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Ken Goodson Mechanical Engineering Stanford University 15 th International Workshop on Computational Electronics Phonon School May 21, 2012 Phonons in NanoElectronics With Wong Group, Stanford EE With Vuckovic Group, Stanford EE silicon nanoladders

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Page 1: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Ken GoodsonMechanical Engineering

Stanford University

15th International Workshop on Computational ElectronicsPhonon School May 21, 2012

Phonons in NanoElectronics

With Wong Group,Stanford EE

With Vuckovic Group,Stanford EE

silicon nanoladders

Page 2: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Electronics Thermal Challenges

portables

servers

transportation defense

energy efficiency

hotspot mitigation

heterogeneousintegration

Page 3: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

portables

servers

transportation defense

Electronics Thermal Challenges

Page 4: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

IBM-3M Press Release

September 2011

iPad3 iPad2March 2012

October 2012

Electronics Cooling in the News

Page 5: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Intel (2012)

Finally, commercialfinFETs

Finally, commercialphase change memory

Phonons in the News?

Samsung Cell PhoneMemory, May 2011

Page 6: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Intel (2012)

Samsung Cell PhoneMemory, May 2011

Phonons in the News?

Page 7: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

- Intel

Gate Length (nm)

Rowlette & GoodsonTrans. Electron Devices (2008)

Phonons in the News?

Page 8: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Intel (2012)

VOL. 94 (2006)

Phonon

tSi

N(T)

300 K 343 K

Phonon Energy [meV]

1.0 V@25 nm

960 K

Boundary Scattering

Local PhononNonequlibrium

Phonons in the News?

Page 9: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Boundary Scattering (SOI MOSFET)

(Goodson & Flik 1992;Sverdrup et al. 2001)

Branch Nonequilibrium(BTE Moments)

(Lai and Arun Majumdar 1996)

Hotspot Emission (BTE)(Gang Chen 1996)

Intel (2012)

N(T)

300 K 343 K

Phonon Energy [meV]

1.0 V@25 nm

960 K

Phonons in the News?

Page 10: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Intel (2012)

IEEE TRANS. ELECTRON DEVICES (55) 2008

Coupled Electron Monte Carlo &Phonon BTE in 20 nm finFET

Effe

ctiv

e Te

mpe

ratu

re (K

)

finFET position (nm)

g-LO

diffusion

phononensembleBTE+MC

diffusionall LO

Phonons in the News?

Page 11: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

VOL. 98 (2010)

WONG, RAOUX, KIM, LIANG, REIFENBERG, RAJENDRAN, ASHEGHI, AND GOODSON

Tem

pera

ture

Phonons in the News?

Page 12: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

VOL. 98 (2010)

WONG, RAOUX, KIM, LIANG, REIFENBERG, RAJENDRAN, ASHEGHI, AND GOODSON

Electrode Interface(Reifenberg et al., 2007 & 2008)

Phase Interfaces & Electrons(Bozorg-Grayeli, 2011)

Thermoelectric Phenomena(Lee et al., 2012)

Phonons in PCRAM

Lee, Asheghi, Goodson,Nanotechnology (2012)

Phonons in the News?

(Kuzum, Wong, et al, 2011/2012)

Page 13: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Phase Change NanoCells

with Bosch(NSF/DOE Partnership)

OpticalNanocrystals

AlGaN

Diamond

with Brongersma group, Stanford MSE

GaN-DiamondComposites

with Intel TMG, IBM (SRC)and Wong Group, Stanford EE

NanoFETs

with KLA Tencor with Vuckovic group, Stanford EE

QuantumCavity Lasers

Extreme UVOptics

with Raytheon, Boeing, Boeing, BAE (DARPA NJTT)

Group4 Labs

with Intel ATD (SRC)

