jozef stefan institute plasma laboratory ljubljana, slovenia chemical cleaning with neutral oxygen...

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Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms M M iran iran Mozeti Mozeti č č Jozef Stefan Institute, P l asm a lab Department of Surface Engineering and Optoelectronics

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Page 1: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute

Plasma laboratory

Ljubljana, Slovenia

Chemical cleaning

with neutral oxygen or nitrogen atoms

MMiraniran Mozeti Mozetičč

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Page 2: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Fast removal of HC deposits

Benign to CFC

No oksidation of metals

Mednarodna podiplomska šola Jožefa Stefana

Application of neutral atoms (O or N)

Page 3: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Tokamak

Remote O – atom source

Connection tube

Page 4: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

O atom source is inductively coupled RF plasma

1.2 kW

5kW

We are building 15 kW source

Page 5: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

O atom density at 500W

Pressure

Ato

m d

ensi

ty

P - limited

p -lim

ited

- lim

ited

Pressure

Ato

m d

ensi

ty

P - limited

p -lim

ited

- lim

ited

These values are measured in a side tube. The density in the major discharge tube is 2x larger

Page 6: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Connection tube is made from material with a low coefficient for heterogeneous surface recombination γ < 10-4

The transmission of the tube depends on • the recombination coefficient• gas drift velocity• length of the tube

Drift velocity is close to sound velocity (300m/s)

Page 7: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

FLUID simulations

plasma

Connection tube

To pump

Page 8: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Experiment fits the theory

Oxy

gen

ato

m d

ensi

ty

Tube length [m]

Page 9: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Influence of effective pumping speed

8 m3/h 16m3/h

Page 10: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Setup under construction

plasma

n = 4x1022m-3

n > 1x1021m-3

Experimental chamber

3m long tube Schott 8250

Roots 500m3/h

Rotary 100m3/h

Page 11: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

Experimental chamber

O atom inlet

To pumps

Heatable sample holder

Oxidation probability depends on

• type of CH

• temperature

Page 12: Jozef Stefan Institute Plasma laboratory Ljubljana, Slovenia Chemical cleaning with neutral oxygen or nitrogen atoms Miran Mozetič Jozef Stefan Institute,

Jozef Stefan Institute,

Plasma

labDepartment of Surface Engineering and Optoelectronics

HC film prepared by magnetron sputtering in Ar + H2 (pretty hard coating)

nO = 1021 m-3