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    Yoghurt FruitPreparations

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    2 3

    Y O G H U RT F R U I T P R E PA R AT I O N S 4

    R E Q U I R E M E N T S F O R Y O G H U R T F R U I T P R E PA R AT I O N S 6

    General requirements with regard to production, storage and transport 6

    General requirements with regard to further processing 8

    Specific requirements for stirred yoghurts 8

    Specific requirements for layered products 9

    D E T E R M I N I N G T H E Q U A L I T Y C R I T E R I A 10

    Rheological characterisation of flow behaviour 10

    Mixing behaviour when added to the milk product 17

    Tendency to syneresis 18

    G E L L I N G B E H AV I O U R O F H & F P E C T I N S 19

    Pectin structure 19

    Gelling mechanisms 20

    Factors influencing the gelation 22

    H & F P E C T I N S F O R Y O G H U R T F R U I T P R E P A R AT I O N S

    S E L E C T I V E L Y I N F L U E N C I N G T H E T E X T U R E ,

    F L O W B E H AV I O U R A N D M I X I N G B E H AV I O U R 32

    Influence of the calcium ion concentration on texture, regenerative capacity and

    mixing behaviour 34

    H IG H M E TH YL ES TE R P EC TI NS F OR Y OG HU RT F RU I T P RE PA R AT IO NS 36

    C O M B I N I N G H & F P E C T I N S W I T H O T H E R H Y D R O C O L L O I D S 37

    S E L E C T E D R E C I P E S 38

    H&F Classic Apple Pectins 38

    H&F Amid Pectins 42

    S P E C I F I C B E N E F I T S O F H & F A P P L E P E C T I N S 45

    O V E R V I E W 46

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    Rheological Characterisation of the Flow

    Behaviour of Yoghurt Fruit Preparations

    The flow behaviour of yoghurt fruit prepara-

    tions can be characterised by determining the

    following parameters, using, for example, a

    shear-stress controlled rheometer:

    Viscosity

    Yield point

    Regenerative capacity

    Viscosity is the property of substances

    indicating their resistance to flow.

    Fruit preparations are shear-thinning, pseudo-

    plastic substances where viscosity drops with

    increasing shear stress (shear rate). Therefore,

    shear-thinning products are subject to a drop in

    viscosity (shear-thinning) during processing

    due to stress (pumping, stirring). During the

    idle state or when exposed to little stress,

    these products have a high viscosity.

    As yoghurt fruit preparations have to be

    frequently pumped or stirred during the manu-

    facturing process, the level of the stress-depen-

    dent viscosity is an important factor.

    The shear stress (shear rate) that can act on the

    fruit preparation differs depending on the

    production facility. In the case of pumping it

    depends on the pipe geometry and the pumps

    delivery rate, with stirring it is mainly determi-

    ned by the stirring speed and the container

    geometry.

    If the viscosity is low during pumping and stir-

    ring, not only is less force and energy required

    to execute the process but the product is also

    prevented from damage due to the smaller

    force exerted, so that fruits or fruit components

    are better preserved.

    The quality criteria of yoghurt fruit prepara-

    tions are mainly determined by their rheologi-

    cal flow behaviour. The formulation of the fruit

    preparation as well as the thickening agents

    used have a decisive effect on the flow beha-

    viour.

    The mixing behaviour with the milk product

    and the syneresis behaviour also affect the

    quality of yoghurt fruit preparations.

    Pectins for yoghurt fruit preparations, such as

    Low Methylester Classic Apple Pectins and Low

    Methylester Amidated Pectins from H&F, are

    systematically standardised to a specific flow

    behaviour. Thus if the appropriate pectin is se-

    lected for a pre-determined formulation, opti-

    mum products are obtained.

    Fig. 2: target profile

    linear rise of shear rate

    Fig. 3: measurement result

    viscosity as function of the shear rate

    Determining the viscosity of

    yoghurt fruit preparations (Fig. 2+3)

    1110

    shear-thinning

    flow behaviour

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    1918

    Tendency to Syneresis

    Syneresis is the release of liquid from gels,

    especially after mechanical destruction of the

    gel network.

    In yoghurt fruit preparations syneresis is un-

    desirable. Especially in layered products, where

    the release of liquid is likely to discolour the

    white milk product, it is important to use fruit

    preparations showing little or no tendency to

    syneresis.

    To determine syneresis behaviour, a defined

    amount of fruit preparation is mechanically

    destroyed under specified conditions and then

    filled into a funnel. The released liquid is

    collected in a test tube or measuring glass. The

    lower the amount of liquid released from the

    test fruit preparation over a specified time

    period, the lower its tendency to syneresis.

    Pectin Structure

    Pectin is an important structure-giving element

    of all plant foods. Chemically speaking, pectin

    is a macromolecular compound belonging to

    the heteropolysaccharides. Its main component

    is polygalacturonic acid, which is partly esteri-

    fied with methanol.

    Pectins with a degree of esterification of 50%

    or more are known as high methylester pectins,

    whereas pectins of a DE below 50% are known

    as low methylester pectins.

    Low methylester amidated pectins are obtained

    if methylester groups are replaced by amidated

    groups under ammoniacalic conditions.

    Degree of esterification and degree of amida-

    tion indicate the percentage of esterified or

    amidated galacturonic acid units.

    Fig. 9: Molecular structure of pectin

    Fig. 8:

    Syneresis test

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    3332

    For use in yoghurt fruit preparations H&F offers

    low methylester and low methylester amidated

    pectins, leaving it up to the user to influence

    the specified properties by adding calcium

    ions.

