jorge martins ana pereira - tecnicelpa.com
TRANSCRIPT
Jorge Martins
Ana Pereira Martinchel 30Jun2016
efficiency for industry Cetaminereg Technology
THE TRIP
3
Boiler water treatment programmes Film formation on metal surfaces amp Magnetite layer
stabilization Improvement of heat transfer rate
Cetamine Concepts ndash Benefits for your System Case studies Approvals amp References
Cetamine Analysis
17-06-2016
Boiler Water Treatment Programmes
Steam Conditioning
Oxygen Scavenging
BOILER WATER CYCLE
Traditional treatment approach
5
Anti-Scaling amp Dispersing
17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
efficiency for industry Cetaminereg Technology
THE TRIP
3
Boiler water treatment programmes Film formation on metal surfaces amp Magnetite layer
stabilization Improvement of heat transfer rate
Cetamine Concepts ndash Benefits for your System Case studies Approvals amp References
Cetamine Analysis
17-06-2016
Boiler Water Treatment Programmes
Steam Conditioning
Oxygen Scavenging
BOILER WATER CYCLE
Traditional treatment approach
5
Anti-Scaling amp Dispersing
17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
THE TRIP
3
Boiler water treatment programmes Film formation on metal surfaces amp Magnetite layer
stabilization Improvement of heat transfer rate
Cetamine Concepts ndash Benefits for your System Case studies Approvals amp References
Cetamine Analysis
17-06-2016
Boiler Water Treatment Programmes
Steam Conditioning
Oxygen Scavenging
BOILER WATER CYCLE
Traditional treatment approach
5
Anti-Scaling amp Dispersing
17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Boiler Water Treatment Programmes
Steam Conditioning
Oxygen Scavenging
BOILER WATER CYCLE
Traditional treatment approach
5
Anti-Scaling amp Dispersing
17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Steam Conditioning
Oxygen Scavenging
BOILER WATER CYCLE
Traditional treatment approach
5
Anti-Scaling amp Dispersing
17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 6
PRODUCTS amp DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
New Volatile Film Forming Approach
7
BOILER WATER CYCLE
Alkalising Amines
Film Forming Amines Dispersants
All-in-one product concept
to treat the
whole
Watersteam
cycle
17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Traditional Treatment Film Forming
Based Concept
Phosphates Caustic
Dispersants Film Forming Amines
Alkalizing Amines
Dispersants
Oxygen Scavengers
Alkalizing Amines
Ammonia
BOILER WATER TREATMENT CONCEPTS
6172016 8
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
1
1 2
2
3
3
3
1
2
3
Oxygen scavenger
Internal treatment
Steam treatment 9
PRODUCTS amp TYPICAL DOSING POINTS TRADITIONAL TREATMENT CONCEPT
17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetamine Alternative Dosing Points
Make-up Water
Filtration Unit
eg Ion Exchanger Reverse Osmosis
Boiler
Blow-down Feedwater
Boiler feeding Pump
Ste
am
Consumer
Condenser
Retu
rn
Co
nd
en
sa
te
Cooling Water
Deaeration
Reservoir of feedwater
10
PRODUCTS amp DOSING POINTS CETAMINEreg TECHNOLOGY
17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Traditional Cetaminecopy
TRADITIONAL APPROACH vs CETAMINEreg
11 17-06-2016
Single active andor combination products Combination Multipurpose products =gt easy to handle and to control
Increase of conductivity ( solids ) Only slight effect on conductivity (all organic)
Toxicity of Hydrazine and other components No toxic ingredients
Corrosion risk after stop of dosage No corrosion during short shut-downs
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
MAIN ASPECTS - PART 1 CETAMINEreg CONCEPT
Simple to
use
Energy amp Water
Savings
Corrosion Protection
Automati
zation
Reference amp
Versatillity
17-06-2016 12
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
13
100 organic Treatment (no cond increase
Patented Technology
Improvement of Corrosion (CFA)
Formulated All-in-One product
Very Easy to apply
FDA amp Kosher compliance
Versatility (multiple applications)
Improvement in Heat Exchange Rate
Savings of Water and Energy
Improvement of Corrosion Protection (Economizer wet lay up crisis situation)
Cetaminereg
Cetaminereg
17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Adsorption and Formation of a Protective Film on Metal Surfaces
Film Formation Principles
untreated Cetaminereg
Protective Film
Metal
Molecules in water phase