Nanostructured Packaging

Page 14: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Selected AlumniProf. Dan Fletcher UC Berkeley Dr. Jeremy Rowlette Daylight SolnsProf. Evelyn Wang MIT Dr. Patricia Gharagozloo Sandia LabsProf. Katsuo Kurabayashi U. Michigan Dr. Per Sverdrup IntelProf. Sungtaek Ju UCLA Dr. Chen Fang Exxon-MobileProf. Mehdi Asheghi Stanford Dr. Milnes David IBMProf. Bill King UIUC Dr. Max Touzelbaev AMDProf. Eric Pop UIUC (EE) Dr. Roger Flynn IntelProf. Sanjiv Sinha UIUC Dr. Julie Steinbrenner Xerox ParcProf. Xeujiao Hu Wuhan Univ. Dr. John Reifenberg IntelProf. Carlos Hidrovo UT Austin Dr. David Fogg CreareProf. Kaustav Banerjee UCSB (EE) Dr. Matthew Panzer KLA-TencorProf. Ankur Jain UT ArlingtonProf. Sarah Parikh Foothill College

Current Group Ken GoodsonJosef Miler Elah Bozorg-Grayeli Lewis HomMichael Barako Amy Marconnet Aditja Sood (MSE)Jaeho Lee Shilpi Roy (EE) Woosung ParcSri Lingamneni Yuan Gao Saniya Leblanc Yiyang Li (MSE) Dr. Takashi KodamaJungwan Cho Zijian Li Dr. Yoonjin Won

Prof. Mehdi Asheghi

Page 15: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Restrict the conduction lengthscale using nanofabrication

Restrict the conduction lengthscale using high speed optics

Nano Thermal Metrology

Sample Complexity

Rig

Com

plex

ity

How can we “see”thermal phonons?

Page 16: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Sample Complexity

Rig

Com

plex

ityNano Thermal Metrology

SiC / Diamond

GaN

12 ps pumpdelayed probe

Students: Cho, Bozorg-GrayeliElectron Device Letters (2012)

Students: Li, Lee, KodamaNano Letters (2012)

CNT Forest

Metal

Catalyst

Substrate

10 ns pumpcw probe

Students: Panzer, GaoNano Letters (2010)

Students: Yoneoka, Li, KodamaNano Letters (2012 in press)

Page 17: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Phonons in Nanowires & NanoTubesAppearing this month from Li Shi, UT Austin

Page 18: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

SiO2

Si3N4

nanotube Pt

Pt gate

2 μmnanotube on substrate suspended

over trench

Pop, Goodson, Dai et al., Nano Letters (2006), Pop, Goodson, Dai et al., Physical Review Letters (2005)

ExternalHeating

InternalHeating

Shi and Li, JHT (2003)Yu, Shi et al., Nanoletters (2005)

McConnell, Goodson et al. (2004)

Li, Majumdar, Yang, et al.Applied Physics Letters (2003)

Phonons in Nanowires & NanoTubes

Page 19: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Asheghi, Goodson, et al., Applied Physics Letters 71 (1997)

single-crystal Siburied oxide, ~2 microns thick

heater / thermometers

thick Si substrate

Measurement Structure

ThermalConductivity(W m-1 K-1)

Temperature (K)

10

100

1000

104

10 100

Bulk

1.60 m0.83 m0.42 m

3505

Phonon-Boundary Scattering

Films(SpectralFuchs/Sondheimer)

predictions

data

single-crystalsilicon

filmthickness

doping

Asheghi, Goodson, et al., J. Heat Transfer 120 (1998)

SOI-Enabled Phonon Studies 1994-

Page 20: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

SOI-Enabled Phonon Studies 1994-

single-crystal Siburied oxide, ~2 microns thick

heater / thermometers

thick Si substrate

Measurement Structure

doping

10 0

10 1

10 2

10 3

20 40 60 80 100

Ther

mal

con

duct

ivity

(Wm

-1K

-1)

300

ds=1.6 m

100 nm

20 nm

0.42 m

0.8 m

Bulk

ThermalConductivity(W m-1 K-1)

Temperature (K)

Asheghi, Goodson, et al., Applied Physics Letters 71 (1997) Asheghi, Goodson, et al., J. Heat Transfer 120 (1998) Liu and AsheghiJ. Heat Transfer 120 (2006)

Page 21: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

single-crystal Siburied oxide, ~2 microns thick

heater / thermometers (varying width)

thick Si substrate

Measurement Structure

Y. Sungtaek Junow with UCLA MAE

SOI-Enabled Phonon Studies 1994-

Ju, GoodsonApplied Physics Letters 74 (1999)