    In addition to this, H&F offers pectins that have

    already been standardised to a specific flow

    behaviour with the respective buffering

    agents, and which are thus able to meet the

    high demands on yoghurt fruit preparations.

    Texture, regenerative behaviour and mixing

    behaviour of yoghurt fruit preparations made

    with low methylester or low methylester

    amidated pectins can be influenced very preci-

    sely by selecting the appropriate formulation

    parameters, and especially by adding buffering

    agents (e.g. calcium salts).

    This results in fruit preparations which, depen-

    ding on the customers requirements, can range

    from viscous and capable of regenerating to

    visco-elastic, and which meet the requirements

    of the respective products (stirred yoghurts,

    layered products, fruit-corner products).

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    4140

    Pectin Classic AY 905 is standardised to constant

    flow behaviour and produces textures of rege-

    nerative capacity with high yield points and

    sufficiently high viscosity. The fruit preparations

    have good fruit retention properties and can

    be easily mixed with the milk product without

    diluting the final product.

    H&F Classic Pectins in Fruit Preparations for

    Stirred Yoghurt

    H&F offers Special Pectin Classic AY 905 for use

    in fruit preparations for stirred yoghurt. When

    this pectin is used, a calcium salt must be added

    separately in order to control the texture and

    to adjust the rheological properties. During

    production of the fruit preparation, the calcium

    salt dosage is specifically adjusted to the pro-

    perties intended for the final product.

    Pectin Classic AY 901

    160g pectin solution 5% (= 0.8%)

    400g fruit

    500g sucrose, crystalline

    x ml sodium citrate solution 10%,

    to adjust the pH-value

    Net weight: 1060gOutput weight: 1000g

    SS content: 55%

    pH-value: 3.6-3.8

    Manufacturing:

    A Make pectin solution (see Technical

    Application Information).

    B Mix fruit and sucrose and heat to

    approx. 90C.

    C Add hot pectin solution and decoct to

    final soluble solids.

    D Add sodium citrate solution to adjust

    the pH.

    E Adapt filling temperature to container

    size.

    Herbstreith & Fox KG Recipe

    Product

    Pectin Classic AY 905

    170g pectin solution 5% (= 0.85%)

    400g fruit

    250g sucrose, crystalline

    230g water

    0.5g tri calcium citrate x 4H2O

    x ml sodium citrate solution 10%,

    to adjust the pH-value

    Net weight: 1050g

    Output weight: 1000g

    SS content: 30%

    pH-value: 3.6-3.8

    Manufacturing:

    A Make pectin solution (see Technical

    Application Information).

    B Add fruit, sucrose, calcium citrate and

    water and heat to approx. 90C.

    C Add hot pectin solution and decoct to

    final soluble solids.

    D Add sodium citrate solution to adjust

    the pH.

    E Adapt filling temperature to container

    size.

    Herbstreith & Fox KG Recipe

    Product

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    46

    Pectin DE

    [%]

    A

    [%]

    Standardisation with

    neutral sugars and

    composition

    Characteristics and

    properties of the fruit

    preparations

    Main area

    of application

    Amid CF 005 33-39 11-15 E 440

    stable breaking strength,

    stable gel strength

    amidated citrus pectin

    low calcium reactivity

    high yield point

    fruit preparations for

    yoghurt

    (SS 50-65%, pH 3.5-4.0)

    Amid CF 010 31-35 15-19 E 440stable breaking strength,

    stable gel strength

    amidated citrus pectinmedium calcium reactivity

    high yield point

    fruit preparations foryoghurt

    (SS 30-50%, pH 3.5-4.0)

    Amid CF 020 28-31 19-22 E 440

    stable breaking strength,

    stable gel strength

    amidated citrus pectin

    high calcium reactivity

    high yield point

    fruit preparations for

    yoghurt

    (SS 10-30%, pH 3.5-4.0)

    Amid AY 005-C 34-39 6-10 E 440, E 331, E 340

    stable gel strength

    amidated apple pectin

    high calcium tolerance

    fruit preparations for

    yoghurt, yoghurt drinks

    (SS 10-60%, pH 3.5-4.0)

    Classic AY 901 41-48 - E 440, E 341stable flow behaviour

    stable calcium reactivity

    apple pectinlow calcium reactivity,

    able to regenerate

    calcium needs to be added

    with low SS

    fruit preparations forlayered products

    (SS 45-65%, pH 3.5-4.0)

    Classic AY 905 34-37 - E 440

    stable calcium reactivity,

    stable flow behaviour

    apple pectin

    able to regenerate,

    high yield point

    calcium needs to be added

    with low SS

    fruit preparations for

    stirred yoghurts

    (SS 20-50%, pH 3.6-4.0)

    Classic AY 601 52-57 - E 440, E 333

    stable flow behaviour

    apple pectin

    able to regenerate

    high viscosity,

    very smooth texture

    calcium needs to be added

    with low SS

    fruit preparations for

    layered products

    (SS 30-50%, pH 3.2-4.0)

    Classic AM 901 38-44 - E 440

    stable calcium reactivity,

    stable flow behaviour

    apple pectin

    low calcium reactivity

    fruit preparations with

    multi-purpose functions

    (yoghurt fruit preparation

    increases the viscosity of

    the fruit yoghurt)

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    Corporate

    Group

    Herbstreith&FoxKGTurnstrae3775305Neuenbrg/Wrtt.Ge

    rmany

    Phone:+4970827913-0

    Fax:+49708220281

    E-Mail:[email protected]:www.herbstreith-fox.com

    www.directeam.de 1. edition