Hydrophobic Barrier between Water and Metal
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Confocal Laser Scanning Microscopy (CLSM) of Tube Surfaces
Cetamine technology - low micro roughness - homogeneous surface
Na3PO4
- high micro roughness - inhomogeneous surface
Magnetite Layer Stabilization Studies University of Rostock Germany
100 mm
17-06-2016 15
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
a) PO4
b) Cetamine V211
(Different Scales)
Cross Section Examination of Tube Surfaces
Cetamine Treatment
Traditional Treatment
15 um
5 um
Magnetite Layer Stabilization Studies University of Rostock Germany
bull Cetaminereg forms - A more compact layer - a layer more homogenoeus (less thickness and porosity)
17-06-2016 16
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
3 Fe + 4 H2O Fe3O4 + 4 H2
Magnetite Layer in Water-Tube Boiler
At high temperature the oxidizing effect of water enables magnetite production
Cetamine prevents diffusion of oxygen towards the surface Oxygen Catalytic effect is suppressed and the magnetite production is stabilized
Takes place at temperatures gt 100 degC Reaction is very fast at temperatures gt 200 degC
Thick and porous stable Magnetite layer Acidic cleaning necessary if densitygt 400 gmsup2
MAGNETITE LAYER STABILIZATION
SHIKORR REACTION
17 6172016
Dissolved Oxygene acts as Catalyst O2
T
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Impact of Cetaminereg on metallic surfaces
Easy Simulation of the Heat Transmission Process
bull Increased number of steam bubbles with
Cetaminereg
bull Increased the frequency of bubbles and decrease of the diameter of the bubbles
Na3PO4 treatment
Cetaminereg treatment
18
17-06-2016
bull First evidences in the improvement of heat
Transmission
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Impact of Cetaminereg on metallic surfaces
Pictures of the tubes during the Thermal Efficiency examinations bull Cetaminereg produces more steam at same
energy
bull Increase of the frequency of steam bubbles decreases the size of the bubbles
bull More active points for energy transfer
Cetaminereg treatment
Phosphate treatment
19
bull Improvement of Heat Transfer Rate
bull All the surface transmit heat more
homogeneous (less corrosion effect) 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
20
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
21
untreated Cetaminereg
pretreated
Test Conditions C (acetic acid) = 2 ppm pH = 47 T = 80 degC Fast motion of 40 minutes
FILM FORMATION ON METAL SURFACES CORROSION PROTECTION UNDER ACIDIC CONDITIONS
17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetaminereg Application Monitoring amp Control
Cetaminereg Test Kit
Cetaminereg Photometric Method
Cetaminereg Online Monitoring System
17-06-2016 22
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
HOW IT ACHIEVES WATER AND ENERGY SAVINGS
CETAMINEreg CONCEPT
17-06-2016 23
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetamine is All-Organic Product
No increase of conductivity in boiler water
Reduction of Carry-Over
Saving of energy and water costs (an average over 20
of water and energy savings based in actual experiences
and references)
COST REDUCTON
Traditional Cetaminereg
Cetaminereg Benefits for your System
Due the decrease of blow-down 24
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Improvement of the Heat Transfer Rate
Rostock PhD study
COST REDUCTON
Cetaminereg Benefits for your System
Due a thinner passive layer 25
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Improvement of Corrosion Protection
Easy Procedure for boiler Conservation
No need of application of N2 or dry air
No need to overdosing ox scavenger
It does not accelerates the formation of magnetite
Excellent Corrosion Protection
Coupling time to turbine significantly improved
Faster restarts after shut-down period
Boiler preservation can be done using the same operation product Flexibility
Corrosion Inhibition
Wet amp Dry Lay Up
17-06-2016 26
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Dosing proportional to the make-up water
instead of feed water
Reduces the volume and cost of
dosing depending on the
application
( of condensate recovery degaser etc)
COST
REDUCTION
Cetaminereg Benefits for your System
Due a stable product dosageconsumption
make-up
17-06-2016 27
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Dosing a single liquid product rather than