Page 22: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

single-crystal Sithinned oxide support from SOI

heater / thermometersMeasurement Structure

doped

Vacuum(suspended structure)

ThermalResistance

Ratio(SILICON / loss)

McConnell, Srinivasan, Goodson,et al., JMEMS 10 (2001)

metallization

Temperature (K) 0.0001

0.001

0.01

0.1

1

10 100Temperature (K)

SOI-Enabled Phonon Studies 1994-

Sverdrup, Sinha, Goodson et al., Applied Physics Letters 78 (2001)

Page 23: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Sverdrup, Sinha, Goodson et al., Applied Physics Letters 78 (2001)

Model: Sinha, Pop, Dutton, Goodson,J. Heat Transfer (2006)

single-crystal Sithinned oxide support from SOI

heater / thermometersMeasurement Structure

doped

Vacuum(suspended structure)

SOI-Enabled Phonon Studies 1994-

Temperature (K)

ExperimentalData

Rdiffusion

RBTE

Rboundaries

Rdiffusion+BTE

ThermalResistance

(K W-1)

Page 24: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

SOI-Enabled Phonon Studies2010- (boundaries & nanoholes)

Input Power (μW)

Quantum Cavity Lasers and WaveguidesGong, Vuckovic, et al., Stanford EE

Page 25: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

1. Silicon-On-Insulator Wafer

2. Deposit & Pattern (E-Beam Lithography) Photoresist

3. DRIE Etch Silicon Device Layer

4. Remove Oxide Layer To Suspend Device

5. Deposit Palladium Film

Nanoladder Device Fabrication

Dr. Taka Kodama

Page 26: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

MetalSilicon

Electron Phonon

Substrate

Current

T0 T0

Heat Path

Current

Ʌbulk

Ʌbulk

SOI-Enabled Phonon Studies2010- (boundaries & nanoholes)

V V

I ILiu and AsheghiApplied Physics Letters (2004)

Marconnet, Kodama, Asheghi, Goodson, et al. Nano & Microscale Thermophys. Eng. (2012)

Page 27: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

MetalSilicon

Electron Phonon

Current

T0 T0

Heat Path

Current

Ʌbulk

Ʌbulk

SOI-Enabled Phonon Studies2010- (boundaries & nanoholes)

Intrinsic

Page 28: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Probing the WFL at 7 nmYoneoka, Lee, Goodson, Kenny, et al., Nano Letters (2012)

ALD Pt

SiO2

Si

10 nm

Free-standing

Atomic Layer Deposition

Thermal conductivity (W/mK)

WFL using electrical conductivity

Metallization Thickness (nm)

phonon limit (MD)

Bulk Thermal Conductivity (W/mK)

Page 29: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

5 nm

a-Si (2.2 nm)

Poly-Mo (2.6 nm)a-MoSi2 (0.7 nm)

a-MoSi2 (1.3 nm)

Page 30: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Extreme UV Optics

Carl Zeiss AG

MoSi

EUV13.5 nm

θ

d

EUV reflection ~70%

Page 31: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

6.9 nm Mo/Si

40 bilayers total

Si Substrate

25 nm Al2O3Ti/Au

5umTi/Au

50nm

Ti/Au

ComparativeSample

Electrons & Phonons in Metal NanoLayers

0 5 10 15 200.6

0.7

0.8

0.9

1

Anisotropy Ratio

Nor

mal

ized

Tem

pera

ture

Ris

e

50nm100nm200nm500nm1m5m

Analytical solutions

Experimental data

25 nm Al2O3

Li, Goodson, et al., Nano Letters (2012), accepted and in pressBozorg-Grayeli, Li, Goodson, et al., Applied Physics Letters (2011)

dMo = 2.8nm, dSi = 4.1nm, kMo ~ 14 W/mK (WFL)

Page 32: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Anisotropy caused by:

- Series vs parallel film resistances = 2-3

- Discrete interface resistances and ballistic electrons, = 4-9

- Disorder and material interdiffusion at interfaces (smudging)

- Weak electron-phonon coupling and ballistic phonons?

