh ranging from *20 to *160 min and CUT length from 5 to 30 min

    fh (min) CUT (min)

    5 10 20 30

    21.6 4.2a 117.7b 3.8 117.6 4.2 117.6 3.7 117.5

    4.2c 117.7d 3.8 117.5 4.2 117.7 3.7 117.5

    55 3.1 114.7 3.2 114.8 3.1 114.7 3.1 114.7

    3.1 114.7 3.2 114.8 3.1 114.7 3.1 114.7

    93 3.0 113.2 3.1 113.5 3.1 113.6 3.1 113.5

    3.0 113.4 3.1 113.5 3.1 113.6 3.1 113.5

    159.6 2.1 110.3 2.0 110.3 2.0 110.2 2.1 110.3

    2.1 110.3 2.0 110.3 2.0 110.3 2.1 110.3

    a and b are theFHeatingand Tgcalculated by the Balls Formula Method and c and d the respective values calculated by the General Method. The

    results in each cell follow the same left-to-right a, b, c, d sequence shown in upper left for CUT 5 and fh 21.6

    112 Food Eng Rev (2012) 4:107113

    1 3

  • 8/11/2019 Is There a Need for the Come-Up Time Correction Factor

    7/7

    experimental data considered for their calculations are

    always the same. In support of these results, it is essential

    to note that the required temperature data for FHeatingcal-

    culations are always beyond the CUT, because in order to

    have an impact in the cumulative lethality, the temperature

    of the coldest point should be above 100 C.

    Final Remarks

    The prediction of operators process time (Pt) by Balls

    Formula Method was the same regardless of where time

    zero was placed within the come-up time (or the CUT

    contribution). This result is due to the linear regression of

    heat penetration data along the straight-line portion of the

    semi-log heat penetration curve, which produces a mathe-

    matical expression (Balls Formula Method) that predicts

    the same timetemperature history independent of the time

    zero location. In addition, given that high correlations were

    obtained in all cases, the calculation of the F-value fromthe regressed data (Balls procedure) was essentially

    identical to the F-value calculated by the General Method,

    which is based directly on the experimental data points. It

    has also been shown that temperaturetime histories pre-

    dicted by Eq.3always have a high correlation (implicitly

    confirmed by the results of Table4) with experimental data

    points, independent of the CUT shape and length, meaning

    that the F-value at the end of heating is well estimated.

    Finally, it was concluded that inaccuracies in Balls

    Formula Method could be attributed in almost 100% of

    cases to the cooling calculations.

    Acknowledgments We kindly appreciate the contribution made by

    Dr. Alik Abakarov (Universidad Politecnica de Madrid, Spain).

    Authors Ricardo Simpson and Sergio Almonacid are grateful for the

    financial support provided by CONICYT through FONDECYT pro-

    ject number 1090689.

    References

    1. Alstrand DV, Benjamin HA (1949) Thermal processing of canned

    foods in tin containers. V. Effect of retorting procedures on

    sterilization values for canned foods. Food Res 14(3):253257

    2. Ball CO (1923) Thermal processing time for canned foods.

    Bulletin 71, vol 37. National Research Council, Washington

    3. Ball CO, Olson FCW (1957) Sterilization in food technology

    theory, practice and calculations. McGraw-Hill, New York

    4. Berry MR Jr (1983) Prediction of come-up time correction factors

    for batch-type agitating and still retorts and the influence on

    thermal process calculations. J Food Sci 48(3):12931299

    5. Bigelow WD, Bohart GS, Richardson AC, Ball CO (1920) Heat

    penetration in processing canned foods. Bulletin no. 16-L.

    Research Laboratory, National Canners Association, Washington

    6. Carslaw HS, Jaeger JC (1959) Conduction of heat in solids.

    Oxford University Press, London

    7. Datta AK (1990) On the theoretical basis of the asymptotic semi

    logarithmic heat penetration curves used in food processing.

    J Food Eng 12(3):177190

    8. Holdsworth SD, Simpson R (2007) Thermal processing of

    packaged foods, 2nd edn. Springer, New York

    9. Ikegami Y (1974a) Effect of various factors in the come-up time

    on processing of canned foods with steam. Report Tokyo Institute

    of Food Technology, serial no. 11, pp 9298 (in Japanese)

    10. Ikegami Y (1974b) Effect of come-up on processing canned

    food with steam. Canners J 53(1):7984 (in Japanese)

    11. Ikegami Y (1977) Heat penetration in canned foods containing

    solids and liquid. Canners J 56(7):548552

    12. Kelder JC (2010) Personal communication. Unilever, Vlaardingen

    13. Merson RL, Singh RP, Carroad PA (1978) An evaluation of

    Balls Formula Method of thermal process calculations. Food

    Technol 32(3):6676

    14. Ramaswamy HS (1993) Come-up time effectiveness for process

    calculations involving thin-packages. J Food Eng 19(2):109117

    15. Simpson R, Almonacid S, Teixeira A (2003) Bigelows general

    method revisited: development of a new calculation technique.

    J Food Sci 68(4):13241333

    16. Spinak SH, Wiley RC (1982) Comparisons of the general and

    Ball Formula Methods for retort pouch process calculations.

    J Food Sci 47(3):880888

    17. Succar J, Hayakawa K (1982) Prediction of time correction factor

    for come-up heating of packaged liquid food. J Food Sci

    47(3):614618

    18. Stumbo CR, Purohit KS, Ramakrishnan TV, Evans DA, Francis

    FJ (1983) Handbook of lethality guides for low-acid canned

    foods. CRC Press, Boca Raton

    19. Uno J, Hayakawa K (1980) Correction factor of come-up heating

    based on critical point in a cylindrical can of heat conduction

    food. J Food Sci 45(4):853859

    20. Uno J, Hayakawa K (1981) Correction factor of come-up heating

    based on mass average survivor concentration in a cylindrical can

    of heat conduction food. J Food Sci 46(5):14841487

    Food Eng Rev (2012) 4:107113 113

    1 3