multiple products
Easier to handle no mixing or dilution
less equipment costs storage and
logistics
Optimizing manpower control timetasks
COSTTIME
REDUCTION
Cetaminereg Benefits for your System
Due a simple dosing amp control 17-06-2016 28
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Lower dosing and no hydrazine sulphites phosphates or nitrites
Less costs for using non-toxic
chemistries and less
blowdown treatment before
discharging to effluent
HEALTH amp
ENVIRONMENT
PROTECTION
Cetaminereg Benefits for your System
Due a lower toxicityimpact 17-06-2016 29
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetamine Ecological and Toxicological Certifications for
Safe applycation
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 30
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetaminereg Technology for Boiler Treatment and CC
17-06-2016 31
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Steam Generators
Cetaminereg G810 Low Pressure boiler Softened water (good quality)
Cetaminereg G811 High Pressure boiler Demin water power plants
Cetaminereg G818 Low P on-line clean Softened water (poor quality)
32
THE CETAMINEreg PRODUCTS SHORT RANGE EXAMPLES
Hydrazine Cyclohexylamine- free
17-06-2016
Closed Heating Cooling
Cetaminereg G900 Closed systems Systems containing copper brass
Specific Products
Cetaminereg G817 Food Industry Food Industry FDA sect 173310
Cetaminereg G815 Dry Lay up DRY LAY-UP
Cetaminereg G830 Wet Lay ip WET LAY-UP
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Over 1000 applications
in Steam Boilers amp Closed loops
Case Studies Approvals
amp References
CETAMINEreg Concept
17-06-2016 33
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
A paper mill reduces by 50 its
water consumption with
Cetaminereg
CREATING VALUE TO CUSTOMERS
17-06-2016 34
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
35
Total Cost of Ownership
A paper mill reduces by 50 its water
consumption with Cetaminereg
17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Total Cost of Ownership
163keuro saved by Wood
Manufacturer with Cetaminereg
17-06-2016 36
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
37
Case 2 Pertochemical Plant Solution to Corrosion
Example of boiler tube in HP Turbine
17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
A steel mill saves 200 000euro in
closed circuit treatment with
Cetaminereg technology
38
Corrosion Protection in front of a
Crisis situation
The entrance of organic matterial in the
steam generator produces acid by
degradation that will cause strong
corrosion
Case 1 Refinery Solution to Corrosion in Crisis
The CFA ndash layer permits to minimize the
corrosion impact significantly in such
crisis situations giving the operator high-
value time to react
17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
39
CETAMINEreg REFERENCES EXAMPLE ndash INDUSTRIAL POWER PLANT
17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
FDA Certification by Prestige Food Organisations
Certifications by European
Food Regulamentation
ISEGA Certification European Regulation (EC) No 49352004 Food Industry Regulacioacuten Animal Food Code ndash LFGB
Toxicological Technical Study Toxicological Study for Cetamine V217 as boiler water additive in
food industries steam production
CERTIFICATIONS Cetaminereg in FampB Industries
Prestige Level
17-06-2016 40
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
41
Cetaminereg for Food Industry
V217
Certification letter issued by the FDA
17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetaminereg ndash Hundreds of Reference Letters in Heavy Industry
42 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Cetaminereg
Reference
In Paper Mill
43 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
CETAMINEreg REFERENCES
BOILER MANUFACTURERS
RECOMMENDATION
17-06-2016 44
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Industria
Refineriacutea amp Petroquiacutemica
Reference Letter
17-06-2016 45
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016
Type of industry Operational pressure
[bar] Steam capacity [Th
lbsh]
CHP plant 113 250
TLE (petrochemical) 125 350
Power plant 145 670
Petrochemical 210 170
Steel Mill 70 340
Power plant 135 660
Gas purification 30 400
Paper mill 90 120
CETAMINEreg TECHNOLOGY ndash TYPICAL APPLICATIONS
46 17-06-2016