Electrons & Phonons in Metal NanoLayers

Mo 2.8 nm

Si 4.1 nm

Si 4.1 nm

p

e-

p

p

e-

Li, Goodson, et al., Nano Letters (2012), accepted and in pressBozorg-Grayeli, Li, Goodson, et al., Applied Physics Letters (2011)

Page 33: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Electrons & Phonons in Metal NanoLayers

Mo 2.8 nm

Si 4.1 nm

Si 4.1 nm

p

e-

p

p

e-

Li, Goodson, et al., Nano Letters (2012), accepted and in pressBozorg-Grayeli, Li, Goodson, et al., Applied Physics Letters (2011)

100 101 102 10310-1

100

101

102

Film Thickness [nm]

Ther

mal

Res

ista

nce

[m2 K

/GW

]

Rp, approx. resistor model

Re, approx. resistor model

Rp, BTE

Re, BTE

Dominant Carrier Transition Thickness

2 /trans p e p e pd k k Gk k k

Page 34: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Future Phase Change Nanodevices

Field-Programmable Gate Arrays

RF-FPGA

SyNAPSE

Synapses for Brain-Inspired ComputingKuzum, Jeyasingh, Lee, Wong,Nano Letters (2011)

Lee, Asheghi, Wong, Goodson, et al. Electron Device Letters (2011)

Page 35: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

in-plane modelin-plane data

out-of-planedatamodel

Conductivity anisotropy modeled using JMAK phase transition and Maxwell-Eucken EMT

Phase Transition Complexity in Ge2Sb2Te5Lee, Li, Sinclair, Goodson, et al., Journal of Applied Physics (2011)

Li, Lee, Wong, Goodson et al., Electron Device Letters (2011)

Page 36: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

amorphous remnant at hcpgrain boundary

Phase Transition Complexity in Ge2Sb2Te5Lee, Li, Sinclair, Goodson, et al., Journal of Applied Physics (2011)

Li, Lee, Wong, Goodson et al., Electron Device Letters (2011)

Page 37: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Sample Complexity

Rig

Com

plex

ityNano Thermal Metrology

SiC / Diamond

GaN

12 ps pumpdelayed probe

Students: Cho, Bozorg-GrayeliElectron Device Letters (2012)

Students: Li, Lee, KodamaNano Letters (2012)

CNT Forest

Metal

Catalyst

Substrate

10 ns pumpcw probe

Students: Panzer, GaoNano Letters (2010)

Students: Yoneoka, Li, KodamaNano Letters (2012 in press)

Page 38: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

100 nm

CNT Forest

Metal

Metal CNT Catalyst

TransparentSubstrate

CNT ForestsStudents: Panzer, Gao, Marconnet

ACS Nano (2011)Nanoletters (2010)

J. Heat Transfer (2008)J. Electronic Materials (2009)

TDTR/TTR Sample Design

KLATencor

Students: Bozorg-Grayeli, Li, Reifenberg

Applied Physics Letters (2007)Electron Device Letters (2008, 2010, 2011)

Phase Change Interfaces

AlTaN

Mo/Si x 40

Si

44 +/- 4 nmwithIntel TMG

Extreme UVNanoOptics

Students: Bozorg-Grayeli, LiApplied Physics Letters (2012)

Nano Letters (2012)

NanoPhotonicCrystals (SRO/SRN)

Students:Rowlette, Kekatpure,

Marconnet

Physical Review B (2009)Applied Physics Lett. (2012)

Page 39: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Thermal Conductivity, k [W/m-K]

Required Measurement Timescales

AlCu

100

10

1

0.1

0.01

100 ns

1 ns

10 ps

OrganicPackagingTIMS,

Underfill

SiO2 , Si3N4 , HfO2, GST

amorphous passivation

Si, SiGe,GaAsGaN

33~* LdMat

eria

l Thi

ckne

ss, d

*[m

icro

ns]

10 s

Interconnect, vias, and transition layers

Semi‐conductors

metallic packageinterfaces

1 ps

Page 40: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Razeghi et al., N. J. Phys. (2009)

Diamond SubMountHEMT Composite Substrates

POWER FET Passivation

Quantum Cascade Laser SubMounts

Daimler

Diamond Composite SubstratesDARPA NJTT Programs

Proc. ITHERM 2012, with Group4 Labs

Page 41: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

0 2 4 6 8 10x 10-9

0

5

10

15

Time (s)

Nor

mal

ized

Ref

lect

ance

ExperimentTBR: 4 m2K/GW(Best Fit)TBR: 10 m2K/GW

SiC

GaN Buffer

50 nm Al Transducer

Probe

30 nm AlN Nucleation Layer

Stanford with Raytheon: Cho, Altman, Asheghi, Goodson, Electron Device Letters (2012)

TDTR Boundary Resistance Extraction

1/kGaN = 0.0055RGaN-SiC = 3.6

Sample kGaNW/m/K

RGaN-SiCm2K/GW

AlN thickness

nmRaytheon HEMT ps TDTR simul-fit

157 ±11

4.2 ± 0.6 27

Raytheon HEMT extrapolation

182 ±33

3.6 ± 1.6 27

12 ps pump

GaN Composite Substrates

1270 nm GaN

880 nm GaN

1562 nmGaN

Pump

Page 42: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Discrete carrier scattering at interfaces

Scattering on imperfections, stoichiometric impurities, and disorder in transition film

Near-interfacial disorder in primary composite substrate materials (GaN & Diamond)

Thermal Resistance Mechanisms

Active Region

Transition Layer

Diamond

P

P

P

Impurity scattering

Grain boundary scattering

Interface Scattering 

Roughness

Defect scattering

Near-interfacial disorder

nanoheat.stanford.edu 42

Page 43: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Discrete carrier scattering at interfaces

Scattering on imperfections, stoichiometric impurities, and disorder in transition film

Near-interfacial disorder in primary composite substrate materials (GaN & Diamond)

Active Region

Transition Layer

Substrate

P

P

P

Impurity scattering

Grain boundary scattering

Interface Scattering 

Roughness

Defect scattering

Near-interfacial disorder

Thermal Resistance Mechanisms

nanoheat.stanford.edu 43

Page 44: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

CVD diamond layer

Si Substrate

Metal coating

Heating pulsesfrom Nd:YAG

ToDetector

CW Radiationfor

Thermometry

Mean free path

Grain-boundary scattering strength2

1111 Gphononboundarygrainphonon

d

typesdefect

znz

x

dL

dG(z)

SINGLE-CRYSTAL SILICON SUBSTRATE

POLY- CRYSTAL DIAMOND

LAYER

OVERLAYER

Substrate

Film thickness, d (µm)

(10-8 m2 K W -1)

Ther

mal

Res

ista

nce

dG = 0.02 + 0.2z

dG = 0.1 + 0.5z

Goodson, ASME J. Heat Transfer (1996)Goodson et al., Journal of Applied Physics (1995)

Near-Interfacial DiamondTouzelbaev & Goodson, Diamond & Related Materials (1998)Touzelbaev & Goodson, J. Thermophysics & Heat Transfer (1998)

Page 45: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Metal

Si

0 0.2 0.4 0.6 0.8 1x 10-5

0

0.2

0.4

0.6

0.8

1

Seconds

T/Tm

ax

h1=3.4e5 W/m2Kh1=2.4e5 W/m2Kh1=4.4e5 W/m2K

0 0.2 0.4 0.6 0.8 1x 10-5

0

0.2

0.4

0.6

0.8

1

Seconds

T/Tm

ax

h2=1.0e5 W/m2Kh2=2.0e5 W/m2Kh2=1.5e5 W/m2K

time (s)

time (s)

Photothe

rmal Signal

Photothe

rmal Signal

Rapid optical heating and thermometry allows vertical resistance contributions to be extracted independently

Panzer, Goodson, et al., J. Heat Transfer (2008), NanoLetters (2010)Kaeding, Goodson, et al., Applied Physics Letters (1993)

Decreasing R1R1

R2

Decreasing R2

λ = 532nm, 6ns pulses at 10Hz

λ = 658nm

Nanosecond Thermoreflectance

Page 46: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Conduction Physics in CNT Films

SubstrateSubstrateSubstrateSubstrate

Individual CNT conductance

Inter-tube contact

Nanoscale metal-CNT interface resistance (phonons)

Partial nanotubeengagement

Spatially varying aligment

Growth interface resistance

Page 47: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

10-3 10-2 10-1 10010-1

100

101

102

103

104

Volume Fraction

Ther

mal

Con

duct

ivity

[W m

-1 K

-1]

(Wang et al., 2007a,b)(Yu et al., 2005)(Pop et al., 2006)(Li et al., 2009)(Choi et al., 2006)(Pettes et al., 2009)(Kim et al., 2001)(Fujii et al., 2005)(Li et al., 2009)(Choi et al., 2005)(Panzer et al., 2008)(Akoshima et al., 2009)(Hu et al., 2006)(Yang et al., 2002,2004)(Tong et al., 2007)(Tong et al., 2006)(Pal et al., 2008)(Borca-Tasciuc et al., 2005)(Ivanov et al., 2006)(Xie et al., 2007)(Okamoto et al., 2011)(Jakubinek et al., 2010)(Y. Xu et al., 2006)(Cola et al., 2007)(Zhang et al., 2005)(Zhang et al., 2007)(Pettes et al., 2009)ki = 3000 W/m/K

ki = 30 W/m/K

Marconnet, Panzer, Goodson, Reviews of Modern Physics (invited & submitted 2012)

Thermal Conductivities of Individual CNTs and Aligned Arrays

Page 48: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Data and Modeling for Individual SWNT-metal Interface Resistance

Hu et al.,2008 Diao et al. 2008;

MD simulationsSWNT-Si contact

geometry

010203040506070

0.005 0.006 0.007 0.008 0.009

Rindividual=Rmeas*φ

TiPt

Pd

Al

Ni

2D-AMM Prediction

φ = Ceff/Cv,individual

MD simulationsSWNT-Si contact

Hu et al.,2008Diao et al.,2008

Ther

mal

Res

ista

nce

(m2 K

/GW

)Panzer, Maruyama, Wardle, Goodson et al.,Nanoletters (2010)

Ceff

Thermal Sink

CNT

Metal

Page 49: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Sample Complexity

Rig

Com

plex

ityNano Thermal Metrology

SiC / Diamond

GaN

12 ps pumpdelayed probe

Students: Cho, Bozorg-GrayeliElectron Device Letters (2012)

Students: Li, Lee, KodamaNano Letters (2012)

CNT Forest

Metal

Catalyst

Substrate

10 ns pumpcw probe

Students: Panzer, GaoNano Letters (2010)

Students: Yoneoka, Li, KodamaNano Letters (2012 in press)

Optics &Nanostructures

Multi-property

Page 50: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Rowlette, Kekatpure, Brongersma, Goodson, et al., Physical Review B (2009)Marconnet, Yerci, Dal Negro, Goodson, et al., Applied Physics Letters (2012)

Förster-Auger

∆E

R

iDiA

fA

fD

phonon

Superlattice (SL)

3D

2D 1D

Thermal & Optical Properties of Silicon-Enriched Oxides & Nitrides

Page 51: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Superlattice (SL)

3D

2D 1D

Pump Intensity(532 nm)

20 nm multilayers

200 nm film~ Φ1/3

~ ΦFree-Carrier Absorption from Probe

(1064 nm)

Förster-Auger

∆E

R

iDiA

fA

fD

phonon

Rowlette, Kekatpure, Brongersma, Goodson, et al., Physical Review B (2009)Marconnet, Yerci, Dal Negro, Goodson, et al., Applied Physics Letters (2012)

Thermal & Optical Properties of Silicon-Enriched Oxides & Nitrides

Page 52: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Mechanical & Thermal Properties of Aligned CNT Films

750 µm

50 µm

Thermal MechanicalPump Laser Doppler 

Vibrometer (LDV)

Piezoelectric Shaker

Probe

Si substratePolysiliconOxideAl2O3FeCNT

Yoonjin Won, Matt Panzer, Amy Marconnet, et al.Carbon (2012)

MEMS Resonator

nanoheat.stanford.edu 52

Page 53: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Fabrication Process

CNT growthPolysilicon deposition

Resonator outline etching

200 Å Al2O3 deposition

10 Å Fe catalyst deposition

Resonator etching

Oxide layer removal

CNT growth process• A mixture of C2H4 and Ar gas flows through a tube furnace at 825°C • The carbon atoms from C2H4 dissolve into the catalyst nanoparticles• The carbons crystallize into stacks of flat sheets of hexagonally patterned carbon, which extrude as nanotubes

Catalyst nanoparticleAl2O3

CNTC2H4 + Ar

Si substratePolysiliconOxide

Al2O3FeCNT

53

Yoonjin Won, Matt Panzer, Amy Marconnet, et al., CARBON (2012)

Page 54: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Three‐layer Analysis

• Interweaving of a thin layer of entangled and randomly oriented nanotubes• Vertical‐aligned growth• Density decay

Growth Stages

crust

middle

DimensionlessEffective Modulus

SWCNTs (U. of Tokyo)

MWCNTs (Monano)

MWCNTs (MIT)

Two‐layer analysis  Three‐layer analysis

Stage 1 Stage 2

Self‐organization   Vertical‐growth

crust middle

SWCNT films

Theoretical curve for MWCNT films

wn

wn,Si,0

ESiISi,1 EMiddleIMiddle ETopITop

SiASi Middle AMiddle Top ATop

SiASi

ESiISi,0

1

: Moduli are scaled by reference sample and volume fraction

Won, Carbon (2011)

Modulus of Nonhomogeneous CNT Films

nanoheat.stanford.edu 54

Yoonjin Won, Matt Panzer, Amy Marconnet, Goodson, et al. CARBON (2012a)Yuan Gao, Takashi Kodama, Goodson, et al., CARBON (2012b)

Page 55: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Carbon 2012

LogicMemoryMemory

Chip Carrier

Primary ThermalInterface

2010

3D NanoPackaging

Page 56: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

LogicMemoryMemory

Chip Carrier

3D Stacking Interfaces

2011

CNT Composites

3D NanoPackaging

Page 57: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

LogicMemoryMemory

Chip Carrier

IBM-3M Press Release

September 2011

Materials Needs

IBM-Micron 3D press release, December 2011

3D NanoPackaging

Page 58: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

portables

servers

transportation defense

Thanks to our Sponsors

Page 59: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

portables

servers

transportation defense

Thanks to our Sponsors

Page 60: Ken Goodson Mechanical Engineering Stanford University · 2019. 10. 24. · Ken Goodson Mechanical Engineering Stanford University 15th International Workshop on Computational Electronics

Selected AlumniProf. Dan Fletcher UC Berkeley Dr. Jeremy Rowlette Daylight SolnsProf. Evelyn Wang MIT Dr. Patricia Gharagozloo Sandia LabsProf. Katsuo Kurabayashi U. Michigan Dr. Per Sverdrup IntelProf. Sungtaek Ju UCLA Dr. Chen Fang Exxon-MobileProf. Mehdi Asheghi Stanford Dr. Milnes David IBMProf. Bill King UIUC Dr. Max Touzelbaev AMDProf. Eric Pop UIUC (EE) Dr. Roger Flynn IntelProf. Sanjiv Sinha UIUC Dr. Julie Steinbrenner Xerox ParcProf. Xeujiao Hu Wuhan Univ. Dr. John Reifenberg IntelProf. Carlos Hidrovo UT Austin Dr. David Fogg CreareProf. Kaustav Banerjee UCSB (EE) Dr. Matthew Panzer KLA-TencorProf. Ankur Jain UT ArlingtonProf. Sarah Parikh Foothill College

Current Group Ken GoodsonJosef Miler Elah Bozorg-Grayeli Lewis HomMichael Barako Amy Marconnet Aditja Sood (MSE)Jaeho Lee Shilpi Roy (EE) Woosung ParcSri Lingamneni Yuan Gao Saniya Leblanc Yiyang Li (MSE) Dr. Takashi KodamaJungwan Cho Zijian Li Dr. Yoonjin Won

Prof. Mehdi Asheghi